CN103422642B - A kind of outer wall flexible photovoltaic decoration wall material and preparation method thereof - Google Patents
A kind of outer wall flexible photovoltaic decoration wall material and preparation method thereof Download PDFInfo
- Publication number
- CN103422642B CN103422642B CN201310368526.0A CN201310368526A CN103422642B CN 103422642 B CN103422642 B CN 103422642B CN 201310368526 A CN201310368526 A CN 201310368526A CN 103422642 B CN103422642 B CN 103422642B
- Authority
- CN
- China
- Prior art keywords
- layer
- flexible
- film
- flame
- photovoltaic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000463 material Substances 0.000 title claims abstract description 70
- 238000005034 decoration Methods 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000003063 flame retardant Substances 0.000 claims abstract description 38
- 239000000758 substrate Substances 0.000 claims abstract description 34
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000011230 binding agent Substances 0.000 claims abstract description 24
- 239000010409 thin film Substances 0.000 claims abstract description 22
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 19
- 239000000853 adhesive Substances 0.000 claims abstract description 17
- 239000011414 polymer cement Substances 0.000 claims abstract description 15
- 239000004576 sand Substances 0.000 claims abstract description 13
- 239000011152 fibreglass Substances 0.000 claims abstract description 12
- 238000000926 separation method Methods 0.000 claims abstract description 7
- 239000010410 layer Substances 0.000 claims description 61
- 239000010408 film Substances 0.000 claims description 41
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 239000002904 solvent Substances 0.000 claims description 19
- 239000003431 cross linking reagent Substances 0.000 claims description 17
- 229910052710 silicon Inorganic materials 0.000 claims description 17
- 239000010703 silicon Substances 0.000 claims description 17
- 230000004888 barrier function Effects 0.000 claims description 16
- 239000002131 composite material Substances 0.000 claims description 16
- 238000000576 coating method Methods 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 14
- 239000012757 flame retardant agent Substances 0.000 claims description 14
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 14
- 239000000347 magnesium hydroxide Substances 0.000 claims description 14
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 13
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 13
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 13
- 239000002585 base Substances 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 210000004027 cell Anatomy 0.000 claims description 12
- 239000004568 cement Substances 0.000 claims description 12
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 11
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 239000011083 cement mortar Substances 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000003365 glass fiber Substances 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 7
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 6
- 210000003850 cellular structure Anatomy 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000011241 protective layer Substances 0.000 claims description 6
- 239000010453 quartz Substances 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 6
- 238000004513 sizing Methods 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- 230000001070 adhesive effect Effects 0.000 claims description 5
- 229910021419 crystalline silicon Inorganic materials 0.000 claims description 5
- 239000000975 dye Substances 0.000 claims description 5
- 239000012188 paraffin wax Substances 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 229920006397 acrylic thermoplastic Polymers 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 4
- 238000004079 fireproofing Methods 0.000 claims description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 4
- 239000011433 polymer cement mortar Substances 0.000 claims description 4
- 239000006004 Quartz sand Substances 0.000 claims description 3
- 239000002390 adhesive tape Substances 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 230000008021 deposition Effects 0.000 claims description 3
- 238000005538 encapsulation Methods 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- 238000010030 laminating Methods 0.000 claims description 3
- 238000012423 maintenance Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 229920006267 polyester film Polymers 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 238000005096 rolling process Methods 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 229920002994 synthetic fiber Polymers 0.000 claims description 3
- 229920002799 BoPET Polymers 0.000 claims description 2
- JHXCINJSAAFBDH-UHFFFAOYSA-N [Ca].O[Si](O)(O)O Chemical compound [Ca].O[Si](O)(O)O JHXCINJSAAFBDH-UHFFFAOYSA-N 0.000 claims description 2
- GGKWFDKOOQELAU-UHFFFAOYSA-N [K].[Se].[In].[Cu] Chemical compound [K].[Se].[In].[Cu] GGKWFDKOOQELAU-UHFFFAOYSA-N 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 125000001153 fluoro group Chemical group F* 0.000 claims description 2
- 150000002632 lipids Chemical class 0.000 claims description 2
- 239000004570 mortar (masonry) Substances 0.000 claims description 2
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims description 2
- AHJKRLASYNVKDZ-UHFFFAOYSA-N DDD Chemical compound C=1C=C(Cl)C=CC=1C(C(Cl)Cl)C1=CC=C(Cl)C=C1 AHJKRLASYNVKDZ-UHFFFAOYSA-N 0.000 claims 2
- 229920002125 Sokalan® Polymers 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 239000004745 nonwoven fabric Substances 0.000 claims 1
- 239000004584 polyacrylic acid Substances 0.000 claims 1
- XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 6
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 238000009413 insulation Methods 0.000 description 7
- 238000011161 development Methods 0.000 description 6
- 230000018109 developmental process Effects 0.000 description 6
- 238000004017 vitrification Methods 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 238000009434 installation Methods 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 4
- 230000005622 photoelectricity Effects 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- -1 25 parts Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000013084 building-integrated photovoltaic technology Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 239000002803 fossil fuel Substances 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- 125000003473 lipid group Chemical group 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 230000001172 regenerating effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- BSZXAFXFTLXUFV-UHFFFAOYSA-N 1-phenylethylbenzene Chemical compound C=1C=CC=CC=1C(C)C1=CC=CC=C1 BSZXAFXFTLXUFV-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- MARUHZGHZWCEQU-UHFFFAOYSA-N 5-phenyl-2h-tetrazole Chemical compound C1=CC=CC=C1C1=NNN=N1 MARUHZGHZWCEQU-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ARUZPCPABCNKIX-UHFFFAOYSA-N [Cu].[K].[In] Chemical compound [Cu].[K].[In] ARUZPCPABCNKIX-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229920000891 common polymer Polymers 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- QHSJIZLJUFMIFP-UHFFFAOYSA-N ethene;1,1,2,2-tetrafluoroethene Chemical compound C=C.FC(F)=C(F)F QHSJIZLJUFMIFP-UHFFFAOYSA-N 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 210000003195 fascia Anatomy 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000002960 lipid emulsion Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000013082 photovoltaic technology Methods 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B10/00—Integration of renewable energy sources in buildings
- Y02B10/10—Photovoltaic [PV]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Laminated Bodies (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a kind of flame retardant type outer wall flexible photovoltaic decoration wall material and preparation method thereof, formed by flexible substrate and photovoltaic decorative layer two parts, described flexible substrate is layer structure, comprise successively from the bottom to top: separation layer, gum layer, lower flame-retardant polymer cement sand bed, high-ductility fiberglass reinforced fire retardant nonwoven tire base and upper flame-retardant polymer cement sand bed, five-layer structure is fixed to be integrated. Described photovoltaic decorative layer comprises flexible thin-film battery assembly, rete and dope layer from the bottom to top successively. Described flexible substrate and photovoltaic decorative layer are mutually bonding by flame-proof type polyalcohol binding agent. The alternative traditional photoelectric curtain wall system of outer wall flexible photovoltaic decoration wall material of the present invention, do not need to adopt all kinds of metal joists, only soft type photovoltaic wall material is bonded on exterior wall lighting surface by self-adhesive, not only saving of labor but also material-saving, greatly shortened construction period and reduced construction cost.
