CN103255543A - Method for preparing borneol synthetic fiber anti-mosquito functional fabric - Google Patents

Method for preparing borneol synthetic fiber anti-mosquito functional fabric Download PDF

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Publication number
CN103255543A
CN103255543A CN2013101621480A CN201310162148A CN103255543A CN 103255543 A CN103255543 A CN 103255543A CN 2013101621480 A CN2013101621480 A CN 2013101621480A CN 201310162148 A CN201310162148 A CN 201310162148A CN 103255543 A CN103255543 A CN 103255543A
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borneol
mosquito
fiber
nylon
synthetic fiber
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CN2013101621480A
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刘志强
刘然
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Zhejiang University ZJU
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Zhejiang University ZJU
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Abstract

The invention relates to a method for preparing a borneol synthetic fiber anti-mosquito functional fabric. The method comprises the steps of picking fresh new sway borneol camphor leaves and branches with more than two tree years, cleaning the leaves and the branches, drying moisture, arranging the leaves and the branches in a sealing steam pressure tank, conducting cooking, collecting borneol crystals in the inner wall of a cooling tank, enabling the borneol crystals and nylon 66 particles or polyester chips to be fused and mixed to be in a liquid state, machining the liquid into a fiber through silk drawing or silk spraying, and enabling the fiber or the fiber and a nylon fiber or polyester filament yarn or real silk fiber to be machined into the anti-mosquito fabric in a knitted mode. The method can be widely used for producing civil anti-mosquito shirts, silk stockings, anti-mosquito silk fabrics, anti-mosquito clothes of soldiers in an army and outdoor workers, and has biocompatibility on a human body and anti-mosquito and insect-prevention durability.

