CN103481593A - Environment-friendly fragrant aluminum-wood composite board as well as preparation method thereof - Google Patents

Environment-friendly fragrant aluminum-wood composite board as well as preparation method thereof Download PDF

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Publication number
CN103481593A
CN103481593A CN201310382946.4A CN201310382946A CN103481593A CN 103481593 A CN103481593 A CN 103481593A CN 201310382946 A CN201310382946 A CN 201310382946A CN 103481593 A CN103481593 A CN 103481593A
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Prior art keywords
paint
coating
coat
parts
aluminium
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CN201310382946.4A
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Chinese (zh)
Inventor
高峰
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SHANGHAI NINGSHENG MATERIAL TECHNOLOGY Co Ltd
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SHANGHAI NINGSHENG MATERIAL TECHNOLOGY Co Ltd
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Priority to CN201310382946.4A priority Critical patent/CN103481593A/en
Publication of CN103481593A publication Critical patent/CN103481593A/en
Priority to PCT/CN2014/000801 priority patent/WO2015027668A1/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/04—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B21/042—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of wood
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/10—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of wood
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/02—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board the layer being formed of fibres, chips, or particles, e.g. MDF, HDF, OSB, chipboard, particle board, hardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/06—Coating on the layer surface on metal layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00—Buildings or parts thereof
    • B32B2419/04—Tiles for floors or walls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2479/00—Furniture

Abstract

The invention discloses an environment-friendly fragrant aluminum-wood composite board. The composite board comprises a first fragrance coating layer, a first paint coating layer, a first aluminum sheet, a first glue coating layer and a base board, wherein the first paint coating layer is arranged on one surface of the first aluminum sheet, the first fragrance coating layer is arranged on the first paint coating layer, and the other surface of the first aluminum sheet is connected with the base board through the first glue coating layer. The composite board also comprises a second fragrance coating layer, a second paint coating layer, a second aluminum sheet and a second glue coating layer, the first paint coating layer is arranged on one surface of the first aluminum sheet, the first fragrance coating layer is arranged on the first paint coating layer, and the other surface of the first aluminum sheet is connected with the upper surface of the base board through the first glue coating layer.,wherein the second paint coating layer is arranged on one surface of the second aluminum sheet, the second fragrance coating layer is arranged on the second paint coating layer, and the other surface of the second aluminum sheet is connected with the lower surface of the base board through the second glue coating layer. The composite board added with a fragrance has a lasting and controllable fragrant smell which is stronger after the composite board is rubbed, and also has a self-closing function.

Description

Aluminium-wood composite board of a kind of environmental protection band fragrance and preparation method thereof
Technical field
The invention belongs to the aluminium-wood composite board technical field, relate in particular to aluminium-wood composite board of a kind of environmental protection band fragrance and preparation method thereof.
Background technology
Aluminium-wood composite board, be composited by aluminium sheet and plank, between aluminium sheet and plank, with seccotine, is bonded together.The aluminium-wood composite board of prior art generally adopts glue coated onboard, then the aluminium skin is attached on plank, and through high pressure, compacting forms.
The moisture-proof anticorrosive performance of the architectural constructional materials of pure plank is generally poor, is easy to make moist after long-term the use and deforms or go mouldy, and service life is very short; Yet the weight of the architectural constructional materials of simple metal system is heavier, be inconvenient to carry, also increased the cost of transportation.
Chinese patent CN101066633A, an open day 2007.11.7, disclose a kind of aluminium-wood composite board and production method thereof, adopts gluing, pastes the aluminium surface, the step such as cold pressing makes aluminium-wood composite board.Owing to wherein relating to colding pressing, make plank and aluminium leather block close, therefore, the defect on plank surface has all embodied out, such as the texture on indentation, projection, surface etc., makes air spots sliding, also not attractive in appearance.
In view of this, how research covers up the defect on plank surface itself, obtains surface smoothing, aluminium-wood composite board attractive in appearance is just necessary.
Summary of the invention
For the deficiencies in the prior art, the purpose of this invention is to provide a kind of aluminium-wood composite board of environmental protection band fragrance.
To achieve these goals, technical scheme of the present invention is as follows:
The invention provides a kind of aluminium-wood composite board of environmental protection band fragrance, comprise the fragrant coating of the first sense, first coat of paint, the first aluminium skin, the first function of glue coating and substrate, first coat of paint is positioned at the one side of the first aluminium skin, the fragrant coating of the first sense is positioned on first coat of paint, and the another side of the first aluminium skin is connected with substrate by the first function of glue coating.
As a kind of preferred technical scheme, the thickness of the fragrant coating of described the first sense is 5～50 μ.
As a kind of preferred technical scheme, the thickness of described first coat of paint is 10～25 μ.
As a kind of preferred technical scheme, the thickness of described the first aluminium skin is 60～120 μ.
As a kind of preferred technical scheme, the thickness of described the first function of glue coating is 20～60 μ.
As a kind of preferred technical scheme, the fragrant coating of described the first sense is modified poly ester paint.
As a kind of preferred technical scheme, described modified poly ester paint comprises the component of following mass percent:
Polyester paint: 75～93%,
Spices: 5～20%,
Diluent: 2～10%.
As a kind of preferred technical scheme, described spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000021
As a kind of preferred technical scheme, described auxiliary agent is geraniol, vanillyl alcohol, rhodinol, Vanillin acetate.
As a kind of preferred technical scheme, described diluent is butyl ether, cyclohexanone, n-butanol, isophorone.
As a kind of preferred technical scheme, described first coat of paint is polyester oil enamelled coating, water-based stoving paint layer, fluorine carbon enamelled coating, acrylic acid formula enamelled coating.
As a kind of preferred technical scheme, the component that described polyester oil enamelled coating polyester oil enamel-cover used is drawn together following weight portion: 400 parts of alkyd resins, 50 parts of delustering agents, 40 parts of dimethylbenzene, 30 parts of acetate resins, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.
As a kind of preferred technical scheme, described delustering agent is silica dioxide delustring agent.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 10 parts of defoamers, 10 parts of levelling agents.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described levelling agent is fluorin modified crylic acid ester levelling agent.
As a kind of preferred technical scheme, described water-based stoving paint layer water-based stoving paint used comprises the component of following weight portion: 50 parts of acrylic emulsions, 10 parts of polyaminoester emulsions, 40 parts of auxiliary agents.
As a kind of preferred technical scheme, the concentration of described acrylic emulsion is 55～60%.
As a kind of preferred technical scheme, the concentration of described polyaminoester emulsion is 35～45%.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 12.5 parts of defoamers, 12.5 parts of levelling agents, 75 parts of wetting agents.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described levelling agent is fluorine modified propylene ester levelling agent.
As a kind of preferred technical scheme, described wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
As a kind of preferred technical scheme, the component that described acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of delustering agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.
As a kind of preferred technical scheme, described delustering agent is silica dioxide delustring agent.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts, antistatic additive, 5 parts of levelling agents, 5 parts of defoamers.
As a kind of preferred technical scheme, described wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
As a kind of preferred technical scheme, described antistatic additive is the alkyl phosphate diethanolamine salt.
As a kind of preferred technical scheme, described levelling agent is fluorine modified propylene ester levelling agent.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described the first function of glue coating is PE macromolecule glue membrane coat.
As a kind of preferred technical scheme, described substrate is particieboard, low-density plank, high-density plate, multi-plywood, oriented structure chipboard.
The present invention also provides a kind of aluminium-wood composite board of environmental protection band fragrance, comprises the fragrant coating of the first sense, first coat of paint, the first aluminium skin, the first function of glue coating, the fragrant coating of the second sense, second coat of paint, the second aluminium skin, the second function of glue coating and substrate; First coat of paint is positioned at the one side of the first aluminium skin, and the fragrant coating of the first sense is positioned on first coat of paint, and the another side of the first aluminium skin is connected with the upper surface of substrate by the first function of glue coating; Second coat of paint is positioned at the one side of the second aluminium skin, and the fragrant coating of the second sense is positioned on second coat of paint, and the another side of the second aluminium skin is connected with the lower surface of substrate by the second function of glue coating.
As a kind of preferred technical scheme, the thickness of described the first fragrant coating of sense and the fragrant coating of the second sense is 5～50 μ.
As a kind of preferred technical scheme, the thickness of described first coat of paint and second coat of paint is 10～25 μ.
As a kind of preferred technical scheme, the thickness of described the first aluminium skin and the second aluminium skin is 60～120 μ.
As a kind of preferred technical scheme, the thickness of described the first function of glue coating and the second function of glue coating is 20～60 μ.
As a kind of preferred technical scheme, described the first fragrant coating of sense and the fragrant coating of the second sense are modified poly ester paint.
As a kind of preferred technical scheme, described modified poly ester paint comprises the component of following mass percent:
Polyester paint: 75～93%,
Spices: 5～20%,
Diluent: 2～10%.
As a kind of preferred technical scheme, described spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000031
Figure BDA0000373187590000041
As a kind of preferred technical scheme, described auxiliary agent is geraniol, vanillyl alcohol, rhodinol, Vanillin acetate.
As a kind of preferred technical scheme, described diluent is butyl ether, cyclohexanone, n-butanol, isophorone.
As a kind of preferred technical scheme, described first coat of paint and second coat of paint are polyester oil enamelled coating, water-based stoving paint layer, fluorine carbon enamelled coating, acrylic acid formula enamelled coating.
As a kind of preferred technical scheme, the component that described polyester oil enamelled coating polyester oil enamel-cover used is drawn together following weight portion: 400 parts of alkyd resins, 50 parts of delustering agents, 40 parts of dimethylbenzene, 30 parts of acetate resins, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.
As a kind of preferred technical scheme, described delustering agent is silica dioxide delustring agent.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 10 parts of defoamers, 10 parts of levelling agents.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described levelling agent is fluorin modified crylic acid ester levelling agent.
As a kind of preferred technical scheme, described water-based stoving paint layer water-based stoving paint used comprises the component of following weight portion: 50 parts of acrylic emulsions, 10 parts of polyaminoester emulsions, 40 parts of auxiliary agents.
As a kind of preferred technical scheme, the concentration of described acrylic emulsion is 55～60%.
As a kind of preferred technical scheme, the concentration of described polyaminoester emulsion is 35～45%.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 12.5 parts of defoamers, 12.5 parts of levelling agents, 75 parts of wetting agents.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described levelling agent is fluorine modified propylene ester levelling agent.
As a kind of preferred technical scheme, described wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
As a kind of preferred technical scheme, the component that described acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of delustering agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.
As a kind of preferred technical scheme, described delustering agent is silica dioxide delustring agent.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts, antistatic additive, 5 parts of levelling agents, 5 parts of defoamers.
As a kind of preferred technical scheme, described wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
As a kind of preferred technical scheme, described antistatic additive is the alkyl phosphate diethanolamine salt.
As a kind of preferred technical scheme, described levelling agent is fluorine modified propylene ester levelling agent.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described the first function of glue coating and the second function of glue coating are PE macromolecule glue membrane coat.
As a kind of preferred technical scheme, described substrate is particieboard, low-density plank, high-density plate, multi-plywood, oriented structure chipboard.
The invention provides a kind of aluminium-wood composite board of environmental protection band fragrance, comprise the fragrant coating of the first sense, the first printed coating, first coat of paint, the first aluminium skin, the first function of glue coating and substrate, first coat of paint is positioned at the one side of the first aluminium skin, the first printed coating is positioned on first coat of paint, the fragrant coating of the first sense is positioned on the first printed coating, and the another side of the first aluminium skin is connected with substrate by the first function of glue coating.
As a kind of preferred technical scheme, the thickness of the fragrant coating of described the first sense is 5～50 μ.
As a kind of preferred technical scheme, the thickness of described the first printed coating is 5～10 μ.
As a kind of preferred technical scheme, the thickness of described first coat of paint is 10～25 μ.
As a kind of preferred technical scheme, the thickness of described the first aluminium skin is 60～120 μ.
