CN103202306A - Pesticide composition - Google Patents
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- CN103202306A CN103202306A CN2013101557338A CN201310155733A CN103202306A CN 103202306 A CN103202306 A CN 103202306A CN 2013101557338 A CN2013101557338 A CN 2013101557338A CN 201310155733 A CN201310155733 A CN 201310155733A CN 103202306 A CN103202306 A CN 103202306A
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Abstract
The invention relates to the technical field of pesticides and in particular relates to a pesticide composition. The pesticide composition is characterized by being prepared from 0.1-60 parts of fluazinam and 0.1-20 parts of abamectin by weight. The pesticide composition provided by the embodiment of the invention can be used for killing various pests causing citrus diseases and reduces the drug varieties and drug cost compared with the traditional modes of using various drugs to kill pests respectively.
Description
Technical field
The present invention relates to technical field of pesticide, in particular to Pesticidal combination.
Background technology
Citrus resin disease (broken skin disease) is one of important disease of citrus, because its site of pathological change is different multiple title is arranged, and occurs in the gummosis that is called on trunk and the limb; The disease of infringement storage period fruit is called blossom-end rot or brown blossom-end rot; The disease that occurs on blade and the fruit is called rubber disease or diplostomiasis; Invade the really top blossom-end rot that cries that causes maturing stage centre rot shedding from fruit top umbilical region; The sick type of rubber and gummosis type have the trend that causes harm year by year and increase the weight of in each citrus producing region, have become one of most important fungal disease of citrus.
The disease of the above-mentioned oranges and tangerines of lifting is all caused by various pests; For example, rubber disease, anthracnose, blister mite, two spotted spider mite, leaf miner etc., in each stage of mandarin tree growth, multiple insect pest often takes place simultaneously; At present, aspect the oranges and tangerines pest control, need utilize different medicines to make control at the citrus disease that different insects causes respectively; Namely adopt multiple medicine to prevent and treat citrus disease in batches; But the mode that this multiple medicine is prevented and treated citrus disease has in batches increased cost and difficulty that citrus disease is prevented and treated greatly.
Summary of the invention
The object of the present invention is to provide a kind of Pesticidal combination, to solve the above problems.
A kind of Pesticidal combination is provided in the embodiments of the invention, and its composition comprises: fluazinam 0.1-60 part, Avermectin 0.1-20 part.
The Pesticidal combination of the above embodiment of the present invention, fluazinam in its active ingredient, belong to 2, the 6-dinitroanilines, it is protective fungicide, can prevent and treat the disease that is caused by grey grape born of the same parents, to interlink spore genus, Botrytis, Phytophthora, Plasmopara, Sclerotinia and black to cultivate the Pseudomonas bacterium very effective, concrete disease such as gray mold of cucumber, rot, downy mildew, anthracnose, tomato late blight, apple scab, leaf spot, the pears black spot, rust, paddy rice pain slightly is sick, banded sclerotial blight, the oat hat lures disease, grape grey mould, downy mildew, citrus scab etc.; Concrete mite class such as citrus red mite, China pink are engraved mite, kamisawa tetranychus etc.; Botrytis cinerea to anti-benzimidazole type and dicarboximide class biocide agent also has good result, and simultaneously, fluazinam also has resistance of rainwater washing against, the effect that the lasting period is long; Avermectin is a kind of antibiotics insecticidal/acaricidal agent of efficient, wide spectrum; It is made up of one group of macrolides compound, active substance is Avermectin, mite class and insect had stomach toxicity and action of contace poison, spray leaf surface and can decompose dissipation rapidly, but the active component long period in the infiltration plant parenchyma is present in the tissue and has conduction, and the insect of getting food harm in evil mite and the plant tissue is had long residual effect; Main controlling object have paddy stem borer, striped rice borer, rice leaf roller, prodenia litura, tomato moth, aphid, diamond-back moth, Americal rice leaf miner, Oeobia undalis, Liriomyza, two spotted spider mite, Panonychus citri, blister mite, mite, heart-eating worm; After the above-mentioned two kinds of medicines of set ratio binary built, the various pests that can cause citrus disease had tangible synergistic insecticidal action, and it is anti-high, especially can reach more than 95% the citrus red mite preventive effect, by both the composition of the binary built of certainty ratio can be simultaneously for the multiple damage by disease and insect of control; Therefore, in the process of control oranges and tangerines insect pest, above-mentioned a kind of composition can be used for killing the multiple insect that causes citrus disease, and the multiple medicine of the more traditional use mode of desinsection is respectively compared, and has reduced types of medicines, has reduced drug cost.
