CN103356407B - Nourishing hair shampoo containing silk fibroin amino acid - Google Patents
Nourishing hair shampoo containing silk fibroin amino acid Download PDFInfo
- Publication number
- CN103356407B CN103356407B CN201310307567.9A CN201310307567A CN103356407B CN 103356407 B CN103356407 B CN 103356407B CN 201310307567 A CN201310307567 A CN 201310307567A CN 103356407 B CN103356407 B CN 103356407B
- Authority
- CN
- China
- Prior art keywords
- amino acid
- silk fibroin
- shampoo
- fibroin amino
- antiseptic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002453 shampoo Substances 0.000 title claims abstract description 38
- 108010022355 Fibroins Proteins 0.000 title claims abstract description 30
- 150000001413 amino acids Chemical class 0.000 title claims abstract description 30
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 230000002421 anti-septic effect Effects 0.000 claims description 17
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- DNKGZSOYWMQDTK-UHFFFAOYSA-N 3-iodoprop-1-ynyl N-butylcarbamate Chemical compound CCCCNC(=O)OC#CCI DNKGZSOYWMQDTK-UHFFFAOYSA-N 0.000 claims description 10
- BCZXFFBUYPCTSJ-UHFFFAOYSA-L Calcium propionate Chemical compound [Ca+2].CCC([O-])=O.CCC([O-])=O BCZXFFBUYPCTSJ-UHFFFAOYSA-L 0.000 claims description 10
- 150000008442 polyphenolic compounds Chemical class 0.000 claims description 10
- 235000013824 polyphenols Nutrition 0.000 claims description 10
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 9
- 239000004330 calcium propionate Substances 0.000 claims description 9
- 235000010331 calcium propionate Nutrition 0.000 claims description 9
- 239000004302 potassium sorbate Substances 0.000 claims description 9
- 235000010241 potassium sorbate Nutrition 0.000 claims description 9
- 229940069338 potassium sorbate Drugs 0.000 claims description 9
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 8
- -1 amido propyl amine Chemical compound 0.000 claims description 8
- 239000010480 babassu oil Substances 0.000 claims description 8
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 8
- WGYKZJWCGVVSQN-UHFFFAOYSA-N mono-n-propyl amine Natural products CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 8
- 235000011152 sodium sulphate Nutrition 0.000 claims description 8
- 244000269722 Thea sinensis Species 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000003755 preservative agent Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- OPVLOHUACNWTQT-UHFFFAOYSA-N azane;2-dodecoxyethyl hydrogen sulfate Chemical compound N.CCCCCCCCCCCCOCCOS(O)(=O)=O OPVLOHUACNWTQT-UHFFFAOYSA-N 0.000 abstract description 3
- 230000002335 preservative effect Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 4
- 230000000813 microbial effect Effects 0.000 description 3
- 210000004761 scalp Anatomy 0.000 description 3
- 208000001840 Dandruff Diseases 0.000 description 2
- 201000004624 Dermatitis Diseases 0.000 description 2
- 229960001617 ethyl hydroxybenzoate Drugs 0.000 description 2
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- JLHMJWHSBYZWJJ-UHFFFAOYSA-N 1,2-thiazole 1-oxide Chemical compound O=S1C=CC=N1 JLHMJWHSBYZWJJ-UHFFFAOYSA-N 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000004403 ethyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000003648 hair appearance Effects 0.000 description 1
- 239000003845 household chemical Substances 0.000 description 1
- ZCTXEAQXZGPWFG-UHFFFAOYSA-N imidurea Chemical compound O=C1NC(=O)N(CO)C1NC(=O)NCNC(=O)NC1C(=O)NC(=O)N1CO ZCTXEAQXZGPWFG-UHFFFAOYSA-N 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- GYCKQBWUSACYIF-UHFFFAOYSA-N o-hydroxybenzoic acid ethyl ester Natural products CCOC(=O)C1=CC=CC=C1O GYCKQBWUSACYIF-UHFFFAOYSA-N 0.000 description 1
- CHHHXKFHOYLYRE-STWYSWDKSA-M potassium sorbate Chemical compound [K+].C\C=C\C=C\C([O-])=O CHHHXKFHOYLYRE-STWYSWDKSA-M 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
The invention discloses a nourishing hair shampoo containing a silk fibroin amino acid. The nourishing hair shampoo comprises the following components, by weight: 8-12% of ammonium lauryl ether sulfate, 0.5-1.5% of babassuamidopropylamine oxide, 2-6% of propylene glycol, 0.4-0.6% of the silk fibroin amino acid, 0.1-0.3% of a preservative, and the balance being water. The nourishing hair shampoo containing the silk fibroin amino acid is rich in bubbles, and has a good nourishing effect on hair damaged by chemical and external reasons.
