CN103442571A - Agricultural and horticultural bactericide/fungicide composition - Google Patents
Agricultural and horticultural bactericide/fungicide composition Download PDFInfo
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- CN103442571A CN103442571A CN2012800136157A CN201280013615A CN103442571A CN 103442571 A CN103442571 A CN 103442571A CN 2012800136157 A CN2012800136157 A CN 2012800136157A CN 201280013615 A CN201280013615 A CN 201280013615A CN 103442571 A CN103442571 A CN 103442571A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/20—N-Aryl derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
- A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
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- Engineering & Computer Science (AREA)
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- Agronomy & Crop Science (AREA)
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Abstract
The present invention pertains to an agricultural and horticultural bactericide/fungicide composition comprising (A) at least one agricultural and horticultural bactericide/fungicide selected from a group consisting of benzimidazole, guanidine, organosulfur, anilinopyrimidine, triazole, organochlorine, and organocopper bactericide/fungicides, (B) a dialkyl sulfosuccinate, and (C) a polyoxyethylene C11 - 15 alkyl ether at a mass ratio (A) : (B) : (C) of 1-70 : 1 : 1-4. This composition enhances, restores, or sustains the effect of the bactericide/fungicide.
Description
Technical field
The present invention relates to a kind of agricultural or horticultural bactericide composition, by freely contain the bactericide (A1) of benzimidazole ring in choosing, the bactericide that contains the guanidine structure (A2), the bactericide that contains organic sulfur (A3), the bactericide that contains the anilino-pyrimidine structure (A4), the bactericide that contains triazole ring (A5), mix dialkyl sulfosuccinates and the polyethylene glycol oxide C11～C15 alkyl ether as surfactant at least one agricultural or horticultural bactericide in the group that the bactericide that contains organochlorine (A6) and the bactericide (A7) that contains organic copper form, can strengthen or thereby the control efficiency of long term maintenance agriculture and garden pathogen makes its stabilisation.
Background technology
For agricultural or horticultural bactericide, spray and use and can give full play to its bactericidal activity effect for the ease of actual farm, on the preparation physical property, descended various time.Studying that the effect that makes bactericide in the preparation of bactericide strengthens or the agricultural or horticultural bactericide composition of stabilisation.Up to the present think, by specific bactericidal active ingredient being made to the agricultural or horticultural bactericide composition that contains specific surfactant, can obtain fungicidal effectiveness and strengthen or static stabilization.
For example, disclose following content in patent documentation 1: at least one the microbicide compositions contained in the benzoylpyridine derivatives as bactericidal active ingredient or its salt in the group of selecting free ethoxylated fatty amine, silicon class surfactant, citrate type surfactant, sulfuric acid ester type surfactant, phosphate-type surfactant, polyethylene oxide alkyl ethers, alkyl sulfo succinate and alkyl polyglucoside to form can make the control efficiency stabilisation.
In addition, disclose following content in patent documentation 2: contain with the weight ratio of 1:0.5～1:20 the microbicide compositions that specific bactericidal properties compound (KNF-1001 or KNF-1002) and bactericidal effect improve material and can strengthen bactericidal activity, described bactericidal effect improves material and is selected from the group consisted of the following composition: select the nonionic surface active agent in the group of castor oil, Pluronic F-127 and their compositions of mixtures of free polyethylene oxide alkyl ethers, polyethylene glycol oxide Arrcostab, ethoxylation; Select the anionic surfactant in the group of free Docusate Sodium, neopelex and their compositions of mixtures; And fatty acid alkyl esters.
The agricultural chemicals effect enhancer compositions that contains sorbitan fatty acid esters class surfactant and Resin Acid surfactant or quaternary ammonium salt surface active agent is disclosed in patent documentation 3.Put down in writing this agricultural chemicals has been applied in insecticide or bactericide by the effect enhancer compositions, particularly, the application examples of the iprodione aqua [3-(3,5-dichlorophenyl)-N-isopropyl-2,4-dioxo imidazoline-1-formamide] be applied to as bactericide is disclosed.But, aspect fungicidal effectiveness, seeking further effect humidification.
On the other hand, the ratio disclosed in patent documentation 4 with specified quantitative contains dialkyl sodium sulfosuccinate, polyethylene oxide alkyl ethers and the flow point reduction auxiliary material combination thing with composition.And to disclose said composition be share with various pesticide active ingredients and can make pesticide active ingredient be attached to the auxiliary material combination thing of crop surface.And, particularly, the insecticidal test of the diamond-back moth in the cabbage is disclosed.
The prior art document
Patent documentation
Patent documentation 1: TOHKEMY 2008-31163 communique
Patent documentation 2: Japanese Unexamined Patent Application Publication 2007-520432 communique
Patent documentation 3: Japanese kokai publication hei 8-151302 communique
Patent documentation 4: No. WO2008/111482, international publication number
Summary of the invention
Invent problem to be solved
Agricultural or horticultural bactericide has the tendency of its sterilization preventing efficiency slow decreasing along with repetitive administration.In addition, the pathogenic fungi that the Reduced susceptibility to using bactericide occurs sometimes.Therefore, the pathogen control efficiency of long term maintenance agricultural or horticultural bactericide and make its stabilisation, to effective control pathogen, significant contribution be arranged.Therefore, effectively play consistently the control efficiency of agricultural or horticultural bactericide widely in the urgent need to the surfactant that uses easy acquisition and pathogenic fungi that insecticide sensitivity is reduced etc. also can bring into play control efficiency agricultural or horticultural bactericide effect enhancer or maintain agent and use containing of its concrete surfactant and the agricultural or horticultural bactericide composition of agriculture chemicals fungicide.
Problem of the present invention be to provide the surfactant that can be applied to utilize easy acquisition agricultural or horticultural bactericide widely, steadily in the long term maintain the sterilization control efficiency and insecticide sensitivity is reduced after the control efficiency etc. of the pathogen agricultural or horticultural bactericide composition that contains bactericide and surfactant that also is enhanced or maintains.
For the means of dealing with problems
The inventor is studied in order to address the above problem, found that, with (A): (B): the content ratio of (C)=1～70:1:1～4 contains bactericide (hereinafter referred to as benzimidazole germicide) that choosing freely contains the benzimidazole ring (A1), the bactericide that contains the guanidine structure (hereinafter referred to as the guanidine series bactericidal agent) (A2), the bactericide that contains organic sulfur (A3) (hereinafter referred to as the organic sulfur series bactericidal agent), the bactericide that contains the anilino-pyrimidine structure (hereinafter referred to as the anilino-pyrimidine series bactericidal agent) (A4), the bactericide that contains triazole ring (hereinafter referred to as triazole bactericidal agent) (A5), the bactericide that contains organochlorine (hereinafter referred to as the organochlorine series bactericidal agent) (A6) and at least one agricultural or horticultural bactericide (A) in the group that (A7) forms of the bactericide that contains organic copper (hereinafter referred to as the organic copper series bactericidal agent), (B) dialkyl sulfosuccinates and (C) the agricultural or horticultural bactericide composition of polyethylene glycol oxide C11～C15 alkyl ether can strengthen or maintain the control efficiency of target pathogen and make its stabilisation, thereby completed the present invention.
That is, the present invention relates to following invention.
(1) a kind of agricultural or horticultural bactericide composition, it contains:
(A) at least one agricultural or horticultural bactericide in the group that the bactericide (A7) that choosing freely contains the bactericide (A1) of benzimidazole ring, the bactericide (A2) that contains the guanidine structure, the bactericide (A3) that contains organic sulfur, the bactericide (A4) that contains anilino-pyrimidine, the bactericide (A5) that contains triazole ring, the bactericide (A6) that contains organochlorine and contains organic copper forms;
(B) dialkyl sulfosuccinates; And
(C) polyethylene glycol oxide C11～C15 alkyl ether,
And the content ratio of mass ratio of take is (A): (B): (C)=1～70:1:1～4.
(2) above-mentioned (1) described agricultural or horticultural bactericide composition, wherein, described dialkyl sulfosuccinates (B) is two (2-ethylhexyl) sulfosuccinate.
(3) the described agricultural or horticultural bactericide composition in above-mentioned (1) or (2), wherein, the described bactericide that contains the benzimidazole ring (A1) is more than one in the group of selecting the mould prestige of free second, thiophanate-methyl and benomyl to form.
(4) the described agricultural or horticultural bactericide composition in above-mentioned (1) or (2), wherein, the described bactericide that contains the guanidine structure (A2) is iminoctadine triacetate or iminoctadine alkylbenzenesulfonate.
(5) the described agricultural or horticultural bactericide composition in above-mentioned (1) or (2), wherein, described organic sulfur series bactericidal agent (A3) is more than one in the group of selecting free tmtd, Polycarbamate, mancozeb and maneb to form.
(6) the described agricultural or horticultural bactericide composition in above-mentioned (1) or (2), wherein, the described bactericide that contains the anilino-pyrimidine structure (A4) is cyprodinil or mepanipyrim.
(7) the described agricultural or horticultural bactericide composition in above-mentioned (1) or (2), wherein, the described bactericide that contains triazole ring (A5) is more than one in the group of selecting free Difenoconazole, Cyproconazole, Tebuconazole and penconazole to form.
(8) the described agricultural or horticultural bactericide composition in above-mentioned (1) or (2), wherein, the described bactericide that contains organochlorine (A6) is TPN or captan.
(9) the described agricultural or horticultural bactericide composition in above-mentioned (1) or (2), wherein, the described bactericide that contains organic copper (A7) is copper 8-quinolinolate.
(10) above-mentioned (1) described agricultural or horticultural bactericide composition, wherein,
(i) bactericide that contains the benzimidazole ring (A1) is at least one in the group of selecting the mould prestige of free second, thiophanate-methyl and benomyl to form;
(ii) bactericide that contains the guanidine structure (A2) is iminoctadine triacetate or iminoctadine alkylbenzenesulfonate;
(iii) bactericide that contains organic sulfur (A3) is at least one in the group of selecting free tmtd, Polycarbamate, mancozeb and maneb to form;
(iv) bactericide that contains the anilino-pyrimidine structure (A4) is cyprodinil or mepanipyrim;
(v) bactericide that contains triazole ring (A5) is at least one in the group of selecting free Difenoconazole, Cyproconazole, Tebuconazole, penconazole to form;
(vi) bactericide that contains organochlorine (A6) is TPN or captan; And
(vii) bactericide that contains organic copper (A7) is for being selected from as at least one in the group of copper 8-quinolinolate.
(11) above-mentioned (10) described agricultural or horticultural bactericide composition, wherein,
(B) composition is two (2-ethylhexyl) sulfosuccinate;
(A) when composition is respectively above-mentioned (i)～(vii), (A) composition, (B) composition and (C) ratio of composition is as follows respectively:
(a) during containing described (i), (A1): (B): (C)=1～40:1:1～4,
(b) during containing described (ii), (A2): (B): (C)=1～10:1:1～4,
(c) during containing described (iii), (A3): (B): (C)=10～70:1:1～4
(d) during containing described (iv), (A4): (B): (C)=1～20:1:1～4
(e) during containing described (v), (A5): (B): (C)=1～20:1:1～4
(f) during containing described (vi), (A6): (B): (C)=1～30:1:1～4
(g) during containing described (vii), (A7): (B): (C)=10～40:1:1～4.
(12) the described agricultural or horticultural bactericide composition in above-mentioned (10) or (11), wherein,
(B) composition is two (2-ethylhexyl) sulfosuccinate;
As (A) composition, contain any one or above-mentioned (vi) in above-mentioned (i)～(v) and (vii) both, (A) mass ratio of the total amount of composition is as follows respectively with respect to (B) composition with (C) for composition:
(a), during containing described (i), be (A1): 1～18,
(b), during containing described (ii), be (A2): 0.4～6,
(c), during containing described (iii), be (A3): 5～35,
(d), during containing described (iv), be (A4): 0.6～7,
(e), during containing described (v), be (A5): 0.5～3,
(f) containing described (vi) and (vii) both the time, be { (A6)+(A7) }: 4～30.
