CN103497614B - A kind of anti-flaming dope and preparation method thereof - Google Patents
A kind of anti-flaming dope and preparation method thereof Download PDFInfo
- Publication number
- CN103497614B CN103497614B CN201310372238.2A CN201310372238A CN103497614B CN 103497614 B CN103497614 B CN 103497614B CN 201310372238 A CN201310372238 A CN 201310372238A CN 103497614 B CN103497614 B CN 103497614B
- Authority
- CN
- China
- Prior art keywords
- flaming dope
- vinylformic acid
- initiator
- parts
- tribromophenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Macromonomer-Based Addition Polymer (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a kind of anti-flaming dope, be made up of each component of following mass fraction: aqueous polyurethane 80-90 part, epoxy resin 15-20 part, vinylformic acid-2,4,6-tribromophenyl 6-8 part, vinyl acetate resin 5-10 part, vinylformic acid 2-5 part, tertiary carbonic acid glycidyl ester 6-8 part, initiator 0.2-0.4 part.Complete processing of the present invention is simple, and reasonable mixture ratio of components, the anti-flaming dope coating of production has good flame retardant effect.After being applied to building surface, once buildings presence of fire, heat reaches certain temperature, and namely the present invention plays the effect of anti-flaming thermal-insulation, thus stops or retarded combustion.
Description
Technical field
The invention belongs to paint field, be specifically related to a kind of anti-flaming dope and preparation method thereof.
Background technology
Anti-flaming dope is that most widely used in modern project, adaptability is the strongest, construction material of construction the most easily, in guarantee building safety, played huge effect.Along with people live taste raising, people favor more to the material of construction such as wooden structures, steel construction.And anti-flaming dope has covering with paint beauty function on the one hand to above-mentioned materials, time on the other hand when presence of fire or by high temperature action, anti-flaming dope has good provide protection to timber, steel construction, is good anti-flaming thermal-insulation material of construction.
Aqueous polyurethane coating is for base-material and with a class coating of water level dispersion medium with aqueous polyurethane resin, there is good storage stability, film mechanical property, water tolerance, resistance to dissolubility and ageing-resistant performance, and with the similar nature of traditional solvent borne polyurethane coating, be an important development direction of aqueous polyurethane coating.But its flame retardant effect is also not obvious, the report improving the flame retardant properties of aqueous polyurethane coating about research is also few.
Summary of the invention
The invention provides a kind of anti-flaming dope, for this reason, the present invention also provides the preparation method of this anti-flaming dope.
A kind of anti-flaming dope provided by the invention, be made up of each component of following mass fraction: aqueous polyurethane 80-90 part, epoxy resin 15-20 part, vinylformic acid-2,4,6-tribromophenyl 6-8 part, vinyl acetate resin 5-10 part, vinylformic acid 2-5 part, tertiary carbonic acid glycidyl ester 6-8 part, initiator 0.2-0.4 part.
Further, described anti-flaming dope is made up of each component of following mass fraction: aqueous polyurethane 85 parts, epoxy resin 18 parts, vinylformic acid-2,4,6-tribromophenyl 7 parts, vinyl acetate resin 8 parts, 4 parts, vinylformic acid, tertiary carbonic acid glycidyl ester 7 parts, initiator 0.3 part.
Further, described anti-flaming dope also comprises the hydroxyethyl methylacrylate of 4-6 mass parts.
Adding of hydroxyethyl methylacrylate makes fire-retardant better effects if.
Further, described anti-flaming dope also comprises the hydroxyethyl methylacrylate of 5 mass parts.
Further, described initiator is at least one in di-t-butyl peroxide, dicumyl peroxide, peroxidized t-butyl perbenzoate.
Second object of the present invention is to provide the preparation method of above-mentioned anti-flaming dope, in reaction vessel, add formula ratio vinylformic acid, vinylformic acid-2,4,6-tribromophenyl and initiator, stirring and evenly mixing, be warming up to 60-70 DEG C, residual solvent is added reaction vessel, and stir 5-6 hour, stirring velocity is 550-650r/min, be down to room temperature afterwards, obtain anti-flaming dope.
Further, described initiator is at least one in di-t-butyl peroxide, dicumyl peroxide, peroxidized t-butyl perbenzoate.
Complete processing of the present invention is simple, and reasonable mixture ratio of components, the anti-flaming dope coating of production has good flame retardant effect.After being applied to building surface, once buildings presence of fire, heat reaches certain temperature, and namely the present invention plays the effect of anti-flaming thermal-insulation, thus stops or retarded combustion.
Embodiment
embodiment 1
The formula of anti-flaming dope of the present invention is as follows:
Aqueous polyurethane 85kg, epoxy resin 18kg, vinylformic acid-2,4,6-tribromophenyl 7kg, vinyl acetate resin 8kg, vinylformic acid 4kg, tertiary carbonic acid glycidyl ester 7kg, initiator 0.3kg.
