CN103410288B - A kind of vacuum thermal insulation photovoltaic decoration integrated board and preparation method thereof - Google Patents

A kind of vacuum thermal insulation photovoltaic decoration integrated board and preparation method thereof Download PDF

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CN103410288B
CN103410288B CN201310368582.4A CN201310368582A CN103410288B CN 103410288 B CN103410288 B CN 103410288B CN 201310368582 A CN201310368582 A CN 201310368582A CN 103410288 B CN103410288 B CN 103410288B
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李晓军
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Shandong Horizon Building Energy Feeiciencv Technology Co ltd
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YANTAI SITANPU FINE CONSTRUCTION Co Ltd
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Abstract

本发明公开了一种真空绝热保温光伏装饰一体化板,所述一体化板为层状结构,由里至外依次包括保温层、加强层和光伏装饰层,其中,所述保温层为STP超薄真空绝热保温板,由防水卷材真空密封包裹;所述防水卷材为聚合物水泥砂浆高分子复合防水卷材;所述加强层为水泥压力板或硅酸钙板,且所述加强层的弹性模量与所述保温板一致;所述光伏装饰层由里至外依次包括柔性薄膜电池组件、膜层和涂料层。本发明所述真空绝热保温光伏装饰一体化板具有不燃防水、部品标准化、施工装配化、光伏保温装饰一体化的优点。

The invention discloses a vacuum thermal insulation photovoltaic decoration integrated board. The integrated board is a layered structure, which sequentially includes a thermal insulation layer, a reinforcement layer and a photovoltaic decorative layer from the inside to the outside, wherein the thermal insulation layer is an STP super The thin vacuum heat insulation board is vacuum-sealed and wrapped by a waterproof coil; the waterproof coil is a polymer cement mortar polymer composite waterproof coil; the reinforcement layer is a cement pressure board or a calcium silicate board, and the reinforcement layer The modulus of elasticity is consistent with that of the thermal insulation board; the photovoltaic decorative layer includes a flexible thin film battery assembly, a film layer and a paint layer from the inside to the outside. The vacuum thermal insulation photovoltaic decoration integrated board of the present invention has the advantages of non-combustible and waterproof, standardized parts, construction assembly, and integration of photovoltaic thermal insulation and decoration.

Description

一种真空绝热保温光伏装饰一体化板及其制备方法A vacuum thermal insulation photovoltaic decoration integrated board and its preparation method

技术领域technical field

本发明涉及建筑节能和光电建筑领域,具体涉及一种真空绝热保温光伏装饰一体化板及其制备方法,应用于有保温隔热要求的光电幕墙建筑。The invention relates to the fields of building energy saving and photoelectric buildings, in particular to a vacuum thermal insulation photovoltaic decoration integrated board and a preparation method thereof, which are applied to photoelectric curtain wall buildings requiring thermal insulation.

背景技术Background technique

绿色建筑是目前建筑科学发展的重点,其核心是运用可持续发展的理论和技术,使建筑在营造和运营的全过程,最大限度的节约资源、能源和减少环境污染。发达国家正在倡导的零能耗建筑,就是在实现建筑节能减排的同时,充分利用太阳能等可再生能源为建筑提供绿色、低碳的永续能源供应,以减少对传统化石能源的依赖。为实现此目的,世界各国一边在大力研制更加安全可靠的环保节能建材,一边在开发更为先进的能源生产型建材,以实现建筑节能与光伏发电一体化,变建筑耗能为建筑生产清洁能源。Green building is the focus of the development of building science at present. Its core is to use the theory and technology of sustainable development to save resources, energy and reduce environmental pollution to the greatest extent in the whole process of building construction and operation. The zero-energy building that developed countries are advocating is to make full use of renewable energy such as solar energy to provide green, low-carbon and sustainable energy supply for buildings while realizing energy conservation and emission reduction in buildings, so as to reduce dependence on traditional fossil energy. To achieve this goal, countries around the world are vigorously developing safer and more reliable environmentally friendly and energy-saving building materials, while developing more advanced energy-producing building materials to realize the integration of building energy conservation and photovoltaic power generation, and transform building energy consumption into clean energy for buildings. .

光伏建材和光伏建筑一体化是国际建筑科学的前沿科学研究。传统的光电建筑多为以光伏玻璃为代表的光伏幕墙系统,这一系统因暴露出来的光污染、安全性差、安装复杂、价格昂贵和维护费用高等问题遭到普遍质疑和诟病。如何将大量的建筑外墙面建设成安全可靠的光电幕墙,对于扩展太阳能光伏建筑一体化的应用范围具有重要意义。我国未来的高层、超高层建筑越来越多,且都需要进行外墙隔热保温,如在这些建筑上实现光伏建筑一体化,就必须慎重考虑光电建筑系统中的隔热保温、防火防水、光伏发电等多种功能的联合作用及相互影响,确保整个系统在实现基本建筑功能的同时,能够安全稳定的给建筑提供所需电力。因此,对整个系统的设计和材料选择上,就要充分考虑材料的重量、防水防潮、防火安全、安装便捷和经济合理性。Photovoltaic building materials and building integrated photovoltaics are cutting-edge scientific research in international building science. Traditional photovoltaic buildings are mostly photovoltaic curtain wall systems represented by photovoltaic glass. This system has been widely questioned and criticized due to exposed light pollution, poor safety, complicated installation, high price and high maintenance costs. How to build a large number of building exterior walls into safe and reliable photovoltaic curtain walls is of great significance for expanding the application range of solar photovoltaic building integration. There will be more and more high-rise and ultra-high-rise buildings in my country in the future, and all of them need to be thermally insulated. The combination and interaction of various functions such as photovoltaic power generation ensures that the entire system can safely and stably provide the required power to the building while realizing the basic building functions. Therefore, in the design and material selection of the entire system, it is necessary to fully consider the weight of the material, waterproof and moisture-proof, fire safety, convenient installation and economic rationality.

幕墙系统已广泛应用于建筑外墙,是商厦、办公楼等建筑外墙装饰不可缺少的技术,现有的幕墙技术只具有对墙体的保温隔热和装饰作用,不具备光伏发电的功能。刚刚开始推广的光伏玻璃幕墙多采用以钢化玻璃为基板的光伏组件,其存在质量重、钢化玻璃易爆裂破碎和光污染等安全隐患。其次,非玻璃幕墙结构的保温光伏幕墙的开发应用上尚是一块亟待开发法的领域。The curtain wall system has been widely used in building exterior walls, and is an indispensable technology for the decoration of commercial buildings, office buildings and other building exterior walls. The existing curtain wall technology only has the function of thermal insulation and decoration of the wall, and does not have the function of photovoltaic power generation. The photovoltaic glass curtain wall that has just started to be promoted mostly uses photovoltaic modules with tempered glass as the substrate, which has potential safety hazards such as heavy weight, tempered glass that is easy to burst and break, and light pollution. Secondly, the development and application of thermal insulation photovoltaic curtain wall with non-glass curtain wall structure is still a field that needs to be developed urgently.

