CN103205185B - Deposed polystyrene polyester dacron prepares the nano environmental protection paint of antagonism adsorption antibacterial function - Google Patents
Deposed polystyrene polyester dacron prepares the nano environmental protection paint of antagonism adsorption antibacterial function Download PDFInfo
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Abstract
The nano environmental protection paint that deposed polystyrene polyester dacron of the present invention prepares antagonism adsorption antibacterial function belongs to the allocation manufacture technology field that paint is produced in the preparation of practical chemical product, deposed polystyrene waste quality is light, volume is degraded greatly, not easily, be embedded in underground, not easily aging rotten and biological degradation, itself is with various toxic chemical substance, easy polluted underground water source, spoiled soil farmland, cause serious white ambient to pollute, polyester plastics, terylene waste material have various inorganic impurity pollutent equally.These fertilizer are processed as film forming matter and add pigment by the present invention exactly, various auxiliary agent, medical stone and tourmalinite nano powder, and Ag-carried nanometer titanium dioxide (AT) antiseptic-germicide, dispersion agent obtains the environmental protection paint of antagonism adsorption antibacterial function through operations such as grindings.
Description
Technical field:
Deposed polystyrene polyester dacron of the present invention prepares the nano environmental protection paint of antagonism adsorption antibacterial function, is to belong to the formula preparing technical field that practical chemical industry miscellaneous goods produces paint.
Polystyrene plastic (PS) or polystyrene foamed plastics (PSF) are one of most widely used plastics in the world, and it is thermoplastics, the little (0.02 ~ 0.04g/cm of density
3), quality is light, shared by waste, volume is large, not easily degrade, the deposed polystyrene being embedded in underground is not easily aging to rot, also be not easily degraded by microorganisms, simultaneously useless return polystyrene foamed plastics itself with various toxic chemical substances again can polluted underground water source, spoiled soil, farmland, serious white ambient is caused to pollute, especially now people are in order to adapt to the allegro needs of society, various fast-food lunch-box arises at the historic moment, be the packing box of raw material with polystyrene (PS) foam sheet, cutlery box, bring a lot of convenience, but plastic packing box after the meal, mess-tin volume is very large, not easily degrade again, very large pollution is caused to environment, because the PS goods transparency is good, corrosion-resistant again, rigidity is strong, various instrument is made so be widely used in, the shell of instrument and various wrapping material, office equipment component, more than consumption, waste is big, really be a worry, in order to effectively solve this contradiction, turn waste into wealth, economize on resources, recycling, these the most effective science invention are clou of the present invention.On the other hand, the wrapping material manufactured with thermoplastic polyester PFT are as this part waste material of polyester bottles, polyester film, rope and fabric, often with oil stain, mix its change plastics or contain the pollutents such as other inorganic impurities, have to pass through purifying, be separated removing pollutent and additional thing, completely can recycling, terylene waste material can prepare the functional paint of production equally, with polystyrene foamed plastics, antagonism absorption poisonous and harmful heavy metallic and gas are produced in polyester dacron preparation and the functional environment-friendly paint with germicidal action is object of the present invention.
Summary of the invention:
A kind of polystyrene polyester dacron is the object of the present invention is to provide to prepare the environmental protection paint of antagonism adsorption antibacterial function.
Technical solution of the present invention is:
Polystyrene polyester dacron prepares an environmental protection paint for antagonism adsorption antibacterial function, it is characterized in that:
1, the acrylic modified alkyd functional polyurethane colored paint of deposed polystyrene preparation energy release of trace elements negative ion antibiotic, by following quality of material part proportioning composition %
Formula point two steps
A, the first step prepare acrylic acid modified alkyd resin formula
(1) Synolac 64.0;
(2) deposed polystyrene PS 7.0;
(3) medical stone nano powder 5.0;
(4) tourmalinite nano powder 6.0;
(5) vinylformic acid 15.0;
(6) initiator B PO 3.0;
B, second step prepare acrylic modified alkyd urethane colored paint formulation
(1) acrylic acid modified alkyd resin 64.0;
(2) pigment 20.0;
(3) dispersion agent 2.2;
(4) flow agent 0.4;
(5) defoamer 0.4;
(6) dimethylbenzene and ester class mixed solvent 13.0.