Description
Technical field
The present invention relates to photoelectricity building field, be specifically related to a kind of outer wall flexible photovoltaic decoration wall material and preparation method thereof, described outsideWall flexible photovoltaic decoration wall material has photovoltaic generation, fire-proof and water-proof damp proof insulation concurrently, strengthens the multiple use functions such as cracking resistance, building decoration,Be applied to the photoelectricity building of newly-built and existing building reducing energy consumption, realize and build the energy-efficient and required electric power of generating power for their own use.
Background technology
Building a harmonious society, realize social development has become the basic state of China's Development of Morden with the harmony between natural environmentPlan. Seriously deficient at global resources, the energy, under the severe situation that environment, weather go from bad to worse, China mainly relies on biography at presentProduction of energy and the consumption structure of the fossil fuel of system, seem to be difficult to continue health, the coordination that remains economic, social and can holdSupervention exhibition, therefore development is clean, green regenerative energy sources and relevant system integration technology are working as of energy industry development efficientlyBeing engaged in anxious, is also the unique selection that solves resource, the energy, natural environment and climate problem. At the World Developed Countries such as Europe, the United States, day,The core of energy policy is that the green continuable, competitive and safety supply of development including solar energy can at presentThe renewable sources of energy, progressively to reduce the ratio of the fossil fuels such as coal, oil, natural gas, the regenerative resources such as the solar energy of China,Resource is very abundant, although through some exploitations, integral level is still very low, in development speed and level far below mostlyNumber developed country.
China is wideling popularize the work of BIPV, but this work also only only limits to the generating of solar energy house top at present,Account for the long-pending external wall over half of building surface and but do not obtain effective exploitation, can not meet market so far away to photovoltaic generationActive demand and building photovoltaic generation scale and benefit. The reason that causes the exploitation of external wall photovoltaic generation to lag behind mainly contains ChinaSeveral aspects such as the limitation of the feature of building and traditional photoelectricity building. Current China's building town and country present following feature: oneThat ratio high-rise, high-rise building obviously increases; The 2nd, adopt in a large number low-intensity, inflammable organic the exterior wall external insulationMaterial; The 3rd, require strict all the more to waterproof fireproofing, cracking resistance, slip-off preventing and the aging-resistant of insulation and ornament materials; The 4th,The combination of photovoltaic cell component and building exterior wall face also only limits to the demonstration projects such as building glass curtain wall, its complex structure, and cost is highExpensive, be difficult to large area and implement.
Part Study person has attempted to develop a kind of photovoltaic generation product used for building exterior wall that is applicable to, and China Patent No. isA kind of solar energy power generating exterior wall finish plate and Side fascia are disclosed in the utility model patent description of CN201354501Y;China Patent No. is in the utility model patent description of CN202263950U, to disclose one to have external wall or finialThe photovoltaic power-generating composite board of function. In above-mentioned two patents, in photovoltaic power-generating composite board, all adopt as the substrate of photovoltaic cell bracketBe the hard plate materials such as metal, cement, plastics, deformation modulus and metope organic insulation material are inconsistent, very easily produce because of protectThe crack that adiabator and the inhomogeneous deformation of exterior wall photovoltaic panel produce.
China Patent No. is to disclose a kind of solar energy ceramic tile in the patent of invention description of CN200720111588.3. Chinese patentNumber can power generation solar ceramic tile for disclosing one in the utility model patent description of CN201738511U, above two inventionsThe form that all adopts metal mechanical erection, complex process is loaded down with trivial details, and needs to adopt expensive curtain skeleton.
Exploitation meets the requirement of external thermal insulation system system, have flexible light weight, fire-proof and water-proof, safe and reliable, strengthen anticracking,Photovoltaic generation, building decoration several functions, and can batch production, standardized production, quality controllable flexible photovoltaic finishing material toolSignificant.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of outer wall flexible photovoltaic decoration wall material, and it has photovoltaic generation concurrently, fire prevention is anti-The multiple use functions such as water, enhancing cracking resistance, building decoration.
A kind of outer wall flexible photovoltaic decoration wall material, is made up of flexible substrate and photovoltaic decorative layer two parts, and described flexible substrate is layerShape structure, comprises from the bottom to top successively: separation layer, gum layer, lower flame-retardant polymer cement sand bed, high-ductility glass strengthen resistanceCombustion nonwoven tire base and upper flame-retardant polymer cement sand bed, five-layer structure is fixed to be integrated.
Described flexible substrate comprises gum layer and separation layer, when construction and installation, only need take off flexible photovoltaic decoration wall material bottom everyFrom film, wall material directly can be sticked on wall face.
