CN103191033A - Shampoo composite containing cationic starch - Google Patents
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- CN103191033A CN103191033A CN2013101203460A CN201310120346A CN103191033A CN 103191033 A CN103191033 A CN 103191033A CN 2013101203460 A CN2013101203460 A CN 2013101203460A CN 201310120346 A CN201310120346 A CN 201310120346A CN 103191033 A CN103191033 A CN 103191033A
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Abstract
The invention discloses a shampoo composite containing cationic starch. The composite is prepared from the following raw materials in percentage by weight: a, 8-40% of a surfactant; b, 0.1-5% of cationic starch; c, 0.1-10% of silicone oil emulsion; and d, the balance of water, wherein the surfactant is selected from one or several anionic surfactants or ampholytic surfactants; the particle size of the silicone oil emulsion is 1 nanometer to 10 micrometers; and the cationic starch is prepared from starch and 2,3-epoxypropyl trimethyl ammonium chloride, 3-chlorine-2-hydroxypropyl trimethyl ammonium chloride or 3-chlorine-2-hydroxypropyl dimethyl-dodecyl ammonium chloride. According to the shampoo composite disclosed by the invention, the cationic starch is compounded with the silicone oil emulsion, so that the hand feeling of hair in a hairdressing process and the hand feeling, the carding performance and gloss of dried hair are improved; and an excellent use feeling is provided and the cost of the composite is reduced.
Description
Technical field
The present invention relates to shampoo composite, particularly relate to a kind of shampoo composite that can give the cation-containing starch of outstanding conditioning functions.
Background technology
Because scalp partly understands sebum secreted, contact with airborne fine particles etc. simultaneously, thereby people's hair is easy to dirtyly, and produce abnormal flavour, influence attractive in appearancely simultaneously, the use of hair caring approved product now is more frequent, and it is dirty more can to aggravate hair.Therefore, people remove excessive dirt and sebum by shampoo, with the cleaning that keeps hair, attractive in appearance.But consumer is not limited to this simple function of cleaning already to the requirement of shampoo, and consumer wishes that also shampoo can provide the good conditioning function, makes hair be easy to combing, soft and smooth, glossy etc.
Cation opsonizing agent is important function composition in the shampoo product, and cation opsonizing agent commonly used in shampoo comprises: cation natural polymer derivant, cationic polymer or micromolecule cation quaternary ammonium salt.Cation natural polymer derivant because of its recyclable regenerative, biodegradable, pollute advantages such as little, environmental protection and receive much concern, cation guar gum, cationic cellulose are cation opsonizing agents most widely used in the present shampoo formula.The cation guar gum price increases substantially because guar bean flour is widely used in petroleum industry, has influenced the shampoo cost.Simultaneously, the cationic cellulose price is also higher relatively, and Cosmetic Manufacture manufacturer has been brought bigger cost pressure.And starch has and cellulose and the similar raw material of melon plastic structure as a kind of, and wide material sources, cheap, quality controllable meet the epoch trend of green regenerating.
As everyone knows, the effect of cation high molecular in shampoo mainly contains aspect two: the one, and improve use feel and wet the sending out of protection of shampoo and avoid loss; The 2nd, in the shampoo dilution, cation high molecular and anion surfactant form wadding glue, and wadding glue is as carrier, help the hair care ingredient of small particle diameter and anti-dandruff dose to be deposited on effectively on hair or the scalp in flushing process as pyridinium zinc.The both finishes by the positive and negative charge wadding glue that forms that attracts each other by the cation high molecular in the hair washing process and anion surfactant.Wadding glue itself has certain spreadability and viscoelasticity, when wherein comprising short grained hair care ingredient such as silicone oil or anti-dandruff dose of composition, can make them obtain best coverage, thereby show best conditioning effect.Present people's amount that time that wadding glue forms and wadding glue form that begins one's study, but the time that wadding glue is formed, amount and the silicone oil of its delivery or the relation between the anti-dandruff composition size are not analyzed.