中国专利号为CN201354501Y的实用新型专利说明书中公开了一种太阳能光伏发电外墙饰面板及外墙板;中国专利号为CN202263950U的实用新型专利说明书中公开了一种具有建筑外墙或屋顶装饰功能的光伏发电复合板。上述两个专利中,光伏发电复合板中作为光伏电池托架的基板都采用的是金属、水泥、塑料等硬质板材,它们都不具备保温隔热作用,不能满足建筑物保温隔热的要求。A utility model patent specification whose Chinese patent number is CN201354501Y discloses a solar photovoltaic power generation exterior wall decorative panel and an external wall panel; photovoltaic composite panels. In the above two patents, the substrate used as the photovoltaic cell bracket in the photovoltaic power generation composite board is made of hard plates such as metal, cement, plastic, etc., which do not have the function of heat preservation and heat insulation, and cannot meet the heat insulation requirements of buildings .

发明内容Contents of the invention

本发明要解决的技术问题是提供一种用于光电建筑的真空绝热保温光伏装饰一体化板及其制备方法,所述真空绝热保温光伏装饰一体化板兼具保温隔热、光伏发电、防火防水、建筑装饰等多种功能,应用于有保温隔热要求的光电幕墙建筑,实现建筑高效节能和自发自用所需电力的作用。The technical problem to be solved by the present invention is to provide a vacuum thermal insulation photovoltaic decoration integrated board for photovoltaic buildings and its preparation method. The vacuum thermal insulation photovoltaic decoration integrated board has thermal insulation, photovoltaic power generation, fire prevention and waterproof , architectural decoration and other functions, it is applied to photoelectric curtain wall buildings with thermal insulation requirements, so as to realize the functions of building high efficiency, energy saving and self-consumption required electricity.

本发明真空绝热保温光伏装饰一体化板,所述一体化板为层状结构,由里至外依次包括保温层、加强层和光伏装饰层,所述保温层为STP超薄真空绝热保温板。According to the present invention, the integrated panel with vacuum thermal insulation and photovoltaic decoration, the integrated panel has a layered structure, which includes a thermal insulation layer, a reinforcement layer and a photovoltaic decorative layer from the inside to the outside, and the thermal insulation layer is an STP ultra-thin vacuum thermal insulation panel.

本发明所述的真空绝热保温光伏装饰一体化板,其中所述STP超薄真空绝热保温板厚度为10~30mm,由防水卷材密封包裹。The vacuum thermal insulation and photovoltaic decoration integrated panel of the present invention, wherein the thickness of the STP ultra-thin vacuum thermal insulation panel is 10-30 mm, and is sealed and wrapped by a waterproof coiled material.

本发明所述的真空绝热保温光伏装饰一体化板,其中所述防水卷材为聚合物水泥砂浆高分子复合防水卷材,由玻璃纤维增强无纺布与聚合物水泥砂浆复合而成,厚度在2~3mm之间;所述聚合物水泥砂浆是由水泥、骨料和可以分散在水中的多种单聚体聚合而成的共聚物搅拌而成,可形成独特的有一定韧性的复合网络结构,对所述真空绝热保温板起到保护和防水双重功能。The vacuum thermal insulation photovoltaic decoration integrated panel of the present invention, wherein the waterproof coiled material is a polymer cement mortar polymer composite waterproof coiled material, which is composed of glass fiber reinforced non-woven fabric and polymer cement mortar, with a thickness of Between 2 and 3 mm; the polymer cement mortar is made by mixing cement, aggregate and a copolymer of various monomers that can be dispersed in water, and can form a unique composite network structure with certain toughness , to play the double function of protection and waterproof for the vacuum heat insulation board.

本发明所述的真空绝热保温光伏装饰一体化板,其中所述光伏装饰层由里至外依次包括柔性薄膜电池组件、膜层和涂料层。According to the vacuum heat insulation and thermal insulation photovoltaic decoration integrated panel of the present invention, the photovoltaic decoration layer includes a flexible thin film battery module, a film layer and a paint layer in sequence from the inside to the outside.

本发明所述的真空绝热保温光伏装饰一体化板,其中所述柔性薄膜电池组件是在塑料等可弯曲的柔性衬底上采用沉积透明导电膜制备的薄膜电池。所述柔性薄膜太阳能电池包括:非晶硅柔性太阳能薄膜电池、铜铟钾硒薄膜太能能电池(CIGS)、碲化镉薄膜太阳能电池(CdTe),染料敏化太阳能电池(DSC)和有机薄膜太阳能电池,所述膜层为含氟TPT聚酯膜或乙烯—四氟乙烯共聚物(ETFE)膜,厚度为250um,主要起密封、保护、抗紫外线、水蒸气阻隔、电气绝缘、稳定尺寸、耐湿热老化及阻燃和防污自洁作用;所述涂料层由粒径为纳米级的防污自洁涂料涂覆而成,优选所述涂料层为纳米级有机硅改性丙烯酸涂料或纳米级氟碳涂料,厚度为30~70um,主要起到自洁、防污染作用,该涂料可有效避免粉尘、雾霾等污染物降低太阳能电池的光电转换效率。According to the vacuum heat insulation and thermal insulation photovoltaic decoration integrated board of the present invention, the flexible thin film battery component is a thin film battery prepared by depositing a transparent conductive film on a bendable flexible substrate such as plastic. The flexible thin-film solar cells include: amorphous silicon flexible solar thin-film solar cells, copper indium potassium selenium thin-film solar cells (CIGS), cadmium telluride thin-film solar cells (CdTe), dye-sensitized solar cells (DSC) and organic thin-film solar cells Solar cells, the film layer is fluorine-containing TPT polyester film or ethylene-tetrafluoroethylene copolymer (ETFE) film, with a thickness of 250um, mainly for sealing, protection, UV resistance, water vapor barrier, electrical insulation, stable size, Moisture and heat aging resistance, flame retardancy and antifouling self-cleaning effect; the coating layer is coated with an antifouling self-cleaning coating with a particle size of nanometer scale, preferably the coating layer is nanoscale silicone modified acrylic coating or nanoscale Grade fluorocarbon coating, with a thickness of 30-70um, mainly plays the role of self-cleaning and anti-pollution. The coating can effectively prevent dust, smog and other pollutants from reducing the photoelectric conversion efficiency of solar cells.