Description

A kind of preparation method of borneol synthetic fiber mosquito proof functional fabric
Technical field
The present invention relates to a kind of preparation method of mosquito proof functional fabric, especially the preparation method of borneol synthetic fiber mosquito proof functional fabric.
Background technology
Mosquito is global to mankind's harassing and wrecking with harm, and is with a long history.Viral disease by killing propagation has multiple, steps on Ge Shi fever virus very harmful to the mankind due to especially biting with yellow-fever mosquito, is a kind of acute infectious disease, have propagate fast, the incidence of disease is high, severe patient can present meningitis, massive haemorrhage and shock cause death.The report of research is arranged, but survived 200 years under the drought condition of yellow-fever mosquito worm's ovum desert, and treatment dengue fever specific drug is not arranged at present in the world as yet, do not have the vaccine protection again, in case dengue fever is popular, will bring great harm to human life's health and socio-economic development.In recent years, Southeast Asian countries dengue fever epidemic situation is very serious, has every year the tens of thousands of people to fall ill, hundreds of people's death.The extremely concern of national government the dengue epidemic example also once appearred, in ground such as China Guangdong, Taiwan.The U.S. develops, and " the biochemical mosquito " of hundreds thousand of of plan inputs through genetic modification, and with the female yellow-fever mosquito mating of nature, output has to the young mosquito of life defective, through behind the several generations, yellow-fever mosquito thoroughly is destroyed.At present, China prevents that yellow-fever mosquito from still adopting environment to spray fast-acting insecticide, and not only contaminated environment equally also can injure beneficial insect, and technology is very backward.
The medicine that employing has distillation character smoke that to keep away be a kind of technology commonly used, and comprise from wormwood and common camphor tree and extract camphor, and naphthalene etc., making manually, " camphor ball " has the effect of mosquito-proof expelling parasite.Have plenty of left-handed and type borneol but wormwood contains, contact with human body skin and can cause redness, irritating in various degree such as ulcer; Camphor is wrongly taken and can be caused poisoning, and 0.5 ~ 1.0g for oral administration can produce dizzy, headache; Naphthalene is a kind of aromatic series Polyphenols chemical substance, and long-term the contact with human body can be caused dizziness, feels sick and waits toxic action.Above material all has the incompatibility that contacts with human body.
1988, in falling in Dong Autonomous County of Xinhuang, China Hunan step head, the virgin forest of Miao Xiang finds the wild canella of Chinese first strain first, because be rich in the natural borneol of dextroform, so the borneol camphor tree of gaining the name ( CirmamonunCamphor), can reach 99.9% through extracting borneol purity, be the valuable ingredient of traditional Chinese medicine that a kind of human body is easy to absorb, the good reputation of plant gold is arranged.So far, manually forest cultivation surpasses 200,000 mu, and all nursery stocks are all named new rolling dryobalanops aromatica Gaertner, have filled up the blank that China does not produce borneol.Borneol mixes under dissolved state with synthetic fiber such as nylon, terylene, adopt conventional spinning technology, make the spinning of borneol nylon or borneol terylene, be made into fabric again, have mosquito-proof, insect protected function, its usefulness is in the following areas: 1) dextroform borneol is free from foreign meter, the purity height, pure natural has the biocompatibility that suitable human body contacts, the safety non-toxic negative interaction has overcome wormwood, camphor tree and naphthalene and human body has been contacted discomfort and the toxic action that produces; 2) borneol can dissolve under uniform temp with nylon, terylene etc., evenly mixes, and adopts conventional spinning technology, makes the synthetic fiber yarn based on borneol, is made into the mosquito proof functional fabric again, does not need increase equipment, is easy to go into operation; 3) borneol nylon, terylene synthetic fiber yarn fabric have the borneol slowly-releasing to put and borneol difficult drop-off effect, are not afraid of and tan by the sun, drench with rain, and high temperature is fit to washing repeatedly, and the mosquito proof effect is lasting; 4) borneol nylon, terylene synthetic fiber fabric are made easy shirt next to the skin, and silk stocking etc. are fit to out receive dry in the air, and prevent all kinds of bite by mosquitos, significantly improve people's quality of life; 5) borneol nylon, terylene synthetic fiber fabric, the suitable mosquito-expelling clothing of making the soldier of army and field worker can improve the adaptive capacity under the special environment; 6) the borneol nylon fiber also can with silk blend, make natural insect protected silk goods, no longer need the camphor ball insect-proof agent when depositing, also can make other clothings that are stacked together, avoid damaging by worms.
Summary of the invention
The preparation method who the purpose of this invention is to provide a kind of borneol synthetic fiber mosquito proof functional fabric.
For reaching above-mentioned purpose, the present invention has following two kinds of technical solutions:
Scheme 1:
The preparation method of borneol synthetic fiber mosquito proof functional fabric comprises the steps:
1) plucks the age of tree more than 2 years, fresh new rolling borneol camphortree leaf and branch, clear water is rinsed well, dry moisture in the shelter from the sun, place in the airtight steam autoclave, boiling 4 ~ 7 hours, make steam pass through cooling tank, collect the borneol crystalline solid at the cooling tank inwall, be stored in the container of close drying, put the cool place and locate standby;
