CN103306030A - Blended fabric of polysulfonamide and viscose fiber - Google Patents
Blended fabric of polysulfonamide and viscose fiber Download PDFInfo
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- CN103306030A CN103306030A CN2013101750528A CN201310175052A CN103306030A CN 103306030 A CN103306030 A CN 103306030A CN 2013101750528 A CN2013101750528 A CN 2013101750528A CN 201310175052 A CN201310175052 A CN 201310175052A CN 103306030 A CN103306030 A CN 103306030A
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- viscose
- synthetic fibre
- blended fabric
- sulfone synthetic
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Abstract
The invention discloses a blended fabric of polysulfonamide and viscose fiber. The blended fabric of polysulfonamide and viscose fiber is formed by blending and weaving 40wt% to 80wt% of polysulfonamide and 20wt% to 60wt% of viscose fiber. The blended fabric of polysulfonamide and viscose fiber has the advantages that the afterflame time, the smoldering time and the damaged length meet the state standards, and the specified flame retardant requirement is met.
Description
Technical field
The present invention relates to a kind of fabric, relate in particular to the BLENDED FABRIC of a kind of fragrant sulfone synthetic fibre and viscose.
Background technology
Polysulphonamide fiber claims polysulfonamides fibre again, is called for short the PSA fiber, commodity special peace synthetic fibre (TANLON) by name.Virtue sulfone synthetic fibre is a kind of aromatic polyamide fibre with special construction, and formal name used at school is PPSU terephthalamide fiber, this fiber by 4,4 '-diamino-diphenyl sulfone, 3,3 '-condensation polymer of diamino-diphenyl sulfone and paraphthaloyl chloride makes.Polysulphonamide fiber has been introduced benzene structure and sulfuryl when producing, and makes amide groups and sulfuryl interconnect contraposition phenyl and a position phenyl formation linear macromolecule.Since exist on the macromolecular main chain strong electrophilic sulfuryl group-(SO2)-, two keys by phenyl ring are gripped effect altogether, by the system of gripping altogether of phenyl ring, make that the cloud density of nitrogen-atoms significantly reduces on the amide groups, so have outstanding heat-resisting, firing resistance, its long-term serviceability temperature is 250 ℃.The experiment proved that the heat resistance of polysulphonamide fiber, high temperature dimensional stability, chemical resistance, hygroscopicity and dyeability are all comparatively good.The polysulphonamide fiber material is applied to fields such as protective article, high-temperature-resistant filtering material, friction sealed material, electrically insulating material more.
But, the volume resistivity that polysulphonamide fiber is higher and initial modulus, lower coefficient of friction and curling stability, to the spinning of fiber, weave, processing such as dyeing is unfavorable.Subject matter in spinning process shows as: interfibrous cohesive force is less, resultant yarn is difficult, yarn strength is lower, and resultant yarn filoplume is particularly outstanding, and the plumage that becomes mildewed is many, thereby influences yarn quality.
The present invention attempts to improve the performance of polysulphonamide fiber by adopting viscose and polysulphonamide fiber blending.
Summary of the invention
At the deficiencies in the prior art, technical problem to be solved by this invention provides the BLENDED FABRIC of a kind of fragrant sulfone synthetic fibre and viscose.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
The BLENDED FABRIC of a kind of fragrant sulfone synthetic fibre and viscose is weaved by 40-80wt% virtue sulfone synthetic fibre and 20-60wt% viscose fiber blending and to be formed.
Preferably,
The BLENDED FABRIC of a kind of fragrant sulfone synthetic fibre and viscose is weaved by 50-70wt% virtue sulfone synthetic fibre and 30-50wt% viscose fiber blending.
Described viscose is Fire resistant viscose fiber.
Described Fire resistant viscose fiber, adopt following method to be prepared from: fire retardant is mixed with viscose solution, and wet spinning spray silk technological forming can make described Fire resistant viscose fiber routinely.