本发明所述的真空绝热保温光伏装饰一体化板,其中所述加强层为硅酸钙板或水泥压力板,所述加强层的厚度为3~5mm,其弹性模量与所述保温层一致。所述硅酸钙板以优质高标号水泥为基体材料,并配以天然纤维增强,经先进生产工艺成型、加压、高温蒸养等特殊技术处理而制成,是一种具有优良性能的新型建筑和工业用板材,其产品防火,防潮,隔音,防虫蛀,耐久性强;所述水泥压力板又称水泥纤维压力板,是以天然纤维和水泥为原料,经制浆、成型、切割、加压、养护而成的一种新型建筑板材,具有轻质、高强、防水、防腐、防火等优点,广泛用于民用和工业建筑中外墙板、幕墙衬板、复合墙体面板;所述硅酸钙板和所述水泥压力板凭借其优良的物理力学性能和耐久性,可有效保护保温层不受长期恶劣环境的破坏;选择与所述保温层弹性模量一致的硅酸钙板和水泥压力板,可防止保温层与加强层因差异变形产生的层间裂隙。The vacuum heat insulation photovoltaic decoration integrated board of the present invention, wherein the reinforcement layer is a calcium silicate board or a cement pressure board, the thickness of the reinforcement layer is 3-5 mm, and its elastic modulus is consistent with the insulation layer . The calcium silicate board is made of high-quality high-grade cement as the base material, reinforced with natural fibers, and processed by advanced production technology molding, pressurization, high-temperature steam curing, etc. Building and industrial boards, its products are fireproof, moisture-proof, sound-proof, moth-proof, and durable; the cement pressure board is also called cement fiber pressure board, which is made of natural fiber and cement, after pulping, molding, cutting, A new type of building board made of pressurized and cured. It has the advantages of light weight, high strength, waterproof, anti-corrosion, and fire prevention. It is widely used in exterior wall panels, curtain wall lining boards, and composite wall panels in civil and industrial buildings; the silicon The calcium silicate board and the cement pressure board can effectively protect the insulation layer from being damaged by long-term harsh environments by virtue of their excellent physical and mechanical properties and durability; The pressure plate can prevent interlayer cracks caused by differential deformation of the insulation layer and the reinforcement layer.

本发明所述的真空绝热保温光伏装饰一体化板,其中所述防水卷材为聚合物水泥砂浆高分子复合防水卷材,由胎基与聚合物水泥砂浆复合而成,厚度为1.5~2.5mm,所述胎基为涤棉无纺布与玻纤网格布的复合毡。The vacuum thermal insulation photovoltaic decoration integrated panel of the present invention, wherein the waterproof coiled material is a polymer cement mortar polymer composite waterproof coiled material, which is composed of tire base and polymer cement mortar, and has a thickness of 1.5-2.5mm , the tire base is a composite felt of polyester-cotton non-woven fabric and glass fiber grid cloth.

本发明所述的真空绝热保温光伏装饰一体化板,其中所述保温层和加强层通过聚合物水泥砂浆粘合剂粘结在一起,所述加强层和光伏装饰层通过防火型聚合物粘结剂(西卡单组分高模量聚氨酯密封胶粘剂)粘结在一起。所述聚合物水泥砂浆粘合剂是由水泥、骨料和可以分散在水中的有机聚合物搅拌而成,聚合物在环境条件下成膜覆盖在水泥颗粒子上,并使水泥机体与骨料形成强有力的粘接。聚合物网状结构具有阻止微裂缝发生和扩展的能力,聚合物水泥砂浆粘结剂为无机材料粘结剂,与保温材料防水层和硅酸钙板等无机材料的相容性好,粘结牢固。所述防火型聚合物粘结剂是一种类似软膏,一旦接触空气中的水分就会固化成一种坚韧的橡胶类固体的材料,该西卡单组分高模量聚氨酯密封胶粘剂粘接力强,拉伸强度大,同时又具有耐候性、抗振性,和防潮、抗臭气和适应冷热变化大的特点,能实现柔性薄膜电池组件塑料衬底与STP超薄真空绝热保温板加强层之间的有效粘结。The integrated panel of vacuum heat insulation and thermal insulation photovoltaic decoration according to the present invention, wherein the insulation layer and the reinforcement layer are bonded together by polymer cement mortar adhesive, and the reinforcement layer and the photovoltaic decoration layer are bonded by a fireproof polymer agent (Sika one-component high modulus polyurethane sealing adhesive) to bond together. The polymer cement mortar binder is made by mixing cement, aggregate and organic polymers that can be dispersed in water. The polymer forms a film and covers the cement particles under environmental conditions, and makes the cement body and the aggregate Forms a strong bond. The polymer network structure has the ability to prevent the occurrence and expansion of micro-cracks. The polymer cement mortar binder is an inorganic material binder, which has good compatibility with inorganic materials such as insulation material waterproof layer and calcium silicate board. firm. The fire-resistant polymer adhesive is an ointment-like material that cures to a tough, rubber-like solid upon exposure to moisture in the air. The Sika one-component high-modulus polyurethane sealant has a strong bond , high tensile strength, and at the same time has the characteristics of weather resistance, vibration resistance, moisture resistance, odor resistance and adaptability to large changes in cold and heat, and can realize the plastic substrate of flexible thin film battery components and the reinforcement layer of STP ultra-thin vacuum insulation board effective bond between them.

一种制备所述的真空绝热保温光伏装饰一体化板的方法,包括如下步骤:A method for preparing the vacuum thermal insulation photovoltaic decoration integrated board, comprising the following steps:

(1)保温层的制备:用防水卷材将所述STP超薄真空保温板密封包裹,所述保温层的厚度为10~30mm;(1) Preparation of the insulation layer: seal and wrap the STP ultra-thin vacuum insulation board with a waterproof membrane, and the thickness of the insulation layer is 10-30mm;

(2)加强层的制备:选择3~5mm的硅钙板或水泥压力板,在其表面涂刷有机硅丙烯酸防水涂料;(2) Preparation of reinforcement layer: select 3-5mm calcium silicate board or cement pressure board, and apply silicone acrylic waterproof coating on its surface;

(3)光伏装饰层的制备:在所述柔性薄膜电池组件的表面覆盖加封TPT聚酯膜或乙烯—四氟乙烯共聚物(ETFE)膜层,并在所述TPT聚酯膜或乙烯—四氟乙烯共聚物(ETFE)膜层的外侧涂覆具有防污功能的纳米级有机硅丙烯酸涂料或纳米级氟碳涂料;(3) Preparation of photovoltaic decorative layer: Cover and seal TPT polyester film or ethylene-tetrafluoroethylene copolymer (ETFE) film layer on the surface of the flexible thin film battery module, and cover the TPT polyester film or ethylene-tetrafluoroethylene copolymer (ETFE) film layer The outside of the ethylene fluoride copolymer (ETFE) film layer is coated with nano-scale silicone acrylic coating or nano-scale fluorocarbon coating with anti-fouling function;