As a kind of preferred technical scheme, the thickness of described the first function of glue coating is 20～60 μ.
As a kind of preferred technical scheme, the fragrant coating of described the first sense is modified poly ester paint.
As a kind of preferred technical scheme, described modified poly ester paint comprises the component of following mass percent:
Polyester paint: 75～93%,
Spices: 5～20%,
Diluent: 2～10%.
As a kind of preferred technical scheme, described spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000051
As a kind of preferred technical scheme, described auxiliary agent is geraniol, vanillyl alcohol, rhodinol, Vanillin acetate.
As a kind of preferred technical scheme, described diluent is butyl ether, cyclohexanone, n-butanol, isophorone.
As a kind of preferred technical scheme, what described the first printed coating applied is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent 3.5%, anti-skinning agent 0.5%, toner 5%.
As a kind of preferred technical scheme, described macromolecule dispersing agent is ethylene group bis-stearamides, stearic acid monoglyceride or glyceryl tristearate.
As a kind of preferred technical scheme, described anti-skinning agent is methyl ethyl ketoxime.
As a kind of preferred technical scheme, described toner is iron oxide red, cadmium red, toluidine red, iron oxide yellow, chrome yellow, benzidine yellow, chrome oxide green, chrome green, barba hispanica, cobalt blue, ultramarine or phthalocyanine blue.
As a kind of preferred technical scheme, described first coat of paint is polyester oil enamelled coating, water-based stoving paint layer, fluorine carbon enamelled coating, acrylic acid formula enamelled coating.
As a kind of preferred technical scheme, the component that described polyester oil enamelled coating polyester oil enamel-cover used is drawn together following weight portion: 400 parts of alkyd resins, 50 parts of delustering agents, 40 parts of dimethylbenzene, 30 parts of acetate resins, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.
As a kind of preferred technical scheme, described delustering agent is silica dioxide delustring agent.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 10 parts of defoamers, 10 parts of levelling agents.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described levelling agent is fluorin modified crylic acid ester levelling agent.
As a kind of preferred technical scheme, described water-based stoving paint layer water-based stoving paint used comprises the component of following weight portion: 50 parts of acrylic emulsions, 10 parts of polyaminoester emulsions, 40 parts of auxiliary agents.
As a kind of preferred technical scheme, the concentration of described acrylic emulsion is 55～60%.
As a kind of preferred technical scheme, the concentration of described polyaminoester emulsion is 35～45%.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 12.5 parts of defoamers, 12.5 parts of levelling agents, 75 parts of wetting agents.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described levelling agent is fluorine modified propylene ester levelling agent.
As a kind of preferred technical scheme, described wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
As a kind of preferred technical scheme, the component that described acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of delustering agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.
As a kind of preferred technical scheme, described delustering agent is silica dioxide delustring agent.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts, antistatic additive, 5 parts of levelling agents, 5 parts of defoamers.
As a kind of preferred technical scheme, described wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
As a kind of preferred technical scheme, described antistatic additive is the alkyl phosphate diethanolamine salt.
As a kind of preferred technical scheme, described levelling agent is fluorine modified propylene ester levelling agent.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described the first function of glue coating is PE macromolecule glue membrane coat.
As a kind of preferred technical scheme, described substrate is particieboard, low-density plank, high-density plate, multi-plywood, oriented structure chipboard.
The present invention also provides a kind of aluminium-wood composite board of environmental protection band fragrance, comprises the fragrant coating of the first sense, the first printed coating, first coat of paint, the first aluminium skin, the first function of glue coating, the fragrant coating of the second sense, the second printed coating, second coat of paint, the second aluminium skin, the second function of glue coating and substrate; First coat of paint is positioned at the one side of the first aluminium skin, and the first printed coating is positioned on first coat of paint, and the fragrant coating of the first sense is positioned on the first printed coating, and the another side of the first aluminium skin is connected with the upper surface of substrate by the first function of glue coating; Second coat of paint is positioned at the one side of the second aluminium skin, and the second printed coating is positioned on second coat of paint, and the fragrant coating of the second sense is positioned on the second printed coating, and the another side of the second aluminium skin is connected with the lower surface of substrate by the second function of glue coating.
As a kind of preferred technical scheme, the thickness of described the first fragrant coating of sense and the fragrant coating of the second sense is 5～50 μ.
As a kind of preferred technical scheme, the thickness of described the first printed coating and the second printed coating is 5～10 μ.
As a kind of preferred technical scheme, the thickness of described first coat of paint and second coat of paint is 10～25 μ.
As a kind of preferred technical scheme, the thickness of described the first aluminium skin and the second aluminium skin is 60～120 μ.
As a kind of preferred technical scheme, the thickness of described the first function of glue coating and the second function of glue coating is 20～60 μ.
As a kind of preferred technical scheme, described the first fragrant coating of sense and the fragrant coating of the second sense are modified poly ester paint.
As a kind of preferred technical scheme, described modified poly ester paint comprises the component of following mass percent:
Polyester paint: 75～93%,
Spices: 5～20%,
Diluent: 2～10%.
As a kind of preferred technical scheme, described spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000071
As a kind of preferred technical scheme, described auxiliary agent is geraniol, vanillyl alcohol, rhodinol, Vanillin acetate.
As a kind of preferred technical scheme, described diluent is butyl ether, cyclohexanone, n-butanol, isophorone.
As a kind of preferred technical scheme, what described the first printed coating and the second printed coating applied is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent 3.5%, anti-skinning agent 0.5%, toner 5%.
As a kind of preferred technical scheme, described macromolecule dispersing agent is ethylene group bis-stearamides, stearic acid monoglyceride or glyceryl tristearate.
As a kind of preferred technical scheme, described anti-skinning agent is methyl ethyl ketoxime.
As a kind of preferred technical scheme, described toner is iron oxide red, cadmium red, toluidine red, iron oxide yellow, chrome yellow, benzidine yellow, chrome oxide green, chrome green, barba hispanica, cobalt blue, ultramarine or phthalocyanine blue.
As a kind of preferred technical scheme, described first coat of paint and second coat of paint are polyester oil enamelled coating, water-based stoving paint layer, fluorine carbon enamelled coating, acrylic acid formula enamelled coating.
As a kind of preferred technical scheme, the component that described polyester oil enamelled coating polyester oil enamel-cover used is drawn together following weight portion: 400 parts of alkyd resins, 50 parts of delustering agents, 40 parts of dimethylbenzene, 30 parts of acetate resins, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.
As a kind of preferred technical scheme, described delustering agent is silica dioxide delustring agent.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 10 parts of defoamers, 10 parts of levelling agents.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described levelling agent is fluorin modified crylic acid ester levelling agent.
As a kind of preferred technical scheme, described water-based stoving paint layer water-based stoving paint used comprises the component of following weight portion: 50 parts of acrylic emulsions, 10 parts of polyaminoester emulsions, 40 parts of auxiliary agents.
As a kind of preferred technical scheme, the concentration of described acrylic emulsion is 55～60%.
As a kind of preferred technical scheme, the concentration of described polyaminoester emulsion is 35～45%.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 12.5 parts of defoamers, 12.5 parts of levelling agents, 75 parts of wetting agents.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described levelling agent is fluorine modified propylene ester levelling agent.
As a kind of preferred technical scheme, described wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
As a kind of preferred technical scheme, the component that described acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of delustering agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.
As a kind of preferred technical scheme, described delustering agent is silica dioxide delustring agent.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts, antistatic additive, 5 parts of levelling agents, 5 parts of defoamers.
As a kind of preferred technical scheme, described wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
As a kind of preferred technical scheme, described antistatic additive is the alkyl phosphate diethanolamine salt.
As a kind of preferred technical scheme, described levelling agent is fluorine modified propylene ester levelling agent.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described the first function of glue coating and the second function of glue coating are PE macromolecule glue membrane coat.
As a kind of preferred technical scheme, described substrate is particieboard, low-density plank, high-density plate, multi-plywood, oriented structure chipboard.
The invention provides a kind of aluminium-wood composite board of environmental protection band fragrance, comprise the fragrant coating of the first sense, the first false proof layer, the first printed coating, first coat of paint, the first aluminium skin, the first function of glue coating and substrate, first coat of paint is positioned at the one side of the first aluminium skin, the first printed coating is positioned on first coat of paint, the first false proof layer is positioned on the first printed coating, the fragrant coating of the first sense is positioned on the first false proof layer, and the another side of the first aluminium skin is connected with substrate by the first function of glue coating.
As a kind of preferred technical scheme, the thickness of the fragrant coating of described the first sense is 5～50 μ.
As a kind of preferred technical scheme, the thickness of described the first false proof layer is 1～10 μ.
As a kind of preferred technical scheme, the thickness of described the first printed coating is 5～10 μ.
As a kind of preferred technical scheme, the thickness of described first coat of paint is 10～25 μ.
As a kind of preferred technical scheme, the thickness of described the first aluminium skin is 60～120 μ.
As a kind of preferred technical scheme, the thickness of described the first function of glue coating is 20～60 μ.
As a kind of preferred technical scheme, the fragrant coating of described the first sense is modified poly ester paint.
As a kind of preferred technical scheme, described modified poly ester paint comprises the component of following mass percent:
Polyester paint: 75～93%,
Spices: 5～20%,
Diluent: 2～10%.
As a kind of preferred technical scheme, described spices comprises the component of following quality percentage composition:
As a kind of preferred technical scheme, described auxiliary agent is geraniol, vanillyl alcohol, rhodinol, Vanillin acetate.
As a kind of preferred technical scheme, described diluent is butyl ether, cyclohexanone, n-butanol, isophorone.
As a kind of preferred technical scheme, what described the first false proof layer was used is fluorescent material.
As a kind of preferred technical scheme, what described the first printed coating applied is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent 3.5%, anti-skinning agent 0.5%, toner 5%.
As a kind of preferred technical scheme, described macromolecule dispersing agent is ethylene group bis-stearamides, stearic acid monoglyceride or glyceryl tristearate.
As a kind of preferred technical scheme, described anti-skinning agent is methyl ethyl ketoxime.
As a kind of preferred technical scheme, described toner is iron oxide red, cadmium red, toluidine red, iron oxide yellow, chrome yellow, benzidine yellow, chrome oxide green, chrome green, barba hispanica, cobalt blue, ultramarine or phthalocyanine blue.
As a kind of preferred technical scheme, described first coat of paint is polyester oil enamelled coating, water-based stoving paint layer, fluorine carbon enamelled coating, acrylic acid formula enamelled coating.
As a kind of preferred technical scheme, the component that described polyester oil enamelled coating polyester oil enamel-cover used is drawn together following weight portion: 400 parts of alkyd resins, 50 parts of delustering agents, 40 parts of dimethylbenzene, 30 parts of acetate resins, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.
As a kind of preferred technical scheme, described delustering agent is silica dioxide delustring agent.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 10 parts of defoamers, 10 parts of levelling agents.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described levelling agent is fluorin modified crylic acid ester levelling agent.
As a kind of preferred technical scheme, described water-based stoving paint layer water-based stoving paint used comprises the component of following weight portion: 50 parts of acrylic emulsions, 10 parts of polyaminoester emulsions, 40 parts of auxiliary agents.
As a kind of preferred technical scheme, the concentration of described acrylic emulsion is 55～60%.
As a kind of preferred technical scheme, the concentration of described polyaminoester emulsion is 35～45%.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 12.5 parts of defoamers, 12.5 parts of levelling agents, 75 parts of wetting agents.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described levelling agent is fluorine modified propylene ester levelling agent.
As a kind of preferred technical scheme, described wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
As a kind of preferred technical scheme, the component that described acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of delustering agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.
As a kind of preferred technical scheme, described delustering agent is silica dioxide delustring agent.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts, antistatic additive, 5 parts of levelling agents, 5 parts of defoamers.
As a kind of preferred technical scheme, described wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
As a kind of preferred technical scheme, described antistatic additive is the alkyl phosphate diethanolamine salt.