Outer wall flexible photovoltaic decoration wall material of the present invention, wherein said photovoltaic decorative layer comprises fexible film from the inside to the outside successivelyBattery component, rete and dope layer.
Outer wall flexible photovoltaic decoration wall material of the present invention, wherein said upper flame-retardant polymer cement sand bed and lower fire-retardant polymerizationThing cement mortar layer thickness is 1.5mm～4mm, and forms by the raw material of following weight portion: general silicon 42.5 cement 12～17Part, 40～45 parts of quartz sands, at least 18～23 parts of Silicone acrylic emulsions-5 DEG C below of vitrification point, 17～25 parts, water, answersClose 4～8 parts of fire retardants.
Outer wall flexible photovoltaic decoration wall material of the present invention, wherein said composite flame-retardant agent is by magnesium hydroxide, aluminium hydroxide, 52Number chlorinated paraffin wax and antimony oxide mix, and mass ratio is magnesium hydroxide: aluminium hydroxide: No. 52 chlorinated paraffin waxs: three oxidationsTwo antimony=2:4:2:3.
Outer wall flexible photovoltaic decoration wall material of the present invention, wherein said composite flame-retardant agent is by aluminium hydroxide, magnesium hydroxide, tenBromine diphenylethane and antimony oxide mix, and mass ratio is aluminium hydroxide: magnesium hydroxide: TDE: three oxidationsTwo antimony=4:2:3:3.
Outer wall flexible photovoltaic decoration wall material of the present invention, the barrier film in wherein said flexible substrate for easily take off from PE film,Any one in PET film, PP barrier film, PA barrier film, silicone oil paper film or brown paper; Described barrier film thickness be 0.2mm～ 0.5mm；
Described gum layer is in self-adhesive, colloidal silicic acid calcium creep self-adhesive, polyacrylate self-adhesive by powerful buttress rubberAny one form, described gum layer thickness is 0.5mm～3mm;
The peace that described high-ductility fiberglass reinforced fire retardant nonwoven tire base adopts alkali-resistant glass fibre to strengthen is spun fire resistance fibre nonwoven, 4080Fabric nonwoven cloth, bar synthetic fibre strengthen any one in nonwoven; Described high-ductility glass fibre strengthen nonwoven thickness be 0.5mm～1mm, weight is 120～180g/m2。
Outer wall flexible photovoltaic decoration wall material of the present invention, wherein said flexible thin-film battery assembly is flexible at plastics etc.The hull cell that adopts deposition of transparent conductive film to prepare in flexible substrate is non-crystalline silicon flexible solar hull cell, copper indium potassium seleniumThin-film solar cells, cadmium telluride diaphragm solar battery, dye-sensitized cell or organic film battery;
Described rete is fluorine-containing TPT polyester film or ethene-TFE copolymer film, and thickness is 250um, mainly rise waterproof,The effect of isolation;
Described dope layer dyes function by having self-cleaning anti-pollution, and particle diameter is that nano level organic silicon acrylic coating or fluorocarbon coating are coated withCover formation, thickness is 30～70um, mainly plays self-cleaning, anti-pollution, and this coating can effectively be avoided the dirt such as dust, hazeDye the photoelectric transformation efficiency of thing reduction solar cell.
Outer wall flexible photovoltaic decoration wall material of the present invention, is provided with both positive and negative polarity on wherein said flexible thin-film battery assembly and leadsLine, described wire outside uses marine glue as protective layer, and outside described protective layer, is wound around the adhesive tape with waterproof fireproofing function.
Outer wall flexible photovoltaic decoration wall material of the present invention, adopts binding agent between wherein said flexible substrate and photovoltaic decorative layerBonding is fixing, and described binding agent is the fast hard binding agent of flame-proof type polyalcohol, and its composition by following mass percent forms: organicSilica acrylic acid lipid emulsion 55～85%, organic phosphates nitrogen based flame retardant 2.5～8.5%, crosslinking agent 10～25%, solvent 2～15%;Described adhesive thickness is 1～2mm; Wherein said crosslinking agent is silicone based or acrylics crosslinking agent, and described solvent is alcoholKind solvent, or ether solvent or lipid solvent.
A preparation method for outer wall flexible photovoltaic decoration wall material, comprises the steps:
(1) preparation of flexible substrate: under normal temperature state, by cement, quartz sand, acrylic emulsion, composite flame-retardant agent,Water philosophy adds mixing apparatus evenly to mix, and obtains flame-proof type polyalcohol cement mortar sizing material;
On proper automation production line, flame-proof type polyalcohol cement mortar sizing material is evenly coated on to described height by machine-processed scraper plateThe upper and lower surface of tough fiberglass reinforced fire retardant nonwoven, then thermal cycle blowing device auto-drying in production line, make polymer sandSlurry reaches rolling after initial set;
Then under the indoor temperature of 5～38 DEG C, deposit, natural drying maintenance reaches 28 days; Treat coiled material surface flame-proof type polyalcoholStrength of cement mortar reaches after requirement completely, and on proper automation production line, carry out gum, cover barrier film, excision forming, pointDo not make as required the soft of 400mm × 600mm, 600mm × 800mm, 1220mm × 2440mm or 600mm × 1200mmProperty sheet material products is for subsequent use;
(2) preparation of photovoltaic decorative layer: dye thering is self-cleaning anti-pollution through the flexible thin-film battery assembly front surface coated of rete encapsulationNanoscale organic silicon acrylic coating or the fluorocarbon coating of function, and be processed into the chi that meets the specification requirement of described flexible photovoltaic wall materialVery little;
(3) adopt the fast hard binding agent of flame-proof type polyalcohol that described flexible thin-film battery assembly bottom adhesive is arrived to described flexible substrateSurface;
(4) merge encapsulation: according to the fast hard binding agent of fexible film photovoltaic cell component, flame-proof type polyalcohol and flexible substrateOrder stacks gradually, and passes through roll-in and vacuumizes processing at laminating machine, makes each layer assembly close adhesion, forms integrative-structure,Obtain product.
