CN103202792B - Skin care lotion containing wax gourd, honey and egg yolk - Google Patents
Skin care lotion containing wax gourd, honey and egg yolk Download PDFInfo
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- CN103202792B CN103202792B CN201310066080.6A CN201310066080A CN103202792B CN 103202792 B CN103202792 B CN 103202792B CN 201310066080 A CN201310066080 A CN 201310066080A CN 103202792 B CN103202792 B CN 103202792B
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Abstract
The invention discloses a skin care lotion containing wax gourd, honey and egg yolk. A preparation method comprises the following steps: (1) preparing a wax gourd Tremella juice with high concentration; (2) preparing a semi-emulsified semi-finished product; (3) preparing a water aqua semi-finished; and (4) preparing a final product. The product provided by the invention not only breaks through the limitations of a traditional skin care agent, such as simple composition and single function, but also enables the novel water aqua to have the advantages of a skin care emulsion and an essence, so as to realize a multifunctional water aqua and comprehensive effect. In appearance, the choice of emulsifier and a unique semi-emulsion technology realize beautiful appearance and unique "jade like" beauty sense of the water aqua. For usage, the product not only can achieve very good effects of moisturizing, moistening, whitening skin, smoothing, and resisting wrinkle and aging, but also can achieve good psychological beautifying effect on a user.
Description
Technical field
The invention belongs to skin care item, belong to cosmetics field.Be specifically related to a kind of substitute water component consumption in formula with Fructus Benincasae, the refining natural juice of Tremella, and with the Fructus Benincasae Mel egg yolk surfactant of the balanced collocation of multiple efficacies component such as Mel, egg oil, jade ball.
Background technology
Along with social development and the raising of living standard, people more and more pay attention to beauty treatment and make up.Liking to be beautiful is people's nature, and skin care, slow down aging, to keep the youth here be the dream that numerous women pursue, so all kinds of cosmetics and skincare product has just become one of approach of realizing their dream.Water preparation class skin care item are the important a member in skin-care cosmetics, but for a long time, and formula is simple, and component is single, and make base material with a large amount of pure water, and this is the common defects of traditional water preparation class skin care item; Some disperse water preparation class skin care item wherein due to cost part oils and fats, the restriction of the factors such as stability, effect level of skin protection water preparation significantly can not be promoted, even some water preparations still rest on the conceptual phase of falling short of the reality, and can not in beauty and skin care process, bring into play larger effect.
Fructus Benincasae claim again white melon, water sesame, sesame, Fructus Benincasae etc.Being the vegetable that stature is larger, is again the non-defective unit of beauty care.China just has many about the record with the skin protection of Fructus Benincasae skin Caring since ancient times.Make face fat as introduced in the Tang Dynasty " Shengji Zonglu " book with Fructus Benincasae and carry out beauty method.In medical science grand ceremony Compendium of Material Medica, record: " Caulis Benincasae is white, soft, with it wash one's face, ablution, can remove skin brown patch, make colour of skin softness bright and clean, pale; " Shennong's Herbal record: wax gourd seed can make us " face blazes "; " large bright book on Chinese herbal medicine " recorded: wax gourd seed can be cured scytitis, makes the colour of skin moist; " the seven white cream " recorded in Ming Dynasty's " Prescriptions for Universal Relief ", adopts Semen Benincasae to do one of main component exactly.In addition, the record that still has many Fructus Benincasae beauty and skin cares, health care among the people: wash one's face, have a bath with the fresh juice of Caulis Benincasae, can skin whitening, make skin glossy; Fructus Benincasae meat is well-done together with wine, water, with cloth elimination slag, endure after cream is encrypted and endure again, when use, temper, painting face, then, with palm friction face, clear water washes away.Can control face unclean, dark and gloomy eclipsed; Semen Benincasae is dried, and the Adeps Sus domestica equivalent mediation low baking temperature of pulverization and equivalent is endured cream, and be sooner or later coated with and put face and hand on the skin every day, can make face, and hand skin is moistened and wrinkle resistant brightening; Mash into after pasty state directly flush coat with fresh Caulis Benincasae, 1-2 time weekly, often wash 15 minutes, there is wrinkle resistant, to discolor speckle effect;
From numerous records at all times, can find out from Caulis Benincasae to Exocarpium Benincasae, Caulis Benincasae, wax gourd seed (core), Fructus Benincasae meat etc., all have suitable or beauty and skin care effect preferably.Angle with modern science is seen, the basis of these effects must be to derive from contained a certain or multiple efficacies composition in the inside and outside each component of Fructus Benincasae.The certified functional components of Modern Analytical Chemistry means is as follows:
1. contained in Fructus Benincasae meat: adenine, cupreol, hydroxymalonic acid, lupeol, tridecyl alcohol, mannitol, Fructus Benincasae polysaccharide, rhamnose, cucurbitacin β, multivitamin, aminoacid and mineral, dietary fiber etc.
2. contained in Caulis Benincasae: trigonelline, histidine, adenine, vitamin C, E, B etc.
3. contained in wax gourd seed: Saponin, carbamide, urea decomposing enzyme, fatty oil (oleic acid), citrulline, histidine, Lupeol, mannitol, cupreol, vitamin B1, protein etc.
4. in Exocarpium Benincasae, contain: wax class and resinae material, chlorophyll, ornithine, y-aminobutyric acid, arginine, several amino acids etc.
Quantitatively in Fructus Benincasae, Vitamin C content is more, reaches 16-18 milligram/hectogram from known, and this may be one of material base of the white and tool white-skinned face function of Fructus Benincasae self.Fructus Benincasae polysaccharide (β-D-pyranose etc.) content is also up to 2.4 grams/hectogram (in carbohydrate), and this may be one of Fructus Benincasae material base with moisturizing skin care effect.The protein, oleic acid (main memory is in melon seed), several amino acids, hydroxymalonic acid, trigonelline and several mineral materials and the trace element etc. that in Fructus Benincasae, are rich in addition.May all in beauty and skin care, play independent or collaborative whitening skin and preserving moisture, skin care effect and become the material base that supports Fructus Benincasae beauty and skin care effect.
Existing Fructus Benincasae class cosmetics and skincare product is especially in water preparation class Fructus Benincasae skin care item, ubiquity two large problems: the one, addition is little, mostly is and adopts commerical grade Fructus Benincasae extracting solution 3-5%(solid content 2.5%); The 2nd, the effective ingredient of Fructus Benincasae extracting solution is comprehensive not, and some biochemical product factories are in the time producing Fructus Benincasae extracting solution, and often based on clarity, the consideration of the aspects such as stability and cost, only extracts the part component in Fructus Benincasae.
Tremella is a kind of famous and precious tonic, can be used as again the fine raw material of cosmetics and skincare product.Wherein contain protein, fat and several amino acids, mineral and polysaccharose substance.Domestic existing biotech company extracts different poly-polysaccharose substance from Tremella, and alternative hyaluronic acid is for cosmetics and skincare product.But due to expensive, in general water preparation class skin care item, consumption is little, even simply need not.
Mel: sweet in the mouth, property are put down, and are exactly nourishing and fit keeping function from ancient times, the good merchantable brand of eliminating toxin and beautifying the skin.Mel is rich in the multiple elements such as VB, VD, VE, fructose, glucose, maltose, high quality protein, several amino acids, potassium, sodium, ferrum, natural perfume material, lactic acid, malic acid, amylase, oxidase, is natural enamel.The beauty functions of Mel is putative always, is mainly manifested in moisturizing moisturizing, delicate skin, reduces wrinkle, desalinates all many-sides such as mottle.Before 1700, China has started to improve looks with Mel, and " clever moth drive with gorgeous face " recorded for Guo Pu in Shanxi in " Apis taxs ".In the well-known doctor Zhen Quan at the age of one hundred years old of the Northern and Southern Dynasties " property of medicine opinion ", record " Mel informal dress is looked like premium ".In modern beauty skin care item, especially water preparation class skin care item, although also once added Mel, but due to general water preparation all require transparent, stable, without precipitate, this just makes the addition of Mel reduce or simply not select, thereby make its selecting in water preparation series products restricted greatly, can not give play to significantly the beauty functions of Mel
Egg oil: be the fatty oil extracting from Fresh Egg, be rich in a large amount of phospholipid, also contain the multiple nutritional components such as lecithin, vitamin A. D. E.Egg coordinates Mel, Fructus Benincasae juice etc. a lot of for the folk prescription of beauty and skin care, but great majority are now with the current.Although there is good skin effect, can not be used for large-scale production, and selects egg oil to add the part effect that will give play to fresh egg beauty treatment in water preparation class skin care item to.