Prior art discloses some and has contained the shampoo composite of kinds of surface activating agent and cation opsonizing agent, but unexposed cationic starch is not studied the composite of starch hydroxypropyl-trimethyl ammonium chloride and silicone oil as the shampoo composite of conditioner yet.
Summary of the invention
Based on this, the purpose of this invention is to provide a kind of shampoo composite of cation-containing starch.
Concrete technical scheme is as follows:
A kind of shampoo composite of cation-containing starch comprises the raw material of following weight percentage:
A.8-40% surfactant;
B.0.1-5% cationic starch;
C.0.1-10% silicone oil emulsion;
D. surplus is water;
Described surfactant is selected from one or more in anion surfactant or the amphoteric surfactant; The particle diameter of described silicone oil emulsion is 1nm-10 μ m; Described cationic starch is by starch and 2.3-epoxypropyl trimethylammonium chloride ammonium, and 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride or 3-chloro-2-hydroxypropyl dimethyl-dodecyl chlorination ammonium prepares and gets.
Among some embodiment, comprise the raw material of following weight percentage therein:
A.10-30% surfactant;
B.0.2-1.5% cationic starch;
C.0.5-8% silicone oil emulsion;
D. surplus is water.
Among some embodiment, described starch is one or more in corn starch, tapioca, potato starch, wheaten starch, sweet potato starch, Radix Puerariae starch or the waxy starch therein.
Among some embodiment, described cationic starch 1% viscosity in aqueous solution is 50mPas-8000mPas therein; Nitrogen content is 0.2%-2.5%.
Among some embodiment, described cationic starch is the starch hydroxypropyl-trimethyl ammonium chloride therein.
Among some embodiment, the particle diameter of described silicone oil emulsion is 10nm-2 μ m therein.
Among some embodiment, the silicone oil in the described silicone oil emulsion is selected from one or more in polydimethylsiloxane, dimethiconol, amino polydimethylsiloxane, Silicone DC 556, organopolysiloxane, oxyalkylsiloxane, polyether modified silicon oil, amino-modified silicone oil, phenyl modified silicone oil, the alkyl modified silicon oil therein.
Among some embodiment, this shampoo composite also contains the cation opsonizing agent that accounts for composition weight 0.01-5% therein, and described cation opsonizing agent is selected from cation natural polymer derivant, cationic polymer or micromolecule cation quaternary ammonium salt.
Among some embodiment, this shampoo composite also contains the thickening stabilizing agent that accounts for composition weight 0.1-8% therein.
Therein among some embodiment, this shampoo composite also comprises one or more in the chelating agen, aliphatic alcohol, foam booster, pearling agent, auxiliary conditioner, wetting agent, anti-dandruff dose, antistatic additive, essence, pigment, antiseptic, ph regulator, viscosity modifier.