2, waste polystyrene foam plastic prepares the functional overprint varnish of release of trace elements negative ion, by following quality of material part proportioning composition %
A, formula:
(1) waste polystyrene foam plastic 15.0;
(2) medical stone nano powder 6.0;
(3) tourmalinite nano powder 7.0;
(4) Ag-carried nanometer titanium dioxide " AT " 3.0;
(5) rosin modified phenolic resin 8.0;
(6) dioctyl phthalate (DOP) 10.0;
(7) aminoresin 2.0;
(8) Synolac 3.0;
(9) toluene 46.0;
3, deposed polystyrene prepares the colored paint of antagonism absorption poisonous and harmful heavy metallic and gas, by following proportion by weight composition %
A, formula:
(1) waste polystyrene foam plastic PSF 13.0;
(2) medical stone nano powder 7.0;
(3) tourmalinite nano powder 6.0;
(4) chloroform or benzene 20.0;
4, Waste Polyester produces the modified alkyd resin paint of antagonism Adsorption of Heavy Metals anion releasing, by following quality of material part proportioning composition %
A, formula:
5, terylene waste material produces the epoxy resin-based paint that the anti-electric wave of release of trace elements negative ion pollutes, by following quality of material part proportioning composition %
A, formula:
(10) dimethylbenzene 30.0;
(11) dispersant polycarboxylate 1.0;
Lightweight for polystyrene plastic, water-fast, fast light, the features such as resistance to chemical attack, with the waste polystyrene foam plastic reclaimed through processing, molten modification processed, the operations such as emulsification can be made into inner-outer wall emulsion paint coating, proved by test and Preliminary Applications, it is low that it has cost, scrubbing resistance, the feature of good decorating effect, therefore adopt waste polystyrene foam plastic (PSF) to prepare and produce various functional paint, not only feasible in production technology, and also have good economic and social benefit, priorly solve a large amount of useless environmental pollution of returning plastics, turn waste into wealth, economize on resources, utilization of waste material, promote the well-being of mankind.
As: emulsion paint coating is produced in waste polystyrene foam plastic (PSF) preparation, be that film forming matter adds pigment exactly with waste polystyrene foam plastic, multiple auxiliary agent and be rich in the medical stone nano powder of abundant trace element, poisonous and hazardous heavy metal in object release of trace elements, antagonism air, water molecules in purifying air, and the spontaneous natural negative ion producer constantly producing negative ion---tourmalinite nano powder and dispersion agent Ag-carried nanometer titanium dioxide (AT) antiseptic-germicide prepare functional environment-friendly paint through operations such as grindings with energy.The far-infrared radiation substance A l contained in the composition of medical stone, tourmalinite
2o
3, TiO
2, SiO
2, Fe
2o
3and conventional maximum metal oxide such as chromic oxide, magnesium oxide, zirconium white and carbide has far-infrared radiation material as zirconium carbide etc. is this in common far infrared materials, the health-care effect that far infrared rays is marvellous was 20th century by seldom falling ill the headache that is namely under the weather burning the people worked in ceramic workshop of it is found that, to be put on head with the mud of potting porcelain sick all right, to find afterwards to have launched a kind of hertzian wave in pottery---Here it is the far infrared rays of 8 ~ 15 μm.Experiment proves, this far-infrared engergy promotes blood circulation of human body just, enhances metabolism and enhances immune function of human body, makes the person healthy.In recent years, medical field also starts to use far-infrared technique Diagnosis and Treat disease, this material nano-powder with function far infrared radiation function is infiltrated in functional paint, it can adsorb again the far infrared rays of sunlight etc. efficiently, these far infrared rayss are distributed in space, supply absorption of human body and convert heat energy to, but also can any temperature more than zero absolute temperature, send the far infrared rays that wavelength and power and its temperature adapt, and there is insulation effect, absorption of human body is to these far infrared rayss, can stimulate circulation, improve the microcirculation of human body, this far-infrared radiation material, under the effect of body temperature, the far infrared rays that wavelength is 8-14 μm can be radiated expeditiously again, this far infrared rays and visible ray are different again, it has ferocious perviousness, subcutis 3-5mm