Wherein, initiator is di-t-butyl peroxide.
The preparation method of anti-flaming dope of the present invention is:
Vinylformic acid 4kg, vinylformic acid-2,4,6-tribromophenyl 7kg and initiator 0.3kg is added, stirring and evenly mixing in reaction vessel, be warming up to 65 DEG C, residual solvent is added reaction vessel, stir 5 hours, stirring velocity is 600r/min, is down to room temperature, obtains anti-flaming dope.
embodiment 2
The formula of anti-flaming dope of the present invention is as follows:
Aqueous polyurethane 80kg, epoxy resin 15kg, vinylformic acid-2,4,6-tribromophenyl 6kg, vinyl acetate resin 5kg, vinylformic acid 2kg, tertiary carbonic acid glycidyl ester 6kg, initiator 0.2kg.
Wherein, initiator is 0.1kg di-t-butyl peroxide and 0.1kg dicumyl peroxide.
The preparation method of anti-flaming dope of the present invention is:
Vinylformic acid 2kg, vinylformic acid-2,4,6-tribromophenyl 6kg and initiator 0.2kg is added, stirring and evenly mixing in reaction vessel, be warming up to 65 DEG C, residual solvent is added reaction vessel, stir 5.5 hours, stirring velocity is 550r/min, is down to room temperature, obtains anti-flaming dope.
embodiment 3
The formula of anti-flaming dope of the present invention is as follows:
Aqueous polyurethane 90kg, epoxy resin 20kg, vinylformic acid-2,4,6-tribromophenyl 8kg, vinyl acetate resin 10kg, vinylformic acid 5kg, tertiary carbonic acid glycidyl ester 8kg, initiator 0.4kg.
Wherein, initiator is peroxidized t-butyl perbenzoate.
The preparation method of anti-flaming dope of the present invention is:
Vinylformic acid 5kg, vinylformic acid-2,4,6-tribromophenyl 8kg and initiator 0.4kg is added, stirring and evenly mixing in reaction vessel, be warming up to 70 DEG C, residual solvent is added reaction vessel, stir 6 hours, stirring velocity is 650r/min, is down to room temperature, obtains anti-flaming dope.
embodiment 4
The formula of anti-flaming dope of the present invention is as follows:
Aqueous polyurethane 90kg, epoxy resin 15kg, vinylformic acid-2,4,6-tribromophenyl 7kg, vinyl acetate resin 5kg, vinylformic acid 4kg, tertiary carbonic acid glycidyl ester 8kg, initiator 0.3kg.
Wherein, initiator is 0.1kg di-t-butyl peroxide, 0.1kg dicumyl peroxide and 0.1kg peroxidized t-butyl perbenzoate.
The preparation method of anti-flaming dope of the present invention is:
Vinylformic acid 4kg, vinylformic acid-2,4,6-tribromophenyl 7kg and initiator 0.3kg is added, stirring and evenly mixing in reaction vessel, be warming up to 68 DEG C, residual solvent is added reaction vessel, stir 6 hours, stirring velocity is 630r/min, is down to room temperature, obtains anti-flaming dope.
embodiment 5
The formula of anti-flaming dope of the present invention is as follows:
Aqueous polyurethane 85kg, epoxy resin 18kg, vinylformic acid-2,4,6-tribromophenyl 7kg, vinyl acetate resin 8kg, vinylformic acid 4kg, tertiary carbonic acid glycidyl ester 7kg, hydroxyethyl methylacrylate 5kg, initiator 0.3kg.
Wherein, initiator is 0.1kg di-t-butyl peroxide, 0.1kg dicumyl peroxide and 0.1kg peroxidized t-butyl perbenzoate.
The preparation method of anti-flaming dope of the present invention is:
Vinylformic acid 4kg, vinylformic acid-2,4,6-tribromophenyl 7kg and initiator 0.3kg is added, stirring and evenly mixing in reaction vessel, be warming up to 65 DEG C, residual solvent is added reaction vessel, stir 5.5 hours, stirring velocity is 600r/min, is down to room temperature, obtains anti-flaming dope.
embodiment 6
The formula of anti-flaming dope of the present invention is as follows:
Aqueous polyurethane 90kg, epoxy resin 20kg, vinylformic acid-2,4,6-tribromophenyl 6kg, vinyl acetate resin 5kg, vinylformic acid 3kg, tertiary carbonic acid glycidyl ester 6kg, hydroxyethyl methylacrylate 4kg, initiator 0.2kg.
Wherein, initiator is 0.1kg di-t-butyl peroxide and 0.1kg peroxidized t-butyl perbenzoate.
