Summary of the invention
One of purpose of the present invention is to provide a kind of color make-up color compositions containing the natural pigment extract containing a kind of color make-up color compositions containing Flos Carthami natural pigment extract, the contained Flos Carthami natural pigment that should contain the color make-up color compositions of Flos Carthami natural pigment extract is pure natural, safe, bright in luster, should be better containing the color make-up color compositions colour stability of Flos Carthami natural pigment extract, color divergence is even, and there is certain antioxidant effect, be applicable to the color make-up pigment such as lipstick.
Two of purpose of the present invention is to provide the preparation method of above-mentioned a kind of color make-up color compositions containing Flos Carthami natural pigment extract.
Technical scheme of the present invention
A kind of color make-up color compositions containing Flos Carthami natural pigment extract comprises water component and oil phase component:
Wherein said water component is greater than 7 water-soluble liquid nonionic emulsifier, coloring agent powder, Flos Carthami natural pigment and distilled water by the HLB value and mixes, calculate in mass ratio, the water-soluble liquid nonionic emulsifier that the HLB value is greater than 7: coloring agent powder: Flos Carthami natural pigment: distilled water is 1:2:2-10:5:
It is the liquid nonionic emulsifying agent that is applicable to prepare the O/W emulsion that wherein said HLB value is greater than 7 water-soluble liquid nonionic emulsifier, is preferably TWEEN80 etc.;
Prepared by the following method by described Flos Carthami natural pigment:
After Flos Carthami is dried to pulverizing, in the ethanol water that to join mass percent concentration be 50%, the ethanol water volume ratio calculating by weight that to control Flos Carthami and mass percent concentration be 50%, i.e. Flos Carthami: mass percent concentration is to obtain mixed liquor after ratio that 50% ethanol water is 1g:4-20ml is mixed;
By the mixed liquor of gained, at power 150W, under the ultrasound condition of frequency 40kHz, and to control temperature be 25 ℃, and the time is that 15-30min carries out supersound extraction, then uses 0.45 μ m filtering with microporous membrane;
Resulting filtrate after filtering is controlled under the condition that vacuum is 0.094-0.096MPa and carried out rotary evaporation in vacuo, obtain the Flos Carthami extract concentrated solution;
The Flos Carthami extract concentrated solution of gained is controlled to temperature and for-55 ℃, carry out lyophilization, obtain the Flos Carthami natural pigment;
Described coloring agent powder is the mixture that superfine titanic oxide, corn starch or superfine titanic oxide and corn starch form, and the particle diameter of described coloring agent powder is 50-500nm;
Wherein said oil phase component is less than 7 oil soluble liquid nonionic emulsifier, antiseptic and liquid fat by the HLB value and mixes;
Wherein to be less than 7 oil soluble liquid nonionic emulsifier be the liquid nonionic emulsifying agent that is applicable to prepare the W/O emulsion to the HLB value, is preferably SPAN80 etc., and its consumption is 2 times of the HLB value quality that is greater than 7 water-soluble liquid nonionic emulsifier;
The consumption of liquid fat is 20 times of distilled water consumption;
The consumption of antiseptic is the 0.1-0.3% of the color make-up color compositions gross mass containing Flos Carthami natural pigment extract;
Described liquid fat is a kind of or two or more in isopropyl palmitate, Jojoba oil, iso-octyl palmitate, isopropyl myristate, Trivent OCG, tricaprin, white oil, dimethicone, synthetic squalane;
Described antiseptic is one or more in methyl hydroxybenzoate, ethyl hydroxybenzoate, propyl hydroxybenzoate, butyl hydroxybenzoate.
