CN103194911B - Mosquito-repellent fabric and preparation method thereof - Google Patents
Mosquito-repellent fabric and preparation method thereof Download PDFInfo
- Publication number
- CN103194911B CN103194911B CN201310151432.8A CN201310151432A CN103194911B CN 103194911 B CN103194911 B CN 103194911B CN 201310151432 A CN201310151432 A CN 201310151432A CN 103194911 B CN103194911 B CN 103194911B
- Authority
- CN
- China
- Prior art keywords
- polyurethane
- fabric
- mosquito
- preparation
- mosquito repellent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 77
- 239000000077 insect repellent Substances 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 title description 2
- 239000004814 polyurethane Substances 0.000 claims abstract description 83
- 229920002635 polyurethane Polymers 0.000 claims abstract description 83
- 239000003094 microcapsule Substances 0.000 claims abstract description 76
- 239000011248 coating agent Substances 0.000 claims abstract description 27
- 238000000576 coating method Methods 0.000 claims abstract description 27
- 239000002245 particle Substances 0.000 claims abstract description 23
- 239000004816 latex Substances 0.000 claims abstract description 20
- 229920000126 latex Polymers 0.000 claims abstract description 20
- 239000002917 insecticide Substances 0.000 claims abstract description 8
- 239000000839 emulsion Substances 0.000 claims description 23
- 239000000575 pesticide Substances 0.000 claims description 22
- 239000007788 liquid Substances 0.000 claims description 21
- 239000002562 thickening agent Substances 0.000 claims description 19
- 239000011159 matrix material Substances 0.000 claims description 17
- 239000007864 aqueous solution Substances 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 14
- 239000003995 emulsifying agent Substances 0.000 claims description 12
- 238000006068 polycondensation reaction Methods 0.000 claims description 10
- 239000000853 adhesive Substances 0.000 claims description 9
- 230000001070 adhesive effect Effects 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000002270 dispersing agent Substances 0.000 claims description 8
- 238000001556 precipitation Methods 0.000 claims description 8
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 claims description 6
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 claims description 6
- 239000002728 pyrethroid Substances 0.000 claims description 6
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical group CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 5
- 235000010413 sodium alginate Nutrition 0.000 claims description 5
- 239000000661 sodium alginate Substances 0.000 claims description 5
- 229940005550 sodium alginate Drugs 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims 1
- 241000255925 Diptera Species 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000008367 deionised water Substances 0.000 description 12
- 229910021641 deionized water Inorganic materials 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 229920000742 Cotton Polymers 0.000 description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000005406 washing Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000001846 repelling effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- -1 polyoxyethylene nonylphenol Polymers 0.000 description 2
- 241000256173 Aedes albopictus Species 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 201000004792 malaria Diseases 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a mosquito-repellent fabric in the field of outdoor goods. The mosquito-repellent fabric comprises a base fabric and a polyurethane microcapsule coating positioned on the base fabric, wherein the polyurethane microcapsule coating is made of polyurethane microcapsules, and each polyurethane microcapsule comprises the raw materials of polyurethane latex particles and insecticide coated in the polyurethane latex particles. The fabric has the technical effects that the insecticide can be slowly released, the mosquito repellence effect is good, the service life is long, after the mosquito-repellent fabric is washed repeatedly, the mosquito repellence effect can not be obviously reduced, and no damage to a human body is easily caused. The invention further discloses a preparation method for the mosquito-repellent fabric in the field of outdoor goods. The preparation method comprises the following steps of: preparing the polyurethane microcapsules, preparing the microcapsule finishing liquor and coating.
Description
Technical field
The present invention relates to a kind of mosquito repellent fabric in outdoor goods field and a kind of preparation method of mosquito repellent fabric.