The preparation method of anti-flaming dope of the present invention is:
Vinylformic acid 3kg, vinylformic acid-2,4,6-tribromophenyl 6kg and initiator 0.2kg is added, stirring and evenly mixing in reaction vessel, be warming up to 60 DEG C, residual solvent is added reaction vessel, stir 5 hours, stirring velocity is 550r/min, is down to room temperature, obtains anti-flaming dope.
embodiment 7
The formula of anti-flaming dope of the present invention is as follows:
Aqueous polyurethane 80kg, epoxy resin 15kg, vinylformic acid-2,4,6-tribromophenyl 8kg, vinyl acetate resin 10kg, vinylformic acid 5kg, tertiary carbonic acid glycidyl ester 8kg, hydroxyethyl methylacrylate 6kg, initiator 0.4kg.
Wherein, initiator be 0.2kg di-t-butyl peroxide and 0.2kg dicumyl peroxide.
The preparation method of anti-flaming dope of the present invention is:
Vinylformic acid 5kg, vinylformic acid-2,4,6-tribromophenyl 8kg and initiator 0.4kg is added, stirring and evenly mixing in reaction vessel, be warming up to 70 DEG C, residual solvent is added reaction vessel, stir 6 hours, stirring velocity is 630r/min, is down to room temperature, obtains anti-flaming dope.
During use, it is evenly applied to building surface.
Last it is noted that the foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment to invention has been detailed description, for a person skilled in the art, it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (8)
1. an anti-flaming dope, it is characterized in that: described anti-flaming dope is made up of each component of following mass fraction: aqueous polyurethane 80-90 part, epoxy resin 15-20 part, vinylformic acid-2,4,6-tribromophenyl 6-8 part, vinyl acetate resin 5-10 part, vinylformic acid 2-5 part, tertiary carbonic acid glycidyl ester 6-8 part, initiator 0.2-0.4 part; Its preparation method is in reaction vessel, add formula ratio vinylformic acid, vinylformic acid-2,4,6-tribromophenyl and initiator, stirring and evenly mixing, is warming up to 60-70 DEG C, and remaining ingredient is added reaction vessel, stir 5-6 hour, stirring velocity is 550-650r/min, is down to room temperature afterwards, obtains anti-flaming dope.
2. anti-flaming dope according to claim 1, it is characterized in that: described anti-flaming dope is made up of each component of following mass fraction: aqueous polyurethane 85 parts, epoxy resin 18 parts, vinylformic acid-2,4,6-tribromophenyl 7 parts, vinyl acetate resin 8 parts, 4 parts, vinylformic acid, tertiary carbonic acid glycidyl ester 7 parts, initiator 0.3 part.
3. anti-flaming dope according to claim 1 and 2, is characterized in that: described anti-flaming dope also comprises the hydroxyethyl methylacrylate of 4-6 mass parts.
4. anti-flaming dope according to claim 3, is characterized in that: described hydroxyethyl methylacrylate is 5 mass parts.
5., according to the arbitrary described anti-flaming dope of claim 1,2,4, it is characterized in that: described initiator is at least one in di-t-butyl peroxide, dicumyl peroxide, peroxidized t-butyl perbenzoate.
6. anti-flaming dope according to claim 3, is characterized in that: described initiator is at least one in di-t-butyl peroxide, dicumyl peroxide, peroxidized t-butyl perbenzoate.
7. the preparation method of the arbitrary described anti-flaming dope of claim 1-6, in reaction vessel, add formula ratio vinylformic acid, vinylformic acid-2,4,6-tribromophenyl and initiator, stirring and evenly mixing, be warming up to 60-70 DEG C, remaining ingredient is added reaction vessel, and stir 5-6 hour, stirring velocity is 550-650r/min, be down to room temperature afterwards, obtain anti-flaming dope.