can be infiltrated, subcutis automatic heating is generated heat, give biomass cells and move vigor, and improve plasma metabolism ability, strengthen the reactivity of calcium ion in cell, thus enhance the function of human body cell, improve sterilization and immunological competence.Scientific research proves, after medical stone and tourmalinite nanometered disposal, there is very large specific surface area and be added in functional paint that contact with the water molecules on paint surface can the very fast stripping Cu useful to human body, Co, Zn, Mn, Se, Sr, Ni, Ge, Mo, Cr, V, Cu, Fe, a few Ten microelements such as W is released in aerial for absorption of human body, supplementing of favourable human elementary, regulate, antagonism and people's in-vivo element balance, promotion health, the adsorptive power of medical stone is extremely strong simultaneously, absorption can paint harmful heavy metal Ca in surface water molecule, Hg, Pb, the odorous gas such as metal ion and hydrogen sulfide such as As, the microorganisms such as intestinal bacteria can also be adsorbed simultaneously, virus and other organic matters, get rid of animal systematic toxicity material, absorb the medical stone nano powder entered in human body, also there is strengthening the spleen and stomach, protect the liver dirty, antifatigue, regulate metabolism, strengthen the biological effect such as blood circulation and immunity.
Tourmalinite nano powder is as a kind of natural anion generator, and tourmalinite has two important features, i.e. pyroelectricity and piezoelectricity, and it produces thermoelectric effect and piezoelectric effect under certain condition.In functional paint, infiltrate tourmalinite nano powder under the fluctuation of certain external energy, as temperature, sunlight, pressure, fluctuation, or even under very small effect, can cause between tourmalinite nano powder crystal and produce up to 1.0 × 10
6eV, electrostatic potential is poor, thus formation electric field, high voltage electric makes the ionization of air in electric field by the electronics hit, by the permanent positive and negative polarity that tourmalinite nanometer powder two ends have, just can produce the ionisation effect that sparks after water molecules in the ortho-water surperficial with paint, dissociated air or the contact with moisture of human skin, be H by water molecules electrolysis
+and OH
-with other water molecules, hydroxyl group anion (H can be generated continuously
3o
2 -).A people can not take food for 7 days, within 5 days, do not intake, but breaking off air 5min will be dead, visible air is how important, but the quality in air is more important, some families why are had to move into the family of new decoration, do not have the raw cancer of 2-3 couple priority and left this world, this is because Air quality contains heavy metal element lead, mercury, cadmium, arsenic exceeds standard, negative ion is little again, negative ion in air is important as the VITAMIN in human body food, be called as " VITAMIN " and " long-lived element " in air, so notice that in functional paint preparation is produced interpolation can discharge various trace elements and regulate the tourmalinite nano powder of medical stone nano powder and the spontaneous continuous generation negative ion supplementing antagonism absorption poisonous and harmful heavy metallic very necessary.
Silver can kill bacteriophage, the microorganisms such as fungi, and it is harmless to human normal cell, general a kind of microbiotic only can kill 6 kinds of pathogenic organisms bacterium, and silver can kill 650 kinds, and effectively can control obstinate antibacterial bacterial strain, the silver of minute quantity just can eliminate a large amount of genic organisms, under lab, so far still do not find that any biology can not be killed by silver in 6min, in the room of human lives's activity, there are various bacteriums invisible in a large number, fungi, the various pathogenic microorganisms such as virus, they are in certain temperature, humidity and sufficient nutrient, just geometricprogression can be become to breed rapidly, fatal disease is brought to the mankind, great harm is caused to society, paint decoration room people for this reason, during furniture, language function environmental protection paint extremely needs, so " Ag-carried nanometer titanium dioxide (AT) antiseptic-germicide that the present invention produces with Zhou Jin non-ferrous metal company limited, detect intestinal bacteria through authority office, the germ killing rate of streptococcus aureus these two kinds serious threat human healths in life is up to 99.99%.