Background technology
All there is the puzzlement of mosquito countries in the world, China's located in subtropical zone.This problem is also quite outstanding.Meanwhile, the disseminator of mosquito or malaria and some other pathogen.Thereby it is very urgent finding a kind of suitable, effective mosquito repellent means.The World Health Organization once proposed with pesticide Impregnated Mosquito Nets, can only be passive prevent mosquito invasion.And the insecticidal effect of employing infusion method fabric is held time shorter, after washing, drug effect significantly declines, and must soak again.So not only bothered but also many consumption medicaments, efficiency is low, and easily contaminated environment, also has potential infringement to human body.
Summary of the invention
The object of the invention is, in order to overcome the deficiencies in the prior art, provides a kind of mosquito repellent fabric, and it can be controlled pesticide and carry out mosquito expelling in its surperficial rate of release, has good durability and repelling effect, and is difficult for human body to cause damage.Correspondingly, the present invention also provides a kind of preparation method of mosquito repellent fabric.
A kind of technical scheme that realizes above-mentioned purpose is: a kind of mosquito repellent fabric, comprise matrix fabric and the polyurethane microcapsule coating that is positioned at described matrix fabric upper surface, described polyurethane microcapsule coating consists of polyurethane microcapsule, described polyurethane microcapsule is by polyurethane latex particle, and is coated on that pesticide in described polyurethane latex particle forms.
Further, described pesticide is pyrethroid insecticides.
Further, described matrix fabric is pure-cotton fabric, pure pitted skin material, polyester fabric, acrylic fabric or nylon facing material.
Another technical scheme that realizes above-mentioned purpose is: a kind of preparation method of mosquito repellent fabric, comprises the following steps:
Polyurethane microcapsule preparation process: take polyethylene glycol and vulcabond as raw material, carry out emulsion polycondensation, and in the process of emulsion polycondensation, add pesticide and dispersant, obtain polyurethane microcapsule, described polyurethane microcapsule is by polyurethane latex particle, and is coated on that pesticide in described polyurethane latex particle forms;
Microcapsules dressing liquid preparation process: after the preparation thickener DRA aqueous solution, by polyurethane microcapsule and adhesive beta-schardinger dextrin-, add the described thickener DRA aqueous solution, stir, obtain microcapsules dressing liquid;
Coating step: after the above microcapsules dressing liquid of the upper surface blade coating of matrix fabric, dry at 85 ℃, then bake at 110-120 ℃, then wash at 80～90 ℃, finally again dry at 85 ℃, obtain mosquito repellent fabric.
Further, in described polyurethane microcapsule preparation process, first prepare the emulsion that OP10 emulsifier concentration is 2g/L, in the described emulsion of every 1000ml, add the PEG400 of 15g, the dispersant of the vulcabond of 3g, 3g and the pesticide of 15～25g again, then under the reaction temperature of the stir speed (S.S.) of 1000r/min and 70 ℃, carry out the emulsion polycondensation of 1.5h, finally naturally lower the temperature, and after being naturally cooled to room temperature standing 24h, obtain the precipitation of polyurethane microcapsule.
Further, described vulcabond is hexamethylene diisocyanate, toluene di-isocyanate(TDI) or methyl diphenylene diisocyanate.
Further, described dispersant is sodium alginate.
Further, described pesticide is pyrethroid insecticides.
Further, in described microcapsules dressing liquid preparation process, first compound concentration is the 15g/L thickener DRA aqueous solution, in the described thickener DRA aqueous solution of every 1000ml, add again the adhesive beta-schardinger dextrin-of 30～40g polyurethane microcapsule and 20g, continue to stir 5min, obtain microcapsules dressing liquid.
Further, in described coating step, the cloth speed of entering of described matrix fabric is 40-50m/min.
