CN103289282B - A kind of cable jacket material containing modified polyphenylene ether resin and preparation method thereof - Google Patents
A kind of cable jacket material containing modified polyphenylene ether resin and preparation method thereof Download PDFInfo
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- CN103289282B CN103289282B CN201310162000.7A CN201310162000A CN103289282B CN 103289282 B CN103289282 B CN 103289282B CN 201310162000 A CN201310162000 A CN 201310162000A CN 103289282 B CN103289282 B CN 103289282B
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- polyphenylene ether
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Abstract
The invention discloses a kind of cable jacket material containing modified polyphenylene ether resin and preparation method thereof, its constitutive material is: modified polyphenylene ether resin, acrylonitrile-butadiene-styrene copolymer, glass fibre, vermiculite power, aluminium nitride, TM monex TM, acceterator TE TD, sec.-propyl distearyl acyloxy Aluminate, maleic acid zinc, two Lauryl Alcohol ester, triglyceride and calcined loess; The present invention adopts modified polyphenylene ether resin as major ingredient, by the modification of polyphenylene ether resin, mechanical property significantly improves, good mechanical property, there is the characteristic of low cigarette, Halogen, fire-retardant, high mechanical strength, high insulation resistance, adopt glass fibre as strengthening agent in the feed, vermiculite power and aluminium nitride are as filler simultaneously.
Description
Technical field
The present invention relates to a kind of cable jacket material, be specifically related to a kind of cable jacket material containing modified polyphenylene ether resin and preparation method thereof.
Background technology
Along with developing rapidly of economy, electric wire is at industry-by-industry, all be widely used in field, the frequent generation of electrical fire accident, the fire-retardant problem of electric wire causes the attention of countries in the world gradually, a large amount of smog and poisonous is discharged during cable fire, corrosive gas is Hazard Factor in fire, hamper safe escape and the fire-fighting work of people in a fire, lives and properties are made to suffer heavy losses, simultaneously along with communication career, the development of automotive industry and computer industry, the specification of quality of cable jacket material is increased day by day, the invention provides a kind of cable jacket material containing modified polyphenylene ether resin and preparation method thereof.
Summary of the invention
The object of the present invention is to provide a kind of cable jacket material containing modified polyphenylene ether resin and preparation method thereof.
The present invention adopts following technical scheme:
Cable jacket material containing modified polyphenylene ether resin, the weight part of its constitutive material is: modified polyphenylene ether resin 60-70, acrylonitrile-butadiene-styrene copolymer 20-25, glass fibre 2.5-3.5, vermiculite power 18-25, aluminium nitride 7.0-9.0, TM monex TM 1.0-1.5, acceterator TE TD 1.6-2.0, sec.-propyl distearyl acyloxy Aluminate 4.0-5.0, maleic acid zinc 2.0-2.5, two Lauryl Alcohol ester 2.3-2.5, triglyceride 1.8-2.0 and calcined loess 10-12.
Cable jacket material containing modified polyphenylene ether resin, the weight part of its constitutive material is: modified polyphenylene ether resin 65, acrylonitrile-butadiene-styrene copolymer 22, glass fibre 3.0, vermiculite power 22, aluminium nitride 8.0, TM monex TM 1.2, acceterator TE TD 1.8, sec.-propyl distearyl acyloxy Aluminate 4.5, maleic acid zinc 2.2, two Lauryl Alcohol ester 2.4, triglyceride 1.9 and calcined loess 11.
The preparation method of the cable jacket material containing modified polyphenylene ether resin, comprises the following steps:
(1) preparation of modified polyphenylene ether resin:
Formula (weight part): polyphenylene oxide resin 15-17, terpine resin 14-18, vinylbenzene 20-30, wilkinite 1.5-3.0, MALEIC ANHYDRIDE 2.3-2.8,2,6 ditertbutylparacresol 4.5-5.0, vinyltrimethoxy silane 1.3-1.5 and linking agent TAIC 2.0-2.5;
Preparation method is as follows:
A: by the weight part of constitutive material by polyphenylene oxide resin, vinylbenzene, MALEIC ANHYDRIDE stirring reaction 3-5 hour at 90-110 DEG C;
B: add terpine resin and wilkinite stirring reaction 1-2 hour at 150-160 DEG C in step (a). by weight;
C: add 2 in step (b), 6 ditertbutylparacresols, vinyltrimethoxy silane and linking agent TAIC stirring reaction 1.0-2.0 hour at 160-180 DEG C, obtains modified polyphenylene ether resin;
(2) modified polyphenylene ether resin taking step (1) by the weight part of constitutive material remains each raw material with other, stirring at low speed 5-7 minute under normal temperature, makes to mix, then at temperature 170-180 DEG C of mixing 10-20 minute, plasticate 2-4 minute again at 170-180 DEG C, discharging.
