CN103351671A - High-efficiency antifouling antibacterial exterior wall coating and preparation method thereof - Google Patents
High-efficiency antifouling antibacterial exterior wall coating and preparation method thereof Download PDFInfo
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- CN103351671A CN103351671A CN2013102466529A CN201310246652A CN103351671A CN 103351671 A CN103351671 A CN 103351671A CN 2013102466529 A CN2013102466529 A CN 2013102466529A CN 201310246652 A CN201310246652 A CN 201310246652A CN 103351671 A CN103351671 A CN 103351671A
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- 239000011248 coating agent Substances 0.000 title claims abstract description 28
- 238000000576 coating method Methods 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims description 7
- 230000000844 anti-bacterial effect Effects 0.000 title 1
- 230000003373 anti-fouling effect Effects 0.000 title 1
- 239000000839 emulsion Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 15
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims abstract description 14
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910017083 AlN Inorganic materials 0.000 claims abstract description 7
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 7
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 7
- 239000011734 sodium Substances 0.000 claims abstract description 7
- 239000010455 vermiculite Substances 0.000 claims abstract description 7
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 7
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 7
- OFEAOSSMQHGXMM-UHFFFAOYSA-N 12007-10-2 Chemical compound [W].[W]=[B] OFEAOSSMQHGXMM-UHFFFAOYSA-N 0.000 claims abstract description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 36
- 238000003756 stirring Methods 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- -1 sodium alkyl benzene Chemical class 0.000 claims description 12
- 238000004581 coalescence Methods 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 230000003115 biocidal effect Effects 0.000 claims description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 229940077388 benzenesulfonate Drugs 0.000 claims description 6
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 3
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- KOVKEDGZABFDPF-UHFFFAOYSA-N n-(triethoxysilylmethyl)aniline Chemical compound CCO[Si](OCC)(OCC)CNC1=CC=CC=C1 KOVKEDGZABFDPF-UHFFFAOYSA-N 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 239000002105 nanoparticle Substances 0.000 claims description 3
- 239000001632 sodium acetate Substances 0.000 claims description 3
- 235000017281 sodium acetate Nutrition 0.000 claims description 3
- 238000005336 cracking Methods 0.000 abstract description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 150000004996 alkyl benzenes Chemical class 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 238000005201 scrubbing Methods 0.000 abstract 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 5
- 238000005034 decoration Methods 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention provides an exterior wall coating which is composed of the following raw materials in parts by weight: 86-90 parts of water-based acrylic emulsion, 15-20 parts of styrene-acrylic emulsion, 30-40 parts of vermiculite powder, 10-15 parts of barite powder, 1-2 parts of 5-chloro-2-methyl-4-isothiazolin-3-ketone, 2-3 parts of butyl methacrylate, 2-3 parts of aluminium nitride, 1-2 parts of sodium alkylbenzene sulfonate, 0.3-1 part of coco fatty acid diethanol amide, 1-2 parts of diethylene triamine, 1-2 parts of tungsten boride, 0.7-1 part of anilmomethyl triethoxy silane, 0.1-0.2 part of polyoxyethylenepolyoxypropylene ether, 3-5 parts of coalescing agent and 10-30 parts of deionized water. The coating provided by the invention has the advantages of low raw material loss, low gel production, simple process, hard coating film, good glossiness, strong impact resistance, low cracking rate, soft texture, excellent decorative property, high weather resistance, good scrubbing resistance, high adhesion force and long service life; and the coating is free of special smell, and contains no heavy metals such as mercury and lead and also contains no formaldehyde volatile, and thus meets the technical requirements of an environment-friendly coating.
Description
Technical field
The present invention relates generally to a kind of coating, relates in particular to antibiotic exterior coating of a kind of high-efficiency pollution-proof and preparation method thereof.
Background technology
In recent years; along with the raising of living standards of the people and the development of society; people are to the selection pay attention to day by day of building decoration coating, and are more simple better to the construction requirement of coating, for particularly in exterior coating; not only rest in the most basic protection to ground; decorative effect to coating is had higher requirement, and exterior coating requires to have water repelling property, requires to have from washing property; it is hard and smooth, dirty once rushing that paint film is wanted.
But the acrylic coating of throwing on the domestic market exists, and gloss is low, poor adhesive force, winter hardiness are poor, not water-fast, water vapour, soda acid, salts solution and organic polar solvent, poor flexibility under the room temperature, the shortcoming such as wear no resistance, and high temperature easily returns sticking, fragile under low temperature splitting, cause coating easily to ftracture, peel off, rainwater etc. easily infiltrate metope, corrosion body of wall, and this not only affects the beautiful decoration of buildings, and will reduce the work-ing life of buildings.
