CN103289503A - Sulfomethal phenolaldehy resin-containing waterproof acid-and-alkali-resistant coating - Google Patents
Sulfomethal phenolaldehy resin-containing waterproof acid-and-alkali-resistant coating Download PDFInfo
- Publication number
- CN103289503A CN103289503A CN2013102160848A CN201310216084A CN103289503A CN 103289503 A CN103289503 A CN 103289503A CN 2013102160848 A CN2013102160848 A CN 2013102160848A CN 201310216084 A CN201310216084 A CN 201310216084A CN 103289503 A CN103289503 A CN 103289503A
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- CN
- China
- Prior art keywords
- parts
- alkali
- coating
- phenol formaldehyde
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000011248 coating agent Substances 0.000 title claims abstract description 44
- 238000000576 coating method Methods 0.000 title claims abstract description 44
- 239000003513 alkali Substances 0.000 title abstract description 8
- 239000011347 resin Substances 0.000 title abstract 4
- 229920005989 resin Polymers 0.000 title abstract 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 18
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000839 emulsion Substances 0.000 claims abstract description 7
- 229920002367 Polyisobutene Polymers 0.000 claims abstract description 6
- 239000010445 mica Substances 0.000 claims abstract description 6
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 6
- 235000019362 perlite Nutrition 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920002907 Guar gum Polymers 0.000 claims abstract description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 5
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000665 guar gum Substances 0.000 claims abstract description 5
- 229960002154 guar gum Drugs 0.000 claims abstract description 5
- 235000010417 guar gum Nutrition 0.000 claims abstract description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims description 30
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 3
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims description 2
- 240000006365 Vitis vinifera Species 0.000 claims description 2
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical class O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 8
- 239000010451 perlite Substances 0.000 abstract description 4
- 239000004615 ingredient Substances 0.000 abstract 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 32
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 16
- 238000003756 stirring Methods 0.000 description 11
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 8
- 239000005028 tinplate Substances 0.000 description 8
- 238000005187 foaming Methods 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Paints Or Removers (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
The invention relates to a sulfomethal phenolaldehy resin-containing waterproof acid-and-alkali-resistant coating which comprises the following ingredients in parts by weight: 30-40 parts of sulfomethal phenolaldehy resin, 10-20 parts of biuret, 10-20 parts of polymerized rosin, 10-20 parts of acetic styrene-acrylic emulsion, 10-20 parts of mica powder, 5-10 parts of perlite, 5-10 parts of polyisobutene, 5-10 parts of guar gum, 5-10 parts of propylene glycol, and 50-70 parts of cyclohexanone. The prepared sulfomethal phenolaldehy resin-containing waterproof acid-and-alkali-resistant coating has good waterproof and acid-and-alkali-resistant effects.
Description
Technical field
The present invention relates to a kind of waterproof acid and alkali-resistance coating, particularly relate to a kind of waterproof acid and alkali-resistance coating that contains sulfonated phenol formaldehyde resin.
Background technology
Present stage, coating market is just flourish, and various types of coating are gushed out as emerging rapidly in large numbersBamboo shoots after a spring rain one after another.Simultaneously, people are increasing to the demand of coating, and the requirement to coating also is more and more higher simultaneously.In the professional domain that relates to waterproof acid and alkali-resistance coating, as building, decoration field, and some special fields, requirement to waterproof acid and alkali-resistance type coating is to uprise day by day, the coating type that has at present waterproof and acid and alkali-resistance effect on the market simultaneously is less, and therefore developing a kind of coating that has excellent waterproofness and resistance to acids and bases simultaneously has the very vast market space.
Summary of the invention
The technical problem that solves: the relatively poor problem of conventional coating water-acid resistance effect.
Technical scheme: the present invention is a kind of waterproof acid and alkali-resistance coating that contains sulfonated phenol formaldehyde resin, formed according to weight ratio by following composition: 30～40 parts of sulfonated phenol formaldehyde resins, 10～20 parts of biurets, 10～20 parts of polymerized rosines, 10～20 parts of acrylate and vinyl acetate emulsions, 10～20 parts of mica powders, 5～10 parts of perlites, 5～10 parts of polyisobutene, 5～10 parts of guar gums, 5～10 parts of propylene glycol, 50～70 parts of pimelinketone.Constantly stir by various compositions are dropped in the reactor, can obtain to have the coating of good waterproof acid and alkali-resistance effect after waiting to stir.
Beneficial effect: after preparing the waterproof acid and alkali-resistance coating that contains sulfonated phenol formaldehyde resin, its water-repellancy and resistance to acids and bases are tested, after coating evenly is sprayed on the tinplate surface, sample is put into water carry out waterproof test, the waterproof test duration is 30～40 days, and other gets the even tinplate sample that has sprayed coating and carries out the acid and alkali-resistance experiment, and alkali lye is the sodium hydroxide solution of 2mol/L, acid solution is the phosphoric acid solution of 2mol/L, and the time is 15～25 days.The result shows the coating that contains sulfonated phenol formaldehyde resin that the present invention the makes foaming phenomenon that do not ftracture in 30～40 days, has excellent waterproofness, under the phosphoric acid solution of the sodium hydroxide solution of 2mol/L and 2mol/L, do not have unusual foaming phenomenon in 15～25 days in addition yet, have good acid and alkali-resistance effect.