Principle of the present invention:
The present invention selects to study to the particle diameter of silicone oil emulsion to formation time and the amount of the wadding glue in the shampoo composite system.Wadding glue is the condensation product that anion surfactant, cation high molecular and water attract each other and form by positive and negative charge.Mainly acting as of wadding glue: 1. use feel and wet the sending out of protection of improving shampoo are avoided damage; 2. wadding glue can help hair care ingredient such as silicone oil and ZPT etc. to be deposited on effectively on hair or the scalp in flushing process as carrier.Therefore, avoid the damage with use feel and wet the sending out of protection of improving shampoo except forming a large amount of wadding glue, it is most important to the hair washing effect of shampoo that can wadding glue wrap up silicone oil.Originally discover that the shampoo that contains starch hydroxypropyl-trimethyl ammonium chloride and anion surfactant is when flushing, than a large amount of wadding of the more Zao formation of the shampoo of general cationic cellulose and cation guar gum and anion surfactant glue, therefore can play good use sense in a wet stage, but in the dilution later stage, the amount of its wadding glue is along with the increase of water, constantly run off, wadding glue amount reduces significantly.Find after deliberation, system of the present invention flushing from the beginning of, therefore the amount of wadding glue is many, all can play effective package action to big small particle diameter silicone oil, but at the flushing middle and late stage, particle diameter as silicone oil excessive (particle diameter is greater than 10 μ m), wadding glue can't play good package action, even can't wrap up silicone oil, make that flushing middle and late stage hair sense of touch and carding property are poor, simultaneously, also it effectively can't be delivered to hair, make effective deposition of silicone oil reduce significantly.And when the particle diameters such as silicone oil emulsion, silicone oil microemulsion or nano silicone fat liquor that use small particle diameter in system of the present invention are lower than the silicone oil emulsion of 10 μ m, not only can effectively wrap up silicone oil at the flushing initial stage, also can guarantee when wadding a quilt with cotton the glue amount more after a little while at the flushing middle and late stage, it also can play effective parcel and the delivery effect of good silicone oil or other insoluble substances, all can provide good combing, submissive sense before and after whole flushing process and dried sending out.
Prior art has been carried out a lot of researchs to the cleaning of shampoo and conditioning effect, but repeatedly washing of causing because of the character of existing cation opsonizing agent own and the over-deposit effect brought, and it is offending with the back sense often to make user produce.Coordinate conditioning performance and feeling with the back of being repeatedly used, this also is a great problem of shampoo formula technology.The present invention discovers, because of starch this body structure of hydroxypropyl-trimethyl ammonium chloride and wadding glue forming process all different with other cation high moleculars commonly used such as polyquaternary ammonium salt-10, guar gum hydroxypropyl-trimethyl ammonium chloride, be not easy to produce deposition in hair surface thereby the starch hydroxypropyl-trimethyl ammonium chloride occurred, but the result of conditioning effect excellence.Simultaneously, because wadding glue can be flushed away major part in the early stage formation of hair washing when flushing, thereby repeatedly use the shampoo that contains the starch hydroxypropyl-trimethyl ammonium chloride can't bring the over-deposit of tangible cation high molecular.Adjust amount and the charge density thereof of starch hydroxypropyl-trimethyl ammonium chloride, can also slightly be finalized the design or increase the effect of the amount of hair.
Compared with prior art, advantage of the present invention is:
The surfactant that the shampoo composite of cation-containing starch of the present invention comprises in conventional shampoo, thickening agent, the conditioner, form theory by wadding glue, wadding glue formation amount, silicone oil size are studied conditioning performance, optimized the composite of cationic starch and silicone oil emulsion, improved feel and glossiness after hair washing effect, carding property, hair are done, splendid use sense is provided and has reduced formulation cost.At present, the commercially available price of cationic starch is lower than 50 yuan/kg, and conventional cation opsonizing agent such as polyquaternary ammonium salt-10 and the commercially available price of guar gum hydroxypropyl-trimethyl ammonium chloride all 100 yuan/more than the kg, therefore, the use of cationic starch can effectively reduce formulation cost.According to the kind of price adjustment cationic starch, also can slightly be finalized the design, salubrious effect, for man's shampoo provides new approaches.Simultaneously, starch source is extensive, cheap, quality controllable, meets the epoch trend of green regenerating.Therefore starch derivatives is applied in the shampoo, except can promoting excellent conditioning performance, also can reduce formulation cost.
The starch hydroxypropyl-trimethyl ammonium chloride is the derivant of starch, and it is used in shampoo, can reduce formulation cost, and excellent conditioning performance more can be provided, and gives prescription excellent cardability, smooth feeling and the over-deposit phenomenon can not occur.
The selecting for use of each component in the shampoo composite:
Surfactant
Shampoo composite of the present invention comprises one or more anion surfactants, amphoteric surfactant, also can be two or more surfactant mixtures of these two big class surfactants.
