CN103355332A - Sterilization composition containing SYP-Z048 and pyraclostrobin - Google Patents
Sterilization composition containing SYP-Z048 and pyraclostrobin Download PDFInfo
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- CN103355332A CN103355332A CN2013102668821A CN201310266882A CN103355332A CN 103355332 A CN103355332 A CN 103355332A CN 2013102668821 A CN2013102668821 A CN 2013102668821A CN 201310266882 A CN201310266882 A CN 201310266882A CN 103355332 A CN103355332 A CN 103355332A
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- pyraclostrobin
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Abstract
The invention relates to a sterilization composition containing SYP-Z048 and pyraclostrobin. The effective components of SYP-Z048 and pyraclostrobin are in binary compound, the mass ratio of SYP-Z048 to pyraclostrobin is 1-50 to 50-1, the mass portion of the effective components of SYP-Z048 and pyraclostrobin in the preparation is 1-80%, the rest components in the preparation are auxiliary elements acceptable in pesticides, and the sterilization composition can be prepared into missible oil, an suspending agent, wettable powder, water dispersible granule, emulsion in water, microemulsion, granula and microcapsule formulation. The sterilization composition has excellent prevention and treatment effects on gray mold of cucurbites, powdery mildew of cucumbers, downy mildew, macrophoma musae and leaf spot disease.
Description
Technical field
The present invention relates to the agriculture chemical compounding technical field, particularly relate to a kind of bactericidal composition that contains SYP-Z048 and pyraclostrobin.
Background technology
SYP-Z048 is the bactericide of Shenyang Chemical Engineering Inst's initiative, belongs to the synthetic inhibition bactericide of sterol, by the root dispenser, can effectively control not generation and the harm of disease of leaf on the ground.Bactericidal activity with wide spectrum; there is protection and therapeutic action and good interior absorption simultaneously; be mainly used in the control of plant botrytis, the chemistry of SYP-Z048 is called N-methyl-3-(4-chlorine) phenyl-5-methyl-5-pyridine-3-methyl-oxazoline, and its chemical structural formula is
.
Pyraclostrobin (pyraclostrobin) is the bactericide of BASF AG's latest model methoxy acrylic.Pyraclostrobin is the New-type wide-spectrum bactericide.The mechanism of action: be the mitochondrial respiratory inhibitor. by stoping electronics to shift in cytochrome b cl is synthetic.There is protection, treatment, blade infiltration conduction.Pyraclostrobin missible oil shows that through the field control effectiveness test result powdery mildew of cucumber, downy mildew and banana freckle, leaf spot are had to control efficiency preferably.Chemical name: N-f2 mono-" 1 one (4 monochloro-benzene) 1H-pyrazoles-3-yloxymethyl " benzene is foretold N mono-methoxy methyl carbamate.Its chemical structural formula is
Using chemical agent is the most effectively means of controlling plant diseases.But long-term use single chemical bactericide continuously high dose, easily cause the problems such as residual, the environmental pollution of medicament and anti-pesticide resistance fungi development.Reasonably chemical bactericide is composite or be mixed and have the expansion fungicidal spectrum, improve control efficiency, extend the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce residual, delay Antifungal resistance and the positive characteristics such as drug-fast generation and development, bactericide compounded is one of the effective method the most addressed the above problem.Exploitation new product bactericide price is constantly soaring, and by contrast, exploitation is efficient with research, low toxicity, low-residual composite be mixed there is small investment, the lead time is short and be subject to domestic and international attention, the numerous and confused dynamics that develops that strengthens.We filter out SYP-Z048 and pyraclostrobin and carry out compositely on the basis of lab screening and field trial, have obvious synergistic effect.And there is no at present the people about the composite bactericidal composition of SYP-Z048 and pyraclostrobin and application reported.
Summary of the invention
Based on above situation, the object of the invention is to provide a kind of new and effective pesticide sterilizing composite.Melon gray mold, powdery mildew of cucumber, downy mildew and banana freckle, leaf spot are had to control efficiency preferably.
