CN103160347A - Synthetic method of synthetic hydrogen fuels - Google Patents

Synthetic method of synthetic hydrogen fuels Download PDF

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Publication number
CN103160347A
CN103160347A CN2012105329497A CN201210532949A CN103160347A CN 103160347 A CN103160347 A CN 103160347A CN 2012105329497 A CN2012105329497 A CN 2012105329497A CN 201210532949 A CN201210532949 A CN 201210532949A CN 103160347 A CN103160347 A CN 103160347A
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China
Prior art keywords
hydrogen
synthetic
hydrogen fuel
fuel
manufacturing process
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Pending
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CN2012105329497A
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Chinese (zh)
Inventor
李亚斌
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Yunnan Yixingzhiguang New Energy Science & Technology Development Co Ltd
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Yunnan Yixingzhiguang New Energy Science & Technology Development Co Ltd
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Priority to CN2012105329497A priority Critical patent/CN103160347A/en
Publication of CN103160347A publication Critical patent/CN103160347A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The invention relates to the synthetic field of fuels, in particular to a manufacturing method which is capable of using chemical synthesis to produce synthetic hydrogen fuels. According to the synthetic method of the synthetic hydrogen fuels, water and special electrodes serve as raw materials, and mixed gas containing hydrogen, carbon monoxide, methane and ethane are combined through an electrolytic process, and then inert gas which enables hydrogen molecules to be stable is added, and the synthetic hydrogen fuels which satisfy using demands and can be carried out long-distance safe transportation are manufactured. Under the standard state, the density of the synthetic hydrogen fuels is 0.66g/l, and the combustion value of the synthetic hydrogen fuels is 4668 k/ m^3. The synthetic hydrogen fuels have the advantages of being high in combustion value, non-toxic and non-harm, safe and pollution-free and the like.