Embodiment
Below by specific embodiment the present invention is described in further detail.
Embodiment one
The Pesticidal combination that the embodiment of the invention one provides, according to the parts by weight meter, its active ingredient comprises: fluazinam 0.1-60 part, Avermectin 0.1-20 part.
The Pesticidal combination of above-described embodiment, fluazinam in its active ingredient, belong to 2, the 6-dinitroanilines, it is protective fungicide, can prevent and treat the disease that is caused by grey grape born of the same parents, to interlink spore genus, Botrytis, Phytophthora, Plasmopara, Sclerotinia with black to cultivate the Pseudomonas bacterium very effective, concrete disease such as gray mold of cucumber, rot, downy mildew, anthracnose, tomato late blight, apple scab, leaf spot, pears black spot, rust, paddy rice be sick, the banded sclerotial blight of pain slightly, and the oat hat lures disease, grape grey mould, downy mildew, citrus scab etc.; Concrete mite class such as citrus red mite, China pink are engraved mite, kamisawa tetranychus etc.; Botrytis cinerea to anti-benzimidazole type and dicarboximide class biocide agent also has good result, and fluazinam is gone back resistance of rainwater washing against simultaneously, and the lasting period is long; Avermectin is a kind of antibiotics insecticidal/acaricidal agent of efficient, wide spectrum; It is made up of one group of macrolides compound, active substance is Avermectin, mite class and insect had stomach toxicity and action of contace poison, spray leaf surface and can decompose dissipation rapidly, but the active component long period in the infiltration plant parenchyma is present in the tissue and has conduction, and the insect of getting food harm in evil mite and the plant tissue is had long residual effect; Main controlling object have paddy stem borer, striped rice borer, rice leaf roller, prodenia litura, tomato moth, aphid, diamond-back moth, Americal rice leaf miner, Oeobia undalis, Liriomyza, two spotted spider mite, Panonychus citri, blister mite, mite, heart-eating worm; After the above-mentioned two kinds of medicines of set ratio binary built, the various pests that can cause citrus disease had tangible synergistic insecticidal action, and it is anti-high, especially can reach more than 95% the citrus red mite preventive effect, by both the composition of the binary built of certainty ratio can be simultaneously for the multiple damage by disease and insect of control; Therefore, in the process of control oranges and tangerines insect pest, above-mentioned a kind of composition can be used for killing the multiple insect that causes citrus disease, and the multiple medicine of the more traditional use mode of desinsection is respectively compared, and has reduced types of medicines, has reduced drug cost.
In order to make the composition of above-described embodiment can better play the effect of desinsection, the present invention also provides following examples, and following embodiment is further increase and the restriction of making on the basis of embodiment one, now makes detailed explanation and elaboration:
On the basis of embodiment one, also comprise: one or more in dispersant 0.1-15 part, emulsifier 0.1-12 part, antifreezing agent 0.1-4 part, thickener 0.1-4 part, defoamer 0.1-2 part, solvent 10-99.7 part, wetting agent 0.1-15 part, disintegrant 0.1-6 part and filler 3-97.5 part.