As a kind of preferred technical scheme, described levelling agent is fluorine modified propylene ester levelling agent.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described the first function of glue coating is PE macromolecule glue membrane coat.
As a kind of preferred technical scheme, described substrate is particieboard, low-density plank, high-density plate, multi-plywood, oriented structure chipboard.
The invention provides a kind of aluminium-wood composite board of environmental protection band fragrance, comprise the fragrant coating of the first sense, the first false proof layer, the first printed coating, first coat of paint, the first aluminium skin, the first function of glue coating, the fragrant coating of the second sense, the second false proof layer, the second printed coating, second coat of paint, the second aluminium skin, the second function of glue coating and substrate; First coat of paint is positioned at the one side of the first aluminium skin, the first printed coating is positioned on first coat of paint, the first false proof layer is positioned on the first printed coating, and the fragrant coating of the first sense is positioned on the first false proof layer, and the another side of the first aluminium skin is connected with the upper surface of substrate by the first function of glue coating; Second coat of paint is positioned at the one side of the second aluminium skin, the second printed coating is positioned on second coat of paint, the second false proof layer is positioned on the second printed coating, and the fragrant coating of the second sense is positioned on the second false proof layer, and the another side of the second aluminium skin is connected with the lower surface of substrate by the second function of glue coating.
As a kind of preferred technical scheme, the thickness of described the first fragrant coating of sense and the fragrant coating of the second sense is 5～50 μ.
As a kind of preferred technical scheme, the thickness of described the first false proof layer and the second false proof layer is 1～10 μ.
As a kind of preferred technical scheme, the thickness of described the first printed coating and the second printed coating is 5～10 μ.
As a kind of preferred technical scheme, the thickness of described first coat of paint and second coat of paint is 10～25 μ.
As a kind of preferred technical scheme, the thickness of described the first aluminium skin and the second aluminium skin is 60～120 μ.
As a kind of preferred technical scheme, the thickness of described the first function of glue coating and the second function of glue coating is 20～60 μ.
As a kind of preferred technical scheme, described the first fragrant coating of sense and the fragrant coating of the second sense are modified poly ester paint.
As a kind of preferred technical scheme, described modified poly ester paint comprises the component of following mass percent:
Polyester paint: 75～93%,
Spices: 5～20%,
Diluent: 2～10%.
As a kind of preferred technical scheme, described spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000111
Figure BDA0000373187590000121
As a kind of preferred technical scheme, described auxiliary agent is geraniol, vanillyl alcohol, rhodinol, Vanillin acetate.
As a kind of preferred technical scheme, described diluent is butyl ether, cyclohexanone, n-butanol, isophorone.
As a kind of preferred technical scheme, what described the first false proof layer and the second false proof layer were used is fluorescent material.
As a kind of preferred technical scheme, what described the first printed coating and the second printed coating applied is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent 3.5%, anti-skinning agent 0.5%, toner 5%.
As a kind of preferred technical scheme, described macromolecule dispersing agent is ethylene group bis-stearamides, stearic acid monoglyceride or glyceryl tristearate.
As a kind of preferred technical scheme, described anti-skinning agent is methyl ethyl ketoxime.
As a kind of preferred technical scheme, described toner is iron oxide red, cadmium red, toluidine red, iron oxide yellow, chrome yellow, benzidine yellow, chrome oxide green, chrome green, barba hispanica, cobalt blue, ultramarine or phthalocyanine blue.
As a kind of preferred technical scheme, described first coat of paint and second coat of paint are polyester oil enamelled coating, water-based stoving paint layer, fluorine carbon enamelled coating, acrylic acid formula enamelled coating.
As a kind of preferred technical scheme, the component that described polyester oil enamelled coating polyester oil enamel-cover used is drawn together following weight portion: 400 parts of alkyd resins, 50 parts of delustering agents, 40 parts of dimethylbenzene, 30 parts of acetate resins, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.
As a kind of preferred technical scheme, described delustering agent is silica dioxide delustring agent.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 10 parts of defoamers, 10 parts of levelling agents.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described levelling agent is fluorin modified crylic acid ester levelling agent.
As a kind of preferred technical scheme, described water-based stoving paint layer water-based stoving paint used comprises the component of following weight portion: 50 parts of acrylic emulsions, 10 parts of polyaminoester emulsions, 40 parts of auxiliary agents.
As a kind of preferred technical scheme, the concentration of described acrylic emulsion is 55～60%.
As a kind of preferred technical scheme, the concentration of described polyaminoester emulsion is 35～45%.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 12.5 parts of defoamers, 12.5 parts of levelling agents, 75 parts of wetting agents.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described levelling agent is fluorine modified propylene ester levelling agent.
As a kind of preferred technical scheme, described wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
As a kind of preferred technical scheme, the component that described acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of delustering agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.
As a kind of preferred technical scheme, described delustering agent is silica dioxide delustring agent.
As a kind of preferred technical scheme, described auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts, antistatic additive, 5 parts of levelling agents, 5 parts of defoamers.
As a kind of preferred technical scheme, described wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
As a kind of preferred technical scheme, described antistatic additive is the alkyl phosphate diethanolamine salt.
As a kind of preferred technical scheme, described levelling agent is fluorine modified propylene ester levelling agent.
As a kind of preferred technical scheme, described defoamer is fluorine modification defoamer.
As a kind of preferred technical scheme, described the first function of glue coating and the second function of glue coating are PE macromolecule glue membrane coat.
As a kind of preferred technical scheme, described substrate is particieboard, low-density plank, high-density plate, multi-plywood, oriented structure chipboard.
The present invention compared with prior art, has the following advantages and beneficial effect:
1, put into spices in product of the present invention, have that lasting fragrance, fragrance are controlled, a function of the denseer and self-closure of fragrance after friction.
2, product of the present invention has advantages of purifying air, adsorbs toxic gas and peculiar smell, improves air quality.
3, product good weatherability of the present invention, be difficult for shank color, there is the water proof fire retardant effect.
4, product of the present invention has sealing, environmental protection, anti-ultraviolet effect.
5, product of the present invention can be used for furniture, at home, office, ornament and metope.
The specific embodiment
Below in conjunction with embodiment, the present invention is further detailed explanation.
Following agents useful for same:
Degreasing agent: main component is sulfuric acid, hydrofluoric acid, Suzhou vast outstanding chemical industry Co., Ltd.
Degreasing agent: main component is non-ionic surface active agent, Suzhou vast outstanding chemical industry Co., Ltd.
1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthalene ethene) ethyl ketone:
（1-(1,2,3,4,5,6,7,8-Octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone）
Secondary alcohol ethoxyl compound: Secondary alcohol ethoxylated
Embodiment 1
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000141
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 75% by quality percentage composition paint and quality percentage composition are 20%, add the diluent that the quality percentage composition is 5% while stirring, stirs 3h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.04:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 2:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 85 ℃, the passivator layer that is 1 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 5.5m by length is again dried for the second time, and temperature is 65 ℃,
Then first coat of paint that the one side applied thickness is 10 μ, first coat of paint is fluorine carbon enamelled coating, dry, temperature is 65 ℃, then the modified poly ester skin of paint that coating thickness is 5 μ on first coat of paint (the fragrant coating of the first sense), dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, temperature is 110 ℃; The baking oven that Second Region length is 10m, temperature is 225 ℃; The baking oven that the 3rd section length is 10m, temperature is 215 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 60 μ.
After particieboard is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 20 μ, and one side is spread the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The aluminium-wood composite board of the environmental protection band fragrance prepared, comprise the fragrant coating of the first sense, first coat of paint, the first aluminium skin, the first function of glue coating and substrate, first coat of paint is positioned at the one side of the first aluminium skin, the fragrant coating of the first sense is positioned on first coat of paint, and the another side of the first aluminium skin is connected with substrate by the first function of glue coating.
Modified poly ester of the present invention paint has anti-pollution function, the application aluminium of preparation has advantages of that output is high, energy consumption is low, continuous productive process manually less, high, the uvioresistant of weather resistance, good toughness, scratch resistant, acid and alkali-resistance, anti-solvent wiping, insect protected, mothproof.Owing to having added spices, lasting fragrance, after friction, fragrance is denseer.
Embodiment 2
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000151
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 80% by quality percentage composition paint and quality percentage composition are 18%, add the diluent that the quality percentage composition is 2% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.07:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.5 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 6m by length is again dried for the second time, and temperature is 70 ℃,
Then first coat of paint that the one side applied thickness is 20 μ, first coat of paint is the polyester oil enamelled coating, dries, temperature is 65 ℃, and the modified poly ester skin of paint that then coating thickness is 25 μ m on first coat of paint is dried for the third time, be divided into 3rd district, the baking oven that the first section length is 10m, temperature is 115 ℃; The baking oven that Second Region length is 10m, temperature is 230 ℃; The baking oven that the 3rd section length is 10m, temperature is 220 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 70 μ.
After low-density plank is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 60 μ, and one side is spread the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (2800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that polyester oil enamelled coating polyester oil enamel-cover used is drawn together following weight portion: 400 parts of alkyd resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of acetate resins, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 10 parts of fluorine modification defoamers, 10 parts of fluorin modified crylic acid ester levelling agents.
Embodiment 3
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000161
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 93% by quality percentage composition paint and quality percentage composition are 5%, add the diluent that the quality percentage composition is 2% while stirring, stirs 5h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.1:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 4:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 95 ℃, the passivator layer that is 2 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.5m by length is again dried for the second time, and temperature is 75 ℃,
Then first coat of paint that the one side applied thickness is 25 μ, first coat of paint is the water-based stoving paint layer, dries, temperature is 65 ℃, and the modified poly ester skin of paint that then coating thickness is 50 μ on first coat of paint is dried for the third time, be divided into 3rd district, the baking oven that the first section length is 10m, temperature is 120 ℃; The baking oven that Second Region length is 10m, temperature is 235 ℃; The baking oven that the 3rd section length is 10m, temperature is 225 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 80 μ.
After high-density plate is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 30 μ, and one side is spread the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (2800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
Water-based stoving paint layer water-based stoving paint used comprises the component of following weight portion: 50 parts of acrylic emulsions, 10 parts of polyaminoester emulsions, 40 parts of auxiliary agents.The concentration of acrylic emulsion is 55～60%; The concentration of polyaminoester emulsion is 35～45%.Auxiliary agent comprises the component of following weight portion: 12.5 parts of fluorine modification defoamers, 12.5 parts of fluorine modified propylene ester levelling agents, 75 parts of wetting agents; Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 4
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000171
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 88% by quality percentage composition paint and quality percentage composition are 9%, add the diluent that the quality percentage composition is 3% while stirring, stirs 2h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.05:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.3 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 5.8m by length is again dried for the second time, and temperature is 67 ℃,
Then first coat of paint that the one side applied thickness is 12.5 μ, first coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the modified poly ester skin of paint that coating thickness is 15 μ on first coat of paint, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, temperature is 112 ℃; The baking oven that Second Region length is 10m, temperature is 228 ℃; The baking oven that the 3rd section length is 10m, temperature is 216 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 90 μ.
After multi-plywood is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 40 μ, and one side is spread the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (2000 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts of antistatic additive alkyl phosphate diethanolamine salts, 5 parts of fluorine modified propylene ester levelling agents, 5 parts of fluorine modification defoamers.Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 5
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000181
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 80% by quality percentage composition paint and quality percentage composition are 10%, add the diluent that the quality percentage composition is 10% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.06:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 88 ℃, the passivator layer that is 1.4 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 6.2m by length is again dried for the second time, and temperature is 72 ℃,
Then first coat of paint that the one side applied thickness is 17.5 μ, first coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the modified poly ester skin of paint that coating thickness is 35 μ on first coat of paint, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, temperature is 116 ℃; The baking oven that Second Region length is 10m, temperature is 232 ℃; The baking oven that the 3rd section length is 10m, temperature is 218 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 100 μ.