(13) the described agricultural or horticultural bactericide composition of any one in above-mentioned (1)～(12), wherein, (A) composition, (B) composition and (C) total amount shared ratio in the total amount of agricultural or horticultural bactericide composition of composition be 40～100 quality %, 60～0 quality % are the agricultural chemicals additive outside (A)～(C).
(14) a kind of flushing liquor of agricultural or horticultural bactericide composition, it,, by above-mentioned (1)～(13), in the described agricultural or horticultural bactericide composition of any one, adding water, makes each constituent concentration be:
(A) constituent concentration is 10～3000ppm;
(B) constituent concentration is 10～200ppm; And
(C) constituent concentration is 10～800ppm
And obtain.
(15) a kind of method of preventing and treating of soybean purple speck, wheat red rust disease or potato purple spot, is characterized in that, above-mentioned (14) described flushing liquor is sprayed onto on the petiole of soybean, wheat or potato.
(16) a kind of method of preventing and treating of grey mould fruit rot of strawberry or apple scab, is characterized in that, the described flushing liquor in (1)～(12) is sprayed onto on the petiole of strawberry or on the tree and leaf of apple.
(17) the mixed surfactant composition manufacturing effect be enhanced or the agricultural or horticultural bactericide composition that contains following (A) that maintains in application,
Described mixed surfactant composition contains (B) dialkyl sulfosuccinates and (C) polyethylene glycol oxide C11～C15 alkyl ether, and (B) of example meter in mass ratio: (C) content ratio is 1:1～4,
At least one agricultural or horticultural bactericide in the group that the bactericide (A7) that described (A) freely contains the bactericide (A1) of benzimidazole ring, the bactericide (A2) that contains the guanidine structure, the bactericide (A3) that contains organic sulfur, the bactericide (A4) that contains the anilino-pyrimidine structure, the bactericide (A5) that contains triazole ring, the bactericide (A6) that contains organochlorine and contain organic copper for choosing forms.
(18) a kind of method that strengthens or maintain the bactericidal effect of agricultural or horticultural bactericide, it is characterized in that, the bactericide (A1) that freely contains the benzimidazole ring in (A) choosing, the bactericide that contains the guanidine structure (A2), the bactericide that contains organic sulfur (A3), the bactericide that contains the anilino-pyrimidine structure (A4), the bactericide that contains triazole ring (A5), in at least one agricultural or horticultural bactericide in the group that the bactericide that contains organochlorine (A6) and the bactericide (A7) that contains organic copper form, count (A) with example in mass ratio: (B): the ratio of (C)=1～70:1:1～4, cooperation is counted (B) with mass ratio: the ratio of (C)=1:1～4 contains (B) dialkyl sulfosuccinates and (C) the mixed surfactant composition of polyethylene glycol oxide C11～C15 alkyl ether.
(19) a kind of effect is enhanced or the manufacture method of the agricultural or horticultural bactericide flushing liquor that maintains, it is characterized in that, and add mixed surfactant composition and water and make flushing liquor in agricultural or horticultural bactericide (A),
At least one in the group that the bactericide (A7) that described agricultural or horticultural bactericide (A) freely contains the bactericide (A1) of benzimidazole ring, the bactericide (A2) that contains the guanidine structure, the bactericide (A3) that contains organic sulfur, the bactericide (A4) that contains the anilino-pyrimidine structure, the bactericide (A5) that contains triazole ring, the bactericide (A6) that contains organochlorine and contains organic copper for choosing forms
Described mixed surfactant composition is with (B): (B) dialkyl sulfosuccinates and (C) polyethylene glycol oxide C11～C15 alkyl ether are contained in (C)=1:1～4,
Described flushing liquor is counted (A) with example in mass ratio: (B): the ratio of (C)=1～70:1:1～4 contains (A), (B) and (C) each composition, and described each constituent concentration is:
(A) composition: 10～3000ppm,
(B) composition: 10～200ppm,
(C) composition: 10～800ppm.
(20) a kind of enhancing, recover or maintain the method for agricultural or horticultural bactericide (A) to the susceptibility of the pathogen after Reduced susceptibility, wherein, the bactericide (A1) that freely contains the benzimidazole ring in choosing, the bactericide that contains the guanidine structure (A2), the bactericide that contains organic sulfur (A3), the bactericide that contains the anilino-pyrimidine structure (A4), the bactericide that contains triazole ring (A5), in at least one agricultural or horticultural bactericide (A) in the group that the bactericide that contains organochlorine (A6) and the bactericide (A7) that contains organic copper form, count (A) with example in mass ratio: (B): the ratio of (C)=1～70:1:1～4, add (B) dialkyl sulfosuccinates and (C) polyethylene glycol oxide C11～C15 alkyl ether.
The invention effect
For agricultural or horticultural bactericide composition of the present invention, bactericidal effect that can the long term maintenance bactericidal active ingredient by it being sprayed on to the object crop.Therefore, the same bactericide of continuous administration for a long time, and there is the effect that effective pathogen pesticide control is contributed.Perhaps, the target pathogenic fungi after the Reduced susceptibility that the effect of bactericide reduces for being identified concomitant administration, by making agricultural or horticultural bactericide composition of the present invention, have the effect that makes preventing efficiency recover, make fungicidal effectiveness strengthen or maintain.
Embodiment
Below, to agricultural or horticultural bactericide composition of the present invention, the method for preventing and treating of utilizing this agricultural or horticultural bactericide composition and enhancing, recover or maintain agricultural or horticultural bactericide the method for the susceptibility of pathogen is described in more detail.
Agricultural or horticultural bactericide composition of the present invention is characterised in that, contain and select free benzimidazole germicide (A1), guanidine series bactericidal agent (A2), organic sulfur series bactericidal agent (A3), anilino-pyrimidine series bactericidal agent (A4), triazole bactericidal agent (A5), organochlorine series bactericidal agent (A6), at least one agricultural or horticultural bactericide (A) in the group that organic copper series bactericidal agent (A7) forms is as bactericidal active ingredient, contain (B) dialkyl sulfosuccinates and (C) polyethylene glycol oxide C11～C15 alkyl ether both as for strengthening, recover or maintain the composition of the effect of this bactericidal active ingredient, and count (A) with example in mass ratio: (B): the ratio of (C)=1～70:1:1～4 contains this three kinds of compositions.
Agricultural or horticultural bactericide composition of the present invention can be by mixing above-mentioned (A) composition, (B) composition and (C) becoming to assign to manufacture with aforementioned proportion, also can add as required above-mentioned (A), (B) and (C) outside the agricultural chemicals additive.A preferred manufacture method is to coordinate (B) composition and (C) composition with aforementioned proportion in commercially available agricultural or horticultural bactericide preparation.
In order to strengthen, recover or maintain the effect of the contained bactericide of agricultural or horticultural bactericide composition of the present invention, with above-mentioned ratio i.e. (A): (B): the ratio of (C)=1～70:1:1～4 contains above-mentioned (A) composition, (B) composition and (C) composition.
In addition, in the present invention, content, contain ratio, % and part etc. unless otherwise noted, be quality standard.Therefore, agricultural or horticultural bactericide composition of the present invention contains mentioned component with the ratio of above-mentioned (A) composition 1～70 mass parts, (B) composition 1 mass parts, (C) composition 1～4 mass parts.Use with (A) composition to (C) composition is arranged by using in above-mentioned ratio ranges, agricultural or horticultural bactericide composition of the present invention can be given full play to the pharmacologically active effect of Fungicidal active substance, compare with existing fungicide preparation, can strengthen significantly, recover or maintain bactericidal effect.
(B) composition and (C) when composition is aforementioned proportion, add to and can separately add as time in the agricultural or horticultural bactericide of (A) composition, also can add together, all no problem.Preferred a kind of mode be using in above-mentioned specific ratio contain (B) composition and (C) form of the mixed surfactant composition of composition add to as the method in the agricultural or horticultural bactericide of (A) composition.The aforementioned proportion of usining add (B) composition and (C) composition there is enhancing, recover or maintain the effect as the bactericidal effect of the agricultural or horticultural bactericide of (A) composition.In addition, above-mentioned (A) agricultural or horticultural bactericide composition is also very important with respect to the ratio of (B) composition (or (B) composition and (C) total amount of composition).If (B) composition (or (B) composition and (C) total amount of composition) is very few with respect to the ratio of above-mentioned (A) agricultural or horticultural bactericide composition, is difficult to maintain and thinks by sterilization control efficiency these surfactant component promotions, significant.In addition, if above-mentioned (B) composition and (C) ratio of composition is too high, this agricultural or horticultural bactericide likely occurring and run off and the poisoning such as the fungicidal effectiveness reduction that causes, leaf blight in crop surface, hinders the possibility of the sound growth of sufficient control efficiency and crop to uprise.Based on these reasons, in order to strengthen or to recover the control efficiency of agriculture and garden pathogen, reach control efficiency reliably, preferably the content ratio of above-mentioned each composition is above-mentioned scope, more preferably (A): (B): (C)=1～60:1:1.5～3, further preferred (A): (B): (C)=1～60:1:1.8～2.5.
Ratio (quality) about (C) composition in above-mentioned mixed surfactant composition with respect to (B) composition, with respect to 1 part of (B) composition, (C) composition is 1～4 part, is preferably approximately 1.5 parts～approximately 3 parts, more preferably from about 1.8 parts～approximately 2.5 parts.In the scope of not damaging effect of the present invention, this mixed surfactant composition also can approximately 0% contain other agricultural chemicals additives to about 20% scope.Usually, preferably do not contain other agricultural chemicals with additive by (B) composition and (C) composition occupy the total amount of this mixed surfactant composition.
In addition, as (B) and the ratio shared with respect to the total amount of microbicide compositions of the present invention of total (C), be generally approximately 4%～approximately 40%, more preferably from about 6%～approximately 30%, most preferably from about 6%～approximately 20%.
In the microbicide compositions of the invention described above (A) composition with respect to (B) composition and (C) ratio of the total amount of composition according to the kind of (A) composition and difference, must not make sweeping generalizations, but usually with respect to (B) composition and (C) 1 part of the total amount of composition be approximately 0.4 part～approximately 35 parts.
In addition, (A) composition, (B) composition and (C) total amount of composition shared ratio in the microbicide compositions of the invention described above with respect to the total amount of said composition, can be 40～100% scope usually, preferably approximately 40%～approximately 90%, more preferably from about 50%～approximately 90%.About remainder, 10%～approximately 60%, more preferably from about 10%～approximately 50% be approximately for example 0 to 60%, preferably above-mentioned (A) composition, (B) composition and (C) the agriculture and garden additive outside composition, such as solvent (organic solvent usually used in agricultural chemicals), (B) composition and (C) surfactant outside composition, other additives etc.
When using agricultural or horticultural bactericide, common dilute with water and make flushing liquor and use.Agricultural or horticultural bactericide composition of the present invention (also referred to as microbicide compositions of the present invention) also can dilute to prepare by adding water the flushing liquor of agricultural or horticultural bactericide composition.In the flushing liquor of this agricultural or horticultural bactericide composition, with the ratio identical with agricultural or horticultural bactericide composition of the present invention, contain (A) composition, (B) composition and (C) composition.Therefore, this flushing liquor is also the another way of agricultural or horticultural bactericide composition of the present invention, comprises in the present invention.
In the present invention, as bactericidal active ingredient for agriculture and garden (A), use at least one agricultural or horticultural bactericide in the group of selecting free benzimidazole germicide, guanidine series bactericidal agent, organic sulfur series bactericidal agent, anilino-pyrimidine series bactericidal agent, triazole bactericidal agent, organochlorine series bactericidal agent, organic copper series bactericidal agent to form.Should contain the various compounds that agriculture and garden is used bactericidal activity that have that belong to this system by (A) composition.The known bactericidal active ingredient that can preferably be used as agricultural or horticultural bactericide and generally use.In the present invention, be somebody's turn to do the compound that (A) composition can directly be used as this bactericidal active ingredient to use.In addition, also can using the mode that keeps its preparation type uses the agricultural or horticultural bactericide preparation that can obtain as commercially available product.When using commercially available agricultural or horticultural bactericide preparation, coordinate (B) composition and (C) composition by take mode that the ratio of each composition is aforementioned proportion in said preparation, can access microbicide compositions of the present invention.Microbicide compositions of the present invention is preferably used in the mode of the flushing liquor after dilute with water usually.Therefore, in the present invention, when the agricultural or horticultural bactericide preparation by commercially available is used for being somebody's turn to do (A) composition, preparation type such as aqua, particle aqua, flowable (floable agent), emulsion or the microcapsules etc. preferably after dilute with water, used.In addition, as the preparation type of microbicide compositions of the present invention, the preparation preferably used after the dilute with waters such as aqua, particle aqua, flowable, emulsion, microcapsules.
