CN103274809B - Oxazine humulone granule - Google Patents
Oxazine humulone granule Download PDFInfo
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- CN103274809B CN103274809B CN201310150732.4A CN201310150732A CN103274809B CN 103274809 B CN103274809 B CN 103274809B CN 201310150732 A CN201310150732 A CN 201310150732A CN 103274809 B CN103274809 B CN 103274809B
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- Prior art keywords
- granule
- agent
- oxazine humulone
- humulone
- gross weight
- Prior art date
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- RMFGNMMNUZWCRZ-UHFFFAOYSA-N Humulone Natural products CC(C)CC(=O)C1=C(O)C(O)(CC=C(C)C)C(O)=C(CC=C(C)C)C1=O RMFGNMMNUZWCRZ-UHFFFAOYSA-N 0.000 title claims abstract description 45
- VMSLCPKYRPDHLN-NRFANRHFSA-N humulone Chemical compound CC(C)CC(=O)C1=C(O)C(CC=C(C)C)=C(O)[C@@](O)(CC=C(C)C)C1=O VMSLCPKYRPDHLN-NRFANRHFSA-N 0.000 title claims abstract description 45
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000008187 granular material Substances 0.000 title claims abstract description 42
- 239000012752 auxiliary agent Substances 0.000 claims abstract 5
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 239000011248 coating agent Substances 0.000 claims description 13
- 239000011230 binding agent Substances 0.000 claims description 12
- 239000003337 fertilizer Substances 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 9
- 239000000470 constituent Substances 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 238000013268 sustained release Methods 0.000 claims description 7
- 239000012730 sustained-release form Substances 0.000 claims description 7
- 239000000975 dye Substances 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 239000006004 Quartz sand Substances 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 229960000892 attapulgite Drugs 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052625 palygorskite Inorganic materials 0.000 claims description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920002799 BoPET Polymers 0.000 claims description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- 229920002261 Corn starch Polymers 0.000 claims description 2
- 239000001828 Gelatine Substances 0.000 claims description 2
- 244000017020 Ipomoea batatas Species 0.000 claims description 2
- 235000002678 Ipomoea batatas Nutrition 0.000 claims description 2
- 239000005041 Mylar™ Substances 0.000 claims description 2
- 239000000020 Nitrocellulose Substances 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 claims description 2
- 235000010489 acacia gum Nutrition 0.000 claims description 2
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 239000011449 brick Substances 0.000 claims description 2
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical group [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 claims description 2
- 229910000020 calcium bicarbonate Inorganic materials 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 235000013877 carbamide Nutrition 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 229920003064 carboxyethyl cellulose Polymers 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 239000008120 corn starch Substances 0.000 claims description 2
- 229940099112 cornstarch Drugs 0.000 claims description 2
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- 239000001923 methylcellulose Substances 0.000 claims description 2
- 229920001220 nitrocellulos Polymers 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000001103 potassium chloride Substances 0.000 claims description 2
- 235000011164 potassium chloride Nutrition 0.000 claims description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
- 235000011151 potassium sulphates Nutrition 0.000 claims description 2
- 229920001592 potato starch Polymers 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- 239000002893 slag Substances 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 229920001059 synthetic polymer Polymers 0.000 claims description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- RNZCSKGULNFAMC-UHFFFAOYSA-L zinc;hydrogen sulfate;hydroxide Chemical compound O.[Zn+2].[O-]S([O-])(=O)=O RNZCSKGULNFAMC-UHFFFAOYSA-L 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 abstract description 7
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 6
- 235000009566 rice Nutrition 0.000 abstract description 6
- 230000002363 herbicidal effect Effects 0.000 abstract description 3
- 239000004009 herbicide Substances 0.000 abstract description 3
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 6
- 241000209094 Oryza Species 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000003556 assay Methods 0.000 description 3
- 238000005538 encapsulation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000012216 screening Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 244000058871 Echinochloa crus-galli Species 0.000 description 1
- FCOHEOSCARXMMS-UHFFFAOYSA-N Oxaziclomefone Chemical compound C1OC(C)=C(C=2C=CC=CC=2)C(=O)N1C(C)(C)C1=CC(Cl)=CC(Cl)=C1 FCOHEOSCARXMMS-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 208000006278 hypochromic anemia Diseases 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000003578 releasing effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003613 toluenes Chemical class 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
Abstract
The present invention relates to Yi Zhong oxazine humulone granule, active ingredient Wei oxazine humulone, surplus is auxiliary agent. The mass percent of oxazine humulone in granule is 0.01%～5%, is applicable to prevent and treat rice terrace annual grassy weeds, is a kind of herbicide safe, efficient, easy to use.