Described fire retardant accounts for the quality percentage composition 5-15% of described Fire resistant viscose fiber.
Described viscose solution refers to the sodium hydrate aqueous solution of cellulose sulfonate, and it is the general intermediate raw material of the industry.Preferably, in the described viscose solution, the weight percent content of first fibre is 8-9%, and the weight percent content of NaOH is 4-6%, falling ball viscosity 45-65 second, degree of ripeness 8-16%.
Described fire retardant is N, N '-two (two phenoxy group thiophosphoryl bases) dithiothyldimaide, N-methylol-3-(dimethoxy phosphono) a kind of or its mixture in propionamide and three (2,3-dibromopropyl) the fulminuric acid ester.
Described fire retardant is made up of following components in mass portion: N, N '-two (two phenoxy group thiophosphoryl bases) dithiothyldimaide 20-40 part; N-methylol-3-(dimethoxy phosphono) propionamide 20-40 part; Three (2,3-dibromopropyl) fulminuric acid ester 30-50 part.
Concrete, in the present invention:
Viscose belongs to regenerated celulose fibre.It is one of chemical fibre that drops into the earliest suitability for industrialized production.Because good hygroscopicity, comfortable and easy to wear, spinnability is good, Chang Yumian, hair or various synthetic fiber blending, interweave, for all kinds of clothes and decorative textile product.
Viscose is to extract pure alpha-cellulose (being called pulp) by cellulosic material, handles with caustic soda, carbon disulfide, obtains orange-yellow sodium cellulose xanthate, is dissolved in the diluted sodium hydroxide solution again, becomes the spinning solution of thickness, is called viscose glue.Viscose glue after filtration, after the maturation (placing about 18~30h at a certain temperature, to reduce the esterification degree of cellulose xanthate ester), deaeration, carry out wet spinning, coagulating bath is made up of sulfuric acid, sodium sulphate and zinc sulfate.Sodium cellulose xanthate in the viscose glue and the effect of sulfuric acid in the coagulating bath and decompose, cellulose regenerated and separate out, the gained cellulose fibre becomes viscose after washing, desulfurization, bleaching, drying.
N, N '-two (two phenoxy group thiophosphoryl bases) dithiothyldimaide, molecular formula is as follows:
N-methylol-3-(dimethoxy phosphono) propionamide, the CAS accession number is 20120-33-6, English name: N-hydroxymethyl-3-(dimethoxyphosphonyl) propionamide is abbreviated as provetex CP.
Three (2,3-dibromopropyl) fulminuric acid ester is called for short TBC.Concrete chemical formula: C
12H
15N
3O
3Br
2
Especially, in the present invention, N, N '-two (two phenoxy group thiophosphoryl bases) dithiothyldimaide, the composite use of N_ methylol-3-(dimethoxy phosphono) propionamide and three (2,3-dibromopropyl) fulminuric acid ester, flame retardant effect Synergistic.
With respect to prior art, the marked improvement of technical solution of the present invention mainly is presented as: adopt fragrant sulfone synthetic fibre and viscose fiber blending, make the after flame time of fabric, glow time and char length all meet national standard, reach the fire-retardant requirement of regulation.
The specific embodiment
Be further described below in conjunction with the present invention of embodiment.
Embodiment 1
Take by weighing N, 30 kilograms of N '-two (two phenoxy group thiophosphoryl bases) dithiothyldimaide; N-methylol-3-(dimethoxy phosphono) propionamide is 30 kilograms; 40 kilograms of three (2,3-dibromopropyl) fulminuric acid esters mix and make composite flame-retardant agent.
Above-mentioned composite flame-retardant agent is mixed with viscose solution, and wet spinning spray silk technological forming can make described Fire resistant viscose fiber routinely, and the length of Fire resistant viscose fiber is 38mm.Wherein, the content of fire retardant is 10wt% in the control finished product Fire resistant viscose fiber.