As the agricultural or horticultural bactericide used in the present invention (A), so long as can be used as the compound of the agricultural or horticultural bactericide use that belongs to above-mentioned (A1)～(A7), can use.Usually generally be used as the compound that above-mentioned agricultural or horticultural bactericide is known.
Below, its concrete example is shown this (A) composition is described.But, be not limited to these concrete examples.
Concrete example as benzimidazole germicide of the present invention (A1), can list: the mould prestige of second (common name) (chemical name: 3, Thiophanate-Methyl), benomyl (common name) (chemical name: 1-n-butyl amine base formyl-methyl 2-benzimidazolecarbamate) etc. 4-diethoxy phenylcarbamic acid isopropyl ester), thiophanate-methyl (common name) (chemical name:.
This benzimidazole germicide (A1) may be used alone, used in two or more.Concrete example during as two or more this bactericide of application, can enumerate: the mould prestige of second and thiophanate-methyl, the mould prestige of second and benomyl, thiophanate-methyl and benomyl etc.As (A1) composition, the particularly preferably mould prestige of second or the thiophanate-methyl of being somebody's turn to do of the present invention.The perhaps preferred mode of the mould prestige of second and thiophanate-methyl use.In also using, usually used as mixture, use.
In the manufacture of microbicide compositions of the present invention, as this benzimidazole germicide (A1), as mentioned above, can directly use the active ingredient compound, in addition, also can directly use the commercially available agricultural or horticultural bactericide preparation that contains this active ingredient compound.
While in microbicide compositions of the present invention, using above-mentioned benzimidazole germicide (A1), preferred benzimidazole germicide (A1): dialkyl sulfosuccinates (B): the content ratio that polyethylene glycol oxide C11～C15 alkyl ether (C) is 1～40:1:1～4.More preferably (A1): (B): the content ratio of (C)=1～30:1:1.5～3.In addition, according to circumstances, also preferred (A1): (B): the content ratio of (C)=5～40:1:1.5～3.
In addition, in microbicide compositions of the present invention, the ratio as (A1) with respect to (B) and total (C) (1 part), be generally approximately 0.5 part～approximately 35 parts, preferably approximately 1 part～approximately 20 parts, more preferably from about 2 parts～approximately 15 parts, most preferably from about 4 parts～approximately 12 parts.
As (B) and the ratio shared with respect to the total amount of microbicide compositions of the present invention of total (C), be generally approximately 4%～approximately 40%, more preferably from about 6%～approximately 30%, most preferably from about 6%～approximately 20%, (A1) the shared ratio of composition is approximately 40%～approximately 90%, preferably 50～80%, remainder be (A1), (B) and (C) outside the agricultural chemicals additive.In addition, (A1), (B) and total amount (C) are generally more than 50% with respect to the ratio of the total amount of microbicide compositions of the present invention, preferably 60%～100%, more preferably 60～80%, remainder be (A1), (B) and (C) outside the agricultural chemicals additive.
Concrete example as the guanidine series bactericidal agent (A2) in the present invention, can enumerate: iminoctadine triacetate (common name) (chemical name: 1,1-imino-diacetic (eight methylene) triacetic acid guazatine), iminoctadine alkylbenzenesulfonate (common name) (chemical name: 1,1-imino-diacetic (eight methylene) three (alkyl benzene sulphonate guazatine)) etc.
In the manufacture of microbicide compositions of the present invention, as this guanidine series bactericidal agent (A2), as mentioned above, can directly use the active ingredient compound, in addition, also can directly use the commercially available agricultural or horticultural bactericide preparation that contains this active ingredient compound.
In microbicide compositions of the present invention, preferred guanidine series bactericidal agent (A2): dialkyl sulfosuccinates (B): polyethylene glycol oxide C11～C15 alkyl ether (C) is 1～20:1:1～4.More preferably (A2): (B): the ratio of (C)=1～10:1:1.5～3.
In addition, in microbicide compositions of the present invention, the ratio as (A2) with respect to (B) and total (C) (1 part), preferably approximately 0.2 part～approximately 10 parts, more preferably from about 0.5 part～approximately 6 parts, most preferably from about 2 parts～approximately 3 parts.
In addition, as (B) and the ratio shared with respect to the total amount of microbicide compositions of the present invention of total (C), be approximately 4%～approximately 40%, more preferably from about 6%～approximately 30%, most preferably from about 6%～approximately 20%, (A2) the shared ratio of composition is approximately 30%～approximately 90%, preferably 35～60%, remainder be (A2), (B) and (C) outside the agricultural chemicals additive.In addition, (A2), (B) and total amount (C) are generally more than 40% with respect to the ratio of the total amount of microbicide compositions of the present invention, preferably 50～100%, more preferably 60～90%, remainder be (A2), (B) and (C) outside the agricultural chemicals additive.
Two (dimethyl thiocarbamoyl) disulphide), Polycarbamate (common name) (chemical name: two Methyl disulfide are for the carbamyl zinc ethylene bisdithiocarbamate), mancozeb (common name) (chemical name: the complex compound of ethylidene dithiocarbamate manganese and zinc), maneb (common name) (chemical name: ethylidene dithiocarbamate manganese) etc. as the concrete example of the organic sulfur series bactericidal agent (A3) in the present invention, can enumerate: tmtd (common name) (chemical name:.As (A3) composition that is somebody's turn to do of the present invention, particularly preferably use mancozeb.
In the manufacture of microbicide compositions of the present invention, as this organic sulfur series bactericidal agent (A3), as mentioned above, can directly use the active ingredient compound, also can directly use the commercially available agricultural or horticultural bactericide preparation that contains this active ingredient compound.
In microbicide compositions of the present invention, preferred organic sulfurcontaining fungicide (A3): dialkyl sulfosuccinates (B): the ratio that polyethylene glycol oxide C11～C15 alkyl ether (C) is 10～70:1:1～4.More preferably (A3): (B): the ratio of (C)=20～70:1:1.5～3.
In addition, in microbicide compositions of the present invention, the ratio as (A3) with respect to (B) and total (C) (1 part), preferably approximately 10 parts～approximately 30 parts, more preferably from about 12 parts～approximately 25 parts.
In addition, as (B) and the ratio shared with respect to the total amount of microbicide compositions of the present invention of total (C), for approximately 2%～approximately 20%, more preferably from about 3%～approximately 15%, most preferably from about 3%～approximately 10%, (A3) the shared ratio of composition is approximately 50%～approximately 90%, preferably 60～85%, remainder be (A3), (B) and (C) outside the agricultural chemicals additive.In addition, (A3), (B) and total amount (C) are generally more than 50% with respect to the ratio of the total amount of microbicide compositions of the present invention, preferably 60～100%, more preferably 60～90%, remainder be (A3), (B) and (C) outside the agricultural chemicals additive.
4-cyclopropyl-6-methyl-N-phenylpyridine-2-amine), mepanipyrim (common name) (chemical name: N-(4-methyl-N-phenyl-6-third-1-alkynyl pyrimidine-2-base) aniline) etc. as the concrete example of anilino-pyrimidine series bactericidal agent (A4) in the present invention, can enumerate: cyprodinil (common name) (chemical name:.As (A4) composition, the particularly preferably mepanipyrim of being somebody's turn to do of the present invention.
In the manufacture of microbicide compositions of the present invention, as this anilino-pyrimidine series bactericidal agent (A4), as mentioned above, can directly use the active ingredient compound, in addition, also can directly use the commercially available agricultural or horticultural bactericide preparation that contains this active ingredient compound.
In microbicide compositions of the present invention, preferred anilino-pyrimidine series bactericidal agent (A4): dialkyl sulfosuccinates (B): the ratio that polyethylene glycol oxide C11～C15 alkyl ether (C) is 1～30:1:1～4.More preferably (A4): (B): the content ratio of (C)=1～20:1:1.5～3.
In addition, in microbicide compositions of the present invention, the ratio as (A4) with respect to (B) and total (C) (1 part), preferably approximately 0.5 part～approximately 10 parts, more preferably from about 0.8 part～approximately 7 parts, further preferred approximately 1 part～approximately 5 parts, most preferably from about 2 parts～approximately 5 parts.
In addition, as (B) and the ratio shared with respect to the total amount of microbicide compositions of the present invention of total (C), be generally approximately 4%～approximately 40%, more preferably from about 5%～approximately 30%, most preferably from about 5%～approximately 15%, (A4) the shared ratio of composition is approximately 30%～approximately 80%, is preferably 35～60%, remainder be (A4), (B) and (C) outside the agricultural chemicals additive.In addition, (A4), (B) and total amount (C) are generally more than 35% with respect to the ratio of the total amount of microbicide compositions of the present invention, preferably 40～100%, more preferably 40～60%, remainder be (A4), (B) and (C) outside the agricultural chemicals additive.
Concrete example as triazole bactericidal agent in the present invention (A5); can enumerate: Difenoconazole (common name) (chemical name: cis; the chloro-4-[4-methyl-2-of trans-3-(1H-1; 2; 4-triazol-1-yl methyl)-1; 3-dioxolane-2-yl) phenyl 4-chlorphenyl ether), Cyproconazole (common name) (chemical name: (2RS, 3RS; 2RS, 3SR)-2-(4-chlorphenyl)-3-cyclopropyl-1-(1H-1,2, the 4-triazol-1-yl) fourth-2-alcohol), Tebuconazole (common name) (chemical name: (RS)-1-(4-chlorphenyl)-4,4-dimethyl-3-(1H-1,2,4 triazol-1-yl methyl) penta-3-alcohol), penconazole (common name) (chemical name: 1-[2-(2, the 4-dichlorophenyl) amyl group]-1H-1,2,4-triazole) etc.As (A5) composition, the particularly preferably Tebuconazole of being somebody's turn to do of the present invention.
In the manufacture of microbicide compositions of the present invention, as this triazole bactericidal agent (A5), as mentioned above, can directly use the active ingredient compound, in addition, also can directly use the commercially available agricultural or horticultural bactericide preparation that contains this active ingredient compound.
In microbicide compositions of the present invention, preferred triazole bactericidal agent (A5): dialkyl sulfosuccinates (B): the ratio that polyethylene glycol oxide C11～C15 alkyl ether (C) is 1～20:1:1～4.More preferably (A5): (B): the ratio of (C)=1～10:1:1.5～3.Most preferably be (A5): (B): the ratio of (C)=1～5:1:1.5～3.
In addition, in microbicide compositions of the present invention, the ratio as (A5) with respect to (B) and total (C) (1 part), preferably approximately 0.5 part～approximately 10 parts, more preferably from about 0.8 part～approximately 7 parts, more preferably from about 1 part～approximately 5 parts, most preferably from about 2 parts～approximately 5 parts.
In addition, as (B) and the ratio shared with respect to the total amount of microbicide compositions of the present invention of total (C), for approximately 5%～approximately 40%, more preferably from about 10%～approximately 35%, most preferably from about 15%～approximately 35%, (A5) the shared ratio of composition is approximately 25%～approximately 80%, is preferably 33～60%, remainder be (A5), (B) and (C) outside the agricultural chemicals additive.In addition, (A5), (B) and total amount (C) are generally more than 35% with respect to the ratio of the total amount of microbicide compositions of the present invention, preferably 40～100%, more preferably 40～60%, remainder be (A5), (B) and (C) outside the agricultural chemicals additive.
Termil), captan (common name) (chemical name: N-trichloro-methylthio tetrahydric phthalimide) etc. as the concrete example of organochlorine series bactericidal agent (A6) in the present invention, can enumerate: TPN (common name) (chemical name:.As (A6) composition that is somebody's turn to do of the present invention, particularly preferably use captan.