The preparation method of above-mentioned a kind of color make-up color compositions containing Flos Carthami natural pigment extract, comprise the following steps:
(1), the extraction of Flos Carthami natural pigment
After Flos Carthami is dried to pulverizing, in the ethanol water that to join mass percent be 50%, the ethanol water that is 50% by Flos Carthami and mass percent volume ratio by weight calculates, i.e. Flos Carthami: the ratio that the ethanol water that mass percent is 50% is 1g:4-20ml obtains mixed liquor after being mixed;
By the mixed liquor of above-mentioned gained at power 150W, under the ultrasound condition of frequency 40kHz, and the control temperature is 25 ℃, time is that 15-30min carries out supersound extraction, then use 0.45 μ m filtering with microporous membrane, resulting filtrate after filtering is controlled under the condition that vacuum is 0.094-0.096MPa and carried out rotary evaporation in vacuo, obtain the Flos Carthami extract concentrated solution;
The Flos Carthami extract concentrated solution of gained is controlled to temperature and for-55 ℃, carry out lyophilization, obtain the Flos Carthami natural pigment;
(2), the preparation of water component
Distilled water, Flos Carthami natural pigment, coloring agent powder and HLB value are greater than after 7 water-soluble liquid nonionic emulsifier is mixed and obtain the water component;
(3), the preparation of oil phase component
The HLB value is less than after 7 oil soluble liquid nonionic emulsifier, antiseptic and liquid fat are mixed and obtains oil phase component;
(4), biphase emulsifying mixes
The water component of step (2) gained, under the condition stirred, is poured into oil phase component in the water component, and homogenizing or stirring 5-8min, after making water component and oil phase component mix homogeneously, obtain the color make-up color compositions containing Flos Carthami natural pigment extract.
Beneficial effect of the present invention
A kind of color make-up color compositions containing Flos Carthami natural pigment extract of the present invention, due to the Flos Carthami natural pigment adopted, be natural, therefore harmless.
Further, a kind of color make-up color compositions containing Flos Carthami natural pigment extract of the present invention, because the Flos Carthami natural pigment is attached on the coloring agent powder, thereby improved the Flos Carthami natural pigment at the heat stability containing in the color make-up color compositions of Flos Carthami natural pigment extract, made the higher and difficult decolouring of its covering power.
Further, the preparation method of a kind of color make-up color compositions containing Flos Carthami natural pigment extract of the present invention, because the method that adopts W/O emulsifying makes the color make-up color compositions containing Flos Carthami natural pigment extract of gained, be uniformly dispersed, and preparation technology is simple, is suitable for suitability for industrialized production.
The specific embodiment
Below by specific embodiment, the present invention is further set forth, but do not limit the present invention.
embodiment 1
A kind of color make-up color compositions containing Flos Carthami natural pigment extract comprises water component and oil phase component:
Wherein said water component is greater than 7 water-soluble liquid nonionic emulsifier, coloring agent powder, Flos Carthami natural pigment and distilled water by the HLB value and mixes, calculate in mass ratio, the water-soluble liquid nonionic emulsifier that the HLB value is greater than 7: coloring agent powder: Flos Carthami natural pigment: distilled water is 1:2:2:5:
It is TWEEN80 that wherein said HLB value is greater than 7 water-soluble liquid nonionic emulsifier;
Prepared by the following method by described Flos Carthami natural pigment:
After the 5g Flos Carthami is dried to pulverizing, in the ethanol water that the mass percent concentration that joins 20ml is 50%, the ethanol water that control Flos Carthami and mass percent concentration are 50% is volume ratio, i.e. Flos Carthami by weight: the ratio that the ethanol water that mass percent concentration is 50% is 1g:4ml obtains mixed liquor after being mixed;
By the mixed liquor of above-mentioned gained, at power 150W, under the ultrasound condition of frequency 40kHz, and to control temperature be 25 ℃, and the time is that 20min carries out supersound extraction, then uses 0.45 μ m filtering with microporous membrane;
Resulting filtrate after filtering is controlled under the condition that vacuum is 0.094-0.096MPa and carried out rotary evaporation in vacuo, obtain the Flos Carthami extract concentrated solution;
The Flos Carthami extract concentrated solution of gained is controlled to temperature and for-55 ℃, carry out lyophilization, obtain 0.46g Flos Carthami natural pigment;
Described coloring agent powder is the superfine titanic oxide that particle diameter is 50-500nm;
Wherein said oil phase component is less than 7 oil soluble liquid nonionic emulsifier, antiseptic and liquid fat by the HLB value and is obtained by mixing;
Wherein to be less than 7 oil soluble liquid nonionic emulsifier be SPAN-80 to the HLB value, and its consumption is 2 times of the HLB value quality that is greater than 7 water-soluble liquid nonionic emulsifier TWEEN80;
The consumption of liquid fat is 20 times of distilled water consumption;
The consumption of antiseptic is 0.145% of the color make-up color compositions gross mass containing Flos Carthami natural pigment extract;
Described liquid fat is that isopropyl palmitate, dimethicone calculate by volume, i.e. isopropyl palmitate: dimethicone is the mixture that 1:1 forms;
Described antiseptic is methyl hydroxybenzoate.