Description
Technical field
A kind of granular pesticide the present invention relates to, active component Wei oxazine humulone.
Technical background
Oxazine humulone, has another name called barnyard grass peace, english common name:oxaziclomefone, molecular formula: C20H19O2Cl2, structural formula:
Oxazine humulone belongs to organic heterocyclic class, is inner sucting conduction type herbicide for paddy field, is mainly absorbed by root and the cauline leaf base portion of weeds. Leaves and stems chlorosis after weeds contacts medicament, stop growing, until withered.
The further investigation of inventor's paroxazine humulone, is prepared into granule, is applicable to prevent and kill off rice terrace annual grassy weeds.
Oxazine humulone agent granule not yet has relevant report at present.
Summary of the invention
Technical problem to be solved: the present invention is directed to prior art a kind of Han oxazine humulone granule is provided, for preventing and treating rice terrace annual grassy weeds, is a kind of herbicide safe, efficient, easy to use.
One of technical scheme of the present invention:
Yi Zhong oxazine humulone granule, the component: oxazine humulone 0.01%-5% that comprises following mass percent, dressing kernel carrier 70%-90%, adhesive 0.5%-10%, coating agent 0.1%-0.3%, dyestuff 0.05%-0.5%.
Wherein, described dressing kernel carrier is the one in particle diameter 8-20 object river sand, quartz sand, deposed brick slag.
Described binding agent is viscosity kaolin, one or both compositions in attapulgite, paraffin, rosin, gelatinized starch, xanthans, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose.
Described coating agent is one or several in polyvinyl alcohol, polyvinylpyrrolidone, mylar, acrylic acid synthetic polymer, acrylic resin film forming agent, butadiene resin film forming agent, polyurethane finishing agent, cellulose nitrate film forming agent.
Described dyestuff is the one in disperse red, disperse blue, disperse violet, active red, reactive blue, active yellow.
The preparation method of Shang Shu oxazine humulone granule, comprises the steps:
1, after being mixed according to a certain ratio, oxazine humulone, binding agent, dyestuff obtain through air-flow crushing
Contain binding agent and the former medicine of dyestuff oxazine humulone to one.
2, coating agent is dissolved to the aqueous solution that obtains coating agent by certain content water.
3, take dressing kernel carrier and be placed in coating equipment in sugar production line, first a certain amount of to adding in encapsulation tool
Coating agent solution be mixed together and stir wetting dressing kernel carrier, then by proportioning to encapsulation tool
The former medicine mix and blend of middle Jia Ru oxazine humulone, makes medicinal powder adhere to be uniformly wrapped in and soaks
On good coating kernel carrier, finally in encapsulation tool, add remaining coating agent solution mixed again
Close and stir.
4, after granule good above-mentioned coating is qualified after testing by drying equipment, obtain 0.01-5%
Oxazine humulone combination particle agent product.
Two of technical scheme of the present invention:
Yi Zhong oxazine humulone granule, the component: oxazine humulone 0.01%～5% that comprises following mass percent, carrier fertilizer 10%～50%, dispersing aid 0.05%～3%, sustained release agent 0.01%～2%, binding agent 0.01%～5%, all the other are filler.
Wherein, described carrier fertilizer is one or more the combination in ammonium chloride, ammonium sulfate, urea, potassium chloride, potassium sulfate, MAP. N constituent content is 5%～20% of granule gross weight, and P constituent content is 0～20% of granule gross weight, and K constituent content is 0～20% of granule gross weight.
Described carrier fertilizer also contains monohydrate zinc sulphate and borax, and its zinc constituent content is 0.05%～2% of granule gross weight, and boron content is 0.05%～2% of granule gross weight.
Described sustained release agent is polyvinyl alcohol or Arabic gum, and binding agent is polyethylene glycol or industrial gelatine, and dispersing aid is cornstarch or sweet potato starch, and filler is calcium bicarbonate and white kaolinic mixture.