In the manufacture of microbicide compositions of the present invention, as this organochlorine series bactericidal agent (A6), as mentioned above, can directly use the active ingredient compound, in addition, also can directly use the commercially available agricultural or horticultural bactericide preparation that contains this active ingredient compound.
In microbicide compositions of the present invention, preferred organochlorine series bactericidal agent (A6): dialkyl sulfosuccinates (B): the ratio that polyethylene glycol oxide C11～C15 alkyl ether (C) is 1～30:1:1～4.More preferably (A6): (B): the ratio of (C)=5～25:1:1.5～3.
As the concrete example of organic copper series bactericidal agent (A7) in the present invention, can enumerate 8-hydroxyquinone copper etc.In the manufacture of microbicide compositions of the present invention, as this organic copper series bactericidal agent (A7), as mentioned above, can directly use the active ingredient compound, in addition, also can directly use the commercially available agricultural or horticultural bactericide preparation that contains this active ingredient compound.
While in microbicide compositions of the present invention, using above-mentioned organic copper series bactericidal agent (A7), the content ratio in said composition is preferably organic copper series bactericidal agent (A7): dialkyl sulfosuccinates (B): polyethylene glycol oxide C11～C15 alkyl ether (C) is (A7): (B): the content ratio of (C)=10～40:1:1～4.More preferably (A7): (B): the content ratio of (C)=10～30:1:1.5～3.
Preferably in microbicide compositions of the present invention and by the mode of above-mentioned organochlorine series bactericidal agent (A6) and above-mentioned organic copper series bactericidal agent (A7).As concrete example, can exemplify also using of captan and 8-hydroxyquinone copper.When also using both, both mixed proportions are not particularly limited, usually preferred (A6): (A7) be about 1:0.5～2.In addition, this bactericidal active ingredient ((A6) and total (A7)) is with respect to (B) composition and (C) preferably approximately 5 parts～approximately 20 parts of the ratios of the total amount of composition (1 part), more preferably from about 7 parts～approximately 15 parts.In addition, this bactericidal active ingredient ((A6) and total (A7)), (B) and total amount (C) are generally more than 40% with respect to the ratio of the total amount of microbicide compositions of the present invention, preferably 40～100%, more preferably 40～60%, remainder be this bactericidal active ingredient, (B) and (C) outside the agricultural chemicals additive.
Microbicide compositions of the present invention contains the dialkyl sulfosuccinates (B) as anion surfactant.The alkyl of dialkyl sulfosuccinates so long as the ester group of succinic acid and playing a role as hydrophobic functional groups be not particularly limited.As this alkyl, straight chained alkyl or the branched alkyl of preferred C6～C12.Such as enumerating: hexyl, heptyl, n-octyl, n-nonyl, decyl, undecyl, dodecyl or 2-ethylhexyl etc.In dialkyl sulfosuccinates, this alkyl can be identical, also can be different.In addition, as the salt of dialkyl sulfosuccinates, there is no particular limitation, can use ammonium salt, alkali metal salt, alkali salt etc.Be preferably alkali metal salt, more preferably sodium salt, sylvite.As this (B) composition, preferred high two (C8～C12 branched alkyl) sodium sulfosuccinate of wettability, wherein, more preferably two (2-ethylhexyl) sulfonic acid sodium succinate.When the impurity of the dialkyl sodium sulfosuccinate used is many, the fungicidal effectiveness of this agricultural or horticultural bactericide composition improves (or enhancing) or stable maintenance weak effect and to spraying crop generation poisoning, the therefore preferred high dialkyl sodium sulfosuccinate of purity, preferably active ingredient is more than 65%.
Dialkyl sulfosuccinates (B) can be used as commercially available product and obtains, and also can directly use these compositions.As representational two (2-ethylhexyl) sodium sulfosuccinate, can enumerate: ラ ピ ゾ ー Le
rTMa90 (trade name, NOF Corp manufactures, containing two (2-ethylhexyl) sodium sulfosuccinate 90%, containing methyl alcohol 3.7%), エ ア ロ ー Le
rTMcT-1L (trade name, Dong Bang KCC manufactures, containing two (2-ethylhexyl) sodium sulfosuccinate 70%), ニ ュ ー カ Le ゲ Application EP-70G (trade name, Zhu Ben's Oil Corporation manufactures, containing two (2-ethylhexyl) sodium sulfosuccinate 70%) etc.
Agricultural or horticultural bactericide composition of the present invention contains polyethylene glycol oxide C11 as nonionic surface active agent～C15 alkyl ether (C).Being somebody's turn to do (C) composition so long as the polyethylene oxide alkyl ethers that alkyl chain is C11～C15 scope just can be used, can be that carbon number is a kind of compound, can be also that carbon number is mixture of more than two kinds.As concrete example, such as enumerating: have C11～C15 alkyl chain compound mixture, have C12～C14 alkyl chain compound mixture or use separately the compound etc. of the alkyl chain with C13.The alkyl chain length of this nonionic surface active agent exerts an influence to the significant sterilization control efficiency that realizes this agricultural or horticultural bactericide composition.Wherein, particularly preferably the alkyl chain of C12～C14, aspect the raising bactericidal action, be preferably based on the mixture of this polyethylene oxide alkyl ethers of C12～C14 alkyl chain.In addition, the degree of polymerization of polyethylene oxide chain also has a significant impact the HLB (Hydrophile-Lipophile Balance, hydrophilic lipophilic balance) of the oil of presentation surface activating agent-water characteristic value, is important factor.The degree of polymerization is various, as long as be, more than 2, all can use.Preferred degree of polymerization is 3～12.More preferably the degree of polymerization is more than 7, and the degree of polymerization is 7～12nd, suitable.
Polyethylene glycol oxide C11～C15 alkyl ether (C) can be used as commercially available product and obtains, and can directly use these commercially available products.As representational example, can enumerate: ペ グ ノ ー Le
rTMt-3 (trade name, Dong Bang KCC manufactures, the polyethylene glycol oxide degree of polymerization=3), ペ グ ノ ー Le
rTMsT-5 (trade name, Dong Bang KCC manufactures, the polyethylene glycol oxide degree of polymerization=5), ペ グ ノ ー Le
rTMsT-7 (trade name, Dong Bang KCC manufactures, the polyethylene glycol oxide degree of polymerization=7), ペ グ ノ ー Le
rTMsT-9 (trade name, Dong Bang KCC manufactures, the polyethylene glycol oxide degree of polymerization=9), ペ グ ノ ー Le
rTMsT-12 (trade name, Dong Bang KCC manufactures, the polyethylene glycol oxide degree of polymerization=12) etc.Wherein, preferably the degree of polymerization of polyethylene glycol oxide is the ペ グ ノ ー Le more than 7
rTMsT-7, ペ グ ノ ー Le
rTMsT-9, ペ グ ノ ー Le
rTMsT-12.It should be noted that above-mentioned ペ グ ノ ー Le
rTMfor polyoxyethylene allylic alkylation (mixing of C12～C14) ether.
In addition, the present invention also relates to be used as the above-mentioned dialkyl sulfosuccinates (B) of anion surfactant and strengthen, recover or maintain the technology with composition as the mixture (also referred to as the mixed surfactant composition) of the above-mentioned polyethylene glycol oxide C11 of non-ionic surface active agent～these two kinds of surfactants of C15 alkyl ether (C) as the effect of agricultural or horticultural bactericide.It is known using the serviceability of surfactant in composition pesticide.But, when crops are used to surfactant, worry can be peeled off etc. poisoning occurs due to the wax layer on this crops surface.Therefore, even the surfactant component of low concentration also can be brought into play the problem that its serviceability is the pesticide combination composition formula.The present invention is based on following discovery: by with special ratios, mixing and use specific two kinds of surfactants, even the concentration of surfactant component is low, also confirm the effect that maintains of pathogen control efficiency for the agricultural or horticultural bactericide as the record of above-mentioned (A) composition.About spraying application concentration, microbicide compositions of the present invention can show effect under the concentration concentration that surfactant concentration is low in than existing composition pesticide, can eliminate the worry that poisoning occurs, and is preferred in this regard.Therefore, using (B): the combination of the ratio of components of (C)=1:1～4 should (B) and (C) composition and the mixed surfactant composition that obtains to strengthen, recover and maintain with composition as good agricultural or horticultural bactericide effect be useful.In addition, these (B) and (C) surfactant of composition be all low price, hold facile surfactant, be favourable aspect this cost in the agriculture and garden control.
These as above-mentioned (B) of surfactant component and (C) content of composition when mix using than (B): the use scope of (C)=1:1～4 in.That is, preferably above-mentioned (C) composition is used at least equivalent with respect to above-mentioned (B) composition or more than equivalent.More preferably (B): (C)=1:1.5～3, more preferably (B): (C)=1:1.8～2.5.
(B) used herein dialkyl sulfosuccinates is identical with dialkyl sulfosuccinates contained in above-mentioned agricultural or horticultural bactericide composition.Wherein, preferred high two (C8～C12 branched alkyl) sodium sulfosuccinate of wettability, wherein more preferably two (2-ethylhexyl) sodium sulfosuccinate.In addition, (C) implication of polyethylene glycol oxide C11～C15 alkyl ether is also identical with the implication of polyethylene glycol oxide C11 contained in above-mentioned agricultural or horticultural bactericide composition～C15 alkyl ether.The alkyl chain of C12～C14 particularly preferably, the mixture of this polyethylene oxide alkyl ethers of expectation based on C12～C14 alkyl chain.Preferably use the polyethylene glycol oxide degree of polymerization preferably more than 7, more preferably 7～12 polyethylene oxide alkyl ethers.
In the present invention, other surfactants that illustrate below can mixing arbitrarily.Such as enumerating: nonionic surface active agent such as the nonionic ionic surfactants such as polyethylene glycol oxide polyoxypropylene copolymer, polyethylene glycol oxide alkyl aryl ether, polyethylene glycol oxide styryl phenyl ether, polyethylene glycol oxide phenyl ether polymer, polyethylene glycol oxide alkylidene aryl phenyl ether, polyethylene glycol oxide polypropylene oxide block polymer, polyethylene glycol oxide styryl phenyl ether sulphate, lignosulfonates, alkylaryl sulfonates, alkylnaphthalene sulfonates.These other surfactants are preferably used in the scope that is generally the 20 quality % of about 0 quality %～approximately with respect to above-mentioned (B) and total amount (C).In the present invention, also, sometimes preferably also with these other surfactants, now, usually in above-mentioned scope, add and get final product, more preferably also use in the scope of 1～10 quality %.
In addition, in agricultural or horticultural bactericide composition of the present invention, except other above-mentioned surfactants, also can contain any composition (additive) that inorganic carrier, organic solvent, preservative, mould inhibitor, polysaccharose, water soluble polymer etc. can be applicable to pesticidal preparations.The physical property that these any compositions (additive) comprise to improve agricultural or horticultural bactericide composition of the present invention is purpose and the composition that actively adds.Perhaps, when applying commercially available agricultural or horticultural bactericide preparation as above-mentioned agricultural or horticultural bactericide (A), preparation base material, the carrier that said preparation is contained and the surfactant contained as additive, solvent, water soluble polymer etc. are also contained in this any composition.
In addition, in agricultural or horticultural bactericide composition of the present invention, as long as do not hinder the effect that maintains as the control efficiency of the bactericide of above-mentioned (A) composition, can use the preparation that contains following pesticide active ingredient with.For example, can use the preparation of record in " distribution on October 19th, 2006,2006 of Japanese plant of civic organization epidemic prevention association's agricultural chemicals guide ".They can use separately, also can be used in combination.Usually, use them in the category of agriculture chemical registration.
As above-mentioned can use with, active ingredient pesticidal preparations, can enumerate: the bactericide active ingredient outside insecticide active ingredient, above-mentioned (A) composition etc.