Below in conjunction with examples of implementation, the present invention is further described:
Embodiment:
Embodiment 1: a kind of polystyrene polyester dacron prepares the environmental protection paint of antagonism adsorption antibacterial function, it is characterized in that:
(1) the acrylic modified alkyd functional polyurethane colored paint of deposed polystyrene preparation energy release of trace elements negative ion antibiotic, by following quality of material part proportioning composition %
Formula point two steps
A, the first step prepare acrylic acid modified alkyd resin formula
(1) Synolac 64.0;
(2) deposed polystyrene PS 7.0;
(3) medical stone nano powder 5.0;
(4) tourmalinite nano powder 6.0;
(5) vinylformic acid 15.0;
(6) initiator B PO 3.0;
B, second step prepare acrylic modified alkyd urethane colored paint formulation
(1) acrylic acid modified alkyd resin 64.0;
(2) pigment 20.0;
(3) dispersion agent 2.2;
(4) flow agent 0.4;
(5) defoamer 0.4;
(6) dimethylbenzene and ester class mixed solvent 13.0.
C, preparation principle and technique
(1) deposed polystyrene crosslinking technology principle, deposed polystyrene is under the effect adding initiator, generate free radical and with vinylbenzene and Acrylic Acid Monomer, poly-graft reaction can occur, unsaturated link(age) simultaneously in deposed polystyrene molecule is under the effect of initiator (BPO), can with vinylbenzene and Acrylic Acid Monomer polymerization reaction take place, generate acrylic polymer, deposed polystyrene molecule is made to obtain modification, add its reactive group, can the acrylic acid modified alkyd resin of lactate synthesis coating further.
(2) preparation of acrylic acid modified alkyd resin
1. the preparation of carboxy acrylic prepolymer
A, by the deposed polystyrene collected or generate the waste leftover material of producer, remove foreign material.Clean, dry, suitably after fragmentation, drop in reactor, add appropriate organic solvent, stir about 1h, make it fully dissolve deposed polystyrene glue;
B, whole monomer and most of initiator be mixed in drip in still, stir, leave standstill a point water;
C, deposed polystyrene glue and a and most of dimethylbenzene dropped in reactor be warming up to backflow;
After d, question response reflux stabilizes, the mixed solution starting evenly to drip monomer and initiator dropwises in about 3h;
E, drip and finish, insulation back flow reaction 0.5h, adds residue initiator and the mixed solution of solvent, and continue insulation reaction 1.5h, after qualified, cooling discharge is for subsequent use;
2. the preparation of acrylic acid modified alkyd resin
A, drop into acrylic polymer and glycerine with agitator, water trap, point gold-plating pipe, prolong, thermometer reactor; B, be warming up to backflow and deviate from solvent, and be progressively warming up to 190-210 DEG C, insulation esterification, when the acid esters of assaying reaction system reaches below 2mg KOH/g, cooling adds ricinolic acid and Tetra hydro Phthalic anhydride;
C, be warming up to backflow, dehydration, and improve refuxing esterification temperature gradually to 220-230 DEG C, when reflecting the water yield and reaching 85% of theoretical aquifer yield, the situation of close observation reaction, strengthen the acid esters of resin, the mensuration of viscosity, until the technical indicator of resin is qualified, just can lower the temperature, latting drown, filtration, packaging;
Acrylic acid modified alkyd resin the key technical indexes
| Project | Technical indicator | Project | Technical indicator |
| Color (Fe-Co)/number | ≤2 | Acid number/mgKOHg -1 | ≤10 |
| Viscosity (being coated with-4) s | 150-250 | Solid content/% | 60±2 |
3. the preparation of polyurethane-modified colored paint
By the acrylic acid modified alkyd resin of synthesis and pigment, wetting dispersing agent disperses together, is ground to regulation fineness, adds solubilizing agent adjustment viscosity after part acrylic acid modified alkyd resin and flow agent, defoamer, filters, packaging.
(2) waste polystyrene foam plastic prepares the functional overprint varnish of release of trace elements negative ion by following quality of material part proportioning composition %
A, formula:
(1) waste polystyrene foam plastic 15.0;
(2) medical stone nano powder 6.0;
(3) tourmalinite nano powder 7.0;
(4) Ag-carried nanometer titanium dioxide " AT " 3.0;
(5) rosin modified phenolic resin 8.0;
(6) dioctyl phthalate (DOP) 10.0;
(7) aminoresin 2.0;
(8) Synolac 3.0;
(9) toluene 46.0;
B, preparation method:
By prescription quality part ratio requirement successively above-mentioned material is added stir in reactor after namely can be made into functionally light varnish.