The preparation method of Shang Shu oxazine humulone granule: 0.01%～5% oxazine humulone, 0.05%～3% dispersing aid, 0.01%～2% sustained release agent, 0.01%～5% binding agent, 10%～60% carrier fertilizer and surplus filler are mixed in airtight compounding kettle, the granulation of coating method, under 110 DEG C～120 DEG C conditions, be dried to particle water content and be less than 3%, screening, particle size range 2000 μ m～4000 μ m, through after the assay was approved, obtain 0.01%～5% required oxazine humulone granule.
The oxazine humulone granule of Ben Faming has the following advantages.
(1) use conveniently. Without adopting apparatus, directly use and spread fertilizer over the fields.
(2) safety, environmental protection. Do not add the materials such as toluene class, DMF, acetone of inflammable and explosive and environmental pollution etc., ethanol, safety non-pollution in production, transport, storage, use procedure, when production without dust, not drift when use.
(3) excellent. Have the granule of slowly-releasing effect, the drug effect lasting period is long.
(4) cost is low, and Product Process is simple, does not add the high price supplies such as solvent, emulsifying agent, dispersant, wetting agent.
Detailed description of the invention
Below in conjunction with embodiment, content of the present invention is described in further detail, in embodiment, mentioned content is not limitation of the invention, material prescription select can suit measures to local conditions and on result without substantial impact. In these embodiments, unless otherwise indicated, all percentage is all weight percentage.
Embodiment 1,The granule of 0.2% oxazine humulone:
In granule gross weight, wherein: oxazine humulone 0.2%, attapulgite 2%, polyvinylpyrrolidone 0.15%, reactive blue 0.1%, quartz sand surplus.
According to the preparation method of granule technical scheme one of the present invention, above-mentioned material is mixed in airtight compounding kettle, the granulation of coating method, under 120 DEG C of conditions, be dried to particle water content 1%, screening, (μ m), through after the assay was approved, obtains 0.2% oxazine humulone granule for 4000 microns of particle size ranges.
Embodiment 2,0.02% oxazine humulone granule:
In granule gross weight, wherein: oxazine humulone 0.02%, fertilizer 30%, sustained release agent 0.5%, binding agent 5%, coating agent 0.3%, all the other are kaolin filler.
According to the preparation method of granule technical scheme two of the present invention, after the former medicine of 0.02% oxazine humulone, 30% fertilizer, 0.5% sustained release agent, 5% binding agent, 0.3% coating agent, appropriate filler are mixed in airtight agitator tank, add and in Granulation Equipments, carry out the granulation of coating method, under 80 DEG C～100 DEG C conditions, be dried to particle water content and be less than 3%, screening (particle size range 2000um～4000um), through after the assay was approved, obtain 0.02% oxazine humulone granule.
Embodiment 3: in order better to verify practical application effect of the present invention, the field control effectiveness test of granule of the present invention and sterilization fertilizer granular formulation is described below with example. The inventor tested in Lao Keng village, Huidong province of Guangdong Province Ren Shan town in July, 2012.
Reagent agent and consumption:
(1) 0.02% oxazine humulone granule, consumption 3g.a.i/667m2. (2) 0.2% oxazine humulone granules, consumption 3g.a.i/667m2. Contrast medicament: (3) 1% oxazine humulone suspending agents, consumption 3g.a.i/667m2。
Prevent and kill off object: rice seedling throwing field annual grassy weeds.
Result of the test:
。
Result of the test shows, 0.02% oxazine humulone granule and 0.2% oxazine humulone granule are prevented and kill off rice terrace seedling throwing field annual grassy weeds excellent, and effect is better than 1% oxazine humulone suspending agent, to rice safety.
Claims (2)
1. Yi Zhong oxazine humulone granule, is characterized in that: active component Wei oxazine humulone, and all the other are auxiliary agent ， oxazine humulone percentage by weight Wei oxazine humulone 0.01%～5% in granule;
The percentage by weight of auxiliary agent is: dressing kernel carrier 70%～90%, binding agent 0.5%～10%, coating agent 0.1%～0.3%, dyestuff 0.05%～0.5%;
Wherein, described dressing kernel carrier is the one in particle diameter 8-20 object river sand, quartz sand, deposed brick slag;
Described binding agent is one or both compositions in viscosity kaolin, attapulgite, paraffin, rosin, gelatinized starch, xanthans, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose;
Described coating agent is one or several in polyvinyl alcohol, polyvinylpyrrolidone, mylar, acrylic acid synthetic polymer, acrylic resin film forming agent, butadiene resin film forming agent, polyurethane finishing agent, cellulose nitrate film forming agent;
Described dyestuff is the one in disperse red, disperse blue, disperse violet, active red, reactive blue, active yellow.