Beneficial effect of the present invention:
The present invention adopts modified polyphenylene ether resin as major ingredient, by the modification of polyphenylene ether resin, mechanical property significantly improves, good mechanical property, there is the characteristic of low cigarette, Halogen, fire-retardant, high mechanical strength, high insulation resistance, adopt glass fibre as strengthening agent in the feed, vermiculite power and aluminium nitride are as filler simultaneously.
Embodiment
Embodiment 1: the cable jacket material containing modified polyphenylene ether resin, the weight (kg) of its constitutive material is: modified polyphenylene ether resin 65, acrylonitrile-butadiene-styrene copolymer 22, glass fibre 3.0, vermiculite power 22, aluminium nitride 8.0, TM monex TM 1.2, acceterator TE TD 1.8, sec.-propyl distearyl acyloxy Aluminate 4.5, maleic acid zinc 2.2, two Lauryl Alcohol ester 2.4, triglyceride 1.9 and calcined loess 11.
The preparation method of the cable jacket material containing modified polyphenylene ether resin, comprises the following steps:
(1) preparation of modified polyphenylene ether resin:
Formula (kg): polyphenylene oxide resin 16, terpine resin 16, vinylbenzene 25, wilkinite 2.3, MALEIC ANHYDRIDE 2.5,2,6 ditertbutylparacresol 4.8, vinyltrimethoxy silane 1.4 and linking agent TAIC 2.2;
Preparation method is as follows:
A: by the weight part of constitutive material by polyphenylene oxide resin, vinylbenzene, MALEIC ANHYDRIDE stirring reaction 4 hours at 100 DEG C;
B: add terpine resin and wilkinite stirring reaction 1-2 hour at 155 DEG C in step (a). by weight;
C: add 2 in step (b), 6 ditertbutylparacresols, vinyltrimethoxy silane and linking agent TAIC stirring reaction 1.5 hours at 170 DEG C, obtains modified polyphenylene ether resin;
(2) take the modified polyphenylene ether resin of step (1) by the weight part of constitutive material and other remain each raw material, under normal temperature, stirring at low speed 6 minutes, makes to mix, then temperature 175 DEG C mixing 15 minutes, then plasticates at 175 DEG C 3 minutes, discharging.
By the CABLE MATERIALS performance data that embodiments of the invention 1 are obtained:
1, hardness (shore A) 94; 2, tensile strength (MPa) 18.5; 3,100% draw and stretch modulus (MPa) 8.9; 4, elongation at break (%) 245; 5, volume resistivity (Ω .cm) 10
16: 3.87; 6, oxygen index: 28.5.
Claims (2)
1. the cable jacket material containing modified polyphenylene ether resin, is characterized in that the weight part of its constitutive material is: modified polyphenylene ether resin 60-70, acrylonitrile-butadiene-styrene copolymer 20-25, glass fibre 2.5-3.5, vermiculite power 18-25, aluminium nitride 7.0-9.0, TM monex TM 1.0-1.5, acceterator TE TD 1.6-2.0, sec.-propyl distearyl acyloxy Aluminate 4.0-5.0, maleic acid zinc 2.0-2.5, two Lauryl Alcohol ester 2.3-2.5, triglyceride 1.8-2.0 and calcined loess 10-12;
The preparation method of this cable jacket material comprises the following steps:
(1) preparation of modified polyphenylene ether resin:
Formula is with parts by weight: polyphenylene oxide resin 15-17, terpine resin 14-18, vinylbenzene 20-30, wilkinite 1.5-3.0, MALEIC ANHYDRIDE 2.3-2.8,2,6 ditertiary butyl p cresol 4.5-5.0, vinyltrimethoxy silane 1.3-1.5 and linking agent TAIC 2.0-2.5;
The preparation method of modified polyphenylene ether resin is as follows:
A: by the weight part of constitutive material by polyphenylene oxide resin, vinylbenzene, MALEIC ANHYDRIDE stirring reaction 3-5 hour at 90-110 DEG C;
B: add terpine resin and wilkinite stirring reaction 1-2 hour at 150-160 DEG C in step (a). by weight;
C: add 2,6 ditertiary butyl p cresol, vinyltrimethoxy silane and linking agent TAIC stirring reaction 1.0-2.0 hour at 160-180 DEG C in step (b), obtain modified polyphenylene ether resin;
(2) modified polyphenylene ether resin taking step (1) by the weight part of constitutive material remains each raw material with other, stirring at low speed 5-7 minute under normal temperature, makes to mix, then at temperature 170-180 DEG C of mixing 10-20 minute, plasticate 2-4 minute again at 170-180 DEG C, discharging.