(1) anion surfactant
The anion surfactant that is suitable for is selected from: the alkanoyl isethionate; alkyl succinate; alkyl sulfo succinate; alkyl ether sulfo succinate; alkylaryl sulfonates; the N-alkyl sarcosine salt; alkylphosphonic; alkyl polyoxyethylene ether carboxylic acid and salt thereof; glycerine monofatty ester sulfate; the fatty acyl glutamate, Glu; alkyl sulfate; the alkyl polyoxyethylene ether phosphate ester; alkylsulfonate; alkyl polyoxyethylene ether sulfate and alpha-alkene sulfonate are preferably alkyl sulfate; alkyl polyoxyethylene ether sulfate; the alkyl polyoxyethylene ether phosphate ester; the alkanoyl isethionate; alkylbenzenesulfonate.
(2) amphoteric surfactant
The amphoteric surfactant that is suitable for is selected from: betaines, imidazolines, Beta-alanine class and oxidation amine surfactant are preferably cocamido propyl betaine.
Cationic starch
It is the starch hydroxypropyl-trimethyl ammonium chloride that etherifying agent obtains that the cationic starch that is suitable for comprises employing 2,3-epoxypropyl trimethylammonium chloride ammonium at least.Other cationic starches are selected from: (organic amine compound can be selected from: 2.3-epoxypropyl trimethylammonium chloride ammonium with the various organic amine compounds that contain halogeno-group or epoxy radicals, 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride, 3-chloro-2-hydroxypropyl dimethyl-alkyl such as dodecyl chlorination ammonium replace the nitrification material) carry out etherification reaction and a kind of amido that contains of generating with hydroxyl in the native starch, and have the macromole ether derivant of positive charge at nitrogen-atoms.
Wherein the source of starch has: a. starch source can be one or more the composite uses in the starch such as corn starch, tapioca, potato starch, wheaten starch, sweet potato starch, Radix Puerariae starch or waxy starch; B. the nitrogen content of cationic starch is 0.2-2.5%, is preferably 0.5%-2.0%; C. the addition of cationic starch is the 0.1%-5% of composition total weight, is preferably 0.3%-1.5%; D. cationic starch 1% solution viscosity excursion is 50mPas-8000mPas.
Wherein starch hydroxypropyl-trimethyl ammonium chloride structural formula is as follows:
Wherein polymerization degree n is 1 * 10
3-5 * 10
5
Silicone oil emulsion
Select silicone oil and suitable emulsifying agent for use, by the silicone oil emulsion (also can be described as emulsified silicone oil) that chemical emulsification technology, emulsion polymerization technique or the machinery emulsification technology that realizes by high-shear mixer obtain, wherein classes of silicone oils is selected from: the compositions of one or more in polydimethylsiloxane, amino polydimethylsiloxane, dimethiconol, ring dimethyl polysiloxane, Silicone DC 556, organopolysiloxane, oxyalkylsiloxane, polyether modified silicon oil, amino-modified silicone oil, phenyl modified silicone oil, the alkyl modified silicon oil.The particle diameter of silicone oil emulsion is preferably 1nm-2 μ m between 1nm-10 μ m.
Cation opsonizing agent
The cation opsonizing agent that is applied in the shampoo field generally is divided into three major types: cation natural polymer derivant, cationic polymer, micromolecule cation quaternary ammonium salt.The adding of cation opsonizing agent mainly be for improve the wet cardability of doing of hair, with the back sense, make hair after hair washing and doing, softness, smooth, easy combing are arranged, be rich in gloss, reduce effect such as static.
Optional cation natural polymer derivant has: cationic quaternary ammonium polysaccharide, Caesalpinia spinosaKuntze hydroxypropyl-trimethyl ammonium chloride, Robinia pseudoacacia L. carob hydroxypropyl-trimethyl ammonium chloride, cassia gum hydroxypropyl-trimethyl ammonium chloride, Semen Trigonellae hydroxypropyl-trimethyl ammonium chloride, guar gum hydroxypropyl-trimethyl ammonium chloride, hydroxypropyl guar gum hydroxypropyl-trimethyl ammonium chloride.
