CN104054709A - Bactericidal composition containing meptyldinocap and fluazinam - Google Patents
Bactericidal composition containing meptyldinocap and fluazinam Download PDFInfo
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- CN104054709A CN104054709A CN201410237720.XA CN201410237720A CN104054709A CN 104054709 A CN104054709 A CN 104054709A CN 201410237720 A CN201410237720 A CN 201410237720A CN 104054709 A CN104054709 A CN 104054709A
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- fluazinam
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Abstract
The invention relates to a bactericidal composition containing meptyldinocap and fluazinam. The active ingredients of the bactericidal composition are meptyldinocap and fluazinam in a mass ratio of (1-50) to (50-1). Meptyldinocap and fluazinam are subjected to binary compounding. The preparation comprises 1-80% by mass of meptyldinocap, 1-80% by mass of fluazinam and the balance of auxiliary ingredients which are allowed to be used and accepted in pesticides. The dosage forms of the bactericidal composition include emulsifiable concentrate, suspension concentrate, wettable powder, water aqua, water dispersible granules, emulsion in water, microemulsion, granules and microcapsules. The bactericidal composition is suitable for controlling various powdery mildew of ornamental plants such as fruit trees, vegetables, flowers and plants and the like and field crops.
Description
Technical field
The present invention relates to agriculture chemical compounding technical field, particularly relate to a kind of bactericidal composition that contains nitre benzene bacterium ester and fluazinam.
Background technology
Nitre benzene bacterium ester (meptyldinocap, 2-different pungent-4,6-dinitrophenyl-2-butenoate (2,4-dinitro-6-(1-methylheptyl) phenylcrotonate, 2,4-DNOPC), CAS:131-72-6) be non-internal-absorting miticide, there is certain contact bactericidal action simultaneously.Gai Yaoyou The Dow Agrosciences, LLC. exploitation, nitre benzene bacterium ester is one of isomer with high bioactivity of separating from 6 kinds of isomer of sterilization (mite) agent karathane (dinocap, CAS:39300-45-3).Be mainly used in preventing and treating two spotted spider mite and the powdery mildew of apple, oranges and tangerines, pears, grape, cucumber, muskmelon, watermelon, pumpkin, strawberry, rose and ornamental plants, mulberry tree powdery mildew and eggplant two spotted spider mite are had to good control efficiency, also there is the effect of killing mite ovum simultaneously.
Fluazinam (SHIRLAN, test code number B-1216, IKF-1216, ICIA0912, the chloro-5-trifluoromethyl-2-of the chloro-N-(3-of 3-pyridine radicals)-α, α, α-tri-fluoro-2,6-dinitro-p-toluidine) be to be developed by the former industry of Japanese stone, by the pyridyl amine bactericide of ICI Agrochemicals (Xian Wei Syngenta Co.,Ltd) exploitation.Fluazinam has the bactericidal activity of wide spectrum, and phytophthora root rot, rotten stalk break, black spot, scab and other pathogene disease are had to good control efficiency.Concrete disease is as gray mold of cucumber, rot, downy mildew, charcoal seasonal febrile diseases, powdery mildew, stem's rot, tomato late blight, apple scab, leaf spot, Pear black spot, rust, rice blast, banded sclerotial blight, crown hull sugar, grape grey mould, downy mildew, citrus scab, gray mold, potato late blight, lawn spot disease.
Using chemical agent is the most effectively means of controlling plant diseases.But long-term use single chemical bactericide continuously high dose, easily cause the problems such as residual, the environmental pollution of medicament and resistance to pesticide resistance fungi development.Reasonably chemical bactericide is composite or be mixed and have expansion fungicidal spectrum, improve control efficiency, extend the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce residual, delay Antifungal resistance and the positive feature such as drug-fast generation and development, bactericide compounded is one of the effective method the most addressing the above problem.Exploitation new product bactericide price is constantly soaring, and by contrast, exploitation is efficient with research, low toxicity, low-residual composite be mixed there is small investment, the lead time is short and be subject to domestic and international attention, the numerous and confused dynamics that develops that strengthens.We filter out nitre benzene bacterium ester and fluazinam and carry out compositely on the basis of lab screening and field trial, have obvious synergistic effect.And about the composite bactericidal composition of nitre benzene bacterium ester and fluazinam and application, there is no at present people reported.