Technical scheme of the present invention realizes by following measures:
A kind of bactericidal composition that contains SYP-Z048 and pyraclostrobin, two yuan of the active ingredient SYP-Z048 of this bactericidal composition and pyraclostrobins are composite, and all the other are auxiliary element.In wherein said bactericidal composition, the mass ratio of active ingredient SYP-Z048 and pyraclostrobin is 1～50: 50～1, described bactericidal composition of the present invention is 1～20: 20～1 o'clock through the mass ratio of toxicity test experimental verification SYP-Z048 and pyraclostrobin, and synergistic effect is better.
The formulations of pesticide that described bactericidal composition of the present invention can be prepared are missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion, granule, microcapsule formulations.Wherein active ingredient SYP-Z048 and the pyraclostrobin gross mass in preparation accounts for 1%～80% of the whole quality of the pharmaceutical preparations, while wherein accounting for 5%～50%, and toxicity and the residual balance preferably that reaches, cost is also lower.
The specific embodiments of the formulations of pesticide that bactericidal composition of the present invention is mixed with is as follows:
Described bactericidal composition is cream preparation, and the mass fraction of component is 1～50 part of: SYP-Z048; 1～50 part of pyraclostrobin; 10～30 parts of conventional emulsifiers; 20～50 parts of conventional solvents; 1～5 part of conventional synergist.The concrete production stage of this cream preparation adds emulsifier, the synergist rear oily liquids that becomes transparent and homogeneous that stirs again for first active ingredient SYP-Z048 and pyraclostrobin being added in solvent after dissolving fully, filling, can be made into the cream preparation of the present composition.
Described bactericidal composition is suspending agent, and the mass fraction of component is 1～50 part of: SYP-Z048; 1～50 part of pyraclostrobin; 5～20 parts of dispersants; 1～5 part of antifreezing agent; 0.1～2 part of thickener; 0.1～0.8 part of defoamer; 0～10 part of penetrating agent; 0.1～5 part of pH value conditioning agent; Water, surplus.The concrete production stage of this suspending agent is for first mixing other auxiliary agents, mix through high speed shear, add active ingredient SYP-Z048 and pyraclostrobin, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, can be made into the suspending agent preparation of the present composition.
Described bactericidal composition is wetting powder, and the mass fraction of component is 1～50 part of: SYP-Z048; 1～50 part of pyraclostrobin; 3～10 parts of dispersants; 1～5 part of wetting agent; Filler, surplus.The concrete production stage of this wetting powder is: by above-mentioned formula, the active ingredient SYP-Z048 is mixed with pyraclostrobin and dispersant, wetting agent and filler, uniform stirring in stirred tank, mixing after airslide disintegrating mill, can be made into the wetting powder of the present composition.
Described bactericidal composition is water dispersible granules, and the mass fraction of component is 1～50 part of: SYP-Z048; 1～50 part of pyraclostrobin; 3～10 parts of dispersants; 1～10 part of wetting agent; 1～5 part of disintegrant; Filler, surplus.The concrete production stage of this water dispersible granules is: by above-mentioned formula, the active ingredient SYP-Z048 is mixed with pyraclostrobin and dispersant, wetting agent, disintegrant and filler, with micro jet, pulverize, through mediating, then add in the fluidized bed prilling dryer and carry out granulation, drying, screening by sample analysis, can be made into the water dispersible granules of the present composition.
Described bactericidal composition is aqueous emulsion, and the mass fraction of component is 1～50 part of: SYP-Z048; 1～50 part of pyraclostrobin; 3～30 parts of emulsifier; 5～15 parts of solvents; 2～15 parts of stabilizing agents; 1～5 part of antifreezing agent; 0.1～8 part of defoamer; 0.2～2 part of thickener; Water, surplus.The concrete production stage of this aqueous emulsion is: at first SYP-Z048 and pyraclostrobin, solvent and emulsifier, cosolvent are added together, make to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes into uniform water; When the reactor high speed stirs, oil phase is added to water, slowly add water until reach the phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type, can be made into the aqueous emulsion of the present composition.