After the oriented structure glued board is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 50 μ, and one side is spread the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (1500 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts of antistatic additive alkyl phosphate diethanolamine salts, 5 parts of fluorine modified propylene ester levelling agents, 5 parts of fluorine modification defoamers.Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 6
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000191
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 84% by quality percentage composition paint and quality percentage composition are 12%, add the diluent that the quality percentage composition is 4% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.08:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 92 ℃, the passivator layer that is 1.8 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.4m by length is again dried for the second time, and temperature is 74 ℃,
Then first coat of paint that the one side applied thickness is 22 μ, first coat of paint is fluorine carbon enamelled coating, dries, temperature is 65 ℃, and the modified poly ester skin of paint that then coating thickness is 45 μ m on first coat of paint is dried for the third time, be divided into 3rd district, the baking oven that the first section length is 10m, temperature is 118 ℃; The baking oven that Second Region length is 10m, temperature is 234 ℃; The baking oven that the 3rd section length is 10m, temperature is 224 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 120 μ.
After particieboard is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 35 μ, and one side is spread the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (1500 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
Embodiment 7
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000192
Figure BDA0000373187590000201
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 75% by quality percentage composition paint and quality percentage composition are 20%, add the diluent that the quality percentage composition is 5% while stirring, stirs 3h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.04:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 2:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 85 ℃, the passivator layer that is 1 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 5.5m by length is again dried for the second time, and temperature is 65 ℃,
Then first coat of paint that the one side applied thickness is 10 μ, first coat of paint is fluorine carbon enamelled coating, dry, temperature is 65 ℃, then the modified poly ester skin of paint that coating thickness is 5 μ on first coat of paint (the fragrant coating of the first sense), dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, temperature is 110 ℃; The baking oven that Second Region length is 10m, temperature is 225 ℃; The baking oven that the 3rd section length is 10m, temperature is 215 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 60 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.04:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 2:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 85 ℃, the passivator layer that is 1 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 5.5m by length is again dried for the second time, and temperature is 65 ℃,
Then second coat of paint that the one side applied thickness is 10 μ, second coat of paint is fluorine carbon enamelled coating, dry, temperature is 65 ℃, then the modified poly ester skin of paint that coating thickness is 5 μ on second coat of paint (the fragrant coating of the second sense), dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, temperature is 110 ℃; The baking oven that Second Region length is 10m, temperature is 225 ℃; The baking oven that the 3rd section length is 10m, temperature is 215 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 60 μ.
After particieboard is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 20 μ, spread respectively the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense prepared above and be coated with second coat of paint and the first aluminium skin of the fragrant coating of the second sense, send into hot press, closure, hot-forming (800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The aluminium-wood composite board of the environmental protection band fragrance of preparation, comprise the fragrant coating of the first sense, first coat of paint, the first aluminium skin, the first function of glue coating, the fragrant coating of the second sense, second coat of paint, the second aluminium skin, the second function of glue coating and substrate; First coat of paint is positioned at the one side of the first aluminium skin, and the fragrant coating of the first sense is positioned on first coat of paint, and the another side of the first aluminium skin is connected with the upper surface of substrate by the first function of glue coating; Second coat of paint is positioned at the one side of the second aluminium skin, and the fragrant coating of the second sense is positioned on second coat of paint, and the another side of the second aluminium skin is connected with the lower surface of substrate by the second function of glue coating.
Modified poly ester of the present invention paint has anti-pollution function, the application aluminium of preparation has advantages of that output is high, energy consumption is low, continuous productive process manually less, high, the uvioresistant of weather resistance, good toughness, scratch resistant, acid and alkali-resistance, anti-solvent wiping, insect protected, mothproof.Owing to having added spices, lasting fragrance, after friction, fragrance is denseer.
Embodiment 8
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000211
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 80% by quality percentage composition paint and quality percentage composition are 18%, add the diluent that the quality percentage composition is 2% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.07:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.5 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 6m by length is again dried for the second time, and temperature is 70 ℃,
Then first coat of paint that the one side applied thickness is 20 μ, first coat of paint is the polyester oil enamelled coating, dries, temperature is 65 ℃, and the modified poly ester skin of paint that then coating thickness is 25 μ m on first coat of paint is dried for the third time, be divided into 3rd district, the baking oven that the first section length is 10m, temperature is 115 ℃; The baking oven that Second Region length is 10m, temperature is 230 ℃; The baking oven that the 3rd section length is 10m, temperature is 220 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 70 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.07:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.5 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 6m by length is again dried for the second time, and temperature is 70 ℃,
Then second coat of paint that the one side applied thickness is 20 μ, second coat of paint is the polyester oil enamelled coating, dries, temperature is 65 ℃, and the modified poly ester skin of paint that then coating thickness is 25 μ m on second coat of paint is dried for the third time, be divided into 3rd district, the baking oven that the first section length is 10m, temperature is 115 ℃; The baking oven that Second Region length is 10m, temperature is 230 ℃; The baking oven that the 3rd section length is 10m, temperature is 220 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 70 μ.
After low-density plank is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 60 μ, spread respectively the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense prepared above and be coated with second coat of paint and the second aluminium skin of the fragrant coating of the second sense, send into hot press, closure, hot-forming (2800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that polyester oil enamelled coating polyester oil enamel-cover used is drawn together following weight portion: 400 parts of alkyd resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of acetate resins, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 10 parts of fluorine modification defoamers, 10 parts of fluorin modified crylic acid ester levelling agents.
Embodiment 9
Spices comprises the component of following quality percentage composition:
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 93% by quality percentage composition paint and quality percentage composition are 5%, add the diluent that the quality percentage composition is 2% while stirring, stirs 5h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.1:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 4:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 95 ℃, the passivator layer that is 2 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.5m by length is again dried for the second time, and temperature is 75 ℃,
Then first coat of paint that the one side applied thickness is 25 μ, first coat of paint is the water-based stoving paint layer, dries, temperature is 65 ℃, and the modified poly ester skin of paint that then coating thickness is 50 μ on first coat of paint is dried for the third time, be divided into 3rd district, the baking oven that the first section length is 10m, temperature is 120 ℃; The baking oven that Second Region length is 10m, temperature is 235 ℃; The baking oven that the 3rd section length is 10m, temperature is 225 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 80 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.1:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 4:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 95 ℃, the passivator layer that is 2 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.5m by length is again dried for the second time, and temperature is 75 ℃,
Then second coat of paint that the one side applied thickness is 25 μ, second coat of paint is the water-based stoving paint layer, dries, temperature is 65 ℃, and the modified poly ester skin of paint that then coating thickness is 50 μ on second coat of paint is dried for the third time, be divided into 3rd district, the baking oven that the first section length is 10m, temperature is 120 ℃; The baking oven that Second Region length is 10m, temperature is 235 ℃; The baking oven that the 3rd section length is 10m, temperature is 225 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 80 μ.
After high-density plate is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 30 μ, spread respectively the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense prepared above and be coated with second coat of paint and the second aluminium skin of the fragrant coating of the second sense, send into hot press, closure, hot-forming (2800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
Water-based stoving paint layer water-based stoving paint used comprises the component of following weight portion: 50 parts of acrylic emulsions, 10 parts of polyaminoester emulsions, 40 parts of auxiliary agents.The concentration of acrylic emulsion is 55～60%; The concentration of polyaminoester emulsion is 35～45%.Auxiliary agent comprises the component of following weight portion: 12.5 parts of fluorine modification defoamers, 12.5 parts of fluorine modified propylene ester levelling agents, 75 parts of wetting agents; Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 10
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000241
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 88% by quality percentage composition paint and quality percentage composition are 9%, add the diluent that the quality percentage composition is 3% while stirring, stirs 2h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.05:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.3 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 5.8m by length is again dried for the second time, and temperature is 67 ℃,
Then first coat of paint that the one side applied thickness is 12.5 μ, first coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the modified poly ester skin of paint that coating thickness is 15 μ on first coat of paint, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, temperature is 112 ℃; The baking oven that Second Region length is 10m, temperature is 228 ℃; The baking oven that the 3rd section length is 10m, temperature is 216 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 90 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.05:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.3 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 5.8m by length is again dried for the second time, and temperature is 67 ℃,
Then second coat of paint that the one side applied thickness is 12.5 μ, second coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the modified poly ester skin of paint that coating thickness is 15 μ on second coat of paint, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, temperature is 112 ℃; The baking oven that Second Region length is 10m, temperature is 228 ℃; The baking oven that the 3rd section length is 10m, temperature is 216 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 90 μ.
After multi-plywood is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 40 μ, spread respectively the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense prepared above and be coated with second coat of paint and the second aluminium skin of the fragrant coating of the second sense, send into hot press, closure, hot-forming (2000 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts of antistatic additive alkyl phosphate diethanolamine salts, 5 parts of fluorine modified propylene ester levelling agents, 5 parts of fluorine modification defoamers.Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 11
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000251
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 80% by quality percentage composition paint and quality percentage composition are 10%, add the diluent that the quality percentage composition is 10% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.06:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 88 ℃, the passivator layer that is 1.4 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 6.2m by length is again dried for the second time, and temperature is 72 ℃,
Then first coat of paint that the one side applied thickness is 17.5 μ, first coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the modified poly ester skin of paint that coating thickness is 35 μ on first coat of paint, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, temperature is 116 ℃; The baking oven that Second Region length is 10m, temperature is 232 ℃; The baking oven that the 3rd section length is 10m, temperature is 218 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 100 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.06:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 88 ℃, the passivator layer that is 1.4 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 6.2m by length is again dried for the second time, and temperature is 72 ℃,
Then second coat of paint that the one side applied thickness is 17.5 μ, second coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the modified poly ester skin of paint that coating thickness is 35 μ on second coat of paint, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, temperature is 116 ℃; The baking oven that Second Region length is 10m, temperature is 232 ℃; The baking oven that the 3rd section length is 10m, temperature is 218 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 100 μ.
After the oriented structure glued board is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 50 μ, spread respectively the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense prepared above and be coated with second coat of paint and the second aluminium skin of the fragrant coating of the second sense, send into hot press, closure, hot-forming (1500 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts of antistatic additive alkyl phosphate diethanolamine salts, 5 parts of fluorine modified propylene ester levelling agents, 5 parts of fluorine modification defoamers.Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 12
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000261
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 84% by quality percentage composition paint and quality percentage composition are 12%, add the diluent that the quality percentage composition is 4% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.08:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 92 ℃, the passivator layer that is 1.8 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.4m by length is again dried for the second time, and temperature is 74 ℃,
Then first coat of paint that the one side applied thickness is 22 μ, first coat of paint is fluorine carbon enamelled coating, dries, temperature is 65 ℃, and the modified poly ester skin of paint that then coating thickness is 45 μ m on first coat of paint is dried for the third time, be divided into 3rd district, the baking oven that the first section length is 10m, temperature is 118 ℃; The baking oven that Second Region length is 10m, temperature is 234 ℃; The baking oven that the 3rd section length is 10m, temperature is 224 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 120 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.08:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 92 ℃, the passivator layer that is 1.8 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.4m by length is again dried for the second time, and temperature is 74 ℃,
Then second coat of paint that the one side applied thickness is 22 μ, second coat of paint is fluorine carbon enamelled coating, dries, temperature is 65 ℃, and the modified poly ester skin of paint that then coating thickness is 45 μ m on second coat of paint is dried for the third time, be divided into 3rd district, the baking oven that the first section length is 10m, temperature is 118 ℃; The baking oven that Second Region length is 10m, temperature is 234 ℃; The baking oven that the 3rd section length is 10m, temperature is 224 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 120 μ.
After particieboard is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 35 μ, spread respectively the first aluminium skin that is coated with first coat of paint and the fragrant coating of the first sense prepared above and be coated with second coat of paint and the second aluminium skin of the fragrant coating of the second sense, send into hot press, closure, hot-forming (1500 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
Embodiment 13
Spices comprises the component of following quality percentage composition:
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 75% by quality percentage composition paint and quality percentage composition are 20%, add the diluent that the quality percentage composition is 5% while stirring, stirs 3h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.04:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 2:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 85 ℃, the passivator layer that is 1 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 5.5m by length is again dried for the second time, and temperature is 65 ℃.
