CN209652201U - Portable methanol Preparation equipment and water hydrogen electricity generation system - Google Patents
Portable methanol Preparation equipment and water hydrogen electricity generation system Download PDFInfo
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- CN209652201U CN209652201U CN201720368717.0U CN201720368717U CN209652201U CN 209652201 U CN209652201 U CN 209652201U CN 201720368717 U CN201720368717 U CN 201720368717U CN 209652201 U CN209652201 U CN 209652201U
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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- Y02E60/30—Hydrogen technology
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Abstract
It includes: hydrogen conveyor, the second conveying device, synthesis reactor that the utility model, which discloses a kind of portable methanol Preparation equipment and water hydrogen electricity generation system, the methanol Preparation equipment,；Second conveying device is carbon dioxide conveying device or/and carbon monoxide conveying device；The hydrogen conveyor, the second conveying device are connect with synthesis reactor respectively；Hydrogen and carbon dioxide or reaction of carbon monoxide in the synthesis reactor, generate methanol and water.The utility model proposes portable methanol Preparation equipment, can cooperate methanol-water reform electricity generation system use, prepare the methanol feedstock needed for it.The utility model proposes water hydrogen electricity generation system, methanol needed for electricity generation system can be made by oneself, and avoid the discharge of carbon dioxide.
Description
Technical field
The utility model belongs to methanol preparation technical field, is related to a kind of methanol Preparation equipment, more particularly to a kind of portable
Formula methanol Preparation equipment；Meanwhile the utility model further relates to a kind of water hydrogen electricity generation system.
Background technique
The development course of human history with the energy using closely related, as the first industrial revolution is to a large amount of of coal
Using starting, the mankind enter the age of industrial civilization, develop and use petroleum, natural gas, nuclear energy, water energy, solar energy, wind energy etc. successively
Various forms of energy.
The energy crisis of last century the seventies has caused the mankind to the deep thought of the energy: not lacking the energy on the earth, lacks
Be more efficient Energy Conversion Technology.
In the existing energy in addition to coal, petroleum, natural gas, nuclear energy, water energy, solar energy, wind energy apply at present compared with
To be extensive, but all there are many disadvantages.
It such as, include: that 1, nuclear energy power plant can generate low-order and high-order radioactive waste the shortcomings that nuclear energy, it is necessary to be prudent in dealing with；2, core
The energy power plant thermal efficiency is lower, and the thermal pollution of nuclear energy power plant is more serious；3, nuclear energy power plant cost of investment is too big, the wealth of Utilities Electric Co.
Risk of being engaged in is higher.And Fukushima, Japan in 2011 causes nuclear leakage accident due to earthquake, the influence of generation still remains so far.
The shortcomings that solar energy includes: 1, unstability: due to by round the clock, season, geographic latitude and height above sea level etc. from
The right limitation of condition and the influence of the enchancement factors such as fine, negative, cloud, rain.2, low efficiency and at high cost: Solar use at present
Development level, some aspects are theoretically feasible, are technically also mature.But some helioplants, because
Efficiency is relatively low, higher cost.
The shortcomings that wind energy includes: that problem of the wind-power electricity generation in ecology is to may interfere with birds.Current solution is
Offshore power generation, offshore generating price is higher but efficiency is also high.It is insufficient in the economy of some areas, wind-power electricity generation: many areas
Wind-force have an intermittence, worse situation be such as Taiwan on electricity needs higher summer and daytime, be that wind-force is less
Time；Have to wait for the development of the energy storage technologies such as compressed air.Wind-power electricity generation needs a large amount of soils to build wind power plant, just may be used
With the energy more than comparision of production.When carrying out wind-power electricity generation, wind-power electricity generation chance issues huge noise, so to look for some spaciousnesses
Place build.The also prematurity of present wind-power electricity generation, there are also suitable development spaces.
The shortcomings that water energy includes: to need to build the big library of high dam on the river that flooding and drying flux differs greatly to carry out water conservancy water energy tune
Section, often flood and submerge lose it is larger, need to largely migrate；Civilwork engineering quantity is larger so that once invest the larger, duration compared with
It is long；Hydroelectric generation is limited by conditions such as landform, geology；River load, natural runoff variation etc. influence it bigger etc.；Have
Groups of people think that the construction of large hydropower station destroys ecology, may cause some bad weathers.
In recent years, there is methanol-water reformation hydrogen production generating equipment (water hydrogen machine can be called), water hydrogen machine is small in size (only
Size as host computer), power it is high, can be applicable to different fields.
The basic composition of water hydrogen machine is that those skilled in the art can realize substantially according to the related patents of the applicant
(utility model patents of such as three authorizations: Chinese patent CN201210339912.2, it is a kind of to prepare hydrogen using methanol-water
System and method；Chinese patent CN201310578035.9, instant preparing hydrogen, generating power system and method；Chinese patent CN
201310520538.0 a kind of instant preparing hydrogen, generating power system and method；Chinese patent CN201410621689.X, methanol-water hydrogen manufacturing
Reformer, Methanol water hydrogen production system and the hydrogen production process of system), it is not described herein.