(4)采用聚合物水泥砂浆粘结剂粘结经防水卷材密封包裹的所述保温层和所述加强层;(4) Using a polymer cement mortar adhesive to bond the thermal insulation layer and the reinforcement layer sealed and wrapped by the waterproof membrane;

(5)采用西卡单组分高模量聚氨酯密封胶粘剂粘结所述加强层和光伏装饰层;(5) Use Sika single-component high-modulus polyurethane sealing adhesive to bond the reinforcement layer and the photovoltaic decoration layer;

(6)合并封装:按照柔性薄膜光伏电池组件、西卡单组分高模量聚氨酯密封胶粘剂、硅酸钙板或水压力板、聚合物水泥砂浆粘结剂和STP超薄真空绝热保温板的顺序依次层叠,经过辊压和高压釜处理,使各层组件紧密粘合,即得产品。(6) Combined packaging: according to the requirements of flexible thin-film photovoltaic cell components, Sika single-component high-modulus polyurethane sealing adhesive, calcium silicate board or water pressure board, polymer cement mortar binder and STP ultra-thin vacuum insulation board Sequentially stacked, after rolling and autoclave treatment, the components of each layer are tightly bonded, and the product is obtained.

所述的真空绝热保温光伏装饰一体化板的制备方法,其中:The preparation method of the vacuum thermal insulation photovoltaic decoration integrated board, wherein:

所述防水卷材的制作方法为:通过机械压延成型技术将聚合物水泥砂浆均匀涂覆、压延于玻璃纤维增强无纺布的两侧,将柔性聚合物水泥砂浆通过机制刮板均匀涂布于所述玻璃纤维增强无纺布胎基的两侧,形成宽1.2米的防水卷材,将制成的防水卷材进行烘干和养护;The production method of the waterproof coiled material is: uniformly coating and calendering the polymer cement mortar on both sides of the glass fiber reinforced non-woven fabric through mechanical calendering molding technology, and evenly coating the flexible polymer cement mortar on the The glass fiber reinforced the two sides of the non-woven fabric base to form a waterproof roll material with a width of 1.2 meters, and the waterproof roll material made was dried and maintained;

所述防水卷材的烘干和养护方法为:制成的防水卷材采用生产线中的热吹风装置自动烘干,达到聚合物砂浆初凝,成卷后的防水卷材,在5~38℃的室内温度下,自然干燥养护28天后备用;The drying and maintenance method of the waterproof coiled material is as follows: the prepared waterproof coiled material is automatically dried by the hot air blowing device in the production line to achieve the initial setting of the polymer mortar. Under the indoor temperature of 28 days after natural drying and maintenance;

所述硅酸钙板是以水泥为基体材料,配以天然纤维增强,经成型、加压、高温蒸养处理而制成;The calcium silicate board is made of cement as the base material, reinforced with natural fibers, and processed through molding, pressurization, and high-temperature steam curing;

所述加强层的防水和抗变形处理方法为:在所述加强层的表面涂刷有机硅丙烯酸防水涂料;The waterproof and anti-deformation treatment method of the reinforcement layer is as follows: coating the surface of the reinforcement layer with silicone acrylic waterproof paint;

所述水泥压力板是以天然纤维和水泥为原料,经制浆、成型、切割、加压、养护而成;The cement pressure plate is made of natural fiber and cement through pulping, molding, cutting, pressurizing and curing;

所述柔性薄膜电池组件的生产方法包括:薄膜电池卷对卷生产、电池片组装、光伏组件封装;The production method of the flexible thin-film battery assembly includes: thin-film battery roll-to-roll production, battery sheet assembly, and photovoltaic module packaging;

所述聚合物水泥砂浆粘合剂是由水泥、骨料和分散在水中的有机聚合物搅拌而成。The polymer cement mortar binder is prepared by stirring cement, aggregate and organic polymer dispersed in water.

本发明真空绝热保温光伏装饰一体化板与现有技术不同之处在于本发明采用了经防水增强处理的STP高效真空绝热保温板与非晶硅等柔性光伏太阳能薄膜电池组件相结合的方式,有效解决了光电幕墙面对轻质、隔热保温、防水防火和高效发电集成系统的迫切要求;本发明所述一体化板的保温层材料使用STP超薄真空绝热保温板,其包括采用由多层材料复合而成的高强度复合阻气膜,具有高阻气性。该板导热系数低,且远低于聚氨酯等有机保温材料,保温效果相当于聚氨酯的2.8倍,所述STP超薄真空绝热保温板为无机保温材料,防火等级为A级不燃。所述STP超薄真空绝热保温板单位面积质量轻,安全性好;非晶硅等柔性光伏太阳能薄膜电池组件具有可折叠和不易破碎、可以任意卷曲、裁剪、粘贴的特性;电池组件对弱光、散射光、漫射光都具有很强的吸收能力,特别适合于建筑立面的太阳能光伏发电。The difference between the vacuum thermal insulation photovoltaic decoration integrated panel of the present invention and the prior art is that the present invention adopts the method of combining the STP high-efficiency vacuum thermal insulation panel treated with waterproof enhancement and flexible photovoltaic solar thin film battery components such as amorphous silicon, which is effective It solves the urgent requirements of photoelectric curtain wall for light weight, thermal insulation, waterproof and fireproof and high-efficiency power generation integrated system; the thermal insulation layer material of the integrated board of the present invention uses STP ultra-thin vacuum thermal insulation board, which includes the use of multi-layer The high-strength composite gas barrier film made of composite materials has high gas barrier properties. The board has a low thermal conductivity and is far lower than polyurethane and other organic insulation materials. The insulation effect is equivalent to 2.8 times that of polyurethane. The STP ultra-thin vacuum insulation board is an inorganic insulation material, and its fire rating is Class A non-combustible. The STP ultra-thin vacuum insulation board has light weight per unit area and good safety; flexible photovoltaic solar thin film battery components such as amorphous silicon have the characteristics of being foldable and not easy to break, and can be curled, cut, and pasted arbitrarily; , scattered light, and diffuse light all have strong absorption capabilities, and are especially suitable for solar photovoltaic power generation on building facades.

