CN103214980A - Discoloring solid rubber stick and preparation method thereof - Google Patents
Discoloring solid rubber stick and preparation method thereof Download PDFInfo
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- CN103214980A CN103214980A CN2013101761170A CN201310176117A CN103214980A CN 103214980 A CN103214980 A CN 103214980A CN 2013101761170 A CN2013101761170 A CN 2013101761170A CN 201310176117 A CN201310176117 A CN 201310176117A CN 103214980 A CN103214980 A CN 103214980A
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Abstract
The invention discloses a discoloring solid rubber stick and a preparation method thereof. The discoloring solid rubber stick is prepared from the following raw materials in parts by weight: 55.0-85.0 parts of water, 15.0-25.0 parts of polyvinylpyrrolidone, 5.0-10.0 parts of styrene-acrylic emulsion, 10.0-15.0 parts of acrylic emulsion, 5.0-10.0 parts of dextrin, 5.0-15.0 parts of propylene glycol or glycerin, 5.0-15.0 parts of stearic acid, 0.5-3.0 parts of sodium hydroxide, 1.0-5.0 parts of light changing pigment, 10.0-15.0 parts of calcium carbonate or kaolinite and 0.2-3.0 parts of butyl p-hydroxybenzoate. The discoloring solid rubber stick disclosed by the invention has the characteristics of high bonding strength, high bonding speed, good temperature resistance, long storage life, beautiful color, unique style and the like, can be cleaned with water and stored for long time, and is safe and environment-friendly, easy to use and wide in range of application.
Description
Technical field
The present invention relates to a kind of allochroic solid rod and preparation method thereof, belong to chemical material technical field.
Background technology
Solid gums claims solid glue stick, solid paste, lipstick formula paste etc. again.System is a raw material with sizing material, essence and water etc., and is formulated through rationally.
Solid gums is a kind of product innovation in the tackiness agent.Its principal feature is: raw material is easy to get, and makes simply, and long preservative period is easy to carry, and is easy to use, and is bonding firm, is applicable to that paper product coheres.Solid gums can be used for bonding various paper and paper product, is suitable for clerical workforce, financial and accountancy personnel, secretarial personnel, teacher, student and related personnel and uses.
The polyvinyl formal solid glue stick has that figuration is good, and rate of drying is fast, bonding strength height, adaptive temperature wide ranges, the characteristics that free formaldehyde content is low.Compare with chemical paste with glue, the maximum characteristics of solid glue stick are use, easy to carry, clean, sanitary, can not produce water clock, diffusion and phenomenon of osmosis, are the office appliances that a kind of ideal substitutes glue.
The allochroic solid rod also is not seen in the report of scientific and technical literature.
Summary of the invention
The technical issues that need to address of the present invention just are to overcome the defective of prior art, and a kind of allochroic solid rod and preparation method thereof is provided, its cohesive strength height, bonding speed is fast, temperature tolerance is good, long preservative period, and color is beautiful, characteristics such as unique style, can clean by water, the shelf time is long, safety and environmental protection, easy to use, applied widely.
For addressing the above problem, the present invention adopts following technical scheme:
The invention provides a kind of allochroic solid rod, described allochroic solid rod is prepared from by following raw materials in weight portion: water 55.0-85.0 part; Polyvinylpyrrolidone 15.0-25.0 part; Benzene emulsion 5.0-10.0 part; ACRYLIC EMULSION 10.0-15.0 part; Dextrin 5.0-10.0 part; Propylene glycol or glycerine 5.0-15.0 part; Stearic acid 5.0-15.0 part; Sodium hydroxide 0.5-3.0 part; Optically variable pigments 1.0-5.0 part; Lime carbonate or kaolin 10.0-15.0 part; Butyl p-hydroxybenzoate 0.2-3.0 part.
The present invention provides a kind of preparation method of described allochroic solid rod simultaneously, in conversion unit, add entry, add polyvinylpyrrolidone, benzene emulsion, ACRYLIC EMULSION, dextrin while stirring, after stirring, begin to stir and be warming up to 85-90 ℃, constant temperature 85-90 ℃ stirring and dissolving is complete, after stirring and dissolving is complete, add propylene glycol or glycerine while stirring, stearic acid stirs, it is complete to add the sodium hydroxide stirring reaction while stirring, adds optically variable pigments, lime carbonate or kaolin while stirring, butyl p-hydroxybenzoate stirs.The static froth breaking in the constant temperature 85-90 ℃ left and right sides carries out can behind the froth breaking fully.