2. the cable jacket material containing modified polyphenylene ether resin according to claim 1, is characterized in that the weight part of its constitutive material is: modified polyphenylene ether resin 65, acrylonitrile-butadiene-styrene copolymer 22, glass fibre 3.0, vermiculite power 22, aluminium nitride 8.0, TM monex TM 1.2, acceterator TE TD 1.8, sec.-propyl distearyl acyloxy Aluminate 4.5, maleic acid zinc 2.2, two Lauryl Alcohol ester 2.4, triglyceride 1.9 and calcined loess 11.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310162000.7A CN103289282B (en) | 2013-05-06 | 2013-05-06 | A kind of cable jacket material containing modified polyphenylene ether resin and preparation method thereof |
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| CN201310162000.7A CN103289282B (en) | 2013-05-06 | 2013-05-06 | A kind of cable jacket material containing modified polyphenylene ether resin and preparation method thereof |
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| CN103289282B true CN103289282B (en) | 2015-10-07 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103937214A (en) * | 2014-04-18 | 2014-07-23 | 安徽省中日农业环保科技有限公司 | Anti-impact bentonite modified polyphenyl ether material for automobile plastic parts |
| CN103928150A (en) * | 2014-04-26 | 2014-07-16 | 芜湖航天特种电缆厂 | Waterproof control cable |
| CN104312133A (en) * | 2014-10-30 | 2015-01-28 | 安徽电信器材贸易工业有限责任公司 | Special material for pressure resistant communication cable protective sleeve and preparation method thereof |
| CN106543686B (en) * | 2016-11-25 | 2018-07-31 | 苏州生益科技有限公司 | A kind of resin combination and prepreg, laminate and interlayer dielectric using its making |
| CN112812420B (en) * | 2021-02-02 | 2023-01-06 | 廊坊崔氏电缆材料股份有限公司 | Low-smoke halogen-free cable material containing functional compatilizer and preparation thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102898809A (en) * | 2011-07-27 | 2013-01-30 | 上海凯波特种电缆料厂有限公司 | Halogen-free flame-retardant polyphenylether cable material, its preparation and application |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102898809A (en) * | 2011-07-27 | 2013-01-30 | 上海凯波特种电缆料厂有限公司 | Halogen-free flame-retardant polyphenylether cable material, its preparation and application |
Non-Patent Citations (2)
| Title |
|---|
| 改性聚苯醚及其在电线电缆中的应用;段春来;《上海凯波第二届高品质射频电缆及组件技术研讨会暨中电元协光电线缆分会第九次专家组会议》;20101231;p116-122 * |
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Effective date of registration: 20190924 Address after: 244099 Room 408, Huaihe Road Copper Commodity Market, Tongling City, Anhui Province Patentee after: Tongling Tiancheng Technology Development Co., Ltd. Address before: 238371 Industrial Zone, Wuwei County, Anhui, Wuhu Patentee before: Anhui Green Ecological Polymer Materials Technology Co., Ltd. |
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Effective date of registration: 20211221 Address after: 250022 1426-02, Gaochuang center, No. 67, Huiyuan street, Laiwu high tech Zone, Jinan City, Shandong Province Patentee after: Shandong future talent development Co.,Ltd. Address before: 244099 Room 408, copper commodity market, Huaihe Road, Tongling City, Anhui Province Patentee before: Tongling Tiancheng Technology Development Co.,Ltd. |
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