Optional synthetic cationoid polymer has: polyquaternary ammonium salt-6, polyquaternary ammonium salt-7, polyquaternary ammonium salt-22, polyquaternary ammonium salt-39, polyquaternary ammonium salt-47, polyquaternary ammonium salt-52, polyquaternary ammonium salt-53, polyquaternary ammonium salt-76.
Optional micromolecule cation quaternary ammonium salt has: hexadecyltrimethylammonium chloride, octadecyl trimethyl ammonium chloride, one or more in palmitamide oxypropyl trimethyl ammonium chloride, the lauryl methyl glucitol polyethers-10 hydroxypropyl dimethyl ammonium chloride.
Thickening stabilizing agent
The use of thickening stabilizing agent, be for water-fast material dispersion suspension in the shampoo system, and increase the viscosity of shampoo, to satisfy the sense organ demand.These thickening stabilizing agents should be compatible on physical chemistry with other compositions of shampoo composite.
Optional thickening stabilizing agent has: HANSHENGJIAO, acrylate copolymer, hydroxypropyl cellulose, hydroxypropyl guar gum, polyvinyl pyrrolidone, PEG-120 methyl glucose dioleate, maleic anhydride-methyl ethylene ether copolymer, two (hydrogenated-tallow group) phthalic acid amide, coconut oil fatty acid monoethanolamide, cocoanut fatty acid diethanolamide, carbomer, acrylic acid (ester) class/C10-30 alkyl acrylate cross-linked polymer.
Shampoo composite of the present invention can also comprise other components: chelating agen, aliphatic alcohol, foam booster, pearling agent, auxiliary conditioner, wetting agent, anti-dandruff dose, essence, pigment, antiseptic, ph regulator, viscosity modifier.Its effect is for obtaining desirable physical and chemical index performance.
Optional chelating agen has: edta and its sodium salt, ascorbic acid, Etidronic Acid solution and sodium salt thereof are preferably disodiumedetate.Optional aliphatic alcohol has: 16 octadecanol.Optional foam booster has: fatty ester monoalkylol amide, the two alkanolamides of fatty ester, Polyethylene Glycol.Optional pearling agent has: ethylene glycol stearate, polyglycol distearate, Ethylene Glycol Distearate is preferably Ethylene Glycol Distearate.Optional auxiliary conditioner has D-panthenol, hydrolyzed protein, animals and plants extracting solution, Sargassum extract, vitamin, aminoacid, polypeptide, fibroin etc.Optional wetting agent has: squalane, glycerol, Polyethylene Glycol, 2-Pyrrolidone-5 carboxylic acid sodium etc.Anti-dandruff dose has: anti-dandruff dose of Chinese medicine, climbazole, pyridinium zinc, two pyrithione, oneself narrows fixed (hydroxyethylsulfonic acid .) salt, octopirox, and selenium sulfide, sulfur are preferably pyridinium zinc.The pH regulator agent has: citric acid, triethanolamine, regulate pH to 5-8, preferably to 5-6.5.Antiseptic has: parabens, Kazon, DMDM dimethyl hydantion, phenoxyethanol, sodium benzoate.Viscosity modifier has: sodium chloride, ammonium chloride etc.The antiseptic that is suitable for, pigment, essence choose the regulation that meets the cosmetics health standard.
In the shampoo composite of cation-containing starch of the present invention, except containing the above component, water mend to content be aequum.
