CN103224693A - 聚酯/聚乙烯合金材料及其制备方法 - Google Patents
聚酯/聚乙烯合金材料及其制备方法 Download PDFInfo
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- CN103224693A CN103224693A CN2013101941671A CN201310194167A CN103224693A CN 103224693 A CN103224693 A CN 103224693A CN 2013101941671 A CN2013101941671 A CN 2013101941671A CN 201310194167 A CN201310194167 A CN 201310194167A CN 103224693 A CN103224693 A CN 103224693A
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- polyester
- polyethylene
- alloy material
- maleic anhydride
- compatilizer
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- 229920000728 polyester Polymers 0.000 title claims abstract description 117
- 239000000956 alloy Substances 0.000 title claims abstract description 93
- 239000004698 Polyethylene Substances 0.000 title claims abstract description 89
- 229920000573 polyethylene Polymers 0.000 title claims abstract description 88
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 51
- 229920000092 linear low density polyethylene Polymers 0.000 claims abstract description 49
- 239000004707 linear low-density polyethylene Substances 0.000 claims abstract description 49
- -1 polyethylene Polymers 0.000 claims abstract description 36
- 238000012545 processing Methods 0.000 claims abstract description 8
- 238000011084 recovery Methods 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 30
- 229920001903 high density polyethylene Polymers 0.000 claims description 21
- 239000004700 high-density polyethylene Substances 0.000 claims description 21
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 20
- 229920006124 polyolefin elastomer Polymers 0.000 claims description 19
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- 239000003960 organic solvent Substances 0.000 claims description 10
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 8
- 238000005469 granulation Methods 0.000 claims description 8
- 230000003179 granulation Effects 0.000 claims description 8
- 229920001526 metallocene linear low density polyethylene Polymers 0.000 claims description 8
- 230000001376 precipitating effect Effects 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 229920001684 low density polyethylene Polymers 0.000 claims description 3
- 239000004702 low-density polyethylene Substances 0.000 claims description 3
- 229920001179 medium density polyethylene Polymers 0.000 claims description 3
- 239000004701 medium-density polyethylene Substances 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 abstract description 16
- 238000005516 engineering process Methods 0.000 abstract description 3
- 238000005491 wire drawing Methods 0.000 abstract description 3
- 229920001971 elastomer Polymers 0.000 abstract 2
- 239000000806 elastomer Substances 0.000 abstract 2
- 229920001910 maleic anhydride grafted polyolefin Polymers 0.000 abstract 2
- 238000001125 extrusion Methods 0.000 abstract 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 41
- 229920000139 polyethylene terephthalate Polymers 0.000 description 41
- 239000000463 material Substances 0.000 description 22
- 238000012360 testing method Methods 0.000 description 22
- 238000003756 stirring Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 239000012467 final product Substances 0.000 description 4
- 230000008014 freezing Effects 0.000 description 4
- 238000007710 freezing Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229920006351 engineering plastic Polymers 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- LLQPHQFNMLZJMP-UHFFFAOYSA-N Fentrazamide Chemical compound N1=NN(C=2C(=CC=CC=2)Cl)C(=O)N1C(=O)N(CC)C1CCCCC1 LLQPHQFNMLZJMP-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical class [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000006353 environmental stress Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Images
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
项目 | 实施例3 | 实施例4 | PETH100 | LLDPE |
密度(g/cm3) | 1.1 | 1.1 | 1.40 | 0.92 |
拉伸强度(MPa) | 48.00 | 37.76 | 87.2 | 11 |
断裂伸长率(%) | 798.3 | 470.0 | 3 | 600 |
冲击强度(KJ/m2) | 21.5 | 18.3 | 73 | 不断 |
Claims (10)
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CN201310194167.1A CN103224693B (zh) | 2013-05-22 | 2013-05-22 | 聚酯/聚乙烯合金材料及其制备方法 |
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CN201310194167.1A CN103224693B (zh) | 2013-05-22 | 2013-05-22 | 聚酯/聚乙烯合金材料及其制备方法 |
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CN103224693A true CN103224693A (zh) | 2013-07-31 |
CN103224693B CN103224693B (zh) | 2016-12-28 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103992625A (zh) * | 2014-06-09 | 2014-08-20 | 上海祥羚光电科技发展有限公司 | 一种显示屏的抗蓝光危害的保护膜及其制备方法 |
CN104312112A (zh) * | 2014-11-06 | 2015-01-28 | 文安东都嘉诚再生资源有限公司 | 一种聚酯聚乙烯合金塑料管材及其制备方法 |
CN105801756A (zh) * | 2016-04-07 | 2016-07-27 | 常州大学 | 一种lldpe/pet高性能共混增容新方法 |
CN107880496A (zh) * | 2017-11-15 | 2018-04-06 | 四川塑金科技有限公司 | 再生一次性购物袋 |
CN107936487A (zh) * | 2017-11-15 | 2018-04-20 | 四川塑金科技有限公司 | 再生一次性购物袋的制备方法 |
CN112250934A (zh) * | 2020-11-17 | 2021-01-22 | 深圳中轩生态环境科技有限公司 | 一种聚乙烯改性的高强复合合金材料制备方法 |
CN112266526A (zh) * | 2020-11-17 | 2021-01-26 | 深圳中轩生态环境科技有限公司 | 一种用于生态固土的聚乙烯改性的高强复合合金材料 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1392169A (zh) * | 2002-07-04 | 2003-01-22 | 上海交通大学 | 聚乙烯-马来酸酐接枝共聚物溶剂热合成制备方法 |
-
2013
- 2013-05-22 CN CN201310194167.1A patent/CN103224693B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1392169A (zh) * | 2002-07-04 | 2003-01-22 | 上海交通大学 | 聚乙烯-马来酸酐接枝共聚物溶剂热合成制备方法 |
Non-Patent Citations (2)
Title |
---|
张华集等: ""MAH-g-LLDPE增容改性rPET/mLLDPE合金材料的研究"", 《塑料助剂》 * |
王春广等: ""PP-g-MA 及其混合相容剂增容r-PET /PP共混物的力学性能"", 《中山大学学报( 自然科学版)》 * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103992625A (zh) * | 2014-06-09 | 2014-08-20 | 上海祥羚光电科技发展有限公司 | 一种显示屏的抗蓝光危害的保护膜及其制备方法 |
CN104312112A (zh) * | 2014-11-06 | 2015-01-28 | 文安东都嘉诚再生资源有限公司 | 一种聚酯聚乙烯合金塑料管材及其制备方法 |
CN105801756A (zh) * | 2016-04-07 | 2016-07-27 | 常州大学 | 一种lldpe/pet高性能共混增容新方法 |
CN105801756B (zh) * | 2016-04-07 | 2018-02-02 | 常州大学 | 一种lldpe/pet高性能共混增容新方法 |
CN107880496A (zh) * | 2017-11-15 | 2018-04-06 | 四川塑金科技有限公司 | 再生一次性购物袋 |
CN107936487A (zh) * | 2017-11-15 | 2018-04-20 | 四川塑金科技有限公司 | 再生一次性购物袋的制备方法 |
CN112250934A (zh) * | 2020-11-17 | 2021-01-22 | 深圳中轩生态环境科技有限公司 | 一种聚乙烯改性的高强复合合金材料制备方法 |
CN112266526A (zh) * | 2020-11-17 | 2021-01-26 | 深圳中轩生态环境科技有限公司 | 一种用于生态固土的聚乙烯改性的高强复合合金材料 |
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Effective date of registration: 20151207 Address after: 100013 No. 9, Xinghua Road, Dongcheng District, Beijing, Hepingli Applicant after: BEIJING NO.5 CONSTRUCTION ENGINEERING GROUP Co.,Ltd. Applicant after: WENAN-DONGDU JIACHENG RECYCLED RESOURCES Co.,Ltd. Address before: 065800 Wen Andong environmental protection industrial park, Wen'an County, Langfang, Hebei Applicant before: WENAN-DONGDU JIACHENG RECYCLED RESOURCES Co.,Ltd. Applicant before: BEIJING NO.5 CONSTRUCTION ENGINEERING GROUP Co.,Ltd. |
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Effective date of registration: 20181010 Address after: 101100 No. 27 building, Yun Li village, Lane Li village, Liyuan Town, Tongzhou District, Beijing 462 Patentee after: Zhu Daofeng Address before: 100013 9 Xinghua Road, Hepingli, Dongcheng District, Beijing. Co-patentee before: WENAN-DONGDU JIACHENG RECYCLED RESOURCES Co.,Ltd. Patentee before: BEIJING NO.5 CONSTRUCTION ENGINEERING GROUP Co.,Ltd. |
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Effective date of registration: 20181108 Address after: 518104 Baoan Renewable Resources Sorting Yard, north of Shangnan Avenue and east of Guangzhou-Shenzhen Expressway, Baoan District, Shenzhen City, Guangdong Province Patentee after: Shenzhen Luhuan Regeneration Resource Development Co.,Ltd. Address before: 101100 No. 27 building, Yun Li village, Lane Li village, Liyuan Town, Tongzhou District, Beijing 462 Patentee before: Zhu Daofeng |
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Denomination of invention: Polyester/polyethylene alloy materials and their preparation methods Effective date of registration: 20231206 Granted publication date: 20161228 Pledgee: Bank of Communications Limited Shenzhen Branch Pledgor: Shenzhen Luhuan Regeneration Resource Development Co.,Ltd. Registration number: Y2023980069736 |