Summary of the invention
Based on above situation, the object of the invention is to provide a kind of new and effective pesticide sterilizing composite.Be mainly used in the various powdery mildews of the ornamental plantss such as fruit tree, vegetables, flowers, field crop.
Technical scheme of the present invention realizes by following measures:
A bactericidal composition that contains nitre benzene bacterium ester and fluazinam, active ingredient nitre benzene bacterium ester and two yuan of the fluazinams of this bactericidal composition are composite, and all the other are auxiliary element.In wherein said bactericidal composition, the mass ratio of active ingredient nitre benzene bacterium ester and fluazinam is 1～50: 50～1, described bactericidal composition of the present invention is through toxicity test experimental verification, the mass ratio of nitre benzene bacterium ester and fluazinam is 1～10: 10～1 o'clock, and synergistic effect is better.
The formulations of pesticide that described bactericidal composition of the present invention can be prepared are missible oil, suspending agent, wetting powder, aqua, water dispersible granules, aqueous emulsion, microemulsion, granule, microcapsule formulations.Wherein active ingredient nitre benzene bacterium ester and the gross mass of fluazinam in preparation account for 1%～80% of the whole quality of the pharmaceutical preparations, while wherein accounting for 10%～60%, and toxicity and residually reach good balance, cost is also lower.
The specific embodiments of the formulations of pesticide that bactericidal composition of the present invention is mixed with is as follows:
Described bactericidal composition is cream preparation, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of fluazinam; 10～30 parts of conventional emulsifiers; 20～50 parts of conventional solvents; 1～5 part of conventional synergist.The concrete production stage of this cream preparation is for first adding active ingredient nitre benzene bacterium ester and fluazinam in solvent the oily liquids that becomes transparent and homogeneous after adding again emulsifier, synergist to stir after dissolving completely, filling, can be made into the cream preparation of the present composition.
Described bactericidal composition is suspending agent, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of fluazinam; 5～20 parts of dispersants; 1～5 part of antifreezing agent; 0.1～2 part of thickener; 0.1～0.8 part of defoamer; 0～10 part of penetrating agent; 0.1～5 part of pH value conditioning agent; Water, surplus.The concrete production stage of this suspending agent is for first mixing other auxiliary agents, through high speed shear, mix, add active ingredient nitre benzene bacterium ester and fluazinam, in ball crusher, abrading-ball is 2～3 hours, make a diameter all below 5mm, can be made into the suspending agent preparation of the present composition.
Described bactericidal composition is wetting powder, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of fluazinam; 3～10 parts of dispersants; 1～5 part of wetting agent; Filler, surplus.The concrete production stage of this wetting powder is: by above-mentioned formula, active ingredient nitre benzene bacterium ester is mixed with fluazinam and dispersant, wetting agent and filler, uniform stirring in stirred tank, after airslide disintegrating mill, mixing, can be made into the wetting powder of the present composition.
Described bactericidal composition is water dispersible granules, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of fluazinam; 3～10 parts of dispersants; 1～10 part of wetting agent; 1～5 part of disintegrant; Filler, surplus.The concrete production stage of this water dispersible granules is: by above-mentioned formula, active ingredient nitre benzene bacterium ester is mixed with fluazinam and dispersant, wetting agent, disintegrant and filler, with micro jet, pulverize, through mediating, then add and in fluidized bed prilling dryer, carry out granulation, dry, screening by sample analysis, can be made into the water dispersible granules of the present composition.
Described bactericidal composition is aqueous emulsion, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of fluazinam; 3～30 parts of emulsifier; 5～15 parts of solvents; 2～15 parts of stabilizing agents; 1～5 part of antifreezing agent; 0.1～8 part of defoamer; 0.2～2 part of thickener; Water, surplus.The concrete production stage of this aqueous emulsion is: first nitre benzene bacterium ester and fluazinam, solvent and emulsifier, cosolvent are added together, make to be dissolved into uniform oil phase; By part water, antifreeze, other the insecticides adjuvant such as antimicrobial mixes into uniform water; When reactor high speed stirs, oil phase is added to water, slowly add water until reach phase inversion point, open clipper and carry out high speed shear, and add remaining water, shear about half an hour, form the aqueous emulsion of oil-in-water type, can be made into the aqueous emulsion of the present composition.