The specific embodiment
Raw material used in the present invention is as follows:
Polyoxyethylene lauryl ether-2 ammonium sulfate (70%) is available from the Ninghua worker of section (China) company limited;
Laurel alkyl ammonium sulfate (70%) is available from the Ninghua worker of section (China) company limited;
Sodium lauroyl sarcosine is available from Guangzhou Tianci Advanced Materials Co., Ltd;
Cocamido propyl betaine (30%) is available from Guangzhou Tianci Advanced Materials Co., Ltd;
The starch hydroxypropyl-trimethyl ammonium chloride is available from Guangzhou Tianci Advanced Materials Co., Ltd;
Particle diameter〉silicone oil emulsion (50% silicone oil content) of 10 μ m is available from Guangzhou Tianci Advanced Materials Co., Ltd;
The silicone oil emulsion of particle diameter＜10 μ m (50% silicone oil content) is available from Guangzhou Tianci Advanced Materials Co., Ltd;
The silicone oil emulsion of particle diameter＜2 μ m (50% silicone oil content) is available from Guangzhou Tianci Advanced Materials Co., Ltd;
Amido silicone oil microemulsion (25% silicone oil content) is available from Guangzhou Tianci Advanced Materials Co., Ltd;
Nano silicone fat liquor (25% silicone oil content) is available from DOW CORNING (China) Investment Co., Ltd;
Disodiumedetate is available from DOW Chemical (China) Investment Co., Ltd;
Two (hydrogenated-tallow group) phthalic acid amide is available from Guangzhou Tianci Advanced Materials Co., Ltd;
Carbomer is available from Guangzhou Tianci Advanced Materials Co., Ltd;
Acrylic acid (ester) class/C10-30 alkyl acrylate cross-linked polymer is available from Guangzhou Tianci Advanced Materials Co., Ltd;
Acrylic acid (ester) copolymer is available from Guangzhou Tianci Advanced Materials Co., Ltd;
Polyquaternary ammonium salt-7 is available from Guangzhou Tianci Advanced Materials Co., Ltd;
Polyquaternary ammonium salt-10 is available from Guangzhou Tianci Advanced Materials Co., Ltd;
The guar gum hydroxypropyl-trimethyl ammonium chloride is available from Guangzhou Tianci Advanced Materials Co., Ltd;
Zinc Pyrithione is available from Guangzhou Tianci Advanced Materials Co., Ltd;
Ethylene Glycol Distearate is available from Kao Corp;
Coconut oleoyl amine MEA is available from BASF China;
Antiseptic is available from Guangzhou Tianci Advanced Materials Co., Ltd;
Essence is available from Robert's essence and flavoring agent (Beijing) company limited;
Citric acid is available from Wujiang south wind Fine Chemical Co., Ltd;
Triethanolamine is available from containing the chemical industry company limited in the Zhongshan city.
The preparation method of embodiment of the invention shampoo composite is as follows:
Earlier chelating agen (if any adding), first type surface activating agent are scattered in the water, stir, form the solution of stable homogeneous.Cationic starch is added in the above-mentioned solution with the pre-dispersed back of a spot of water.The addition sequence of unclassified stores and operational approach can adopt the technology of preparing of shampoo composite conventional in the prior art to be prepared.
The using method of embodiment of the invention shampoo composite:
The using method of shampoo composite of the present invention can be carried out according to the cleaning using method of the shampoo of routine, mainly comprises following step:
A) water is with the hair moistening;
B) get an amount of shampoo composite cleaning hair of the present invention;
C) water flushing hair is washed above-mentioned shampoo composite off.
Can repeat as required hair is washed.
Below by specific embodiment the present invention is further elaborated.
Table 1 and table 2 are non-limiting examples of shampoo composite of the present invention.Providing of these embodiment only is to be illustrative purposes, but not as limitation of the invention, therefore do not breaking away from the basis of the present invention, can carry out many changes to the present invention.Among these embodiment, its content is all represented percetage by weight.Wherein, refer to that in right amount this kind material can adjust its content according to the needs of the selection of final physical of the present invention, chemical characteristic.