Among the present invention, water is solvent, and dissolve medium is provided; Polyvinylpyrrolidone (PVP) is main binder resin; PVP has good hydrophilicity, can mix with the water of any ratio, and be a water-soluble good especially polymer, micromolecular PVP has good dissemination, prevents that particle from assembling mutually and precipitate, and polymer PVP has good cementability and film-forming properties; Benzene emulsion is the Aided Modification resin, mainly improves the sticking power of main binder resin and strengthens cohesive strength; ACRYLIC EMULSION also is the Aided Modification resin, mainly improves the sticking power of main binder resin and strengthens cohesive strength; Dextrin is the Aided Modification resin, mainly improves the sticking power of main binder resin and strengthens cohesive strength; Propylene glycol or glycerine are wetting Agent for Printing Inks, and the moisture-keeping functions of product is provided, and prolong preservation period; Stearic acid is a stiffening agent, and the curing molding of product is provided; Sodium hydroxide is the stable molding auxiliary agent, and the product stability in the quality guaranteed period behind the curing molding of product is provided; Optically variable pigments is a tinting material, and the color and luster and the extraordinary effect of product is provided; Lime carbonate or kaolin are hardness reinforcer, increase the hardness and the plasticity of product, and reducing the cost increases the opacifying power of product; Butyl p-hydroxybenzoate is a sanitas, and the barrier propterty of the microorganism of product is provided.
Allochroic solid rod of the present invention is that water, polyvinylpyrrolidone are the solid binder of major ingredient, can be used for bonding various paper and paper product, fabric, paperboard, reaches plastic sheet, wood chip etc., cohesive strength height, bonding speed is fast, and temperature tolerance is good, long preservative period, color is beautiful, unique style can be cleaned by water, and the shelf time is long, safety and environmental protection, easy to use, applied widely, be suitable for related personnel's use that needs are pasted associated materials.When particularly pasting, can apply glue at the position that relevant needs are pasted accurately, do the back and become colorless, to the nothing influence attractive in appearance around pasting by coloured in the location.
Embodiment
Embodiment 1
The allochroic solid rod is prepared from by following raw materials in weight portion: 55.0 parts in water; 25.0 parts of polyvinylpyrrolidones; 5.0 parts of benzene emulsions; 15.0 parts of ACRYLIC EMULSION; 5.0 parts in dextrin; 15.0 parts of propylene glycol; 5.0 parts of stearic acid; 3.0 parts in sodium hydroxide; 1.0 parts of optically variable pigments; 15.0 parts of kaolin; 0.2 part of butyl p-hydroxybenzoate.
In conversion unit, add entry, add polyvinylpyrrolidone, benzene emulsion, ACRYLIC EMULSION, dextrin while stirring, after stirring, begin to stir and be warming up to 90 ℃, 90 ℃ of stirring and dissolving of constant temperature are complete, stirring and dissolving fully after, add propylene glycol while stirring, stearic acid stirs, it is complete to add the sodium hydroxide stirring reaction while stirring, adds optically variable pigments, kaolin, butyl p-hydroxybenzoate while stirring and stirs.90 ℃ of static froth breakings in the left and right sides of constant temperature carry out can behind the froth breaking fully.
Embodiment 2
The allochroic solid rod is prepared from by following raw materials in weight portion: 85.0 parts in water; 15.0 parts of polyvinylpyrrolidones; 10.0 parts of benzene emulsions; 10.0 parts of ACRYLIC EMULSION; 10.0 parts in dextrin; 5.0 parts of glycerine; 15.0 parts of stearic acid; 0.5 part in sodium hydroxide; 5.0 parts of optically variable pigments; 10.0 parts in lime carbonate; 3.0 parts of butyl p-hydroxybenzoates.
In conversion unit, add entry, add polyvinylpyrrolidone, benzene emulsion, ACRYLIC EMULSION, dextrin while stirring, after stirring, begin to stir and be warming up to 85 ℃, 85 ℃ of stirring and dissolving of constant temperature are complete, stirring and dissolving fully after, add glycerine while stirring, stearic acid stirs, it is complete to add the sodium hydroxide stirring reaction while stirring, adds optically variable pigments, lime carbonate, butyl p-hydroxybenzoate while stirring and stirs.85 ℃ of static froth breakings in the left and right sides of constant temperature carry out can behind the froth breaking fully.
Embodiment 3
The allochroic solid rod is prepared from by following raw materials in weight portion: 60 parts in water; 20 parts of polyvinylpyrrolidones; 8 parts of benzene emulsions; 12 parts of ACRYLIC EMULSION; 8 parts in dextrin; 13 parts of glycerine; 10 parts of stearic acid; 1 part in sodium hydroxide; 2 parts of optically variable pigments; 12 parts of kaolin; 1 part of butyl p-hydroxybenzoate.
In conversion unit, add entry, add polyvinylpyrrolidone, benzene emulsion, ACRYLIC EMULSION, dextrin while stirring, after stirring, begin to stir and be warming up to 87 ℃, 87 ℃ of stirring and dissolving of constant temperature are complete, stirring and dissolving fully after, add glycerine while stirring, stearic acid stirs, it is complete to add the sodium hydroxide stirring reaction while stirring, adds optically variable pigments, kaolin, butyl p-hydroxybenzoate while stirring and stirs.87 ℃ of static froth breakings in the left and right sides of constant temperature carry out can behind the froth breaking fully.