Described bactericidal composition is microemulsion, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of fluazinam; 10～30 parts of emulsifier, 1～8 part of antifreezing agent, 0.5～10 part of stabilizing agent, 20～50 parts of conventional solvent cosolvents.Nitre benzene bacterium ester and fluazinam are dissolved completely with cosolvent, then add other compositions such as emulsifier, antifreezing agent stabilizing agent, evenly mix, finally add water, after fully stirring, can be made into microemulsion.
Described bactericidal composition is granule, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of fluazinam; 1～10 part of wetting dispersing agent; 0.1～5 part of thickener; 0.1～5 part of defoamer; Castor oil, surplus is supplied.Each components such as active ingredient nitre benzene bacterium ester and fluazinam, dispersant, stabilizing agent, defoamer and solvent are mixed in the ratio of formula, put into after the grinding of sand milling still, send in mixer for well-distribution and mix and get product.
Described bactericidal composition is aqua, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of fluazinam; 0.1～30 part of wetting dispersing agent; 2～8 parts of antifreezing agents; 0.1～1 part of defoamer; 0.1～3 part of thickener; 5～15 parts of spreader-stickers; Water, surplus is supplied.By active ingredient nitre benzene bacterium ester and fluazinam, dissolve completely with cosolvent, then add other compositions such as dispersant, antifreezing agent, defoamer, evenly mix, finally add water, after fully stirring, get final product to obtain finished product.
Described bactericidal composition is microcapsule formulations, and the mass fraction of component is: 1～50 part of nitre benzene bacterium ester; 1～50 part of fluazinam; 5～20 parts, urea; 5～20 parts, formaldehyde; 5～20 parts of emulsifying dispersants; 1～5 part of antifreezing agent; 0.1～2 part of thickener; 0.1～0.8 part of defoamer; Water, surplus.In being housed, the there-necked flask of agitating device adds urea and formaldehyde (amount of substance ratio is about l:1.5～2.0), left and right, pH value to 8～9 with sodium hydroxide solution regulator solution, then be warming up to 70～80 ℃, reaction obtains stable urea resin prepolymer.Get a certain amount of nitre benzene bacterium ester and fluazinam and be dissolved in cyclohexane, and add emulsifying dispersant in solution, follow vigorous stirring, the O/W type stable emulsion that to be made into the aqueous solution of take containing emulsifying dispersant be water.Above-mentioned urea resin prepolymer is added in emulsion, regulate pH value, polymerization reaction take place under acid catalysis condition, is wrapped oil phase substance, forms microcapsule granule.Slowly heat up, solidify, temperature is controlled at 40～50 ℃, hardening time 1h.Selection adds appropriate auxiliary agent, the microcapsules that gets final product stablely.
Wherein above-described emulsifier is selected from calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, any or more than one any mixtures than forming in polyoxyethylene aliphatic alcohol ether.
Described solvent is dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine-based vegetable oil code name is ND-45, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), one or more in water equal solvent are arbitrarily than the mixture forming.
It is LG-3, GY-D1252, GY-D1256, SNWGF-01 that described dispersant is selected from polycarboxylate code name, lignosulfonates code name is 201107,201108, alkylphenol polyoxyethylene methyl ether condensate sulfate, alkylsulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, aliphatic amine polyoxyethylene ether, one or more in fatty acid glyceride APEO.
Described wetting agent is selected from lauryl sodium sulfate, calcium dodecyl benzene sulfonate, and Nekal BX, moistening bleeding agent F, alkylbenzenesulfonate polyoxyethylene triphen is phosphenylic acid salt dimly, spaonin powder, silkworm excrement, one or more in soapberry powder.
Described disintegrant is selected from bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, one or more in sodium bicarbonate.
Described thickener is selected from xanthans, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose, Magnesiumaluminumsilicate, in polyvinyl alcohol one or more.
Described stabilizing agent is selected from sodium citrate, a kind of in resorcinol.
Described antifreezing agent is selected from ethylene glycol, propane diols, one or more in glycerine.
Described defoamer is selected from silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10one or more of fatty alcohol.