Described bactericidal composition is microemulsion, and the mass fraction of component is 1～50 part of: SYP-Z048; 1～50 part of pyraclostrobin; 10～30 parts of emulsifier, 1～8 part of antifreezing agent, 0.5～10 part of stabilizing agent, 20～50 parts of conventional solvent cosolvents.SYP-Z048 and pyraclostrobin are dissolved fully with cosolvent, then add other compositions such as emulsifier, antifreezing agent stabilizing agent, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Described bactericidal composition is granule, and the mass fraction of component is 1～50 part of: SYP-Z048; 1～50 part of pyraclostrobin; 1～10 part of wetting dispersing agent; 0.1～5 part of thickener; 0.1～5 part of defoamer; Castor oil, surplus is supplied.The active ingredient SYP-Z048 is mixed in the ratio of formula with each components such as pyraclostrobin, dispersant, stabilizing agent, defoamer and solvents, after putting into the grinding of sand milling still, send in mixer for well-distribution and mix and get product.
Described bactericidal composition is microcapsule formulations, and the mass fraction of component is 1～50 part of: SYP-Z048; 1～50 part of pyraclostrobin; 5～20 parts, urea; 5～20 parts, formaldehyde; 5～20 parts of emulsifying dispersants; 1～5 part of antifreezing agent; 0.1～2 part of thickener; 0.1～0.8 part of defoamer; Water, surplus.In being housed, the there-necked flask of agitating device adds urea and formaldehyde (the amount of substance ratio is about l:1.5～2.0), with the pH value to 8 of sodium hydroxide solution regulator solution～9 left and right, then be warming up to 70～80 ℃, reaction obtains stable urea resin prepolymer.The former medicine of getting a certain amount of SYP-Z048 and pyraclostrobin is dissolved in cyclohexane, and adds emulsifying dispersant in solution, follows vigorous stirring, the O/W type stable emulsion that to be made into the aqueous solution of take containing emulsifying dispersant be water.Above-mentioned urea resin prepolymer is added in emulsion, regulate the pH value, polymerization reaction take place under the acid catalysis condition, be wrapped oil phase substance, forms microcapsule granule.Slowly heat up, solidify, temperature is controlled at 40～50 ℃, hardening time 1h.Selection adds appropriate auxiliary agent, the microcapsule suspending agent that gets final product stablely.
Wherein above-described emulsifier is selected from calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, the alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, any or more than one any mixtures than forming in polyoxyethylene aliphatic alcohol ether.
Described solvent is dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, the turpentine-based vegetable oil code name is ND-45, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), one or more in the water equal solvent are arbitrarily than the mixture formed.
It is LG-3, GY-D1252, GY-D1256, SNWGF-01 that described dispersant is selected from the polycarboxylate code name, the lignosulfonates code name is 201107,21108, alkylphenol polyoxyethylene methyl ether condensate sulfate, the alkylsulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, aliphatic amine polyoxyethylene ether, one or more in the fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, and Nekal BX, moistening bleeding agent F, alkylbenzenesulfonate polyoxyethylene triphen is phosphenylic acid salt dimly, spaonin powder, silkworm excrement, one or more in the soapberry powder.
Described disintegrant is selected from bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, one or more in sodium bicarbonate.
Described thickener is selected from xanthans, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, Magnesiumaluminumsilicate, in polyvinyl alcohol one or more.
Described stabilizing agent is selected from sodium citrate, a kind of in resorcinol.
Described antifreezing agent is selected from ethylene glycol, propane diols, one or more in glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20the saturated fat acid compounds, C
8-10one or more of fatty alcohol.
Described filler is selected from kaolin, diatomite, bentonite, attapulgite, white carbon, starch, one or more in precipitated calcium carbonate.
The present invention be take the composite bactericide that SYP-Z048 and pyraclostrobin be active ingredient and is had obvious synergistic effect, delay the drug-fast generation in key, and reduced to become to produce cost and use cost, melon gray mold, powdery mildew of cucumber, downy mildew and banana freckle, leaf spot are had to control efficiency preferably.
Embodiment
For making technical scheme of the present invention, purpose and advantage are clearer, and the present invention describes with following specific embodiment, but the present invention is not limited to these examples.The mode that effect experiment of the present invention adopts indoor biometrics and field trial to combine, if no special instructions, the ratio of below mentioning is all ratio of quality and the number of copies.