Summary of the invention
The object of the invention is exactly in order to remedy the defective of prior art, exterior coating that a kind of paint film is stable, glossiness is good, tolerance is strong and preparation method thereof to be provided.
The present invention is achieved by the following technical solutions:
The exterior coating that a kind of high-efficiency pollution-proof is antibiotic, it is comprised of the raw material of following weight parts:
Aqueous acrylic emulsion 86-90, benzene emulsion 15-20, vermiculite power 30-40, ground barium sulfate 10-15,5-chloro-2-methyl-4-isothiazoline-3-ketone 1-2, butyl methacrylate 2-3, aluminium nitride 2-3, sodium alkyl benzene sulfonate 1-2, lauric acid amide of ethanol 0.3-1, Diethylenetriaminee (DETA) 1-2, tungsten boride 1-2, anilinomethyl triethoxysilane 0.7-1, polyoxyethylene polyoxy propyl alcohol amidogen ether 0.1-0.2, film coalescence aid 3-5, deionized water 10-30;
Described film coalescence aid is comprised of the raw material of following weight parts:
Nano silicon 30-40, polyvinyl alcohol 4-6, vinyltriethoxysilane 6-10, alkylphenol Polyoxyalkylene ethers 0.8-1, benzene emulsion 3-4, nano-sized carbon 1-2;
Polyvinyl alcohol is joined in the 4-5 times of water, be steam heated to 95-100 ℃, stirring and dissolving adds benzene emulsion, and reducing temperature is 60-70 ℃, constant temperature stirred 3-4 minute, add each raw material of residue, low speed 300-400 rev/min was disperseed 2-3 minute, and 100-120 ℃ of insulation left standstill 1-2 hour, be cooled to normal temperature, namely get described film coalescence aid.
The preparation method of the exterior coating that a kind of high-efficiency pollution-proof is antibiotic may further comprise the steps:
Butyl methacrylate, the Diethylenetriaminee (DETA) of above-mentioned weight part are mixed to join in the aluminium nitride, add lauric acid amide of ethanol after fully stirring, it is 80-90 ℃ of lower dispersed with stirring 3-4 minute in temperature, add sodium alkyl benzene sulfonate, 500-600 rev/min was stirred 6-8 minute, add benzene emulsion, stir, 90-96 ℃ lower insulation reaction 1-2 hour; Add aqueous acrylic emulsion, deionized water, 900-1000 rev/min was stirred 8-10 minute; Add again vermiculite power, ground barium sulfate, stirred 15-20 minute at 700-800 rev/min; Add each raw material of residue, under 600-700 rev/min speed, fully stir, add acetic acid or sodium acetate, adjusting PH is 8-9, stirs to be described exterior coating.
Advantage of the present invention is:
The coating raw material loss that the present invention produces is few, gel generates few, technique is simple, paint film is hard, glossiness is good, anti-impact force is strong, be not easy cracking, texture is soft, ornamental strong, high weather resisteant is arranged, brushing resistance, strong adhesion, long service life, without special odor, not mercurous, the plumbous heavy metal that waits, formaldehydeless volatile matter, meet the technical requirements of environmental protection coating material, the film coalescence aid of adding has very high stability, efficient binding property, film-forming properties has increased the density of coated membrane, improved quality of forming film, so that rete has strong adhesion, without the cavity, split sunken, the fine and close advantage such as even.
Embodiment
Embodiment 1
The exterior coating that a kind of high-efficiency pollution-proof is antibiotic, it is comprised of the raw material of following weight parts (kilogram):
Aqueous acrylic emulsion 90, benzene emulsion 20, vermiculite power 40, ground barium sulfate 15,5-chloro-2-methyl-4-isothiazoline-3-ketone 2, butyl methacrylate 2, aluminium nitride 2, sodium alkyl benzene sulfonate 2, lauric acid amide of ethanol 0.3, Diethylenetriaminee (DETA) 1, tungsten boride 1, anilinomethyl triethoxysilane 0.7, polyoxyethylene polyoxy propyl alcohol amidogen ether 0.2, film coalescence aid 5, deionized water 30;
Described film coalescence aid is comprised of the raw material of following weight parts:
Nano silicon 40, polyvinyl alcohol 6, vinyltriethoxysilane 10, alkylphenol Polyoxyalkylene ethers 0.8, benzene emulsion 3, nano-sized carbon 2;
Polyvinyl alcohol is joined in 5 times of water, be steam heated to 100 ℃, stirring and dissolving adds benzene emulsion, reducing temperature is 70 ℃, and constant temperature stirred 4 minutes, adds each raw material of residue, 400 rev/mins of dispersions of low speed 3 minutes, 120 ℃ of insulations were left standstill 1 hour, were cooled to normal temperature, namely got described film coalescence aid.
