CN106118768B - A kind of safety-type synthesis hydrogen fuel - Google Patents
A kind of safety-type synthesis hydrogen fuel Download PDFInfo
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- CN106118768B CN106118768B CN201610457858.XA CN201610457858A CN106118768B CN 106118768 B CN106118768 B CN 106118768B CN 201610457858 A CN201610457858 A CN 201610457858A CN 106118768 B CN106118768 B CN 106118768B
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/003—Additives for gaseous fuels
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/094—Char
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0943—Coke
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0969—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
- C10J2300/0986—Catalysts
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
Abstract
The invention discloses a kind of safety-type synthesis hydrogen fuels, the safety-type synthesis hydrogen fuel, is prepared by the raw material of following weight parts: 2800-3200 parts of carbon dioxide, 280-520 parts of water, 180-320 parts of carbon, 0.05-0.15 parts of hydrogen stabilizer, 20-100 parts of catalyst.A kind of safety-type synthesis hydrogen fuel of the present invention has many advantages, such as that fuel value is high, has good burning performance, safety non-pollution.
Description
Technical field
The present invention relates to gaseous fuel technical fields, and in particular to a kind of safety-type synthesis hydrogen fuel.
Background technique
In recent years, the exhaustion and environmental disruption of earth resource become problem highly visible, and people increasingly wish to
Construct the no pollution discharge society based on renewable energy.To solve this problem, people make great efforts to carry out wind-force or sunlight etc.
The utilization of natural energy resources and effective use to the still unused energy existing for nature.In addition, infinitely being deposited in nature
Hydrogen utilization it is also of interest by people.But the effective use of above-mentioned natural energy resources is there are no widely available, but also
It is that great amount of carbon dioxide (CO will be discharged in dependence2) fossil fuel as raw material power generation and most power supply.With right
The implementation of the inhibition of environmental disruption, customer demand the case where clean energy resource using also gradually increasing.And Hydrogen Energy is exactly people institute
The new energy of expectation.Hydrogen is resourceful on the earth, and hydrogen itself is nontoxic, burns pollution-free, and calorific value is high, has good burning performance.
The present invention provides a kind of safety-type synthesis hydrogen fuel, have many advantages, such as that calorific value is high, burning is pollution-free.
Summary of the invention
Aiming at the above shortcomings existing in the prior art, technical problem to be solved by the invention is to provide a kind of safety-type
Synthesize hydrogen fuel.
Object of the present invention is to what is be achieved through the following technical solutions:
A kind of safety-type synthesis hydrogen fuel, is prepared by the raw material of following weight parts: 2800-3200 parts of carbon dioxide,
280-520 parts of water, 180-320 parts of carbon, 0.05-0.15 parts of hydrogen stabilizer, 20-100 parts of catalyst.
Preferably, the catalyst is mixed by nickel monoxide, cobaltosic oxide, palladium monoxide, an oxidation
Nickel, cobaltosic oxide, palladium monoxide mass ratio be (1-3): (1-3): (1-3).
Preferably, the hydrogen stabilizer is mixed by neon, helium, xenon, the neon, helium, xenon
Mass ratio is (1-3): (1-3): (1-3).
The present invention also provides a kind of safety-type synthesis hydrogen fuels, are prepared using the above method, by following weight hundred
The group of ratio is divided to be grouped as: hydrogen 30-60%, carbon monoxide 20-30%, hydrogen stabilizer 0.0001-0.01%, surplus C1-C4
Paraffin gas.
Specifically, in the present invention:
Nickel monoxide, No. CAS: 1313-99-1, partial size 20-40nm.
Cobaltosic oxide, No. CAS: 1308-06-1, partial size 20-40nm.
Palladium monoxide, No. CAS: 1314-08-5, partial size 20-40nm.
Carbon dioxide, No. CAS: 124-38-9.
Carbon, No. CAS: 7440-44-0.
Neon, No. CAS: 7440-01-9.
Helium, No. CAS: 7440-59-7.
Xenon, No. CAS: 7440-63-3.