Further, for the Pesticidal combination that makes the embodiment of the invention provide can be realized purposes more widely, concrete, composition can be made multiple formulation, optionally, the formulation of described composition is suspending agent, aqueous emulsion, water dispersible granules, microemulsion, wetting powder or missible oil formulation;
Simultaneously, it should be noted that multiple auxiliary agents such as the dispersant in the present embodiment, emulsifier, antifreezing agent, thickener, defoamer, solvent, wetting agent, disintegrant and filler all can specifically comprise multiple composition; Now make following specifying;
Concrete, described emulsifier is one or more in calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, styryl phenol APEO, polyoxyethylene nonylphenol ether, polyoxyethylene nonylphenol ether phosphate, aliphatic acid polyethenoxy base ester, polyoxyethylene aliphatic alcohol ether, alkyl polyoxyethylene sulfate salt, the phenethyl phenol polyethenoxy ether;
Described solvent can be in dimethylbenzene, diesel oil, toluene, cyclohexanol, methyl alcohol, vegetable oil, turpentine oil, solvent naphtha, dimethyl formamide, ethanol, N-pyrrolidones, ethyl acetate, the water equal solvent any one or more;
Wetting agent can be lauryl sodium sulfate, calcium dodecyl benzene sulfonate, methyl naphthalene sulfonate formaldehyde condensate, draw back in powder, alkylnaphthalene sulfonate, the spaonin powder etc. one or more;
Dispersant can be one or more in sodium lignin sulfonate, calcium lignosulfonate, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, alkylphenol polyoxyethylene, polycarboxylate, aliphatic amine polyoxyethylene ether, the glycerine fatty acid fat acid esters APEO;
Antifreezing agent can be one or more in ethylene glycol, propane diols, glycerine, the urea; Thickener can be one or more in xanthans, Magnesiumaluminumsilicate, CMC, the polyvinyl alcohol;
Defoamer is one or more in silicone oil, C8-10 aliphatic alcohols compound, the C10-20 saturated fat acid compounds;
Disintegrant can be one or more in bentonite, ammonium sulfate, succinic acid, sodium bicarbonate, aluminium chloride, the succinic acid;
Filler can be one or more in white carbon, kaolin, diatomite, precipitated calcium carbonate, the starch.
Embodiment two
When the formulation of described Pesticidal combination was suspending agent, its component comprised: fluazinam 0.1-50 part, Avermectin 0.1-10 part, dispersant 0.1-10 part, emulsifier 0.1-10 part, antifreezing agent 0.1-4 part, thickener 0.1-4 part, defoamer 0.1-2 part, solvent 10-99.3 part.
Embodiment three
When the formulation of described Pesticidal combination was aqueous emulsion, its component comprised: fluazinam 0.1-50 part, Avermectin 0.1-5 part, dispersant 0.1-10 part, emulsifier 0.1-10 part, antifreezing agent 0.1-4 part, solvent 21-99.5 part.
Embodiment four
When the formulation of described Pesticidal combination was water dispersible granules, its component comprised: fluazinam 0.1-50 part, Avermectin 0.1-5 part, dispersant 0.1-10 part, emulsifier 0.1-10 part, wetting agent 0.1-10 part, disintegrant 0.1-6 part, thickener 0.1-4 part, defoamer 0.1-2 part, filler 3-92 part.
Embodiment five
When the formulation of described Pesticidal combination was microemulsion, its component comprised: fluazinam 0.1-30 part, Avermectin 0.1-5 part, dispersant 0.1-15 part, wetting agent 0.1-15 part, antifreezing agent 0.1-4 part, solvent 31-99.5 part.
Embodiment six
When the formulation of described Pesticidal combination was missible oil, its component comprised: fluazinam 0.1-40 part, Avermectin 0.1-10 part, emulsifier 0.1-12 part, solvent 38-99.7 part;
Perhaps, when the formulation of described Pesticidal combination was wetting powder, its component comprised: fluazinam 0.1-50 part, Avermectin 0.1-10 part, dispersant 0.1-10 part, wetting agent 0.1-10 part, filler 20-99.6%.