Description
Technical field
The present invention relates to a kind of shampoo, be specifically related to a kind of silk fibroin amino acid and nourish shampoo.
Background technology
Shampoo is indispensable requisites in people's daily life, can remove greasy dirt and the scurf on surface, and have no adverse effects to hair, scalp and health of human body during use from hair and scalp.Shampoo is of a great variety, divides mainly contain transparent hair shampoo, paste shampoo, bead light shampoo, recuperating shampoo, scalp care hair shampoo, special shampoo etc. by dosage form and function.
In recent years, due to the raising of people's quality of the life, increasing of shampoos, it is also proposed increasing requirement to shampoo.Both needed shampoo to have the anti-dandruff effect of good decontamination, and needed again it to have good abnormal smells from the patient, and also needed the gloss keeping hair quality simultaneously, there is the longer shelf-life.
In order to extend the shelf-life of shampoo, its long-term placement after Kaifeng uses still is never degenerated, usual meeting adds a certain amount of antiseptic in shampoo, but the efficient antiseptic that shampoo at present is on the market conventional has methyl parahydroxybenzoate (i.e. methyl hydroxybenzoate), ethylparaben (i.e. ethyl hydroxybenzoate), sodium benzoate, isothiazolone etc., they have certain zest to skin and eyes, with eye contact after, need to rinse with a large amount of clear water immediately; Even can cause part population skin allergy, the symptom such as dermatitis occurs, therefore its consumption in shampoo is also subject to strict control.
In addition, imidazolidinyl urea and in uride be all as formaldehyde donor as the principle of antiseptic, reached the effect of killing microorganisms by release formaldehyde, also can cause damage to human body skin when release formaldehyde exceeds standard, all strictly limit its content in a lot of country and even prohibit the use.
Summary of the invention
For above shortcomings in prior art, one of technical problem to be solved by this invention provides a kind of silk fibroin amino acid to nourish shampoo.
The present invention seeks to be achieved through the following technical solutions:
A kind of silk fibroin amino acid nourishes shampoo, is made up of: lauryl polyethenoxy ether sodium sulfate 8-12%, babassu oil amido propyl amine oxide 0.5-1.5% following compositions in weight percentage, propylene glycol 2-6%, silk fibroin amino acid 0.4-0.6%, antiseptic 0.1-0.2%, surplus is water.
Preferably,
Described antiseptic is made up of by weight following component: tea polyphenols 10-15 part, potassium sorbate 10-15 part, calcium propionate 10-15 part, butyl carbamic acid iodopropynyl ester 5-10 part.
In the present invention,
Lauryl polyethenoxy ether sodium sulfate, English name: Ammonium lauryl ether sulfate, No. CAS: 32612-48-9.
Babassu oil amido propyl amine oxide, No. CAS: 124046-26-0.
Propylene glycol, No. CAS: 26264-14-2.
Silk fibroin amino acid, CAS accession number: 96690-41-4.
Tea polyphenols, Tea Polyphenols, No. CAS: 84650-60-2.
Potassium sorbate, CAS:24634-61-5.
Calcium propionate, No. CAS: 4075-81-4.
