CN103304867A - Non-asphaltic reaction bonding high polymer waterproof roll material and preparation method thereof - Google Patents
Non-asphaltic reaction bonding high polymer waterproof roll material and preparation method thereof Download PDFInfo
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- CN103304867A CN103304867A CN2013102172811A CN201310217281A CN103304867A CN 103304867 A CN103304867 A CN 103304867A CN 2013102172811 A CN2013102172811 A CN 2013102172811A CN 201310217281 A CN201310217281 A CN 201310217281A CN 103304867 A CN103304867 A CN 103304867A
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Abstract
The invention relates to a non-asphaltic reaction bonding high polymer waterproof roll material and a preparation method thereof and belongs to the technical field of waterproof roll materials for buildings. The non-asphaltic reaction bonding high polymer waterproof roll material is prepared from the following components in percentage by weight: 28-40 percent of high polymer resin, 15-35 percent of naphthenic oil, 1-10 percent of EVA, 1-10 percent of SBS, 1-10 percent of polystyrene, 1-10 percent of petroleum resin and 15-25 percent of talcum powder, wherein the high polymer resin is selected from one of TPO and PPO. The non-asphaltic reaction bonding high polymer waterproof roll material has the beneficial effects that the product is non-toxic and harmless, small in odor, safe and environment-friendly, and the adverse influence on the personnel in the production and construction process is greatly reduced; the preparation method is simple and feasible in process, the traditional two production lines are changed into a production line, so that production can be performed, the production process is saved, and the production cost is greatly reduced.
Description
Technical field
The invention belongs to the building waterproof coil technical field, be specifically related to sticking polymer membranes of a kind of non-pitch reaction and preparation method thereof.
Background technology
At present, waterproof roll is all produced take pitch as base-material mostly, because contain multiple carcinogenic substance in the pitch, human body is existed the hidden danger of serious safety.It is 200910066313.6 Chinese invention patent " a kind of preparation method of polymer membranes " such as application number.
In addition, high-polymer self-adhesion waterproof coiled material adopts two end production process: at first be shaped to sheet material by forcing machine, after sheet material was coated the self-adhesion sizing material, compound one deck barrier film became the adhesive waterproof coil of high-elongation by compressed together to last item again.And having become normal temperature in the temperature of the self-adhesion sizing material of coating casting films sheet material during with composite isolated film, caking ability is not high alone can to cause like this sizing material and sheet material.In addition, owing to adopting two end production process, workman's operation also takes a lot of work, consuming time, and production cost is high.Be 201120435738.2 Chinese invention patent " the two-sided composite water-proof rolled material of a kind of TPO polymer " such as application number, it also exists the shortcoming of complete processing complexity.
Summary of the invention
The purpose of this invention is to provide a kind of the have safety of use, the sticking polymer membranes of well behaved non-pitch reaction.
Another object of the present invention provides the preparation method of the sticking polymer membranes of this non-pitch reaction.
The technical solution used in the present invention is the sticking polymer membranes of a kind of non-pitch reaction, is prepared from by the component of pressing column weight amount per-cent: macromolecule resin 28%～40%, naphthenic oil 15%～35%, EVA1%～10%, SBS1%～10%, polystyrene 1%～10%, petroleum resin 1%～10% and talcum powder 15%～25%; Described macromolecule resin is selected from a kind of among TPO or the PPO.
As preferably, the present invention is prepared from by the component of pressing column weight amount per-cent: TPO30%～38%, naphthenic oil 20%～30%, EVA2%～8%, SBS2%～8%, polystyrene 4%～8%, petroleum resin 2%～4% and talcum powder 18%～22%.
As preferably, the present invention is prepared from by the component of pressing column weight amount per-cent: TPO34%, naphthenic oil 25%, EVA5%, SBS7%, polystyrene 6%, petroleum resin 3% and talcum powder 20%.
As preferably, the present invention is prepared from by the component of pressing column weight amount per-cent: PPO32%～38%, naphthenic oil 20%～26%, EVA5%～9%, SBS2%～8%, polystyrene 2%～8%, petroleum resin 2%～6% and talcum powder 18%～24%.
