CN103208633A - Horizon battery and manufacturing method thereof - Google Patents
Horizon battery and manufacturing method thereof Download PDFInfo
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- CN103208633A CN103208633A CN2013100946165A CN201310094616A CN103208633A CN 103208633 A CN103208633 A CN 103208633A CN 2013100946165 A CN2013100946165 A CN 2013100946165A CN 201310094616 A CN201310094616 A CN 201310094616A CN 103208633 A CN103208633 A CN 103208633A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
The invention discloses a horizon battery and a manufacturing method thereof. Grid of existing horizon batteries is woven by glass fiber and lead composite. Lead layer on the surface of the grid is corroded fast, and conductivity is lowered when the lead layer is corroded. The horizon battery comprises a battery shell and an upper cover. A plurality of battery plate groups and partitions for blocking electrolyte circulation among the battery plate groups are disposed in the battery shell. Leading-out terminals connected to the battery plate groups are disposed at two ends of the battery shell. The battery plate groups comprise positive plates and negative plates which are alternately stacked, porous partition plates are disposed between the positive plates and the negative plates, and each positive plate and each negative plate comprise a plastic grid frame and a grid framework. The grid framework is made of lead alloy, and high in strength, corrosion resistance and conductivity. By the grid frame, usage of lead alloy is reduced, mass of the grid is lowered, and mass ratio energy of the horizon battery is improved.
Description
[technical field]
The present invention relates to a kind of storage battery, especially a kind of horizon battery belongs to the battery product field.
[background technology]
The pole plate of tradition lead acid accumulator is perpendicular to ground-mounted, also is perpendicular to ground during use and installs and uses, and the plate ear of positive and negative pole plate all places the top of storage battery, and conductive component bus-bar, end pole all are to draw from last connection.The electrolyte stratification phenomenon in use appears in storage battery easily, storage battery in discharge process because the sulfuric acid concentration height of bottom, the capacity of emitting is more relatively, storage battery top then sulfuric acid concentration is low, the capacity of emitting is few, and the trend that active material has progressively reaction from the top down to transform when charging, top then appears preferentially fill electricity with, if the battery discharging degree of depth is bigger, pole plate conductivity weakens, and when storage battery top had been in full charge even overcharge condition, the bottom did not also have full charge, along with the accumulation that recycles number of times, this unbalanced meeting forms vicious circle, causes the quick decay of battery capacity, the life-span premature termination.
Therefore developed a kind of level and lead acid battery, the grid of pole plate adopts glass fibre, lead composite material braiding to form, the pole plate dipolar configuration that is as the criterion, and namely half the coating positive electrode active material at grid is positive plate, second half coating negative electrode active material is negative plate.Be made into ambipolar green plate through operations such as multiple film, pickling, dry tack free, curing.Assembling: separate with barrier film between bipolar plates, fix with pressure frame up and down.Bipolar plates and dividing plate are according to certain position, level is staggered stacks, setting pressure frame fixation then, the formation battery module is packed in the cell jar, after cast welding, seal, then through after irritate acid, change into, in the storage battery space, pour into paraffin at last, load onto safety valve, making becomes horizon battery.
But, because the electrode plate grid of this horizon battery adopts glass fibre, lead composite material braiding to form, though saved lead material, but this grid is in use particularly recycling process deeply or is depositing in the process, the lead layer on grid surface can very fast corrosion, corrosion back conductive capability weakens greatly, and battery capacity will reduce significantly, finally causes battery malfunction.
Simultaneously, the existing level battery, isolate irritating pouring into paraffin after acidifying becomes to finish and carry out isolating seal between the monomer, because before irritating wax, internal storage battery has residual acid solution, unfavorable to sealing, be difficult to reach the effect that excellent sealing is isolated, as long as seal isolation is bad, string lattice phenomenon occur, the storage battery self discharge is big, causes the bad quality problems of storage battery consistency easily.
