CN103373862B - 在陶瓷基质复合材料中产生内腔室的方法及用于其的心轴 - Google Patents
在陶瓷基质复合材料中产生内腔室的方法及用于其的心轴 Download PDFInfo
- Publication number
- CN103373862B CN103373862B CN201310149615.6A CN201310149615A CN103373862B CN 103373862 B CN103373862 B CN 103373862B CN 201310149615 A CN201310149615 A CN 201310149615A CN 103373862 B CN103373862 B CN 103373862B
- Authority
- CN
- China
- Prior art keywords
- mandrel
- cmc
- preformed member
- inner cavity
- cavity chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
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- 239000000463 material Substances 0.000 claims abstract description 52
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 28
- 239000010703 silicon Substances 0.000 claims abstract description 28
- 229910000676 Si alloy Inorganic materials 0.000 claims abstract description 12
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- 238000011282 treatment Methods 0.000 claims abstract description 3
- 230000008595 infiltration Effects 0.000 claims description 20
- 238000001764 infiltration Methods 0.000 claims description 20
- 238000005245 sintering Methods 0.000 claims description 14
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- 238000006243 chemical reaction Methods 0.000 abstract description 9
- 239000011347 resin Substances 0.000 description 15
- 229920005989 resin Polymers 0.000 description 15
- 229910003978 SiClx Inorganic materials 0.000 description 8
- 239000000919 ceramic Substances 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
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- 239000012779 reinforcing material Substances 0.000 description 5
- 238000007711 solidification Methods 0.000 description 5
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- 229910052799 carbon Inorganic materials 0.000 description 4
- 150000003377 silicon compounds Chemical class 0.000 description 4
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- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229910010271 silicon carbide Inorganic materials 0.000 description 3
- 238000001291 vacuum drying Methods 0.000 description 3
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- 229910000831 Steel Inorganic materials 0.000 description 2
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- 230000009931 harmful effect Effects 0.000 description 2
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- 239000000155 melt Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
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- 210000004483 pasc Anatomy 0.000 description 2
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- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
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- 230000000704 physical effect Effects 0.000 description 1
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- -1 silicon carbide) Chemical class 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
- C04B35/565—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D22/00—Producing hollow articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/54—Producing shaped prefabricated articles from the material specially adapted for producing articles from molten material, e.g. slag refractory ceramic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators or shrinkage compensating agents
- C04B22/02—Elements
- C04B22/04—Metals, e.g. aluminium used as blowing agent
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/30—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
- C04B26/32—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
- C04B35/565—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
- C04B35/573—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide obtained by reaction sintering or recrystallisation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
- C04B35/65—Reaction sintering of free metal- or free silicon-containing compositions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/28—Solid state diffusion of only metal elements or silicon into metallic material surfaces using solids, e.g. powders, pastes
- C23C10/34—Embedding in a powder mixture, i.e. pack cementation
- C23C10/36—Embedding in a powder mixture, i.e. pack cementation only one element being diffused
- C23C10/44—Siliconising
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/48—Coating with alloys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y80/00—Products made by additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/602—Making the green bodies or pre-forms by moulding
- C04B2235/6026—Computer aided shaping, e.g. rapid prototyping
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/602—Making the green bodies or pre-forms by moulding
- C04B2235/6028—Shaping around a core which is removed later
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/14—Form or construction
- F01D5/18—Hollow blades, i.e. blades with cooling or heating channels or cavities; Heating, heat-insulating or cooling means on blades
- F01D5/187—Convection cooling
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/282—Selecting composite materials, e.g. blades with reinforcing filaments
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/284—Selection of ceramic materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/60—Properties or characteristics given to material by treatment or manufacturing
- F05D2300/603—Composites; e.g. fibre-reinforced
- F05D2300/6033—Ceramic matrix composites [CMC]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/131—Glass, ceramic, or sintered, fused, fired, or calcined metal oxide or metal carbide containing [e.g., porcelain, brick, cement, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Ceramic Products (AREA)