Margarita hydrolyzed solution: Margarita claims again natural pearls, is famous and precious ornament, is also the fine raw material of cosmetics, be rich in various trace elements and 16 seed amino acids, its hydrolyzed solution is beneficial to skin and absorbs, and can increase cell viability, prevent skin aging, make skin moisturizing, softness, smooth, pure white.
Collagen protein powder: test and show, the average molecular mass of collagen hydrolysate, in the time of 700-1000 scope, is selected suitable adding proportion, can give play to the beauty functions such as good moisturizing, skin care, light speckle, reparation.Along with the development of modern biotechnology, the production cost of collagen protein powder reduces greatly, and this is just for the collagen protein powder that adds larger proportion in aqua product provides feasibility.
Jade pearl, agate bead, Aeschna melanictera pearl, crystal ball: China just has the good name of " state of jade " since ancient times.Ancients look beautiful for precious, both can be used as precious decorations pendant use, also can be used as the non-defective unit of beauty and skin care health care.Famous singing-girl Pang Sanniang of legend the Tang Dynasty, though over fifty, but still just like young girl, the secret formula of its skin-protecting face nursing is to have used extraordinary jade; In " imperial fragrant dimly discernible record ", also record the method for the Empress Dowager with beautiful chi beauty treatment.Modern age, high-tech test was found, was not only rich in the multiple trace element useful to human body in extraordinary jade, also had special photoelectricity magnetic field and energy-structure, and this is also not available in common metal article " intelligence " place.Visible, the beauty functions of extraordinary jade is not only embodied in aspect of material, is also embodied in energy aspect and spirit level.Tailing in extraordinary jade factory is processed into jade pearl, agate bead, Aeschna melanictera pearl or the crystal ball of different-grain diameter.Join in water preparation class beauty and skin care product, can not only leach the trace element useful to human body, can also promote effect by activated water, increase aesthetic feeling.Allow people in enjoying material beauty treatment, also can obtain the joyful of soul.
In the market also not with high concentration all nutrition type Fructus Benincasae, Tremella natural juice instead of pure water component, and with after the balanced collocation such as Mel, egg oil, Jojoba oil, Margarita hydrolyzed solution, collagen protein powder, emulsifying agent, jade pearl, agate bead, crystal ball, use again unique semi-emulsifying technology and conventional water preparation technology of preparing, the refining functional balanced auxotype forming and the high-grade skin protection water preparation of outward appearance uniqueness.
Summary of the invention
The object of the invention is provides for the deficiency of existing beauty and skin care water preparation technology the novel high-grade skin protection water preparation that a kind of multicomponent, high collocation balanced in nutrition and outward appearance are peculiar.This has not only broken through the limitation that traditional skin protection water preparation component is simple, effect is single; Can also make this novel water preparation have the advantage of the product such as facial treatment milk, essence concurrently, be that potion is multiplex, and effect is comprehensive.Aspect outward appearance, the invention of the selection of emulsifying agent and unique semi-emulsifying technology, has realized that this water preparation outward appearance is beautiful, unique aesthetic feeling of " beautiful hidden jade is existing ".While allowing people use this product, can not only reach good replenishing water and preserving moisture, tender white beautiful skin, moisten smooth, wrinkle resistant anti-ageing effect, can also reach good psychological cosmetic result.
The technical solution used in the present invention is:
Fructus Benincasae Mel egg yolk surfactant of the present invention, its preparation method comprises the steps:
(1) preparation of high concentration Fructus Benincasae Tremella natural juice: described high concentration Fructus Benincasae Tremella natural juice is made up of the raw material of following mass parts: 100 parts, Fructus Benincasae, 0.1 ~ 0.5 part, Tremella, 120 ~ 150 parts of deionized waters, 0.5 ~ 1 part of ethanol, propylene glycol 0.5-1 part;
(2) semi-emulsifying half-finished preparation: by 100, described semi-emulsifying semi-finished product are made up of the raw material of following mass parts with final Fructus Benincasae Mel egg yolk surfactant (part except jade pearl):
A: oil phase part: egg oil 0.1-10 part, Jojoba oil 0.1-8 part, squalane 0.1-8 part, vitamin E oil 0.1-1.0 part, ditertbutylparacresol 0.01-0.05 part;
B: water and emulsifying agent part: high concentration Fructus Benincasae Tremella natural juice 20-50 part, ethoxy acrylates/sodium acryloyldimethyl taurate copolymers (trade name: SEPINOVEMT10, manufacturer: match BIC Corp of France (seppic)) 0.1-2.0 part or acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross linked polymer (trade name: TR-1, production firm: Lubrizol Corp. of the U.S.) 0.1-2.0 part;
(3) the half-finished preparation of water preparation: described water preparation semi-finished product are made up of the raw material of following mass parts: glycerol 5-10 part, amino acid humectant 0.1-5 part, water solublity lanoline 0.1-5 part, allantoin 0.05-0.5 part, polyquaternary ammonium salt-39:0.1-5 part, Sargassum rock polysaccharide 0.1-5 part, Mel 1-10 part, collagen protein powder 0.5-5 part, Margarita hydrolyzed solution 0.1-5 part, high concentration Fructus Benincasae Tremella natural juice 20-40 part;
(4) preparation of final products: semi-emulsifying semi-finished product prepared by step (2) join among water preparation semi-finished product prepared by step (3), stirs, and adds antiseptic, essence obtain Fructus Benincasae Mel egg yolk surfactant of the present invention.
Described high concentration Fructus Benincasae Tremella natural juice prepares by the following method:
(1) 100 mass parts Fructus Benincasaes are first cleaned with tap water, clean with pure water again, afterwards with 75% alcoholic solution sterilization crust, it is the rectangular of 6-7mm × 30-60mm that Exocarpium Benincasae, Fructus Benincasae meat are processed into diameter, Caulis Benincasae (band seed) is cut into the rectangular of 15 × 15 × 30-60mm, adds in stainless steel cask;
(2) 0.1-0.5 mass parts Tremella is first soaked 15 minutes in tap water, clean with pure water again after removing impurity part, be divided into after small pieces with hands, add in stainless steel cask;
(3) by 120-150 mass parts deionized water, 0.5-1.0 mass parts ethanol, 0.5-1.0 mass parts propylene glycol adds respectively in stainless steel cask;
(4) after boiled with big fire, use little fire instead and boil more than two hours, in the time that system gross mass is reduced to 100-110 mass parts, stop boiling cooling rear use 600 order filter-cloth filterings; The filtrate of gained, is high concentration (total solids content >=2.5%) Fructus Benincasae Tremella natural juice.
Described semi-emulsifying semi-finished product prepare by following technique:
(1) oil phase part preparation: after the egg oil of formula ratio, Jojoba oil, squalane, vitamin E oil, ditertbutylparacresol are taken in proportion, add with in the rustless steel still stirring, under the stirring of rotating speed 20-30 rev/min, be heated to 80-85 DEG C, constant temperature disinfection 20 minutes, be cooled to afterwards 40 DEG C for subsequent use;
(2) water and the preparation of emulsifying agent part: by the ethoxy acrylates/sodium acryloyldimethyl taurate copolymers taking in proportion or acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross linked polymer, dispersing and dissolving is in the high concentration Fructus Benincasae Tremella natural juice taking in proportion, under the stirring of rotating speed 20-30 rev/min, dispersing and dissolving 4-8 hour;
(3) oil phase above-mentioned steps (1) being obtained under agitation slowly adds in the water that step (2) obtains, after adding, make emulsifying agent if select ethoxy acrylates/sodium acryloyldimethyl taurate copolymers, semi-emulsifying mixing speed is controlled at 40-60 rev/min, and semi-emulsifying mixing time is controlled at 3-5 minute; Make emulsifying agent if select acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross linked polymer, semi-emulsifying homogenizing speed controlling is at 1000-1500 rev/min, scrape wall mixing speed and be controlled at 40-50 rev/min, the semi-emulsifying time is controlled at 0.5-2.0 minute (emulsifying temperature is 40 DEG C), can obtain semi-emulsifying semi-finished product.
Described water preparation semi-finished product prepare by following technique:
(1) by the glycerol of formula ratio, amino acid humectant, water solublity lanoline, allantoin, polyquaternary ammonium salt-39, Sargassum rock polysaccharide and high concentration Fructus Benincasae Tremella natural juice, add in the rustless steel still of stirring, heating for dissolving under the stirring of 20-40 rev/min, constant temperature sterilizing 20 minutes 80-85 DEG C time, afterwards cooling;
(2) while cooling to 50 DEG C, add the collagen protein powder of formula ratio, Mel and Margarita hydrolyzed solution, continue stirring and dissolving and cooling afterwards;
(3) temperature drops to 40 DEG C, after wherein collagen protein powder dissolves completely, is water preparation semi-finished product.