[summary of the invention]
The invention provides a kind of horizon battery and manufacture method thereof, can material saving, guarantee seal isolation good between useful life and battery electrode group simultaneously.
For solving the problems of the technologies described above, the present invention adopts following technical scheme: a kind of horizon battery, comprise battery container and loam cake, the separator that is provided with some battery electrode groups in the described battery container and intercepts electrolyte circulation between battery electrode group, the two ends of described battery container are provided with the leading-out terminal that connects battery electrode group, described battery electrode group comprises alternately laminated positive plate and negative plate, be provided with porous barrier between described positive plate and the negative plate, described positive plate and negative plate comprise plastic grid frame and grid skeleton.
Further, described separator comprises the connection plastic frame, and described connection plastic frame is located between stacked negative plate, the positive plate, and described connection plastic frame is connected with the plastic grid frame of negative plate, positive plate, and described porous barrier is located at and is connected in the plastic frame.
Further, described connection plastic frame comprises a plurality of end to end square frames, described square frame is corresponding with the plastic grid frame, by being connected of described connection plastic frame and plastic grid frame some battery electrode groups being connected and intercepting electrolyte between battery electrode group.
Further, adopt the ultrasonic bonding mode to connect described plastic grid frame and the described plastic frame that is connected.
Further, described grid skeleton is made of lead alloy, is coated with positive electrode active material on the grid skeleton of positive plate, is coated with negative electrode active material on the grid skeleton of negative plate.
Further, positive plate in the described battery electrode group links to each other with negative plate among the adjacent cell utmost point group and forms the double polarity plate of integrative-structure, the positive plate of described double polarity plate is led mutually with negative plate, and logical real described double polarity plate is realized the polyphone between the battery electrode group.
Further, seal by fluid sealant between described battery container and the battery electrode group.
Further, described fluid sealant is epoxy resin sealant.
Further, cover on described and be provided with valve opening and valve gap.
A kind of manufacture method of horizon battery may further comprise the steps:
A, employing lead alloy are made the grid skeleton of positive plate, negative plate and double polarity plate, adopt Shooting Technique to make the plastic grid frame at the grid skeleton of positive plate, negative plate and double polarity plate;
B, on the grid skeleton of positive plate the full-filling positive electrode active material, full-filling negative electrode active material on the grid skeleton of negative plate, full-filling positive electrode active material on the grid skeleton of double polarity plate one end, full-filling negative electrode active material on the grid skeleton of the double polarity plate other end, and then carry out compacting, pouring acid, dry tack free, curing, oven dry and removing surface;
C, finish the lamination of battery electrode group with positive plate, porous barrier, negative plate and double polarity plate, and be provided with the connection plastic frame between the plastic grid frame of levels, and will connect plastic frame and the plastic grid frame is connected by supersonic welding;
D, battery electrode group is packed in the battery container, the bottom of battery electrode group is by connecting the base plate that plastic frame connects battery container, and with battery electrode group and battery container by ultrasonic bonding;
E, at the two ends of battery electrode group welding leading-out terminal;
Filling with sealant in f, the gap between battery container and battery electrode group;
G, weld loam cake at battery container, and inject electrolyte by valve opening.
Beneficial effect of the present invention:
The positive plate of horizon battery and negative plate comprise grid skeleton and plastic grid frame among the present invention, and the grid skeleton adopts lead alloy, compare and adopt glass fibre, the lead composite material braiding forms has higher intensity, decay resistance and conductive capability.
Compare original grid skeleton and grid frame and adopt material of the same race, the plastic grid frame can reduce the consumption of lead alloy, and reduces grid quality, the specific energy of the battery of improving the standard.
Be provided with the connection plastic frame between simultaneously stacked positive plate and the negative plate, connect plastic frame and be melted in by ultrasonic bonding with the plastic grid frame, can connect continuous battery electrode group, and with adjacent battery electrode group good isolation sealing.
These characteristics of the present invention and advantage will be below embodiment, accompanying drawing in detailed exposure.