For example, for insecticide active ingredient, can enumerate: acrinathrin, acequinocyl, Acetamiprid, orthen, Amitraz, alanycarb, allethrin,
azoles phosphorus, Imidacloprid, indoxacarb MP, esfenvalerate, ethiofencarb, second worm nitrile, disulfoton, second mite azoles, ether chrysanthemum ester, emamection benaoate, levamisole hydrochloride, oxamyl, cadusafos, the cartap hydrochloride, carbosulfan, clothianidin, clofentezine, ring worm hydrazides, poison the slave girl with poison, chlorfenapyr, UC 62644, cycloprothrin, MTI-446, cyfloxylate, Rogor, pleocidin, basudin, thiacloprid, Diacloden, thiodicarb, the thiocyclam oxalate, the worm hydrazides, tebufenpyrad, tefluthrin, the fluorobenzene urea, tralomethrin, Tolfenpyrad, the fluorine uride, halfenprox, Bifenazate, Biphenthrin, pymetrozine, pyraclofos, pyridaphethione, pyridaben, pyridalyl, Nylar, pyrimidifen, pirimiphos-methyl, pyrethrins, ethiprole, fenisobromolate, fenothiocarb, fluacrypyrim, flucythrinate, taufluvalinate, flufenoxuron, Kayaphos, Profenofos, Hexythiazox, permethrin, bensultap, 5a,6,9,9a-hexahydro-6,9-methano-2,4, Benfuracard micro, beauveria bassiana, muscardine, Phosalone, mineral oil, malathion, the fenthion sulfoxide, Methomyl, methoxyfenozide, lufenuron, BPMC, BT (bacillus thuringiensis), methidathion, sumithion, Mobucin, fenthion, NAC etc.These active ingredients are suitably selected according to crop, insect.
In addition, (A) bactericide outside composition is also as long as do not hinder as the enhancing of the control efficiency of the specific bactericide of (A) of the present invention composition or maintain and can use arbitrarily.Concrete example below is shown, but is not limited to this.
Can enumerate: the iprodione of the tricyclazole of the EDDP of the bordeaux mixture of inorganic compound, lime sulfur etc., organic phosphates, IBP etc., melanin biosynthesis inhibition class, pyroquilon, Rabcide etc., dicarboximide class or procymidone etc., sour amide-type
the Fluoxastrobin of frost spirit, flutolanil, metalaxyl or mebenil etc., methoxy acrylic, kresoxim-methyl, SSF 126 or
cycloheximide triazole etc., synthetic antibacterial agents
the hay bacillus of the kasugarnycin of quinoline acid or tecloftalam etc., antibiotics, jinggangmeisu or polyoxin etc., biopesticide, agrobacterium radiobacter, dark green trichoderma or avirulence carrot soft rot Erwinia etc.
Microbicide compositions of the present invention as previously mentioned can by by (A) composition, (B) composition and (C) composition with aforementioned proportion, mix to manufacture.More specifically, can prepare by following manufacture method.Certainly can suitably use similar machinery, operation, be not limited to this.
The weighing choosing freely contains the bactericide (A1) of benzimidazole ring respectively, the bactericide that contains the guanidine structure (A2), the bactericide that contains organic sulfur (A3), the bactericide that contains anilino-pyrimidine (A4), the bactericide that contains triazole ring (A5), more than one agricultural or horticultural bactericides (A) in the group that the bactericide that contains organochlorine (A6) and the bactericide (A7) that contains organic copper form, dialkyl sulfosuccinates (B), polyethylene glycol oxide C11～C15 alkyl ether (C) and any additive as required, with (A): (B): the proportion of (C)=1～70:1:1～4 adds, and mixed under normal temperature or the condition of heating, obtain thus microbicide compositions of the present invention.
Agricultural or horticultural bactericide (A) can directly be used above-mentioned bactericidal active ingredient compound.In addition, also can directly use the agricultural or horticultural bactericide preparation that contains this agricultural or horticultural bactericide (A).Now, take the mode that the amount of contained (A) composition is above-mentioned scope in said preparation uses this fungicide preparation.
Each composition of above-mentioned (A) to (C) can add mixing simultaneously, also can add successively mixing, can also only mix in advance a part of composition, and then mix all the other compositions.For example, as above-mentioned a kind of last method, can mix using the alkyl sulfo succinate as anion surfactant (B) with as the polyethylene glycol oxide C11 of non-ionic surface active agent～C15 alkyl ether (C), previously prepared mixed surfactant composition, add wherein more above-mentioned agricultural or horticultural bactericide (A) and any composition (additive) as required, be prepared.Now, while preparing the mixed surfactant composition, also can be as required part or all of any composition be added together and make the mixed surfactant composition that contains any composition.
As preferred microbicide compositions of the present invention, can enumerate following composition.
(I) microbicide compositions of the present invention, wherein, the bactericide that contains the benzimidazole ring (A1), the bactericide (A2) that contains the guanidine structure, the bactericide (A3) that contains organic sulfur, the bactericide (A4) that contains anilino-pyrimidine, the bactericide (A5) that contains triazole ring, the bactericide (A6) that contains organochlorine and the bactericide (A7) that contains organic copper are respectively the bactericide of following record
(A1): the mould prestige of second, thiophanate-methyl or benomyl,
(A2): iminoctadine triacetate or iminoctadine alkylbenzenesulfonate,
(A3): tmtd, Polycarbamate, mancozeb or maneb,
(A4): cyprodinil or mepanipyrim,
(A5): Difenoconazole, Cyproconazole, Tebuconazole or penconazole,
(A6): TPN or captan,
(A7): copper 8-quinolinolate.
(II) above-mentioned (I) described microbicide compositions, wherein, dialkyl sulfosuccinates (B) is (B) with the ratio of polyethylene glycol oxide C11～C15 alkyl ether (C): (C)=1:1.5～3.
(III) above-mentioned (II) described microbicide compositions wherein, is (B) (B) with ratio (C): (C)=1:1.8～2.5.
(IV) the described microbicide compositions of any one in above-mentioned (I)～(III), wherein, (A1)～(A7) ratio with respect to (B) 1 part is respectively following ratio,
(A1): 1～40 part, (A2): 1～10 part, (A3): 10～70 parts, (A4): 1～20 part, (A5): 1～20 part, (A6): 1～30 part, (A7): 10～40 parts.
(V) described microbicide compositions of any one in above-mentioned (I)～(IV), wherein, (A) ratio with respect to 1 part of (B) and total (C) is approximately 0.4 part～approximately 35 parts.
(VI) described microbicide compositions of any one in above-mentioned (I)～(V), wherein, (A1)～(A7) ratio with respect to 1 part of (B) and total (C) is respectively following ratio,
(A1): 1～18 part, (A2): 0.4～6 part, (A3): 5～35 parts, (A4): 0.6～7 part, (A5): 0.5～3 part, and both add up to (A6) and (A7) time: 4～30 parts.
(VII) the described microbicide compositions of any one in above-mentioned (I)～(VI), wherein, (B) and the ratio shared with respect to the total amount of microbicide compositions of the present invention of total (C) be approximately 4%～approximately 40%, (A1) the shared ratio of composition is approximately 40%～approximately 90%, remainder be (A1), (B) and (C) outside the agricultural chemicals additive.
(VIII) above-mentioned (VII) described microbicide compositions, wherein, the shared ratio of total (B) and (C) is approximately 6%～approximately 30%, (A1) the shared ratio of composition is 50～80%.
(IX) the described microbicide compositions of any one in above-mentioned (I)～(VIII), wherein, (A1), (B) and total amount (C) be 60%～100% with respect to the ratio of the total amount of microbicide compositions of the present invention, remainder be (A1), (B) and (C) outside the agricultural chemicals additive.
(X) the described microbicide compositions of any one in above-mentioned (I)～(IX), wherein, (B) be two (2-ethylhexyl) sulfosuccinic acid alkali metal salt, the polyethylene glycol oxide C12 that is (C) 7～12 for the degree of polymerization～C14 alkyl ether.
Microbicide compositions of the present invention can dilute with water, forms flushing liquor and uses.
The present invention also comprises this flushing liquor.This flushing liquor usually can by with light water by microbicide compositions of the present invention be diluted with water to approximately 500 times～approximately 3000 times usually, preferably approximately 700 times～approximately 2000 times, more preferably from about 700 times～approximately 1500 times obtain.In addition, also can by each composition (A) by microbicide compositions of the present invention, (B) and (C) and any additive as required so that (A), (B) and ratio (C) mode that is aforementioned proportion adds to respectively in any order in the water of ormal weight and mixes and prepare.In addition, also can be by previously prepared mixed surfactant composition of the present invention and (A) composition and any additive as required be take mode that (A), (B) and ratio (C) be aforementioned proportion and added to respectively in the water of ormal weight and mix.More specifically, above-mentioned microbicide compositions of the present invention is put in the tank that the regulation water gaging is housed, carried out normal temperature or the mixing of heating, obtain thus the flushing liquor of the agricultural or horticultural bactericide composition of expectation.In addition, can also be using the alkyl sulfo succinate as anionic surfactant (B) with as the polyethylene glycol oxide C11 of nonionic surface active agent～C15 alkyl ether (C), and any additive as required is pre-mixed, first prepare mixed surfactant composition of the present invention, after putting in the tank that the regulation water gaging is housed by above-mentioned agricultural or horticultural bactericide (A), the mixed surfactant composition of the present invention first prepared is added in this tank, carry out normal temperature or the mixing of heating, the flushing liquor of the agricultural or horticultural bactericide composition that preparation is expected thus.Perhaps, can also in the tank that the regulation water gaging is housed, add respectively or simultaneously above-mentioned (A) to (C) composition and any composition, carry out normal temperature or the mixing of heating, thus the flushing liquor of the agricultural or horticultural bactericide composition of preparation expectation.
In preparation during above-mentioned flushing liquor, determine each constituent concentration of water-spraying amount and flushing liquor according to the kind of crop, weather, soil, the vegetative stage of crop, the production of object mushroom etc.The normally every 10a (1000m of the sprinkling liquid measure of the flushing liquor of microbicide compositions of the present invention
2) to spray farm be 3～1000L/10a (1000m
2).
Concentration for above-mentioned in this flushing liquor (A) composition to (C) composition, as long as the ratio that ratio (A)～(C) separately is afore mentioned rules can be regulated with any concentration.In above-mentioned flushing liquor (B) composition and (C) composition preferred concentration separately be that dialkyl sulfosuccinates (B) is the scope that 10～200ppm, polyethylene glycol oxide C11～C15 alkyl ether (C) is 10～800ppm.Spray this agricultural or horticultural bactericide according to this formula, can strengthen or maintain thus the bactericidal effect of this bactericide.
For the humidification of stablizing the sterilization control efficiency or maintain effect, preferably in following ranges, regulate each constituent concentration of the flushing liquor of this agricultural or horticultural bactericide composition.Below, each constituent concentration in flushing liquor is the concentration with respect to the total amount of flushing liquor.
Agricultural or horticultural bactericide (A): 10～3000ppm,
Dialkyl sulfosuccinates (B): 10～200ppm,
Polyethylene glycol oxide C11～C15 alkyl ether (C): 10～800ppm.
More preferably (A) composition: 50～2000ppm, (B) composition: 10～100ppm and (C) scope of composition: 10～400ppm.The scope of (A) composition: 50～2000ppm, (B) composition: 10～100ppm, (C) composition: 30～300ppm more preferably.
In addition, (B) composition in flushing liquor and (C) the total concentration of composition (with respect to the concentration of flushing liquor total amount) be generally about 20ppm～about 400ppm, be preferably about 40ppm～about 350ppm, more preferably about 40ppm～about 300ppm, more preferably about 40ppm～about 200ppm.According to circumstances, 40ppm～about 150ppm most preferably from about.(B) composition in this flushing liquor and (C) the total concentration of composition is all basic identical while being any one in (A1)～(A7) at following bactericide (A).But, in the situation that the bactericide that contains triazole ring (A5), most preferably from about 40ppm～about 300ppm.
Flushing liquor (hereinafter referred to as flushing liquor of the present invention) for microbicide compositions of the present invention, when this bactericide (A) is benzimidazole germicide (A1), each constituent concentration in flushing liquor (with respect to the concentration of flushing liquor total amount: lower with) is following ranges preferably.