本发明所述由STP板和非晶硅等柔性光伏太阳能薄膜电池组件构成的一体化板,是光电技术与现代保温装饰体系的集成融合,是一种集光伏发电、隔音防噪、保温隔热、防火防水、外墙装饰等功能于一身的外墙光电体系,充分体现了建筑多功能化、高智能化的特点;本发明所述一体化板在生产清洁能源的同时,也满足了建筑的各种功能性需求,这种能源生产型建筑幕墙是绿色建筑技术发展的典型代表。The integrated board composed of STP board and flexible photovoltaic solar thin film battery components such as amorphous silicon is an integration of photoelectric technology and modern heat preservation and decoration system. , fire prevention, waterproof, exterior wall decoration and other functions in one exterior wall photoelectric system, which fully embodies the characteristics of multi-functionality and high intelligence of the building; the integrated board of the present invention also meets the needs of the building while producing clean energy. Various functional requirements, this energy-producing building curtain wall is a typical representative of the development of green building technology.

本发明所述真空绝热保温光伏装饰一体化板具有不燃防水、部品标准化、施工装配化、光伏保温装饰一体化的优点,其中,柔性光伏装饰层、加强层、保温层及与墙体基层各界面的抗拉强度高、整体系统安全系数大;通过把STP高效真空绝热保温板与非晶硅等柔性光伏太阳能薄膜电池组件复合,制成具保温装饰和太阳能发电多种复合功能的光伏建材部品,在提高光电建筑综合功能的同时,大幅度降低了其建设成本;本发明所述真空绝热保温光伏装饰一体化板在应用中除考虑光电池组、光电板、导线、集成电路、整流器等各因素外,还充分考虑到幕墙传统的安全、防护、密封、装饰等功能。The vacuum thermal insulation and photovoltaic decoration integrated board of the present invention has the advantages of non-combustible and waterproof, standardized parts, construction assembly, and integration of photovoltaic thermal insulation and decoration. The tensile strength is high, and the safety factor of the overall system is large; by combining STP high-efficiency vacuum insulation panels with flexible photovoltaic solar thin-film battery components such as amorphous silicon, it is made into photovoltaic building material parts with multiple functions of thermal insulation decoration and solar power generation. While improving the comprehensive functions of the photovoltaic building, its construction cost is greatly reduced; the vacuum heat insulation and thermal insulation photovoltaic decoration integrated board of the present invention considers various factors such as photovoltaic cell groups, photovoltaic panels, wires, integrated circuits, and rectifiers in the application. , also fully consider the traditional security, protection, sealing, decoration and other functions of the curtain wall.

下面结合附图对本发明的真空绝热保温光伏装饰一体化板作进一步说明。The vacuum thermal insulation photovoltaic decoration integrated panel of the present invention will be further described below in conjunction with the accompanying drawings.

附图说明Description of drawings

图1为本发明真空绝热保温光伏装饰一体化板的结构示意图;Fig. 1 is a structural schematic diagram of a vacuum thermal insulation photovoltaic decoration integrated panel of the present invention;

图2为图1M处的局部放大图。Fig. 2 is a partially enlarged view of Fig. 1M.

具体实施方式detailed description

实施例1Example 1

如图1和图2所示,本发明真空绝热保温光伏装饰一体化板为层状结构,由里至外依次包括保温层2、加强层3和光伏装饰层9,其中,所述保温层2由防水卷材1密封包裹,所述保温层2为STP超薄真空绝热保温板,厚度为10mm,所述防水卷材1为聚合物水泥砂浆高分子复合防水卷材,由玻璃纤维增强涤棉无纺布与聚合物水泥砂浆复合而成,厚度为1.5mm。所述加强层3为水泥压力板或硅酸钙板,厚度为3mm,且其弹性模量与所述保温层2一致。所述光伏装饰层9由里至外依次包括柔性薄膜电池组件5、膜层8和涂料层7;所述柔性薄膜电池组件5为非晶硅柔性太阳能薄膜电池;所述膜层8为含氟TPT聚酯膜或乙烯—四氟乙烯共聚物膜(ETFE),厚度为250um;所述涂料层7由粒径为纳米级的防污自洁涂料涂覆而成,所述防污涂料优选为纳米级有机硅改性丙烯酸涂料或纳米级氟碳涂料,厚度为30um。所述保温层2和加强层3通过聚合物水泥砂浆粘合剂4粘结在一起,所述加强层3和光伏装饰层9通过防火型聚合物粘结剂6粘结在一起。As shown in Figures 1 and 2, the vacuum thermal insulation photovoltaic decoration integrated panel of the present invention is a layered structure, which sequentially includes an insulation layer 2, a reinforcement layer 3 and a photovoltaic decoration layer 9 from the inside to the outside, wherein the insulation layer 2 Sealed and wrapped by a waterproof membrane 1, the insulation layer 2 is an STP ultra-thin vacuum insulation board with a thickness of 10mm, and the waterproof membrane 1 is a polymer cement mortar polymer composite waterproof membrane, which is made of glass fiber reinforced polyester cotton The non-woven fabric is compounded with polymer cement mortar, and the thickness is 1.5mm. The reinforcement layer 3 is a cement pressure board or a calcium silicate board with a thickness of 3 mm, and its modulus of elasticity is consistent with that of the insulation layer 2 . The photovoltaic decorative layer 9 includes a flexible thin film battery assembly 5, a film layer 8 and a paint layer 7 from the inside to the outside; the flexible thin film battery assembly 5 is an amorphous silicon flexible solar thin film battery; the film layer 8 is fluorine-containing TPT polyester film or ethylene-tetrafluoroethylene copolymer film (ETFE), with a thickness of 250um; the coating layer 7 is formed by coating an antifouling self-cleaning coating with a nanoscale particle size, and the antifouling coating is preferably Nano-scale silicone modified acrylic coating or nano-scale fluorocarbon coating with a thickness of 30um. The thermal insulation layer 2 and the reinforcement layer 3 are bonded together by a polymer cement mortar adhesive 4 , and the reinforcement layer 3 and the photovoltaic decoration layer 9 are bonded together by a fireproof polymer adhesive 6 .