[description of drawings]
The present invention is described further below in conjunction with accompanying drawing:
Fig. 1 is structural representation of the present invention;
Fig. 2 a is the front view of positive plate among the present invention;
Fig. 2 b is the vertical view of positive plate among the present invention;
Fig. 3 a is the vertical view of negative plate among the present invention;
Fig. 3 b is the front view of negative plate among the present invention;
Fig. 4 a is the front view of double polarity plate among the present invention;
Fig. 4 b is the vertical view of double polarity plate among the present invention.
[embodiment]
The invention provides a kind of horizon battery, comprise battery container and loam cake, the separator that is provided with some battery electrode groups in the described battery container and intercepts electrolyte circulation between battery electrode group, the two ends of described battery container are provided with the leading-out terminal that connects battery electrode group, described battery electrode group comprises alternately laminated positive plate and negative plate, be provided with porous barrier between described positive plate and the negative plate, described positive plate and negative plate comprise plastic grid frame and grid skeleton.
Be explained and illustrated below in conjunction with the accompanying drawing of the embodiment of the invention technical scheme to the embodiment of the invention, but following embodiment is the preferred embodiments of the present invention only, is not whole.Based on the embodiment in the execution mode, those skilled in the art belong to protection scope of the present invention at following other embodiment that obtains of the prerequisite of not making creative work.
With reference to figure 1, Fig. 2 a, Fig. 2 b, Fig. 3 a and Fig. 3 b, shown in horizon battery, a plurality of battery electrode groups are arranged in battery container 1, the two ends of battery container 1 are equipped with leading-out terminal 11, leading-out terminal 11 is connected with battery electrode group, battery electrode group is provided with porous barrier 8 by positive plate 3 and negative plate 4 alternately laminated forming between positive plate 3 and negative plate 4, the positive plate 5 of the negative plate 4 of battery electrode group left end and right-hand member is connected with leading-out terminal 11 by bus-bar 12 as described in Figure 1.
The positive plate 3 that adopts among the present invention comprises grid skeleton 31 and plastic grid frame 32, and negative plate 4 also comprises grid skeleton 41 and plastic grid frame 42; Grid skeleton 31 at positive plate applies positive electrode active material, applies negative electrode active material at the grid skeleton 41 of negative plate.Wherein the grid skeleton of positive plate 3 and negative plate 4 all adopts lead alloy, compares and adopts glass fibre, higher intensity, decay resistance and the conductive capability of lead composite material braiding tool, to satisfy horizon battery high power, long-life requirement.Adopt the plastic grid frame simultaneously, can reduce the lead alloy consumption, and reduce the grid quality, the specific energy of the battery of improving the standard, and more accurate in grid skeleton coating active matter mass-energy; The grid skeleton also can adopt other metal or conductive non-metals
Preferably, the plastic grid frame adopts injection moulding to process, and can improve each positive plate and negative plate consistency.
Conventional levels battery in the past, in groove, put into and carry out paraffin behind the battery electrode group and seal to isolate electrolyte between adjacent cell machine utmost point group, but effect is relatively poor, as further improvement, battery electrode group described in the present invention also comprises connection plastic frame 6, described connection plastic frame 6 is located between stacked negative plate 4, the positive plate 3, and described porous barrier 8 is located at and connects in the plastic frame 6, and connects adjacent battery electrode group by connecting plastic frame.
As a kind of preferred, described connection plastic frame 6 comprises a plurality of continuous square frames, and described square frame is corresponding with the plastic grid frame of positive plate 3 and negative plate 4.Adopt ultrasonic bonding mode welding plastic grid frame and be connected plastic frame, some battery electrode groups are connected into integral body, adopt ultrasonic bonding mode battery electrode group to be welded in the battery container simultaneously, the plastic grid frame is melted in the good isolation that can realize electrolyte between the cell utmost point group with connecting plastic frame; Connect plastic frame and also can be a plurality of independent square frames, and then with independent square frame by ultrasonic bonding.