Butyl carbamic acid iodopropynyl ester, No. CAS: 55406-53-6.
Silk fibroin amino acid of the present invention nourishes shampoo, foaming abundancy, has good nourishing act on for the hair by chemistry and exopathogenic factor damage.Silk fibroin amino acid of the present invention nourishes shampoo, selects the antiseptic that the compatibility of tea polyphenols, potassium sorbate, calcium propionate and butyl carbamic acid iodopropynyl ester is made, but there is good Synergistic kill effect and security performance.
Detailed description of the invention
Embodiment further illustrates of the present invention below, instead of limit the scope of the invention.In the present invention, if no special instructions, each raw material all in working substance content for 100%.
Embodiment 1
A kind of silk fibroin amino acid nourishes shampoo, and be made up of following compositions in weight percentage: lauryl polyethenoxy ether sodium sulfate 10%, babassu oil amido propyl amine oxide 1%, propylene glycol 4%, silk fibroin amino acid 0.5%, antiseptic 0.2%, surplus is water.
Foregoing preservatives, is made up of by weight following component: tea polyphenols 10 parts, potassium sorbate 10 parts, calcium propionate 10 parts, butyl carbamic acid iodopropynyl ester 10 parts.Tea polyphenols, potassium sorbate, calcium propionate and butyl carbamic acid iodopropynyl ester are uniformly mixed, namely can be made into mixing antiseptic.
Get appropriate water, be heated to 80-90 DEG C, in whipping process, add lauryl polyethenoxy ether sodium sulfate and babassu oil amido propyl amine oxide in described ratio, after stirring, reduce temperature to 50-60 DEG C, add propylene glycol, silk fibroin amino acid and mixing antiseptic, stir after 1.5 hours, be cooled to room temperature, obtain silk fibroin amino acid and nourish shampoo.
Embodiment 2
A kind of silk fibroin amino acid nourishes shampoo, and be made up of following compositions in weight percentage: lauryl polyethenoxy ether sodium sulfate 10%, babassu oil amido propyl amine oxide 1%, propylene glycol 4%, silk fibroin amino acid 0.5%, antiseptic 0.2%, surplus is water.
Foregoing preservatives, is made up of by weight following component: potassium sorbate 20 parts, calcium propionate 10 parts, butyl carbamic acid iodopropynyl ester 10 parts.
Be prepared by the method for embodiment 1, obtain silk fibroin amino acid and nourish shampoo.
Embodiment 3
A kind of silk fibroin amino acid nourishes shampoo, and be made up of following compositions in weight percentage: lauryl polyethenoxy ether sodium sulfate 10%, babassu oil amido propyl amine oxide 1%, propylene glycol 4%, silk fibroin amino acid 0.5%, antiseptic 0.2%, surplus is water.
Foregoing preservatives, is made up of by weight following component: tea polyphenols 10 parts, calcium propionate 20 parts, butyl carbamic acid iodopropynyl ester 10 parts.
Be prepared by the method for embodiment 1, obtain silk fibroin amino acid and nourish shampoo.
Embodiment 4
A kind of silk fibroin amino acid nourishes shampoo, and be made up of following compositions in weight percentage: lauryl polyethenoxy ether sodium sulfate 10%, babassu oil amido propyl amine oxide 1%, propylene glycol 4%, silk fibroin amino acid 0.5%, antiseptic 0.2%, surplus is water.
Foregoing preservatives, is made up of by weight following component: tea polyphenols 20 parts, potassium sorbate 10 parts, butyl carbamic acid iodopropynyl ester 10 parts.
Be prepared by the method for embodiment 1, obtain silk fibroin amino acid and nourish shampoo.
Test case
The silk fibroin amino acid of embodiment 1-4 is nourished shampoo and puts into couveuse (40 DEG C, 95% humidity), place and carry out Microbial Challenge test in 28 days, select Hu Mei, " potentiation of formulation preservative for cosmetic " of Chen Yijun (" household chemicals science " the 29th volume the 12nd phase, in December, 2006) test strain of page 4 table 6, with reference to the evaluation criterion of document 2.3.2.3, when Microbial Challenge tests 0 day, the initial strains concentration of mixed cell and mixing mycete is 5 × 10
5cfu/g (ml).
