CN103404530A - Insecticide compound and application and preparation thereof - Google Patents
Insecticide compound and application and preparation thereof Download PDFInfo
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- CN103404530A CN103404530A CN2013103730567A CN201310373056A CN103404530A CN 103404530 A CN103404530 A CN 103404530A CN 2013103730567 A CN2013103730567 A CN 2013103730567A CN 201310373056 A CN201310373056 A CN 201310373056A CN 103404530 A CN103404530 A CN 103404530A
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- 238000002360 preparation method Methods 0.000 title abstract description 26
- 150000001875 compounds Chemical class 0.000 title abstract description 7
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- 230000000361 pesticidal effect Effects 0.000 claims description 48
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- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 2
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- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the technical field of insecticides, in particular to an insecticide compound and application and a preparation thereof. The insecticide compound consists of 3-chlorine-N1-(2-methyl-4-heptafluoroisopropylanilina)-N2-(1-methyl-1-cyano ethyl) phthalic diamide and dinotefuran. Compared with a single preparation, the insecticide compound has an obvious synergism effect, can be used for effectively preventing and controlling lepidoptera pests, orthoptera pests or piercing-sucking mouthpart pests; therefore, the amount of used pesticides is reduced and the pesticide application cost is lowered, a wide insecticidal spectrum is wider. The insecticide compound and the preparation method thereof are beneficial to environment protection and comprehensive treatment of agricultural pests.
Description
Technical field
The present invention relates to technical field of pesticide, particularly a kind of Pesticidal combination and application thereof, preparation.
Background technology
China is large agricultural country, and pest species is various, and all can run into the threat from pest every year in the production process of grain, cotton and vegetables etc.Common pest mainly comprise Semiptera insect (typical insect has cotten aphid, cabbage aphid etc.), homoptera pest (typical insect has rice fulgorid, Bemisia tabaci etc.), lepidoptera pest (typical insect has striped rice borer, rice leaf roller etc.), orthoptera pest (typical insect has locust, cricket etc.) etc.Wherein, cotten aphid is one of important pests of cotton in seedling stage, and it with piercing mouth parts, inserts cotton leaf back or tender head part tissue is sucked juice, the blade of being injured is crispaturaed to the back side, and the leaf table has the honeydew of aphid excretion, and often grows mould, cause development delay and the underproduction, and can propagate various plants virus; Rice fulgorid inhales the plant juice crops such as paddy rice of causing harm with thorn, makes its growth retardation, and when serious, the rice clump is agglomerating withered, the dead stalk lodging in even full field; Striped rice borer is on China paddy rice, to endanger one of the most serious Occurrence, and main harm, in rice plant of tillering stage, to cause withered sheath, withered heart seedling, causes and hinders strain and dead ears in the fringe phase, causes the underproduction, the general time underproduction 3%～5%, and when serious, the underproduction is more than 3 one-tenth; Locust is locust section orthopteran, and the whole world has over 10,000 kinds.Be distributed in meadow and the desert area in the global torrid zone, temperate zone.Mouthpart is hard, main harm gramineous plants, the agricultural production of serious threat China.Based on the harm of these insects to crops, be the top priority in China's agricultural production for the monitorings of these insects, early warning and control all the time.
At present, the method for pest control is mainly chemical control.Chemical control is called again pesticide control, is to carry out prevention and elimination of disease and pests by the toxicity of chemical agent, has efficient, quick-acting, easy to use, economic benefit advantages of higher, and it is the most frequently used method of plant protection, is also important measures in integrated control.
But along with the continuity of chemical control, increase and the non-science of agricultural chemicals usage amount are used agricultural chemicals, pest resistance is day by day serious, the pest species that produces resistance is on the increase, the Lepidoptera class pest of particularly causing harm serious to agricultural production, resistance level is higher, resistance development speed is relatively very fast, and the resistance problem of pest becomes a global problem.Simultaneously, high-intensity use agricultural chemicals, cause that Practice for Pesticide Residue in Agricultural Products exceeds standard, environmental pollution and the increase of peasant's drug cost etc., is unfavorable for agricultural sustainable development.Therefore, efficient, the low toxicity of research and development, environmental protection, insecticidal spectrum pesticide wide, that the lasting period is long have positive effect to agricultural sustainable development.
Summary of the invention
In view of this, the invention provides a kind of Pesticidal combination and application thereof, preparation.This Pesticidal combination and preparation thereof have obvious synergistic effect with respect to single dose; can effectively prevent and treat lepidoptera pest, orthoptera pest or sucking pest; reduced the using dosage of agricultural chemicals; saved drug cost; insecticidal spectrum is more extensive, is conducive to the comprehensive regulation of environmental protection and pest.