实施例2Example 2

如图1和图2所示,本发明真空绝热保温光伏装饰一体化板为层状结构,由里至外依次包括保温层2、加强层3和光伏装饰层9,其中,所述保温层2由防水卷材1密封包裹,所述保温层2为STP超薄真空绝热保温板,厚度为30mm,所述防水卷材1为聚合物水泥砂浆高分子复合防水卷材,由玻璃纤维增强涤棉无纺布与聚合物水泥砂浆复合而成,厚度为2.5mm。所述加强层3为水泥压力板或硅酸钙板,厚度为5mm,且其弹性模量与所述保温层2一致。所述光伏装饰层9由里至外依次包括柔性薄膜电池组件5、膜层8和涂料层7;所述柔性薄膜电池组件5为铜铟钾硒薄膜太阳能电池;所述膜层8为含氟TPT聚酯膜或乙烯—四氟乙烯共聚物(ETFE)膜,厚度为250um;所述涂料层7由粒径为纳米级的防污自洁涂料涂覆而成,所述防污自洁涂料优选为纳米级有机硅改性丙烯酸涂料或氟碳涂料,厚度为70um。所述保温层2和加强层3通过聚合物水泥砂浆粘合剂4粘结在一起,所述加强层3和光伏装饰层9通过防火型聚合物粘结剂西卡单组分高模量聚氨酯密封胶粘剂6粘结在一起。As shown in Figures 1 and 2, the vacuum thermal insulation photovoltaic decoration integrated panel of the present invention is a layered structure, which sequentially includes an insulation layer 2, a reinforcement layer 3 and a photovoltaic decoration layer 9 from the inside to the outside, wherein the insulation layer 2 Sealed and wrapped by a waterproof membrane 1, the insulation layer 2 is an STP ultra-thin vacuum insulation board with a thickness of 30mm, and the waterproof membrane 1 is a polymer cement mortar polymer composite waterproof membrane, which is made of glass fiber reinforced polyester cotton The non-woven fabric is compounded with polymer cement mortar, and the thickness is 2.5mm. The reinforcement layer 3 is a cement pressure board or a calcium silicate board with a thickness of 5 mm, and its modulus of elasticity is consistent with that of the insulation layer 2 . The photovoltaic decoration layer 9 includes a flexible thin film battery component 5, a film layer 8 and a coating layer 7 from the inside to the outside; the flexible thin film battery component 5 is a copper indium potassium selenium thin film solar cell; the film layer 8 is a fluorine-containing TPT polyester film or ethylene-tetrafluoroethylene copolymer (ETFE) film, with a thickness of 250um; the coating layer 7 is coated with an anti-fouling self-cleaning coating with a particle size of nanoscale, and the anti-fouling self-cleaning coating It is preferably nano-scale silicone-modified acrylic paint or fluorocarbon paint, with a thickness of 70um. The thermal insulation layer 2 and the reinforcement layer 3 are bonded together by polymer cement mortar adhesive 4, and the reinforcement layer 3 and photovoltaic decoration layer 9 are bonded together by fireproof polymer adhesive Sika single-component high-modulus polyurethane Sealing adhesive 6 is bonded together.

实施例3Example 3

如图1和图2所示,本发明真空绝热保温光伏装饰一体化板为层状结构,由里至外依次包括保温层2、加强层3和光伏装饰层9,其中,所述保温层2由防水卷材1密封包裹,所述保温层2为STP超薄真空绝热保温板,厚度为20mm,所述防水卷材1为聚合物水泥砂浆高分子复合防水卷材,由玻璃纤维增强涤棉无纺布与聚合物水泥砂浆复合而成,厚度为2mm。所述加强层3为水泥压力板或硅酸钙板,厚度为4mm,且其弹性模量与所述保温层2一致。所述光伏装饰层9由里至外依次包括柔性薄膜电池组件5、膜层8和涂料层7;所述柔性薄膜电池组件5为有机薄膜电池;所述膜层8为含氟TPT聚酯膜或乙烯—四氟乙烯共聚物(ETFE)膜,厚度为250um;所述涂料层7由粒径为纳米级的防污自洁涂料涂覆而成,所述防污自洁涂料优选为纳米级有机硅改性丙烯酸涂料或氟碳涂料,厚度为50um。所述保温层2和加强层3通过聚合物水泥砂浆粘合剂4粘结在一起,所述加强层3和光伏装饰层9通过防火型聚合物粘结剂西卡单组分高模量聚氨酯密封胶粘剂6粘结在一起。As shown in Figures 1 and 2, the vacuum thermal insulation photovoltaic decoration integrated panel of the present invention is a layered structure, which sequentially includes an insulation layer 2, a reinforcement layer 3 and a photovoltaic decoration layer 9 from the inside to the outside, wherein the insulation layer 2 Sealed and wrapped by a waterproof membrane 1, the insulation layer 2 is an STP ultra-thin vacuum insulation board with a thickness of 20mm, and the waterproof membrane 1 is a polymer cement mortar polymer composite waterproof membrane, which is made of glass fiber reinforced polyester cotton The non-woven fabric is compounded with polymer cement mortar, and the thickness is 2mm. The reinforcement layer 3 is a cement pressure board or a calcium silicate board with a thickness of 4 mm, and its modulus of elasticity is consistent with that of the insulation layer 2 . The photovoltaic decorative layer 9 includes a flexible thin film battery assembly 5, a film layer 8 and a paint layer 7 from inside to outside; the flexible thin film battery assembly 5 is an organic thin film battery; the film layer 8 is a fluorine-containing TPT polyester film Or an ethylene-tetrafluoroethylene copolymer (ETFE) film with a thickness of 250um; the coating layer 7 is formed by coating an antifouling self-cleaning paint with a nanoscale particle size, and the antifouling self-cleaning paint is preferably nanoscale Silicone modified acrylic paint or fluorocarbon paint, thickness 50um. The thermal insulation layer 2 and the reinforcement layer 3 are bonded together by polymer cement mortar adhesive 4, and the reinforcement layer 3 and photovoltaic decoration layer 9 are bonded together by fireproof polymer adhesive Sika single-component high-modulus polyurethane Sealing adhesive 6 is bonded together.

实施例4Example 4

一种STP高效真空绝热保温板的制备方法,它包括如下步骤:A preparation method of STP high-efficiency vacuum heat insulation board, it comprises the steps:

(1)保温层2的制备:用由聚合物水泥砂浆等高分子复合材料制成的防水卷材1将STP高效真空绝热保温板四周密封包裹,形成全封闭、厚度在10~30mm之间的防水防火保温板;(1) Preparation of thermal insulation layer 2: Use waterproof coiled material 1 made of polymer cement mortar and other polymer composite materials to seal and wrap the STP high-efficiency vacuum thermal insulation board around to form a fully enclosed, thickness between 10 and 30mm. Waterproof and fireproof insulation board;

所述防水卷材1的制作方法为:将柔性聚合物水泥砂浆通过机制刮板均匀涂布于由玻璃纤维增强涤棉无纺布组成胎基的两侧,形成宽1.2米的防水卷材1,制成的防水卷材1采用生产线中的热吹风装置自动烘干,达到聚合物砂浆初凝,成卷后的防水卷材,在5~38℃的室内温度下,自然干燥养护28天后备用;The manufacturing method of the waterproof coiled material 1 is as follows: the flexible polymer cement mortar is evenly coated on both sides of the tire base composed of glass fiber reinforced polyester-cotton non-woven fabric through a mechanism scraper to form a waterproof coiled material 1 with a width of 1.2 meters. , the waterproof membrane 1 is automatically dried by the hot blowing device in the production line to achieve the initial setting of the polymer mortar, and the waterproof membrane after being rolled is naturally dried and maintained for 28 days at an indoor temperature of 5-38°C. ;