2) with borneol crystalline solid and nylon 66 particles by weight 1:9~1:12, in 260~270 ℃ down fusion be mixed into liquid state, through wire drawing or spray silk, obtain borneol nylon synthetic fiber;
3) be raw material with borneol nylon synthetic fiber, be knitted into the mosquito proof fabric; Perhaps with borneol nylon synthetic fiber and nylon fiber in ratio proportioning warp and the parallel of 1:1, be knitted into the mosquito proof fabric.
Scheme 2:
The preparation method of borneol synthetic fiber mosquito proof functional fabric comprises the steps:
1) plucks the age of tree more than 2 years, fresh new rolling borneol camphortree leaf and branch, clear water is rinsed well, dry moisture in the shelter from the sun, place in the airtight steam autoclave, boiling 4 ~ 7 hours, make steam pass through cooling tank, collect the borneol crystalline solid at the cooling tank inwall, be stored in the container of close drying, put the cool place and locate standby;
2) with borneol crystalline solid and terylene chips by weight 1:4~1:6, in 270~285 ℃ down fusion be mixed into liquid state, through the spray silk, obtain borneol terylene synthetic thread;
3) with borneol terylene synthetic thread and polyester filament in ratio proportioning warp and the parallel of 2:1, be knitted into the mosquito proof fabric, perhaps with borneol terylene synthetic thread and cocoon fiber in ratio proportioning warp and the parallel of 1:3, be knitted into the mosquito proof fabric.
Beneficial effect of the present invention is:
Preparation technology of the present invention is simple, and the borneol synthetic fiber mosquito proof functional fabric of making can be widely used in the mosquito-expelling clothing of the civilian mosquito-proof shirt of production, silk stocking, insect protected silk goods, the soldier of army and field worker etc.Have biocompatibility and persistence mosquito-proof, insect protected to human body.
The specific embodiment
Embodiment 1:
1) plucks the age of tree more than 2 years, fresh new rolling borneol camphortree leaf and branch, clear water flushing surface dirt and earth, under shading shed, drain or dry up moisture, place in the airtight steam autoclave, boiling 4 hours, making steam pass through cooling tank discharges again, obtain the borneol crystalline solid of the translucent lobate or hexagon sheet of a large amount of whites at the cooling tank inwall, be stored in the container of close drying, it is standby to put shady and cool place;
2) with borneol crystalline solid and nylon 66 particles by weight 1:11.5, in 263 ℃ down fusion be mixed into liquid state, through wire drawing preparation technology, make borneol nylon synthetic fiber;
3) with borneol nylon synthetic fiber and nylon fiber ratio proportioning warp and the parallel with 1:1, adopt needleloom process to make borneol synthetic fiber functional fabric, be fit to processing casual shirt next to the skin and casual pants, prevent the outer cashier bite by mosquitos that dries in the air.
Embodiment 2:
1) plucks the age of tree more than 2 years, fresh new rolling borneol camphortree leaf and branch, clear water flushing surface dirt and earth, under shading shed, drain or dry up moisture, place in the airtight steam autoclave, boiling 7 hours, making steam pass through cooling tank discharges again, obtain the translucent lobate or hexagon sheet borneol crystalline solid of a large amount of whites at the cooling tank inwall, be stored in the container of close drying, put the cool place and locate standby;
2) with borneol crystalline solid and nylon 66 particles by weight 1:9, in 265 ℃ down fusion be mixed into liquid state, through wire drawing preparation technology, make borneol nylon synthetic fiber;
3) be raw material with borneol nylon synthetic fiber, on stocking leg loom, prepare silk stocking, directly contact skin, prevent bite by mosquitos.
Embodiment 3:
1) plucks the age of tree more than 2 years, fresh new rolling borneol camphortree leaf and branch, clear water flushing surface dirt and earth, under shading shed, drain or dry up moisture, place in the airtight steam autoclave, boiling 5 hours, making steam pass through cooling tank discharges again, obtain the translucent lobate or hexagon sheet borneol crystalline solid of a large amount of whites at the cooling tank inwall, be stored in the container of close drying, put the cool place and locate standby;
2) with borneol crystalline solid and terylene chips by weight 1:4.9, in 273 ℃ down fusion be mixed into liquid state, make not have with high speed spinning up-coiler technology through aperture plate spray silk and pick up amorphous borneol terylene synthetic thread;
3) with borneol terylene synthetic thread and polyester filament ratio proportioning warp and the parallel with 2:1, adopt needleloom process to prepare borneol terylene synthetic fiber functional fabric, be fit to the mosquito-expelling clothing of the processing soldier of army and field worker, can improve the adaptive capacity under the special environment.
Embodiment 4:
1) plucks the age of tree more than 2 years, fresh new rolling borneol camphortree leaf and branch, clear water flushing surface dirt and earth, under shading shed, drain or dry up moisture, place in the airtight steam autoclave, boiling 6 hours, making steam pass through cooling tank discharges again, obtain the translucent lobate or hexagon sheet borneol crystalline solid of a large amount of whites at the cooling tank inwall, be stored in the container of close drying, put the cool place and locate standby;
2) with borneol crystalline solid and terylene chips by weight 1:5.7, in 282 ℃ down fusion be mixed into liquid state, make not have with high speed spinning up-coiler technology through aperture plate spray silk and pick up amorphous borneol terylene synthetic thread;
3) with borneol terylene synthetic thread and cocoon fiber ratio proportioning warp and the parallel with 1:3, adopt needleloom process to prepare borneol terylene cocoon fiber functional fabric, be fit to the natural mosquito proof real silk fabric of processing, improve real silk fabric quality.