In order to realize the foregoing invention purpose, the invention provides following technical scheme:
The invention provides a kind of Pesticidal combination, by the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide and MTI-446 form.
The chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) (test code number: ZJ4042), be the novel pesticide that develop voluntarily Zhejiang Provincial Chemical Engineering Research Inst, structural formula is suc as formula shown in I for phthalic amide.The insecticidal activity of this compound and the fipronil bisamide of recent development substantially suitable, belong to Novel ortho benzenedicarboxamide insecticides, it can activate calcium release channel in blue Buddhist nun's alkali recipient cell, cause storing the property out of control release of calcium ion, it is at present few in number compounds that acts on blue Buddhist nun's alkali (Ryanodine) acceptor of insect cell, lepidoptera pest is had to the wide spectrum preventive effect, produce without cross resistance with existing insecticide, be suitable for very much the control that existing insecticide is produced to the insect of resistance.
MTI-446, chemical name is (EZ)-(RS)-1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine, structural formula is suc as formula shown in II, belong to third generation nicotinic insecticide, it is the acting body of nicotinic acid nAChR ligands, disturb the pest movements nervous system that chemical signal is transmitted malfunctioning, without the cross resistance problem, have the characteristics such as tag, absorption is strong, quick-acting in stomach toxicity, root, the lasting period is long, insecticidal spectrum is wide, and sucking pest is had to good preventive effect, and namely shown very high insecticidal activity at very low dosage.Be mainly used in preventing and treating aphid, leafhopper, plant hopper, thrips, aleyrodid and the resistant strain thereof on the various crop such as wheat, paddy rice, cotton, vegetables, fruit tree, tobacco leaf, simultaneously coleoptera, diptera and Lepidoptera, diptera, beetle order and total wing order insect are had to higher preventive effect, and to blattaria, have higher preventive effect from sanitary insect pests such as ant, houseflies.
The different insecticides active component is mixed the difference of rear each active component due to composition, structure, physicochemical property, makes the synergy between each active component be typically expressed as synergistic effect, summation action or antagonism.So-called synergistic effect is exactly the mutual synergism between different material, and the effect of its generation is greater than the sum total of each composition effect; And the effect that summation action is exactly its generation equals the sum total of each composition effect; Antagonism refers to when two kinds of materials act on living organism, and a kind of material disturbs the effect of another kind of material, or the effect of interfering with an opponent each other, the phenomenon that general effect is descended.In the present invention, by the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide and MTI-446 have obvious synergistic effect after composite, can effectively prevent and treat lepidoptera pest, orthoptera pest or sucking pest.
In order to guarantee that Pesticidal combination has preventive effect and synergistic effect preferably, as preferably, the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) mass ratio of phthalic amide and MTI-446 is (1～90): (1～30).
Preferably, the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) mass ratio of phthalic amide and described MTI-446 is (1～50): (1～30).
More preferably, the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) mass ratio of phthalic amide and MTI-446 is (1～30): (1～10).
In embodiment more provided by the invention, the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) mass ratio of phthalic amide and MTI-446 is 90:1.
In other embodiment provided by the invention, the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) mass ratio of phthalic amide and MTI-446 is 50:1.
In other embodiment provided by the invention, the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) mass ratio of phthalic amide and MTI-446 is 30:1.
In other embodiment provided by the invention, the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) mass ratio of phthalic amide and MTI-446 is 20:1.
In other embodiment provided by the invention, the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) mass ratio of phthalic amide and MTI-446 is 4:1.
In other embodiment provided by the invention, the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) mass ratio of phthalic amide and MTI-446 is 1:10.
In other embodiment provided by the invention, the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) mass ratio of phthalic amide and MTI-446 is 1:30.
The present invention also provides the application of a kind of Pesticidal combination provided by the invention in control lepidoptera pest, orthoptera pest or sucking pest.But the prevention and treatment range of Pesticidal combination provided by the invention is not limited to this, the present invention does not do restriction at this.
In embodiment more provided by the invention, but Pesticidal combination prevention and control of aphides provided by the invention, cabbage aphid, rice fulgorid, striped rice borer and rice leaf roller.
Pesticidal combination provided by the invention is for preventing and treating sucking pest, and the sucking pest of control comprises Homoptera, Semiptera, Siphonaptera, Anoplura and part Diptera pest.