The preparation of described final products prepares by following technique:
(1) the semi-emulsifying semi-finished product part of preparation is added among water preparation semi-finished product part, under the mixing speed of 20-30 rev/min, stir 1-3 minute;
(2) add antiseptic: A type solubilising type methyl hydroxybenzoate, ethyl ester, propyl ester mixture (wos-40A, Shanghai Simpson thing Science and Technology Ltd.) 0.6 part, Type B solubilising type methyl hydroxybenzoate, butyl ester mixture (wos-40B, Shanghai Simpson thing Science and Technology Ltd.) 0.6 part, mixture 0.1-0.8 part of MIT and butyl carbamic acid 3-iodo-2-propynyl ester and propylene glycol;
(3) add fruit extrait 0.01-0.05 part, under the mixing speed of 20-30 rev/min, stir 3-5 minute afterwards;
(4) if select acrylic acid (ester)
/when C10-30 alkyl acrylate cross-linked polymer is made emulsifying agent, still need and add triethanolamine 0.1-2.0 part, stir afterwards 3-5 minute;
(5) before fill, add any one or the multiple 1-30 grain/bottle in jade pearl that the particle diameter after washing and sterilizing is 1-30mm, agate bead, Aeschna melanictera pearl, crystal ball.
The cleaning of described jade pearl, agate bead, Aeschna melanictera pearl, crystal ball, sterilization, adding technology are: the above-mentioned jade pearl ball of customization is first cleaned with tap water, clean with pure water again, be immersed in afterwards in 75% alcoholic solution, when interpolation, add in the Packaging Bottle of the poison that disappeared with the tweezers of the poison that disappeared.
Surfactant of the present invention is the cycle length of (Ji Jingfanghou lower floor thin out, present jade pearl state) from jade hidden (i.e. shake uniform state) to beautiful showing, can be controlled by parameters such as adjusting emulsifier, oily components consumption, emulsification times and emulsification stirring speed, emulsifying temperature, or a couple of days or several weeks or several months etc. arbitrarily determine, also can determine according to user's use habit and hobby; In the situation that oily components consumption, emulsification times, emulsifying temperature, emulsification stirring speed are fixing, emulsifier is larger, hidden longer to the beautiful existing cycle by jade, otherwise shorter; Emulsifier is main control parameter.
Before product-filled, the finished product water preparation after answering agitation as appropriate to deposit, especially designed from the hidden finished product water preparation to existing cycle of jade shorter (as a couple of days etc.) of jade, after depositing, before fill, should stir, to ensure the harmony of product.
After aqua product long-term storage after fill, it is dense that upper strata turns gradually, and lower floor turns light genus normal phenomenon gradually, is also one of existing bright spot of the hidden jade of jade of this aqua product institute tool uniqueness; When use, shake up, do not affect result of use; Before using, client can see in detail operation instructions and the relevant use prompting of joining with product.Product package bottle after fill is marked with " used time please shake up " printed words.
Base material of the present invention is high concentration all nutrition type Fructus Benincasae Tremella natural juice.The unusual part of this natural juice is that the selection of Fructus Benincasae raw material follows the principle of " natural proportion " completely,, in the time buying Fructus Benincasae, is advisable with whole melon, cuts purchase if meet, and still cuts by natural ratio.Exocarpium Benincasae, Fructus Benincasae meat, Caulis Benincasae, wax gourd seed are all by the natural ratio juice processed that feeds intake, to guarantee the wherein natural balance of each nutritional labeling.It is good that color and luster is chosen in the selection of Tremella, individual dry tremella uniformly.In method for making, select the little Huo decoction method of safe easy row.Clean with clear water by the Fructus Benincasae of fresh maturation, then by 75% alcoholic solution sterilize appearance and cutting plane part, stripping and slicing is afterwards wiped into the rectangular of diameter 6-7mm × 30-50mm with clean grater.Tremella is steep raising afterwash, after together adding in stainless steel cask big fire boiled together with ethanol propylene glycol, changing little fire into boils more than 2 hours, in the time that being reduced to 100-110 part, the total amount that feeds intake stops boiling, leach the Fructus Benincasae Tremella natural juice of 70 parts of left and right with 600 order filter clothes, be high concentration (solid content reaches more than 2.5%) balanced nutritious (natural proportion) type Fructus Benincasae Tremella natural juice.
The invention of the selection of emulsifying agent and consumption and semi-emulsifying technology is the key of making these novel high-grade water preparation skin care item.Well-known water, oily objectionable intermingling, if make the oily components such as egg oil, Jojoba oil, squalane affine with the numerous water-soluble components in formula, must select suitable emulsifying agent and suitable consumption, but can not adopt conventional emulsifying technology, because conventional emulsifying agent and emulsifying technology are easy to transfer the beautiful outward appearance of this characteristic water preparation to milli indistinctive ordinary emulsion, that is to say that emulsifying degree is excessively dark, whole system has just become milky mixture.Egg oil, Jojoba oil, Mel and Fructus Benincasae Tremella natural juice etc. all have flaxen beautiful outward appearance.The preferred New-type emulsifier of the present invention: ethoxy acrylates/sodium acryloyldimethyl taurate copolymers; or acrylic acid (ester) class/alkyl acrylate cross-linked polymer is in the scope of consumption 0.1-2%; control emulsification times, temperature and mixing speed and can make the fresh faint yellow beautiful water preparation of semitransparent type; shake beautiful hidden, quiet beautiful existing.The invention of semi-emulsifying technology has not only solved the fusion problem of oily components, has also retained dexterously the naturally fresh color in raw material, can make water preparation in the situation that not adding any pigment, have the tempting outward appearance of nature.
The key of semi-emulsifying technology is according to formula and raw material type, selects suitable emulsifying agent and consumption, and controls addition manner and mixing speed, time, temperature, finally obtains a kind of complex art of middle emulsified state of expectation.As everyone knows, if the selection of emulsifying agent is improper, or when consumption is too low and emulsifying degree is on the low side, just cannot break the surface tension in oil phase component, oil phase component cannot merge with water component easily, in the course of time, upper collection is arrived system top by oil ingredient in water preparation, even if firmly shake, is also difficult to merge evenly, make troubles to use; Otherwise if emulsifier is too large, when emulsifying degree is too high, whole water preparation system has become dilute emulsion, has completely lost the beautiful characteristic of water preparation, although solved the fusion problem of oil ingredient, characteristic and an aesthetic feeling are not had.The utilization of semi-emulsifying technology is between low emulsifying and high emulsifying, to find an optimal point of operation.
The semi-emulsifying body that semi-emulsifying operation makes is a part of semi-finished product in this water preparation, is referred to as semi-emulsifying semi-finished product part.
Still have the conventional type water preparation semi-finished product part that needs heating and the rear preparation of cooling, method for making is described above,
Below 40 DEG C time, the semi-emulsifying semi-finished product that made are joined in water preparation semi-finished product, under the stirring of 20-30 rev/min, stir 2-3 minute, adding afterwards antiseptic total amount is that 0.3-2.0%(amounts to three kinds of antiseptic: two kinds is methyl hydroxybenzoate, ethyl ester, propyl ester, butyl ester mixture after solubilising, and total amount is 0.2-2.0%; Another kind is the mixture of MIT and butyl carbamic acid 3-iodo-2-propynyl ester and propylene glycol, and consumption is 0.1-0.5%), essence 0.01-0.5%.If select acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross linked polymer to make emulsifying agent, still need and add triethanolamine 0.1-1.0%, under the stirring of 20-30 rev/min, stir 3-5 minute afterwards, can discharging fill.Jade pearl, agate bead, Aeschna melanictera pearl and crystal ball add by following technique:
The jade pearl that is 1-30mm by diameter customized, agate bead, Aeschna melanictera pearl, crystal ball are first cleaned with pure water, be immersed in again in 75% alcoholic solution and sterilize, before water preparation fill, clamping above-mentioned jade pearl etc. with the tweezers after sterilization afterwards joins in the Packaging Bottle after sterilization, addition every kind of 1-30/bottle, the water preparation that fill is afterwards made completes the overall process of this invention.