Outer wall flexible photovoltaic decoration wall material difference from prior art of the present invention is:
The present invention merges the flexible thin-film solar photovoltaic cell components such as traditional decoration wall material and non-crystalline silicon, makes oneCan External Wall prevent fires, waterproof and decoration, can carry out again the functional Wall of building component of photovoltaic generation; Because exterior wall is softThe weight of property photovoltaic decoration wall material is only the 1/5-1/8 of common outdoor tile and stone material, and pliability meets external thermal insulation systemTo successively discharging the cracking resistance design concept of stress. Product is combined with construction wall by the bonding mode of similar tack roofing tile,Thereby realize on external wall heat insulation system large area, in flakes solar photovoltaic battery component be installed; By Building Fire Protection,Waterproof and decorative building material and photovoltaic technology integrated fusion, significantly reduced photoelectricity building construction cost.
Domestic building with good conditionsi all requires to carry out external wall thermal insulation with all kinds of lightweight organic foam materials at present, in such buildingOn carry out decoration of exterior wall and photovoltaic generation, need special weight, pliability, splitting resistance, water proofing property and the resistance of considering exterior materialThe physico mechanical characteristics such as combustion property. The present invention has given full play to the fexible films such as polymer-modified cement-based flexible wall material and non-crystalline silicon tooCan the photovoltaic cell component total thin light weight of body of sun, pliable and tough can be around, fire-proof and water-proof, long-lived advantage; The exterior wall of developingThe direct alternative traditional photoelectric curtain wall system of flexible photovoltaic decoration wall material, does not need to adopt all kinds of metal joists, only uses soft type photovoltaicThe self-adhesive at the wall material back side is bonded on wall face, and not only saving of labor but also material-saving have greatly shortened construction period and reduced constructionCost, for the extensive enforcement of BIPV provides a technology path of getting twice the result with half the effort.
Below in conjunction with accompanying drawing, outer wall flexible photovoltaic decoration wall material of the present invention is described further.
Brief description of the drawings
Fig. 1 is the structural representation of the outer wall flexible photovoltaic decoration wall material under one embodiment of the present invention.
Detailed description of the invention
Embodiment 1
As shown in Figure 1, a kind of outer wall flexible photovoltaic decoration wall material, is made up of flexible substrate 1 and photovoltaic decorative layer 6 two parts,Described flexible substrate 1 is layer structure, comprises successively from the bottom to top: separation layer 7, gum layer 8, lower flame-retardant polymer cement bonded sandSlurry layer 9, high-ductility fiberglass reinforced fire retardant nonwoven tire base 10 and upper flame-retardant polymer cement sand bed 11, five-layer structure is fixed is oneBody. Described photovoltaic decorative layer 6 comprises flexible thin-film battery assembly 3, rete 4 and dope layer 5 from the inside to the outside successively; Described upper resistanceCombustion cement mortar with polymer layer 11 and lower flame-retardant polymer cement sand bed 9 thickness are 1.5mm, and former by following weight portionMaterial composition: 12 parts of general silicon 42.5 cement, 40 parts of quartz sands, at least 18 parts of Silicone acrylic emulsions below-5 DEG C of vitrification point,17 parts, water, 4 parts of composite flame-retardant agents. Described composite flame-retardant agent is magnesium hydroxide by mass ratio: aluminium hydroxide: No. 52 chlorination stonesThe raw material of wax: antimony oxide=2:4:2:3 mixes.
Barrier film 7 in described flexible substrate is for easily taking off the film from PE, and thickness is 0.2mm; Described gum layer 8 is by powerful isobutylRubber series self-adhesive forms, and described gum layer 8 thickness are 0.5mm; Described high-ductility fiberglass reinforced fire retardant nonwoven tire base 10 adoptsThe peace that alkali-resistant glass fibre strengthens is spun fire resistance fibre nonwoven, and thickness is 0.5mm, and weight is 120g/m2。
Described flexible thin-film battery assembly 3 is in the flexible flexible substrate such as plastics, to adopt prepared by deposition of transparent conductive film thinFilm battery is non-crystalline silicon flexible solar hull cell; Described rete 4 is fluorine-containing TPT polyester film, and thickness is 250um; InstituteState dope layer 5 and dye function by having self-cleaning anti-pollution, particle diameter is that nano level organic silicon acrylic coating applies and forms, and thickness is30um. Between described flexible substrate 1 and photovoltaic decorative layer 6, adopt binding agent 2 bondings fixing, described binding agent 2 is flame retardant typeThe fast hard binding agent of polymer, its one-tenth by following mass percent is grouped into: organosilicon acrylic fat class emulsion 85%, organophosphorClass nitrogen based flame retardant 2.5%, crosslinking agent 10%, solvent 2.5%, wherein said crosslinking agent is silicone based crosslinking agent, described solventFor alcohols solvent, described tack coat 2 thickness are 1mm.
On described flexible thin-film battery assembly 3, be provided with both positive and negative polarity wire, described wire outer surface uses marine glue as protective layer, andOutside described protective layer, be wound around the adhesive tape with waterproof fireproofing function.