Embodiment
Embodiment 1
Open reactor, get sulfonated phenol formaldehyde resin 30kg, drop in the reactor, stir, add biuret 10kg simultaneously, do not stop to stir, add polymerized rosin 10kg again, add acrylate and vinyl acetate emulsion 10kg, add mica powder 10kg again, add perlite 5kg more successively, polyisobutene 5kg, guar gum 5kg, propylene glycol 5kg, add pimelinketone 50kg at last, can contain the coating of sulfonated phenol formaldehyde resin after treating thoroughly to stir.After coating evenly is sprayed on the tinplate surface, sample is put into water carry out waterproof test, the waterproof test duration is 30 days, other gets the even tinplate sample that has sprayed coating and carries out the acid and alkali-resistance experiment, alkali lye is the sodium hydroxide solution of 2mol/L, acid solution is the phosphoric acid solution of 2mol/L, and the time is 15 days.The result shows the coating that contains sulfonated phenol formaldehyde resin that the present invention the makes foaming phenomenon that do not ftracture in 30 days, has excellent waterproofness, in the phosphoric acid solution of the sodium hydroxide solution of 2mol/L and 2mol/L, also do not bubble or other unusual phenomenoies in 15 days in addition, have good acid and alkali-resistance effect.
Embodiment 2
Open reactor, get sulfonated phenol formaldehyde resin 40kg, drop in the reactor, stir, add biuret 20kg simultaneously, do not stop to stir, add polymerized rosin 20kg again, add acrylate and vinyl acetate emulsion 20kg, add mica powder 20kg again, add perlite 10kg more successively, polyisobutene 10kg, guar gum 10kg, propylene glycol 10kg, add pimelinketone 70kg at last, can contain the coating of sulfonated phenol formaldehyde resin after treating thoroughly to stir.After coating evenly is sprayed on the tinplate surface, sample is put into water carry out waterproof test, the waterproof test duration is 35 days, other gets the even tinplate sample that has sprayed coating and carries out the acid and alkali-resistance experiment, alkali lye is the sodium hydroxide solution of 2mol/L, acid solution is the phosphoric acid solution of 2mol/L, and the time is 20 days.The result shows the coating that contains sulfonated phenol formaldehyde resin that the present invention the makes foaming phenomenon that do not ftracture in 35 days, has excellent waterproofness, in the phosphoric acid solution of the sodium hydroxide solution of 2mol/L and 2mol/L, also do not bubble or other unusual phenomenoies in 20 days in addition, have good acid and alkali-resistance effect.
Embodiment 3
Open reactor, get sulfonated phenol formaldehyde resin 35kg, drop in the reactor, stir, add biuret 15kg simultaneously, do not stop to stir, add polymerized rosin 15kg again, add acrylate and vinyl acetate emulsion 15kg, add mica powder 15kg again, add perlite 7kg more successively, polyisobutene 8kg, guar gum 7kg, propylene glycol 8kg, add pimelinketone 60kg at last, can contain the coating of sulfonated phenol formaldehyde resin after treating thoroughly to stir.After coating evenly is sprayed on the tinplate surface, sample is put into water carry out waterproof test, the waterproof test duration is 40 days, other gets the even tinplate sample that has sprayed coating and carries out the acid and alkali-resistance experiment, alkali lye is the sodium hydroxide solution of 2mol/L, acid solution is the phosphoric acid solution of 2mol/L, and the time is 25 days.The result shows the coating that contains sulfonated phenol formaldehyde resin that the present invention the makes foaming phenomenon that do not ftracture in 40 days, has excellent waterproofness, in the phosphoric acid solution of the sodium hydroxide solution of 2mol/L and 2mol/L, also do not bubble or other unusual phenomenoies in 25 days in addition, have good acid and alkali-resistance effect.
Claims (6)
1. waterproof acid and alkali-resistance coating that contains sulfonated phenol formaldehyde resin, it is characterized in that: formed according to weight ratio by following composition: 30～40 parts of sulfonated phenol formaldehyde resins, 10～20 parts of biurets, 10～20 parts of polymerized rosines, 10～20 parts of acrylate and vinyl acetate emulsions, 10～20 parts of mica powders, 5～10 parts of perlites, 5～10 parts of polyisobutene, 5～10 parts of guar gums, 5～10 parts of propylene glycol, 50～70 parts of pimelinketone.
2. a kind of waterproof acid and alkali-resistance coating that contains sulfonated phenol formaldehyde resin according to claim 1 is characterized in that: sulfonated phenol formaldehyde resin was 30 parts during coating was formed.
3. a kind of waterproof acid and alkali-resistance coating that contains sulfonated phenol formaldehyde resin according to claim 1 is characterized in that: biuret was 10 parts during coating was formed.
4. a kind of waterproof acid and alkali-resistance coating that contains sulfonated phenol formaldehyde resin according to claim 1 is characterized in that: polymerized rosin was 20 parts during coating was formed.