A kind of safety-type synthesis hydrogen fuel of the present invention has many advantages, such as that fuel value is high, has good burning performance, safety non-pollution.
Specific embodiment
Embodiment 1
A kind of preparation of safety-type synthesis hydrogen fuel, comprising the following steps:
(1) 2kg carbon is placed in the bottom of reactor first half, the partial size of carbon is 2mm, lines up rectangle carbon by airflow direction
Bed, carbon bed length are 80cm, width 20cm；300g catalyst is uniformly attached to 9kg ceramic monolith and (Chuan Kuang is moistened using Lingshou County
The diameter that powder processing factory provides is 5mm ceramic catalyst carrier) on, and the ceramic monolith of supported catalyst is uniformly set
In the bottom of reactor；By 30kg carbon dioxide pressurization 10kg/cm2It afterwards, is 152.4cm, a length of 1219.2cm into internal diameter
In the horizontal reactor of closed isolation air, the flow velocity of carbon dioxide is 2.5 meter per seconds；By 3kg water pressurization 10kg/cm2, adding
Water is added while entering carbon dioxide, forms water mist in the reactor through nozzle；Under the action of catalyst, it is in reaction temperature
1000 DEG C, pressure 10kg/cm2Under the conditions of reacted；Mixed gas is obtained after reaction, mixed gas stops in the reactor
Time is to flow out from reactor after 5 seconds；
(2) after mixing by mixed gas and 0.9g hydrogen stabilizer, safety-type conjunction is obtained by 180 mesh filter-cloth filterings
At hydrogen fuel.
The catalyst is uniformly mixed in mass ratio for 1:1:1 by nickel monoxide, cobaltosic oxide, palladium monoxide
It obtains.
The hydrogen stabilizer is that 1:1:1 is uniformly mixed to obtain by neon, helium, xenon in mass ratio.
Embodiment 2
Substantially the same manner as Example 1, difference is only in that: the hydrogen stabilizer is in mass ratio by helium, xenon
1:1 is uniformly mixed to obtain.Obtain the safety-type synthesis hydrogen fuel of embodiment 2.
Embodiment 3
Substantially the same manner as Example 1, difference is only in that: the hydrogen stabilizer is in mass ratio by neon, xenon
1:1 is uniformly mixed to obtain.Obtain the safety-type synthesis hydrogen fuel of embodiment 3.
Embodiment 4
Substantially the same manner as Example 1, difference is only in that: the hydrogen stabilizer is in mass ratio by neon, helium
1:1 is uniformly mixed to obtain.Obtain the safety-type synthesis hydrogen fuel of embodiment 4.
Embodiment 5
Substantially the same manner as Example 1, difference is only in that: the catalyst is by cobaltosic oxide, palladium monoxide by matter
Amount is than being that 1:1 is uniformly mixed to obtain.Obtain the safety-type synthesis hydrogen fuel of embodiment 5.
Embodiment 6
Substantially the same manner as Example 1, difference is only in that: the catalyst is by nickel monoxide, palladium monoxide by quality
Than being uniformly mixed to obtain for 1:1.Obtain the safety-type synthesis hydrogen fuel of embodiment 6.
Embodiment 7
Substantially the same manner as Example 1, difference is only in that: the catalyst is by nickel monoxide, cobaltosic oxide by matter
Amount is than being that 1:1 is uniformly mixed to obtain.Obtain the safety-type synthesis hydrogen fuel of embodiment 7.
Test case 1
The safety-type synthesis hydrogen fuel reaction production rate of step (1) in embodiment 1 and embodiment 5-7 is tested, is had
Body the results are shown in Table 1.
Table 1: safety-type synthesis hydrogen fuel reacts production rate result table
| Production rate, % | |
| Embodiment 1 | 95.2 |
| Embodiment 5 | 91.8 |
| Embodiment 6 | 91.5 |
| Embodiment 7 | 90.6 |
Comparing embodiment 1 and embodiment 5-7, embodiment 1 (nickel monoxide, cobaltosic oxide, palladium monoxide compounding) safety
Type synthesis hydrogen fuel reaction production rate be apparently higher than embodiment 5-7 (nickel monoxide, cobaltosic oxide, any two in palladium monoxide
Person's compounding).