Table 1: Microbial Challenge result of the test (cfu/g (ml))
From table 1 result, the silk fibroin amino acid of embodiment 1 is nourished shampoo and after 28 days in test, is made the bacterial strain concentration of mixed cell all be down to 10cfu/g (ml) below, prove that it has stronger inhibitory or killing effect to antibacterial.Antiseptic effect is obviously better than embodiment 2-4.
Therefore the antiseptic that the compatibility of tea polyphenols, potassium sorbate, calcium propionate and butyl carbamic acid iodopropynyl ester is made has been selected, but what have good Synergistic kills effect, the silk fibroin amino acid that the present invention selects this antiseptic to make is nourished shampoo and is had good anti-corrosive properties and security performance simultaneously.
Claims (1)
1. a silk fibroin amino acid nourishes shampoo, it is characterized in that, be made up of following compositions in weight percentage: lauryl polyethenoxy ether sodium sulfate 8-12%, babassu oil amido propyl amine oxide 0.5-1.5%, propylene glycol 2-6%, silk fibroin amino acid 0.4-0.6%, antiseptic 0.1-0.2%, surplus is water;
Described antiseptic is made up of by weight following component: tea polyphenols 10-15 part, potassium sorbate 10-15 part, calcium propionate 10-15 part, butyl carbamic acid iodopropynyl ester 5-10 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310307567.9A CN103356407B (en) | 2013-07-20 | 2013-07-20 | Nourishing hair shampoo containing silk fibroin amino acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310307567.9A CN103356407B (en) | 2013-07-20 | 2013-07-20 | Nourishing hair shampoo containing silk fibroin amino acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103356407A CN103356407A (en) | 2013-10-23 |
| CN103356407B true CN103356407B (en) | 2015-04-29 |
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| CN201310307567.9A Expired - Fee Related CN103356407B (en) | 2013-07-20 | 2013-07-20 | Nourishing hair shampoo containing silk fibroin amino acid |
Country Status (1)
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108498369A (en) * | 2018-05-08 | 2018-09-07 | 江苏澳特丝生物科技有限公司 | A kind of application of fibroin albumen in shampoo |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1080320A (en) * | 1992-06-16 | 1994-01-05 | 张许昌 | Natural silksaine proteins and vitamin soothing soap |
-
2013
- 2013-07-20 CN CN201310307567.9A patent/CN103356407B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1080320A (en) * | 1992-06-16 | 1994-01-05 | 张许昌 | Natural silksaine proteins and vitamin soothing soap |
Non-Patent Citations (3)
| Title |
|---|
| 中华人民共和国卫生部.化妆品组分中限用防腐剂.《化妆品卫生规范》.2007,第70-72页. * |
| 天然丝素在化妆品中的护肤特性及应用;贾艳梅;《精细与专用化学品》;19991231(第14期);第13-14页 * |
| 徐艳萍等.多功能洗发香波.《化妆品》.科学技术文献出版社,2002,第199页. * |
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| CN103356407A (en) | 2013-10-23 |
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Inventor after: Yu Wenfeng Inventor before: Chen Longdi |
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Free format text: CORRECT: INVENTOR; FROM: CHEN LONGDI TO: YU WENFENG |
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Effective date of registration: 20160222 Address after: Yongxing village, Taihe Town Longxing Road, Baiyun District of Guangzhou City, Guangdong Province, No. 8 by 510540 Patentee after: GUANGZHOU KOUYAN COSMETICS CO.,LTD. Address before: 201111 Shanghai city Minhang District Yuanjiang Road No. 5500 building first room E2128 Patentee before: SHANGHAI YANZI CHEMICAL TECHNOLOGY Co.,Ltd. |
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