However, the raw material of water hydrogen machine needs in addition to buy at present, if water hydrogen machine widespread adoption, raw material in world wide
The problem of may become restrict the fast development of water hydrogen machine one of problem.
In view of this, nowadays there is an urgent need to design a kind of methanol Preparation equipment that hydrous water hydrogen machine uses, it is existing to overcome
There is drawbacks described above existing for water hydrogen machine.
Utility model content
The technical problem to be solved by the utility model is to provide a kind of portable methanol Preparation equipments, can cooperate methanol
Water is reformed electricity generation system and is used, and the methanol feedstock needed for it is prepared.
In addition, the utility model also provides a kind of water hydrogen electricity generation system, methanol needed for can making electricity generation system by oneself, and avoid
The discharge of carbon dioxide.
In order to solve the above technical problems, the utility model adopts the following technical solution:
A kind of portable methanol Preparation equipment, the methanol Preparation equipment include: nitrogen gas conveying device, hydrogen conveying dress
Set, carbon dioxide conveying device, the first mixer, the second mixer, micro fixed-bed reactor, counterbalance valve, alcohol-water separation device,
Chromatograph, methanol liquefying plant, methanol collection vessel, main control module；
The nitrogen gas conveying device includes nitrogen storage container, the first transfer pipeline, and the first transfer pipeline is equipped with first section
Only valve, the first mass flowmenter；
The carbon dioxide conveying device includes carbon dioxide storage container, the second transfer pipeline, and the second transfer pipeline is set
There are the second shut-off valve, the second mass flowmenter；
The hydrogen conveyor includes hydrogen storage vessel, third transfer pipeline, the 4th transfer pipeline, third delivery pipe
Road is equipped with third shut-off valve, third mass flowmenter, and the 4th transfer pipeline is equipped with the 4th shut-off valve, the 4th mass flowmenter；
The hydrogen storage vessel is connect by third transfer pipeline with the first transfer pipeline, third transfer pipeline and first
Transfer pipeline is intersected in one first triple valve；
The hydrogen storage vessel is connect by the 4th transfer pipeline with the second transfer pipeline, the 4th transfer pipeline and second
Transfer pipeline is intersected in one first four-way valve；
First triple valve is connect with the first mixer, and the other end of the first mixer is connect with the second triple valve；The
Two triple valves by the 5th transfer pipeline connect micro fixed-bed reactor, the 5th transfer pipeline be equipped with the 5th mass flowmenter,
Pressure gage；
The other end of the micro fixed-bed reactor connects the 4th triple valve, and the 4th triple valve is also connected with counterbalance valve, carries on the back
The other end of pressure valve connects one second four-way valve；
First four-way valve is connect with the second mixer, and the other end of the second mixer is connect with third triple valve；Alcohol
Separator, the second triple valve connect third triple valve, and alcohol-water separation device, methanol liquefying plant, chromatograph connect the second four-way
Valve；Methanol liquefying plant is connect with methanol collection vessel；The main control module control all parts movement；
The methanol Preparation equipment further includes generating electricity by natural energy device, utilizes solar energy or/and wind energy or/and biological energy source
Power generation, is hydrolyzed to hydrogen and oxygen for water using the electric energy of sending, and the hydrogen being collected into and carbon dioxide are prepared as methanol.
A kind of portable methanol Preparation equipment, the methanol Preparation equipment include: hydrogen conveyor, the second conveying dress
It sets, synthesis reactor；
Second conveying device is carbon dioxide conveying device or/and carbon monoxide conveying device；The hydrogen conveying
Device, the second conveying device are connect with synthesis reactor respectively；Hydrogen and carbon dioxide or an oxidation in the synthesis reactor
Carbon reaction, generates methanol and water.
As a kind of preferred embodiment of the utility model, the methanol Preparation equipment includes alcohol-water separation device, synthetic reaction
Device is connect with alcohol-water separation device, and methanol is separated from water by alcohol-water separation device.
As a kind of preferred embodiment of the utility model, the methanol Preparation equipment includes mixer, and mixer is set to
Before synthesis reactor, synthesis reactor is entered after first mixing hydrogen, carbon dioxide or carbon monoxide according to set proportion.
As a kind of preferred embodiment of the utility model, the methanol Preparation equipment further includes nitrogen gas conveying device, with conjunction
It is connected at reactor, first passes through nitrogen before hydrogen and carbon dioxide or reaction of carbon monoxide, other gases are discharged.