Adopted the technical scheme of a kind of mosquito repellent fabric of the present invention, the upper surface at matrix fabric scribbles polyurethane microcapsule coating, polyurethane microcapsule coating consists of polyurethane microcapsule, polyurethane microcapsule is by polyurethane latex particle, and the technical scheme that is coated on the pesticide formation in polyurethane latex particle.Its technique effect is: because the polyurethane latex particle in polyurethane microcapsule has by polyurethane housing, and the double-decker that is coated on the external emulsifying agent housing formation of described polyurethane shell, can make like this pesticide in polyurethane microcapsule slowly discharge, play the initiatively good result of mosquito repellent; Polyurethane adhesion performance is good simultaneously, poor permeability, therefore a kind of mosquito repellent fabric of the present invention only has upper surface to scribble polyurethane microcapsule coating, like this when using a kind of mosquito repellent fabric of the present invention, the upper surface that scribbles polyurethane microcapsule coating does not contact with human body, has guaranteed user's health.Can there is not because of washing the obvious decline of mosquito repellent ability in a kind of mosquito repellent fabric of the present invention simultaneously.Correspondingly, the present invention also provides a kind of preparation method of mosquito repellent fabric, comprises polyurethane microcapsule preparation process; Microcapsules dressing liquid preparation process and coating step.It also can realize above-mentioned technique effect.
Accompanying drawing explanation
Fig. 1 is the structural representation of a kind of mosquito repellent fabric of the present invention.
Fig. 2 is the structural representation of polyurethane microcapsule in a kind of mosquito repellent fabric of the present invention.
The specific embodiment
Refer to Fig. 1 and Fig. 2, the present inventor is in order to understand technical scheme of the present invention better, below by embodiment particularly, and is described in detail by reference to the accompanying drawings:
Embodiment 1:
Polyurethane microcapsule preparation process: first the emulsifying agent 0P10 of 2g is added in the deionized water of 1000ml to the emulsion 1000ml that preparation emulsifying agent 0P10 concentration is 2g/L.Again the pesticide of the PEG400 of 15g, 3g hexamethylene diisocyanate and 15g is joined in described emulsion, then the sodium alginate that adds 3g in described emulsion is as dispersant.Then, in stir speed (S.S.), be 1000r/min, reaction temperature is, under the reaction condition of 70 ℃, to carry out emulsion polycondensation reaction.After 1.5h, emulsion polycondensation reaction terminating.Naturally be cooled to standing 24h after room temperature, generate the precipitation of polyurethane microcapsule 21, the particle diameter of polyurethane microcapsule 21 is 5～15 microns.The pesticide 4 that polyurethane microcapsule 21 comprises polyurethane latex particle 3 and is positioned at polyurethane latex particle 3.Polyurethane latex particle 3 is by polyurethane housing 31, and the emulsifying agent housing 32 being coated on outside polyurethane housing 31 forms.Upper strata clear aqueous solution is gone, and the precipitation that leaves polyurethane microcapsule 21 is standby.Wherein PEG400 is that molecular weight is 400 polyethylene glycol.Room temperature is 25 ℃ of left and right.
Microcapsules dressing liquid preparation process: microcapsules dressing liquid is formed by polyurethane microcapsule 21, adhesive beta-schardinger dextrin-, thickener DRA and deionized water mixed preparing.First take thickener DRA15g, add in 1000ml deionized water, stir, until thick dose of DRA mix at deionized water, till obtaining concentration and be the 15g/L thickener DRA aqueous solution.Then in the described thickener DRA aqueous solution, add polyurethane microcapsule 30g and adhesive beta-schardinger dextrin-20g, continue to stir 5min, finally make transparent uniform microcapsules dressing liquid.
Coating step: the upper surface using the microcapsules dressing liquid blade coating preparing at the pure-cotton fabric as matrix fabric 1, then this fabric is first dried 3min at 85 ℃, at 110-120 ℃, bake 3min again, then at 85～90 ℃, wash 1min, finally at 85 ℃, dry again 3min, obtain a kind of mosquito repellent fabric of the present invention, in coating step, the cloth speed of entering of matrix fabric 1 is 40-50m/min.
A kind of mosquito repellent fabric of the present invention, comprises matrix fabric 1 and the polyurethane microcapsule coating 2 that is positioned at matrix fabric 1 upper surface, and polyurethane microcapsule coating 2 consists of polyurethane microcapsule 21.