The invention has the beneficial effects as follows: thoroughly overturned the water preparation concept in traditional cosmetics and skincare product, also overturned the concept of conventional emulsification technology simultaneously, prove semi-emulsifying technology to apply in the preparation technology of novel water preparation, not only can jump out traditional water preparation limitation single, effect is limited of selecting materials, can also make the aqua product of preparation have more beautiful tempting outward appearance, meet people and both focused on inherent quality, focus on again the multi-level demand of product appearance.This novel high-grade skin protection water preparation, taking self-control high concentration, balanced nutritious type Fructus Benincasae Tremella natural juice as base material, the equilibrium multiple beauty and skin care compositions such as Mel, egg oil, Jojoba oil, collagen protein, Margarita hydrolyzed solution, Sargassum rock polysaccharide, water solublity lanoline, aminoacid of having arranged in pairs or groups again, be nutritious, effect is comprehensive, by traditional water preparation rare; And adding of numerous oily components makes again this water preparation have the advantage of facial treatment milk concurrently, therefore use this top grade skin protection water preparation, equal to have used facial treatment milk simultaneously, the effect of facial treatment repair and three kinds of products of traditional surfactant, this has especially practical value concerning busy modern.Use adding of beautiful outward appearance that semi-emulsifying technology makes and jade pearl, agate bead, Aeschna melanictera pearl and crystal ball simultaneously, make again this water preparation have to shake beautiful hidden, quiet beautiful existing marvellous outward appearance, allow people obtain moisturizing, tender white, moisten, in the cosmetic result such as health care, also can obtain good psychological cosmetic result.
Detailed description of the invention
Embodiment 1
The Fructus Benincasae Mel egg yolk surfactant of the present embodiment, its preparation method comprises the steps:
(1) preparation of high concentration Fructus Benincasae Tremella natural juice:
(1) 100 kg Fructus Benincasaes are first cleaned with tap water, clean with pure water again, afterwards with 75% alcoholic solution sterilization crust, it is the rectangular of 6-7mm × 30-60mm that Exocarpium Benincasae, Fructus Benincasae meat are processed into diameter, Caulis Benincasae (band seed) is cut into the rectangular of 15 × 15 × 30-60mm, adds in stainless steel cask;
(2) 0.1-0.5 kg Tremella is first soaked 15 minutes in tap water, clean with pure water again after removing impurity part, be divided into after small pieces with hands, add in stainless steel cask;
(3) by 120-150 kg deionized water, 0.5-1.0 kg ethanol, 0.5-1.0 kg propylene glycol adds respectively in stainless steel cask;
(4) after boiled with big fire, use little fire instead and boil more than two hours, in the time that system gross mass is reduced to 110 kg, stop boiling cooling rear use 600 order filter-cloth filterings; The filtrate of gained, is high concentration (total solids content >=2.5%) Fructus Benincasae Tremella natural juice.
(2) semi-emulsifying half-finished preparation:
Described semi-emulsifying semi-finished product prepare by following technique:
(1) oil phase part preparation: by egg oil 8 kg, Jojoba oil 0.1kg, squalane 0.1 kg, vitamin E oil 0.2 kg, ditertbutylparacresol 0.02 kg, add with in the rustless steel still stirring, under the stirring of rotating speed 20-30 rev/min, be heated to 80-85 DEG C, constant temperature disinfection 20 minutes, be cooled to afterwards 40 DEG C for subsequent use;
(2) water and the preparation of emulsifying agent part: by the acrylic acid taking in proportion (ester) class/C10-30 alkylol acrylamide acid esters cross linked polymer 0.28 kg, dispersing and dissolving is in the high concentration Fructus Benincasae Tremella natural juice of 31kg, under the stirring of rotating speed 20-30 rev/min, dispersing and dissolving 4-8 hour;
(3) oil phase above-mentioned steps (1) being obtained under agitation slowly adds in the water that step (2) obtains, after adding, semi-emulsifying homogenizing speed controlling is at 1500 revs/min, scrape wall mixing speed and be controlled at 50 revs/min, the semi-emulsifying time is controlled at 2.0 minutes (emulsifying temperature is 40 DEG C), can obtain semi-emulsifying semi-finished product.
(3) the half-finished preparation of water preparation:
(1) by glycerol 8.3 kg, amino acid humectant 1.8 kg, water solublity lanoline 0.8 kg, allantoin 0.2 kg, polyquaternary ammonium salt-39 1.45 kg, Sargassum rock polysaccharide 2.8 kg and high concentration Fructus Benincasae Tremella natural juice 40 kg, add in the rustless steel still of stirring, heating for dissolving under the stirring of 40 revs/min, constant temperature sterilizing 20 minutes 85 DEG C time, afterwards cooling;
(2) while cooling to 50 DEG C, add collagen protein powder 1 kg, Mel 2 kg and Margarita hydrolyzed solution 0.5 kg, continue stirring and dissolving and cooling afterwards;
(3) temperature drops to 40 DEG C, after wherein collagen protein powder dissolves completely, is water preparation semi-finished product.
(4) preparation of final products:
(1) the semi-emulsifying semi-finished product part of preparation is added among water preparation semi-finished product part, under the mixing speed of 30 revs/min, stir 3 minutes;
(2) add antiseptic: A type solubilising type methyl hydroxybenzoate, ethyl ester, propyl ester mixture (wos-40A, Shanghai Simpson thing Science and Technology Ltd.) 0.5 kg, Type B solubilising type methyl hydroxybenzoate, butyl ester mixture (wos-40B, Shanghai Simpson thing Science and Technology Ltd.) 0.5 kg, mixture 0.2 kg of MIT and butyl carbamic acid 3-iodo-2-propynyl ester and propylene glycol;
(3) add fruit extrait 0.05 kg, under the mixing speed of 20-30 rev/min, stir 3-5 minute afterwards;
(4) add triethanolamine 0.2 kg, stir afterwards 5 minutes;
(5) before fill, add 10/bottle, the jade pearl that the particle diameter after washing and sterilizing is 5mm.
Embodiment 2
The Fructus Benincasae Mel egg yolk surfactant of the present embodiment, its preparation method comprises the steps:
(1) preparation of high concentration Fructus Benincasae Tremella natural juice:
(1) 100 kg Fructus Benincasaes are first cleaned with tap water, clean with pure water again, afterwards with 75% alcoholic solution sterilization crust, it is the rectangular of 6-7mm × 30-60mm that Exocarpium Benincasae, Fructus Benincasae meat are processed into diameter, Caulis Benincasae (band seed) is cut into the rectangular of 15 × 15 × 30-60mm, adds in stainless steel cask;
(2) 0.1kg Tremella is first soaked 15 minutes in tap water, clean with pure water again after removing impurity part, be divided into after small pieces with hands, add in stainless steel cask;
(3) by 120 kg deionized waters, 0.5 kg ethanol, 0.5kg propylene glycol adds respectively in stainless steel cask;
(4) after boiled with big fire, use little fire instead and boil more than two hours, in the time that system gross mass is reduced to 100 kg, stop boiling cooling rear use 600 order filter-cloth filterings; The filtrate of gained, is high concentration (total solids content >=2.5%) Fructus Benincasae Tremella natural juice.
(2) semi-emulsifying half-finished preparation:
Described semi-emulsifying semi-finished product prepare by following technique:
(1) oil phase part preparation: by egg oil 0.1 kg, Jojoba oil 0.1 kg, squalane 8kg, vitamin E oil 0.2 kg, ditertbutylparacresol 0.02 kg, add with in the rustless steel still stirring, under the stirring of 30 revs/min of rotating speeds, be heated to 80 DEG C, constant temperature disinfection 20 minutes, be cooled to afterwards 40 DEG C for subsequent use;
(2) water and the preparation of emulsifying agent part: by the ethoxy acrylates/sodium acryloyldimethyl taurate copolymers taking in proportion (trade name model: SEPINOV EMT10 and manufacturer: match BIC Corp of France) 1 kg, dispersing and dissolving is in the high concentration Fructus Benincasae Tremella natural juice of 35.6kg, under the stirring of 20 revs/min of rotating speeds, dispersing and dissolving 8 hours;
(3) oil phase above-mentioned steps (1) being obtained under agitation slowly adds in the water that step (2) obtains, and after adding, semi-emulsifying mixing speed is controlled at 60 revs/min, and semi-emulsifying mixing time is controlled at 5 minutes; Can obtain semi-emulsifying semi-finished product.
(3) the half-finished preparation of water preparation:
(1) by glycerol 8kg, amino acid humectant 4 kg, water solublity lanoline 0.6kg, allantoin 0.18kg, polyquaternary ammonium salt-39 0.2kg, Sargassum rock polysaccharide 2kg and high concentration Fructus Benincasae Tremella natural juice 35.2 kg, add in the rustless steel still of stirring, heating for dissolving under the stirring of 40 revs/min, constant temperature sterilizing 20 minutes 85 DEG C time, afterwards cooling;
(2) while cooling to 50 DEG C, add collagen protein powder 1.2kg, Mel 2 kg and Margarita hydrolyzed solution 0.2 kg, continue stirring and dissolving and cooling afterwards;
(3) temperature drops to 40 DEG C, after wherein collagen protein powder dissolves completely, is water preparation semi-finished product.