With reference to figure 1, Fig. 4 a and Fig. 4 b, the series connection of battery need converge to the pole plate of all same polarities of an element cell utmost point group on the plate ear by grid in the conventional batteries in the past, converge by bus-bar again, the pole plate that adjacent monomer battery electrode group Semi-polarity is opposite converges on the plate ear by grid, converge by bus-bar again, by stride bridging connect two bus-bars realize the series connection, in the present embodiment, be connected with negative plate 4 on the adjacent cell utmost point group double polarity plate 5 of structure of the positive plate 3 of being separated by in the described battery electrode group, positive plate in the double polarity plate 5 and negative plate mutual conduction, by the polyphone between the double polarity plate 5 realization adjacent cell utmost point groups, the battery electrode group of a side is formed by stacking by double polarity plate 5 and negative plate 4 as shown in Figure 1, the battery electrode group of opposite side is by positive plate 3 and double polarity plate 5 stacks, and middle battery electrode group all adopts double polarity plate 5; Use double polarity plate to save to conflux and be connected, reduced conductive resistance, reduced the lead loss consumption, and improved specific energy.
Be the sealing property of the battery of improving the standard, the gap location between battery container 1 and battery electrode group is provided with fluid sealant 7.Fluid sealant 7 can adopt epoxy resin sealant, also can seal by paraffin or rubber-type fluid sealant.
Loam cake 2 is provided with for the valve opening 21 that injects electrolyte to battery container 1, and valve opening 21 is provided with valve gap 22, is provided with cellular-plastic panels 9 between loam cake 2 and the battery electrode group.
In addition, be provided with a plurality of stoppers 23 in loam cake 2, stopper 23 intercepts the electrolyte that links to each other between the battery electrode group by stopper 23 in the upper end between adjacent cell utmost point group.
With reference to figure 1, Fig. 2 b, Fig. 3 a, Fig. 4 b during the manufacturing of the horizon battery of this invention, comprises following steps:
The first step, adopt lead alloy, other metal or conductive non-metals as the grid skeleton of positive plate 3, negative plate 4 and double polarity plate 5, adopt Shooting Technique to make the plastic grid frame at the grid skeleton of positive plate 3, negative plate 4 and double polarity plate 5;
Second step, full-filling anode diachylon on the grid skeleton 31 of positive plate, full-filling cathode lead plaster on the grid skeleton 41 of negative plate, double polarity plate is divided into positive terminal 511 and negative pole end 512, full-filling anode diachylon on the grid skeleton of positive terminal, full-filling cathode lead plaster on the grid skeleton of negative pole end, and then carry out compacting, pouring acid, dry tack free, curing, oven dry and removing surface;
The 3rd step with reference to figure 1, lay to connect plastic frame 6 at bottom, connected in the plastic frame porous barrier 8 is set, and was connecting the end to end double polarity plates 5 of the many rows of plastic frame stack, and the left end of double polarity plate 5 is for just, and right-hand member is for bearing; Connect plastic frame and porous barrier in double polarity plate 5 stacks then, connecting plastic frame stack positive plate 3, negative plate 4 and double polarity plate 5 again, positive plate 3 is at right-hand member, and negative plate 4 is at left end, and double polarity plate is between negative plate and positive plate; Repeat to be superimposed as the battery electrode group that regulation requires by the way, and will connect plastic frame and plastic grid frame weldering company by supersonic welding;
In the 4th step, battery electrode group is packed in the battery container 1, and by ultrasonic bonding both will be welded;
In the 5th step, the lug of negative plate 4 links to each other by the welding bus-bar, and the plate ear of positive plate 3 also links to each other by the welding bus-bar, respectively solder terminal 11 on two bus-bars 12;
The 6th step, filling epoxy resin fluid sealant 7 in the gap between battery container 1 and battery electrode group;
The 7th step, at battery container 1 welding loam cake 2, and by valve opening 21 injection electrolyte.