Described filler is selected from kaolin, diatomite, bentonite, attapulgite, white carbon, starch, one or more in precipitated calcium carbonate.
The present invention be take the composite bactericide that nitre benzene bacterium ester and fluazinam be active ingredient and is had obvious synergistic effect, delay the drug-fast generation in key, and reduced to become to produce cost and use cost, be mainly used in the various powdery mildews of the ornamental plantss such as fruit tree, vegetables, flowers, field crop.
Embodiment
For making technical scheme of the present invention, object and advantage are clearer, and the present invention describes with following specific embodiment, but the present invention is not limited to these examples.The mode that effect experiment of the present invention adopts indoor biometrics and field trial to combine, if no special instructions, the ratio of below mentioning is all ratio of quality and the number of copies.
Embodiment: nitre benzene bacterium ester proportioning co-toxicity experiments different from fluazinam.
1.1 reagent agent
The former medicine of 96% fluazinam, the former medicine of 95% nitre benzene bacterium ester, above-mentioned former medicine provides by research and development department of extra large rel medicine company limited company.
1.2 test targets
Wheat powdery mildew germ, separation and purification gained the wheat powdery mildew incidence of leaf taking back from Fengyang County is cultivated and is preserved in 4 ℃ of refrigerators on PDA inclined-plane.
For examination medium
:
PDA medium
:potato 200g, glucose 20g, agar 20g, water 1000ml.
AEA medium
:dusty yeast 5g/L, glycerine 20mL/L, MgSO
40.25g/L, NaNO
36g/L, KCl 0.5g/L, KH
2pO
41.5g/L, agar powder 20g/L, deionized water 1L.
1.3 test method
1.3.1 medicament preparation
First use the former medicine of acetone solution, according to the result of preliminary experiment, two appropriate former medicines are made into several different proportionings, then it is stand-by with acetone, each processing to be diluted to respectively to several concentration gradients.
Susceptible wheat cultivation, in pot for growing seedlings, is placed in to greenhouse and cultivates, and plant grows to three to four leaf after dates, gathers the blade of identical leaf age, for cultivation and the mensuration of wheat powdery mildew.
1.3.2 the cultivation of wheat powdery mildew and the preparation of spore suspension
Wheat powdery mildew adopts plants method to cultivate under 20 ℃, the condition of 12h alternation of light and darkness, and every 30 d turn culture 1 time.During inoculation, with the conidium on sterile water wash-out incidence of leaf, being mixed with spore concentration is l * 10
6the suspension of individual/mL.
1.3.3 strains tested sensitivity testing
Adopt leaf dish moisturizing method to carry out toxicity test.First the blade of collection is prepared into the leaf dish that diameter is 1.5cm, mix at random, be placed in respectively the series concentration liquid configuring and soak lh, 50 leaf dishes of each concentration, test is with the blank that is treated to of adding medicine not, after immersion finishes, leaf faces up and puts on the wetting blotting paper of identical liquor strength, liquid on leaf dish is blotted, the spore suspension l0L preparing is inoculated in to leaf dish central authorities, and room temperature is placed after 5 min, is placed under 20 ℃, the condition of 1 2h alternation of light and darkness and cultivates, after 10d, measure the onset area on leaf dish, calculate EC
50.
The percentage that accounts for leaf disc area according to lesion area is divided sick level
0 grade: anosis;
1 grade: sorus area accounts for below 5% of whole leaf area;
3 grades: sorus area accounts for below the 6%-10% of whole leaf area;
5 grades: sorus area accounts for below the 11%-20% of whole leaf area;
7 grades: sorus area accounts for below the 21%-50% of whole leaf area;
9 grades: sorus area accounts for the more than 50% of whole leaf area;
1.3.4 mixture toxicity test and interpretation of result
By single dose toxicity test method, according to mixed ratio, carry out the toxicity test of mixture.
If contrast lethality <5%, does not proofread and correct, contrast lethality, between 5%-20%, is proofreaied and correct by formula 2, contrast lethality >20%, and test need be reformed.