As preferably, the present invention is prepared from by the component of pressing column weight amount per-cent: PPO35%, naphthenic oil 23%, EVA7%, SBS5%, polystyrene 5%, petroleum resin 4% and talcum powder 21%.
As preferably, the invention provides the preparation method of the sticking polymer membranes of a kind of non-pitch reaction, may further comprise the steps: macromolecule resin, naphthenic oil, EVA, SBS, polystyrene, petroleum resin and talcum powder after will heating respectively are fed into reactor, and mixing and stirring gets final product.
As preferably, described macromolecule resin is heated to 140～150 ℃, and naphthenic oil is heated to 150～180 ℃, EVA is heated to 160～180 ℃, and SBS is heated to 170～180 ℃, and polystyrene is heated to 170～180 ℃, petroleum resin are heated to 170～180 ℃, and talcum powder is heated to 170～180 ℃.
Among the present invention, TPO is Thermoplastic Elastomer, Olefinic, and PPO is polyphenylene oxide, and EVA is ethylene-vinyl acetate copolymer, and SBS is thermoplastic elastomer.
Beneficial effect of the present invention is:
(1) nontoxic, smell is less, greatly reduce produce and construction process in to personnel's detrimentally affect, safety and environmental protection;
(2) the present invention has good thermostability and low-temperature bending, can be fit to use under the extreme climates such as all parts of the country even high low temperature area and the environment;
(3) the present invention has lasting adhesive property, can with onsite concrete generation chemical crosslink reaction, form fine and close and the high-intensity fourth of the twelve Earthly Branches connects face;
(4) the present invention has excellent ageing-resistant performance, has solved traditional coiled material take pitch as base-material loses waterproof effect in time with the passing in season drawback;
(5) the present invention has good stripping strength, and stripping strength is 2 times of traditional coiled material of making take pitch as base-material, can accurate combination with concrete, form the waterproof effect of " skin-type ";
(6) the present invention has wide range of applications, and can be used for the engineerings such as buildings, vault, roofing, subway, high ferro, tunnel and bridge;
(7) preparation method of the present invention, the technique simple possible, becoming a production line by two traditional production lines can produce, and has saved production process, thereby has greatly reduced production cost.
Embodiment
For making those skilled in the art understand in detail production technique of the present invention and technique effect, the below further introduces application of the present invention and technique effect with concrete production instance.
Embodiment one:
Respectively by weight percentage, TPO34%, naphthenic oil 25%, EVA5%, SBS7%, polystyrene 6%, petroleum resin 3% and talcum powder 20% after the heating are fed into reactor, mixing and stirring, calendering is cooled off in flakes, rolling, packing gets finished product.
Wherein, TPO is heated to 140 ℃, and naphthenic oil is heated to 160 ℃, and EVA is heated to 170 ℃, and SBS is heated to 180 ℃, and polystyrene is heated to 180 ℃, and petroleum resin are heated to 170 ℃, and talcum powder is heated to 170 ℃.
Embodiment two:
Respectively by weight percentage, TPO38%, naphthenic oil 22%, EVA4%, SBS6%, polystyrene 4%, petroleum resin 4% and talcum powder 22% after the heating are fed into reactor, mixing and stirring, calendering is cooled off in flakes, rolling, packing gets finished product.
Wherein, TPO is heated to 150 ℃, and naphthenic oil is heated to 170 ℃, and EVA is heated to 180 ℃, and SBS is heated to 170 ℃, and polystyrene is heated to 170 ℃, and petroleum resin are heated to 170 ℃, and talcum powder is heated to 170 ℃.
Embodiment three:
Respectively by weight percentage, TPO30%, naphthenic oil 30%, EVA3%, SBS7%, polystyrene 8%, petroleum resin 2% and talcum powder 20% after the heating are fed into reactor, mixing and stirring, calendering is cooled off in flakes, rolling, packing gets finished product.
Wherein, TPO is heated to 160 ℃, and naphthenic oil is heated to 150 ℃, and EVA is heated to 160 ℃, and SBS is heated to 170 ℃, and polystyrene is heated to 170 ℃, and petroleum resin are heated to 170 ℃, and talcum powder is heated to 170 ℃.