The proportioning co-toxicity experiments different from pyraclostrobin of embodiment: SYP-Z048.
1.1 reagent agent
The former medicine of 96% SYP-Z048, the former medicine of 95% pyraclostrobin, above-mentioned former medicine provides by research and development department of extra large rel medicine company limited company.
1.2 test target
The powdery mildew of cucumber germ, separation and purification gained from the highly dense powdery mildew of cucumber incidence of leaf taken back in Weifang is cultivated and is preserved in 4 ℃ of refrigerators on the PDA inclined-plane.
For the examination medium
:
The PDA medium
:potato 200g, glucose 20g, agar 20g, water 1000ml.
The AEA medium
:dusty yeast 5g/L, glycerine 20mL/L, MgSO
40.25g/L, NaNO
36g/L, KCl 0.5g/L, KH
2pO
41.5g/L, agar powder 20g/L, deionized water 1L.
1.3 test method
1.3.1 medicament preparation
First use the former medicine of acetone solution, according to the result of preliminary experiment, two appropriate former medicines are made into to several different proportionings, then it is stand-by with acetone, each processing to be diluted to respectively to several concentration gradients.
Susceptible cucumber cultivation, in pot for growing seedlings, is placed in to greenhouse and cultivates, and plant grows to three to four leaf after dates, gathers the blade of identical leaf age, for cultivation and the mensuration of powdery mildew of cucumber bacterium.
1.3.2 the cultivation of wheat powdery mildew and the preparation of spore suspension
Wheat powdery mildew adopts the plants method to cultivate under 20 ℃, the condition of 12h alternation of light and darkness, and every 30 d turn culture 1 time.During inoculation, with the conidium on sterile water wash-out incidence of leaf, being mixed with spore concentration is l * 10
6the suspension of individual/mL.
1.3.3 strains tested sensitivity testing
Adopt leaf dish moisturizing method to carry out toxicity test.First the blade of collection is prepared into to the leaf dish that diameter is 1.5cm, mix at random, be placed in respectively the series concentration liquid configured and soak lh, 50 leaf dishes of each concentration, test is with the blank that is treated to of adding medicine not, after soaking end, leaf faces up and puts on the blotting paper wetting in identical liquor strength, liquid on the leaf dish is blotted, the spore suspension l0L prepared is inoculated in to leaf dish central authorities, after room temperature is placed 5 min, is placed under 20 ℃, the condition of 1 2h alternation of light and darkness and cultivates, measure the onset area on the leaf dish after 10d, calculate EC
50.
On the basis of preliminary experiment, respectively single dose SYP-Z048 and pyraclostrobin are carried out to toxicity test in order to upper method, the two EC
50value is respectively 4.9772 ㎎/l and 12.1579 ㎎/l.
The percentage that accounts for the leaf disc area according to lesion area is divided sick level
0 grade: anosis;
1 grade: the sorus area accounts for below 5% of whole leaf area;
3 grades: the sorus area accounts for below the 6%-10% of whole leaf area;
5 grades: the sorus area accounts for below the 11%-20% of whole leaf area;
7 grades: the sorus area accounts for below the 21%-50% of whole leaf area;
9 grades: the sorus area accounts for more than 50% of whole leaf area;
1.3.4 mixture toxicity test and interpretation of result
Carry out the toxicity test of mixture according to mixed ratio by single dose toxicity test method.
If contrast lethality<5%, do not proofread and correct, the contrast lethality, between 5%-20%, is proofreaied and correct by formula 2, the contrast lethality > 20%, test need be reformed.