The logarithm value of drug concentration (mg/L) of take is independent variable x, and the probability value of corrected mortality of take is dependent variable y, sets up respectively virulence regression equation formula, adopts DPS software to calculate the EC of single dose and each proportioning mixture
50according to the abundant method of Sun Yun, calculate co-toxicity coefficient (CTC).Co-toxicity coefficient CTC, computing formula is as follows: (the nitre benzene bacterium ester of take is standard medicament, and its toxicity index is 100):
The EC of the toxicity index of fluazinam (TI)=nitre benzene bacterium ester
50the EC of/fluazinam
50* 100
The EC of true toxicity index (ATI)=nitre benzene bacterium ester of M
50the EC of/M
50* 100
TI * P fluazinam of TI * P nitre benzene bacterium ester+fluazinam of theoretical toxicity index (TTI)=nitre benzene bacterium ester of M
TTI * 100 of the ATI/M of the co-toxicity coefficient of M (CTC)=M
In formula:
M is nitre benzene bacterium ester and the mixture of the different proportionings of fluazinam
P nitre benzene bacterium ester is nitre benzene bacterium ester shared ratio in mixture
P fluazinam is fluazinam shared ratio in mixture.
2.1 toxicity test results
Table 1 fluazinam and the toxicity test of nitre benzene bacterium ester to wheat powdery mildew
As can be seen from the table, the result of the test of different proportion proportioning shows, in active ingredient ratio, dilute respectively and all show stronger synergistic effect, wherein take nitre benzene bacterium ester and fluazinam as 1:10～10:1 time the good suggestion of synergistic effect suitable proportion 1:10～10:1 left and right mixture preparation is carried out to further field control effectiveness test, to evaluate its field practical application effect.
3, field trial control wheat powdery mildew, the experimental result of powdery mildew of cucumber
3.1 field trial control wheat powdery mildews
3.1.1 test method
Test site, in great Tong Qiao village, capital town, Fengyang County, is wheat for studying thing, and kind is short morning 781, broadcasts sowing, and growing way is better, and test is established every mu and established contrast totally 10 processing.Every processing repeats 4 times, and random district group is arranged, 30 square metres of community areas.
3.1.2 control time and number of times
Before dispenser, after the 1st medicine after 10 days and the 2nd dispenser 10 days, 20 days, every community adopted 5 samplings of diagonal, every some investigation 20 strains, before blooming, 2 leaves are got in every strain from upper end, after blooming, sword-like leave 2 leaves are got in every strain, by leaf classification investigation occurring degree, calculate disease and refer to and control efficiency.
Grade scale is as follows:
0 grade: anosis;
1 grade: lesion area accounts for below 5% of one-piece blade area;
3 grades: lesion area accounts for the 6%-15% of one-piece blade area;
5 grades: lesion area accounts for the 16%-25% of one-piece blade area;
7 grades: lesion area accounts for the 26%-50% of one-piece blade area;
9 grades: lesion area accounts for the more than 50% of one-piece blade area.
3.1.3 drug effect computational methods
The total number of sheets * 100 of sick leaf rate (%)=sick number of sheets/investigate
Disease index=∑ (the sick number of sheets * relative level numerical value at different levels)/(investigating the total number of sheets * 9) * 100
Control efficiency (%)=(disease index after the front disease index * treatment region medicine of 1-(blank district medicine)/(the front disease index of disease index * treatment region medicine after blank district medicine)) * 100.
3.1.4 poisoning investigation method
After dispenser, whether 20d range estimation medicament has poisoning to crop continuously.
3.1.5 result of the test and analysis
Each processes the effect of control wheat powdery mildew.(table 2)
As shown in Table 2 30% nitre benzene bacterium ester fluazinam composite bactericide for wheat powdery mildew control successful higher than nitre benzene bacterium ester and fluazinam single dose, bactericidal effect increases progressively with the increase of dosage.According to field range estimation, within the scope of test dose, plant growth is normal, and the poisoning phenomenon to wheat does not all appear in each treatment agent, illustrates that it is safe to wheat.Advise that the bactericide different from the mechanism of action mixes use to delay the drug-fast generation of germ.
3.2 field trials are prevented and treated powdery mildew of cucumber
3.2.1 test method
Test site, in the Pingdu herbary of Shandong, is cucumber for examination vegetables, and growing way is better, and test is established every mu and established contrast totally 10 processing.Every processing repeats 4 times, and random district group is arranged, 14 square metres of community areas.