In embodiment more provided by the invention, Pesticidal combination provided by the invention is for suckings pest such as prevention and control of aphides, cabbage aphid and rice fulgorids, but the sucking pest of those skilled in the art's approval is all within the prevention and treatment range of Pesticidal combination provided by the invention, the kind of sucking pest is not limited to this, and the present invention does not do restriction at this.
Pesticidal combination provided by the invention is for preventing and treating lepidoptera pest.In embodiment more provided by the invention, Pesticidal combination provided by the invention is for preventing and treating the lepidoptera pests such as striped rice borer, rice leaf roller, but the lepidoptera pest of those skilled in the art's approval is all within the prevention and treatment range of Pesticidal combination provided by the invention, the kind of lepidoptera pest is not limited to this, and the present invention does not do restriction at this.
The present invention also provides a kind of insecticide, comprises acceptable auxiliary material on Pesticidal combination provided by the invention and Pesticide Science.
In order to guarantee that insecticide has preventive effect preferably, as preferably, the quality percentage composition that Pesticidal combination accounts for insecticide is 3.1%～91%.
Preferably, to account for the quality percentage composition of insecticide be 10%～91% to Pesticidal combination.
More preferably, to account for the quality percentage composition of insecticide be 40%～80% to Pesticidal combination.
In embodiment more provided by the invention, the quality percentage composition that Pesticidal combination accounts for insecticide is 3.1%.
In other embodiment provided by the invention, the quality percentage composition that Pesticidal combination accounts for insecticide is 10.2%.
In other embodiment provided by the invention, the quality percentage composition that Pesticidal combination accounts for insecticide is 21%.
In other embodiment provided by the invention, the quality percentage composition that Pesticidal combination accounts for insecticide is 25%.
In other embodiment provided by the invention, the quality percentage composition that Pesticidal combination accounts for insecticide is 31%.
In other embodiment provided by the invention, the quality percentage composition that Pesticidal combination accounts for insecticide is 40%.
In other embodiment provided by the invention, the quality percentage composition that Pesticidal combination accounts for insecticide is 42%.
In other embodiment provided by the invention, the quality percentage composition that Pesticidal combination accounts for insecticide is 55%.
In other embodiment provided by the invention, the quality percentage composition that Pesticidal combination accounts for insecticide is 80%.
In other embodiment provided by the invention, the quality percentage composition that Pesticidal combination accounts for insecticide is 91%.
According to different user demands, insecticide provided by the invention can be made into multiple formulation.In embodiment more provided by the invention, the formulation of insecticide is wetting powder, microemulsion, missible oil or suspending agent.
Wherein, by the solvent species difference of adding, suspending agent is divided into aqueous suspension agent and oil-suspending agent, and solvent is that the suspending agent of water is aqueous suspension agent, and solvent is that the suspending agent of oils is oil-suspending agent.
In embodiment more provided by the invention, on Pesticide Science, acceptable auxiliary material is the mixture of a kind of and surfactant in solid carrier, liquid diluent.On the Pesticide Science of those skilled in the art's approval, all within protection scope of the present invention, the present invention does not do restriction at this to acceptable auxiliary material.
Surfactant refers to have fixing hydrophilic and oleophilic group, on the surface of solution, can align, and the material that surface tension is significantly descended.For spread and the infiltration capacity that strengthens agricultural chemicals, be conducive to dispersion and the suspension of particle, increase the stability of pesticidal preparations, in insecticide of the present invention, add surfactant.In embodiment more provided by the invention, surfactant is selected from alkylsulfonate, fatty alcohol sulfonate, alkylphenol polyoxyethylene, lauryl sodium sulfate, calcium dodecyl benzene sulfonate, lignosulfonates, carboxymethyl cellulose, phenethyl phenol polyethenoxy ether phosphate, agriculture breast 500, agriculture breast 600, Nongru-700, agriculture breast 1601, agriculture breast 1602, agriculture breast 2201, agriculture breast 8209, agriculture breast 8312, agriculture breast 8210, agriculture breast NP-10, agriculture breast 0425, agriculture breast 0408, agriculture breast 3517, agriculture breast 8220, agriculture breast 8210, dispersant NNO(di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate), Nekal BX (1, 2-di-n-butyl naphthalene-6-sodium sulfonate), detergent LS, penetrating agent JFC (fatty alcohol-polyoxyethylene ether) or NMP(N-methyl pyrrolidone).