C, efficacy effect:
The present invention is widely used in the furniture in decoration, floor, the gloss varnish of wall and artwork, include the medical stone nano-powder small molecules of abundant various trace elements and the tourmalinite nano powder of natural anion generator and Ag-carried nanometer titanium dioxide (AT) antiseptic-germicide small molecules, the various trace elements negative ion discharged in contacting with sunlight air, biocide molecules had not only been of value to body trace element and has supplemented and to regulate but also can the poisonous and harmful heavy metallic that discharges of antagonism paint itself and toluene gas, again can the negative ion of the useful HUMAN HEALTH of spontaneous continuous generation, kill the bacterium in air and virus.
(3) deposed polystyrene prepares the colored paint of antagonism absorption poisonous and harmful heavy metallic and gas by following proportion by weight composition %
A, formula:
(1) waste polystyrene foam plastic PSF 13.0;
(2) medical stone nano powder 7.0;
(3) tourmalinite nano powder 6.0;
(4) chloroform or benzene 20.0;
(5) rosin 21.0;
(6) dimethylbenzene 21.0;
(7) oil-soluble colourant 8.0;
(8) gasoline or kerosene 3.0;
(9) aluminum stearate or zinc 1.0;
B, preparation method:
Waste polystyrene foam plastic is cleaned and dries, after xylene soluble, again rosin is dissolved in benzene or chloroform, and aluminum stearate or zinc are also dissolved in wherein, the miscible stirring of both mixings, again gasoline or kerosene, medical stone nano powder, tourmalinite nano powder add rear stirring, finally add colorant and stir in right amount again.
C, performance
| Film | Flat appearance is smooth | Opacifying power (g/cm 2) |
| Fineness/mm | 40-90 | Black >=40 |
| Viscosity (being coated with-4 glasss)/s | 75-110 | Blue≤100 |
D, purposes
Coating for internal and external wall colored paint.
(4) Waste Polyester produces the modified alkyd resin paint of antagonism Adsorption of Heavy Metals anion releasing by following quality of material part proportioning composition %
A, formula:
(11) vegetables oil 31.0;
(12) waste polyethylene terephthalate 15.0;
B, preparation method:
(1) alcoholysis.Be equipped with reflux cooler, agitator, thermometer three in, add polyester waste silks, line oil, rosin and polyvalent alcohol make material be warming up to 120 DEG C to add basic catalyst, material is made to continue to be warming up to 240 DEG C, add medical stone nano powder, strange ice stone nano powder, disperse to continue alcoholysis gradually under constantly stirring, the molecular mass size of reacting polyester waste silks material after reaching requirement to vegetables oil tolerance depends on the materials proportioning of polyester waste silks and polyvalent alcohol.
(2) esterifying polycondensation.When temperature is down to 200 DEG C, water-and-oil separator is installed and adds rebasing solvent, then adding dibasic alcohol acid anhydride, then add reflux solvent, react at 200 DEG C, until acid number is not more than 12, stopped reaction.
(3) latting drown filters.Make reactant be cooled to less than 160 DEG C, add mixed solvent and siccative in stirring, to be mixed evenly after filter barrelling.
(5) terylene waste material produces the epoxy resin-based paint of release of trace elements negative ion anti-electric wave pollution by following quality of material part proportioning composition %
A, formula:
(22) dispersant polycarboxylate 1.0;
B, preparation method:
Semi-drying oleic acid, rosin, terylene waste material, medical stone nano powder, ferric oxide Fe is weighed up by prescription quality part proportioning
2o
3, tourmalinite nano powder, catalyzer add in the reactor of belt stirrer, thermometer, condenser successively, be warming up to 180 DEG C to start stirrer and stir and continue to be warming up to 240-250 DEG C, add dispersant polycarboxylate, object makes medical stone nano powder, ferric oxide Fe
2o
3, small molecules in tourmalinite nano-powder is dispersed in insulated and stirred 1-2h in above-mentioned material, add epoxy resin, backflow dimethylbenzene, at 220-230 DEG C of insulation 1-2h, be warming up to 230-240 DEG C again, insulation 2-3h, sampling detecting acid number, viscosity, when acid number drops to 6mg KOH/g, viscosity is 120s (being coated with-4 glasss), now be cooled to 130 DEG C, with dimethylbenzene to rare, filter, discharging obtained epoxy resin and color stuffing added auxiliary agent roller be milled to fineness qualified after, add siccative, regulate viscosity namely to obtain finished product of the present invention with dimethylbenzene.