Embodiment 2
Described upper flame-retardant polymer cement sand bed 11 and lower flame-retardant polymer cement sand bed 9 thickness are 4mm, and by as followsThe raw material composition of weight portion: 17 parts of general silicon 42.5 cement, 45 parts of quartz sands, vitrification point is the silicon third below-5 DEG C at least23 parts of emulsions, 25 parts, water, 8 parts of composite flame-retardant agents. Described composite flame-retardant agent is by aluminium hydroxide, magnesium hydroxide, decabrominated diphenyEthane and antimony oxide mix, and mass ratio is aluminium hydroxide: magnesium hydroxide: TDE: antimony oxide=4:2:3:3. Barrier film 7 in described flexible substrate is PP barrier film, and thickness is 0.5mm; Described gum layer 8 is by colloidal silicic acidCalcium creep self-adhesive forms, and described gum layer 8 thickness are 3mm; Described high-ductility fiberglass reinforced fire retardant nonwoven tire base 10 adopts resistance to4080 fabric nonwoven cloths that alkali containing glass fibre strengthens; It is 1mm that described high-ductility glass fibre strengthens nonwoven 10 thickness, and weight is180g/m2。
Described flexible thin-film battery assembly 3 is copper indium potassium selenium thin-film solar cells; Described rete 4 is that ethene-tetrafluoroethene is commonPolymers film; Described dope layer 5 fluorocarbon coatings apply and form, and thickness is 70um. Described flexible substrate 1 and photovoltaic decorative layer 6 itBetween adopt binding agent bonding fixing, described binding agent 2 be flame-proof type polyalcohol binding agent firmly soon, it is by following mass percentOne-tenth is grouped into: organosilicon acrylic fat class emulsion 55%, and organic phosphates nitrogen based flame retardant 8.5%, crosslinking agent 25%, solvent 11.5%,Wherein said crosslinking agent is acrylics crosslinking agent, and described solvent is ether solvent. Described tack coat 2 thickness are 2mm. ItsHe is with embodiment 1.
Embodiment 3
Described upper flame-retardant polymer cement sand bed 11 and lower flame-retardant polymer cement sand bed 9 thickness are 2mm, and by as followsThe raw material composition of weight portion: 15 parts of general silicon 42.5 cement, 42 parts of quartz sands, vitrification point is the silicon third below-5 DEG C at least20 parts of emulsions, 20 parts, water, 6 parts of composite flame-retardant agents. Described composite flame-retardant agent is magnesium hydroxide by mass ratio: aluminium hydroxide:The raw material of 52# chlorinated paraffin wax: antimony oxide=2:4:2:3 forms.
Barrier film 7 in described flexible substrate is PA barrier film; Described barrier film 7 thickness are 0.3mm; Described gum layer 8 byPolyacrylate self-adhesive forms, and described gum layer 8 thickness are 2mm; Described high-ductility fiberglass reinforced fire retardant nonwoven tire base 10Adopt the bar synthetic fibre that alkali-resistant glass fibre strengthens to strengthen nonwoven, thickness is 0.8mm, and weight is 150g/m2。
Described flexible thin-film battery assembly 3 is organic film battery; Described dope layer 5 thickness are 50um. Described flexible substrate 1And between photovoltaic decorative layer 6, adopting binding agent 2 bondings fixing, described binding agent 2 is the fast hard binding agent of flame-proof type polyalcohol, itsOne-tenth by following mass percent is grouped into: organosilicon acrylic fat class emulsion 65%, and organic phosphates nitrogen based flame retardant 5%, crosslinkedAgent 15%, solvent 15%, thickness is 1.5mm, and wherein said crosslinking agent is silicone based crosslinking agent, and described solvent is lipid solvent.Other are with embodiment 1.
Embodiment 4
Described upper flame-retardant polymer cement mortar layer 11 and lower flame-retardant polymer cement sand bed 9 thickness are 3mm, and by as followsThe raw material composition of weight portion: 16 parts of general silicon 42.5 cement, 44 parts of quartz sands, vitrification point is the silicon third below-5 DEG C at least19 parts of emulsions, 18 parts, water, 7 parts of composite flame-retardant agents. Described composite flame-retardant agent is by aluminium hydroxide, magnesium hydroxide, decabrominated diphenyEthane and antimony oxide mix, and mass ratio is aluminium hydroxide: magnesium hydroxide: TDE: antimony oxide=4:2:3:3. Barrier film 7 in described flexible substrate is for easily taking off from silicone oil paper film; Described barrier film 7 thickness are 0.3mm; The described back of the bodyGlue-line 8 is that self-adhesive forms by powerful butyl rubber, and described gum layer 8 thickness are 1.5mm; Described high-ductility fiberglass reinforced fire retardant withoutSpin the peace that cloth tire base 10 adopts alkali-resistant glass fibre to strengthen and spin fire resistance fibre nonwoven, thickness is, 0.9mm, and weight is 160g/m2。
Described flexible thin-film battery assembly 3 is dye-sensitized cell; Described rete 4 is ethene-TFE copolymer film, thickDegree is 250um; Described dope layer 5 is applied and is formed by fluorocarbon coating, and thickness is 60um. Described flexible substrate 1 and photovoltaic are decoratedBetween layer 6, adopt binding agent 2 bondings fixing, described binding agent 2 is the fast hard binding agent of flame-proof type polyalcohol, and it is by following qualityThe one-tenth of percentage is grouped into: organosilicon acrylic fat class emulsion 70%, and organic phosphates nitrogen based flame retardant 8%, crosslinking agent 20%, moltenAgent 2%, wherein said crosslinking agent is acrylics crosslinking agent, and described solvent is lipid solvent, and described tack coat 2 thickness are1.8mm. Other are with embodiment 1.
Embodiment 5
A preparation method for outer wall flexible photovoltaic decoration wall material, comprises the steps:
(1) preparation of flexible substrate 1: under normal temperature state, by cement, quartz sand, acrylic emulsion, composite flame-retardant agent, waterPhilosophy adds mixing apparatus evenly to mix, and obtains flame-proof type polyalcohol cement mortar sizing material. At proper automation production lineUpper, flame-proof type polyalcohol cement mortar sizing material is evenly coated on to described high-ductility fiberglass reinforced fire retardant nonwoven 10 by machine-processed scraper plateUpper and lower surface, then thermal cycle blowing device auto-drying in production line, makes polymer mortar reach rolling after initial set. SoAfter under the indoor temperature of 5～38 DEG C, deposit, natural drying maintenance reaches 28 days. Treat coiled material surface flame-proof type polyalcohol cement mortarIntensity reaches after requirement completely, then on proper automation production line, carry out gum (form gum layer 8), cover barrier film 7, cutBe slit into type, make as required respectively 400mm × 600mm, 600mm × 800mm, 1220mm × 2440mm andThe flexible sheet material goods of 600mm × 1200mm are for subsequent use;
(2) preparation of photovoltaic decorative layer 6: flexible thin-film battery assembly 3 front surface coated that encapsulate through rete 4 are had self-cleaningThe nanoscale organic silicon acrylic coating of anti-pollution function or fluorocarbon coating (form dope layer 5), and be processed into and meet described flexibilityThe size of substrate 1 specification requirement;
(3) adopt the fast hard binding agent of flame-proof type polyalcohol that described flexible thin-film battery assembly 3 bottom adhesive are arrived to described flexible linerThe surface at the end 1;
(4) merge encapsulation: according to fexible film photovoltaic cell component 3, the fast hard binding agent of flame-proof type polyalcohol and flexible substrate 1Order stack gradually, through roll-in and vacuumize processing at laminating machine, make each layer assembly close adhesion, form integrative-structure,Obtain product.