When the formulation of insecticide is solid dosage forms, need to use solid carrier.In embodiment more provided by the invention, solid carrier is selected from bentonite, white carbon, kaolin, potter's clay, diatomite, precipitated calcium carbonate or talcum powder.
When the formulation of insecticide is liquid dosage form, need to use liquid diluent.In embodiment more provided by the invention, liquid diluent is selected from cyclohexanone, acetone, dimethylacetylamide, butyl glycidyl ether (BGE), isoamyl alcohol, isopropyl alcohol, methyl alcohol, methyl oleate, soybean salad oil, dimethyl sulfoxide (DMSO) or water.
The invention provides a kind of Pesticidal combination and application thereof, preparation.This Pesticidal combination is by the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide and MTI-446 form.By Toxicity Determination, test, result shows the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide and MTI-446 be when composite with 90:1,50:1,30:1,20:1,4:1,1:10,1:30 ratio according to the active ingredient proportioning, its co-toxicity coefficient to cotton aphid, rice fulgorid, cabbage aphid and rice-stem borer all is greater than 120, all show as synergistic effect, show that Pesticidal combination provided by the invention compares with single dose and have obvious synergistic effect; By the field efficacy comparative trial, result shows that insecticide insecticidal effect provided by the invention, higher than single dose, shows that Pesticidal combination provided by the invention and preparation thereof can improve the preventive effect to sucking pest, lepidoptera pest, and has synergistic effect.As can be seen here; Pesticidal combination provided by the invention and preparation thereof have obvious synergistic effect with respect to single dose; can effectively prevent and treat lepidoptera pest, orthoptera pest or sucking pest; thereby reduced the using dosage of agricultural chemicals; saved drug cost; insecticidal spectrum is more extensive, is conducive to the comprehensive regulation of environmental protection and pest.
Embodiment
The invention discloses a kind of Pesticidal combination and application thereof, preparation, those skilled in the art can use for reference this paper content, suitably improve technological parameter and realize.Special needs to be pointed out is, all similar replacements and change apparent to those skilled in the artly, they all are deemed to be included in the present invention.Method of the present invention and application are described by preferred embodiment, the related personnel obviously can change methods and applications as herein described or suitably change and combination within not breaking away from content of the present invention, spirit and scope, realize and apply the technology of the present invention.
In Pesticidal combination provided by the invention and application thereof, preparation, institute's with medicament, bulk drug or auxiliary material all can be buied by market.
Below in conjunction with embodiment, further set forth the present invention:
Embodiment 1 Toxicity Determination test
Adopt infusion process to carry out the indoor virulence biologicall test, selecting cotton aphid, rice fulgorid, cabbage aphid, rice-stem borer is target pest, repeats the latter 24 hours check results of investigating 4 times.Drug concentration (mg/l) logarithm value of take is independent variable x, and the probit value of its corresponding corrected mortality of take is dependent variable y, sets up respectively virulence regression equation, obtains the co-toxicity coefficient of the different proportionings of two single doses, the results are shown in Table 1, table 2, table 3, table 4.According to co-toxicity coefficient, estimate the interaction of two single doses in Pesticidal combination provided by the invention, evaluation criterion is: co-toxicity coefficient >=120 show as synergistic effect; Co-toxicity coefficient≤80 show as antagonism; 80<co-toxicity coefficient<120 show as summation action.
The chloro-N1-(2-methyl of table 13--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide and the composite different proportionings of MTI-446 are to cotton aphid toxicity test result
The chloro-N1-(2-methyl of table 23--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide and the composite different proportionings of the MTI-446 toxicity test result to rice fulgorid
The chloro-N1-(2-methyl of table 33--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide and the composite different proportionings of the MTI-446 toxicity test result to cabbage aphid
The chloro-N1-(2-methyl of table 43--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide and the composite different proportionings of the MTI-446 toxicity test result to rice-stem borer
As can be known by above-mentioned result of the test, when the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide and MTI-446 are composite with 90:1,50:1,30:1,20:1,4:1,1:10,1:30 ratio according to the active ingredient proportioning, its co-toxicity coefficient to cotton aphid, rice fulgorid, cabbage aphid and rice-stem borer all is greater than 120, all show as synergistic effect, when wherein proportioning is 20:1,4:1,1:10,1:30, spend coefficient together more than 140, synergistic effect is especially remarkable, during with 4:1 for the highest.
As can be seen here, Pesticidal combination provided by the invention is compared with single dose has obvious synergistic effect, can effectively prevent and treat cotton aphid, rice fulgorid, cabbage aphid and rice-stem borer.