By above-described embodiment, purpose of the present invention is by in full force and effect having reached.The personage who is familiar with this skill should be understood that the content that the present invention includes but be not limited to describe in accompanying drawing and the top embodiment.Any modification that does not depart from function of the present invention and structural principle all will be included in the scope of claims.
Claims (10)
1. horizon battery, comprise battery container and loam cake, the separator that is provided with some battery electrode groups in the described battery container and intercepts electrolyte circulation between battery electrode group, the two ends of described battery container are provided with the leading-out terminal that connects battery electrode group, described battery electrode group comprises alternately laminated positive plate and negative plate, be provided with porous barrier between described positive plate and the negative plate, it is characterized in that: described positive plate and negative plate comprise plastic grid frame and grid skeleton.
2. a kind of horizon battery according to claim 1, it is characterized in that: described separator comprises the connection plastic frame, described connection plastic frame is located between stacked negative plate, the positive plate, described connection plastic frame is connected with the plastic grid frame of negative plate, positive plate, and described porous barrier is located at and is connected in the plastic frame.
3. a kind of horizon battery according to claim 2, it is characterized in that: described connection plastic frame comprises a plurality of end to end square frames, described square frame is corresponding with the plastic grid frame, by being connected of described connection plastic frame and plastic grid frame some battery electrode groups being connected and intercepting electrolyte between battery electrode group.
4. according to claim 2 or 3 described a kind of horizon batteries, it is characterized in that: adopt the ultrasonic bonding mode to connect described plastic grid frame and the described plastic frame that is connected.
5. a kind of horizon battery according to claim 1, it is characterized in that: described grid skeleton is made of lead alloy, is coated with positive electrode active material on the grid skeleton of positive plate, is coated with negative electrode active material on the grid skeleton of negative plate.
6. a kind of horizon battery according to claim 5, it is characterized in that: the positive plate in the described battery electrode group links to each other with negative plate among the adjacent cell utmost point group and forms the double polarity plate of integrative-structure, the positive plate of described double polarity plate is led mutually with negative plate, and logical real described double polarity plate is realized the polyphone between the battery electrode group.
7. a kind of horizon battery according to claim 1 is characterized in that: seal by fluid sealant between described battery container and the battery electrode group.
8. a kind of horizon battery according to claim 7, it is characterized in that: described fluid sealant is epoxy resin sealant.
9. a kind of horizon battery according to claim 1 is characterized in that: cover on described and be provided with valve opening and valve gap.
10. the manufacture method of a horizon battery is characterized in that may further comprise the steps:
A, employing lead alloy are made the grid skeleton of positive plate, negative plate and double polarity plate, adopt Shooting Technique to make the plastic grid frame at the grid skeleton of positive plate, negative plate and double polarity plate;
B, on the grid skeleton of positive plate the full-filling positive electrode active material, full-filling negative electrode active material on the grid skeleton of negative plate, full-filling positive electrode active material on the grid skeleton of double polarity plate one end, full-filling negative electrode active material on the grid skeleton of the double polarity plate other end, and then carry out compacting, pouring acid, dry tack free, curing, oven dry and removing surface;
C, finish the lamination of battery electrode group with positive plate, porous barrier, negative plate and double polarity plate, and be provided with the connection plastic frame between the plastic grid frame of levels, and will connect plastic frame and the plastic grid frame is connected by supersonic welding;
D, battery electrode group is packed in the battery container, the bottom of battery electrode group is by connecting the base plate that plastic frame connects battery container, and with battery electrode group and battery container by ultrasonic bonding;
E, at the two ends of battery electrode group welding leading-out terminal;
Filling with sealant in f, the gap between battery container and battery electrode group;
G, weld loam cake at battery container, and inject electrolyte by valve opening.