(2)加强层3的制备:将3~5mm的硅钙板或水泥压力板表面涂刷丙烯酸防水涂料,使其具备良好的耐久性,所述硅酸钙板是以水泥为基体材料,配以天然纤维增强,经成型、加压、高温蒸养处理而制成;所述水泥压力板是以天然纤维和水泥为原料,经制浆、成型、切割、加压、养护而成;(2) Preparation of reinforcement layer 3: paint the surface of 3-5mm calcium silicate board or cement pressure board with acrylic waterproof paint to make it have good durability. Reinforced with natural fibers, it is made by molding, pressurizing, and high-temperature steam curing; the cement pressure plate is made of natural fibers and cement through pulping, molding, cutting, pressurizing, and curing;

(3)光伏装饰层9的制备:在所述柔性薄膜电池组件5的表面覆盖加封TPT聚酯膜或乙烯—四氟乙烯共聚物(ETFE)膜层8,并在所述TPT聚酯膜或乙烯—四氟乙烯共聚物(ETFE)膜层8的外侧涂覆具有防污功能的纳米级有机硅丙烯酸涂料或纳米级氟碳涂料;所述柔性薄膜电池组件5的生产方法包括:薄膜电池卷对卷生产、电池片组装、光伏组件封装;(3) Preparation of photovoltaic decorative layer 9: Cover and seal the TPT polyester film or ethylene-tetrafluoroethylene copolymer (ETFE) film layer 8 on the surface of the flexible thin film battery module 5, and cover the TPT polyester film or The outer side of the ethylene-tetrafluoroethylene copolymer (ETFE) film layer 8 is coated with nano-scale silicone acrylic paint or nano-scale fluorocarbon paint with antifouling function; the production method of the flexible thin film battery assembly 5 includes: thin film battery roll Roll production, cell assembly, photovoltaic module packaging;

(4)聚合物水泥砂浆粘结剂形成第一粘结层4,粘结经防水卷,1密封包裹的所述保温层2和所述加强层3;所述聚合物水泥砂浆粘合剂是由水泥、骨料和分散在水中的有机聚合物搅拌而成;(4) The polymer cement mortar binder forms the first bonding layer 4, bonding the insulation layer 2 and the reinforcement layer 3 sealed and wrapped by the waterproof roll, 1; the polymer cement mortar binder is It is made by mixing cement, aggregate and organic polymer dispersed in water;

(5)采用西卡单组分高模量聚氨酯密封胶粘剂粘结所述加强层和光伏装饰层;(5) Use Sika single-component high-modulus polyurethane sealing adhesive to bond the reinforcement layer and the photovoltaic decoration layer;

(6)合并封装:按照柔性薄膜光伏电池组件、西卡单组分高模量聚氨酯密封胶粘剂、硅酸钙板或水压力板、聚合物水泥砂浆粘结剂和STP真空绝热保温板的顺序依次层叠,经过辊压和高压釜处理,使各层组件紧密粘合,即得产品。(6) Combined packaging: in the order of flexible thin-film photovoltaic cell modules, Sika single-component high-modulus polyurethane sealing adhesive, calcium silicate board or water pressure board, polymer cement mortar binder and STP vacuum insulation board Stacking, after rolling and autoclave treatment, the components of each layer are tightly bonded, and the product is obtained.

将真空绝热保温光伏板通过粘接与锚固相结合的方式安装于建筑物外墙的采光面上。每块保温光伏板上的太阳能电池板都有独立的正负极电流导线引出,电导线及接线盒布置在位于延保温光伏板长度方向侧壁的导线槽孔内。安装时,将每块保温光伏板上的电导线通过接线盒进行电路连接组合(串联或并联电路连接),然后利用每块保温光伏板之间的结构缝将电导线引导连接至逆变器,将直流电转变为交流电,经安装在建筑物屋内的配电箱送上电网(并网使用)或直接提供给建筑负载用电。用密封胶对保温光伏板之间的结构缝进行防水密封保温处理,对其中的电导线及接线盒进行防水、防冻、防高温的防护。The vacuum thermal insulation photovoltaic panel is installed on the daylighting surface of the outer wall of the building by bonding and anchoring. The solar panels on each thermal insulation photovoltaic panel have independent positive and negative current leads, and the electrical conductors and junction boxes are arranged in the wire groove holes located on the side wall of the thermal insulation photovoltaic panel in the length direction. During installation, connect the electric wires of each thermal insulation photovoltaic panel through the junction box for circuit connection combination (series or parallel circuit connection), and then use the structural seam between each thermal insulation photovoltaic panel to guide and connect the electrical wires to the inverter. Convert direct current into alternating current, and send it to the grid (connected to the grid) through the distribution box installed in the building or directly provide electricity to the building load. Use sealant to waterproof, seal and heat-insulate the structural joints between thermal insulation photovoltaic panels, and protect the electrical wires and junction boxes among them from waterproof, antifreeze, and high temperature protection.

以上所述的实施例仅仅是对本发明的优选实施方式进行描述,并非对本发明的范围进行限定,在不脱离本发明设计精神的前提下,本领域普通技术人员对本发明的技术方案作出的各种变形和改进,均应落入本发明权利要求书确定的保护范围内。The above-mentioned embodiments are only descriptions of preferred implementations of the present invention, and are not intended to limit the scope of the present invention. Variations and improvements should fall within the scope of protection defined by the claims of the present invention.

Claims (9)