Benzimidazole germicide (A1): 50～1000ppm,
Above-mentioned dialkyl sulfosuccinates (B): 10～200ppm,
Above-mentioned polyethylene glycol oxide C11～C15 alkyl ether (C): 10～800ppm.
As preferred scope, can list following ranges.
(A1) composition: 50～1000ppm, according to circumstances 500～1000ppm,
(B) composition: 10～100ppm,
(C) composition: 10～400ppm.
More preferably (A1) composition is that 50～1000ppm, (B) composition are 10～100ppm and scope that (C) composition is 30～300ppm.
For flushing liquor of the present invention, when this bactericide (A) is guanidine series bactericidal agent (A2), each constituent concentration in flushing liquor (with respect to the concentration of flushing liquor total amount) is following ranges preferably.
Guanidine series bactericidal agent (A2): 50～500ppm,
Dialkyl sulfosuccinates (B): 10～200ppm,
Polyethylene glycol oxide C11～C15 alkyl ether (C): 10～800ppm.
More preferably above-mentioned (A2) is that 100～400ppm, (B) composition are the scope that 10～100ppm, (C) composition are 10～400ppm.Further preferably (A2) composition is that 100～400ppm, (B) composition are the scope that 10～100ppm, (C) composition are 30～300ppm.
For flushing liquor of the present invention, when this bactericide (A) is organic sulfur series bactericidal agent (A3), each constituent concentration in flushing liquor (with respect to the concentration of flushing liquor total amount) is following ranges preferably.
Organic sulfur series bactericidal agent (A3): 500～3000ppm,
Dialkyl sulfosuccinates (B): 10～200ppm,
Polyethylene glycol oxide C11～C15 alkyl ether (C): 10～800ppm.
More preferably (A3) is that 800～2000ppm, (B) composition are the scope that 10～100ppm, (C) composition are 10～400ppm.Further preferably (A3) composition is that 800～2000ppm, (B) composition are the scope that 10～100ppm, (C) composition are 30～300ppm.
For flushing liquor of the present invention, when this bactericide (A) is anilino-pyrimidine series bactericidal agent (A4), the preferred following ranges of each constituent concentration in flushing liquor.
Anilino-pyrimidine series bactericidal agent (A4): 50～500ppm,
Dialkyl sulfosuccinates (B): 10～200ppm,
Polyethylene glycol oxide C11～C15 alkyl ether (C): 10～800ppm.
More preferably (A4) composition: 100～400ppm, (B) composition: 10～100ppm and (C) scope of composition: 10～400ppm.Further preferably (A4) composition: 100～400ppm, (B) composition: 10～100ppm and (C) scope of composition: 30～300ppm.
For flushing liquor of the present invention, when this bactericide (A) is triazole bactericidal agent (A5), the preferred following ranges of each constituent concentration in flushing liquor.
Triazole bactericidal agent (A5): 50～500ppm,
Dialkyl sulfosuccinates (B): 10～200ppm,
Polyethylene glycol oxide C11～C15 alkyl ether (C): 10～800ppm.
More preferably above-mentioned (A5): 100～400ppm, (B) composition: 10～100ppm and (C) scope of composition: 10～400ppm.Further preferably (A5) composition: 100～400ppm, (B) composition: 10～100ppm and (C) scope of composition: 30～300ppm.
For flushing liquor of the present invention, when this bactericide (A) is organochlorine series bactericidal agent (A6), the preferred following ranges of each constituent concentration in flushing liquor.
Organochlorine series bactericidal agent (A6): 100～1000ppm,
Dialkyl sulfosuccinates (B): 10～200ppm,
Polyethylene glycol oxide C11～C15 alkyl ether (C): 10～800ppm.
More preferably above-mentioned (A6): 200～800ppm, (B) composition: 10～100ppm and (C) scope of composition: 10～400ppm.Further preferably (A6) composition: 200～800ppm, (B) composition: 10～100ppm and (C) scope of composition: 30～300ppm.
For flushing liquor of the present invention, when this bactericide (A) is organic copper series bactericidal agent (A7), the preferred following ranges of each constituent concentration in flushing liquor.
Organic copper series bactericidal agent (A7): 500～3000ppm,
Dialkyl sulfosuccinates (B): 10～200ppm,
Polyethylene glycol oxide C11～C15 alkyl ether (C): 10～800ppm.
More preferably (A7) composition: 800～2000ppm, (B) composition: 10～100ppm and (C) scope of composition: 10～400ppm.Further preferably (A7) composition: 50～2000ppm, (B) composition: 10～100ppm and (C) scope of composition: 30～300ppm.
Flushing liquor of the present invention can directly be sprayed by the spray method that uses common spraying machine.As spray method, can enumerate: power sprayer sprinkling, spray boom atomizers spray, high-speed sprayer sprinkling and depopulated helicopter sprinkling etc.
Microbicide compositions of the present invention and flushing liquor of the present invention can be applied to various crops.Such as can be for fruit tree kinds such as the greengroceries such as the cereal such as rice, wheat, Chinese cabbage, potato, soybean, cucumber, eggplant, tea, apple, strawberry, oranges and tangerines etc.
In addition, microbicide compositions of the present invention and flushing liquor of the present invention can be tackled the spot defoliation, ring spot, anthracnose, diplostomiasis, rust, black spot, late blight, downy mildew of purple spot, seasonal febrile diseases, stalk break, anthracnose, downy mildew, white powder mildew, gray mold, the fruit tree kind of the head blight of the pathogen such as grain class of crops, red rust disease, snow mold, rice blast, banded sclerotial blight, greengrocery for these agriculture and gardens etc.Particularly effective to the pathogen of control Reduced susceptibility.
It should be noted that, according to the active ingredient compound, the suitableeest crop or target pathogen etc. is known, therefore preferably corresponding use.
Embodiment
Next, by embodiment, the present invention is described in more detail, but the invention is not restricted to this.
Embodiment 1
Add ニ ュ ー カ Le ゲ Application EP-70G (trade name, Zhu Ben's Oil Corporation manufactures, containing two (2-ethylhexyl) sodium sulfosuccinate 70%) 10.7 mass parts and ペ グ ノ ー Le in the 500mL beaker
rTMsT-9 (trade name, Dong Bang KCC manufactures, containing polyethylene oxide alkyl ethers 100%) 16.7 mass parts, ゲ ッ タ ー
rTMaqua (trade name, Tso Tat Co., Ltd., Japan manufactures, the mould prestige 12.5% of second, thiophanate-methyl 52.5%) 100 mass parts (mould prestige 12.5 mass parts of second, thiophanate-methyl 52.5 mass parts), and mixed, obtain the agricultural or horticultural bactericide composition.
Embodiment 2
Add ニ ュ ー カ Le ゲ Application EP-70G (trade name, Zhu Ben's Oil Corporation manufactures, containing two (2-ethylhexyl) sodium sulfosuccinate 70%) 3.2 mass parts and ペ グ ノ ー Le in the 500mL beaker
rTMsT-9 (trade name, Dong Bang KCC manufactures, containing polyethylene oxide alkyl ethers 100%) 5.0 mass parts, ゲ ッ タ ー
rTMaqua (trade name, Tso Tat Co., Ltd., Japan manufactures, the mould prestige 12.5% of second, thiophanate-methyl 52.5%) 100 mass parts (mould prestige 12.5 mass parts of second, thiophanate-methyl 52.5 mass parts), and mixed, obtain the agricultural or horticultural bactericide composition.
Embodiment 3
Add ニ ュ ー カ Le ゲ Application EP-70G (trade name, Zhu Ben's Oil Corporation manufactures, containing two (2-ethylhexyl) sodium sulfosuccinate 70%) 10.7 mass parts and ペ グ ノ ー Le in the 500mL beaker
rTMsT-9 (trade name, Dong Bang KCC manufactures, containing polyethylene oxide alkyl ethers 100%) 16.7 mass parts, ベ Le Network ー ト
rTMaqua (trade name, Mitsui Chemicals ア グ ロ Co., Ltd. manufactures, iminoctadine alkylbenzenesulfonate 40.0%) 50 mass parts (iminoctadine alkylbenzenesulfonate 20 mass parts), and mixed, the agricultural or horticultural bactericide composition obtained.
Embodiment 4
Add ニ ュ ー カ Le ゲ Application EP-70G (trade name, Zhu Ben's Oil Corporation manufactures, containing two (2-ethylhexyl) sodium sulfosuccinate 70%) 3.2 mass parts and ペ グ ノ ー Le in the 500mL beaker
rTMsT-9 (trade name, Dong Bang KCC manufactures, containing polyethylene oxide alkyl ethers 100%) 5.0 mass parts, ベ Le Network ー ト
rTMaqua (trade name, Mitsui Chemicals ア グ ロ Co., Ltd. manufactures, iminoctadine alkylbenzenesulfonate 40.0%) 50 mass parts (iminoctadine alkylbenzenesulfonate 20 mass parts), and mixed, the agricultural or horticultural bactericide composition obtained.
Embodiment 5
Add ニ ュ ー カ Le ゲ Application EP-70G (trade name, Zhu Ben's Oil Corporation manufactures, containing two (2-ethylhexyl) sodium sulfosuccinate 70%) 10.7 mass parts and ペ グ ノ ー Le in the 500mL beaker
rTMsT-9 (trade name, Dong Bang KCC manufactures, containing polyethylene oxide alkyl ethers 100%) 16.7 mass parts, Off Le ピ カ
rTMoff ロ ア Block Le (trade name, Tso Tat Co., Ltd., Japan manufactures, mepanipyrim 40.0%) 67 mass parts (mepanipyrim 27 mass parts), and mixed, the agricultural or horticultural bactericide composition obtained.
Embodiment 6
Add ニ ュ ー カ Le ゲ Application EP-70G (trade name, Zhu Ben's Oil Corporation manufactures, containing two (2-ethylhexyl) sodium sulfosuccinate 70%) 3.2 mass parts and ペ グ ノ ー Le in the 500mL beaker
rTMsT-9 (trade name, Dong Bang KCC manufactures, containing polyethylene oxide alkyl ethers 100%) 5.0 mass parts, Off Le ピ カ
rTMoff ロ ア Block Le (trade name, Tso Tat Co., Ltd., Japan manufactures, mepanipyrim 40.0%) 67 mass parts (mepanipyrim 27 mass parts), and mixed, the agricultural or horticultural bactericide composition obtained.
Embodiment 7
Add ニ ュ ー カ Le ゲ Application EP-70G (trade name, Zhu Ben's Oil Corporation manufactures, containing two (2-ethylhexyl) sodium sulfosuccinate 70%) 3.2 mass parts and ペ グ ノ ー Le in the 500mL beaker
rTMsT-9 (trade name, Dong Bang KCC manufactures, containing polyethylene oxide alkyl ethers 100%) 5.0 mass parts, ジ マ Application ダ イ セ Application
rTMaqua (trade name, Tso Tat Co., Ltd., Japan manufactures, mancozeb 75.0%) 167 mass parts (mancozeb 125 mass parts), and mixed, the agricultural or horticultural bactericide composition obtained.
Embodiment 8
Add ニ ュ ー カ Le ゲ Application EP-70G (trade name, Zhu Ben's Oil Corporation manufactures, containing two (2-ethylhexyl) sodium sulfosuccinate 70%) 10.7 mass parts and ペ グ ノ ー Le in the 500mL beaker
rTMsT-9 (trade name, Dong Bang KCC manufactures, containing polyethylene oxide alkyl ethers 100%) 16.7 mass parts, シ Le バ キ ュ ア
rTMaqua (trade name, Ishihara Sangyo Kaisha, Ltd. manufactures, Tebuconazole 40.0%) 67 mass parts (Tebuconazole 27 mass parts), and mixed, the agricultural or horticultural bactericide composition obtained.
Embodiment 9
Add ニ ュ ー カ Le ゲ Application EP-70G (trade name, Zhu Ben's Oil Corporation manufactures, containing two (2-ethylhexyl) sodium sulfosuccinate 70%) 3.2 mass parts and ペ グ ノ ー Le in the 500mL beaker
rTMsT-9 (trade name, Dong Bang KCC manufactures, containing polyethylene oxide alkyl ethers 100%) 5.0 mass parts, オ キ シ ラ Application
rTMaqua (trade name, Nihon Nihyaku Co., Ltd manufactures, captan 20.0%, copper 8-quinolinolate 30.0%) 200 mass parts (captan 40 mass parts, copper 8-quinolinolate 60 mass parts), and mixed, obtain the agricultural or horticultural bactericide composition.