Embodiment 6
Install and construction method:
(1) first cleaning building base course wall. As not reaching decoration of exterior wall engineering base course wall flatness, exterior wall flatness checks and acceptsStandard, need be to metope hanging wire, and with cement mortar screeding;
(2) brushing interfacial agents on metope, interfacial agents is emulsion or the solution containing polyacrylate resinoid, or containing poly-secondEnol resinoid, or emulsion or the solution of polyvinyl alcohol contracting acid resin;
(3) in interfacial agents, locate, and eject bonding control line by actual installation position. According to on-the-spot feature and flexible photovoltaicThe specification of decoration wall material, determines the density of snap the line in length and breadth, smooth vertical and horizontal to guarantee the stickup of wall material;
(4) bore wire guide in the position of every block of wall material, and place therein conduit;
(5), after the separation layer on wall material is peeled off, paving is in building substrate surface. Wall material is pressed from top to bottom, from a left side extremelyRight ceramic tile, the method for attaching of stone material are installed. Meanwhile the contact conductor on wall material is penetrated indoor by conduitIn installation pipe;
(6) in strict accordance with pasting control line examination paving and actual sticky paving wall material, should not occur causing wall material crooked because of cumulative errorsPhenomenon.
(7) use plastics rod from wall material middle part to both sides roll extrusion, deaeration, makes wall material firmly stick on building exterior wall face.
(8) by the contact conductor of introducing in installation pipe within the walls by terminal box corresponding connection mutually, by every outer wall flexible lightThe both positive and negative polarity wire of volt on decoration wall material with draw terminal box and carry out circuit and be connected combination (connection of serial or parallel connection circuit), then generalConnection, to inverter, changes direct current into alternating current, and the distribution box in being arranged on building is served electrical network (grid-connected makingWith) or directly offer building load electricity consumption. Be provided with fluid sealant at exterior wall flexible photovoltaic decoration wall material side seam place and carry out anti-watertightEnvelope insulation is processed, and makes it to reach the requirement of waterproof, antifreeze, anti-high temperature.
Above-described embodiment is described the preferred embodiment of the present invention, not scope of the present invention is carried outLimit, design under the prerequisite of spirit not departing from the present invention, those of ordinary skill in the art make technical scheme of the present inventionVarious distortion and improvement, all should fall in the definite protection domain of the claims in the present invention book.
Claims (10)
1. an outer wall flexible photovoltaic decoration wall material, is characterized in that: by flexible substrate and photovoltaic decorative layer twoPart forms, and described flexible substrate is layer structure, comprises successively from the bottom to top: separation layer, gum layer, underFlame-retardant polymer cement sand bed, high-ductility fiberglass reinforced fire retardant nonwoven tire base and upper flame-retardant polymer cement mortarLayer, five-layer structure is fixed to be integrated.
2. outer wall flexible photovoltaic decoration wall material according to claim 1, is characterized in that: described photovoltaicDecorative layer comprises flexible thin-film battery assembly, rete and dope layer from the inside to the outside successively.
3. outer wall flexible photovoltaic decoration wall material according to claim 1, is characterized in that: described upper resistanceCombustion polymer cement mortar layer and lower flame-retardant polymer cement mortar layer thickness are: 1.5mm～4mm, and byThe raw material composition of following weight portion: 12～17 parts of general silicon 42.5 cement, 40～45 parts of quartz sands, vitrifyingAt least 18～23 parts of Silicone acrylic emulsions below-5 DEG C of temperature, 17～25 parts, water, 4～8 parts of composite flame-retardant agents.
4. outer wall flexible photovoltaic decoration wall material according to claim 3, is characterized in that: described compoundFire retardant is mixed by magnesium hydroxide, aluminium hydroxide, No. 52 chlorinated paraffin waxs and antimony oxide, mass ratioFor magnesium hydroxide: aluminium hydroxide: 52# chlorinated paraffin wax: antimony oxide=2:4:2:3.
5. outer wall flexible photovoltaic decoration wall material according to claim 3, is characterized in that: described compoundFire retardant is mixed by aluminium hydroxide, magnesium hydroxide, TDE and antimony oxide, and mass ratio isAluminium hydroxide: magnesium hydroxide: TDE: antimony oxide=4:2:3:3.