(4) preparation of final products:
(1) the semi-emulsifying semi-finished product part of preparation is added among water preparation semi-finished product part, under the mixing speed of 20-30 rev/min, stir 1-3 minute;
(2) add antiseptic: A type solubilising type methyl hydroxybenzoate, ethyl ester, propyl ester mixture (wos-40A, Shanghai Simpson thing Science and Technology Ltd.) 0.6 kg, Type B solubilising type methyl hydroxybenzoate, butyl ester mixture (wos-40B, Shanghai Simpson thing Science and Technology Ltd.) 0.6 kg, mixture 0.1 kg of MIT and butyl carbamic acid 3-iodo-2-propynyl ester and propylene glycol;
(3) add fruit extrait 0.1 kg, under the mixing speed of 30 revs/min, stir 5 minutes afterwards;
(4) before fill, add 30/bottle of the agate beads that the particle diameter after washing and sterilizing is 3mm.
Embodiment 3
The Fructus Benincasae Mel egg yolk surfactant of the present embodiment, its preparation method comprises the steps:
(1) preparation of high concentration Fructus Benincasae Tremella natural juice:
(1) 100 kg Fructus Benincasaes are first cleaned with tap water, clean with pure water again, afterwards with 75% alcoholic solution sterilization crust, it is the rectangular of 6-7mm × 30-60mm that Exocarpium Benincasae, Fructus Benincasae meat are processed into diameter, Caulis Benincasae (band seed) is cut into the rectangular of 15 × 15 × 30-60mm, adds in stainless steel cask;
(2) 0.5 kg Tremella is first soaked 15 minutes in tap water, clean with pure water again after removing impurity part, be divided into after small pieces with hands, add in stainless steel cask;
(3) by 150 kg deionized waters, 1.0 kg ethanol, 1.0 kg propylene glycol add respectively in stainless steel cask;
(4) after boiled with big fire, use little fire instead and boil more than two hours, in the time that system gross mass is reduced to 110 kg, stop boiling cooling rear use 600 order filter-cloth filterings; The filtrate of gained, is high concentration (total solids content >=2.5%) Fructus Benincasae Tremella natural juice.
(2) semi-emulsifying half-finished preparation:
Described semi-emulsifying semi-finished product prepare by following technique:
(1) oil phase part preparation: by egg oil 3 kg, Jojoba oil 3 kg, squalane 0.5 kg, vitamin E oil 0.5 kg, ditertbutylparacresol 0.02 kg, add with in the rustless steel still stirring, under the stirring of 30 revs/min of rotating speeds, be heated to 80 DEG C, constant temperature disinfection 20 minutes, be cooled to afterwards 40 DEG C for subsequent use;
(2) water and the preparation of emulsifying agent part: by acrylic acid (ester)
/c10-30 alkylol acrylamide acid esters cross linked polymer 0.18 kg, dispersing and dissolving in the high concentration Fructus Benincasae Tremella natural juice of 40kg, under the stirring of 30 revs/min of rotating speeds, dispersing and dissolving 4 hours;
(3) oil phase above-mentioned steps (1) being obtained under agitation slowly adds in the water that step (2) obtains, after adding, semi-emulsifying homogenizing speed controlling is at 1500 revs/min, scrape wall mixing speed and be controlled at 50 revs/min, the semi-emulsifying time is controlled at 2.0 minutes (emulsifying temperature is 40 DEG C), can obtain semi-emulsifying semi-finished product.
(3) the half-finished preparation of water preparation:
(1) by glycerol 7 kg, amino acid humectant 2 kg, water solublity lanoline 1kg, allantoin 0.2 kg, polyquaternary ammonium salt-39 0.3 2kg, Sargassum rock polysaccharide 1.4 kg and high concentration Fructus Benincasae Tremella natural juice 35 kg, add in the rustless steel still of stirring, heating for dissolving under the stirring of 40 revs/min, constant temperature sterilizing 20 minutes 80-85 DEG C time, afterwards cooling;
(2) while cooling to 50 DEG C, add collagen protein powder 1.8 kg, Mel 2 kg and Margarita hydrolyzed solution 0.7 kg, continue stirring and dissolving and cooling afterwards;
(3) temperature drops to 40 DEG C, after wherein collagen protein powder dissolves completely, is water preparation semi-finished product.
(4) preparation of final products:
(1) the semi-emulsifying semi-finished product part of preparation is added among water preparation semi-finished product part, under the mixing speed of 30 revs/min, stir 1 minute;
(2) add antiseptic: A type solubilising type methyl hydroxybenzoate, ethyl ester, propyl ester mixture (wos-40A, Shanghai Simpson thing Science and Technology Ltd.) 0.5 kg, Type B solubilising type methyl hydroxybenzoate, butyl ester mixture (wos-40B, Shanghai Simpson thing Science and Technology Ltd.) 0.5 kg, mixture 0.1 kg of MIT and butyl carbamic acid 3-iodo-2-propynyl ester and propylene glycol;
(3) add fruit extrait 0.1 kg, under the mixing speed of 20-30 rev/min, stir 3-5 minute afterwards;
(4) add triethanolamine 0.18 kg, stir afterwards 3-5 minute;
(5) before fill, adding the particle diameter after washing and sterilizing is 20/bottle, 4mm Aeschna melanictera pearl.
Embodiment 4
The Fructus Benincasae Mel egg yolk surfactant of the present embodiment, its preparation method comprises the steps:
(1) preparation of high concentration Fructus Benincasae Tremella natural juice:
(1) 100 kg Fructus Benincasaes are first cleaned with tap water, clean with pure water again, afterwards with 75% alcoholic solution sterilization crust, it is the rectangular of 6-7mm × 30-60mm that Exocarpium Benincasae, Fructus Benincasae meat are processed into diameter, Caulis Benincasae (band seed) is cut into the rectangular of 15 × 15 × 30-60mm, adds in stainless steel cask;
(2) 0.3 kg Tremella is first soaked 15 minutes in tap water, clean with pure water again after removing impurity part, be divided into after small pieces with hands, add in stainless steel cask;
(3) by 130 kg deionized waters, 0.8 kg ethanol, 0.8kg propylene glycol adds respectively in stainless steel cask;
(4) after boiled with big fire, use little fire instead and boil more than two hours, in the time that system gross mass is reduced to 100-110 kg, stop boiling cooling rear use 600 order filter-cloth filterings; The filtrate of gained, is high concentration (total solids content >=2.5%) Fructus Benincasae Tremella natural juice.
(2) semi-emulsifying half-finished preparation:
Described semi-emulsifying semi-finished product prepare by following technique:
(1) oil phase part preparation: by egg oil 0.1 kg, Jojoba oil 8kg, squalane 0.1 kg, vitamin E oil 0.5kg, ditertbutylparacresol 0.02 kg, add with in the rustless steel still stirring, under the stirring of rotating speed 20-30 rev/min, be heated to 80-85 DEG C, constant temperature disinfection 20 minutes, be cooled to afterwards 40 DEG C for subsequent use;
(2) water and the preparation of emulsifying agent part: by the ethoxy acrylates/sodium acryloyldimethyl taurate copolymers 0.6kg taking in proportion, dispersing and dissolving is in the high concentration Fructus Benincasae Tremella natural juice of 36.25kg, under the stirring of rotating speed 20-30 rev/min, dispersing and dissolving 4-8 hour;
(3) oil phase above-mentioned steps (1) being obtained under agitation slowly adds in the water that step (2) obtains, and after adding, semi-emulsifying mixing speed is controlled at 60 revs/min, and semi-emulsifying mixing time is controlled at 5 minutes; Can obtain semi-emulsifying semi-finished product.
(3) the half-finished preparation of water preparation:
(1) by glycerol 5kg, amino acid humectant 1kg, water solublity lanoline 1.23kg, allantoin 0.1 kg, polyquaternary ammonium salt-39 0.4kg, Sargassum rock polysaccharide 2.7 kg and high concentration Fructus Benincasae Tremella natural juice 40 kg, add in the rustless steel still of stirring, heating for dissolving under the stirring of 20-40 rev/min, constant temperature sterilizing 20 minutes 80-85 DEG C time, afterwards cooling;
(2) while cooling to 50 DEG C, add collagen protein powder 1.2 kg, Mel 1kg and Margarita hydrolyzed solution 0.4 kg, continue stirring and dissolving and cooling afterwards;
(3) temperature drops to 40 DEG C, after wherein collagen protein powder dissolves completely, is water preparation semi-finished product.