Description

A kind of synthetic method of synthetic hydrogen fuel
Technical field
The present invention relates to fuel synthetic field, is a kind ofly to utilize various water to synthesize the hydrogen fuel synthetic method by electrolytic action specifically.
Background technology
In recent years, the exhaustion of earth resources and environmental disruption become problem highly visible, and people wish that more and more the zero disposal of pollutants that can construct based on renewable energy source is social.For addressing this problem, people make great efforts to carry out the utilization of the natural energy resources such as wind-force or sunlight and the Efficient use of energy that not yet utilizes that nature is existed.In addition, the utilization of the unlimited hydrogen that exists of occurring in nature is also paid close attention to by people.Hydrogen is the energy that can store, pays close attention to it as the substitute energy of fossil oil.But effective utilization of above-mentioned natural energy resources is also extensively not universal, but also is to rely on to discharge great amount of carbon dioxide (CO 2) fossil oil give altogether as raw material generating and most power.Along with the implementation to the inhibition of environmental disruption, the human consumer requires to use the situation of clean energy also to increase gradually.
Therefore, in order to solve energy problem, wait in expectation hydrogen energy source and use its fuel battery energy to be introduced in automobile or family of people.Hydrogen only generates water by emitting energy with the oxygen reaction.The whole bag of tricks such as other any materials, the electrolysis that can make water, fossil energy or methanol recapitalization that do not generate in this reaction beyond dewatering are made hydrogen, and use as raw material.And, can be stored in pressure pan, liquefied pot or hydrogen storage alloy, become organic hydride, methyl alcohol etc. and store as hydrogen fuel and supply with by chemical transformation.
Summary of the invention
The purpose of this invention is to provide a kind ofly by the various water generates hydrogen of electrolysis, then hydrogen is manufactured the method for synthetic hydrogen fuel, solve the problem of present energy supply deficiency.
For achieving the above object, the technical solution used in the present invention is: a kind of synthetic method of synthetic hydrogen fuel, and fuel composition and percent by volume thereof are:
Hydrogen: 50.0%-60.0%
Carbon monoxide: 30.0%-40.0%
Ethane: 1.0%-5.0%
Methane: 3.0%-7.0%
Rare gas element: 1.0%-3.0%.
Preferably: described fuel composition and percent by volume thereof are:
Hydrogen: 51.9%
Carbon monoxide: 36.4%
Ethane: 3.0%
Methane: 6.7%
Rare gas element: 2.0%.
Preferably: the synthetic method of described a kind of synthetic hydrogen fuel comprises as follows:
Hydrogen producing apparatus make hydrogen hydrogen manufacturing process, by the hydrogen fuel manufacturing installation, the hydrogen of affiliated hydrogen producing apparatus manufacturing is changed into the synthetic hydrogen fuel manufacturing installation that fuel uses the synthetic hydrogen fuel that state makes, the hydrogen fuel manufacture that hydrogen fuel manufacture receiving trap is accepted relevant hydrogen fuel manufacturing installation manufacture receives operation, in hydrogen fuel manufacturing process, receive that based on hydrogen fuel manufacture receiving trap the information of relevant hydrogen manufacture controls the amount that the hydrogen fuel manufacturing installation is made hydrogen fuel.
Preferably: also comprise adding in the described hydrogen fuel manufacturing installation making the stable inert gas storage operation of hydrogen fuel.
Preferably: described hydrogen manufacturing process, hydrogen fuel manufacturing process, manufacture detect between operation and rare gas element storage operation gas valve are set, described gas valve is the operation production information of making by synthetic hydrogen fuel, controls to be arranged on the aperture that the valve on pipe arrangement between operation and described rare gas element storage operation detects in described hydrogen manufacturing process, described hydrogen fuel manufacturing process, described manufacture.
Preferably: described hydrogen producing apparatus is a kind of high-pressure electrolysis pool device, and described electrolytic cell device comprises the first electrode, the second electrode and one deck solid dielectric between described the first electrode and the second electrode.
Preferably: described the first electrode and the second electrode are Graphite Electrodess.
Preferably: the synthetic method of described a kind of synthetic hydrogen fuel, that required raw material is added to hydrogen producing apparatus, the mixed gas that the electrolytic action of the electrolyzer by described hydrogen producing apparatus produces, the mixed gas of generation generates synthetic hydrogen fuel by described hydrogen fuel manufacturing installation.
More preferably: described raw material is water.
Useful technique effect of the present invention is: the present invention utilizes the synthetic hydrogen fuel of the method for brine electrolysis, the universal utilization of synthetic hydrogen fuel has reduced the use of fossil oil widely, and the product of synthetic Hydrogen fuel combustion only has water, positive provide protection has been played in environment protection, the raw material of synthetic hydrogen fuel use is various water simultaneously, particularly sanitary sewage and industrial sewage, improved the Water reuse rate significantly; And add in synthetic hydrogen fuel and make its stable rare gas element, be more conducive to storage and the transportation of synthetic hydrogen fuel.
Embodiment
Below in conjunction with embodiment, technical solution of the present invention is clearly and completely described, obviously, described embodiment is only the present invention's part embodiment, rather than whole embodiment.Based on the embodiment in the present invention, those of ordinary skills belong to the scope of protection of the invention not making the every other embodiment that obtains under the creative work prerequisite.
Embodiment 1
The working method of synthetic hydrogen fuel comprises following concrete steps;
(1) sanitary sewage is passed in hydrogen producing apparatus, then give the Graphite Electrodes energising of hydrogen producing apparatus, under the electrolytic action of Graphite Electrodes, water and the reaction of Graphite Electrodes generating electrodes generate the mixed gas of hydrogen, carbon monoxide, methane and ethane;
(2) gas that generates in hydrogen producing apparatus is controlled the aperture of valve between hydrogen producing apparatus and hydrogen fuel manufacturing installation according to the resultant velocity information of hydrogen fuel manufacturing installation hydrogen fuel;
(3) information Control hydrogen fuel manufacturing installation and the aperture of the valve between the rare gas element storage equipment, the synthetic hydrogen fuel of the finished product of synthetic following proportioning at last of the synthetic hydrogen fuel amount of hydrogen fuel manufacturing installation;
Hydrogen: 51.9%
Carbon monoxide: 36.4%
Ethane: 3.0%
Methane: 6.7%
Rare gas element: 2.0%.
Embodiment 2
The working method of synthetic hydrogen fuel comprises following concrete steps;
(1) sanitary sewage is passed in hydrogen producing apparatus, then give the Graphite Electrodes energising of hydrogen producing apparatus, under the electrolytic action of Graphite Electrodes, water and the reaction of Graphite Electrodes generating electrodes generate the mixed gas of hydrogen, carbon monoxide, methane and ethane;
(2) gas that generates in hydrogen producing apparatus is controlled the aperture of valve between hydrogen producing apparatus and hydrogen fuel manufacturing installation according to the resultant velocity information of hydrogen fuel manufacturing installation hydrogen fuel;
(3) information Control hydrogen fuel manufacturing installation and the aperture of the valve between the rare gas element storage equipment, the synthetic hydrogen fuel of the finished product of synthetic following proportioning at last of the synthetic hydrogen fuel amount of hydrogen fuel manufacturing installation;
Hydrogen: 56.9%
Carbon monoxide: 31.4%
Ethane: 3.0%
Methane: 6.7%
Rare gas element: 2.0%.
Embodiment 3
The working method of synthetic hydrogen fuel comprises following concrete steps;
(1) sanitary sewage is passed in hydrogen producing apparatus, then give the Graphite Electrodes energising of hydrogen producing apparatus, under the electrolytic action of Graphite Electrodes, water and the reaction of Graphite Electrodes generating electrodes generate the mixed gas of hydrogen, carbon monoxide, methane and ethane;
(2) gas that generates in hydrogen producing apparatus is controlled the aperture of valve between hydrogen producing apparatus and hydrogen fuel manufacturing installation according to the resultant velocity information of hydrogen fuel manufacturing installation hydrogen fuel;
(3) information Control hydrogen fuel manufacturing installation and the aperture of the valve between the rare gas element storage equipment, the synthetic hydrogen fuel of the finished product of synthetic following proportioning at last of the synthetic hydrogen fuel amount of hydrogen fuel manufacturing installation;
Hydrogen: 59.9%
Carbon monoxide: 24.4%
Ethane: 5.0%
Methane: 7.7%
Rare gas element: 3.0%.
The above is only the preferred embodiments of the present invention; not thereby limit protection scope of the present invention; the equivalent structure of doing on specification sheets of the present invention basis, or directly, indirectly be used in other relevant technical field, within all in like manner being included in protection scope of the present invention.

