CN103214747A - 一种三元乙丙橡胶基电导非线性绝缘材料 - Google Patents
一种三元乙丙橡胶基电导非线性绝缘材料 Download PDFInfo
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- CN103214747A CN103214747A CN2013101757423A CN201310175742A CN103214747A CN 103214747 A CN103214747 A CN 103214747A CN 2013101757423 A CN2013101757423 A CN 2013101757423A CN 201310175742 A CN201310175742 A CN 201310175742A CN 103214747 A CN103214747 A CN 103214747A
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- 239000011810 insulating material Substances 0.000 title claims abstract description 50
- 229920001577 copolymer Polymers 0.000 title abstract 3
- 229920001971 elastomer Polymers 0.000 claims abstract description 40
- 239000005060 rubber Substances 0.000 claims abstract description 40
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 39
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 31
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 31
- 239000006229 carbon black Substances 0.000 claims abstract description 24
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000005864 Sulphur Substances 0.000 claims abstract description 23
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 20
- 239000010439 graphite Substances 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000945 filler Substances 0.000 claims description 52
- 239000011159 matrix material Substances 0.000 claims description 51
- 230000005611 electricity Effects 0.000 claims description 50
- 229920002943 EPDM rubber Polymers 0.000 claims description 43
- 239000002245 particle Substances 0.000 claims description 40
- 229920001897 terpolymer Polymers 0.000 claims description 35
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 34
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical group C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 claims description 22
- -1 dicumyl peroxides Chemical class 0.000 claims description 22
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 19
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 239000002048 multi walled nanotube Substances 0.000 claims description 3
- 230000015556 catabolic process Effects 0.000 abstract description 16
- 239000002131 composite material Substances 0.000 abstract description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 5
- 239000012767 functional filler Substances 0.000 abstract description 4
- 239000003989 dielectric material Substances 0.000 abstract description 3
- 239000011787 zinc oxide Substances 0.000 abstract description 3
- 239000005543 nano-size silicon particle Substances 0.000 abstract 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 abstract 1
- WMVSVUVZSYRWIY-UHFFFAOYSA-N [(4-benzoyloxyiminocyclohexa-2,5-dien-1-ylidene)amino] benzoate Chemical compound C=1C=CC=CC=1C(=O)ON=C(C=C1)C=CC1=NOC(=O)C1=CC=CC=C1 WMVSVUVZSYRWIY-UHFFFAOYSA-N 0.000 abstract 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 1
- 235000019241 carbon black Nutrition 0.000 description 18
- 229920002379 silicone rubber Polymers 0.000 description 8
- 230000005684 electric field Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 238000005987 sulfurization reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 239000007788 liquid Substances 0.000 description 2
- 229920000260 silastic Polymers 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical group C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Abstract
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CN201310175742.3A CN103214747B (zh) | 2013-05-13 | 2013-05-13 | 一种三元乙丙橡胶基电导非线性绝缘材料 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105131437A (zh) * | 2015-08-14 | 2015-12-09 | 烟台顺隆化工科技有限公司 | 一种乙丙橡胶电缆绝缘料 |