It should be noted that at last: obviously, the foregoing description only is for example of the present invention clearly is described, and is not the qualification to embodiment.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here need not also can't give exhaustive to all embodiments.And conspicuous variation of being amplified out thus or change still are among protection scope of the present invention.
Claims (2)
1. an allochroic solid rod is characterized in that, described allochroic solid rod is prepared from by following raw materials in weight portion: water 55.0-85.0 part; Polyvinylpyrrolidone 15.0-25.0 part; Benzene emulsion 5.0-10.0 part; ACRYLIC EMULSION 10.0-15.0 part; Dextrin 5.0-10.0 part; Propylene glycol or glycerine 5.0-15.0 part; Stearic acid 5.0-15.0 part; Sodium hydroxide 0.5-3.0 part; Optically variable pigments 1.0-5.0 part; Lime carbonate or kaolin 10.0-15.0 part; Butyl p-hydroxybenzoate 0.2-3.0 part.
2. the preparation method of allochroic solid rod as claimed in claim 1, it is characterized in that: in conversion unit, add entry, add polyvinylpyrrolidone, benzene emulsion, ACRYLIC EMULSION, dextrin while stirring, after stirring, begin to stir and be warming up to 85-90 ℃, constant temperature 85-90 ℃ stirring and dissolving is complete, after stirring and dissolving is complete, add propylene glycol or glycerine while stirring, stearic acid stirs, it is complete to add the sodium hydroxide stirring reaction while stirring, adds optically variable pigments, lime carbonate or kaolin while stirring, butyl p-hydroxybenzoate stirs.The static froth breaking in the constant temperature 85-90 ℃ left and right sides carries out can behind the froth breaking fully.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310176117.0A CN103214980B (en) | 2013-05-13 | 2013-05-13 | Preparation method of discoloring solid rubber stick |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310176117.0A CN103214980B (en) | 2013-05-13 | 2013-05-13 | Preparation method of discoloring solid rubber stick |
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| CN103214980A true CN103214980A (en) | 2013-07-24 |
| CN103214980B CN103214980B (en) | 2015-05-13 |
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| CN201310176117.0A Active CN103214980B (en) | 2013-05-13 | 2013-05-13 | Preparation method of discoloring solid rubber stick |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015137104A1 (en) * | 2014-03-13 | 2015-09-17 | 日本ゼトック株式会社 | Sock slippage inhibitor |
| CN106189920A (en) * | 2015-05-28 | 2016-12-07 | 李承烨 | File security process solid gum |
| CN112210316A (en) * | 2020-09-23 | 2021-01-12 | 漯河市罗弗文具制造有限公司 | Environment-friendly dual-purpose color-changing solid glue stick and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101624505A (en) * | 2008-07-10 | 2010-01-13 | 宁波松鹤文具有限公司 | Pressure-sensitive solid adhesive and preparation method thereof |
| CN102134460A (en) * | 2011-02-25 | 2011-07-27 | 浙江大学宁波理工学院 | Blue solid glue stick with color being changed after application and preparation method thereof |
| CN102321443A (en) * | 2011-09-15 | 2012-01-18 | 宋仕良 | Environmental protection type transparent solid glue and preparation method thereof |
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2013
- 2013-05-13 CN CN201310176117.0A patent/CN103214980B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101624505A (en) * | 2008-07-10 | 2010-01-13 | 宁波松鹤文具有限公司 | Pressure-sensitive solid adhesive and preparation method thereof |
| CN102134460A (en) * | 2011-02-25 | 2011-07-27 | 浙江大学宁波理工学院 | Blue solid glue stick with color being changed after application and preparation method thereof |
| CN102321443A (en) * | 2011-09-15 | 2012-01-18 | 宋仕良 | Environmental protection type transparent solid glue and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015137104A1 (en) * | 2014-03-13 | 2015-09-17 | 日本ゼトック株式会社 | Sock slippage inhibitor |
| JP2015174891A (en) * | 2014-03-13 | 2015-10-05 | 日本ゼトック株式会社 | Sock slippage inhibitor |
| CN105492562A (en) * | 2014-03-13 | 2016-04-13 | 日本泽托克株式会社 | Sock slippage inhibitor |
| CN105492562B (en) * | 2014-03-13 | 2017-07-21 | 日本泽托克株式会社 | Socks slip preventing agent |
| US9803102B2 (en) | 2014-03-13 | 2017-10-31 | Nippon Zettoc Co., Ltd. | Slip preventing agent for socks |
| CN106189920A (en) * | 2015-05-28 | 2016-12-07 | 李承烨 | File security process solid gum |
| CN112210316A (en) * | 2020-09-23 | 2021-01-12 | 漯河市罗弗文具制造有限公司 | Environment-friendly dual-purpose color-changing solid glue stick and preparation method thereof |
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| CN103214980B (en) | 2015-05-13 |
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