Example I-VII
Table 1
Example VII A I-XIV
Table 2
The embodiment effect is estimated
Sensory evaluation is adopted in evaluation methodology to described non-limiting examples, evaluation methodology is: preparation example I-XIV, these embodiment are issued 112 respectively through the tester of training, in the test process, everyone uses specimen at least continuously and (is carrying out test period 3 times, must not use other shampoos, hair conditioner etc.), the tester marks according to own impression after washing process and hair are done.5 fens systems are adopted in scoring, and score value is more high, shows that effect is more good.1 be divided into the poorest, 5 be divided into best.Evaluation result is listed in table 3 and table 4.
Table 3
Table 4
From the test result of above embodiment as can be known, along with the particle diameter of the silicone oil emulsion of selecting among the embodiment diminishes, do wet cardability and obtained result preferably.And when using conventional cation opsonizing agent such as polyquaternary ammonium salt-10 and small particle diameter silicone oil composite, conditioning effect is not as the present invention.And when increasing other conditioners such as polyquaternary ammonium salt-7, can further strengthen the conditioning performance of prescription.The present invention can provide good conditioning effect, particularly at doing wet cardability, smooth feeling, good improvement is arranged.
From the prescription of example I-VII and test result thereof as can be seen, in prescription, adopt respectively starch hydroxypropyl-trimethyl ammonium chloride+small particle diameter silicone oil emulsion composite with the big particle diameter silicone oil emulsion of polyquaternary ammonium salt-10+ when composite, the particularly sliding puckery sense of the former prescription test result, carding property are better.The prescription of Comparative Example IV-V and test result thereof as can be seen, when the use amount of starch hydroxypropyl-trimethyl ammonium chloride increases, conditioning performance strengthens.The prescription of comparative example I-IV and test result thereof as can be seen, when the particle diameter of silicone oil emulsion is more little, its sliding puckery sense, carding property are better.
From the prescription of example VII A I-XIV and test result thereof as can be seen, when using the composite mode of starch hydroxypropyl-trimethyl ammonium chloride+small particle diameter silicone oil emulsion+other conditioner compositions in the prescription, the conditioning performance of prescription particularly sliding puckery sense, carding property is better than the performance formula of guar gum hydroxypropyl-trimethyl ammonium chloride+small particle diameter silicone oil emulsion+other conditioner compositions, also is better than taking the performance of the composite prescription of the big particle diameter silicone oil emulsion of guar gum hydroxypropyl-trimethyl ammonium chloride+polyquaternary ammonium salt-10++other conditioner compositions.
By above embodiment and test result thereof as can be known: when the particle diameters such as silicone oil emulsion, silicone oil microemulsion or nano silicone fat liquor that use cationic starch and small particle diameter in system of the present invention are lower than the silicone oil emulsion of 10 μ m when composite, not only can effectively wrap up silicone oil at the flushing initial stage, also can guarantee when wadding a quilt with cotton the glue amount more after a little while at the flushing middle and late stage, it also can play parcel and the delivery effect of good silicone oil or other insoluble substances, all can provide good combing, submissive sense before and after whole flushing process and dried sending out.When using particle diameter composite with cationic starch greater than the silicone oil emulsion of 10 μ m in system of the present invention, at the flushing middle and late stage, the glue of wadding a quilt with cotton can't form effective parcel and delivery effect to silicone oil, so conditioning performance is relatively poor.
The above embodiment has only expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but can not therefore be interpreted as the restriction to claim of the present invention.Should be pointed out that for the person of ordinary skill of the art without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Claims (10)
1. the shampoo composite of a cation-containing starch is characterized in that, comprises the raw material of following weight percentage:
A.8-40% surfactant;
B.0.1-5% cationic starch;
C.0.1-10% silicone oil emulsion;
D. surplus is water;
Described surfactant is selected from one or more in anion surfactant or the amphoteric surfactant; The particle diameter of described silicone oil emulsion is 1nm-10 μ m; Described cationic starch is by starch and 2.3-epoxypropyl trimethylammonium chloride ammonium, and 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride or 3-chloro-2-hydroxypropyl dimethyl-dodecyl chlorination ammonium prepares and gets.