Test case 2
Combustion heat value test is carried out to the safety-type synthesis hydrogen fuel of embodiment 1-7 preparation.Concrete outcome is shown in Table 2.
Table 2: combustion heat value test result table
| Sample | Combustion heat value, kcal/m3 |
| Embodiment 1 | 7524 |
| Embodiment 2 | 7466 |
| Embodiment 3 | 7522 |
| Embodiment 4 | 7456 |
| Embodiment 5 | 7356 |
| Embodiment 6 | 7328 |
| Embodiment 7 | 7402 |
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (neon, argon, krypton compounding) combustion heat value are apparently higher than embodiment 2-4
(neon, argon, both any compounding in krypton).Comparing embodiment 1 and embodiment 5-7, embodiment 1 (nickel monoxide, cobaltosic oxide,
Palladium monoxide compounding) to be apparently higher than embodiment 5-7 (nickel monoxide, cobaltosic oxide, both any in palladium monoxide for combustion heat value
Compounding).
Claims (1)
1. a kind of safety-type synthesis hydrogen fuel, which is characterized in that be prepared by the raw material of following weight parts: carbon dioxide
2800-3200 parts, 280-520 parts of water, 180-320 parts of carbon, 0.05-0.15 parts of hydrogen stabilizer, 20-100 parts of catalyst；
The hydrogen stabilizer is mixed by neon, helium, xenon, the neon, helium, xenon mass ratio be (1-
3): (1-3): (1-3)；
The catalyst is mixed by nickel monoxide, cobaltosic oxide, palladium monoxide, the nickel monoxide, four oxidations three
Cobalt, palladium monoxide mass ratio be (1-3): (1-3): (1-3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201610457858.XA CN106118768B (en) | 2016-06-22 | 2016-06-22 | A kind of safety-type synthesis hydrogen fuel |
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| CN201610457858.XA CN106118768B (en) | 2016-06-22 | 2016-06-22 | A kind of safety-type synthesis hydrogen fuel |
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| CN106118768A CN106118768A (en) | 2016-11-16 |
| CN106118768B true CN106118768B (en) | 2019-02-12 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1407071A (en) * | 2001-08-31 | 2003-04-02 | 全球能源开发股份有限公司 | Synthetic gas and its production |
| CN1664081A (en) * | 2004-03-01 | 2005-09-07 | 全球能源开发股份有限公司 | Method for producing synthetic fuel gas |
| CN102149464A (en) * | 2008-09-12 | 2011-08-10 | 约翰森·马瑟公开有限公司 | Shaped heterogeneous catalysts |
| CN103160347A (en) * | 2012-12-11 | 2013-06-19 | 云南亿星之光新能源科技开发有限公司 | Synthetic method of synthetic hydrogen fuels |
| CN103571552A (en) * | 2012-07-27 | 2014-02-12 | 广西中新生物能源开发有限责任公司 | Method for preparing hydrocarbon synthesized civil gas |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060013759A1 (en) * | 2004-07-13 | 2006-01-19 | Conocophillips Company | Systems and methods for hydrogen production |
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2016
- 2016-06-22 CN CN201610457858.XA patent/CN106118768B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1407071A (en) * | 2001-08-31 | 2003-04-02 | 全球能源开发股份有限公司 | Synthetic gas and its production |
| CN1664081A (en) * | 2004-03-01 | 2005-09-07 | 全球能源开发股份有限公司 | Method for producing synthetic fuel gas |
| CN102149464A (en) * | 2008-09-12 | 2011-08-10 | 约翰森·马瑟公开有限公司 | Shaped heterogeneous catalysts |
| CN103571552A (en) * | 2012-07-27 | 2014-02-12 | 广西中新生物能源开发有限责任公司 | Method for preparing hydrocarbon synthesized civil gas |
| CN103160347A (en) * | 2012-12-11 | 2013-06-19 | 云南亿星之光新能源科技开发有限公司 | Synthetic method of synthetic hydrogen fuels |
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