In above-described embodiment, polyoxyethylene nonylphenol ether 10 is polyoxyethylene nonylphenol ether, and thickener DRA is agent for polyacrylic acid thickening, and it is produced by German Clariant company.The pesticide using in the present embodiment is pyrethroid insecticides.
Embodiment 2:
Polyurethane microcapsule preparation process: first the emulsifying agent 0P10 of 2g is added in the deionized water of 1000ml to the emulsion 1000ml that preparation emulsifying agent 0P10 concentration is 2g/L.Again the pesticide of the PEG400 of 15g, 3g methyl diphenylene diisocyanate and 20g is joined in described emulsion, then the sodium alginate that adds 3g in described emulsion is as dispersant.Then, in stir speed (S.S.), be 1000r/min, reaction temperature is, under the reaction condition of 70 ℃, to carry out emulsion polycondensation reaction.After 1.5h, emulsion polycondensation reaction terminating.Naturally be cooled to standing 24h after room temperature, generate the precipitation of polyurethane microcapsule 21, the particle diameter of polyurethane microcapsule 21 is 5～15 microns.The pesticide 4 that polyurethane microcapsule 21 comprises polyurethane latex particle 3 and is positioned at polyurethane latex particle 3.Polyurethane latex particle 3 is by polyurethane housing 31, and the emulsifying agent housing 32 being coated on outside polyurethane housing 31 forms.Upper strata clear aqueous solution is gone, and the precipitation that leaves polyurethane microcapsule 21 is standby.
Microcapsules dressing liquid preparation process: microcapsules dressing liquid is formed by polyurethane microcapsule 21, adhesive beta-schardinger dextrin-, thickener DRA and deionized water mixed preparing.First take thickener DRA15g, add in 1000ml deionized water, stir, until thick dose of DRA mix at deionized water, till obtaining concentration and be the 15g/L thickener DRA aqueous solution.Then in the described thickener DRA aqueous solution, add polyurethane microcapsule 35g and adhesive beta-schardinger dextrin-20g, continue to stir 5min, finally make transparent uniform microcapsules dressing liquid.
Coating step: the upper surface using the microcapsules dressing liquid blade coating preparing at the pure-cotton fabric as matrix fabric 1, then this fabric is first dried 3min at 85 ℃, at 110-120 ℃, bake 3min again, then at 85～90 ℃, wash 1min, finally at 85 ℃, dry again 3min, obtain a kind of mosquito repellent fabric of the present invention, in coating step, the cloth speed of entering of matrix fabric 1 is 40-50m/min.
The pesticide using in the present embodiment is pyrethroid insecticides.
Embodiment 3:
Polyurethane microcapsule preparation process: first the emulsifying agent 0P10 of 2g is added in the deionized water of 1000ml to the emulsion 1000ml that preparation emulsifying agent 0P10 concentration is 2g/L.Again the pesticide of the PEG400 of 15g, 3g toluene di-isocyanate(TDI) and 25g is joined in described emulsion, then the sodium alginate that adds 3g in described emulsion is as dispersant.Then, in stir speed (S.S.), be 1000r/min, reaction temperature is, under the reaction condition of 70 ℃, to carry out emulsion polycondensation reaction.After 1.5h, emulsion polycondensation reaction terminating.Naturally be cooled to standing 24h after room temperature, generate the precipitation of polyurethane microcapsule 21, the particle diameter of polyurethane microcapsule 21 is 5～15 microns.The pesticide 4 that polyurethane microcapsule 21 comprises polyurethane latex particle 3 and is positioned at polyurethane latex particle 3.Polyurethane latex particle 3 is by polyurethane housing 31, and the emulsifying agent housing 32 being coated on outside polyurethane housing 31 forms.Upper strata clear aqueous solution is gone, and the precipitation that leaves polyurethane microcapsule 21 is standby.