The logarithm value of drug concentration (mg/L) of take is independent variable x, and the probability value of corrected mortality of take is dependent variable y, sets up respectively the virulence regression equation formula, adopts DPS software to calculate the EC of single dose and each proportioning mixture
50calculate co-toxicity coefficient (CTC) according to the abundant method of Sun Yun.Co-toxicity coefficient CTC, computing formula is as follows: (take SYP-Z048 as the standard medicament, its toxicity index is 100):
The EC of the toxicity index of pyraclostrobin (TI)=SYP-Z048
50the EC of/pyraclostrobin
50* 100
The EC of true toxicity index (ATI) the=SYP-Z048 of M
50the EC of/M
50* 100
The TI of the TI of theoretical toxicity index (TTI) the=SYP-Z048 of M * P SYP-Z048+pyraclostrobin * P pyraclostrobin
The TTI of the ATI/M of the co-toxicity coefficient of M (CTC)=M * 100
In formula:
M is SYP-Z048 and the mixture of the different proportionings of pyraclostrobin
The P SYP-Z048 is SYP-Z048 shared ratio in mixture
The P pyraclostrobin is pyraclostrobin shared ratio in mixture.
2.1 toxicity test result
Table 1 SYP-Z048 and the pyraclostrobin toxicity test to powdery mildew of cucumber
As can be seen from the table, the result of the test of different proportion proportioning shows, dilute respectively and all show stronger synergistic effect in the active ingredient ratio, wherein take SYP-Z048 and pyraclostrobin as 1:20～20:1 the time the good suggestion of synergistic effect suitable proportion 1:10～10:1 left and right mixture preparation is carried out to further field control effectiveness test, to estimate its field practical application effect.
3, field trial is prevented and treated powdery mildew of cucumber, the experimental result of gray mold of cucumber
3.1 field trial is prevented and treated powdery mildew of cucumber
3.1.1 test method
Test is at 4 points of Pingdu City cucumber Di，Mei community, Shandong investigation, and every some investigation 2 strains, put down in writing occurring degree by staging, and grade scale is as follows:
0 grade: anosis;
1 grade: the sorus area accounts for below 5% of whole leaf area;
3 grades: the sorus area accounts for below the 6%-10% of whole leaf area;
5 grades: the sorus area accounts for below the 11%-20% of whole leaf area;
7 grades: the sorus area accounts for below the 21%-50% of whole leaf area;
9 grades: the sorus area accounts for more than 50% of whole leaf area.
3.1.2 control time and number of times
Test is investigated 4 times altogether, and radix investigation before medicine is investigated after 7 days, 7 days for the second time and medicine after medicine for the first time in 15 days.
3.1.3 drug effect computational methods
Sick leaf rate (%)=sick number of sheets/investigate total number of sheets * 100
Disease index=∑ (the sick numbers of sheets at different levels * relative level numerical value)/(investigating total number of sheets * 9) * 100
Control efficiency (%)=(disease index after disease index before 1-(blank district medicine * treatment region medicine)/(disease index before disease index after blank district medicine * treatment region medicine)) * 100.
3.1.4 poisoning investigation method
After dispenser, whether continuous 15d range estimation medicament has poisoning to crop.
3.1.5 result of the test and analysis
Each processes the effect of preventing and treating powdery mildew of cucumber.(table 2)
Each processes the effect of preventing and treating powdery mildew of cucumber table 2
As shown in Table 2 the SYP-Z048 pyraclostrobin with 5:1 ratio composite bactericide for powdery mildew of cucumber control successful higher than SYP-Z048 pyraclostrobin single dose, bactericidal effect increases progressively with the increase of dosage.According to the field range estimation, in the test dose scope, plant growth is normal, and the poisoning phenomenon to cucumber does not all appear in each treatment agent, illustrates that it is safe to cucumber.Advise that the bactericide different from the mechanism of action mixes use to delay the drug-fast generation of germ.
3.2 field trial control gray mold of cucumber
3.2.1 test method
Test site, in the Pingdu herbary of Shandong, is cucumber for the examination vegetables, and growing way is better, and test is established every mu and established contrast totally 10 processing.Every processing repeats 4 times, and random district group is arranged, 14 square metres of community areas.
3.2.2 control time and number of times
Before dispenser, after the 1st medicine, after 7 days and the 2nd dispenser, 7 days, 14 Tian，Mei communities adopt 5 samplings of diagonal, every some investigation 2 strains, and totally 10 strains, investigation complete stool blade, by leaf classification investigation occurring degree, calculate disease and refer to and control efficiency.