The preparation method of the exterior coating that a kind of high-efficiency pollution-proof is antibiotic may further comprise the steps:
Butyl methacrylate, the Diethylenetriaminee (DETA) of above-mentioned weight part are mixed to join in the aluminium nitride, add lauric acid amide of ethanol after fully stirring, be 90 ℃ of lower dispersed with stirring 4 minutes in temperature, add sodium alkyl benzene sulfonate, 600 rev/mins were stirred 8 minutes, add benzene emulsion, stir, 96 ℃ of lower insulation reaction 1 hour; Add aqueous acrylic emulsion, deionized water, 1000 rev/mins were stirred 10 minutes; Add again vermiculite power, ground barium sulfate, stirred 20 minutes at 800 rev/mins; Add each raw material of residue, under 600 rev/mins speed, fully stir, add acetic acid or sodium acetate, regulating PH is 9, and stirring is described exterior coating.
Performance test:
Paint film appearance is full, smooth, good without lump, glossiness;
The property test that high-efficiency pollution-proof is antibiotic: pass through for 10000 times, paint film is without breakage;
The artificial ageing resistance test: 2000 hours non-foaming, do not peel off, flawless;
Temperature-change resistance (5 circulations): without unusual;
Alkali resistance: 200 hours without unusual.
Claims (2)
1. exterior coating that high-efficiency pollution-proof is antibiotic is characterized in that what it was comprised of the raw material of following weight parts:
Aqueous acrylic emulsion 86-90, benzene emulsion 15-20, vermiculite power 30-40, ground barium sulfate 10-15,5-chloro-2-methyl-4-isothiazoline-3-ketone 1-2, butyl methacrylate 2-3, aluminium nitride 2-3, sodium alkyl benzene sulfonate 1-2, lauric acid amide of ethanol 0.3-1, Diethylenetriaminee (DETA) 1-2, tungsten boride 1-2, anilinomethyl triethoxysilane 0.7-1, polyoxyethylene polyoxy propyl alcohol amidogen ether 0.1-0.2, film coalescence aid 3-5, deionized water 10-30;
Described film coalescence aid is comprised of the raw material of following weight parts:
Nano silicon 30-40, polyvinyl alcohol 4-6, vinyltriethoxysilane 6-10, alkylphenol Polyoxyalkylene ethers 0.8-1, benzene emulsion 3-4, nano-sized carbon 1-2;
Polyvinyl alcohol is joined in the 4-5 times of water, be steam heated to 95-100 ℃, stirring and dissolving adds benzene emulsion, and reducing temperature is 60-70 ℃, constant temperature stirred 3-4 minute, add each raw material of residue, low speed 300-400 rev/min was disperseed 2-3 minute, and 100-120 ℃ of insulation left standstill 1-2 hour, be cooled to normal temperature, namely get described film coalescence aid.
2. the preparation method of the antibiotic exterior coating of a high-efficiency pollution-proof as claimed in claim 1 is characterized in that may further comprise the steps:
Butyl methacrylate, the Diethylenetriaminee (DETA) of above-mentioned weight part are mixed to join in the aluminium nitride, add lauric acid amide of ethanol after fully stirring, it is 80-90 ℃ of lower dispersed with stirring 3-4 minute in temperature, add sodium alkyl benzene sulfonate, 500-600 rev/min was stirred 6-8 minute, add benzene emulsion, stir, 90-96 ℃ lower insulation reaction 1-2 hour; Add aqueous acrylic emulsion, deionized water, 900-1000 rev/min was stirred 8-10 minute; Add again vermiculite power, ground barium sulfate, stirred 15-20 minute at 700-800 rev/min; Add each raw material of residue, under 600-700 rev/min speed, fully stir, add acetic acid or sodium acetate, adjusting PH is 8-9, stirs to be described exterior coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310246652.9A CN103351671B (en) | 2013-06-20 | 2013-06-20 | Exterior coating that a kind of high-efficiency pollution-proof is antibacterial and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310246652.9A CN103351671B (en) | 2013-06-20 | 2013-06-20 | Exterior coating that a kind of high-efficiency pollution-proof is antibacterial and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103351671A true CN103351671A (en) | 2013-10-16 |
| CN103351671B CN103351671B (en) | 2016-03-30 |
