CN103275438B - 一种高聚合度pvc鞋底材料 - Google Patents
一种高聚合度pvc鞋底材料 Download PDFInfo
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- CN103275438B CN103275438B CN201310249771.XA CN201310249771A CN103275438B CN 103275438 B CN103275438 B CN 103275438B CN 201310249771 A CN201310249771 A CN 201310249771A CN 103275438 B CN103275438 B CN 103275438B
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- 239000000463 material Substances 0.000 title claims abstract description 20
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 8
- 239000003381 stabilizer Substances 0.000 claims abstract description 11
- 239000004593 Epoxy Substances 0.000 claims abstract description 5
- 241000551547 Dione <red algae> Species 0.000 claims abstract description 3
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims abstract description 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 6
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical group C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 claims description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- -1 Zinic stearas Chemical compound 0.000 claims description 2
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 2
- 239000006096 absorbing agent Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 159000000007 calcium salts Chemical class 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 claims description 2
- 229960003656 ricinoleic acid Drugs 0.000 claims description 2
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 150000003751 zinc Chemical class 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 230000006835 compression Effects 0.000 abstract description 3
- 238000007906 compression Methods 0.000 abstract description 3
- 238000001746 injection moulding Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000008188 pellet Substances 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明公开了一种高聚合度PVC鞋底材料，以重量百分比计包括如下组分：PVC45-50％；DOP35-45％；Ca/Zn复合稳定剂0.8-1％；辅助稳定剂1-2％；CaCO34-13％；其中，辅助稳定剂是亚磷酸酯类、环氧类、二酮类中的一种或几种混合物。本发明的PVC鞋底材料具有较高的回弹性、较低的压缩变形、较高的拉伸强度以及优良的耐磨性、耐热性、耐寒性。
Description
技术领域：
本发明涉及鞋材技术领域，尤其涉及一种PVC鞋底材料。
背景技术：
众所周知，中国制造的鞋遍及全世界。中国的鞋年产量超过100亿双，占全球鞋产量的45％。鞋业商品零售额达3000亿元人民币。近年来，由于胶鞋行业开始追求高质量，注重胶鞋的穿着舒适、美观、防滑、寿命长，在用料上也有较大变化。我国制鞋材料大多采用传统原料—硫化橡胶、PVC材料，但性能已不满足要求，也有用SBS、PU和改性PVC材料，但是价格较高。
高聚合度PVC耐寒性好，有弹性、弯曲疲劳强度大、摩擦系数大，主要用于注塑鞋、运动鞋，劳保鞋和皮鞋底。比普通PVC鞋底耐磨性好，同样也克服了SBS鞋底材料遇热容易发生弯曲的缺点。
发明内容：
本发明的目的是提供一种高聚合度PVC鞋底材料，由该材料制得的PVC鞋底具有较高的回弹性、较低的压缩变形、较高的拉伸强度以及优良的耐磨性、耐热性、耐寒性。
本发明的目的通过如下技术方案实现：
一种PVC鞋底胶黏剂，以重量百分比计包括如下组分：
其中，辅助稳定剂是亚磷酸酯类、环氧类、二酮类中的一种或几种混合物。
作为上述技术方案的优选，所述PVC的含量为47-50％。
作为上述技术方案的优选，所述的DOP是邻苯二甲酸二辛酯，其主要成分是邻苯二甲酸酐和2-乙基己醇。
作为上述技术方案的优选，所述的钙锌稳定剂是易溶于有机溶剂的碳数较少的脂肪钙盐和锌盐，主要成分有硬脂酸钙、蓖麻油酸钙、硬脂酸锌、蓖麻油酸锌、以及环氧大豆油、紫外线吸收剂。
作为上述技术方案的优选，
本发明的有益效果在于：本发明的PVC鞋底材料具有较高的回弹性、较低的压缩变形、较高的拉伸强度以及优良的耐磨性、耐热性、耐寒性。
具体实施方式：
为了加深对本发明的理解，下面结合实施例对本发明作进一步详述，该实施例仅用于解释本发明，并不构成对本发明保护范围的限定。
实施例1：
称取PVC材料45g，DOP45g，Ca/Zn复合稳定剂1g，辅助稳定剂2g，CaCO37g于95℃热混10min，再冷混至室温，然后在锥形双螺杆挤出机中挤出造粒，转速15r/min，将粒料在注塑机中注塑成型。
实施例2：
称取PVC材料50g，DOP35g，Ca/Zn复合稳定剂1g，辅助稳定剂1g，CaCO313g于95℃热混10min，再冷混至室温，然后在锥形双螺杆挤出机中挤出造粒，转速15r/min，将粒料在注塑机中注塑成型。
Claims (4)
1.一种高聚合度PVC鞋底材料，其特征在于：以重量百分比计包括如下组分：
其中，辅助稳定剂是亚磷酸酯类、环氧类、二酮类中的一种或几种混合物。
2.根据权利要求1所述的一种高聚合度PVC鞋底材料，其特征在于：所述PVC的含量为47-50%。
3.根据权利要求1所述的一种高聚合度PVC鞋底材料，其特征在于：所述的DOP是邻苯二甲酸二辛酯，其主要成分是邻苯二甲酸酐和2-乙基己醇。
4.根据权利要求1所述的一种高聚合度PVC鞋底材料，其特征在于：所述的钙锌稳定剂是易溶于有机溶剂的碳数较少的脂肪钙盐和锌盐，主要成分有硬脂酸钙、蓖麻油酸钙、硬脂酸锌、蓖麻油酸锌、以及环氧大豆油、紫外线吸收剂。
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| CN103275438B true CN103275438B (zh) | 2016-01-06 |
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| CN103589087A (zh) * | 2013-10-15 | 2014-02-19 | 苏州市景荣科技有限公司 | 一种抗菌防臭pvc鞋底材料 |
| CN104262855A (zh) * | 2014-10-22 | 2015-01-07 | 苏州市景荣科技有限公司 | 一种高耐折的pvc鞋材及其制造方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101323693A (zh) * | 2008-08-05 | 2008-12-17 | 沈阳化工学院 | 一种动态硫化的热塑性弹性体及其制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101323693A (zh) * | 2008-08-05 | 2008-12-17 | 沈阳化工学院 | 一种动态硫化的热塑性弹性体及其制备方法 |
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| C14 | Grant of patent or utility model | ||
| C41 | Transfer of patent application or patent right or utility model | ||
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Inventor after: Wang Xu Inventor before: Huang Chao |
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| TA01 | Transfer of patent application right |
Effective date of registration: 20151214 Address after: 266000 Shandong province Qingdao City, Shandong Road No. 109 Building No. 3 3102 Taiwan Jing Applicant after: QINGDAO JINZHI HIGH AND NEW TECHNOLOGY CO., LTD. Address before: 215000 Suzhou high tech Zone, Jiangsu, the British road, No. 88 Applicant before: Suzhou Jingro Technology Co., Ltd. |
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Inventor after: Wu Yunmiao Inventor before: Wang Xu |
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Effective date of registration: 20160829 Address after: Baiyun District of Guangzhou City, Guangdong province 510000 Wo Street Changhong Industrial Zone No. 1 by second Patentee after: Guangzhou Zhuo shini Footwear Company Limited Address before: 266000 Shandong province Qingdao City, Shandong Road No. 109 Building No. 3 3102 Taiwan Jing Patentee before: QINGDAO JINZHI HIGH AND NEW TECHNOLOGY CO., LTD. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160106 Termination date: 20180621 |