1. a vacuum thermal insulation photovoltaic decoration integrated board, is characterized in that: described integrated board is layer structure, comprises insulation layer, enhancement Layer and photovoltaic decorative layer from the inside to the outside successively, and described insulation layer is the ultra-thin vacuum thermal insulation plate of STP;
Described photovoltaic decorative layer comprises flexible thin-film battery assembly, rete and dope layer from the inside to the outside successively;
Described rete is fluorine-containing TPT polyester film or ethene-TFE copolymer film; Described dope layer is that nano level anti-fouling and self-cleaning paint forms by particle diameter.
2. vacuum thermal insulation photovoltaic decoration integrated board according to claim 1, is characterized in that: the ultra-thin vacuum thermal insulation plate thickness of described STP is 10 ~ 30mm, by waterproof roll sealed envelope.
3. vacuum thermal insulation photovoltaic decoration integrated board according to claim 2, it is characterized in that: described flexible thin-film battery assembly is non-crystalline silicon flexible solar hull cell, copper indium potassium selenium thin-film solar cells, cadmium telluride diaphragm solar battery, dye-sensitized cell or organic thin film cells; Described thicknesses of layers is 250 μm.
4. vacuum thermal insulation photovoltaic decoration integrated board according to claim 3, is characterized in that: described enhancement Layer is cement pressure plate or calcium silicate board, the thickness of described enhancement Layer is 3 ~ 5mm, and its modulus of elasticity is consistent with described insulation layer.
5. vacuum thermal insulation photovoltaic decoration integrated board according to claim 4, is characterized in that: described anti-fouling and self-cleaning coating is nanoscale organosilicon-modified acrylic coating or nanoscale fluorocarbon coating, and thickness is 30 ~ 70 μm.
6. vacuum thermal insulation photovoltaic decoration integrated board according to claim 5, it is characterized in that: described waterproof roll is polymer cement mortar macromolecular compounded waterproof material, be composited by tire base and polymer cement mortar, thickness is 1.5 ~ 2.5mm, and described tire base is the composite felt of polyester-cotton blend non-woven fabrics and glass fiber reticular cloth.
7. vacuum thermal insulation photovoltaic decoration integrated board according to claim 6, it is characterized in that: described insulation layer and enhancement Layer pass through together with polymer cement mortar adhesives, described enhancement Layer and photovoltaic decorative layer are bonded together by fire-type polymeric binder, and described fire-type polymeric binder is western card one pack system high modulus polyurethane sealant.
8. prepare a method for the vacuum thermal insulation photovoltaic decoration integrated board described in above-mentioned any claim, it is characterized in that: comprise the steps:
(1) preparation of insulation layer: with waterproof roll by described warming plate sealed envelope, the thickness of described insulation layer is 10 ~ 30mm;
(2) preparation of enhancement Layer: calcium silicate board or the cement pressure plate of selecting 3 ~ 5mm, carries out waterproof and resistance to deformation process to it;
(3) preparation of photovoltaic decorative layer: seal up TPT polyester film or ethene-TFE copolymer rete in the surface coverage of described flexible thin-film battery assembly, and nanoscale organic silicon acrylic coating or the nanoscale fluorocarbon coating at the outer application of described TPT polyester film or ethene-TFE copolymer rete with anti-pollution function;
(4) adopt polymer cement mortar adhesives through the described insulation layer of waterproof roll sealed envelope and described enhancement Layer;
(5) western card one pack system high modulus polyurethane sealant is adopted to bond described enhancement Layer and described photovoltaic decorative layer;
(6) encapsulation is merged: stack gradually according to the order of flexible thin film photovoltaic's battery component, western card one pack system high modulus polyurethane sealant, calcium silicate board or water pressure plate, polymer cement mortar adhesive and warming plate, through roll-in and autoclave process, make each layer assembly close adhesion, obtain product.
9. method according to claim 8, is characterized in that:
The preparation method of described waterproof roll is: evenly applied by polymer cement mortar by mechanical calendering formation technology, roll both sides in glass fiber reinforcement polyester-cotton blend non-woven fabrics, flexible polymer cement mortar is spread evenly across the both sides of described glass fiber reinforcement polyester-cotton blend non-woven fabrics tire base by machine-processed scraper plate, form the waterproof roll of wide 1.2 meters, the waterproof roll made is carried out drying and maintenance;
The oven dry of described waterproof roll and maintenance process are: the waterproof roll made adopts the Hot air blast device auto-drying in production line, reach polymer mortar initial set, waterproof roll after rolling, under the interior temperature of 5 ~ 38 DEG C, natural drying maintenance is for subsequent use after 28 days;
Waterproof and the resistance to deformation processing method of described enhancement Layer are: at the external coating acid-organosilicon crylic acid water-repellent paint of described enhancement Layer;
Described calcium silicate board is matrix material with cement, is equipped with natural fiber and strengthens, through shaping, pressurization, high-temperature steam curing process and making;
Described cement pressure plate is with natural fiber and cement for raw material, forms through slurrying, shaping, cutting, pressurization, maintenance;
The production method of described flexible thin-film battery assembly comprises: hull cell volume to volume is produced, cell piece is assembled, photovoltaic component encapsulating;
Described polymer cement mortar adhesive is stirred by cement, aggregate and the organic polymer that is dispersed in water to form.
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CN106639212A (en) * 2014-07-18 2017-05-10 张家港市盛港新型建材科技有限公司 Fireproof and environment-friendly integrated board and manufacturing method thereof
CN104675042A (en) * 2014-12-26 2015-06-03 高俊丽 Manufacturing method of vacuum thermal-insulation and decoration integrated board
CN104912213B (en) * 2015-06-16 2018-09-28 建研科技股份有限公司 Vacuum heat insulation composite board and preparation method for preparing thin plastering system by using same
CN107542188A (en) * 2017-08-25 2018-01-05 绵阳鹏志远科技有限公司 A kind of wall body structure for computer room
CN114068744A (en) * 2021-12-20 2022-02-18 徐州洋海清洁能源科技研究院有限公司 Photovoltaic module with heat preservation function
CN116714342A (en) * 2023-06-30 2023-09-08 浙江乐邦节能科技有限公司 A kind of metal sheet STP vacuum insulation sandwich insulation decorative board technology

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101964398A (en) * 2010-10-11 2011-02-02 福建钧石能源有限公司 Flexible thin film solar cell and manufacturing method thereof
CN102097591A (en) * 2010-11-16 2011-06-15 福建钧石能源有限公司 Flexible thin film solar cell
CN202248591U (en) * 2011-09-09 2012-05-30 上海陆道工程设计管理有限公司 Solar building material
CN203475748U (en) * 2013-08-22 2014-03-12 烟台斯坦普精工建设有限公司 Vacuum heat-insulation heat-preservation photovoltaic decoration integrated board

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITTO20070633A1 (en) * 2007-09-10 2009-03-11 Isolpack S P A INSULATING PANEL FOR BUILDING EQUIPPED WITH AN AUXILIARY UNIT, IN PARTICULAR A PHOTOVOLTAIC UNIT, AND OF PERFECT MEDIA FOR THE SUPPORT AND THE HOLDING OF THE AUXILIARY UNIT.

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101964398A (en) * 2010-10-11 2011-02-02 福建钧石能源有限公司 Flexible thin film solar cell and manufacturing method thereof
CN102097591A (en) * 2010-11-16 2011-06-15 福建钧石能源有限公司 Flexible thin film solar cell
CN202248591U (en) * 2011-09-09 2012-05-30 上海陆道工程设计管理有限公司 Solar building material
CN203475748U (en) * 2013-08-22 2014-03-12 烟台斯坦普精工建设有限公司 Vacuum heat-insulation heat-preservation photovoltaic decoration integrated board

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