Viscose solution in the described raw material, the weight percent content of first fibre are 8.5%, and the weight percent content of NaOH is 5%, falling ball viscosity 50 seconds, degree of ripeness 12%.
(Shanghai Tanlon Fibre Co., Ltd. provides virtue sulfone synthetic fibre
Polysulphonamide fiber, fiber number 2.22dtex, length 51mm) and the mass ratio of Fire resistant viscose fiber (said method makes, length 38mm) be 60:40.
The fragrant sulfone synthetic fibre shredding preliminary treatment that will take by weighing by said ratio is carded to the carded sliver at carding machine; The Fire resistant viscose fiber shredding preliminary treatment that will take by weighing by said ratio is carded to the carded sliver at carding machine; Then with the fragrant sulfone synthetic fibre carded sliver and the Fire resistant viscose fiber carded sliver on drawing frame and close, make ripe; Carry out drawing-off and twisting at Speed frames, blended yarn is made in further draw twisting on fine spining machine at last, and yarn linear density is 39tex.Again blended yarn is adopted large circle machine weft knitting weaving method to weave, weft-knitted rib stitch, gross density is (100 stringer * 60 lines)/5cm, finally makes BLENDED FABRIC.
Obviously, above-mentioned blended yarn and the preparation technology of fabric are the universal method of the industry, for well known to those of ordinary skill in the art.
Embodiment 2
The preparation method is substantially with embodiment 1, and difference only is: used fire retardant is N, N '-two (two phenoxy group thiophosphoryl bases) dithiothyldimaide, but not composite flame-retardant agent.
Embodiment 3
The preparation method is substantially with embodiment 1, and difference only is: used fire retardant is N-methylol-3-(dimethoxy phosphono) propionamide, but not composite flame-retardant agent.
Embodiment 4
The preparation method is substantially with embodiment 1, and difference only is: used fire retardant is three (2,3-dibromopropyl) fulminuric acid ester, but not composite flame-retardant agent.
Embodiment 5
The preparation method is substantially with embodiment 1, and difference only is: used fire retardant is FPK8002 type antiflaming finishing agent, but not composite flame-retardant agent.
Embodiment 6
(Shanghai Tanlon Fibre Co., Ltd. provides virtue sulfone synthetic fibre
Polysulphonamide fiber, fiber number 2.22dtex, length 51mm) and the mass ratio of viscose (viscose staple fibre that Shandong Hailong Co., Ltd. provides, length 38mm) be 60:40.
The preparation technology of blended yarn and fabric is with embodiment 1.
Test case 1
Adopt vertical combustion method test after flame time, glow time and char length, test with reference to the GB/T5455-1997 standard.
Table 2: fire resistance test chart
? | After flame time, s | Glow the time s | Char length, cm |
Embodiment 1 | 0 | 0 | 2.5 |
Embodiment 2 | 0 | 0 | 4.0 |
Embodiment 3 | 0 | 0 | 4.5 |
Embodiment 4 | 0 | 0 | 3.5 |
Embodiment 5 | 0 | 0 | 5.5 |
Although fragrant sulfone synthetic fibre has excellent flame, behind the mixed viscose fiber, fire resistance descends greatly, and the fabric of embodiment 6 all burns.
As seen; the present invention is by carrying out the blending method flame-proof treatment to viscose; make the Fire resistant viscose fiber of preparation have fire resistance preferably; again with the polysulphonamide fiber blending after; the fabric after flame time that makes; glow time and char length all meets national standard; reach the fire-retardant requirement of regulation; especially; with N; N '-two (two phenoxy group thiophosphoryl bases) dithiothyldimaide; N-methylol-3-(dimethoxy phosphono) propionamide and three (2; the 3-dibromopropyl) these three kinds of composite uses of fire retardant of fulminuric acid ester, flame retardant effect Synergistic (char length declines to a great extent), its mechanism remains follow-up study.