6. according to the outer wall flexible photovoltaic decoration wall material described in claim 4 or 5, it is characterized in that: described inSeparation layer in flexible substrate is for easily taking off from PE film, PET film, PP barrier film, PA barrier film, silicone oil paperAny one in film or brown paper; Described separation layer thickness is 0.2mm～0.5mm;
Described gum layer is self-adhesive, colloidal silicic acid calcium creep self-adhesive, polyacrylic acid by powerful buttress rubberAny one in ester class self-adhesive forms, and described gum layer thickness is 0.5mm～3mm;
The peace that described high-ductility fiberglass reinforced fire retardant nonwoven tire base adopts alkali-resistant glass fibre to strengthen is spun fire resistance fibreNonwoven, 4080 fabric nonwoven cloths, bar synthetic fibre strengthen any one in nonwoven; Described high-ductility glass strengthensFire retardant nonwoven fabric tire base thickness is 0.5mm～1mm, and weight is 120～180g/m2。
7. outer wall flexible photovoltaic decoration wall material according to claim 2, is characterized in that: described flexibilityFilm battery assembly is the thin-film electro that adopts deposition of transparent conductive film to prepare on flexible flexible substrate plasticsPond is non-crystalline silicon flexible solar hull cell, copper indium potassium selenium thin-film solar cells, the Cadimium telluride thin film sunEnergy battery, dye-sensitized cell or organic film battery;
Described rete is fluorine-containing TPT polyester film or ethene-TFE copolymer film, and thickness is 250um;
Described dope layer dyes function by having self-cleaning anti-pollution, and particle diameter is nano level organic silicon acrylic coatingOr fluorocarbon coating coating formation, thickness is 30～70um.
8. outer wall flexible photovoltaic decoration wall material according to claim 2, is characterized in that: described flexibilityOn film battery assembly, be provided with both positive and negative polarity wire, described wire outside uses marine glue as protective layer, and in instituteState the outer adhesive tape with waterproof fireproofing function that is wound around of protective layer.
9. outer wall flexible photovoltaic decoration wall material according to claim 1, is characterized in that: described flexibilityBetween substrate and photovoltaic decorative layer, adopt binding agent bonding fixing, described binding agent is that flame-proof type polyalcohol is fast hard stickyKnot agent, its composition by following mass percent forms: organosilicon acrylic fat class emulsion 55～85%, organicPhosphorus nitrogen based flame retardant 2.5～8.5%, crosslinking agent 10～25%, solvent 2～15%; Described adhesive thicknessBe 1～2mm; Wherein said crosslinking agent is silicone based or acrylics crosslinking agent, and described solvent is alcoholsSolvent, or ether solvent or lipid solvent.
10. a preparation method for any one outer wall flexible photovoltaic decoration wall material in claim 1-9, its spyLevy and be: comprise the steps:
(1) preparation of flexible substrate: under normal temperature state, by general silicon 42.5 cement, quartz sand, silicon thirdEmulsion, composite flame-retardant agent, water add respectively mixing apparatus evenly to mix, and obtain flame-proof type polyalcohol cementMortar sizing material;
On proper automation production line, flame-proof type polyalcohol cement mortar sizing material is even by machine-processed scraper plateBe coated on the upper and lower surface of described high-ductility fiberglass reinforced fire retardant nonwoven tire base, then thermal cycle in production line is blownWind apparatus auto-drying, makes polymer mortar reach rolling after initial set;
Then under the indoor temperature of 5～38 DEG C, deposit, natural drying maintenance reaches 28 days; Treat coiled material surface resistanceCombustion type polymer cement mortar intensity reaches after requirement completely, carries out gum, covers on proper automation production lineBarrier film, excision forming, make as required respectively 400mm × 600mm, 600mm × 800mm,The flexible sheet material goods of 1220mm × 2440mm or 600mm × 1200mm are for subsequent use;
(2) preparation of photovoltaic decorative layer: will have through the flexible thin-film battery assembly front surface coated of rete encapsulationSelf-cleaning anti-pollution dyes nanoscale organic silicon acrylic coating or the fluorocarbon coating of function, and is processed into and meets described flexibilityThe size of photovoltaic decoration wall material specification requirement;
(3) adopt the fast hard binding agent of flame-proof type polyalcohol that described flexible thin-film battery assembly bottom adhesive is arrived to instituteState the surface of flexible substrate;
(4) merge encapsulation: according to the fast hard binding agent of fexible film photovoltaic cell component, flame-proof type polyalcohol andThe order of flexible substrate stacks gradually, and passes through roll-in and vacuumizes processing at laminating machine, makes each layer assembly closely stickyClose, form integrative-structure, obtain product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310368526.0A CN103422642B (en) | 2013-08-22 | 2013-08-22 | A kind of outer wall flexible photovoltaic decoration wall material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310368526.0A CN103422642B (en) | 2013-08-22 | 2013-08-22 | A kind of outer wall flexible photovoltaic decoration wall material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103422642A CN103422642A (en) | 2013-12-04 |
| CN103422642B true CN103422642B (en) | 2016-05-18 |
Family
ID=49647984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310368526.0A Active CN103422642B (en) | 2013-08-22 | 2013-08-22 | A kind of outer wall flexible photovoltaic decoration wall material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103422642B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3934094A1 (en) * | 2020-07-04 | 2022-01-05 | Mitrex Inc. | Building-integrated photovoltaic system |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103938810B (en) * | 2014-03-22 | 2017-03-15 | 烟台斯坦普精工建设有限公司 | A kind of photovoltaic sun shading system and preparation method thereof |
| CN103929120B (en) * | 2014-03-22 | 2016-09-21 | 烟台斯坦普精工建设有限公司 | A kind of external wall photovoltaic generating system and preparation method thereof |