Comparative example 1
Use ゲ ッ タ ー
rTMaqua (trade name, Tso Tat Co., Ltd., Japan manufactures, the mould prestige 12.5% of second, thiophanate-methyl 52.5%).
Comparative example 2
Use ベ ル ク ー ト
rTMaqua (trade name, Mitsui Chemicals ア グ ロ Co., Ltd. manufactures, iminoctadine alkylbenzenesulfonate 40.0%).
Comparative example 3
Use Off Le ピ カ
rTMoff ロ ア Block Le (trade name, Tso Tat Co., Ltd., Japan manufactures, mepanipyrim 40.0%).
Comparative example 4
Use ジ マ Application ダ イ セ Application
rTMaqua (trade name, Tso Tat Co., Ltd., Japan manufactures, mancozeb 75.0%).
Comparative example 5
Add グ ラ ミ Application S in the 500mL beaker
rTM(trade name, Mitsui Chemicals ア グ ロ company manufactures, polyoxyethylene fatty acid esters 5.0%, polyoxyethylene nonylplenyl ether 15.0%, poly-naphthalene methanesulfonic sodium 4.0%) 33 mass parts, シ Le バ キ ュ ア
rTMaqua (trade name, Ishihara Sangyo Kaisha, Ltd. manufactures, Tebuconazole 40.0%) 67 mass parts (Tebuconazole 27 mass parts), and mixed, the agricultural or horticultural bactericide composition obtained.
Comparative example 6
Add ア PVC オ Application E (trade name, ア PVC オ ン コ ー ポ レ ー シ ョ Application Co., Ltd. manufactures, containing paraffin 24%) 100 mass parts, オ キ シ ラ Application in the 500mL beaker
rTMaqua (trade name, Nihon Nihyaku Co., Ltd manufactures, captan 20.0%, copper 8-quinolinolate 30.0%) 200 mass parts (captan 40 mass parts, copper 8-quinolinolate 60 mass parts), and mixed, obtain the agricultural or horticultural bactericide composition.
Comparative example 7
Add ア PVC オ Application E (trade name, ア PVC オ ン コ ー ポ レ ー シ ョ Application Co., Ltd. manufactures, containing paraffin 24%) 50 mass parts, オ キ シ ラ Application as adhesive agent in the 500mL beaker
rTMaqua (trade name, Nihon Nihyaku Co., Ltd manufactures, captan 20.0%, copper 8-quinolinolate 30.0%) 200 mass parts (captan 40 mass parts, copper 8-quinolinolate 60 mass parts), and mixed, obtain the agricultural or horticultural bactericide composition.
Comparative example 8
Use オ キ シ ラ Application in the 500mL beaker
rTMaqua (trade name, Nihon Nihyaku Co., Ltd manufactures, captan 20.0%, copper 8-quinolinolate 30.0%).
Test example 1: the control test of soybean purple speck
For above-described embodiment 1 and 2 and comparative example 1 in the agricultural or horticultural bactericide composition that obtains, implement the test of soybean purple speck by following test method.Result is summarized in table 1.
(1) for studying thing and spraying condition
Crop: soybean (after after planting, 70 days)
District's area processed: 1st district: 10m
2, 3 times repeatedly
Water-spraying amount: be equivalent to 200L/10a
Spray method: the composition 100g of the composition 108.2g of the composition 127.4g of embodiment 1, embodiment 2 and comparative example 1 is respectively charged in the tank of 100L, adds water to the scale of 100L, fully mix, thereby prepare flushing liquor.Take out the amount that will spray from tank, the backpack power sprayer of packing into, sprayed.
Evaluation method: leaf fall period 30 strains of respectively sampling, after natural seasoning, shell, the grain number of investigating ripe grain and suffering from purple spot.In addition, the computational methods that control is worth are as follows.
Control value={ ((the morbidity grain rate of non-processor)-(the morbidity grain rate of embodiment or comparative example))/(the morbidity grain rate of non-processor) } * 100
The result of table 1 test example 1
According to table 1, embodiment 1 and 2 compares with comparative example 1, and control is worth high, demonstrates good purple spot inhibition.But it is lower result on the whole that control is worth.This result has implied: except the medicament of this test sprays, missed the experimental condition that suitable sprinkling period, bactericide effect is difficult to give full play to, the target pathogenic fungi also reduces very severely to the susceptibility of this bactericide.Due to such test background, the control in comparative example is worth very low, is 8.On the other hand, for the agricultural or horticultural bactericide composition of embodiment 1 and 2, demonstrating under the same conditions control value is probably 35～42 such control efficiency, and composition of the present invention makes the control efficiency of benzimidazole germicide maintain highlyer.
Test example 2: the control test of soybean purple speck
For above-described embodiment 3 and 4 and comparative example 2 in the agricultural or horticultural bactericide composition that obtains, implement the test of soybean purple speck by following test method.Result is summarized in table 2.
(1) for studying thing and spraying condition
Crop: soybean (after after planting, 70 days)
District's area processed: 1st district: 4m
2, 3 times repeatedly
Water-spraying amount: be equivalent to 250L/10a
Spray method: by the composition 77.4g of embodiment 3, the composition 58.2g of embodiment 4 and the composition 50g of comparative example 2 are respectively charged in the tank of 100L, add water to the scale of 100L, fully mix, thereby prepare flushing liquor.Take out the amount that will spray from tank, the backpack power sprayer of packing into, sprayed.
Evaluation method: leaf fall period 20 strains of respectively sampling, after natural seasoning, shell, the grain number of investigating ripe grain and suffering from purple spot.In addition, the computational methods that control is worth are as follows.
Control value=(((the morbidity grain rate of non-processor)-(the morbidity grain rate of embodiment or comparative example))/(the morbidity grain rate of non-processor)) * 100
The result of table 2 test example 2
According to table 2, embodiment 3 and 4 compares with comparative example 2, and control is worth high, demonstrates good purple spot inhibition.In this test, implied: the control efficiency of the comparative example 2 generally used is very low, is therefore the pathogen after the susceptibility of this bactericide significantly reduces.For such Test condition, embodiment 3 and 4 agricultural or horticultural bactericide compositions display go out control to be worth constant are 40～50 control efficiency.Therefore, microbicide compositions of the present invention makes the control efficiency of guanidine series bactericidal agent maintain highlyer.
Test example 3: the control test of grey mould fruit rot of strawberry
For above-described embodiment 5 and 6 and comparative example 3 in the agricultural or horticultural bactericide composition that obtains, implement the test of grey mould fruit rot of strawberry by following test method.Result is summarized in table 3.
(1) for studying thing and spraying condition
Crop: strawberry (after field planting, after 5 months)
District's area processed: 1st district: 3.9m
2, 3 times repeatedly
Water-spraying amount: be equivalent to 260L/10a
Spray method: the composition 67g of the composition 75.2g of the composition 94.4g of embodiment 5, embodiment 6 and comparative example 3 is respectively charged in the tank of 100L, adds water to the scale of 100L, fully mix, thereby prepare flushing liquor.Take out the amount that will spray from tank, sprayed with the battery power sprayer.
Evaluation method: the fruit number that 26 strains of Dui Ge district are investigated the morbidity fruit and entered harvest time.
It should be noted that, the computational methods that control is worth are as follows.
Be worth=(((diseased fruit rate of non-processor)-(diseased fruit rate of embodiment or comparative example))/(diseased fruit rate of non-processor)) * 100 of control
The result of table 3 test example 3
According to table 3, embodiment 5 and 6 compares with comparative example 3, and control is worth high, demonstrates the inhibition of good gray mold.In this test, use the comparative example 3 of commercially available fungicide preparation also to show the so better control efficiency of control value 87, therefore can confirm, pathogen is few to the reduction of the insecticide sensitivity of the medicament for after examination.But it is slightly low that the preferred control of control value 87 ratio is worth (more than 90), so implied the slight reduction of susceptibility.On the other hand, embodiment 5 and 6 agricultural or horticultural bactericide composition have all obtained being worth 90 control higher than control and have been worth, and show to make the control efficiency of anilino-pyrimidine series bactericidal agent to maintain highlyer.
Test example 4: the control test of potato seasonal febrile diseases
For the agricultural or horticultural bactericide composition obtained in the above embodiments 7 and comparative example 4, by following test method, implement the test of potato seasonal febrile diseases.Result is summarized in table 4.
(1) for studying thing and spraying condition
Crop: potato (after sowing 2 months)
District's area processed: 1st district: 11.2m
2, 2 times repeatedly
Water-spraying amount: be equivalent to 200L/10a
Spray method: the composition 167g of the composition 175.2g of embodiment 7 and comparative example 4 is respectively charged in the tank of 100L, adds water to the scale of 100L, fully mix, thereby prepare flushing liquor.Take out the amount that will spray from tank, use the battery power sprayer to be sprayed.
Evaluation method: morbidity strain number is investigated in 20 strains of Dui Ge district.It should be noted that, the computational methods that control is worth are as follows.
Control value=(((occurring degree of non-processor)-(occurring degree of embodiment or comparative example))/(occurring degree of non-processor)) * 100
The result of table 4 test example 4
According to table 4, embodiment 7 compares with comparative example 4, and control is worth high, demonstrates the inhibition of good seasonal febrile diseases.The agricultural or horticultural bactericide composition that shows embodiment 7 makes the control efficiency of organic sulfur series bactericidal agent maintain highlyer.
Test example 5: the control test of wheat red rust disease
For the agricultural or horticultural bactericide composition obtained in above-described embodiment 8 and comparative example 5, by following test method, implement the test of wheat red rust disease.Result is summarized in table 5.
(1) for studying thing and spraying condition
Crop: wheat (while blooming)
District's area processed: 1st district: 13.5m
2, 3 times repeatedly
Water-spraying amount: be equivalent to 100L/10a
Spray method: the composition 100g of the composition 94.4g of embodiment 8 and comparative example 5 is respectively charged in the tank of 100L, adds water to the scale of 100L, fully mix, thereby prepare flushing liquor.Take out the amount that will spray from tank, use the battery power sprayer to be sprayed.
Evaluation method: 1 district's 100 fringes are investigated to morbidity small ear rate and red mould grain rate.
It should be noted that, the computational methods that control is worth are as follows.
Be worth=(((the red mould grain rate of non-processor)-(the red mould grain rate of embodiment or comparative example))/(the red mould grain rate of non-processor)) * 100 of control
The result of table 5 test example 5
According to table 5, embodiment 8 compares with comparative example 5, and control is worth high, demonstrates the inhibition of good head blight.In this test, insufficient as the control efficiency of the comparative example 5 of general bactericide, implied that the head blight pathogen has the tendency of reduction to the insecticide sensitivity of this bactericide.Implied: under such Test condition, the agricultural or horticultural bactericide composition of embodiment 8 makes the control efficiency of triazole bactericidal agent maintain highlyer.
Test example 6: the control test of alternaria leaf spot of apple
For the agricultural or horticultural bactericide composition obtained in the above embodiments 9 and comparative example 6,7,8, by following test method, implement the test of alternaria leaf spot of apple.Result is summarized in table 6.
(1) for studying thing and spraying condition
Crop: apple (Fuji)
District's area processed: 1st district: 1 the tree, 1 time repeatedly
Water-spraying amount: 3L/ tree
Spray method: the composition 200g of the composition 250g of the composition 300g of the composition 208.2g of embodiment 9, comparative example 6, comparative example 7 and comparative example 8 is respectively charged in the 100L tank, adds water to the scale of 100L, fully mix, thereby prepare flushing liquor.Take out the amount that will spray from tank, use the battery power sprayer to be sprayed.
Evaluation method: the whole leaf to 1 20 shoots in district carries out incidence survey, investigates the scab number of 400 leaves of every approximately 300 leaves～approximately.It should be noted that, the computational methods that control is worth are as follows.