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| CN201310246652.9A Active CN103351671B (en) | 2013-06-20 | 2013-06-20 | Exterior coating that a kind of high-efficiency pollution-proof is antibacterial and preparation method thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103756385A (en) * | 2013-12-31 | 2014-04-30 | 邹平绿环安装装饰有限公司 | Spar-texture azulejo paint and preparation method thereof |
| CN104231695A (en) * | 2014-10-15 | 2014-12-24 | 合肥环照高分子材料厂 | Green antibacterial coating for interior wall |
| CN104263037A (en) * | 2014-10-15 | 2015-01-07 | 合肥环照高分子材料厂 | Water-based radon-proof interior wall paint |
| CN104263036A (en) * | 2014-10-15 | 2015-01-07 | 合肥环照高分子材料厂 | Bactericidal organic silicon coating |
| CN104387879A (en) * | 2014-11-11 | 2015-03-04 | 合肥不老传奇保健科技有限公司 | Outer wall coating with self-cleaning heat-preservation function and preparation method of outer wall coating |
| CN105152795A (en) * | 2015-10-23 | 2015-12-16 | 武汉工程大学 | Diammonium phosphate slow-release compound fertilizer coated with blending modified silicon dioxide emulsion and preparation method thereof |
| CN105419559A (en) * | 2015-11-25 | 2016-03-23 | 浙江华彩化工有限公司 | Antifouling antibacterial electronic element fluorescent powder coating and preparation method thereof |
| CN106752434A (en) * | 2016-12-30 | 2017-05-31 | 赵晓光 | A kind of fireproof antibacterial environmental protection coating material and its production and use |
| CN109054548A (en) * | 2018-06-25 | 2018-12-21 | 滁州麦斯特新型建材有限公司 | A kind of exterior wall latex paint and preparation method thereof |
| CN109054522A (en) * | 2018-06-25 | 2018-12-21 | 滁州麦斯特新型建材有限公司 | A kind of environment-friendly exterior wall emulsion paint and preparation method thereof |
| CN109111803A (en) * | 2018-06-25 | 2019-01-01 | 滁州麦斯特新型建材有限公司 | A kind of natural real stone paint of color stable and preparation method thereof |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103756385A (en) * | 2013-12-31 | 2014-04-30 | 邹平绿环安装装饰有限公司 | Spar-texture azulejo paint and preparation method thereof |
| CN104231695A (en) * | 2014-10-15 | 2014-12-24 | 合肥环照高分子材料厂 | Green antibacterial coating for interior wall |
| CN104263037A (en) * | 2014-10-15 | 2015-01-07 | 合肥环照高分子材料厂 | Water-based radon-proof interior wall paint |
| CN104263036A (en) * | 2014-10-15 | 2015-01-07 | 合肥环照高分子材料厂 | Bactericidal organic silicon coating |
| CN104387879A (en) * | 2014-11-11 | 2015-03-04 | 合肥不老传奇保健科技有限公司 | Outer wall coating with self-cleaning heat-preservation function and preparation method of outer wall coating |
| CN105152795A (en) * | 2015-10-23 | 2015-12-16 | 武汉工程大学 | Diammonium phosphate slow-release compound fertilizer coated with blending modified silicon dioxide emulsion and preparation method thereof |
| CN105419559A (en) * | 2015-11-25 | 2016-03-23 | 浙江华彩化工有限公司 | Antifouling antibacterial electronic element fluorescent powder coating and preparation method thereof |
| CN106752434A (en) * | 2016-12-30 | 2017-05-31 | 赵晓光 | A kind of fireproof antibacterial environmental protection coating material and its production and use |
| CN106752434B (en) * | 2016-12-30 | 2018-11-20 | 赵晓光 | A kind of fireproof antibacterial environmental protection coating material and its preparation method and application |
| CN109054548A (en) * | 2018-06-25 | 2018-12-21 | 滁州麦斯特新型建材有限公司 | A kind of exterior wall latex paint and preparation method thereof |
| CN109054522A (en) * | 2018-06-25 | 2018-12-21 | 滁州麦斯特新型建材有限公司 | A kind of environment-friendly exterior wall emulsion paint and preparation method thereof |
| CN109111803A (en) * | 2018-06-25 | 2019-01-01 | 滁州麦斯特新型建材有限公司 | A kind of natural real stone paint of color stable and preparation method thereof |
| CN109111805A (en) * | 2018-06-25 | 2019-01-01 | 滁州麦斯特新型建材有限公司 | A kind of exterior coating and preparation method thereof with insulation effect |
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Denomination of invention: An efficient anti fouling and antibacterial exterior wall coating and its preparation method Effective date of registration: 20231026 Granted publication date: 20160330 Pledgee: Lai An county Jinan financing Company limited by guarantee Pledgor: CHUZHOU BEST NEW BUILDING MATERIAL CO.,LTD. Registration number: Y2023980062875 |
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