3.2.2 control time and number of times
Before dispenser, after the 1st medicine after 10 days and the 2nd dispenser 10 days, 20 days, every community adopted 5 samplings of diagonal, every some investigation 2 strains, and totally 10 strains, investigation complete stool blade, by leaf classification investigation occurring degree, calculates disease and refers to and control efficiency.
Grade scale is as follows:
0 grade: anosis;
1 grade: lesion area accounts for below 5% of one-piece blade area;
3 grades: lesion area accounts for the 6%-15% of one-piece blade area;
5 grades: lesion area accounts for the 16%-25% of one-piece blade area;
7 grades: lesion area accounts for the 26%-50% of one-piece blade area;
9 grades: lesion area accounts for the more than 50% of one-piece blade area.
3.2.3 drug effect computational methods
The total number of sheets * 100 of sick leaf rate (%)=sick number of sheets/investigate
Disease index=∑ (the sick number of sheets * relative level numerical value at different levels)/(investigating the total number of sheets * 9) * 100
Control efficiency (%)=(disease index after the front disease index * treatment region medicine of 1-(blank district medicine)/(the front disease index of disease index * treatment region medicine after blank district medicine)) * 100.
3.2.4 poisoning investigation method
After dispenser, whether 20d range estimation medicament has poisoning to crop continuously.
3.2.5 result of the test and analysis
Each processes the effect of preventing and treating powdery mildew of cucumber.(table 3)
The Mixed Pharmacy of different proportion, tests by different consumptions as can be seen from Table 3, and 30% its right control of nitre benzene bacterium ester fluazinam composite bactericide is all better than contrasting medicament and bactericidal effect and increases progressively with the increase of dosage.According to field range estimation, within the scope of test dose, plant growth is normal, and the poisoning phenomenon to cucumber does not all appear in each treatment agent, illustrates that it is safe to cucumber.Advise that the bactericide different from the mechanism of action mixes use to delay the drug-fast generation of germ.
In sum, the bactericidal composition that the present invention contains nitre benzene bacterium ester and fluazinam, has good control efficiency to wheat powdery mildew, powdery mildew of cucumber, and it is to target crop safety.Complex preparation has not only improved preventive effect, and has expanded fungicidal spectrum, widens the scope of application, reduces costs, and multiple diseases is played to the double effect of controlling of a medicine, alleviates manpower and materials, improves productivity effect.So the invention of this complex preparation is of great significance social tool with popularization.
Claims (4)
1. a bactericidal composition that contains nitre benzene bacterium ester and fluazinam, it is characterized in that: the active ingredient of this bactericidal composition is nitre benzene bacterium ester and fluazinam binary built, all the other are auxiliary element, and wherein the mass ratio of active ingredient nitre benzene bacterium ester and fluazinam is 1～50: 50～1.
2. bactericidal composition according to claim 1, is characterized in that: nitre benzene bacterium ester and the gross weight of fluazinam in preparation account for 1%～80% of the whole quality of the pharmaceutical preparations.
3. bactericidal composition according to claim 2, is characterized in that: nitre benzene bacterium ester and the gross weight of fluazinam in preparation account for 5%～60% of the whole quality of the pharmaceutical preparations.
4. according to the bactericidal composition described in claim 1 or 2 or 3, it is characterized in that: the formulation of this bactericidal composition is missible oil, suspending agent, aqua, wetting powder, water dispersible granules, aqueous emulsion, microemulsion, granule, microcapsule formulations
.
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Cited By (2)
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| WO2015166499A1 (en) * | 2014-05-01 | 2015-11-05 | Tapazol Chemical Works Ltd. | Method for breaking dormancy in deciduous trees |
| CN107593711A (en) * | 2016-07-12 | 2018-01-19 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
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| WO2015166499A1 (en) * | 2014-05-01 | 2015-11-05 | Tapazol Chemical Works Ltd. | Method for breaking dormancy in deciduous trees |
| US10881105B2 (en) | 2014-05-01 | 2021-01-05 | Tapazol Chemical Works Ltd. | Method for breaking dormancy in deciduous trees |
| CN107593711A (en) * | 2016-07-12 | 2018-01-19 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
| CN107593711B (en) * | 2016-07-12 | 2020-02-11 | 江苏龙灯化学有限公司 | Bactericidal composition |
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