Claims (9)

1. the synthetic method of a synthetic hydrogen fuel, it is characterized in that: fuel composition and percent by volume thereof are:
Hydrogen: 50.0%-60.0%
Carbon monoxide: 30.0%-40.0%
Ethane: 1.0%-5.0%
Methane: 3.0%-7.0%
Rare gas element: 1.0%-3.0%.
2. a kind of synthetic method of synthetic hydrogen fuel according to claim 1, it is characterized in that: fuel composition and percent by volume thereof are:
Hydrogen: 51.9%
Carbon monoxide: 36.4%
Ethane: 3.0%
Methane: 6.7%
Rare gas element: 2.0%.
3. the synthetic method of described a kind of synthetic hydrogen fuel according to claim 1 and 2 is characterized in that comprising as follows:
Hydrogen producing apparatus make hydrogen hydrogen manufacturing process, by the hydrogen fuel manufacturing installation, the hydrogen of affiliated hydrogen producing apparatus manufacturing is changed into the synthetic hydrogen fuel manufacturing process that fuel uses synthetic hydrogen fuel that state makes, the hydrogen fuel manufacture that hydrogen fuel manufacture receiving trap is accepted the information of relevant hydrogen fuel manufacturing installation manufacture receives operation, in described hydrogen fuel manufacturing process, receive that based on hydrogen fuel manufacture receiving trap the information of the relevant hydrogen manufacture of described hydrogen producing apparatus controls the amount that the hydrogen fuel manufacturing installation is made hydrogen fuel.
4. a kind of synthetic method of synthetic hydrogen fuel according to claim 3 is characterized in that: also comprise adding in the described hydrogen fuel manufacturing installation making the stable inert gas storage operation of hydrogen fuel.
5. a kind of synthetic method of synthetic hydrogen fuel according to claim 3, it is characterized in that: described hydrogen manufacturing process, hydrogen fuel manufacturing process, manufacture detect between operation and rare gas element storage operation gas valve are set, described gas valve is the production information by synthetic hydrogen fuel manufacturing process, controls to be arranged on the aperture that the valve on pipe arrangement between operation and described rare gas element storage operation detects in described hydrogen manufacturing process, described hydrogen fuel manufacturing process, described manufacture.
6. a kind of synthetic method of synthetic hydrogen fuel according to claim 3, it is characterized in that: described hydrogen producing apparatus is a kind of high-pressure electrolysis pool device, and described electrolytic cell device comprises the first electrode, the second electrode and one deck solid dielectric between described the first electrode and the second electrode.
7. a kind of synthetic method of synthetic hydrogen fuel according to claim 5, it is characterized in that: described the first electrode and the second electrode are Graphite Electrodess.
8. a kind of synthetic method of synthetic hydrogen fuel according to claim 3, it is characterized in that: required raw material is added to hydrogen producing apparatus, the mixed gas that the electrolytic action of the electrolyzer by described hydrogen producing apparatus produces, the mixed gas of generation generates synthetic hydrogen fuel by described hydrogen fuel manufacturing installation.
9. a kind of synthetic method of synthetic hydrogen fuel according to claim 8, it is characterized in that: described raw material is water.
CN2012105329497A 2012-12-11 2012-12-11 Synthetic method of synthetic hydrogen fuels Pending CN103160347A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106085526A (en) * 2016-06-22 2016-11-09 刘世超 A kind of synthesis hydrogen fuel
CN106118768A (en) * 2016-06-22 2016-11-16 刘世超 A kind of safety synthesis hydrogen fuel
CN110612366A (en) * 2017-05-19 2019-12-24 昭和电工株式会社 Method for electrochemically producing germane
CN110612365A (en) * 2017-05-19 2019-12-24 昭和电工株式会社 Method for electrochemically producing germane
CN110621810A (en) * 2017-05-19 2019-12-27 昭和电工株式会社 Method for electrochemically producing germane