Above-described embodiment has provided contained auxiliary agent kind and the umber of composition according to the different formulation of composition, concrete, in the process of configuration, can choose the concrete weight of various components, obtain following specific embodiment, embodiment seven to embodiment 12 has listed concrete formulation and the manufacturing process thereof of composition of the present invention:
Embodiment seven: take by weighing fluazinam 50g, Avermectin 0.8g, lignin sulfonic acid sodium salt 2g, polyoxyethylene nonylphenol ether 4g, Magnesiumaluminumsilicate 1g, ethylene glycol 4g, silicone oil 0.2g, Jia Shui complement to 100g; Above raw material is mixed shearing, makes 50.8% fluazinam Avermectin suspending agent under the effect of sand mill.
In order to detect the insecticidal effect of composition of the present invention, now enumerate following experimental data:
Take by weighing fluazinam 50g, Avermectin 0.8g, lignin sulfonic acid sodium salt 2g, alkylphenol polyoxyethylene formaldehyde condensation products sulphate 4g, Magnesiumaluminumsilicate 1g, ethylene glycol 4g, silicone oil 0.2g, Jia Shui complement to 100g; Above raw material is mixed shearing, under the effect of sand mill, make 50.8% fluazinam Avermectin suspending agent.To dilute 2500 times, 2000 times and 1500 times respectively by the made product of above proportioning, 500 grams per liter fluazinam suspending agents, 1.8% abamectin emulsifiable concentrate control citrus red mite, the control phyllocnistis citrella stainton dilutes 3000 times, 2000 times and 2000 times respectively, and control oranges and tangerines blister mite dilutes 6000 times, 3000 times and 4000 times respectively and carries out the test of pesticide effectiveness; To dilute 2500 times, 2500 times and 1500 respectively and carry out the test of pesticide effectiveness by the made product of above proportioning, 500 grams per liter fluazinam suspending agents, 10% Flusilazole aqueous emulsion control oranges and tangerines rubber disease, anthracnose, every test of pesticide effectiveness data see Table 1-table 5.
Table 1 50.8% fluazinam Avermectin suspending agent control citrus red mite test of pesticide effectiveness result
| Handle | Behind the medicine 1 day | Behind the medicine 7 days | Behind the medicine 15 days | Behind the medicine 30 days |
| 1 | 86.3% | 95.0% | 97.8% | 99.8% |
| 500 grams per liter fluazinam suspending agents | 79.1% | 82.6% | 85.1% | 87.6% |
| 1.8% abamectin emulsifiable concentrate | 60.7% | 80.2% | 81.3% | 85.9% |
Table 2 50.8% fluazinam Avermectin suspending agent control oranges and tangerines blister mite test of pesticide effectiveness result
| Handle | Behind the medicine 1 day | Behind the medicine 7 days | Behind the medicine 14 days | Behind the medicine 28 days |
| 2 | 90.6% | 96.0% | 95.2% | 91.4% |
| 500 grams per liter fluazinam suspending agents | 83.3% | 92.6% | 89.8% | 82.9% |
| 1.8% abamectin emulsifiable concentrate | 76.7% | 89.2% | 84.3% | 77.5% |
Table 3 50.8% fluazinam Avermectin suspending agent control phyllocnistis citrella stainton test of pesticide effectiveness result
| Handle | Behind the medicine 3 days | Behind the medicine 7 days |
| 3 | 85.3% | 96.0% |
| 500 grams per liter fluazinam suspending agents | 66.8% | 92.6% |
| 1.8% abamectin emulsifiable concentrate | 72.6% | 89.2% |
Table 4 50.8% fluazinam Avermectin suspending agent control citrus anthracnose test of pesticide effectiveness result
The sick test of pesticide effectiveness result of table 5 50.8% fluazinam Avermectin suspending agent control oranges and tangerines rubber
By above-mentioned experiment as can be seen, 50.8% fluazinam Avermectin suspending agent of the embodiment of the invention seven has preventive effect preferably to different types of oranges and tangerines insect at different growth periods.