The preparation of embodiment 221% wetting powder
Get the chloro-N1-(2-methyl of 1g3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, 20g MTI-446,8g carboxymethyl cellulose, 6g NNO, 65g kaolin, preparing routinely the method for wetting powder fully mixes, pulverize, obtain 21% wetting powder.
The preparation of embodiment 331% microemulsion
Get the chloro-N1-(2-methyl of 1g3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, 30g MTI-446,7g calcium dodecyl benzene sulfonate, 3.5g phenethyl phenol polyethenoxy ether phosphate, 2g agriculture breast 500#, 1g alkylphenol polyoxyethylene, 10g isopropyl alcohol, 45.5g water, the method of preparing routinely microemulsion mixes, and obtains 31% microemulsion.
The preparation of embodiment 455% missible oil
Get the chloro-N1-(2-methyl of 5g3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, 50g MTI-446,10g alkylphenol polyoxyethylene, 15g agriculture breast 600#, 20g soybean oil, the method of preparing routinely missible oil mixes, and obtains 55% missible oil.
The preparation of embodiment 580% wetting powder
Get the chloro-N1-(2-methyl of 20g3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, 60g MTI-446,4g lignosulfonates, 3g lauryl sodium sulfate, 5g white carbon, 8g kaolin, preparing routinely the wettable powder agent method fully mixes, pulverize, obtain 80% wetting powder.
The preparation of embodiment 640% aqueous suspension agent
Get the chloro-N1-(2-methyl of 20g3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, 20g MTI-446,20g agriculture breast 600#, 6g bentonite, 34g water, the method of preparing routinely suspending agent mixes, and obtains 40% suspending agent.
The preparation of embodiment 725% oil-suspending agent
Get the chloro-N1-(2-methyl of 20g3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, 5g MTI-446,6g white carbon, 5g agriculture breast 500#, 64g soybean oil, the method of preparing routinely oil-suspending agent mixes, pulverize, obtain 25% oil-suspending agent.
The preparation of embodiment 831% missible oil
Get the chloro-N1-(2-methyl of 30g3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, 1g MTI-446,5g calcium dodecyl benzene sulfonate, 6g agriculture breast 600#, 58g soybean oil, the method of preparing routinely missible oil mixes, and obtains 31% missible oil.
The preparation of embodiment 942% microemulsion
Get the chloro-N1-(2-methyl of 40g3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, 2g MTI-446,5g agriculture breast 600#, 5g butyl glycidyl ether, 3g sodium alkyl benzene sulfonate, 3.5g isoamyl alcohol, 41.5g deionized water, the method of preparing routinely microemulsion mixes, standing, heating, fully stir, and obtains 42% microemulsion.
The preparation of embodiment 103.1% microemulsion
Get the chloro-N1-(2-methyl of 3g3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, 0.1g MTI-446,4g agriculture breast 1602#, 3g agriculture breast 500#, 5g NMP, 6g isopropyl alcohol, 6g soybean oil, 72.9g deionized water, the method of preparing routinely microemulsion mixes, and obtains 3.1% microemulsion.
The preparation of embodiment 1110.2% oil-suspending agent
Get the chloro-N1-(2-methyl of 10g3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, 0.2g MTI-446,6g white carbon, 6g agriculture breast 1601#, 77.8g methyl oleate, the method of preparing routinely oil-suspending agent mixes, pulverize, obtain 10.2% oil-suspending agent.
The preparation of embodiment 1291% wetting powder
Get the chloro-N1-(2-methyl of 90g3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, 1g MTI-446,1g methylcellulose, 4g NNO, 1g white carbon, 3g kaolin, preparing routinely the method for wetting powder fully mixes, pulverize, obtain 91% wetting powder.
Embodiment 13 field efficacy comparative trials
Get insecticide and the chloro-N1-(2-methyl of commercially available single dose 20%3--4-sevoflurane isopropyl base that embodiment 2～12 makes)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide SC(suspending agent), 20% MTI-446 WDG(water dispersible granules) carry out the field efficacy comparative trial.Subjects is cotton aphid, cabbage aphid, rice fulgorid and rice-stem borer, and whole duration of test is without rainfall.This tests 24h, 72h investigation result after dispenser.Field control effectiveness test the results are shown in Table 5,6,7,8.