(4) preparation of final products:
(1) the semi-emulsifying semi-finished product part of preparation is added among water preparation semi-finished product part, under the mixing speed of 20-30 rev/min, stir 1-3 minute;
(2) add antiseptic: A type solubilising type methyl hydroxybenzoate, ethyl ester, propyl ester mixture (wos-40A, Shanghai Simpson thing Science and Technology Ltd.) 0.6 kg, Type B solubilising type methyl hydroxybenzoate, butyl ester mixture (wos-40B, Shanghai Simpson thing Science and Technology Ltd.) 0.6 kg, mixture 0.1 kg of MIT and butyl carbamic acid 3-iodo-2-propynyl ester and propylene glycol;
(3) add fruit extrait 0.1 kg, under the mixing speed of 20-30 rev/min, stir 3-5 minute afterwards;
(4) before fill, adding the particle diameter after washing and sterilizing is 5/bottle of 6mm crystal pearls.
Embodiment 5
The Fructus Benincasae Mel egg yolk surfactant of the present embodiment, its preparation method comprises the steps:
(1) preparation of high concentration Fructus Benincasae Tremella natural juice:
(1) 100 kg Fructus Benincasaes are first cleaned with tap water, clean with pure water again, afterwards with 75% alcoholic solution sterilization crust, it is the rectangular of 6-7mm × 30-60mm that Exocarpium Benincasae, Fructus Benincasae meat are processed into diameter, Caulis Benincasae (band seed) is cut into the rectangular of 15 × 15 × 30-60mm, adds in stainless steel cask;
(2) 0.2kg Tremella is first soaked 15 minutes in tap water, clean with pure water again after removing impurity part, be divided into after small pieces with hands, add in stainless steel cask;
(3) by 140 kg deionized waters, 0.6kg ethanol, 0.8kg propylene glycol adds respectively in stainless steel cask;
(4) after boiled with big fire, use little fire instead and boil more than two hours, in the time that system gross mass is reduced to 100-110 kg, stop boiling cooling rear use 600 order filter-cloth filterings; The filtrate of gained, is high concentration (total solids content >=2.5%) Fructus Benincasae Tremella natural juice.
(2) semi-emulsifying half-finished preparation:
Described semi-emulsifying semi-finished product prepare by following technique:
(1) oil phase part preparation: by egg oil 2 kg, Jojoba oil 4kg, squalane 1.5kg, vitamin E oil 0.5kg, ditertbutylparacresol 0.02 kg, add with in the rustless steel still stirring, under the stirring of rotating speed 20-30 rev/min, be heated to 80-85 DEG C, constant temperature disinfection 20 minutes, be cooled to afterwards 40 DEG C for subsequent use;
(2) water and the preparation of emulsifying agent part: by acrylic acid (ester)
/c10-30 alkylol acrylamide acid esters cross linked polymer 0.15 kg, dispersing and dissolving in the high concentration Fructus Benincasae Tremella natural juice of 40 kg, under the stirring of rotating speed 20-30 rev/min, dispersing and dissolving 8 hours;
(3) oil phase above-mentioned steps (1) being obtained under agitation slowly adds in the water that step (2) obtains, after adding, semi-emulsifying homogenizing speed controlling is at 1500 revs/min, scrape wall mixing speed and be controlled at 50 revs/min, the semi-emulsifying time is controlled at 2.0 minutes (emulsifying temperature is 40 DEG C), can obtain semi-emulsifying semi-finished product.
(3) the half-finished preparation of water preparation:
(1) by glycerol 10 kg, amino acid humectant 2kg, water solublity lanoline 0.5 kg, allantoin 0.2 kg, polyquaternary ammonium salt-39 0.6 kg, Sargassum rock polysaccharide 1.9 kg and high concentration Fructus Benincasae Tremella natural juice 30 kg, add in the rustless steel still of stirring, heating for dissolving under the stirring of 20-40 rev/min, constant temperature sterilizing 20 minutes 85 DEG C time, afterwards cooling;
(2) while cooling to 50 DEG C, add collagen protein powder 2 kg, Mel 2kg and Margarita hydrolyzed solution 1.3kg, continue stirring and dissolving and cooling afterwards;
(3) temperature drops to 40 DEG C, after wherein collagen protein powder dissolves completely, is water preparation semi-finished product.
(4) preparation of final products:
(1) the semi-emulsifying semi-finished product part of preparation is added among water preparation semi-finished product part, under the mixing speed of 30 revs/min, stir 3 minutes;
(2) add antiseptic: A type solubilising type methyl hydroxybenzoate, ethyl ester, propyl ester mixture (wos-40A, Shanghai Simpson thing Science and Technology Ltd.) 0.5 kg, Type B solubilising type methyl hydroxybenzoate, butyl ester mixture (wos-40B, Shanghai Simpson thing Science and Technology Ltd.) 0.5 kg, mixture 0.08 kg of MIT and butyl carbamic acid 3-iodo-2-propynyl ester and propylene glycol;
(3) add fruit extrait 0.1kg, under the mixing speed of 20-30 rev/min, stir 3-5 minute afterwards;
(4) add triethanolamine 0.15 kg, stir afterwards 3-5 minute;
(5) before fill, adding the particle diameter after washing and sterilizing is 15/bottle, 5mm Aeschna melanictera pearl.
Embodiment 6
The preparation of the balanced nutritious type Fructus Benincasae of self-control high concentration Tremella natural juice.In natural proportion Fructus Benincasae: dry tremella: pure water: ethanol: the ratio that propylene glycol is 100:0.5:120:1:1 feeds intake.Fructus Benincasae is bought back rear first clean with tap water, more clean with pure water, rear 75% ethanol disinfection of using.Cut afterwards, melon pulp (band seed) part be cut into the rectangular of 15 × 15 × 30-60mm, melon skin melon meat for part grater (a kind of kitchen tools) be processed into diameter 6mm, length 45mm's is rectangular.Dry tremella steep raising afterwash is divided into small pieces with hands again and adds in the lump in stainless steel cask, adds according to the above ratio pure water, ethanol (by straight alcohol) and propylene glycol.After big fire is boiled, uses little fire instead and boil about 2 hours, the mixture of 110 parts of gained is crossed to 600 order filter clothes (can filter at normal temperatures), get final product to obtain 70 parts of Fructus Benincasae Tremella natural juice.
The processing quality control index of the balanced nutritious type Fructus Benincasae of self-control high concentration Tremella natural juice is: while boiling, final boiling point reaches more than 110 DEG C, and system weight is reduced to 110 parts, wherein solid contents >=2.5% of Fructus Benincasae Tremella natural juice leaching.
Semi-emulsifying half-finished preparation.Oil phase component feeds intake by egg oil 0.1kg, Jojoba oil 8 kg, squalane 0.1 kg, vitamin E oil 0.5 kg, ditertbutylparacresol 0.05 kg; water and emulsifying agent part are by Fructus Benincasae Tremella natural juice 33.5 kg, and ethoxy acrylates/sodium acryloyldimethyl taurate copolymers 0.8 kg feeds intake.Oil phase component weighs post-heating to 80-85 DEG C, and constant temperature disinfection 20 minutes, is cooled to room temperature for subsequent use afterwards.Water and emulsifying agent part evenly join the emulsifying agent dry powder of 0.8 kg in the room temperature Fructus Benincasae Tremella natural juice of 33.5 kg, under the speed of agitator of 30 revs/min, soak and dissolve more than four hours, in the time that dispersing and dissolving becomes even translucent colloid, oil phase is added, speed of agitator is raised to 50 revs/min, emulsifying stir after 4 minutes semi-emulsifying semi-finished product.
The preparation of conventional type semi-finished product part: first feed intake in following ratio: glycerol 8 kg, amino acid humectant 3 kg, water solublity lanoline 1.0 kg, allantoin 0.1 kg, polyquaternary ammonium salt-39:1.5 kg, Sargassum rock polysaccharide 4 kg, Fructus Benincasae Tremella natural juice 30 kg.After said components is weighed, under the stirring of 30 revs/min, be heated to 80-85 DEG C, constant temperature disinfection 20 minutes, adds collagen protein powder 1.0 kg, Margarita hydrolyzed solution 2 kg, Mel 5 kg again when then stirring cools to 50 DEG C.Continue while under agitation cooling to 40 DEG C by follow procedure preparation except the final products jade pearl etc.