CN105255022A (zh) * | 2015-11-04 | 2016-01-20 | 长园电力技术有限公司 | 用于高压直流电缆附件的半导电三元乙丙橡胶材料及制备方法 |
WO2018130190A1 (zh) * | 2017-01-13 | 2018-07-19 | 杭州星庐科技有限公司 | 一种橡胶基电导非线性绝缘材料及其加工方法 |
CN108299741A (zh) * | 2017-01-13 | 2018-07-20 | 杭州星庐科技有限公司 | 一种橡胶基电导非线性绝缘材料及其加工方法 |
CN109880239A (zh) * | 2019-01-30 | 2019-06-14 | 南瑞集团有限公司 | 一种非线性三元乙丙橡胶复合材料及其制备方法 |
CN110915087A (zh) * | 2017-07-13 | 2020-03-24 | 住友电气工业株式会社 | 非欧姆组合物及其制造方法、电缆中间连接单元以及电缆终端连接单元 |
CN113583353A (zh) * | 2021-08-30 | 2021-11-02 | 长缆电工科技股份有限公司 | 一种绝缘橡胶及其制备方法与应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101284925A (zh) * | 2008-05-23 | 2008-10-15 | 山东大学 | 硅橡胶/三元乙丙并用导热橡胶及其制备方法 |
CN102504358A (zh) * | 2011-11-22 | 2012-06-20 | 广东石油化工学院 | 一种高导热橡胶复合材料及其制备方法 |
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2013
- 2013-05-13 CN CN201310175742.3A patent/CN103214747B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101284925A (zh) * | 2008-05-23 | 2008-10-15 | 山东大学 | 硅橡胶/三元乙丙并用导热橡胶及其制备方法 |
CN102504358A (zh) * | 2011-11-22 | 2012-06-20 | 广东石油化工学院 | 一种高导热橡胶复合材料及其制备方法 |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105131437A (zh) * | 2015-08-14 | 2015-12-09 | 烟台顺隆化工科技有限公司 | 一种乙丙橡胶电缆绝缘料 |
CN105255022A (zh) * | 2015-11-04 | 2016-01-20 | 长园电力技术有限公司 | 用于高压直流电缆附件的半导电三元乙丙橡胶材料及制备方法 |
CN105255022B (zh) * | 2015-11-04 | 2018-06-19 | 长园电力技术有限公司 | 用于高压直流电缆附件的半导电三元乙丙橡胶材料及制备方法 |
WO2018130190A1 (zh) * | 2017-01-13 | 2018-07-19 | 杭州星庐科技有限公司 | 一种橡胶基电导非线性绝缘材料及其加工方法 |
CN108299741A (zh) * | 2017-01-13 | 2018-07-20 | 杭州星庐科技有限公司 | 一种橡胶基电导非线性绝缘材料及其加工方法 |
CN108299741B (zh) * | 2017-01-13 | 2021-06-22 | 杭州星庐科技有限公司 | 一种橡胶基电导非线性绝缘材料及其加工方法 |
CN110915087A (zh) * | 2017-07-13 | 2020-03-24 | 住友电气工业株式会社 | 非欧姆组合物及其制造方法、电缆中间连接单元以及电缆终端连接单元 |
CN110915087B (zh) * | 2017-07-13 | 2021-04-16 | 住友电气工业株式会社 | 非欧姆组合物及其制造方法、电缆中间连接单元以及电缆终端连接单元 |
CN109880239A (zh) * | 2019-01-30 | 2019-06-14 | 南瑞集团有限公司 | 一种非线性三元乙丙橡胶复合材料及其制备方法 |
CN113583353A (zh) * | 2021-08-30 | 2021-11-02 | 长缆电工科技股份有限公司 | 一种绝缘橡胶及其制备方法与应用 |
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Owner name: POWER GRID TECHNIQUE RESEARCH CENTER OF CHINA SOUT Effective date: 20150521 |
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CB03 | Change of inventor or designer information |
Inventor after: Li Zhonghua Inventor after: Han Baozhong Inventor after: Chen Yu Inventor after: Li Changming Inventor after: Fu Mingli Inventor after: Hou Shuai Inventor before: Li Zhonghua Inventor before: Han Baozhong Inventor before: Chen Yu Inventor before: Li Changming |
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Free format text: CORRECT: INVENTOR; FROM: LI ZHONGHUA HAN BAOZHONG CHEN YU LI CHANGMING TO: LI ZHONGHUA HAN BAOZHONG CHEN YU LI CHANGMING FU MINGLI HOU SHUAI |
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Effective date of registration: 20150521 Address after: 150080 Harbin, Heilongjiang, Nangang District Road, No. 52 Applicant after: HARBIN University OF SCIENCE AND TECHNOLOGY Applicant after: POWER GRID TECHNOLOGY RESEARCH CENTER. CHINA SOUTHERN POWER GRID Address before: 150080 Harbin, Heilongjiang, Nangang District Road, No. 52 Applicant before: Harbin University of Science and Technology |
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Effective date of registration: 20210830 Address after: 150080 No. 52, Xuefu Road, Nangang District, Heilongjiang, Harbin Patentee after: HARBIN University OF SCIENCE AND TECHNOLOGY Patentee after: China South Power Grid International Co.,Ltd. Address before: 150080 No. 52, Xuefu Road, Nangang District, Heilongjiang, Harbin Patentee before: HARBIN University OF SCIENCE AND TECHNOLOGY Patentee before: POWER GRID TECHNOLOGY RESEARCH CENTER. CHINA SOUTHERN POWER GRID |
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