Then first coat of paint that the one side applied thickness is 10 μ, first coat of paint is fluorine carbon enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 5 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, iron oxide red 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 5 μ on the first printed coating (the fragrant coating of the first sense), dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 110 ℃; The baking oven that Second Region length is 10m, temperature is 225 ℃; The baking oven that the 3rd section length is 10m, temperature is 215 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 60 μ.
After particieboard is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 20 μ, and one side is spread the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The aluminium-wood composite board of the environmental protection band fragrance of preparation, comprise the fragrant coating of the first sense, the first printed coating, first coat of paint, the first aluminium skin, the first function of glue coating and substrate, first coat of paint is positioned at the one side of the first aluminium skin, the first printed coating is positioned on first coat of paint, the fragrant coating of the first sense is positioned on the first printed coating, and the another side of the first aluminium skin is connected with substrate by the first function of glue coating.
Embodiment 14
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000281
Figure BDA0000373187590000291
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 80% by quality percentage composition paint and quality percentage composition are 18%, add the diluent that the quality percentage composition is 2% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.07:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.5 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 6m by length is again dried for the second time, and temperature is 70 ℃,
Then first coat of paint that the one side applied thickness is 20 μ, first coat of paint is the polyester oil enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 6 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent stearic acid monoglyceride 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, iron oxide yellow 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 25 μ m on the first printed coating, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 115 ℃; The baking oven that Second Region length is 10m, temperature is 230 ℃; The baking oven that the 3rd section length is 10m, temperature is 220 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 70 μ.
After low-density plank is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 60 μ, and one side is spread the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (2800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that polyester oil enamelled coating polyester oil enamel-cover used is drawn together following weight portion: 400 parts of alkyd resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of acetate resins, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 10 parts of fluorine modification defoamers, 10 parts of fluorin modified crylic acid ester levelling agents.
Embodiment 15
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000292
Figure BDA0000373187590000301
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 93% by quality percentage composition paint and quality percentage composition are 5%, add the diluent that the quality percentage composition is 2% while stirring, stirs 5h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.1:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 4:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 95 ℃, the passivator layer that is 2 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.5m by length is again dried for the second time, and temperature is 75 ℃.
Then first coat of paint that the one side applied thickness is 25 μ, first coat of paint is the water-based stoving paint layer, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 7 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent glyceryl tristearate 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, chrome oxide green 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 50 μ on the first printed coating, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 120 ℃; The baking oven that Second Region length is 10m, temperature is 235 ℃; The baking oven that the 3rd section length is 10m, temperature is 225 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 80 μ.
After high-density plate is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 30 μ, and one side is spread the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (2800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
Water-based stoving paint layer water-based stoving paint used comprises the component of following weight portion: 50 parts of acrylic emulsions, 10 parts of polyaminoester emulsions, 40 parts of auxiliary agents.The concentration of acrylic emulsion is 55～60%; The concentration of polyaminoester emulsion is 35～45%.Auxiliary agent comprises the component of following weight portion: 12.5 parts of fluorine modification defoamers, 12.5 parts of fluorine modified propylene ester levelling agents, 75 parts of wetting agents; Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 16
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000311
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 88% by quality percentage composition paint and quality percentage composition are 9%, add the diluent that the quality percentage composition is 3% while stirring, stirs 2h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.05:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.3 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 5.8m by length is again dried for the second time, and temperature is 67 ℃,
Then first coat of paint that the one side applied thickness is 12.5 μ, first coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 8 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent glyceryl tristearate 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, toluidine red 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 15 μ on the first printed coating, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 112 ℃; The baking oven that Second Region length is 10m, temperature is 228 ℃; The baking oven that the 3rd section length is 10m, temperature is 216 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 90 μ.
After multi-plywood is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 40 μ, and one side is spread the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (2000 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts of antistatic additive alkyl phosphate diethanolamine salts, 5 parts of fluorine modified propylene ester levelling agents, 5 parts of fluorine modification defoamers.Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 17
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000321
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 80% by quality percentage composition paint and quality percentage composition are 10%, add the diluent that the quality percentage composition is 10% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.06:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 88 ℃, the passivator layer that is 1.4 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 6.2m by length is again dried for the second time, and temperature is 72 ℃,
Then first coat of paint that the one side applied thickness is 17.5 μ, first coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 9 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, benzidine yellow 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 35 μ on the first printed coating, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 116 ℃; The baking oven that Second Region length is 10m, temperature is 232 ℃; The baking oven that the 3rd section length is 10m, temperature is 218 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 100 μ.
After the oriented structure glued board is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 50 μ, and one side is spread the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (1500 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts of antistatic additive alkyl phosphate diethanolamine salts, 5 parts of fluorine modified propylene ester levelling agents, 5 parts of fluorine modification defoamers.Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 18
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000331
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 84% by quality percentage composition paint and quality percentage composition are 12%, add the diluent that the quality percentage composition is 4% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.08:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 92 ℃, the passivator layer that is 1.8 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.4m by length is again dried for the second time, and temperature is 74 ℃,
Then first coat of paint that the one side applied thickness is 22 μ, first coat of paint is fluorine carbon enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 10 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, phthalocyanine blue 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 45 μ m on the first printed coating, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 118 ℃; The baking oven that Second Region length is 10m, temperature is 234 ℃; The baking oven that the 3rd section length is 10m, temperature is 224 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 120 μ.
After particieboard is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 35 μ, and one side is spread the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (1500 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
Embodiment 19
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000341
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 75% by quality percentage composition paint and quality percentage composition are 20%, add the diluent that the quality percentage composition is 5% while stirring, stirs 3h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.04:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 2:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 85 ℃, the passivator layer that is 1 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 5.5m by length is again dried for the second time, and temperature is 65 ℃.
Then first coat of paint that the one side applied thickness is 10 μ, first coat of paint is fluorine carbon enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 5 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, iron oxide red 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 5 μ on the first printed coating (the fragrant coating of the first sense), dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 110 ℃; The baking oven that Second Region length is 10m, temperature is 225 ℃; The baking oven that the 3rd section length is 10m, temperature is 215 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 60 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.04:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 2:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 85 ℃, the passivator layer that is 1 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 5.5m by length is again dried for the second time, and temperature is 65 ℃,
Then second coat of paint that the one side applied thickness is 10 μ, second coat of paint is fluorine carbon enamelled coating, dry, temperature is 65 ℃, then the second printed coating that coating thickness is 5 μ on second coat of paint, the second printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, iron oxide red 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 5 μ on the second printed coating (the fragrant coating of the second sense), dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 110 ℃; The baking oven that Second Region length is 10m, temperature is 225 ℃; The baking oven that the 3rd section length is 10m, temperature is 215 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint, the second printed coating and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 60 μ.
After particieboard is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 20 μ, spread respectively the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense prepared above and the second aluminium skin that is coated with second coat of paint, the second printed coating and the fragrant coating of the second sense, send into hot press, closure, hot-forming (800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The aluminium-wood composite board of the environmental protection band fragrance of preparation, comprise the fragrant coating of the first sense, the first printed coating, first coat of paint, the first aluminium skin, the first function of glue coating, the fragrant coating of the second sense, the second printed coating, second coat of paint, the second aluminium skin, the second function of glue coating and substrate; First coat of paint is positioned at the one side of the first aluminium skin, and the first printed coating is positioned on first coat of paint, and the fragrant coating of the first sense is positioned on the first printed coating, and the another side of the first aluminium skin is connected with the upper surface of substrate by the first function of glue coating; Second coat of paint is positioned at the one side of the second aluminium skin, and the second printed coating is positioned on second coat of paint, and the fragrant coating of the second sense is positioned on the second printed coating, and the another side of the second aluminium skin is connected with the lower surface of substrate by the second function of glue coating.
Embodiment 20
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000351
Figure BDA0000373187590000361
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 80% by quality percentage composition paint and quality percentage composition are 18%, add the diluent that the quality percentage composition is 2% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.07:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.5 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 6m by length is again dried for the second time, and temperature is 70 ℃,
Then first coat of paint that the one side applied thickness is 20 μ, first coat of paint is the polyester oil enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 6 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent stearic acid monoglyceride 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, iron oxide yellow 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 25 μ m on the first printed coating, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 115 ℃; The baking oven that Second Region length is 10m, temperature is 230 ℃; The baking oven that the 3rd section length is 10m, temperature is 220 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 70 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.07:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.5 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 6m by length is again dried for the second time, and temperature is 70 ℃,
Then second coat of paint that the one side applied thickness is 20 μ, second coat of paint is the polyester oil enamelled coating, dry, temperature is 65 ℃, then the second printed coating that coating thickness is 6 μ on second coat of paint, the second printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent stearic acid monoglyceride 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, iron oxide yellow 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 25 μ m on the second printed coating, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 115 ℃; The baking oven that Second Region length is 10m, temperature is 230 ℃; The baking oven that the 3rd section length is 10m, temperature is 220 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint, the second printed coating and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 70 μ.
After low-density plank is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 60 μ, spread respectively the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense prepared above and the second aluminium skin that is coated with second coat of paint, the second printed coating and the fragrant coating of the second sense, send into hot press, closure, hot-forming (2800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that polyester oil enamelled coating polyester oil enamel-cover used is drawn together following weight portion: 400 parts of alkyd resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of acetate resins, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 10 parts of fluorine modification defoamers, 10 parts of fluorin modified crylic acid ester levelling agents.
Embodiment 21
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000371
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 93% by quality percentage composition paint and quality percentage composition are 5%, add the diluent that the quality percentage composition is 2% while stirring, stirs 5h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.1:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 4:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 95 ℃, the passivator layer that is 2 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.5m by length is again dried for the second time, and temperature is 75 ℃,
Then first coat of paint that the one side applied thickness is 25 μ, first coat of paint is the water-based stoving paint layer, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 7 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent glyceryl tristearate 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, chrome oxide green 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 50 μ on the first printed coating, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 120 ℃; The baking oven that Second Region length is 10m, temperature is 235 ℃; The baking oven that the 3rd section length is 10m, temperature is 225 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 80 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.1:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 4:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 95 ℃, the passivator layer that is 2 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.5m by length is again dried for the second time, and temperature is 75 ℃,
Then second coat of paint that the one side applied thickness is 25 μ, second coat of paint is the water-based stoving paint layer, dry, temperature is 65 ℃, then the second printed coating that coating thickness is 7 μ on second coat of paint, the second printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent glyceryl tristearate 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, chrome oxide green 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 50 μ on the second printed coating, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 120 ℃; The baking oven that Second Region length is 10m, temperature is 235 ℃; The baking oven that the 3rd section length is 10m, temperature is 225 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint, the second printed coating and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 80 μ.
After high-density plate is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 30 μ, spread respectively the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense prepared above and the second aluminium skin that is coated with second coat of paint, the second printed coating and the fragrant coating of the second sense, send into hot press, closure, hot-forming (2800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
Water-based stoving paint layer water-based stoving paint used comprises the component of following weight portion: 50 parts of acrylic emulsions, 10 parts of polyaminoester emulsions, 40 parts of auxiliary agents.The concentration of acrylic emulsion is 55～60%; The concentration of polyaminoester emulsion is 35～45%.Auxiliary agent comprises the component of following weight portion: 12.5 parts of fluorine modification defoamers, 12.5 parts of fluorine modified propylene ester levelling agents, 75 parts of wetting agents; Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 22
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000381
Figure BDA0000373187590000391
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 88% by quality percentage composition paint and quality percentage composition are 9%, add the diluent that the quality percentage composition is 3% while stirring, stirs 2h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.05:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.3 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 5.8m by length is again dried for the second time, and temperature is 67 ℃,
Then first coat of paint that the one side applied thickness is 12.5 μ, first coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 8 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent glyceryl tristearate 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, toluidine red 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 15 μ on the first printed coating, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 112 ℃; The baking oven that Second Region length is 10m, temperature is 228 ℃; The baking oven that the 3rd section length is 10m, temperature is 216 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 90 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.05:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.3 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 5.8m by length is again dried for the second time, and temperature is 67 ℃,
Then second coat of paint that the one side applied thickness is 12.5 μ, second coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the second printed coating that coating thickness is 8 μ on second coat of paint, the second printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent glyceryl tristearate 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, toluidine red 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 15 μ on the second printed coating, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 112 ℃; The baking oven that Second Region length is 10m, temperature is 228 ℃; The baking oven that the 3rd section length is 10m, temperature is 216 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint, the second printed coating and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 90 μ.