Embodiment eight: take by weighing fluazinam 10g, Avermectin 1.0g, calcium dodecyl benzene sulfonate 5g, alkyl benzene sulfonate calcium salt 3g, ethylene glycol 5g, cyclohexanol 10g, toluene 5g, add water to 100g.Emulsifier and water are mixed and made into water, add former medicine and stir, make 11% fluazinam avermectin micro-emulsion.
Embodiment nine: take by weighing fluazinam 40g, Avermectin 2g, alkylphenol polyoxyethylene 5g, styryl phenol APEO 2g, ethylene glycol 3g, dimethylbenzene 8g, Jia Shui complement to 100g.Above raw material is mixed stirring and dissolving, add emulsifier and shear, make 42% Avermectin fluazinam aqueous emulsion.
Embodiment ten: take by weighing fluazinam 15g, Avermectin 5g, polyoxyethylene nonylphenol ether phosphate 3g, phenethyl phenol polyethenoxy ether 5g, dimethylbenzene 8g, turpentine oil adds to 100g.The method that above raw material is prepared missible oil routinely drops in the mixing kettle mixes, and makes 20% fluazinam abamectin emulsifiable concentrate.
Embodiment 11: take by weighing fluazinam 30g, Avermectin 5g, sodium lignin sulfonate 8g, alkylphenol polyoxyethylene 3g, polycarboxylate 2g, ammonium sulfate 5g, draw back powder 4g, aluminium-magnesium silicate 1g, diatomite is mended to 100g, above raw material is mixed pulverizing, make 35% fluazinam Avermectin water dispersible granules through granulation.
Embodiment 12: take by weighing fluazinam 50g, Avermectin 3g, sodium lignin sulfonate 10g, calcium dodecyl benzene sulfonate 7g, add to 100g with kaolin; Above raw material is mixed ultramicro grinding, make 53% fluazinam Avermectin wetting powder.
Pesticidal combination of the present invention can be prevented and treated multiple citrus disease, for example, rubber disease, anthracnose, blister mite, two spotted spider mite, leaf miner etc., concrete, now enumerate this composition to experimentation and the result of the Toxicity Determination of oranges and tangerines resin disease (broken skin disease) and citrus red mite, please refer to following content:
1, composition of the present invention is to the Toxicity Determination of oranges and tangerines resin disease (broken skin disease):
The mycelial growth rate method is adopted in test, getting experiment soup that 5ml prepares joins the hot medium of 45ml (PDA medium is housed, 45-50 ℃) conical flask in, after shaking up, pour diameter 90mm glass culture dish rapidly into, each culture dish is poured band medicine medium 12ml into, and each handles 4 repetitions, level leaves standstill, cooling back flat board.Cut bacterium cake from what cultivate 4d for examination bacterium edge with diameter 5mm card punch, receive and be with on the malicious medium with choosing one side that pin will have a mycelia, all operations all carries out sterile working at superclean bench.After the processing flat board is placed on and adopts the right-angled intersection method to measure the colony diameter that each is handled respectively after cultivating 4d in 20 ℃ the constant temperature aseptic culture case, calculate the mean value of respectively handling colony diameter, average clean amount of growth and the mycelial growth inhibition rate of colony diameter.
The clean amount of growth of bacterium colony (mm)=colony diameter-5
Mycelial growth inhibition rate (%)=((the clean amount of growth of the contrast bacterium colony-clean amount of growth of processing bacterium colony)/clean amount of growth of contrast bacterium colony) * 100
Concentration conversion is become the natural logrithm value, and inhibiting rate conversion arcsin function value is dependent variable with arcsine letter replacement value, be independent variable with dosage natural logrithm value, carry out linear regression analysis with the DPS Biological Statistic Analysis Software, draw regression equation, carry out anti-natural logrithm conversion again and draw EC50; Calculate toxicity index and the co-toxicity coefficient (CTC) of medicament according to the abundant method of Sun Yun.