2. Yi Zhong oxazine humulone granule, is characterized in that: active component Wei oxazine humulone, and all the other are auxiliary agent ， oxazine humulone percentage by weight Wei oxazine humulone 0.01%～5% in granule;
The percentage by weight of auxiliary agent is: carrier fertilizer 10%～50%, and dispersing aid 0.05%～3%, sustained release agent 0.01%～2%, binding agent 0.01%～5%, all the other are filler;
Wherein, described carrier fertilizer is one or more the combination in ammonium chloride, ammonium sulfate, urea, potassium chloride, potassium sulfate, MAP, N constituent content is 5%～20% of granule gross weight, P constituent content is 0～20% of granule gross weight, and K constituent content is 0～20% of granule gross weight;
Described carrier fertilizer also contains monohydrate zinc sulphate and borax, and its zinc constituent content is 0.05%～2% of granule gross weight, and boron content is 0.05%～2% of granule gross weight;
Described sustained release agent is polyvinyl alcohol or Arabic gum;
Described binding agent is polyethylene glycol or industrial gelatine;
Described dispersing aid is cornstarch or sweet potato starch;
Described filler is calcium bicarbonate and white kaolinic mixture.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310150732.4A CN103274809B (en) | 2013-04-27 | 2013-04-27 | Oxazine humulone granule |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310150732.4A CN103274809B (en) | 2013-04-27 | 2013-04-27 | Oxazine humulone granule |
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| CN103274809A CN103274809A (en) | 2013-09-04 |
| CN103274809B true CN103274809B (en) | 2016-05-11 |
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| CN103783062A (en) * | 2014-02-27 | 2014-05-14 | 江苏省激素研究所股份有限公司 | Oxaziclomefone compound herbicide |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102415388A (en) * | 2011-11-07 | 2012-04-18 | 广东中迅农科股份有限公司 | Environmentally friendly high efficiency paddy field herbicide and preparation method thereof |
| CN102432392A (en) * | 2011-09-28 | 2012-05-02 | 广东中迅农科股份有限公司 | Drug fertilizer granules for controlling watermelon wilt and preparation method thereof |
| CN102515936A (en) * | 2011-11-20 | 2012-06-27 | 广东中迅农科股份有限公司 | Granular formulation for paddy pesticide fertilizer and preparation method thereof |
| CN102669137A (en) * | 2012-05-17 | 2012-09-19 | 广东中迅农科股份有限公司 | Sterilization medical fertilizer granules |
| CN103039513A (en) * | 2012-12-27 | 2013-04-17 | 广东中迅农科股份有限公司 | Fosthiazate nematicide granules and preparation method thereof |
| CN103058766A (en) * | 2012-12-29 | 2013-04-24 | 广东中迅农科股份有限公司 | Weeding fertilizer granules of penoxsulam and preparation method thereof |
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| TWI245601B (en) * | 2001-09-26 | 2005-12-21 | Kumiai Chemical Industry Co | Granular agricultural chemical preparations and its scattering method with uniformly diffusivity |
| JP5932367B2 (en) * | 2011-02-07 | 2016-06-08 | 三井化学アグロ株式会社 | Rice rice mildew control method |
-
2013
- 2013-04-27 CN CN201310150732.4A patent/CN103274809B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102432392A (en) * | 2011-09-28 | 2012-05-02 | 广东中迅农科股份有限公司 | Drug fertilizer granules for controlling watermelon wilt and preparation method thereof |
| CN102415388A (en) * | 2011-11-07 | 2012-04-18 | 广东中迅农科股份有限公司 | Environmentally friendly high efficiency paddy field herbicide and preparation method thereof |
| CN102515936A (en) * | 2011-11-20 | 2012-06-27 | 广东中迅农科股份有限公司 | Granular formulation for paddy pesticide fertilizer and preparation method thereof |
| CN102669137A (en) * | 2012-05-17 | 2012-09-19 | 广东中迅农科股份有限公司 | Sterilization medical fertilizer granules |
| CN103039513A (en) * | 2012-12-27 | 2013-04-17 | 广东中迅农科股份有限公司 | Fosthiazate nematicide granules and preparation method thereof |
| CN103058766A (en) * | 2012-12-29 | 2013-04-24 | 广东中迅农科股份有限公司 | Weeding fertilizer granules of penoxsulam and preparation method thereof |
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