8. preparation method according to claim 7, is characterized in that: described initiator is at least one in di-t-butyl peroxide, dicumyl peroxide, peroxidized t-butyl perbenzoate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310372238.2A CN103497614B (en) | 2013-08-23 | 2013-08-23 | A kind of anti-flaming dope and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310372238.2A CN103497614B (en) | 2013-08-23 | 2013-08-23 | A kind of anti-flaming dope and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103497614A CN103497614A (en) | 2014-01-08 |
| CN103497614B true CN103497614B (en) | 2016-02-03 |
Family
ID=49862880
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310372238.2A Active CN103497614B (en) | 2013-08-23 | 2013-08-23 | A kind of anti-flaming dope and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103497614B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107868606A (en) * | 2017-11-30 | 2018-04-03 | 明光市裕阳新材料有限公司 | A kind of fire-retardant environmental type coating and preparation method thereof |
| CN109280450B (en) * | 2018-08-02 | 2020-10-16 | 广东鑫皇冠新材料有限公司 | Epoxy acrylic resin flame-retardant coating and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101313030A (en) * | 2005-11-21 | 2008-11-26 | 住友电气工业株式会社 | Flame retardant resin composition and insulated wire using the flame retardant resin composition, insulated shielding wire, insulated cable and insulated pipe |
| CN101519562A (en) * | 2008-10-10 | 2009-09-02 | 兰州理工大学 | Flame-retardant protective coating for bromocarbon acrylic acid printed circuit and preparation method thereof |
| CN101654570A (en) * | 2009-09-24 | 2010-02-24 | 中国海洋石油总公司 | Water-based ultraviolet curing coating |
| CN102993798A (en) * | 2012-10-22 | 2013-03-27 | 宿迁市英杰装饰材料有限公司 | Flame-retardant coating composition |
-
2013
- 2013-08-23 CN CN201310372238.2A patent/CN103497614B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101313030A (en) * | 2005-11-21 | 2008-11-26 | 住友电气工业株式会社 | Flame retardant resin composition and insulated wire using the flame retardant resin composition, insulated shielding wire, insulated cable and insulated pipe |
| CN101519562A (en) * | 2008-10-10 | 2009-09-02 | 兰州理工大学 | Flame-retardant protective coating for bromocarbon acrylic acid printed circuit and preparation method thereof |
| CN101654570A (en) * | 2009-09-24 | 2010-02-24 | 中国海洋石油总公司 | Water-based ultraviolet curing coating |
| CN102993798A (en) * | 2012-10-22 | 2013-03-27 | 宿迁市英杰装饰材料有限公司 | Flame-retardant coating composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103497614A (en) | 2014-01-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104130611B (en) | Heat insulating coatings | |
| CN104877481A (en) | Polyvinyl acetate coating and preparation method thereof | |
| CN103497614B (en) | A kind of anti-flaming dope and preparation method thereof | |
| CN105647321A (en) | Environment-friendly imitation-stone elastic exterior wall coating | |
| CN109233498A (en) | A kind of outdoor super-thin steel structure fire-proof paint and preparation method thereof | |
| CN103333577B (en) | A kind of anti-flaming dope and preparation method thereof | |
| US11859097B2 (en) | Functional aqueous paint composition having incombustibility, flame resistance, heat shielding, heat insulation and dew condensation prevention effects | |
| CN102976678B (en) | Partition board material | |
| CN110343447B (en) | Preparation method of high-temperature corrosion-resistant modifier | |
| CN104829193A (en) | Modified forming cement board | |
| CN105062290A (en) | Flame retardant coating composition | |
| CN104647535A (en) | Eco-friendly anti-loss timber fire retardant and its preparation method and treatment process | |
| CN107177288A (en) | A kind of fireproof coating | |
| CN103421375B (en) | A kind of fire retardant coating compositions and preparation method thereof | |
| CN104844131A (en) | Flame-retardant heat insulating material | |
| CN104559768A (en) | Paint for buildings | |
| CN109593404A (en) | Dedicated furniture heat preservation powdery paints of a kind of cold district and preparation method thereof | |
| KR101331550B1 (en) | The tile binding cement having polymer with elasticity | |
| CN103421375A (en) | Flame-retardant coating composition and preparation method thereof | |
| CN105062387A (en) | Preparation method of highly water resistant adhesive used for buildings | |
| CN105542528A (en) | Flame-resistant waterproof antibacterial decorative coating | |
| CN104046098A (en) | Flame-retardant environmental-friendly coating material for buildings | |
| CN107032702B (en) | A kind of fire-retardant corrosion-resistant construction concrete | |
| CN103289503A (en) | Sulfomethal phenolaldehy resin-containing waterproof acid-and-alkali-resistant coating | |
| CN108689633A (en) | A kind of environment-friendly type building material and preparation method thereof with flame retarding function |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20151231 Address after: 214000 Xinhua Road, Wuxi province national high tech Industrial Development Zone, No. innovation Creative Industrial Park, building, room 109, B, China, Jiangsu Applicant after: Jiangsu Gaobo Zhirong Technology Co., Ltd. Address before: 214000 Jiangsu Province, Wuxi city Xishan District Beizhen Zhang Shan chemical District Jingquan tin Applicant before: Wuxi Jinsheng Auxiliaries Factory |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Sun Jiafu Inventor before: Zhu Renzu |
|
| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161018 Address after: 101304 Beijing city Shunyi District Lijiaqiao Center Primary School Patentee after: Beijing Mao Yuan fire protection material factory Address before: 214000 Xinhua Road, Wuxi province national high tech Industrial Development Zone, No. innovation Creative Industrial Park, building, room 109, B, China, Jiangsu Patentee before: Jiangsu Gaobo Zhirong Technology Co., Ltd. |