Actual measurement toxicity index=standard medicament EC50/ reagent agent EC50 * 100; The theoretical toxicity index of the single agent=single agent actual measurement toxicity index * content of single agent in mixture; The theoretical toxicity index of the mixture=theoretical toxicity index sum of each single agent; The theoretical toxicity index of toxicity index/mixture * 100 of co-toxicity coefficient=mixture actual measurement; Evaluation criterion: CTC≤80 are antagonism, and 80＜CTC＜120 are summation action, and CTC 〉=120 are synergistic effect, and experimental result please refer to table 6;
Table 6: the co-toxicity coefficient of the toxicity index of each medicament and A Wei fluazinam
| Reagent agent | Proportioning | EC 50（mg/kg） | Co-toxicity coefficient |
| Avermectin | - | 10.74 | - |
| Fluazinam | - | 0.89 | - |
| Avermectin: fluazinam | 1：60 | 0.60 | 137.5 |
| Avermectin: fluazinam | 1：50 | 0.59 | 141.6 |
| Avermectin: fluazinam | 1：40 | 0.55 | 187.1 |
| Avermectin: fluazinam | 1：30 | 0.65 | 235.6 |
| Avermectin: fluazinam | 1：15 | 0.38 | 284.3 |
| Avermectin: fluazinam | 1：1 | 0.77 | 303.2 |
| Avermectin: fluazinam | 5：1 | 1.88 | 338.4 |
| Avermectin: fluazinam | 10：1 | 2.76 | 260.21 |
| Avermectin: fluazinam | 15：1 | 5.14 | 232.16 |
| Avermectin: fluazinam | 20：1 | 5.63 | 159.7 |
The experimental result of table 6 shows that fluazinam and Avermectin are composite by mass ratio 1:60-20:1, and oranges and tangerines resin disease (broken skin disease) is all had synergistic effect, and when especially proportioning was between 1:50-10:1, synergy was more remarkable.
2, composition of the present invention is to the Toxicity Determination of citrus red mite:
The slide infusion process that test adopts FAO (Food and Agriculture Organization of the United Nation) (FAO) to recommend.The female one-tenth mite of 20 work of every slide inoculation, the row concentration value of setting up departments on the basis of 3 preliminary experimenies, the clear water contrast, every processing repeats (totally 60 female one-tenth mites) 3 times.Soak medicine and blot with blotting paper immediately after 5 seconds, put into 24-26 ℃ of insulating box then, 48 hours inspection lethality behind the medicine, calculation correction lethality.
Concentration conversion is become the natural logrithm value, corrected mortality is converted into the arcsine transformation value, is dependent variable with the arcsine transformation value again, is independent variable with dosage natural logrithm value, carry out linear regression analysis with the DPS Biological Statistic Analysis Software, draw the toxicity regression linear equation of each medicament.Obtain corrected mortality arcsine transformation value (y) according to the toxicity regression linear equation of each medicament, draw the EC50 value by looking into antilogarithm table, calculate toxicity index and the co-toxicity coefficient (CTC) of medicament again according to the abundant method of Sun Yun.
Actual measurement toxicity index=standard medicament EC50/ reagent agent EC50 * 100
The theoretical toxicity index of the single agent=single agent actual measurement toxicity index * content of single agent in mixture
The theoretical toxicity index of the mixture=theoretical toxicity index sum of each single agent
The theoretical toxicity index of toxicity index/mixture * 100 of co-toxicity coefficient=mixture actual measurement
Evaluation criterion: CTC≤80 are antagonism, and 80＜CTC＜120 are summation action, and CTC 〉=120 are synergistic effect, and experimental result please refer to table 7:
Table 7: the co-toxicity coefficient of the toxicity index of each medicament and Avermectin fluazinam
| Reagent agent | Proportioning | EC 50（mg/kg） | Co-toxicity coefficient |
| Avermectin | -- | 8.16 | - |
| Fluazinam | -- | 0.91 | - |
| Avermectin: fluazinam | 1：60 | 0.84 | 135.1 |
| Avermectin: fluazinam | 1：50 | 0.68 | 197. |
| Avermectin: fluazinam | 1：40 | 0.66 | 190.5 |
| Avermectin: fluazinam | 1：30 | 0.54 | 186.2 |
| Avermectin: fluazinam | 1：15 | 0.36 | 210.3 |
| Avermectin: fluazinam | 1：1 | 0.73 | 197.5 |
| Avermectin: fluazinam | 5：1 | 1.38 | 189.6 |
| Avermectin: fluazinam | 10：1 | 1.92 | 215.7 |
| Avermectin: fluazinam | 15：1 | 2.44 | 203.4 |
| Avermectin: fluazinam | 20：1 | 5.17 | 142.3 |
The experimental result of table 7 shows that fluazinam and Avermectin are composite by mass ratio 1:60～20:1, and citrus red mite is all had synergistic effect, and when especially proportioning was between 1:50～10:1, synergy was more remarkable.