After multi-plywood is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 40 μ, spread respectively the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense prepared above and the second aluminium skin that is coated with second coat of paint, the second printed coating and the fragrant coating of the second sense, send into hot press, closure, hot-forming (2000 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts of antistatic additive alkyl phosphate diethanolamine salts, 5 parts of fluorine modified propylene ester levelling agents, 5 parts of fluorine modification defoamers.Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 23
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000401
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 80% by quality percentage composition paint and quality percentage composition are 10%, add the diluent that the quality percentage composition is 10% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.06:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 88 ℃, the passivator layer that is 1.4 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 6.2m by length is again dried for the second time, and temperature is 72 ℃,
Then first coat of paint that the one side applied thickness is 17.5 μ, first coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 9 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, benzidine yellow 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 35 μ on the first printed coating, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 116 ℃; The baking oven that Second Region length is 10m, temperature is 232 ℃; The baking oven that the 3rd section length is 10m, temperature is 218 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 100 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.06:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 88 ℃, the passivator layer that is 1.4 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 6.2m by length is again dried for the second time, and temperature is 72 ℃,
Then second coat of paint that the one side applied thickness is 17.5 μ, second coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the second printed coating that coating thickness is 9 μ on second coat of paint, the second printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, benzidine yellow 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 35 μ on the second printed coating, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 116 ℃; The baking oven that Second Region length is 10m, temperature is 232 ℃; The baking oven that the 3rd section length is 10m, temperature is 218 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint, the second printed coating and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 100 μ.
After the oriented structure glued board is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 50 μ, spread respectively the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense prepared above and the second aluminium skin that is coated with second coat of paint, the second printed coating and the fragrant coating of the second sense, send into hot press, closure, hot-forming (1500 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts of antistatic additive alkyl phosphate diethanolamine salts, 5 parts of fluorine modified propylene ester levelling agents, 5 parts of fluorine modification defoamers.Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 24
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000421
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 84% by quality percentage composition paint and quality percentage composition are 12%, add the diluent that the quality percentage composition is 4% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.08:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 92 ℃, the passivator layer that is 1.8 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.4m by length is again dried for the second time, and temperature is 74 ℃,
Then first coat of paint that the one side applied thickness is 22 μ, first coat of paint is fluorine carbon enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 10 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, phthalocyanine blue 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 45 μ m on the first printed coating, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 118 ℃; The baking oven that Second Region length is 10m, temperature is 234 ℃; The baking oven that the 3rd section length is 10m, temperature is 224 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 120 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.08:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 92 ℃, the passivator layer that is 1.8 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.4m by length is again dried for the second time, and temperature is 74 ℃,
Then second coat of paint that the one side applied thickness is 22 μ, second coat of paint is fluorine carbon enamelled coating, dry, temperature is 65 ℃, then the second printed coating that coating thickness is 10 μ on second coat of paint, the second printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, phthalocyanine blue 5%; Dry, temperature is 80 ℃.
Then the modified poly ester skin of paint that coating thickness is 45 μ m on the second printed coating, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 118 ℃; The baking oven that Second Region length is 10m, temperature is 234 ℃; The baking oven that the 3rd section length is 10m, temperature is 224 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint, the second printed coating and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 120 μ.
After particieboard is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 35 μ, spread respectively the first aluminium skin that is coated with first coat of paint, the first printed coating and the fragrant coating of the first sense prepared above and the second aluminium skin that is coated with second coat of paint, the second printed coating and the fragrant coating of the second sense, send into hot press, closure, hot-forming (1500 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
Embodiment 25
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000431
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 75% by quality percentage composition paint and quality percentage composition are 20%, add the diluent that the quality percentage composition is 5% while stirring, stirs 3h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.04:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 2:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 85 ℃, the passivator layer that is 1 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 5.5m by length is again dried for the second time, and temperature is 65 ℃.
Then first coat of paint that the one side applied thickness is 10 μ, first coat of paint is fluorine carbon enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 5 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, iron oxide red 5%; Dry, temperature is 80 ℃.
Then the first false proof layer that coating thickness is 1 μ on the first printed coating, what the first false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 5 μ on the first false proof layer (the fragrant coating of the first sense), dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 110 ℃; The baking oven that Second Region length is 10m, temperature is 225 ℃; The baking oven that the 3rd section length is 10m, temperature is 215 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 60 μ.
After particieboard is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 20 μ, and one side is spread the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The aluminium-wood composite board of the environmental protection band fragrance of preparation, comprise the fragrant coating of the first sense, the first false proof layer, the first printed coating, first coat of paint, the first aluminium skin, the first function of glue coating and substrate, first coat of paint is positioned at the one side of the first aluminium skin, the first printed coating is positioned on first coat of paint, the first false proof layer is positioned on the first printed coating, the fragrant coating of the first sense is positioned on the first false proof layer, and the another side of the first aluminium skin is connected with substrate by the first function of glue coating.
Embodiment 26
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000441
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 80% by quality percentage composition paint and quality percentage composition are 18%, add the diluent that the quality percentage composition is 2% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.07:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.5 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 6m by length is again dried for the second time, and temperature is 70 ℃,
Then first coat of paint that the one side applied thickness is 20 μ, first coat of paint is the polyester oil enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 6 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent stearic acid monoglyceride 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, iron oxide yellow 5%; Dry, temperature is 80 ℃.
Then the first false proof layer that coating thickness is 5 μ on the first printed coating, what the first false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 25 μ m on the first false proof layer, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 115 ℃; The baking oven that Second Region length is 10m, temperature is 230 ℃; The baking oven that the 3rd section length is 10m, temperature is 220 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 70 μ.
After low-density plank is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 60 μ, and one side is spread the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (2800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that polyester oil enamelled coating polyester oil enamel-cover used is drawn together following weight portion: 400 parts of alkyd resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of acetate resins, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 10 parts of fluorine modification defoamers, 10 parts of fluorin modified crylic acid ester levelling agents.
Embodiment 27
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000451
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 93% by quality percentage composition paint and quality percentage composition are 5%, add the diluent that the quality percentage composition is 2% while stirring, stirs 5h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.1:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 4:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 95 ℃, the passivator layer that is 2 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.5m by length is again dried for the second time, and temperature is 75 ℃.
Then first coat of paint that the one side applied thickness is 25 μ, first coat of paint is the water-based stoving paint layer, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 7 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent glyceryl tristearate 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, chrome oxide green 5%; Dry, temperature is 80 ℃.
Then the first false proof layer that coating thickness is 10 μ on the first printed coating, what the first false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 50 μ on the first false proof layer, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 120 ℃; The baking oven that Second Region length is 10m, temperature is 235 ℃; The baking oven that the 3rd section length is 10m, temperature is 225 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 80 μ.
After high-density plate is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 30 μ, and one side is spread the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (2800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
Water-based stoving paint layer water-based stoving paint used comprises the component of following weight portion: 50 parts of acrylic emulsions, 10 parts of polyaminoester emulsions, 40 parts of auxiliary agents.The concentration of acrylic emulsion is 55～60%; The concentration of polyaminoester emulsion is 35～45%.Auxiliary agent comprises the component of following weight portion: 12.5 parts of fluorine modification defoamers, 12.5 parts of fluorine modified propylene ester levelling agents, 75 parts of wetting agents; Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 28
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000461
Figure BDA0000373187590000471
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 88% by quality percentage composition paint and quality percentage composition are 9%, add the diluent that the quality percentage composition is 3% while stirring, stirs 2h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.05:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.3 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 5.8m by length is again dried for the second time, and temperature is 67 ℃,
Then first coat of paint that the one side applied thickness is 12.5 μ, first coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 8 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent glyceryl tristearate 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, toluidine red 5%; Dry, temperature is 80 ℃.
Then the first false proof layer that coating thickness is 3 μ on the first printed coating, what the first false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 15 μ on the first false proof layer, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 112 ℃; The baking oven that Second Region length is 10m, temperature is 228 ℃; The baking oven that the 3rd section length is 10m, temperature is 216 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 90 μ.
After multi-plywood is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 40 μ, and one side is spread the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (2000 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts of antistatic additive alkyl phosphate diethanolamine salts, 5 parts of fluorine modified propylene ester levelling agents, 5 parts of fluorine modification defoamers.Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 29
Spices comprises the component of following quality percentage composition:
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 80% by quality percentage composition paint and quality percentage composition are 10%, add the diluent that the quality percentage composition is 10% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.06:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 88 ℃, the passivator layer that is 1.4 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 6.2m by length is again dried for the second time, and temperature is 72 ℃,
Then first coat of paint that the one side applied thickness is 17.5 μ, first coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 9 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, benzidine yellow 5%; Dry, temperature is 80 ℃.
Then the first false proof layer that coating thickness is 7 μ on the first printed coating, what the first false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 35 μ on the first false proof layer, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 116 ℃; The baking oven that Second Region length is 10m, temperature is 232 ℃; The baking oven that the 3rd section length is 10m, temperature is 218 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 100 μ.
After the oriented structure glued board is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 50 μ, and one side is spread the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (1500 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts of antistatic additive alkyl phosphate diethanolamine salts, 5 parts of fluorine modified propylene ester levelling agents, 5 parts of fluorine modification defoamers.Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 30
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000491
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 84% by quality percentage composition paint and quality percentage composition are 12%, add the diluent that the quality percentage composition is 4% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.08:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 92 ℃, the passivator layer that is 1.8 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.4m by length is again dried for the second time, and temperature is 74 ℃,
Then first coat of paint that the one side applied thickness is 22 μ, first coat of paint is fluorine carbon enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 10 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, phthalocyanine blue 5%; Dry, temperature is 80 ℃.
Then the first false proof layer that coating thickness is 8 μ on the first printed coating, what the first false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 45 μ m on the first false proof layer, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 118 ℃; The baking oven that Second Region length is 10m, temperature is 234 ℃; The baking oven that the 3rd section length is 10m, temperature is 224 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 120 μ.
After particieboard is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 35 μ, and one side is spread the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense prepared above, and another side is spread trimerization azanol paper, and (temperature is 180～220 ℃, 10～60s), send into hot press, closure, hot-forming (1500 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
Embodiment 31
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000501
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 75% by quality percentage composition paint and quality percentage composition are 20%, add the diluent that the quality percentage composition is 5% while stirring, stirs 3h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.04:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 2:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 85 ℃, the passivator layer that is 1 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 5.5m by length is again dried for the second time, and temperature is 65 ℃.
Then first coat of paint that the one side applied thickness is 10 μ, first coat of paint is fluorine carbon enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 5 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, iron oxide red 5%; Dry, temperature is 80 ℃.
Then the first false proof layer that coating thickness is 1 μ on the first printed coating, what the first false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 5 μ on the first false proof layer (the fragrant coating of the first sense), dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 110 ℃; The baking oven that Second Region length is 10m, temperature is 225 ℃; The baking oven that the 3rd section length is 10m, temperature is 215 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 60 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.04:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 2:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 85 ℃, the passivator layer that is 1 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 5.5m by length is again dried for the second time, and temperature is 65 ℃,
Then second coat of paint that the one side applied thickness is 10 μ, second coat of paint is fluorine carbon enamelled coating, dry, temperature is 65 ℃, then the second printed coating that coating thickness is 5 μ on second coat of paint, the second printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, iron oxide red 5%; Dry, temperature is 80 ℃.