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261639617P | 2012-04-27 | 2012-04-27 | |
| US61/639617 | 2012-04-27 | ||
| US61/639,617 | 2012-04-27 | ||
| US13/780,306 | 2013-02-28 | ||
| US13/780306 | 2013-02-28 | ||
| US13/780,306 US10450235B2 (en) | 2012-04-27 | 2013-02-28 | Method of producing an internal cavity in a ceramic matrix composite and mandrel therefor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103373862A CN103373862A (zh) | 2013-10-30 |
| CN103373862B true CN103373862B (zh) | 2019-01-08 |
Family
ID=48143215
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310149615.6A Expired - Fee Related CN103373862B (zh) | 2012-04-27 | 2013-04-26 | 在陶瓷基质复合材料中产生内腔室的方法及用于其的心轴 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US10450235B2 (enExample) |
| EP (1) | EP2657209B1 (enExample) |
| JP (1) | JP6276514B2 (enExample) |
| CN (1) | CN103373862B (enExample) |
| BR (1) | BR102013010197A2 (enExample) |
| CA (1) | CA2813313A1 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10011043B2 (en) * | 2012-04-27 | 2018-07-03 | General Electric Company | Method of producing an internal cavity in a ceramic matrix composite |
| US10450235B2 (en) | 2012-04-27 | 2019-10-22 | General Electric Company | Method of producing an internal cavity in a ceramic matrix composite and mandrel therefor |
| EP3004559B1 (en) | 2013-05-29 | 2020-01-15 | General Electric Company | Method of forming a ceramic matrix composite component with cooling features |
| US9624138B2 (en) | 2014-04-08 | 2017-04-18 | United Technologies Corporation | Formation of voids within components formed from porous substrates |
| US10808554B2 (en) | 2016-11-17 | 2020-10-20 | Raytheon Technologies Corporation | Method for making ceramic turbine engine article |
| US10196315B2 (en) * | 2017-01-11 | 2019-02-05 | General Electric Company | Melt infiltration with SiGa and/or siln alloys |
| US10562210B2 (en) | 2017-03-22 | 2020-02-18 | General Electric Company | Method for forming passages in composite components |
| US11066335B2 (en) | 2017-09-06 | 2021-07-20 | General Electric Company | Articles for creating hollow structures in ceramic matrix composites |
| US10895448B2 (en) * | 2019-04-09 | 2021-01-19 | General Electric Company | System and method for collecting measurement data of shaped cooling holes of CMC components |
| US11867067B2 (en) | 2022-06-03 | 2024-01-09 | Rtx Corporation | Engine article with ceramic insert and method therefor |
| US20250289762A1 (en) * | 2024-03-13 | 2025-09-18 | Ii-Vi Delaware, Inc. | Silicon consumable core for internal features in reaction bonded ceramics |
Citations (2)
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|---|---|---|---|---|
| EP1262468A1 (en) * | 2001-05-30 | 2002-12-04 | General Electric Company | Method for producing melt-infiltrated ceramic compositions using formed supports |
| US20050056020A1 (en) * | 2003-08-26 | 2005-03-17 | Honeywell International Inc. | Tube cooled combustor |
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| US3907949A (en) | 1970-10-27 | 1975-09-23 | Westinghouse Electric Corp | Method of making tubular polycrystalline oxide body with tapered ends |
| US4040849A (en) * | 1976-01-06 | 1977-08-09 | General Electric Company | Polycrystalline silicon articles by sintering |
| US4615855A (en) | 1984-03-15 | 1986-10-07 | Programmed Composites, Inc. | Process for forming composite article |
| JPS62227603A (ja) | 1986-03-31 | 1987-10-06 | 日本碍子株式会社 | セラミツクス焼結体の製造方法及び該製造方法に用いるための成形型 |
| JPS62256605A (ja) | 1986-04-30 | 1987-11-09 | マツダ株式会社 | セラミツク成形品の製造法 |
| US5015540A (en) | 1987-06-01 | 1991-05-14 | General Electric Company | Fiber-containing composite |
| US5330854A (en) | 1987-09-24 | 1994-07-19 | General Electric Company | Filament-containing composite |
| JPH01198343A (ja) | 1988-02-02 | 1989-08-09 | Toray Ind Inc | 筒状炭素・炭素複合材料の製造方法 |
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| US5066454A (en) | 1990-06-20 | 1991-11-19 | Industrial Materials Technology, Inc. | Isostatic processing with shrouded melt-away mandrel |
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| JPH07195147A (ja) | 1993-12-29 | 1995-08-01 | Masaru Nemoto | 成形用特殊中子を用いた成形方法 |
| US5725044A (en) | 1994-08-30 | 1998-03-10 | Hirokawa; Koji | Casting method using a forming die |
| US5628938A (en) | 1994-11-18 | 1997-05-13 | General Electric Company | Method of making a ceramic composite by infiltration of a ceramic preform |
| US6024898A (en) | 1996-12-30 | 2000-02-15 | General Electric Company | Article and method for making complex shaped preform and silicon carbide composite by melt infiltration |
| US5910095A (en) | 1997-02-21 | 1999-06-08 | Northrop Grumman Corporation | Fiber reinforced ceramic matrix composite marine engine riser elbow |
| US6001436A (en) | 1997-05-12 | 1999-12-14 | Northrop Grumman Corporation | Ceramic matrix composite turbocharger housing |
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- 2013-04-23 JP JP2013089883A patent/JP6276514B2/ja not_active Expired - Fee Related
- 2013-04-24 EP EP13165241.4A patent/EP2657209B1/en not_active Not-in-force
- 2013-04-26 BR BR102013010197-4A patent/BR102013010197A2/pt not_active Application Discontinuation
- 2013-04-26 CN CN201310149615.6A patent/CN103373862B/zh not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| CN103373862A (zh) | 2013-10-30 |
| US10450235B2 (en) | 2019-10-22 |
| JP2013256436A (ja) | 2013-12-26 |
| EP2657209B1 (en) | 2014-12-17 |
| EP2657209A1 (en) | 2013-10-30 |
| US20140072736A1 (en) | 2014-03-13 |
| CA2813313A1 (en) | 2013-10-27 |
| JP6276514B2 (ja) | 2018-02-07 |
| BR102013010197A2 (pt) | 2017-07-11 |
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