Embodiment four:
Respectively by weight percentage, PPO35%, naphthenic oil 23%, EVA7%, SBS5%, polystyrene 5%, petroleum resin 4% and talcum powder 21% after the heating are fed into reactor, mixing and stirring, calendering is cooled off in flakes, rolling, packing gets finished product.
Wherein, PPO is heated to 140 ℃, and naphthenic oil is heated to 150 ℃, and EVA is heated to 160 ℃, and SBS is heated to 170 ℃, and polystyrene is heated to 180 ℃, and petroleum resin are heated to 170 ℃, and talcum powder is heated to 170 ℃.
Embodiment five:
Respectively by weight percentage, PPO38%, naphthenic oil 20%, EVA6%, SBS4%, polystyrene 4%, petroleum resin 4% and talcum powder 24% after the heating are fed into reactor, mixing and stirring, calendering is cooled off in flakes, rolling, packing gets finished product.
Wherein, PPO is heated to 160 ℃, and naphthenic oil is heated to 150 ℃, and EVA is heated to 160 ℃, and SBS is heated to 170 ℃, and polystyrene is heated to 170 ℃, and petroleum resin are heated to 170 ℃, and talcum powder is heated to 170 ℃.
Embodiment six:
Respectively by weight percentage, PPO32%, naphthenic oil 26%, EVA9%, SBS5%, polystyrene 4%, petroleum resin 4% and talcum powder 20% after the heating are fed into reactor, mixing and stirring, calendering is cooled off in flakes, rolling, packing gets finished product.
Wherein, PPO is heated to 160 ℃, and naphthenic oil is heated to 150 ℃, and EVA is heated to 160 ℃, and SBS is heated to 180 ℃, and polystyrene is heated to 180 ℃, and petroleum resin are heated to 180 ℃, and talcum powder is heated to 180 ℃.
For verifying effect of the present invention, carry out correlation detection according to the standard of GB/T23260-2009, detected result is as follows:
The above technical scheme that the embodiment of the invention is provided is described in detail, used specific case herein principle and the embodiment of the embodiment of the invention are set forth, the explanation of above embodiment is only applicable to help to understand the principle of the embodiment of the invention; Simultaneously, for one of ordinary skill in the art, according to the embodiment of the invention, all will change on embodiment and range of application, in sum, this description should not be construed as limitation of the present invention.
Claims (7)
1. the sticking polymer membranes of non-pitch reaction is characterized in that being prepared from by the component of pressing column weight amount per-cent: macromolecule resin 28%～40%, naphthenic oil 15%～35%, EVA1%～10%, SBS1%～10%, polystyrene 1%～10%, petroleum resin 1%～10% and talcum powder 15%～25%; Described macromolecule resin is selected from a kind of among TPO or the PPO.
2. the sticking polymer membranes of non-pitch reaction according to claim 1 is characterized in that being prepared from by the component of pressing column weight amount per-cent: TPO30%～38%, naphthenic oil 20%～30%, EVA2%～8%, SBS2%～8%, polystyrene 4%～8%, petroleum resin 2%～4% and talcum powder 18%～22%.
3. the sticking polymer membranes of non-pitch reaction according to claim 2 is characterized in that being prepared from by the component of pressing column weight amount per-cent: TPO34%, naphthenic oil 25%, EVA5%, SBS7%, polystyrene 6%, petroleum resin 3% and talcum powder 20%.
4. the sticking polymer membranes of non-pitch reaction according to claim 1 is characterized in that being prepared from by the component of pressing column weight amount per-cent: PPO32%～38%, naphthenic oil 20%～26%, EVA5%～9%, SBS2%～8%, polystyrene 2%～8%, petroleum resin 2%～6% and talcum powder 18%～24%.
5. the sticking polymer membranes of non-pitch reaction according to claim 4 is characterized in that being prepared from by the component of pressing column weight amount per-cent: PPO35%, naphthenic oil 23%, EVA7%, SBS5%, polystyrene 5%, petroleum resin 4% and talcum powder 21%.
6. preparation method based on the sticking polymer membranes of non-pitch reaction claimed in claim 1, it is characterized in that: may further comprise the steps: macromolecule resin, naphthenic oil, EVA, SBS, polystyrene, petroleum resin and talcum powder after will heating respectively are fed into reactor, mixing and stirring gets final product.