2. the shampoo composite of cation-containing starch according to claim 1 is characterized in that, comprises the raw material of following weight percentage:
A.10-30% surfactant;
B.0.2-1.5% cationic starch;
C.0.5-8% silicone oil emulsion;
D. surplus is water.
3. the shampoo composite of cation-containing starch according to claim 1 and 2 is characterized in that, described starch is one or more in corn starch, tapioca, potato starch, wheaten starch, sweet potato starch, Radix Puerariae starch or the waxy starch.
4. the shampoo composite of cation-containing starch according to claim 1 and 2 is characterized in that, described cationic starch 1% viscosity in aqueous solution is 50mPas-8000mPas; Nitrogen content is 0.2%-2.5%.
5. the shampoo composite of cation-containing starch according to claim 1 and 2 is characterized in that, described cationic starch is the starch hydroxypropyl-trimethyl ammonium chloride.
6. the shampoo composite of cation-containing starch according to claim 1 and 2 is characterized in that, the particle diameter of described silicone oil emulsion is 10nm-2 μ m.
7. the shampoo composite of cation-containing starch according to claim 1 and 2, it is characterized in that the silicone oil in the described silicone oil emulsion is selected from one or more in polydimethylsiloxane, dimethiconol, amino polydimethylsiloxane, Silicone DC 556, organopolysiloxane, oxyalkylsiloxane, polyether modified silicon oil, amino-modified silicone oil, phenyl modified silicone oil, the alkyl modified silicon oil.
8. the shampoo composite of cation-containing starch according to claim 1 and 2, it is characterized in that, this shampoo composite also contains the cation opsonizing agent that accounts for composition weight 0.01-5%, and described cation opsonizing agent is selected from cation natural polymer derivant, cationic polymer or micromolecule cation quaternary ammonium salt.
9. the shampoo composite of cation-containing starch according to claim 1 and 2 is characterized in that, this shampoo composite also contains the thickening stabilizing agent that accounts for composition weight 0.1-8%.
10. the shampoo composite of cation-containing starch according to claim 1 and 2, it is characterized in that this shampoo composite also comprises one or more in chelating agen, aliphatic alcohol, foam booster, pearling agent, auxiliary conditioner, wetting agent, anti-dandruff dose, antistatic additive, essence, pigment, antiseptic, ph regulator, viscosity modifier.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106619183A (en) * | 2017-03-14 | 2017-05-10 | 广东龙湖科技股份有限公司 | Washing-free powdery shampoo and preparation method thereof |
| CN107822927A (en) * | 2017-12-06 | 2018-03-23 | 湖北工程学院 | Hair conditioner and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1976739A (en) * | 2004-07-02 | 2007-06-06 | 宝洁公司 | Personal care compositions containing cationic modified starch and an anionic surfactant system |
-
2013
- 2013-04-08 CN CN201310120346.0A patent/CN103191033B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1976739A (en) * | 2004-07-02 | 2007-06-06 | 宝洁公司 | Personal care compositions containing cationic modified starch and an anionic surfactant system |
Non-Patent Citations (1)
| Title |
|---|
| 王 琛等: "微波干法制备阳离子淀粉絮凝剂及其应用", 《化工进展》, vol. 22, no. 11, 31 December 2003 (2003-12-31) * |
Cited By (3)
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| CN106619183A (en) * | 2017-03-14 | 2017-05-10 | 广东龙湖科技股份有限公司 | Washing-free powdery shampoo and preparation method thereof |
| CN107822927A (en) * | 2017-12-06 | 2018-03-23 | 湖北工程学院 | Hair conditioner and preparation method thereof |
| CN107822927B (en) * | 2017-12-06 | 2021-09-07 | 湖北工程学院 | Hair conditioner and preparation method thereof |
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