The preparation method of above-mentioned a kind of color make-up color compositions containing Flos Carthami natural pigment extract, comprise the following steps:
(1), get the 1mL distilled water, add 0.4g Flos Carthami natural pigment, the 0.4g superfine titanic oxide, the TWEEN-80 of 0.2g, obtain the water component after mix homogeneously;
(2), get 10mL dimethicone, 10mL isopropyl palmitate, 0.4gSPAN-80 and 0.03g methyl hydroxybenzoate, obtain oil phase component after mix homogeneously;
(3), by the water component of step (1) gained under the condition stirred, oil phase component is poured in the water component, homogenizing or stirring 5min, after making water component and oil phase component mix homogeneously, obtain the color make-up color compositions containing Flos Carthami natural pigment extract of 20.63g.
The color make-up color compositions containing Flos Carthami natural pigment extract of above-mentioned gained, through more than 80 ℃, heating 2h, color is without significant change.
embodiment 2
A kind of color make-up color compositions containing Flos Carthami natural pigment extract comprises water component and oil phase component:
Wherein said water component is greater than 7 water-soluble liquid nonionic emulsifier, coloring agent powder, Flos Carthami natural pigment and distilled water by the HLB value and mixes, calculate in mass ratio, the water-soluble liquid nonionic emulsifier that the HLB value is greater than 7: coloring agent powder: Flos Carthami natural pigment: distilled water is 1:2:2:5:
It is TWEEN80 that wherein said HLB value is greater than 7 water-soluble liquid nonionic emulsifier;
Prepared by the following method by described Flos Carthami natural pigment:
After the Flos Carthami of 5g is dried to pulverizing, in the ethanol water that the mass percent concentration that joins 50ml is 50%, control the ethanol water volume ratio calculating by weight that Flos Carthami and mass percent concentration are 50%, i.e. Flos Carthami: the ethanol water that mass percent concentration is 50% is to obtain mixed liquor after 1g:10ml is mixed;
By the mixed liquor of gained, at power 150W, under the ultrasound condition of frequency 40kHz, and to control temperature be 25 ℃, and the time is that 15-30min carries out supersound extraction and then uses 0.45 μ m filtering with microporous membrane;
Resulting filtrate after filtering is controlled under the condition that vacuum is 0.094-0.096MPa and carried out rotary evaporation in vacuo, obtain the Flos Carthami extract concentrated solution;
The Flos Carthami extract concentrated solution of gained is controlled to temperature and for-55 ℃, carry out lyophilization, obtain the Flos Carthami natural pigment of 0.53g;
Described coloring agent powder is that the corn starch that the particle diameter superfine titanic oxide that is 50-500nm and particle diameter are 50-500nm calculates in mass ratio, i.e. superfine titanic oxide: the mixture that the ratio that corn starch is 1:1 forms;
Wherein said oil phase component is less than 7 oil soluble liquid nonionic emulsifier, antiseptic and liquid fat by the HLB value and mixes;
Wherein to be less than 7 oil soluble liquid nonionic emulsifier be SPAN-80 to the HLB value, and its consumption is 2 times of the HLB value quality that is greater than 7 water-soluble liquid nonionic emulsifier TWEEN80;
The consumption of liquid fat is 20 times of distilled water consumption;
The consumption of antiseptic is 0.145% of the color make-up color compositions gross mass containing Flos Carthami natural pigment extract;
Described liquid fat is that isopropyl palmitate and dimethicone calculate by volume, i.e. isopropyl palmitate: dimethicone is the mixture that 1:1 forms;
Described antiseptic is methyl hydroxybenzoate.