Then the second false proof layer that coating thickness is 1 μ on the second printed coating, what the second false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 5 μ on the second false proof layer (the fragrant coating of the second sense), dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 110 ℃; The baking oven that Second Region length is 10m, temperature is 225 ℃; The baking oven that the 3rd section length is 10m, temperature is 215 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint, the second printed coating, the second false proof layer and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 60 μ.
After particieboard is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 20 μ, spread respectively the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense prepared above and the second aluminium skin that is coated with second coat of paint, the second printed coating, the second false proof layer and the fragrant coating of the second sense, send into hot press, closure, hot-forming (800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The aluminium-wood composite board of the environmental protection band fragrance of preparation, comprise the fragrant coating of the first sense, the first false proof layer, the first printed coating, first coat of paint, the first aluminium skin, the first function of glue coating, the fragrant coating of the second sense, the second false proof layer, the second printed coating, second coat of paint, the second aluminium skin, the second function of glue coating and substrate; First coat of paint is positioned at the one side of the first aluminium skin, the first printed coating is positioned on first coat of paint, the first false proof layer is positioned on the first printed coating, and the fragrant coating of the first sense is positioned on the first false proof layer, and the another side of the first aluminium skin is connected with the upper surface of substrate by the first function of glue coating; Second coat of paint is positioned at the one side of the second aluminium skin, the second printed coating is positioned on second coat of paint, the second false proof layer is positioned on the second printed coating, and the fragrant coating of the second sense is positioned on the second false proof layer, and the another side of the second aluminium skin is connected with the lower surface of substrate by the second function of glue coating.
Embodiment 32
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000511
Figure BDA0000373187590000521
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 80% by quality percentage composition paint and quality percentage composition are 18%, add the diluent that the quality percentage composition is 2% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.07:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.5 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 6m by length is again dried for the second time, and temperature is 70 ℃,
Then first coat of paint that the one side applied thickness is 20 μ, first coat of paint is the polyester oil enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 6 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent stearic acid monoglyceride 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, iron oxide yellow 5%; Dry, temperature is 80 ℃.
Then the first false proof layer that coating thickness is 5 μ on the first printed coating, what the first false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 25 μ m on the first false proof layer, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 115 ℃; The baking oven that Second Region length is 10m, temperature is 230 ℃; The baking oven that the 3rd section length is 10m, temperature is 220 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 70 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.07:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.5 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 6m by length is again dried for the second time, and temperature is 70 ℃,
Then second coat of paint that the one side applied thickness is 20 μ, second coat of paint is the polyester oil enamelled coating, dry, temperature is 65 ℃, then the second printed coating that coating thickness is 6 μ on second coat of paint, the second printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent stearic acid monoglyceride 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, iron oxide yellow 5%; Dry, temperature is 80 ℃.
Then the second false proof layer that coating thickness is 5 μ on the second printed coating, what the second false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 25 μ m on the second false proof layer, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 115 ℃; The baking oven that Second Region length is 10m, temperature is 230 ℃; The baking oven that the 3rd section length is 10m, temperature is 220 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint, the second printed coating, the second false proof layer and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 70 μ.
After low-density plank is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 60 μ, spread respectively the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense prepared above and the second aluminium skin that is coated with second coat of paint, the second printed coating, the second false proof layer and the fragrant coating of the second sense, send into hot press, closure, hot-forming (2800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that polyester oil enamelled coating polyester oil enamel-cover used is drawn together following weight portion: 400 parts of alkyd resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of acetate resins, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 10 parts of fluorine modification defoamers, 10 parts of fluorin modified crylic acid ester levelling agents.
Embodiment 33
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000531
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 93% by quality percentage composition paint and quality percentage composition are 5%, add the diluent that the quality percentage composition is 2% while stirring, stirs 5h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.1:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 4:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 95 ℃, the passivator layer that is 2 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.5m by length is again dried for the second time, and temperature is 75 ℃,
Then first coat of paint that the one side applied thickness is 25 μ, first coat of paint is the water-based stoving paint layer, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 7 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent glyceryl tristearate 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, chrome oxide green 5%; Dry, temperature is 80 ℃.
Then the first false proof layer that coating thickness is 10 μ on the first printed coating, what the first false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 50 μ on the first false proof layer, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 120 ℃; The baking oven that Second Region length is 10m, temperature is 235 ℃; The baking oven that the 3rd section length is 10m, temperature is 225 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 80 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.1:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 4:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 95 ℃, the passivator layer that is 2 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.5m by length is again dried for the second time, and temperature is 75 ℃,
Then second coat of paint that the one side applied thickness is 25 μ, second coat of paint is the water-based stoving paint layer, dry, temperature is 65 ℃, then the second printed coating that coating thickness is 7 μ on second coat of paint, the second printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent glyceryl tristearate 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, chrome oxide green 5%; Dry, temperature is 80 ℃.
Then the second false proof layer that coating thickness is 10 μ on the second printed coating, what the second false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 50 μ on the second false proof layer, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 120 ℃; The baking oven that Second Region length is 10m, temperature is 235 ℃; The baking oven that the 3rd section length is 10m, temperature is 225 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint, the second printed coating, the second false proof layer and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 80 μ.
After high-density plate is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 30 μ, spread respectively the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense prepared above and the second aluminium skin that is coated with second coat of paint, the second printed coating, the second false proof layer and the fragrant coating of the second sense, send into hot press, closure, hot-forming (2800 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
Water-based stoving paint layer water-based stoving paint used comprises the component of following weight portion: 50 parts of acrylic emulsions, 10 parts of polyaminoester emulsions, 40 parts of auxiliary agents.The concentration of acrylic emulsion is 55～60%; The concentration of polyaminoester emulsion is 35～45%.Auxiliary agent comprises the component of following weight portion: 12.5 parts of fluorine modification defoamers, 12.5 parts of fluorine modified propylene ester levelling agents, 75 parts of wetting agents; Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 34
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000551
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 88% by quality percentage composition paint and quality percentage composition are 9%, add the diluent that the quality percentage composition is 3% while stirring, stirs 2h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.05:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.3 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 5.8m by length is again dried for the second time, and temperature is 67 ℃,
Then first coat of paint that the one side applied thickness is 12.5 μ, first coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 8 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent glyceryl tristearate 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, toluidine red 5%; Dry, temperature is 80 ℃.
Then the first false proof layer that coating thickness is 3 μ on the first printed coating, what the first false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 15 μ on the first false proof layer, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 112 ℃; The baking oven that Second Region length is 10m, temperature is 228 ℃; The baking oven that the 3rd section length is 10m, temperature is 216 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 90 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 12m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.05:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7m, then entering the long baking oven of 6m dries for the first time, temperature is 90 ℃, the passivator layer that is 1.3 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:4.The baking oven that is 5.8m by length is again dried for the second time, and temperature is 67 ℃,
Then second coat of paint that the one side applied thickness is 12.5 μ, second coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the second printed coating that coating thickness is 8 μ on second coat of paint, the second printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent glyceryl tristearate 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, toluidine red 5%; Dry, temperature is 80 ℃.
Then the second false proof layer that coating thickness is 3 μ on the second printed coating, what the second false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 15 μ on the second false proof layer, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 112 ℃; The baking oven that Second Region length is 10m, temperature is 228 ℃; The baking oven that the 3rd section length is 10m, temperature is 216 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint, the second printed coating, the second false proof layer and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 90 μ.
After multi-plywood is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 40 μ, spread respectively the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense prepared above and the second aluminium skin that is coated with second coat of paint, the second printed coating, the second false proof layer and the fragrant coating of the second sense, send into hot press, closure, hot-forming (2000 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts of antistatic additive alkyl phosphate diethanolamine salts, 5 parts of fluorine modified propylene ester levelling agents, 5 parts of fluorine modification defoamers.Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 35
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000561
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 80% by quality percentage composition paint and quality percentage composition are 10%, add the diluent that the quality percentage composition is 10% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.06:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 88 ℃, the passivator layer that is 1.4 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 6.2m by length is again dried for the second time, and temperature is 72 ℃,
Then first coat of paint that the one side applied thickness is 17.5 μ, first coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 9 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, benzidine yellow 5%; Dry, temperature is 80 ℃.
Then the first false proof layer that coating thickness is 7 μ on the first printed coating, what the first false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 35 μ on the first false proof layer, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 116 ℃; The baking oven that Second Region length is 10m, temperature is 232 ℃; The baking oven that the 3rd section length is 10m, temperature is 218 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 100 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 13m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.06:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 7.5m, then entering the long baking oven of 6m dries for the first time, temperature is 88 ℃, the passivator layer that is 1.4 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:3.The baking oven that is 6.2m by length is again dried for the second time, and temperature is 72 ℃,
Then second coat of paint that the one side applied thickness is 17.5 μ, second coat of paint is acrylic acid formula enamelled coating, dry, temperature is 65 ℃, then the second printed coating that coating thickness is 9 μ on second coat of paint, the second printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, benzidine yellow 5%; Dry, temperature is 80 ℃.
Then the second false proof layer that coating thickness is 7 μ on the second printed coating, what the second false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 35 μ on the second false proof layer, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 116 ℃; The baking oven that Second Region length is 10m, temperature is 232 ℃; The baking oven that the 3rd section length is 10m, temperature is 218 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint, the second printed coating, the second false proof layer and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 100 μ.
After the oriented structure glued board is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 50 μ, spread respectively the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense prepared above and the second aluminium skin that is coated with second coat of paint, the second printed coating, the second false proof layer and the fragrant coating of the second sense, send into hot press, closure, hot-forming (1500 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The component that acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of silica dioxide delustring agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.Auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts of antistatic additive alkyl phosphate diethanolamine salts, 5 parts of fluorine modified propylene ester levelling agents, 5 parts of fluorine modification defoamers.Wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
Embodiment 36
Spices comprises the component of following quality percentage composition:
Figure BDA0000373187590000581
Diluent comprises butyl ether (30%), cyclohexanone (30%), n-butanol (30%), isophorone (10%).
The preparation method of modified poly ester paint comprises the following steps:
The spices stirring added together that the polyester that is 84% by quality percentage composition paint and quality percentage composition are 12%, add the diluent that the quality percentage composition is 4% while stirring, stirs 4h, obtains modified poly ester paint after filtration.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.08:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 92 ℃, the passivator layer that is 1.8 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.4m by length is again dried for the second time, and temperature is 74 ℃,
Then first coat of paint that the one side applied thickness is 22 μ, first coat of paint is fluorine carbon enamelled coating, dry, temperature is 65 ℃, then the first printed coating that coating thickness is 10 μ on first coat of paint, the first printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, phthalocyanine blue 5%; Dry, temperature is 80 ℃.
Then the first false proof layer that coating thickness is 8 μ on the first printed coating, what the first false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 45 μ m on the first false proof layer, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 118 ℃; The baking oven that Second Region length is 10m, temperature is 234 ℃; The baking oven that the 3rd section length is 10m, temperature is 224 ℃; Cooling, rolling, prepare the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense, and the thickness of the first aluminium skin is 120 μ.
At first, area is 2.97m 2the aluminium skin take the degreasing bath that the speed of 20m/min is 14m by length successively, be preset with Degreasing medicament in degreasing bath, the ratio of Degreasing medicament and water is 0.08:1, wherein: Degreasing medicament comprises degreasing agent and degreasing agent, the ratio of degreasing agent and degreasing agent is 3:1, the Rinsing Area that length is 8m, then entering the long baking oven of 6m dries for the first time, temperature is 92 ℃, the passivator layer that is 1.8 μ m toward coating thickness on the aluminium skin after drying, the aqueous solution that the passivator layer is chromic anhydride, wherein, the ratio of chromic anhydride and water is 1:5.The baking oven that is 6.4m by length is again dried for the second time, and temperature is 74 ℃,
Then second coat of paint that the one side applied thickness is 22 μ, second coat of paint is fluorine carbon enamelled coating, dry, temperature is 65 ℃, then the second printed coating that coating thickness is 10 μ on second coat of paint, the second printed coating is printing ink, the component that comprises following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent ethylene group bis-stearamides 3.5%, anti-skinning agent methyl ethyl ketoxime 0.5%, phthalocyanine blue 5%; Dry, temperature is 80 ℃.