C, performance:
D, purposes:
The epoxy resin-based paint of the energy release of trace elements negative ion anti-electromagnetic wave produced with terylene waste material.
Claims (1)
1. polystyrene polyester dacron prepares an environmental protection paint for antagonism adsorption antibacterial function, it is characterized in that:
(1) the acrylic modified alkyd functional polyurethane colored paint of deposed polystyrene preparation energy release of trace elements negative ion antibiotic, by following quality of material part proportioning composition %
Formula point two steps
A, the first step prepare acrylic acid modified alkyd resin formula
B, second step prepare acrylic modified alkyd urethane colored paint formulation
(2) waste polystyrene foam plastic prepares the functional overprint varnish of release of trace elements negative ion, by following quality of material part proportioning composition %
A, formula:
(3) deposed polystyrene prepares the colored paint of antagonism absorption poisonous and harmful heavy metallic and gas, by following proportion by weight composition %
A, formula:
(4) Waste Polyester produces the modified alkyd resin paint of antagonism Adsorption of Heavy Metals anion releasing, by following quality of material part proportioning composition %
A, formula:
(5) terylene waste material produces the epoxy resin-based paint that the anti-electric wave of release of trace elements negative ion pollutes, by following quality of material part proportioning composition %
A, formula;
Lower value≤100 of higher limit+other components of a certain component, higher limit >=100 of lower value+other components of a certain component.
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|---|---|---|---|
| CN201310102487.XA CN103205185B (en) | 2013-03-15 | 2013-03-15 | Deposed polystyrene polyester dacron prepares the nano environmental protection paint of antagonism adsorption antibacterial function |
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|---|---|---|---|
| CN201310102487.XA CN103205185B (en) | 2013-03-15 | 2013-03-15 | Deposed polystyrene polyester dacron prepares the nano environmental protection paint of antagonism adsorption antibacterial function |
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| CN103205185B true CN103205185B (en) | 2015-09-23 |
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| CN103602207B (en) * | 2013-09-18 | 2016-08-17 | 兰州陇嘉化工科技有限公司 | A kind of lacquer type organic coating utilizing waste plastic bottle to prepare and preparation method thereof |
| CN103788845B (en) * | 2014-01-22 | 2016-04-20 | 南通市海鸥救生防护用品有限公司 | A kind of anti-mould and anti-moth fungicidal paint and preparation method thereof |
| BR112016015467B1 (en) * | 2014-01-27 | 2021-05-11 | Swimc Llc | coating system and method, and, coated article |
| CN104320064A (en) * | 2014-11-19 | 2015-01-28 | 苏州东润太阳能科技有限公司 | Solar battery frame |
| CN104987468B (en) * | 2015-07-01 | 2017-11-24 | 湖南晟通纳米新材料有限公司 | Waterborne acrylic modified alkyd resins emulsion and preparation method thereof |
| CN105567055A (en) * | 2015-11-09 | 2016-05-11 | 南通蛇类治疗研究所 | Functional environment-friendly paint produced by waste polyester plastic |
| CN107163646A (en) * | 2017-06-15 | 2017-09-15 | 南通蛇类治疗研究所 | Deposed polystyrene environment-friendly fireproof fire retardant functionality coating |
| CN107216720A (en) * | 2017-07-11 | 2017-09-29 | 南通蛇类治疗研究所 | Waste plastics prepares environment protection type functional varnish |
| CN109971297A (en) * | 2019-04-12 | 2019-07-05 | 万桓宇 | Pyramid craftwork function magnetic coating and the pyramid craftwork of relaxing tendons and activating collaterals |
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