Be worth=(((the morbidity leaf rate of non-processor)-(the morbidity leaf rate of embodiment or comparative example))/(the red mould grain rate of non-processor)) * 100 of control
The result of table 6 test example 6
According to table 6, embodiment 9 compares with comparative example 6～8, and control is worth high, demonstrates the inhibition of good spot defoliation.For the medicament for spot defoliation in this test, spray, the control efficiency of the comparative example 8 of general bactericide is insufficient, has implied the reduction to the susceptibility of this bactericide.Even use the comparative example 6,7 of mixed commercially available adhesive agent in bactericide, control efficiency is also insufficient.Shown: under such experimental condition, the agricultural or horticultural bactericide composition of embodiment 9 makes the control efficiency of organochlorine series bactericidal agent, organic copper series bactericidal agent maintain highlyer.
Claims (20)
1. an agricultural or horticultural bactericide composition, it contains:
(A) at least one agricultural or horticultural bactericide in the group that the bactericide (A7) that choosing freely contains the bactericide (A1) of benzimidazole ring, the bactericide (A2) that contains the guanidine structure, the bactericide (A3) that contains organic sulfur, the bactericide (A4) that contains anilino-pyrimidine, the bactericide (A5) that contains triazole ring, the bactericide (A6) that contains organochlorine and contains organic copper forms;
(B) dialkyl sulfosuccinates; And
(C) polyethylene glycol oxide C11～C15 alkyl ether,
And the content ratio of mass ratio of take is (A): (B): (C)=1～70:1:1～4.
2. agricultural or horticultural bactericide composition according to claim 1, wherein, described dialkyl sulfosuccinates (B) is two (2-ethylhexyl) sulfosuccinate.
3. agricultural or horticultural bactericide composition according to claim 1 and 2, wherein, the described bactericide that contains the benzimidazole ring (A1) is more than one in the group of selecting the mould prestige of free second, thiophanate-methyl and benomyl and forming.
4. agricultural or horticultural bactericide composition according to claim 1 and 2, wherein, the described bactericide that contains the guanidine structure (A2) is iminoctadine triacetate or iminoctadine alkylbenzenesulfonate.
5. agricultural or horticultural bactericide composition according to claim 1 and 2, wherein, described organic sulfur series bactericidal agent (A3) is more than one in the group of selecting free tmtd, Polycarbamate, mancozeb and maneb and forming.
6. agricultural or horticultural bactericide composition according to claim 1 and 2, wherein, the described bactericide that contains the anilino-pyrimidine structure (A4) is cyprodinil or mepanipyrim.
7. agricultural or horticultural bactericide composition according to claim 1 and 2, wherein, the described bactericide that contains triazole ring (A5) is more than one in the group of selecting free Difenoconazole, Cyproconazole, Tebuconazole and penconazole and forming.
8. agricultural or horticultural bactericide composition according to claim 1 and 2, wherein, the described bactericide that contains organochlorine (A6) is TPN or captan.
9. agricultural or horticultural bactericide composition according to claim 1 and 2, wherein, the described bactericide that contains organic copper (A7) is copper 8-quinolinolate.
10. agricultural or horticultural bactericide composition according to claim 1, wherein,
(i) bactericide that contains the benzimidazole ring (A1) is at least one in the group of selecting the mould prestige of free second, thiophanate-methyl and benomyl to form;
(ii) bactericide that contains the guanidine structure (A2) is iminoctadine triacetate or iminoctadine alkylbenzenesulfonate;
(iii) bactericide that contains organic sulfur (A3) is at least one in the group of selecting free tmtd, Polycarbamate, mancozeb and maneb to form;
(iv) bactericide that contains the anilino-pyrimidine structure (A4) is cyprodinil or mepanipyrim;
(v) bactericide that contains triazole ring (A5) is at least one in the group of selecting free Difenoconazole, Cyproconazole, Tebuconazole, penconazole to form;
(vi) bactericide that contains organochlorine (A6) is TPN or captan; And
(vii) bactericide that contains organic copper (A7) is for being selected from as at least one in the group of copper 8-quinolinolate.
11. agricultural or horticultural bactericide composition according to claim 10, wherein,
(B) composition is two (2-ethylhexyl) sulfosuccinate;
(A) when composition is respectively described (i)～(vii), (A) composition, (B) composition and (C) ratio of composition is as follows respectively:
(a) during containing described (i), (A1): (B): (C)=1～40:1:1～4,
(b) during containing described (ii), (A2): (B): (C)=1～10:1:1～4,
(c) during containing described (iii), (A3): (B): (C)=10～70:1:1～4,
(d) during containing described (iv), (A4): (B): (C)=1～20:1:1～4,
(e) during containing described (v), (A5): (B): (C)=1～20:1:1～4,
(f) during containing described (vi), (A6): (B): (C)=1～30:1:1～4,
(g) during containing described (vii), (A7): (B): (C)=10～40:1:1～4.
12. according to the described agricultural or horticultural bactericide composition of claim 10 or 11, wherein,
(B) composition is two (2-ethylhexyl) sulfosuccinate;
As (A) composition, contain any one or described (vi) in described (i)～(v) and (vii) both, (A) mass ratio of the total amount of composition is as follows respectively with respect to (B) composition with (C) for composition:
(a), during containing described (i), be (A1): 1～18,
(b), during containing described (ii), be (A2): 0.4～6,
(c), during containing described (iii), be (A3): 5～35,
(d), during containing described (iv), be (A4): 0.6～7,
(e), during containing described (v), be (A5): 0.5～3,
(f) containing described (vi) and (vii) both the time, be { (A6)+(A7) }: 4～30.
13. according to the described agricultural or horticultural bactericide composition of any one in claim 1～12, wherein, (A) composition, (B) composition and (C) total amount shared ratio in the total amount of agricultural or horticultural bactericide composition of composition be 40～100 quality %, 60～0 quality % are the agricultural chemicals additive outside (A)～(C).
14. the flushing liquor of an agricultural or horticultural bactericide composition, it,, by the described agricultural or horticultural bactericide composition of any one in claim 1～13, adding water, makes each constituent concentration be:
(A) constituent concentration is 10～3000ppm;
(B) constituent concentration is 10～200ppm; And
(C) constituent concentration is 10～800ppm
And obtain.
15. the method for preventing and treating of a soybean purple speck, wheat red rust disease or potato purple spot, is characterized in that, the described flushing liquor of claim 14 is sprayed onto on the petiole of soybean, wheat or potato.
16. the method for preventing and treating of a grey mould fruit rot of strawberry or apple scab, is characterized in that, the described flushing liquor of claim 14 is sprayed onto on the petiole of strawberry or on the tree and leaf of apple.
17. the mixed surfactant composition manufacturing effect be enhanced or the agricultural or horticultural bactericide composition that contains following (A) that maintains in application,
Described mixed surfactant composition contains (B) dialkyl sulfosuccinates and (C) polyethylene glycol oxide C11～C15 alkyl ether, and (B) of example meter in mass ratio: (C) content ratio is 1:1～4,
At least one agricultural or horticultural bactericide in the group that the bactericide (A7) that described (A) freely contains the bactericide (A1) of benzimidazole ring, the bactericide (A2) that contains the guanidine structure, the bactericide (A3) that contains organic sulfur, the bactericide (A4) that contains the anilino-pyrimidine structure, the bactericide (A5) that contains triazole ring, the bactericide (A6) that contains organochlorine and contain organic copper for choosing forms.
A 18. method that strengthens or maintain the bactericidal effect of agricultural or horticultural bactericide, it is characterized in that, the bactericide (A1) that freely contains the benzimidazole ring in (A) choosing, the bactericide that contains the guanidine structure (A2), the bactericide that contains organic sulfur (A3), the bactericide that contains the anilino-pyrimidine structure (A4), the bactericide that contains triazole ring (A5), in at least one agricultural or horticultural bactericide in the group that the bactericide that contains organochlorine (A6) and the bactericide (A7) that contains organic copper form, count (A) with example in mass ratio: (B): the ratio of (C)=1～70:1:1～4, cooperation is counted (B) with mass ratio: the ratio of (C)=1:1～4 contains (B) dialkyl sulfosuccinates and (C) the mixed surfactant composition of polyethylene glycol oxide C11～C15 alkyl ether.
19. an effect is enhanced or the manufacture method of the agricultural or horticultural bactericide flushing liquor that maintains, it is characterized in that, and add mixed surfactant composition and water and make flushing liquor in agricultural or horticultural bactericide (A),
At least one in the group that the bactericide (A7) that described agricultural or horticultural bactericide (A) freely contains the bactericide (A1) of benzimidazole ring, the bactericide (A2) that contains the guanidine structure, the bactericide (A3) that contains organic sulfur, the bactericide (A4) that contains the anilino-pyrimidine structure, the bactericide (A5) that contains triazole ring, the bactericide (A6) that contains organochlorine and contains organic copper for choosing forms
Described mixed surfactant composition is with (B): (B) dialkyl sulfosuccinates and (C) polyethylene glycol oxide C11～C15 alkyl ether are contained in (C)=1:1～4,
Described flushing liquor is counted (A) with example in mass ratio: (B): the ratio of (C)=1～70:1:1～4 contains (A), (B) and (C) each composition, and described each constituent concentration is:
(A) composition: 10～3000ppm,
(B) composition: 10～200ppm,
(C) composition: 10～800ppm.
A 20. enhancing, recover or maintain the method for agricultural or horticultural bactericide (A) to the susceptibility of the pathogen after Reduced susceptibility, wherein, the bactericide (A1) that freely contains the benzimidazole ring in choosing, the bactericide that contains the guanidine structure (A2), the bactericide that contains organic sulfur (A3), the bactericide that contains the anilino-pyrimidine structure (A4), the bactericide that contains triazole ring (A5), in at least one agricultural or horticultural bactericide (A) in the group that the bactericide that contains organochlorine (A6) and the bactericide (A7) that contains organic copper form, count (A) with example in mass ratio: (B): the ratio of (C)=1～70:1:1～4, add (B) dialkyl sulfosuccinates and (C) polyethylene glycol oxide C11～C15 alkyl ether.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011-056100 | 2011-03-15 | ||
| JP2011056100A JP2012193116A (en) | 2011-03-15 | 2011-03-15 | Agriculture and horticulture fungicidal composition |
| PCT/JP2012/001686 WO2012124308A1 (en) | 2011-03-15 | 2012-03-12 | Agricultural and horticultural bactericide/fungicide composition |
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| CN103442571A true CN103442571A (en) | 2013-12-11 |
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| CN2012800136157A Pending CN103442571A (en) | 2011-03-15 | 2012-03-12 | Agricultural and horticultural bactericide/fungicide composition |
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| JP (1) | JP2012193116A (en) |
| KR (1) | KR20140041451A (en) |
| CN (1) | CN103442571A (en) |
| WO (1) | WO2012124308A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103988846A (en) * | 2014-05-29 | 2014-08-20 | 江苏龙灯化学有限公司 | Fungicidal composition |
| CN106978470A (en) * | 2017-05-27 | 2017-07-25 | 湖北省农业科学院经济作物研究所 | A kind of method that petiole tangent plane applies dientification of bacteria Strawberry anthracnose resistance |
| CN114467967A (en) * | 2020-10-26 | 2022-05-13 | 山东省联合农药工业有限公司 | Synergistic bactericidal composition containing quinolone compound and copper preparation |
Families Citing this family (3)
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| CN103988843B (en) * | 2014-05-29 | 2016-06-22 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN106572651B (en) * | 2014-08-05 | 2021-01-29 | 陶氏环球技术有限责任公司 | Emulsifiable concentrate of indoxacarb |
| CN114097827B (en) * | 2021-12-15 | 2023-03-17 | 台州市农业科学研究院 | Bactericide composition, preparation method and application |
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| CN114467967A (en) * | 2020-10-26 | 2022-05-13 | 山东省联合农药工业有限公司 | Synergistic bactericidal composition containing quinolone compound and copper preparation |
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Also Published As
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| WO2012124308A1 (en) | 2012-09-20 |
| JP2012193116A (en) | 2012-10-11 |
| KR20140041451A (en) | 2014-04-04 |
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