Microcapsules dressing liquid preparation process: microcapsules dressing liquid is formed by polyurethane microcapsule 21, adhesive beta-schardinger dextrin-, thickener DRA and deionized water mixed preparing.First take thickener DRA15g, add in 1000ml deionized water, stir, until thick dose of DRA mix at deionized water, till obtaining concentration and be the 15g/L thickener DRA aqueous solution.Then in the described thickener DRA aqueous solution, add polyurethane microcapsule 40g and adhesive beta-schardinger dextrin-20g, continue to stir 5min, finally make transparent uniform microcapsules dressing liquid.
Coating step: the upper surface using the microcapsules dressing liquid blade coating preparing at the pure-cotton fabric as matrix fabric 1, then this fabric is first dried 3min at 85 ℃, at 110-120 ℃, bake 3min again, then at 85～90 ℃, wash 1min, finally at 85 ℃, dry again 3min, obtain a kind of mosquito repellent fabric of the present invention, in coating step, the cloth speed of entering of matrix fabric 1 is 40-50m/min.
The pesticide using in the present embodiment is pyrethroid insecticides.
Should be noted that, matrix fabric 1 can be not only pure-cotton fabric, can also be other fabrics such as pure pitted skin material, polyester fabric, acrylic fabric or nylon facing material.
Below the repelling effect of a kind of mosquito repellent fabric of the present invention is evaluated: the standard of evaluating institute's reference is AATCC135-2004 standard.
That selects examination worm that attack is qualified packs mosquito cage into, it is the 300/cage of the female mosquito of the aedes albopictus of not yet sucking blood of 3-5 age in days, and 4 experimenters, of the present invention a kind of mosquito repellent fabric that preparation method according to embodiment 1 to 3 is prepared, and of the present invention a kind of mosquito repellent fabric of preparing of the preparation method according to embodiment 1 to 3 of washing after 20 times, and pure-cotton fabric is placed on respectively by two arms of experimenter, hand is worn plastic glove, in mosquito cage, stop 2min, each test of first doing pure-cotton fabric is carried out after blank, make again the test of a kind of mosquito repellent fabric of the present invention.In counting 2min, on experimenter's arm, try the number of times that falls that stops of worm, as shown in table 1.
The list of table 1 a kind of mosquito repellent fabric result of use of the present invention
| Sample | Before washing, stop the number of times that falls | Wash the number of times that falls that stops after 20 times |
| Embodiment 1 | 5 | 37 |
| Embodiment 2 | 1 | 19 |
| Embodiment 3 | 3 | 25 |
| Pure-cotton fabric | 106 | 113 |
As can be seen from Table 1, a kind of mosquito repellent fabric of the present invention has good repelling effect, and still has good repelling effect after washing 20 times.
Claims (4)
1. a preparation method for mosquito repellent fabric, comprises the following steps:
Polyurethane microcapsule preparation process: first prepare the emulsion that OP10 emulsifier concentration is 2g/L, in the described emulsion of every 1000ml, add again the PEG400 of 15g, the vulcabond of 3g, the dispersant of 3g and the pesticide of 15～25g, then under the reaction temperature of the stir speed (S.S.) of 1000r/min and 70 ℃, carry out the emulsion polycondensation of 1.5h, last cooling naturally, and after being naturally cooled to room temperature standing 24h, obtain the precipitation of polyurethane microcapsule, described polyurethane microcapsule is by polyurethane latex particle, and be coated on that pesticide in described polyurethane latex particle forms,
Microcapsules dressing liquid preparation process: first compound concentration is the 15g/L thickener DRA aqueous solution, in the thickener DRA of the every 1000ml aqueous solution, add again the adhesive beta-schardinger dextrin-of 30～40g polyurethane microcapsule and 20g, continue to stir 5min, obtain microcapsules dressing liquid;
Coating step: after the above microcapsules dressing liquid of the upper surface blade coating of matrix fabric, dry at 85 ℃, then bake at 110-120 ℃, then wash at 80～90 ℃, finally again dry at 85 ℃, obtain mosquito repellent fabric.