5. a kind of waterproof acid and alkali-resistance coating that contains sulfonated phenol formaldehyde resin according to claim 1 is characterized in that: acrylate and vinyl acetate emulsion was 10 parts during coating was formed.
6. a kind of waterproof acid and alkali-resistance coating that contains sulfonated phenol formaldehyde resin according to claim 1 is characterized in that: guar gum was 10 parts during coating was formed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310216084.8A CN103289503B (en) | 2013-06-04 | 2013-06-04 | A kind of waterproof acid and alkali-resistance coating containing sulfonated phenol formaldehyde resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310216084.8A CN103289503B (en) | 2013-06-04 | 2013-06-04 | A kind of waterproof acid and alkali-resistance coating containing sulfonated phenol formaldehyde resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103289503A true CN103289503A (en) | 2013-09-11 |
| CN103289503B CN103289503B (en) | 2015-09-30 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310216084.8A Active CN103289503B (en) | 2013-06-04 | 2013-06-04 | A kind of waterproof acid and alkali-resistance coating containing sulfonated phenol formaldehyde resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103289503B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103614020A (en) * | 2013-10-28 | 2014-03-05 | 蚌埠凯盛工程技术有限公司 | Thermostable waterproof coating |
| CN104130644A (en) * | 2014-06-26 | 2014-11-05 | 安徽快来防水防腐有限公司 | Stable waterproof coating |
Citations (5)
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| CN101104776A (en) * | 2007-08-23 | 2008-01-16 | 李国树 | Macromolecule emulsion waterproofing paint |
| CN101117543A (en) * | 2006-08-04 | 2008-02-06 | 中宏（天津）实业有限公司 | Solvent type waterproofing paint capable of filming by volatilization |
| CN102850909A (en) * | 2012-08-30 | 2013-01-02 | 苏州市德莱尔建材科技有限公司 | Waterproof coating |
| CN102964927A (en) * | 2012-12-24 | 2013-03-13 | 青岛宣威涂层材料有限公司 | High-efficiency waterproof anticorrosive paint |
| CN102993796A (en) * | 2012-10-15 | 2013-03-27 | 怀远县巨龙机械制造有限公司 | Metal anti-rust paint and preparation method thereof |
-
2013
- 2013-06-04 CN CN201310216084.8A patent/CN103289503B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117543A (en) * | 2006-08-04 | 2008-02-06 | 中宏（天津）实业有限公司 | Solvent type waterproofing paint capable of filming by volatilization |
| CN101104776A (en) * | 2007-08-23 | 2008-01-16 | 李国树 | Macromolecule emulsion waterproofing paint |
| CN102850909A (en) * | 2012-08-30 | 2013-01-02 | 苏州市德莱尔建材科技有限公司 | Waterproof coating |
| CN102993796A (en) * | 2012-10-15 | 2013-03-27 | 怀远县巨龙机械制造有限公司 | Metal anti-rust paint and preparation method thereof |
| CN102964927A (en) * | 2012-12-24 | 2013-03-13 | 青岛宣威涂层材料有限公司 | High-efficiency waterproof anticorrosive paint |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103614020A (en) * | 2013-10-28 | 2014-03-05 | 蚌埠凯盛工程技术有限公司 | Thermostable waterproof coating |
| CN103614020B (en) * | 2013-10-28 | 2016-03-09 | 蚌埠凯盛工程技术有限公司 | A kind of thermally-stabilised waterproof paint |
| CN104130644A (en) * | 2014-06-26 | 2014-11-05 | 安徽快来防水防腐有限公司 | Stable waterproof coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103289503B (en) | 2015-09-30 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP02 | Change in the address of a patent holder | ||
| CP02 | Change in the address of a patent holder |
Address after: 215211 No. 1397, Xinli Avenue, FenHu high tech Industrial Development Zone, Wujiang District, Suzhou, Jiangsu Patentee after: SUZHOU AITESI FURTHER MATERIALS Co.,Ltd. Address before: 215211 Suzhou, Jiangsu FenHu hi tech Development Zone, Santa tower, No. 551 West South Road. Patentee before: SUZHOU AITESI FURTHER MATERIALS Co.,Ltd. |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190827 Address after: 215000 North of Fenyue East Road, Lili Town, Wujiang District, Suzhou City, Jiangsu Province Patentee after: SUZHOU AITESI ENVIRONMENTAL PROTECTION EQUIPMENT Co.,Ltd. Address before: 215211 No. 1397 Xinta Kangli Avenue, Fenhu High-tech Industrial Development Zone, Wujiang District, Suzhou City, Jiangsu Province Patentee before: SUZHOU AITESI FURTHER MATERIALS Co.,Ltd. |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A waterproof, acid and alkali resistant coating containing sulfonated phenolic resin Granted publication date: 20150930 Pledgee: Bank of Jiangsu Co.,Ltd. Suzhou Branch Pledgor: SUZHOU AITESI ENVIRONMENTAL PROTECTION EQUIPMENT Co.,Ltd. Registration number: Y2024980012011 |