Drug effect is calculated as follows:
Borer population after borer population * treatment region medicine before control efficiency (%)=1-(blank district)/(borer population before borer population behind the blank district * treatment region medicine)
Table 5 control cotton aphid test of pesticide effectiveness result
Table 6 control rice fulgorid test of pesticide effectiveness result
Table 7 control cabbage aphid test of pesticide effectiveness result
Table 8 control rice-stem borer test of pesticide effectiveness result
By above-mentioned result of the test, can be found out, test is under the identical prerequisite of effective ingredient consumption, the insecticide insecticidal effect that the embodiment of the present invention 2～12 provides is higher than each single dose, show that Pesticidal combination provided by the invention and preparation thereof have synergistic effect with respect to single dose, can improve the preventive effect to sucking pest, lepidoptera pest.
A bit need in addition explanation, indivedual preventive effect data in result of the test and the preventive effect data of two kinds of single doses are quite or slightly low, synergistic effect is not remarkable, this is because insecticide can be subject to the impact of the many factors such as natural conditions, agriculture condition, pesticide resistance interference and test operation in field control effectiveness test, and cause the appearance of this situation, this is ubiquitous phenomenon in field control effectiveness test, do not have the conclusion of synergistic effect but do not affect the insecticide provided by the invention obtained by the Toxicity Determination test.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (10)
1. a Pesticidal combination, is characterized in that, by the chloro-N1-(2-methyl of 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide and MTI-446 form.
2. Pesticidal combination according to claim 1, it is characterized in that the chloro-N1-(2-methyl of described 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) mass ratio of phthalic amide and described MTI-446 is (1～90): (1～30).
3. Pesticidal combination according to claim 2, it is characterized in that the chloro-N1-(2-methyl of described 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) mass ratio of phthalic amide and described MTI-446 is (1～50): (1～30).
4. Pesticidal combination according to claim 3, it is characterized in that the chloro-N1-(2-methyl of described 3--4-sevoflurane isopropyl base)-N2-(1-methyl isophthalic acid-cyano ethyl) mass ratio of phthalic amide and described MTI-446 is (1～30): (1～10).
5. the application of Pesticidal combination as described as any one in claim 1 to 4 in control lepidoptera pest, orthoptera pest or sucking pest.
6. an insecticide, is characterized in that, comprises in claim 1 to 4 acceptable auxiliary material on the described Pesticidal combination of any one and Pesticide Science.
7. insecticide according to claim 6, is characterized in that, the quality percentage composition that described Pesticidal combination accounts for described insecticide is 3.1%～91%.
8. insecticide according to claim 7, is characterized in that, the quality percentage composition that described Pesticidal combination accounts for described insecticide is 10%～91%.
9. insecticide according to claim 6, is characterized in that, the formulation of described insecticide is wetting powder, microemulsion, missible oil or suspending agent.
10. insecticide according to claim 6, is characterized in that, on described Pesticide Science, acceptable auxiliary material is the mixture of a kind of and surfactant in solid carrier, liquid diluent.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104054742A (en) * | 2014-06-24 | 2014-09-24 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition |
| CN104054741A (en) * | 2014-06-24 | 2014-09-24 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition |
| CN104186526A (en) * | 2014-08-04 | 2014-12-10 | 广东中迅农科股份有限公司 | Pesticide composition containing cyhalodiamide and dinotefuran |
| CN104222139A (en) * | 2014-09-19 | 2014-12-24 | 浙江省化工研究院有限公司 | Insecticide composition containing dinotefuran and ZJ4042 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102630693A (en) * | 2012-03-28 | 2012-08-15 | 联保作物科技有限公司 | Insecticidal composition, and preparation and application thereof |
| CN102907453A (en) * | 2012-11-09 | 2013-02-06 | 中化蓝天集团有限公司 | Pesticide composition for agricultural pests |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102630693A (en) * | 2012-03-28 | 2012-08-15 | 联保作物科技有限公司 | Insecticidal composition, and preparation and application thereof |
| CN102907453A (en) * | 2012-11-09 | 2013-02-06 | 中化蓝天集团有限公司 | Pesticide composition for agricultural pests |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104054742A (en) * | 2014-06-24 | 2014-09-24 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition |
| CN104054741A (en) * | 2014-06-24 | 2014-09-24 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition |
| CN104186526A (en) * | 2014-08-04 | 2014-12-10 | 广东中迅农科股份有限公司 | Pesticide composition containing cyhalodiamide and dinotefuran |
| CN104222139A (en) * | 2014-09-19 | 2014-12-24 | 浙江省化工研究院有限公司 | Insecticide composition containing dinotefuran and ZJ4042 |
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