7. non-pitch according to claim 6 reacts the preparation method of sticking polymer membranes, it is characterized in that: described macromolecule resin is heated to 140～150 ℃, naphthenic oil is heated to 150～180 ℃, EVA is heated to 160～180 ℃, SBS is heated to 170～180 ℃, polystyrene is heated to 170～180 ℃, and petroleum resin are heated to 170～180 ℃, and talcum powder is heated to 170～180 ℃.
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| CN201310217281.1A CN103304867B (en) | 2013-06-04 | 2013-06-04 | The sticky polymer membranes of non-bituminous reaction and its preparation method |
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| CN201310217281.1A CN103304867B (en) | 2013-06-04 | 2013-06-04 | The sticky polymer membranes of non-bituminous reaction and its preparation method |
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| CN103304867A true CN103304867A (en) | 2013-09-18 |
| CN103304867B CN103304867B (en) | 2016-06-15 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103756352A (en) * | 2014-01-25 | 2014-04-30 | 王勇 | TPO (thermoplastic polyolefin) waterproof sealing paste and processing process thereof |
| CN105295829A (en) * | 2015-11-25 | 2016-02-03 | 贵州蓝图新材料股份有限公司 | Environment-friendly type high-strength waterproof coiled material self-adhesive |
| CN106519972A (en) * | 2016-11-04 | 2017-03-22 | 贵州中科万通生态科技股份有限公司 | Manufacturing method for non-asphalt and non-curing waterproof coating |
| CN108587036A (en) * | 2018-05-04 | 2018-09-28 | 昆山科顺防水材料有限公司 | A kind of new type rubber waterproof roll and preparation method thereof |
| CN114292562A (en) * | 2022-01-26 | 2022-04-08 | 北京宇阳泽丽防水材料有限责任公司 | Nano-grade filler modified non-asphalt waterproof material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1203257A (en) * | 1998-06-29 | 1998-12-30 | 北京化工大学 | Thermoplastic rubber-type water-proof coiled material |
| CN101358028A (en) * | 2008-09-02 | 2009-02-04 | 宁波一舟塑胶有限公司 | Halogen-free flame-retardant thermoplastic elastomer electrical cable material using polyphenylene ether as base material and preparation method thereof |
-
2013
- 2013-06-04 CN CN201310217281.1A patent/CN103304867B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1203257A (en) * | 1998-06-29 | 1998-12-30 | 北京化工大学 | Thermoplastic rubber-type water-proof coiled material |
| CN101358028A (en) * | 2008-09-02 | 2009-02-04 | 宁波一舟塑胶有限公司 | Halogen-free flame-retardant thermoplastic elastomer electrical cable material using polyphenylene ether as base material and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103756352A (en) * | 2014-01-25 | 2014-04-30 | 王勇 | TPO (thermoplastic polyolefin) waterproof sealing paste and processing process thereof |
| CN105295829A (en) * | 2015-11-25 | 2016-02-03 | 贵州蓝图新材料股份有限公司 | Environment-friendly type high-strength waterproof coiled material self-adhesive |
| CN105295829B (en) * | 2015-11-25 | 2018-04-13 | 贵州蓝图新材料股份有限公司 | Environment-friendly type high intensity waterproof roll self-adhesive |
| CN106519972A (en) * | 2016-11-04 | 2017-03-22 | 贵州中科万通生态科技股份有限公司 | Manufacturing method for non-asphalt and non-curing waterproof coating |
| CN108587036A (en) * | 2018-05-04 | 2018-09-28 | 昆山科顺防水材料有限公司 | A kind of new type rubber waterproof roll and preparation method thereof |
| CN108587036B (en) * | 2018-05-04 | 2020-11-17 | 昆山科顺防水材料有限公司 | Rubber waterproof coiled material and preparation method thereof |
| CN114292562A (en) * | 2022-01-26 | 2022-04-08 | 北京宇阳泽丽防水材料有限责任公司 | Nano-grade filler modified non-asphalt waterproof material |
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| CN103304867B (en) | 2016-06-15 |
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