The above; it only is the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the disclosed technical scope of the present invention; variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (8)
1. the BLENDED FABRIC of a fragrant sulfone synthetic fibre and viscose is characterized in that: weaved by 40-80wt% virtue sulfone synthetic fibre and 20-60wt% viscose fiber blending and form.
2. the BLENDED FABRIC of fragrant sulfone synthetic fibre as claimed in claim 1 and viscose is characterized in that: weaved by 50-70wt% virtue sulfone synthetic fibre and 30-50wt% viscose fiber blending.
3. the BLENDED FABRIC of fragrant sulfone synthetic fibre as claimed in claim 1 or 2 and viscose, it is characterized in that: described viscose is Fire resistant viscose fiber.
4. the BLENDED FABRIC of fragrant sulfone synthetic fibre as claimed in claim 3 and viscose is characterized in that, described Fire resistant viscose fiber adopts following method to be prepared from: fire retardant is mixed with viscose solution, routinely wet spinning spray silk technological forming.
5. the BLENDED FABRIC of fragrant sulfone synthetic fibre as claimed in claim 4 and viscose, it is characterized in that: described fire retardant accounts for the quality percentage composition 5-15% of described Fire resistant viscose fiber.
6. the BLENDED FABRIC of fragrant sulfone synthetic fibre as claimed in claim 4 and viscose, it is characterized in that: in the described viscose solution, the weight percent content of first fibre is 8-9%, and the weight percent content of NaOH is 4-6%, falling ball viscosity 45-65 second, degree of ripeness 8-16%.
7. the BLENDED FABRIC of fragrant sulfone synthetic fibre as claimed in claim 4 and viscose; it is characterized in that: described fire retardant is N; N '-two (two phenoxy group thiophosphoryl bases) dithiothyldimaide, N-methylol-3-(dimethoxy phosphono) a kind of or its mixture in propionamide and three (2,3-dibromopropyl) the fulminuric acid ester.
8. the BLENDED FABRIC of fragrant sulfone synthetic fibre as claimed in claim 7 and viscose is characterized in that described fire retardant is made up of following components in mass portion: N, N '-two (two phenoxy group thiophosphoryl bases) dithiothyldimaide 20-40 part; N-methylol-3-(dimethoxy phosphono) propionamide 20-40 part; Three (2,3-dibromopropyl) fulminuric acid ester 30-50 part.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103643547A (en) * | 2013-11-06 | 2014-03-19 | 上海工程技术大学 | Method for dyeing blended fabric of polysulfonamide and viscose glue |
CN104611805A (en) * | 2015-02-13 | 2015-05-13 | 上海特安纶纤维有限公司 | Yarn, fabric and product made of aromatic polymer fiber containing sulfuryl and cellulose fiber and preparation method thereof |
CN107663696A (en) * | 2017-10-16 | 2018-02-06 | 天津工业大学 | One kind is permanently from fire-retardant household textiles fabric |
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CN102561031A (en) * | 2012-02-03 | 2012-07-11 | 上海韬鸿化工科技有限公司 | Flame retardant viscose fiber and preparation method thereof |
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US20060029770A1 (en) * | 2004-08-04 | 2006-02-09 | Jacques Fourmeux | Flame-retardant heat insulating barrier |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103643547A (en) * | 2013-11-06 | 2014-03-19 | 上海工程技术大学 | Method for dyeing blended fabric of polysulfonamide and viscose glue |
CN103643547B (en) * | 2013-11-06 | 2016-08-17 | 上海工程技术大学 | The colouring method of PSA fiber/viscose blend fabric |
CN104611805A (en) * | 2015-02-13 | 2015-05-13 | 上海特安纶纤维有限公司 | Yarn, fabric and product made of aromatic polymer fiber containing sulfuryl and cellulose fiber and preparation method thereof |
CN107663696A (en) * | 2017-10-16 | 2018-02-06 | 天津工业大学 | One kind is permanently from fire-retardant household textiles fabric |
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Application publication date: 20130918 |