2. the preparation method of a kind of mosquito repellent fabric according to claim 1, is characterized in that: described dispersant is sodium alginate.
3. the preparation method of a kind of mosquito repellent fabric according to claim 1, is characterized in that: described pesticide is pyrethroid insecticides.
4. according to the preparation method of a kind of mosquito repellent fabric described in any one in claims 1 to 3, it is characterized in that: in described coating step, the cloth speed of entering of described matrix fabric is 40-50m/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310151432.8A CN103194911B (en) | 2013-04-27 | 2013-04-27 | Mosquito-repellent fabric and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310151432.8A CN103194911B (en) | 2013-04-27 | 2013-04-27 | Mosquito-repellent fabric and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103194911A CN103194911A (en) | 2013-07-10 |
| CN103194911B true CN103194911B (en) | 2014-10-01 |
Family
ID=48717718
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310151432.8A Active CN103194911B (en) | 2013-04-27 | 2013-04-27 | Mosquito-repellent fabric and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103194911B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2539552B1 (en) * | 2013-07-23 | 2016-04-13 | María Pilar MATEO HERRERO | Repellent composition and microencapsulated biocide with double repellent action, textile garment comprising it and use of said garment |
| CN103444691A (en) * | 2013-07-30 | 2013-12-18 | 山东鲁普科技有限公司 | Mosquito and insect repellent rope net and production method thereof |
| CN103554428B (en) * | 2013-11-18 | 2015-05-13 | 中国林业科学研究院林产化学工业研究所 | Core-shell synergistic flame retardant polyurethane microencapsulation expandable graphite and application thereof in rigid polyurethane foaming plastic |
| WO2016077944A1 (en) * | 2014-11-17 | 2016-05-26 | 汪海银 | Insect-resistant and antibiotic fabric containing activated carbon |
| CN104947435B (en) * | 2015-04-08 | 2017-11-28 | 江苏工程职业技术学院 | A kind of preparation method of mosquito net intelligent surface mosquito repellent polyester fiber |
| CN104823996A (en) * | 2015-05-13 | 2015-08-12 | 山东农业大学 | Preparation method of pyraclostrobin microcapsules |
| CN104878607B (en) * | 2015-06-04 | 2016-08-31 | 常州美胜生物材料有限公司 | A kind of method using anophelifuge microcapsule finish fabric |
| CN109023961A (en) * | 2018-05-29 | 2018-12-18 | 黄河科技学院 | A kind of preparation method of Chinese medicine microcapsules and Chinese medicine textile |
| CN111387180A (en) * | 2020-04-28 | 2020-07-10 | 连云港杜钟新奥神氨纶有限公司 | Preparation method of aromatic mosquito-repellent microcapsule and spandex |
| CN117005099A (en) * | 2023-08-03 | 2023-11-07 | 福建德孚新材料科技有限公司 | Polymer mesh with mosquito-repellent and insect-repellent functions and preparation process |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1034655A (en) * | 1987-12-25 | 1989-08-16 | 住友化学工业株式会社 | The inhibition composition of cockroach of microencapsulation |
| CN1664227A (en) * | 2005-03-04 | 2005-09-07 | 天津永阔国际贸易有限公司 | A fabric finishing solution for repelling and killing mosquitoes, its use method and product |
| CN1936170A (en) * | 2006-09-14 | 2007-03-28 | 华明扬 | Method for preparing polyurethane fragrant microcapsules |
| CN1966850A (en) * | 2006-11-24 | 2007-05-23 | 华明浩 | Method for preparing inorganic cladded nano silver-supported antibacterial composite polyurethane microcapsule anophelifuge fabrics |
| CN101161921A (en) * | 2007-11-08 | 2008-04-16 | 华明扬 | Method for preparing polyurethane anti-mosquito fragrant microcapsules |
| CN102051819A (en) * | 2010-11-19 | 2011-05-11 | 志向（中国）集团有限公司 | Method for producing mosquito prevention textile fabric |
-
2013
- 2013-04-27 CN CN201310151432.8A patent/CN103194911B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1034655A (en) * | 1987-12-25 | 1989-08-16 | 住友化学工业株式会社 | The inhibition composition of cockroach of microencapsulation |