Claims (2)

1. the preparation method of a borneol synthetic fiber mosquito proof functional fabric is characterized in that comprising the steps:
1) plucks the age of tree more than 2 years, fresh new rolling borneol camphortree leaf and branch, clear water is rinsed well, dry moisture in the shelter from the sun, place in the airtight steam autoclave, boiling 4 ~ 7 hours, make steam pass through cooling tank, collect the borneol crystalline solid at the cooling tank inwall, be stored in the container of close drying, put the cool place and locate standby;
2) with borneol crystalline solid and nylon 66 particles by weight 1:9~1:12, in 260~270 ℃ down fusion be mixed into liquid state, through wire drawing or spray silk, obtain borneol nylon synthetic fiber;
3) be raw material with borneol nylon synthetic fiber, be knitted into the mosquito proof fabric; Perhaps with borneol nylon synthetic fiber and nylon fiber in ratio proportioning warp and the parallel of 1:1, be knitted into the mosquito proof fabric.
2. the preparation method of a borneol synthetic fiber mosquito proof functional fabric is characterized in that comprising the steps:
1) plucks the age of tree more than 2 years, fresh new rolling borneol camphortree leaf and branch, clear water is rinsed well, dry moisture in the shelter from the sun, place in the airtight steam autoclave, boiling 4 ~ 7 hours, make steam pass through cooling tank, collect the borneol crystalline solid at the cooling tank inwall, be stored in the container of close drying, put the cool place and locate standby;
2) with borneol crystalline solid and terylene chips by weight 1:4~1:6, in 270~285 ℃ down fusion be mixed into liquid state, through the spray silk, obtain borneol terylene synthetic thread;
3) with borneol terylene synthetic thread and polyester filament in ratio proportioning warp and the parallel of 2:1, be knitted into the mosquito proof fabric, perhaps with borneol terylene synthetic thread and cocoon fiber in ratio proportioning warp and the parallel of 1:3, be knitted into the mosquito proof fabric.
CN2013101621480A 2013-05-06 2013-05-06 Method for preparing borneol synthetic fiber anti-mosquito functional fabric Pending CN103255543A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105177794A (en) * 2015-07-14 2015-12-23 爱谱诗(苏州)服装有限公司 Manufacturing process of anti-mosquito garment material
CN105926278A (en) * 2016-05-17 2016-09-07 芜湖三刀材料科技有限公司 Synthetic-fiber composite fabric
CN107198271A (en) * 2017-07-27 2017-09-26 合肥远科服装设计有限公司 A kind of production method of flowery odour anti-mosquito clothes
CN110306340A (en) * 2019-05-16 2019-10-08 北京化工大学 Antimicrobial natural textile material of surface modification borneol and the preparation method and application thereof
CN113022058A (en) * 2021-04-16 2021-06-25 安正时尚集团股份有限公司 Mosquito-proof high-elasticity fabric and production process and device thereof

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Publication number Priority date Publication date Assignee Title
CN1075710A (en) * 1992-02-26 1993-09-01 新晃侗族自治县林业局 From camphor leaf, extract the method for d-Bomeol
CN202052227U (en) * 2011-02-22 2011-11-30 北京京棉纺织集团有限责任公司 Fire-fighting face mask
WO2012138012A1 (en) * 2011-04-08 2012-10-11 Han Kyun Sick Fabric for preventing mosquito bites, and method for manufacturing same
CN202530231U (en) * 2012-04-03 2012-11-14 昆山华阳复合材料科技有限公司 Ice-cold anti-mosquito fabric
CN102808287A (en) * 2012-08-02 2012-12-05 上海理工大学 Nanofiber membrane shaped borneol composite and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1075710A (en) * 1992-02-26 1993-09-01 新晃侗族自治县林业局 From camphor leaf, extract the method for d-Bomeol
CN202052227U (en) * 2011-02-22 2011-11-30 北京京棉纺织集团有限责任公司 Fire-fighting face mask
WO2012138012A1 (en) * 2011-04-08 2012-10-11 Han Kyun Sick Fabric for preventing mosquito bites, and method for manufacturing same
CN202530231U (en) * 2012-04-03 2012-11-14 昆山华阳复合材料科技有限公司 Ice-cold anti-mosquito fabric
CN102808287A (en) * 2012-08-02 2012-12-05 上海理工大学 Nanofiber membrane shaped borneol composite and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
马正升等: ""防螨纤维及织物的研究进展"", 《金山油化纤》, no. 4, 25 December 2002 (2002-12-25) *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105177794A (en) * 2015-07-14 2015-12-23 爱谱诗(苏州)服装有限公司 Manufacturing process of anti-mosquito garment material
CN105926278A (en) * 2016-05-17 2016-09-07 芜湖三刀材料科技有限公司 Synthetic-fiber composite fabric
CN107198271A (en) * 2017-07-27 2017-09-26 合肥远科服装设计有限公司 A kind of production method of flowery odour anti-mosquito clothes
CN110306340A (en) * 2019-05-16 2019-10-08 北京化工大学 Antimicrobial natural textile material of surface modification borneol and the preparation method and application thereof
CN113022058A (en) * 2021-04-16 2021-06-25 安正时尚集团股份有限公司 Mosquito-proof high-elasticity fabric and production process and device thereof

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Application publication date: 20130821