Grade scale is as follows:
0 grade: anosis;
1 grade: lesion area accounts for below 5% of one-piece blade area;
3 grades: lesion area accounts for the 6%-15% of one-piece blade area;
5 grades: lesion area accounts for the 16%-25% of one-piece blade area;
7 grades: lesion area accounts for the 26%-50% of one-piece blade area;
9 grades: lesion area accounts for more than 50% of one-piece blade area.
3.2.3 drug effect computational methods
Sick leaf rate (%)=sick number of sheets/investigate total number of sheets * 100
Disease index=∑ (the sick numbers of sheets at different levels * relative level numerical value)/(investigating total number of sheets * 9) * 100
Control efficiency (%)=(disease index after disease index before 1-(blank district medicine * treatment region medicine)/(disease index before disease index after blank district medicine * treatment region medicine)) * 100.
3.2.4 poisoning investigation method
After dispenser, whether continuous 14d range estimation medicament has poisoning to crop.
3.2.5 result of the test and analysis
Each processes the effect of control gray mold of cucumber.(table 3)
The Mixed Pharmacy of different proportion, tested by different consumptions as can be seen from Table 3, the SYP-Z048 pyraclostrobin with 5:1 ratio compound medicine after its right control all be better than contrasting medicament and bactericidal effect and increase progressively with the increase of dosage.According to the field range estimation, in the test dose scope, plant growth is normal, and the poisoning phenomenon to cucumber does not all appear in each treatment agent, illustrates that it is safe to cucumber.Advise that the bactericide different from the mechanism of action mixes use to delay the drug-fast generation of germ.
In sum, the bactericidal composition that the present invention contains SYP-Z048 and pyraclostrobin, have good control efficiency to powdery mildew of cucumber, gray mold, and it is to the target crop safety.Complex preparation has not only improved preventive effect, and has enlarged fungicidal spectrum, widens the scope of application, reduces costs, and multiple diseases is played to the double effect of controlling of a medicine, alleviates manpower and materials, improves productivity effect.So the invention of this complex preparation is of great significance social tool with popularization.
Claims (4)
1. a bactericidal composition that contains SYP-Z048 and pyraclostrobin, it is characterized in that: the active ingredient of this bactericidal composition is SYP-Z048 and pyraclostrobin binary built, all the other are auxiliary element, and wherein the mass ratio of active ingredient SYP-Z048 and pyraclostrobin is 1～50: 50～1.
2. bactericidal composition according to claim 1, is characterized in that: SYP-Z048 and the pyraclostrobin gross weight in preparation accounts for 1%～80% of the whole quality of the pharmaceutical preparations.
3. bactericidal composition according to claim 2, is characterized in that: SYP-Z048 and the pyraclostrobin gross weight in preparation accounts for 5%～50% of the whole quality of the pharmaceutical preparations.
4. according to claim 1 or 2 or 3 described bactericidal compositions, it is characterized in that: the formulation of this bactericidal composition is missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion, microemulsion, granule, microcapsule formulations
.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104823985A (en) * | 2015-05-07 | 2015-08-12 | 深圳诺普信农化股份有限公司 | Bactericidal composition containing SYP-Z048 and applications thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1035122A1 (en) * | 1999-03-11 | 2000-09-13 | Rohm And Haas Company | Heterocyclic subsituted isoxazolidines and their use as fungicides |
| CN101087529A (en) * | 2004-12-23 | 2007-12-12 | 巴斯福股份公司 | Fungicidal mixtures |
-
2013
- 2013-06-29 CN CN2013102668821A patent/CN103355332A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1035122A1 (en) * | 1999-03-11 | 2000-09-13 | Rohm And Haas Company | Heterocyclic subsituted isoxazolidines and their use as fungicides |
| CN101087529A (en) * | 2004-12-23 | 2007-12-12 | 巴斯福股份公司 | Fungicidal mixtures |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104823985A (en) * | 2015-05-07 | 2015-08-12 | 深圳诺普信农化股份有限公司 | Bactericidal composition containing SYP-Z048 and applications thereof |
| CN104823985B (en) * | 2015-05-07 | 2016-07-06 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition containing pyridine bacterium azoles and application thereof |
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