The above is the preferred embodiments of the present invention only, is not limited to the present invention, and for a person skilled in the art, the present invention can have various changes and variation.Within the spirit and principles in the present invention all, any modification of doing, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. Pesticidal combination is characterized in that, according to the parts by weight meter, its composition comprises: fluazinam 0.1-60 part, Avermectin 0.1-20 part.
2. Pesticidal combination according to claim 1 is characterized in that, according to the parts by weight meter, its active ingredient comprises: fluazinam 0.1-50 part, Avermectin 0.1-10 part.
3. Pesticidal combination according to claim 1 and 2, it is characterized in that, also comprise: one or more in dispersant 0.1-15 part, emulsifier 0.1-12 part, antifreezing agent 0.1-4 part, thickener 0.1-4 part, defoamer 0.1-2 part, solvent 10-99.7 part, wetting agent 0.1-15 part, disintegrant 0.1-6 part and filler 3-97.5 part.
4. Pesticidal combination according to claim 3 is characterized in that, the formulation of described Pesticidal combination is suspending agent, aqueous emulsion, water dispersible granules, microemulsion, wetting powder or missible oil formulation.
5. Pesticidal combination according to claim 3, it is characterized in that described emulsifier is one or more in calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, styryl phenol APEO, polyoxyethylene nonylphenol ether, polyoxyethylene nonylphenol ether phosphate, aliphatic acid polyethenoxy base ester, polyoxyethylene aliphatic alcohol ether, alkyl polyoxyethylene sulfate salt, the phenethyl phenol polyethenoxy ether;
Described solvent be in dimethylbenzene, diesel oil, toluene, cyclohexanol, methyl alcohol, vegetable oil, turpentine oil, solvent naphtha, dimethyl formamide, ethanol, N-pyrrolidones, ethyl acetate, the water equal solvent one or more;
Described wetting agent is lauryl sodium sulfate, calcium dodecyl benzene sulfonate, methyl naphthalene sulfonate formaldehyde condensate, draw back in powder, alkylnaphthalene sulfonate, the spaonin powder etc. one or more;
Described dispersant is one or more in sodium lignin sulfonate, calcium lignosulfonate, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, alkylphenol polyoxyethylene, polycarboxylate, aliphatic amine polyoxyethylene ether, the glycerine fatty acid fat acid esters APEO;
Described antifreezing agent is one or more in ethylene glycol, propane diols, glycerine, the urea;
Described thickener is one or more in xanthans, Magnesiumaluminumsilicate, CMC, the polyvinyl alcohol;
Described defoamer is one or more in silicone oil, C8-10 aliphatic alcohols compound, the C10-20 saturated fat acid compounds;
Described disintegrant is one or more in bentonite, ammonium sulfate, succinic acid, sodium bicarbonate, aluminium chloride, the succinic acid;
Described filler is one or more in white carbon, kaolin, diatomite, precipitated calcium carbonate, the starch.