The preparation method of above-mentioned a kind of color make-up color compositions containing Flos Carthami natural pigment extract, comprise the following steps:
(1), get the 1mL distilled water, add 0.4g Flos Carthami natural pigment, the 0.2g superfine titanic oxide, the 0.2g corn starch, the TWEEN-80 of 0.2g, obtain the water component after mix homogeneously;
(2), get 10mL dimethicone, 10mL isopropyl palmitate, 0.4g SPAN-80 and 0.03g methyl hydroxybenzoate, obtain oil phase component after mix homogeneously;
(3), by the water component of step (1) gained under the condition stirred, oil phase component is poured in the water component, homogenizing or stirring 8min, after making water component and oil phase component mix homogeneously, obtain the color make-up color compositions containing Flos Carthami natural pigment extract of 20.63g.
The color make-up color compositions containing Flos Carthami natural pigment extract of above-mentioned gained, through more than 80 ℃, heating 2h, color is without significant change.
embodiment 3
A kind of color make-up color compositions containing Flos Carthami natural pigment extract comprises water component and oil phase component:
Wherein said water component is greater than 7 water-soluble liquid nonionic emulsifier, coloring agent powder, Flos Carthami natural pigment and distilled water by the HLB value and mixes, calculate in mass ratio, the water-soluble liquid nonionic emulsifier that the HLB value is greater than 7: coloring agent powder: Flos Carthami natural pigment: distilled water is 1:2:5:5;
It is TWEEN80 that wherein said HLB value is greater than 7 water-soluble liquid nonionic emulsifier;
Prepared by the following method by described Flos Carthami natural pigment:
After the Flos Carthami of 10g is dried to pulverizing, in the ethanol water that the mass percent concentration that adds 200ml is 50%, the ethanol water that control Flos Carthami and mass percent concentration are 50% is volume ratio, i.e. Flos Carthami by weight: the ratio that the ethanol water that mass percent concentration is 50% is 1g:20ml obtains mixed liquor after being mixed;
By the mixed liquor of gained, at power 150W, under the ultrasound condition of frequency 40kHz, and to control temperature be 25 ℃, and the time is that 20min carries out supersound extraction, then uses 0.45 μ m filtering with microporous membrane;
Resulting filtrate after filtering is controlled under the condition that vacuum is 0.094-0.096MPa and carried out rotary evaporation in vacuo, obtain the Flos Carthami extract concentrated solution;
The Flos Carthami extract concentrated solution of gained is controlled to temperature and for-55 ℃, carry out lyophilization, obtain the Flos Carthami natural pigment of 1.46g;
Described coloring agent powder is the superfine titanic oxide that particle diameter is 50-500nm;
Wherein said oil phase component is less than 7 oil soluble liquid nonionic emulsifier, antiseptic and liquid fat by the HLB value and is obtained by mixing;
Wherein to be less than 7 oil soluble liquid nonionic emulsifier be SPAN-80 to the HLB value, and its consumption is 2 times that the HLB value is greater than 7 water-soluble liquid nonionic emulsifier TWEEN80;
The consumption of liquid fat is 20 times of distilled water consumption;
The consumption of antiseptic is 0.141% of the color make-up color compositions gross mass containing Flos Carthami natural pigment extract;
Described liquid fat is that isopropyl palmitate and dimethicone calculate by volume, i.e. isopropyl palmitate: dimethicone is the mixture that 1:1 forms;
Described antiseptic is methyl hydroxybenzoate.
The preparation method of above-mentioned a kind of color make-up color compositions containing Flos Carthami natural pigment extract, comprise the following steps:
(1), get the 1mL distilled water, add 1.0g Flos Carthami natural pigment, the 0.4g superfine titanic oxide, the TWEEN-80 of 0.2g, obtain the water component after mix homogeneously;
(2), get 10mL dimethicone, 10mL isopropyl palmitate, 0.4g SPAN-80 and 0.03g methyl hydroxybenzoate, obtain oil phase component after mix homogeneously;
(3), by the water component of step (1) gained under the condition stirred, oil phase component is poured in the water component, homogenizing or stirring 8min, after making water component and oil phase component mix homogeneously, obtain the color make-up color compositions containing Flos Carthami natural pigment extract of 21.23g.
The color make-up color compositions containing Flos Carthami natural pigment extract of above-mentioned gained, through more than 80 ℃, heating 2h, color is without significant change.
Above said content is the basic explanation under conceiving for the present invention only, and, according to any equivalent transformation that technical scheme of the present invention is done, all should belong to protection scope of the present invention.