Then the second false proof layer that coating thickness is 8 μ on the second printed coating, what the second false proof layer was used is fluorescent material, dries, temperature is 90 ℃.Then the modified poly ester skin of paint that coating thickness is 45 μ on the second false proof layer, dry for the third time, is divided into 3rd district, the baking oven that the first section length is 10m, and temperature is 118 ℃; The baking oven that Second Region length is 10m, temperature is 234 ℃; The baking oven that the 3rd section length is 10m, temperature is 224 ℃; Cooling, rolling, prepare the second aluminium skin that is coated with second coat of paint, the second printed coating, the second false proof layer and the fragrant coating of the second sense, and the thickness of the second aluminium skin is 120 μ.
After particieboard is cleaned up, two-sided standby glue, glue is the PE polymeric laminate, the thickness of PE macromolecule glue membrane coat is 35 μ, spread respectively the first aluminium skin that is coated with first coat of paint, the first printed coating, the first false proof layer and the fragrant coating of the first sense prepared above and the second aluminium skin that is coated with second coat of paint, the second printed coating, the second false proof layer and the fragrant coating of the second sense, send into hot press, closure, hot-forming (1500 tons/2.97m 2, 10～30s), ejecting plate, cooling, peritonaeum.
The above-mentioned description to embodiment is can understand and apply the invention for ease of those skilled in the art.The person skilled in the art obviously can easily make various modifications to these embodiment, and General Principle described herein is applied in other embodiment and needn't passes through performing creative labour.Therefore, the invention is not restricted to the embodiment here, those skilled in the art are according to announcement of the present invention, and not breaking away from the improvement that category of the present invention makes and revise all should be within protection scope of the present invention.

Claims (25)

1. the aluminium-wood composite board of an environmental protection band fragrance, it is characterized in that, comprise the fragrant coating of the first sense, first coat of paint, the first aluminium skin, the first function of glue coating and substrate, first coat of paint is positioned at the one side of the first aluminium skin, the fragrant coating of the first sense is positioned on first coat of paint, and the another side of the first aluminium skin is connected with substrate by the first function of glue coating.
2. the aluminium-wood composite board of environmental protection band fragrance according to claim 1, is characterized in that, also comprises the fragrant coating of the second sense, second coat of paint, the second aluminium skin and the second function of glue coating; First coat of paint is positioned at the one side of the first aluminium skin, and the fragrant coating of the first sense is positioned on first coat of paint, and the another side of the first aluminium skin is connected with the upper surface of substrate by the first function of glue coating; Second coat of paint is positioned at the one side of the second aluminium skin, and the fragrant coating of the second sense is positioned on second coat of paint, and the another side of the second aluminium skin is connected with the lower surface of substrate by the second function of glue coating.
3. the aluminium-wood composite board of environmental protection band fragrance according to claim 1, it is characterized in that, also comprise the first printed coating, first coat of paint is positioned at the one side of the first aluminium skin, the first printed coating is positioned on first coat of paint, the fragrant coating of the first sense is positioned on the first printed coating, and the another side of the first aluminium skin is connected with substrate by the first function of glue coating.
4. the aluminium-wood composite board of environmental protection band fragrance according to claim 3, is characterized in that, also comprises the fragrant coating of the second sense, the second printed coating, second coat of paint, the second aluminium skin, the second function of glue coating; First coat of paint is positioned at the one side of the first aluminium skin, and the first printed coating is positioned on first coat of paint, and the fragrant coating of the first sense is positioned on the first printed coating, and the another side of the first aluminium skin is connected with the upper surface of substrate by the first function of glue coating; Second coat of paint is positioned at the one side of the second aluminium skin, and the second printed coating is positioned on second coat of paint, and the fragrant coating of the second sense is positioned on the second printed coating, and the another side of the second aluminium skin is connected with the lower surface of substrate by the second function of glue coating.
5. the aluminium-wood composite board of environmental protection band fragrance according to claim 3, it is characterized in that, also comprise the first false proof layer, first coat of paint is positioned at the one side of the first aluminium skin, the first printed coating is positioned on first coat of paint, the first false proof layer is positioned on the first printed coating, and the fragrant coating of the first sense is positioned on the first false proof layer, and the another side of the first aluminium skin is connected with substrate by the first function of glue coating.
6. the aluminium-wood composite board of environmental protection band fragrance according to claim 5, is characterized in that, also comprises the fragrant coating of the second sense, the second false proof layer, the second printed coating, second coat of paint, the second aluminium skin, the second function of glue coating; First coat of paint is positioned at the one side of the first aluminium skin, the first printed coating is positioned on first coat of paint, the first false proof layer is positioned on the first printed coating, and the fragrant coating of the first sense is positioned on the first false proof layer, and the another side of the first aluminium skin is connected with the upper surface of substrate by the first function of glue coating; Second coat of paint is positioned at the one side of the second aluminium skin, the second printed coating is positioned on second coat of paint, the second false proof layer is positioned on the second printed coating, and the fragrant coating of the second sense is positioned on the second false proof layer, and the another side of the second aluminium skin is connected with the lower surface of substrate by the second function of glue coating.
7. according to the aluminium-wood composite board of the arbitrary described environmental protection band fragrance of claim 1 to 6, it is characterized in that,
The thickness of the fragrant coating of described the first sense, the fragrant coating of described the second sense is 5～50 μ;
The thickness of described the first false proof layer, described the second false proof layer is 1～10 μ;
The thickness of described the first printed coating, described the second printed coating is 5～10 μ;
The thickness of described first coat of paint, described second coat of paint is 10～25 μ;
The thickness of described the first aluminium skin, described the second aluminium skin is 60～120 μ;
The thickness of described the first function of glue coating, described the second function of glue coating is 20～60 μ;
The fragrant coating of described the first sense, the fragrant coating of described the second sense are modified poly ester paint.
8. the aluminium-wood composite board of environmental protection band fragrance according to claim 7, is characterized in that, described modified poly ester paint comprises the component of following mass percent:
Polyester paint: 75～93%,
Spices: 5～20%,
Diluent: 2～10%.
9. the aluminium-wood composite board of environmental protection band fragrance according to claim 8, is characterized in that, described spices comprises the component of following quality percentage composition:
Figure FDA0000373187580000021
Described diluent is butyl ether, cyclohexanone, n-butanol, isophorone.
10. the aluminium-wood composite board of environmental protection band fragrance according to claim 9, is characterized in that, described auxiliary agent is geraniol, vanillyl alcohol, rhodinol, Vanillin acetate.
11. the aluminium-wood composite board according to the described environmental protection band of claim 5 or 6 fragrance, is characterized in that, what described the first false proof layer, described the second false proof layer were used is fluorescent material.
12. the aluminium-wood composite board according to claim 3 or 4 or 5 or 6 described environmental protection band fragrance, it is characterized in that, what described the first printed coating, described the second printed coating applied is printing ink, comprises the component of following quality percentage composition: nitrocellulose 25%, butyl acetate 21%, ethyl acetate 10%, toluene 10%, butyl glycol ether 5%, alkyd resins 20%, macromolecule dispersing agent 3.5%, anti-skinning agent 0.5%, toner 5%.
13. the aluminium-wood composite board of environmental protection band fragrance according to claim 12, is characterized in that, described macromolecule dispersing agent is ethylene group bis-stearamides, stearic acid monoglyceride or glyceryl tristearate;
Described anti-skinning agent is methyl ethyl ketoxime;
Described toner is iron oxide red, cadmium red, toluidine red, iron oxide yellow, chrome yellow, benzidine yellow, chrome oxide green, chrome green, barba hispanica, cobalt blue, ultramarine or phthalocyanine blue.
14. the aluminium-wood composite board according to the arbitrary described environmental protection band fragrance of claim 1 to 6, is characterized in that, described first coat of paint, described second coat of paint are polyester oil enamelled coating, water-based stoving paint layer, fluorine carbon enamelled coating, acrylic acid formula enamelled coating.
15. the aluminium-wood composite board of environmental protection band fragrance according to claim 14, it is characterized in that, the component that described polyester oil enamelled coating polyester oil enamel-cover used is drawn together following weight portion: 400 parts of alkyd resins, 50 parts of delustering agents, 40 parts of dimethylbenzene, 30 parts of acetate resins, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.
16. the aluminium-wood composite board of environmental protection band fragrance according to claim 15, is characterized in that, described delustering agent is silica dioxide delustring agent;
Described auxiliary agent comprises the component of following weight portion: 10 parts of defoamers, 10 parts of levelling agents.
17. the aluminium-wood composite board of environmental protection band fragrance according to claim 16, is characterized in that, described defoamer is fluorine modification defoamer;
Described levelling agent is fluorin modified crylic acid ester levelling agent.
18. the aluminium-wood composite board of environmental protection band fragrance according to claim 14, is characterized in that, described water-based stoving paint layer water-based stoving paint used comprises the component of following weight portion: 50 parts of acrylic emulsions, 10 parts of polyaminoester emulsions, 40 parts of auxiliary agents.
19. the aluminium-wood composite board of environmental protection band fragrance according to claim 18, is characterized in that, the concentration of described acrylic emulsion is 55～60%;
The concentration of described polyaminoester emulsion is 35～45%.
Described auxiliary agent comprises the component of following weight portion: 12.5 parts of defoamers, 12.5 parts of levelling agents, 75 parts of wetting agents.
20. the aluminium-wood composite board of environmental protection band fragrance according to claim 19, is characterized in that, described defoamer is fluorine modification defoamer;
Described levelling agent is fluorine modified propylene ester levelling agent;
Described wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene.
21. the aluminium-wood composite board of environmental protection band fragrance according to claim 14, it is characterized in that, the component that described acrylic acid formula enamelled coating acrylic acid formula enamel-cover used is drawn together following weight portion: 400 parts of acrylic resins, 50 parts of delustering agents, 40 parts of dimethylbenzene, 30 parts of butyl acetates, 7 parts of 1-Methoxy-2-propyl acetates, 20 parts of auxiliary agents.
22. the aluminium-wood composite board of environmental protection band fragrance according to claim 21, is characterized in that, described delustering agent is silica dioxide delustring agent;
Described auxiliary agent comprises the component of following weight portion: 5 parts of wetting agents, 5 parts, antistatic additive, 5 parts of levelling agents, 5 parts of defoamers.
23. the aluminium-wood composite board of environmental protection band fragrance according to claim 22, is characterized in that, described wetting agent is the polyphosphazene polymer acid amides, and solvent used is dimethylbenzene;
Described antistatic additive is the alkyl phosphate diethanolamine salt;
Described levelling agent is fluorine modified propylene ester levelling agent;
Described defoamer is fluorine modification defoamer.
24. the aluminium-wood composite board according to the arbitrary described environmental protection band fragrance of claim 1 to 6, is characterized in that, described the first function of glue coating, described the second function of glue coating are PE macromolecule glue membrane coat.
25. the aluminium-wood composite board according to the arbitrary described environmental protection band fragrance of claim 1 to 6, is characterized in that, described substrate is particieboard, low-density plank, high-density plate, multi-plywood, oriented structure chipboard.
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CN103214918A (en) * 2013-02-21 2013-07-24 上海宁升材料科技有限公司 Modified polyester paint, and preparation method and application thereof

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WO2015027668A1 (en) * 2013-08-28 2015-03-05 上海宁升材料科技有限公司 Environmentally friendly fragrant aluminium-wood composite board and preparation method thereof
CN105062212A (en) * 2015-10-08 2015-11-18 苏州市永津彩印包装有限公司 High-performance aromatic ink
CN110626107A (en) * 2019-09-17 2019-12-31 苏州兴禾源复合材料有限公司 PCM color coated sheet capable of emitting fragrance after touch
CN115283226A (en) * 2022-06-27 2022-11-04 合肥河钢新材料科技有限公司 Production process of fragrant color plate

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