40 DEG C time, semi-emulsifying semi-finished product are joined in water preparation semi-finished product, stir 3 minutes with the mixing speeds of 30 revs/min, add afterwards the A type solubilising type methyl hydroxybenzoate after solubilising, ethyl ester, propyl ester mixture (wos-40A, Shanghai Simpson thing Science and Technology Ltd.) 0.6 kg, Type B solubilising type methyl hydroxybenzoate, butyl ester mixture (wos-40B, Shanghai Simpson thing Science and Technology Ltd.) 0.6 kg, , add mixture 0.1 kg of another kind of antiseptic MIT and butyl carbamic acid 3-iodo-2-propynyl ester and propylene glycol simultaneously, add fruit extrait 0.05 kg, stir 5 minutes with the mixing speed of 30 revs/min afterwards, after observing collagen protein powder dissolving completely wherein, get final product fill.Before fill, the preparatory technology of jade pearl, agate bead, Aeschna melanictera pearl and crystal ball is as follows:
After jade pearl, agate bead, Aeschna melanictera pearl and the crystal ball that is 8mm by the diameter of customization processing cleaned with pure water, be immersed in 75% alcoholic solution and sterilize, afterwards with the above-mentioned four kinds of pearls of antimagnetic type tweezer gripping after sterilization each one in the water preparation Packaging Bottle after sterilization, last fill aqua product, completes the invention manufacturing process of Fructus Benincasae Mel egg yolk surfactant.
Embodiment 7
The preparation of the balanced nutritious type Fructus Benincasae of self-control high concentration Tremella natural juice.In natural proportion Fructus Benincasae: dry tremella: pure water: ethanol: the ratio that propylene glycol is 100:0.5:120:1:1 feeds intake.Fructus Benincasae is bought back rear first clean with tap water, more clean with pure water, rear 75% ethanol disinfection of using.Cut afterwards, melon pulp (band seed) part be cut into the rectangular of 15 × 15 × 30-60mm, melon skin melon meat for part grater (a kind of kitchen tools) be processed into diameter 6mm, length 30-60mm's is rectangular.Dry tremella steep raising afterwash is divided into small pieces with hands again and adds in the lump in stainless steel cask, adds according to the above ratio pure water, ethanol (by straight alcohol) and propylene glycol.After big fire is boiled, uses little fire instead and boil about 2 hours, the mixture of gained 100-110 part is crossed to 600 order filter clothes (can filter at normal temperatures), get final product to obtain 70 parts of Fructus Benincasae Tremella natural juice.
The processing quality control index of the balanced nutritious type Fructus Benincasae of self-control high concentration Tremella natural juice is: while boiling, final boiling point reaches more than 110 DEG C, and system weight is reduced to 100-110 part, wherein solid contents >=2.5% of Fructus Benincasae Tremella natural juice leaching.
The preparation of semi-emulsifying semi-finished product part, oil phase component feeds intake by egg oil 10 kg, Jojoba oil 0.1 kg, squalane 0.1 kg, ditertbutylparacresol 0.05 kg; Water and emulsifier component are by Fructus Benincasae Tremella natural juice 40 kg, and emulsifying agent acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross linked polymer 0.18 kg feeds intake.Oil phase component weigh after be stirred and heated to 80-85 DEG C, constant temperature sterilizing 20 minutes, be cooled to afterwards 40 DEG C for subsequent use; Water and emulsifier component are by the emulsifying agent dry powder of 0.18 kg, join in the aseptic Fructus Benincasae Tremella of the room temperature natural juice of 40 kg, stir lower immersion more than 4 hours, then oil phase component is added, start 50 revs/min and scrape wall stirring, after 3 minutes, open 1000 revs/min, homogenizing agitator, emulsifying homogeneous after one minute semi-emulsifying semi-finished product.
The preparation of conventional type water preparation semi-finished product part: first feed intake in following ratio: glycerol 8 kg, amino acid humectant 3 kg, water solublity lanoline 1.0 kg, allantoin 0.1 kg, polyquaternary ammonium salt-39:1.0 kg, Sargassum rock polysaccharide 3 kg, Fructus Benincasae Tremella natural juice 26.44 kg; After said components is weighed, under the mixing speed of 30 revs/min, be heated to 80-85 DEG C, constant temperature sterilizing 20 minutes, adds collagen protein powder 1.0 kg, Margarita hydrolyzed solution 1.5 kg, Mel 3 kg when then stirring cools to 50 DEG C; Continue to stir and continue while cooling to after 40 DEG C by follow procedure preparation except the final products jade pearl etc.
40 DEG C time, semi-emulsifying semi-finished product are joined in water preparation semi-finished product system, stir 3 minutes with the mixing speeds of 30 revs/min, add afterwards the A type solubilising type methyl hydroxybenzoate after solubilising, ethyl ester, propyl ester mixture (wos-40A, Shanghai Simpson thing Science and Technology Ltd.) 0.6 kg, Type B solubilising type methyl hydroxybenzoate, butyl ester mixture (wos-40B, Shanghai Simpson thing Science and Technology Ltd.) 0.6 kg, , add mixture 0.1 kg of another kind of antiseptic MIT and butyl carbamic acid 3-iodo-2-propynyl ester and propylene glycol simultaneously, add fruit extrait 0.05 kg, add triethanolamine 0.18 kg, stir 5 minutes with the mixing speed of 30 revs/min afterwards, after observing collagen protein powder dissolving completely wherein, get final product fill.Before fill, the preparatory technology of jade pearl, agate bead, Aeschna melanictera pearl and crystal ball is as follows:
After jade pearl, agate bead, Aeschna melanictera pearl and the crystal ball that is 6mm by the diameter of customization processing cleaned with pure water, be immersed in 75% alcoholic solution and sterilize, afterwards with the above-mentioned four kinds of pearls of antimagnetic type tweezer gripping after sterilization each two in the water preparation Packaging Bottle after sterilization, last fill aqua product, completes the invention manufacturing process of Fructus Benincasae Mel egg yolk surfactant.
Effect embodiment:
One. detection method
The sample preparation of previous embodiment being become to concentration respectively with dimethyl sulfoxide is the concentration of mass volume ratio 1%, carries out following experiment.
The mensuration of ﹙ 1 ﹚ free radical scavenging effect
Extracting sample solution 2ml and concentration are that diphenyl picryl Ben Jing ﹙ DPPH ﹚ solution (solvent of this solution is the to be water) 2ml of 100 u mol/L first adds in same tool plug test tube, shake up, under room temperature, leave standstill 30 minutes, taking solvent as blank, working sample absorbance under 517nm wavelength.
Suppression ratio: k%=[1-(Ai-Aj)/AC] × 100%
The absorbance of Ai:2ml DPPH solution+2ml sample solution
The absorbance of Aj:2ml sample solution+2ml solvent (being dimethyl sulfoxide)
The absorbance of AC:2ml DPPH solution+2ml solvent (being dimethyl sulfoxide)
(3): melanocyte synthetic test in suppressing in mouse melanin cell.
By B16 mouse melanin tumor cell with 1 × 10
5the density of individual/ml is connected to the culture dish that diameter is 9cm, at 37 DEG C ﹑ 5% CO
2condition under cultivate 2 days, abandon supernatant, add the sample solution 18-22ml after filtration sterilization, then cultivate 3 days, abandon supernatant, PBS washing, every hole adds the pancreatin solution peptic cell 3min of 0.5ml mass percent 0.2%, every ware adds 2ml maintenance medium and stops digestion. after piping and druming mixes, every kind of concentration is taken out 0.5ml and is made cell counting. and all the other cell suspension, with the centrifugal 5min of 2500r/min, are abandoned supernatant, in precipitation, add NaoH solution, heating is dissolved melanin, on the enzyme-linked immunosorbent assay instrument of selection 490nm wavelength, surveys absorbance.
Melanin synthesizes suppression ratio=(1-(medicine hole absorbance+medicine porocyte density)+(control wells absorbance+control wells cell density)) × 100%.
(2) detection of moistening effect:
Keratodermatitis hydration rate test: operation principle is taking capacitor as instrument probe, because water is the material of dielectric constant maximum on skin, in the time that skin moisture content changes, the capacitance of skin also changes, so can be by measuring skin capacitance, analyzing skin surface moisture content.Conventional instrument is Cor neometer CM825.Use the variation of product front and back keratodermatitis capacitance to weigh the variation of water content of stratum corneum by measurement, thereby evaluate the moisture-keeping efficacy of cosmetics, this kind of method carried out quantification to the moisture of keratodermatitis, can react delicately the variation of skin moisture content, and favorable reproducibility is one of conventional method of current moisture-keeping cosmetics effect evaluation.
Experimental technique: bend side at candidate left and right forearm and mark 3 × 3cm
2the square Experimental Area of size, the test zone at left arm as moisturizer, the corresponding symmetrical region of right arm is blank, then detect the moisture at each test position with Cor neometer CM825 test, repeat respectively 5 times, draw meansigma methods, by formula (1) calculated hydration rate.