| CN1664227A (en) * | 2005-03-04 | 2005-09-07 | 天津永阔国际贸易有限公司 | A fabric finishing solution for repelling and killing mosquitoes, its use method and product |
| CN1936170A (en) * | 2006-09-14 | 2007-03-28 | 华明扬 | Method for preparing polyurethane fragrant microcapsules |
| CN1966850A (en) * | 2006-11-24 | 2007-05-23 | 华明浩 | Method for preparing inorganic cladded nano silver-supported antibacterial composite polyurethane microcapsule anophelifuge fabrics |
| CN101161921A (en) * | 2007-11-08 | 2008-04-16 | 华明扬 | Method for preparing polyurethane anti-mosquito fragrant microcapsules |
| CN102051819A (en) * | 2010-11-19 | 2011-05-11 | 志向（中国）集团有限公司 | Method for producing mosquito prevention textile fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103194911A (en) | 2013-07-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103194911B (en) | Mosquito-repellent fabric and preparation method thereof | |
| CN103726224B (en) | Non-woven film and charged non-woven biological protection mask prepared by same and preparation method | |
| CN106480602B (en) | A kind of preparation method of highly hygroscopic nontoxic non-stimulated non-woven fabrics | |
| CN102383304B (en) | Household textile product with insecticidal effect and processing method thereof | |
| WO2011063554A1 (en) | Insect proof fabric and producing method thereof | |
| CN1851109A (en) | Fabric finishing liquid for insecticidal medium, and its use method and fabric product | |
| CN102579399A (en) | Preparation method of antibacterial Chinese mugwort oil microcapsules | |
| CN105369610A (en) | Anti-mosquito and washable fabric and preparation method and application thereof | |
| CN110592954A (en) | Mosquito-repellent fabric finishing liquid, mosquito-repellent finishing fabric and preparation method thereof | |
| CN106436302A (en) | Cotton fabric with hydrophilic outer layer and hydrophobic inner layer | |
| CN106259502A (en) | A kind of idle call natural plants anthelmintic flavor compositions | |
| CN103668956B (en) | The anti-acarid method for sorting of anti-acarid finishing agent, fabric and anti-acarid fabric | |
| CN109881478A (en) | A kind of antimicrobial health care function scrambled eggs fabric and preparation method thereof | |
| CN102817237A (en) | Production method for mosquito net capable of expelling mosquitoes | |
| CN102220692A (en) | Textile fabric with long-lasting insect-dispelling effect | |
| CN102444020A (en) | Textile fabric with insect prevention function and production method thereof | |
| CN104562659A (en) | Insect-resistant fabric and preparation method thereof | |
| CN105696329A (en) | Finishing agent containing bendiocarb microcapsules and application of finishing agent | |
| CN105638759A (en) | Air purification material and preparation method thereof | |
| CN108283332A (en) | A kind of composite construction cool-down garments | |
| CN204687496U (en) | A kind of anti-mite adhesive interlining substrates | |
| CN104875454A (en) | Anti-mite adhesive lining base cloth | |
| CN112281479A (en) | Moisture-absorbing and quick-drying anti-mosquito fabric and preparation method thereof | |
| CN101019548A (en) | Prepn process and usage of liquid insect repellant | |
| CN206201582U (en) | A kind of improved sportswear fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent for invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Liu Yeduo Inventor after: Wang Xingui Inventor after: Wang Wenbin Inventor before: Cui Ming Inventor before: Wang Xingui Inventor before: Wang Wenbin Inventor before: Chen Qiang |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: CUI MING WANG XINGUI WANG WENBIN CHEN QIANG TO: LIU YEDUO WANG XINGUI WANGWENBIN |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |