CN103215072B - 一种高效加氢转化煤焦油生产柴油的方法 - Google Patents
一种高效加氢转化煤焦油生产柴油的方法 Download PDFInfo
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- CN103215072B CN103215072B CN201310171259.8A CN201310171259A CN103215072B CN 103215072 B CN103215072 B CN 103215072B CN 201310171259 A CN201310171259 A CN 201310171259A CN 103215072 B CN103215072 B CN 103215072B
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- coal tar
- diesel oil
- bed reactor
- oil
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- 239000011280 coal tar Substances 0.000 title claims abstract description 52
- 239000002283 diesel fuel Substances 0.000 title claims abstract description 33
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 title abstract description 5
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 14
- 239000003054 catalyst Substances 0.000 claims abstract description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 239000002002 slurry Substances 0.000 claims abstract description 8
- 238000000926 separation method Methods 0.000 claims abstract description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 230000001131 transforming effect Effects 0.000 claims description 9
- 230000000694 effects Effects 0.000 claims description 4
- 238000004062 sedimentation Methods 0.000 claims description 3
- 239000012141 concentrate Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 abstract description 14
- 239000000295 fuel oil Substances 0.000 abstract description 3
- 230000011218 segmentation Effects 0.000 abstract 2
- 239000000047 product Substances 0.000 description 7
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
- 239000002994 raw material Substances 0.000 description 5
- 238000009835 boiling Methods 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000004939 coking Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
浆态床催化剂 | 固定床催化剂 | |
比表面积,m2/g | 287 | 120 |
孔容,mL/g | 0.85 | 0.37 |
可几孔径,nm | 11.8 | 7.2 |
载体 | γ-Al2O3 | γ-Al2O3 |
氧化钴,% | 4.7 | / |
氧化钼,% | 15.2 | / |
氧化镍,% | / | 4.2 |
氧化钨,% | / | 27.4 |
20℃密度/(kg/m3) | 1.058 |
50℃粘度/(mm2/s) | 93.46 |
O含量/% | 8.50 |
C含量/% | 82.71 |
H含量/% | 8.35 |
S含量/% | 0.26 |
N含量/% | 0.57 |
馏程,D-1160/℃ | |
IBP | 195 |
10% | 279 |
30% | 327 |
50% | 365 |
70% | 392 |
90% | 435 |
95% | 471 |
20℃密度/(kg/m3) | 0.8497 |
20℃粘度/(mm2/s) | 3.92 |
S含量/(μg/g) | 5.1 |
十六烷值 | 46.2 |
烃类组成/% | |
链烷烃 | 26.4 |
环烷烃 | 70.6 |
芳烃 | 3.0 |
馏程,D-1160/℃ | |
IBP | 152 |
10% | 195 |
30% | 247 |
50% | 281 |
70% | 314 |
90% | 346 |
95% | 359 |
贫沥青质相 | 富沥青质相 | |
20℃密度/(kg/m3) | 0.8985 | 1.069 |
50℃粘度/(mm2/s) | / | 139.2 |
O含量/% | 1.02 | 4.28 |
C7不溶物(沥青质)/% | 0.8 | 22.4 |
馏程,D-1160/℃ | ||
IBP | 196 | 235 |
10% | 218 | 271 |
30% | 236 | 308 |
50% | 265 | 354 |
70% | 295 | 392 |
90% | 312 | 441 |
95% | 435 | 457 |
石脑油 | 柴油 | 蜡油 | |
液体产品收率(相对煤焦油全馏分)/% | 9.17 | 54.67 | 33.83 |
20℃密度/(kg/m3) | 0.7811 | 0.8497 | 0.9127 |
S含量/(μg/g) | 1.6 | 5.1 | 10.2 |
凝固点/℃ | / | -3 | 22 |
闪点/℃ | / | 66 | / |
十六烷值 | / | 46.2 | / |
馏程/℃ | D-86 | D-86 | D-1160 |
IBP | 39 | 152 | 355 |
50 | 102 | 287 | 396 |
95 | / | / | 439 |
FBP | 157 | 359 | / |
Claims (6)
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CN103215072B true CN103215072B (zh) | 2015-01-07 |
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Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105778987B (zh) * | 2016-02-23 | 2017-08-29 | 新疆恒晟能源科技有限公司 | 一种生物质柴油和船用燃料油的生产方法 |
CN107557069B (zh) * | 2016-06-30 | 2020-03-24 | 中国石油化工股份有限公司 | 煤焦油原料加氢转化的方法和煤焦油原料加氢转化的系统 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6207041B1 (en) * | 1997-10-14 | 2001-03-27 | Institut Francais Du Petrole | Process for converting heavy crude oil fractions, comprising an ebullating bed hydroconversion step and a hydrotreatment step |
CN1903994A (zh) * | 2006-08-03 | 2007-01-31 | 湖南长岭石化科技开发有限公司 | 一种煤焦油加氢改质生产燃料油的方法 |
CN101838550A (zh) * | 2010-06-17 | 2010-09-22 | 湖南长岭石化科技开发有限公司 | 一种煤焦油的预处理方法 |
CN101838549A (zh) * | 2010-06-17 | 2010-09-22 | 湖南长岭石化科技开发有限公司 | 一种煤焦油的预处理方法 |
CN102311799A (zh) * | 2010-07-07 | 2012-01-11 | 中国石油化工股份有限公司 | 一种渣油处理组合工艺方法 |
CN103059973A (zh) * | 2011-10-24 | 2013-04-24 | 中国科学院过程工程研究所 | 一种煤焦油全馏分加氢的浆态床与固定床耦合方法 |
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2013
- 2013-05-10 CN CN201310171259.8A patent/CN103215072B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6207041B1 (en) * | 1997-10-14 | 2001-03-27 | Institut Francais Du Petrole | Process for converting heavy crude oil fractions, comprising an ebullating bed hydroconversion step and a hydrotreatment step |
CN1903994A (zh) * | 2006-08-03 | 2007-01-31 | 湖南长岭石化科技开发有限公司 | 一种煤焦油加氢改质生产燃料油的方法 |
CN101838550A (zh) * | 2010-06-17 | 2010-09-22 | 湖南长岭石化科技开发有限公司 | 一种煤焦油的预处理方法 |
CN101838549A (zh) * | 2010-06-17 | 2010-09-22 | 湖南长岭石化科技开发有限公司 | 一种煤焦油的预处理方法 |
CN102311799A (zh) * | 2010-07-07 | 2012-01-11 | 中国石油化工股份有限公司 | 一种渣油处理组合工艺方法 |
CN103059973A (zh) * | 2011-10-24 | 2013-04-24 | 中国科学院过程工程研究所 | 一种煤焦油全馏分加氢的浆态床与固定床耦合方法 |
Non-Patent Citations (1)
Title |
---|
高温煤焦油加氢技术与进展;周军等;《山东化工》;20120630;第41卷;第38-40页 * |
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