Hydration rate=
test value-blank value× 100%
Blank value
(2) experimental result
(1) mensuration of free radical scavenging effect, result is as shown in table 1:
Table 1
| ? | Suppression ratio (%) |
| Embodiment 1 | 87．2 |
| Embodiment 2 | 88．7 |
| Embodiment 3 | 87．5 |
| Embodiment 4 | 88．3 |
| Embodiment 5 | 88．6 |
| Embodiment 6 | 87．9 |
| Embodiment 7 | 88．4 |
(2) melanocyte synthetic test in suppressing in mouse melanin cell, result is as shown in table 2
Table 2
| ? | Suppression ratio (%) |
| Embodiment 1 | 59．3 |
| Embodiment 2 | 58．9 |
| Embodiment 3 | 60．7 |
| Embodiment 4 | 61．9 |
| Embodiment 5 | 62．0 |
| Embodiment 6 | 60．9 |
| Embodiment 7 | 61．8 |
(3) detection of moistening effect, result is as shown in table 3:
Table 3
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 |
| 1h | 76% | 78% | 78% | 77% | 79% | 76% | 78% |
| 2h | 60% | 60% | 59% | 60% | 61% | 58% | 60% |
| 4h | 39% | 40% | 40% | 38% | 41% | 39% | 40% |
| 6h | 40% | 39% | 40% | 37% | 39% | 40% | 41% |
| 8h | 40% | 40% | 39% | 38% | 39% | 38% | 40% |
Above-mentioned experimental result shows, Fructus Benincasae Tremella egg yolk surfactant of the present invention can effectively be imitated check melanin and be generated, and has the function of removing free radical simultaneously, and moistening effect is remarkable.
Above-described embodiment is preferably embodiment of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other any Gai Bian ﹑ Xiu Shi ﹑ Ti Dai ﹑ Zu He ﹑ doing under spirit of the present invention and principle that do not deviate from simplifies; all should be equivalent substitute mode, within being included in protection scope of the present invention.
Claims (2)
1. a Fructus Benincasae Mel egg yolk surfactant, is characterized in that, its preparation method comprises the steps:
(1) preparation of high concentration Fructus Benincasae Tremella natural juice: described high concentration Fructus Benincasae Tremella natural juice is made up of the raw material of following mass parts: 100 parts, Fructus Benincasae, 0.1 ~ 0.5 part, Tremella, 120 ~ 150 parts of deionized waters, 0.5 ~ 1 part of ethanol, propylene glycol 0.5-1 part;
Described high concentration Fructus Benincasae Tremella natural juice prepares by the following method:
(a) 100 mass parts Fructus Benincasaes are first cleaned with tap water, clean with pure water, with 75% alcoholic solution sterilization crust, it is the rectangular of 6-7mm × 30-60mm that Exocarpium Benincasae, Fructus Benincasae meat are processed into diameter afterwards again, band seed Caulis Benincasae is cut into the rectangular of 15 × 15 × 30-60mm, adds in stainless steel cask;
(b) 0.1-0.5 mass parts Tremella is first soaked 15 minutes in tap water, clean with pure water again after removing impurity part, be divided into after small pieces with hands, add in stainless steel cask;
(c) by 120-150 mass parts deionized water, 0.5-1.0 mass parts ethanol, 0.5-1.0 mass parts propylene glycol adds respectively in stainless steel cask;
(d) after boiled with big fire, use little fire instead and boil more than two hours, in the time that system gross mass is reduced to 100-110 mass parts, stop boiling cooling rear use 600 order filter-cloth filterings; The filtrate of gained, is the high concentration Fructus Benincasae Tremella natural juice of total solids content >=2.5%;
(2) semi-emulsifying half-finished preparation: so that finally the Fructus Benincasae Mel egg yolk surfactant except jade pearl is by 100 parts, described semi-emulsifying semi-finished product are made up of the raw material of following mass parts:
A: oil phase part: egg oil 0.1-10 part, Jojoba oil 0.1-8 part, squalane 0.1-8 part, vitamin E oil 0.1-1.0 part, ditertbutylparacresol 0.01-0.05 part;
B: water and emulsifying agent part: high concentration Fructus Benincasae Tremella natural juice 20-50 part, ethoxy acrylates/sodium acryloyldimethyl taurate copolymers 0.1-2.0 part or acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross linked polymer 0.1-2.0 part;
Described semi-emulsifying semi-finished product prepare by following technique:
(a) oil phase part preparation: after the egg oil of formula ratio, Jojoba oil, squalane, vitamin E oil, ditertbutylparacresol are taken in proportion, add with in the rustless steel still stirring, under the stirring of rotating speed 20-30 rev/min, be heated to 80-85 DEG C, constant temperature disinfection 20 minutes, be cooled to afterwards 40 DEG C for subsequent use;
(b) water and the preparation of emulsifying agent part: by the ethoxy acrylates/sodium acryloyldimethyl taurate copolymers taking in proportion or acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross linked polymer, dispersing and dissolving is in the high concentration Fructus Benincasae Tremella natural juice taking in proportion, under the stirring of rotating speed 20-30 rev/min, dispersing and dissolving 4-8 hour;
(c) oil phase above-mentioned steps (a) being obtained under agitation slowly adds in the water that step (b) obtains, after adding, make emulsifying agent if select ethoxy acrylates/sodium acryloyldimethyl taurate copolymers, semi-emulsifying mixing speed is controlled at 40-60 rev/min, and semi-emulsifying mixing time is controlled at 3-5 minute; Make emulsifying agent if select acrylic acid (ester) class/C10-30 alkylol acrylamide acid esters cross linked polymer, semi-emulsifying homogenizing speed controlling is at 1000-1500 rev/min, scrape wall mixing speed and be controlled at 40-50 rev/min, the semi-emulsifying time is controlled at 0.5-2.0 minute, emulsifying temperature is 40 DEG C, can obtain semi-emulsifying semi-finished product;
(3) the half-finished preparation of water preparation: described water preparation semi-finished product are made up of the raw material of following mass parts: glycerol 5-10 part, amino acid humectant 0.1-5 part, water solublity lanoline 0.1-5 part, allantoin 0.05-0.5 part, polyquaternary ammonium salt-39:0.1-5 part, Sargassum rock polysaccharide 0.1-5 part, Mel 1-10 part, collagen protein powder 0.5-5 part, Margarita hydrolyzed solution 0.1-5 part, high concentration Fructus Benincasae Tremella natural juice 20-40 part;
Described water preparation semi-finished product prepare by following technique:
(a) by the glycerol of formula ratio, amino acid humectant, water solublity lanoline, allantoin, polyquaternary ammonium salt-39, Sargassum rock polysaccharide and high concentration Fructus Benincasae Tremella natural juice, add in the rustless steel still of stirring, heating for dissolving under the stirring of 20-40 rev/min, constant temperature sterilizing 20 minutes 80-85 DEG C time, afterwards cooling;
(b) while cooling to 50 DEG C, add the collagen protein powder of formula ratio, Mel and Margarita hydrolyzed solution, continue stirring and dissolving and cooling afterwards;
(c) temperature drops to 40 DEG C, after wherein collagen protein powder dissolves completely, is water preparation semi-finished product;
(4) preparation of final products: semi-emulsifying semi-finished product prepared by step (2) join among water preparation semi-finished product prepared by step (3), stirs, and adds antiseptic, essence obtain described Fructus Benincasae Mel egg yolk surfactant.
2. Fructus Benincasae Mel egg yolk surfactant according to claim 1, is characterized in that, the preparation of described final products prepares by following technique:
(1) the semi-emulsifying semi-finished product part of preparation is added among water preparation semi-finished product part, under the mixing speed of 20-30 rev/min, stir 1-3 minute;
(2) add antiseptic: 0.6 part of A type solubilising type methyl hydroxybenzoate, ethyl ester, propyl ester mixture, 0.6 part, Type B solubilising type methyl hydroxybenzoate, butyl ester mixture, mixture 0.1-0.8 part of MIT and butyl carbamic acid 3-iodo-2-propynyl ester and propylene glycol;
(3) add fruit extrait 0.01-0.05 part, under the mixing speed of 20-30 rev/min, stir 3-5 minute afterwards;
(4) if select acrylic acid (ester)
/when C10-30 alkyl acrylate cross-linked polymer is made emulsifying agent, still need and add triethanolamine 0.1-2.0 part, stir afterwards 3-5 minute;
(5) before fill, add any one or the multiple 1-30 grain/bottle in jade pearl that the particle diameter after washing and sterilizing is 1-30mm, agate bead, Aeschna melanictera pearl, crystal ball.
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| CN105695182B (en) * | 2016-01-18 | 2019-04-05 | 上海蔚科精细化工有限公司 | A kind of emollient and its application for soap base face cleaning product |
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