| CN103938811B (en) * | 2014-03-22 | 2017-02-01 | 烟台斯坦普精工建设有限公司 | Photovoltaic awning system and manufacturing method thereof |
| CN103938819B (en) * | 2014-03-22 | 2016-09-07 | 烟台斯坦普精工建设有限公司 | A kind of indoor flame-retardant environmental-protection decorative wall material and preparation method thereof |
| CN104196191B (en) * | 2014-08-28 | 2016-05-04 | 山东省建筑科学研究院 | Decorative Prefabricated Membranes with Textured Paint for Building Exteriors |
| CN105197379A (en) * | 2015-10-30 | 2015-12-30 | 苏州凯康化工科技有限公司 | Water-based paint bucket with oxidation-resistant and dustproof functions |
| CN105236024A (en) * | 2015-10-30 | 2016-01-13 | 苏州凯康化工科技有限公司 | Water-based paint bucket with high-temperature resisting and oxidation preventing functions |
| CN107963843A (en) * | 2017-11-29 | 2018-04-27 | 万卓（江苏）新材料有限公司 | A kind of solar energy porcelain tendre ornament materials and preparation method thereof |
| CN111139987A (en) * | 2018-11-02 | 2020-05-12 | 光之科技(北京)有限公司 | Surface layer material, photovoltaic building material and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201354501Y (en) * | 2009-01-16 | 2009-12-02 | 广州绿欣然环保节能科技发展有限公司 | Solar photovoltaic power generation exterior wall decorative panels and exterior wall panels |
| CN102086663A (en) * | 2010-12-17 | 2011-06-08 | 上海市第四建筑有限公司 | Building outer wall heat insulation flame-retardant belt and construction method thereof |
| CN202324421U (en) * | 2011-11-24 | 2012-07-11 | 深圳市创益科技发展有限公司 | Photovoltaic building component of solar battery |
| CN102797297A (en) * | 2012-08-24 | 2012-11-28 | 北京立高防水工程有限公司 | Solar power generation composite waterproof self-adhesive coiled material and construction method thereof |
| CN203452308U (en) * | 2013-08-22 | 2014-02-26 | 烟台斯坦普精工建设有限公司 | Outer wall flexible photovoltaic decorating wall material |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITTO20070633A1 (en) * | 2007-09-10 | 2009-03-11 | Isolpack S P A | INSULATING PANEL FOR BUILDING EQUIPPED WITH AN AUXILIARY UNIT, IN PARTICULAR A PHOTOVOLTAIC UNIT, AND OF PERFECT MEDIA FOR THE SUPPORT AND THE HOLDING OF THE AUXILIARY UNIT. |
-
2013
- 2013-08-22 CN CN201310368526.0A patent/CN103422642B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201354501Y (en) * | 2009-01-16 | 2009-12-02 | 广州绿欣然环保节能科技发展有限公司 | Solar photovoltaic power generation exterior wall decorative panels and exterior wall panels |
| CN102086663A (en) * | 2010-12-17 | 2011-06-08 | 上海市第四建筑有限公司 | Building outer wall heat insulation flame-retardant belt and construction method thereof |
| CN202324421U (en) * | 2011-11-24 | 2012-07-11 | 深圳市创益科技发展有限公司 | Photovoltaic building component of solar battery |
| CN102797297A (en) * | 2012-08-24 | 2012-11-28 | 北京立高防水工程有限公司 | Solar power generation composite waterproof self-adhesive coiled material and construction method thereof |
| CN203452308U (en) * | 2013-08-22 | 2014-02-26 | 烟台斯坦普精工建设有限公司 | Outer wall flexible photovoltaic decorating wall material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3934094A1 (en) * | 2020-07-04 | 2022-01-05 | Mitrex Inc. | Building-integrated photovoltaic system |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103422642A (en) | 2013-12-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103422642B (en) | A kind of outer wall flexible photovoltaic decoration wall material and preparation method thereof | |
| CN103410279B (en) | A kind of insulation photovoltaic tile and preparation method thereof | |
| CN103426957B (en) | A kind of metal photovoltaic tile and preparation method thereof | |
| CN103413847B (en) | A kind of photovoltaic tile on roof and preparation method thereof | |
| CN103441168B (en) | A kind of flexible roof photovoltaic tile and preparation method thereof | |
| CN208738279U (en) | A kind of photovoltaic shoe plate | |
| CN103410289B (en) | A kind of foam glass heat insulating photovoltaic decoration integrated board and preparation method thereof | |
| CN103410288B (en) | A kind of vacuum thermal insulation photovoltaic decoration integrated board and preparation method thereof | |
| CN103437509B (en) | A kind of fire-proof and water-proof photovoltaic coiled material and preparation method thereof | |
| CN103422641B (en) | A kind of fireproof heat insulating photovoltaic decoration composite plate and preparation method thereof | |
| CN203514665U (en) | Fireproof and waterproof photovoltaic coiled materials | |
| CN203080820U (en) | Solar power generation composite heat-preserving board | |
| CN203457102U (en) | Metal photovoltaic tile | |
| CN102704629A (en) | Pressure sensitive adhesive type modularized crystalline silicon solar generation waterproof thermal-insulation integrated board system | |
| CN201620531U (en) | A photovoltaic building integrated solar wall panel | |
| CN203452283U (en) | Roof photovoltaic tile | |
| CN203452284U (en) | Heat-insulated photovoltaic tile | |
| CN203452308U (en) | Outer wall flexible photovoltaic decorating wall material | |
| CN107882276A (en) | A kind of laminating packaging photovoltaic panel | |
| CN103774806B (en) | Photovoltaic color steel and the color steel unit of photovoltaic thereof | |
| CN203475749U (en) | Foam glass heat-preservation photovoltaic and decoration integrated board | |
| CN108018723A (en) | A kind of photoelectricity building materials and preparation method thereof | |
| CN203475731U (en) | Photovoltaic tile for flexible roof | |
| CN107963843A (en) | A kind of solar energy porcelain tendre ornament materials and preparation method thereof | |
| CN203514692U (en) | Fireproof heat-preservation photovoltaic decorative composite board |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20201208 Address after: 535500 Chengxi Industrial Zone, Shangsi County, Fangchenggang City, Guangxi Zhuang Autonomous Region Patentee after: Guangxi Shangsi Hualin forest products industry Co.,Ltd. Address before: 264006 Hua River Industrial Zone, Yantai economic and Technological Development Zone, Shandong, Yantai Patentee before: YANTAI SITANPU FINE CONSTRUCTION Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240407 Address after: 226600 group 33, Liuwei village, Qutang Town, Hai'an City, Nantong City, Jiangsu Province Patentee after: Jiangsu Xinba New Material Technology Co.,Ltd. Country or region after: China Address before: 535500 Chengxi Industrial Zone, Shangsi County, Fangchenggang City, Guangxi Zhuang Autonomous Region Patentee before: Guangxi Shangsi Hualin forest products industry Co.,Ltd. Country or region before: China |