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1098482A (en) * 1976-01-16 1981-03-31 Talenti, Pier F. Internal combustion engine with automatic control of electrolyte hydrogen generator
CN86100626A (en) * 1985-01-03 1986-08-20 伊奥沃思·索马斯 Gas generator
CN1093759A (en) * 1993-04-10 1994-10-19 何学智 Hydrogen-fuel generating device
CN1407071A (en) * 2001-08-31 2003-04-02 全球能源开发股份有限公司 Synthetic gas and its production
WO2011124872A1 (en) * 2010-04-08 2011-10-13 Advanced Fuel Technologies Uk Limited Fuel enrichment method and device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1098482A (en) * 1976-01-16 1981-03-31 Talenti, Pier F. Internal combustion engine with automatic control of electrolyte hydrogen generator
CN86100626A (en) * 1985-01-03 1986-08-20 伊奥沃思·索马斯 Gas generator
CN1093759A (en) * 1993-04-10 1994-10-19 何学智 Hydrogen-fuel generating device
CN1407071A (en) * 2001-08-31 2003-04-02 全球能源开发股份有限公司 Synthetic gas and its production
WO2011124872A1 (en) * 2010-04-08 2011-10-13 Advanced Fuel Technologies Uk Limited Fuel enrichment method and device

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106085526A (en) * 2016-06-22 2016-11-09 刘世超 A kind of synthesis hydrogen fuel
CN106118768A (en) * 2016-06-22 2016-11-16 刘世超 A kind of safety synthesis hydrogen fuel
CN106118768B (en) * 2016-06-22 2019-02-12 河南格揽环保科技有限公司 A kind of safety-type synthesis hydrogen fuel
CN106085526B (en) * 2016-06-22 2019-02-26 刘世超 A kind of synthesis hydrogen fuel
CN110612366A (en) * 2017-05-19 2019-12-24 昭和电工株式会社 Method for electrochemically producing germane
CN110612365A (en) * 2017-05-19 2019-12-24 昭和电工株式会社 Method for electrochemically producing germane
CN110621810A (en) * 2017-05-19 2019-12-27 昭和电工株式会社 Method for electrochemically producing germane
CN110612365B (en) * 2017-05-19 2022-04-05 昭和电工株式会社 Method for electrochemically producing germane
CN110612366B (en) * 2017-05-19 2022-04-05 昭和电工株式会社 Method for electrochemically producing germane

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Application publication date: 20130619