6. Pesticidal combination according to claim 5, it is characterized in that, when the formulation of described composition was suspending agent, its component comprised: fluazinam 0.1-50 part, Avermectin 0.1-10 part, dispersant 0.1-10 part, emulsifier 0.1-10 part, antifreezing agent 0.1-4 part, thickener 0.1-4 part, defoamer 0.1-2 part, solvent 10-99.3 part.
7. Pesticidal combination according to claim 5, it is characterized in that, when the formulation of described Pesticidal combination was aqueous emulsion, its component comprised: fluazinam 0.1-50 part, Avermectin 0.1-5 part, dispersant 0.1-10 part, emulsifier 0.1-10 part, antifreezing agent 0.1-4 part, solvent 21-99.5 part.
8. Pesticidal combination according to claim 5, it is characterized in that, when the formulation of described Pesticidal combination was water dispersible granules, its component comprised: fluazinam 0.1-50 part, Avermectin 0.1-5 part, dispersant 0.1-10 part, emulsifier 0.1-10 part, wetting agent 0.1-10 part, disintegrant 0.1-6 part, thickener 0.1-4 part, defoamer 0.1-2 part, filler 3-92 part.
9. Pesticidal combination according to claim 5, it is characterized in that, when the formulation of described Pesticidal combination was microemulsion, its component comprised: fluazinam 0.1-30 part, Avermectin 0.1-5 part, dispersant 0.1-15 part, wetting agent 0.1-15 part, antifreezing agent 0.1-4 part, solvent 31-99.5 part.
10. Pesticidal combination according to claim 5 is characterized in that, when the formulation of described Pesticidal combination was emulsifiable concentrate, its component comprised: fluazinam 0.1-40 part, Avermectin 0.1-10 part, emulsifier 0.1-12 part, solvent 38-99.7 part;
Or,
When the formulation of described Pesticidal combination was wetting powder, its component comprised:
Fluazinam 0.1-50 part, Avermectin 0.1-10 part, dispersant 0.1-10 part, wetting agent 0.1-10 part, filler 20-99.6%.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103651523A (en) * | 2013-12-06 | 2014-03-26 | 济南凯因生物科技有限公司 | Water dispersible granules containing phthalthrin and application |
| CN105145580A (en) * | 2015-07-31 | 2015-12-16 | 京博农化科技股份有限公司 | Anti-mite composition |
| CN105794802A (en) * | 2016-04-16 | 2016-07-27 | 广东中迅农科股份有限公司 | Pesticide composition containing fluazinam and emamectin benzoate |
| RU2636524C2 (en) * | 2015-05-21 | 2017-11-27 | Сяоми Инк. | Method, device and system of administration communication control between account and device |
| CN110800741A (en) * | 2019-12-06 | 2020-02-18 | 李玉洁 | Efficient pesticide for preventing and treating field red spiders and preparation method thereof |
| CN111528221A (en) * | 2020-04-29 | 2020-08-14 | 辽宁省林业发展服务中心 | Nematicide taking turpentine as carrier and application thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651523A (en) * | 2013-12-06 | 2014-03-26 | 济南凯因生物科技有限公司 | Water dispersible granules containing phthalthrin and application |
| RU2636524C2 (en) * | 2015-05-21 | 2017-11-27 | Сяоми Инк. | Method, device and system of administration communication control between account and device |
| CN105145580A (en) * | 2015-07-31 | 2015-12-16 | 京博农化科技股份有限公司 | Anti-mite composition |
| CN105794802A (en) * | 2016-04-16 | 2016-07-27 | 广东中迅农科股份有限公司 | Pesticide composition containing fluazinam and emamectin benzoate |
| CN110800741A (en) * | 2019-12-06 | 2020-02-18 | 李玉洁 | Efficient pesticide for preventing and treating field red spiders and preparation method thereof |
| CN111528221A (en) * | 2020-04-29 | 2020-08-14 | 辽宁省林业发展服务中心 | Nematicide taking turpentine as carrier and application thereof |
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| Publication number | Publication date |
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| CN103202306B (en) | 2014-04-02 |
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