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| CN201310094616.5A CN103208633B (en) | 2013-03-22 | 2013-03-22 | Horizon battery and manufacturing method thereof |
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| CN201310094616.5A CN103208633B (en) | 2013-03-22 | 2013-03-22 | Horizon battery and manufacturing method thereof |
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| CN103208633A true CN103208633A (en) | 2013-07-17 |
| CN103208633B CN103208633B (en) | 2015-06-17 |
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Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103633280A (en) * | 2013-11-21 | 2014-03-12 | 河南超威电源有限公司 | Four-pole-ear pole plate, four-pole-ear pole group and four-pole-ear storage battery |
| CN104466267A (en) * | 2014-12-31 | 2015-03-25 | 淄博市淄川区华淄蓄电池厂 | Dual-electrode-rod horizontal valve regulated sealed lead acid storage battery |
| CN104577218A (en) * | 2014-12-03 | 2015-04-29 | 超威电源有限公司 | Unipolar horizontal battery and manufacturing method thereof |
| CN104651879A (en) * | 2015-02-15 | 2015-05-27 | 长飞光纤光缆股份有限公司 | Self-circulating brown gas electrolysis module |
| CN104674295A (en) * | 2015-02-15 | 2015-06-03 | 长飞光纤光缆股份有限公司 | Resin casting type Brown gas electrolysis module |
| CN105244459A (en) * | 2015-04-21 | 2016-01-13 | 超威电源有限公司 | Lead-acid storage battery and electric vehicle |
| CN105514305A (en) * | 2015-12-15 | 2016-04-20 | 超威电源有限公司 | Horizontal battery box |
| CN105552315A (en) * | 2015-12-15 | 2016-05-04 | 超威电源有限公司 | Polar group press plate of horizontal battery and horizontal battery applying polar group press plate |
| CN105576250A (en) * | 2015-12-15 | 2016-05-11 | 超威电源有限公司 | Battery grid |
| CN105576249A (en) * | 2015-12-15 | 2016-05-11 | 超威电源有限公司 | Battery plate |
| CN105742644A (en) * | 2016-03-08 | 2016-07-06 | 超威电源有限公司 | Storage battery grid with brick wall structure, and storage battery |
| CN106486666A (en) * | 2015-09-01 | 2017-03-08 | 甄占波 | A kind of new lead-acid battery manufacture method |
| CN107026287A (en) * | 2016-06-24 | 2017-08-08 | 巨江电源科技有限公司 | A kind of preparation method of plumbic acid horizon battery |
| CN107305966A (en) * | 2016-04-20 | 2017-10-31 | 深圳市佰特瑞储能系统有限公司 | A kind of modularization multi-cell battery |
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| CN103633280A (en) * | 2013-11-21 | 2014-03-12 | 河南超威电源有限公司 | Four-pole-ear pole plate, four-pole-ear pole group and four-pole-ear storage battery |
| CN104577218A (en) * | 2014-12-03 | 2015-04-29 | 超威电源有限公司 | Unipolar horizontal battery and manufacturing method thereof |
| CN104577218B (en) * | 2014-12-03 | 2017-06-06 | 超威电源有限公司 | Unipolarity horizon battery and its manufacture method |
| CN104466267A (en) * | 2014-12-31 | 2015-03-25 | 淄博市淄川区华淄蓄电池厂 | Dual-electrode-rod horizontal valve regulated sealed lead acid storage battery |
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| CN104651879B (en) * | 2015-02-15 | 2017-11-17 | 长飞光纤光缆股份有限公司 | Self-loopa Brown Gas electrolytic module |
| CN104674295A (en) * | 2015-02-15 | 2015-06-03 | 长飞光纤光缆股份有限公司 | Resin casting type Brown gas electrolysis module |
| CN105244459A (en) * | 2015-04-21 | 2016-01-13 | 超威电源有限公司 | Lead-acid storage battery and electric vehicle |
| CN106098983B (en) * | 2015-04-21 | 2019-05-07 | 超威电源有限公司 | A kind of lead-acid accumulator and electric vehicle |
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| CN106098983A (en) * | 2015-04-21 | 2016-11-09 | 超威电源有限公司 | A kind of lead-acid accumulator and electric motor car |
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