As a kind of preferred embodiment of the utility model, the methanol Preparation equipment further includes nitrogen gas conveying device, second
Mixer, micro fixed-bed reactor, counterbalance valve；
The nitrogen gas conveying device includes nitrogen storage container, the first transfer pipeline；The carbon dioxide conveying device packet
Include carbon dioxide storage container, the second transfer pipeline；The hydrogen conveyor includes hydrogen storage vessel, third delivery pipe
Road, the 4th transfer pipeline；
The hydrogen storage vessel is connect by third transfer pipeline with the first transfer pipeline, third transfer pipeline and first
Transfer pipeline is intersected in one first triple valve；
The hydrogen storage vessel is connect by the 4th transfer pipeline with the second transfer pipeline, the 4th transfer pipeline and second
Transfer pipeline is intersected in one first four-way valve；
First triple valve is connect with the first mixer, and the other end of the first mixer is connect with the second triple valve；The
Two triple valves connect micro fixed-bed reactor by the 5th transfer pipeline；
The other end of the micro fixed-bed reactor connects the 4th triple valve, and the 4th triple valve is also connected with counterbalance valve, carries on the back
The other end of pressure valve connects one second four-way valve；
First four-way valve is connect with the second mixer, and the other end of the second mixer is connect with third triple valve；Alcohol
Separator, the second triple valve connect third triple valve, and alcohol-water separation device, methanol liquefying plant, chromatograph connect the second four-way
Valve；Methanol liquefying plant is connect with methanol collection vessel；The main control module control all parts movement.
As a kind of preferred embodiment of the utility model, the methanol Preparation equipment further includes generating electricity by natural energy device,
Using solar energy or/and wind energy or/and bioenergy power generation, water is hydrolyzed to hydrogen and oxygen using the electric energy of sending, will be collected
To hydrogen and carbon dioxide be prepared as methanol.
A kind of water hydrogen electricity generation system, the water hydrogen electricity generation system include: methanol-water reforming hydrogen production device, hydrogen fuel cell,
Methanol Preparation equipment；
The methanol-water reforming hydrogen production device connects hydrogen fuel cell；Methanol-water reforming hydrogen production device is reformed using methanol-water
Hydrogen is made, hydrogen is delivered to hydrogen fuel cell, hydrogen fuel cell is equipped with air pump, and oxygen-containing gas is pumped into hydrogen fuel electricity by air pump
Pond；Hydrogen fuel cell occurs redox reaction using hydrogen and oxygen and generates electricity；
The methanol Preparation equipment connects methanol-water reforming hydrogen production device, provides methanol original for methanol-water reforming hydrogen production device
Material；
The electric energy that the hydrogen fuel cell issues is for methanol-water reforming hydrogen production device, hydrogen fuel cell, methanol Preparation equipment
Work.
As a kind of preferred embodiment of the utility model, the methanol Preparation equipment includes: that nitrogen gas conveying device, hydrogen are defeated
Send device, carbon dioxide conveying device, the first mixer, the second mixer, micro fixed-bed reactor, counterbalance valve, alcohol moisture
From device, chromatograph, methanol liquefying plant, methanol collection vessel, main control module；The carbon dioxide conveying device connects the storage
Deposit the side of container collection carbon dioxide；The methanol being prepared is delivered to the methanol water mixed liquid side of storage container；
The nitrogen gas conveying device includes nitrogen storage container, the first transfer pipeline, and the first transfer pipeline is equipped with first section
Only valve, the first mass flowmenter；
The carbon dioxide conveying device includes carbon dioxide storage container, the second transfer pipeline, and the second transfer pipeline is set
There are the second shut-off valve, the second mass flowmenter；
The hydrogen conveyor includes hydrogen storage vessel, third transfer pipeline, the 4th transfer pipeline, third delivery pipe
Road is equipped with third shut-off valve, third mass flowmenter, and the 4th transfer pipeline is equipped with the 4th shut-off valve, the 4th mass flowmenter；
The hydrogen storage vessel is connect by third transfer pipeline with the first transfer pipeline, third transfer pipeline and first
Transfer pipeline is intersected in one first triple valve；
The hydrogen storage vessel is connect by the 4th transfer pipeline with the second transfer pipeline, the 4th transfer pipeline and second
Transfer pipeline is intersected in one first four-way valve；
First triple valve is connect with the first mixer, and the other end of the first mixer is connect with the second triple valve；The
Two triple valves by the 5th transfer pipeline connect micro fixed-bed reactor, the 5th transfer pipeline be equipped with the 5th mass flowmenter,
Pressure gage；
The other end of the micro fixed-bed reactor connects the 4th triple valve, and the 4th triple valve is also connected with counterbalance valve, carries on the back
The other end of pressure valve connects one second four-way valve；
First four-way valve is connect with the second mixer, and the other end of the second mixer is connect with third triple valve；Alcohol
Separator, the second triple valve connect third triple valve, and alcohol-water separation device, methanol liquefying plant, chromatograph connect the second four-way
Valve；Methanol liquefying plant is connect with methanol collection vessel；The main control module control all parts movement.
The utility model has the beneficial effects that: the utility model proposes portable methanol Preparation equipment, first can be cooperated
Alcohol water is reformed electricity generation system and is used, and the methanol feedstock needed for it is prepared.The utility model proposes water hydrogen electricity generation system, can make by oneself
Methanol needed for electricity generation system, and avoid the discharge of carbon dioxide.
Detailed description of the invention
Fig. 1 is the composition schematic diagram of the utility model portable methanol Preparation equipment.
Fig. 2 is the composition schematic diagram of the utility model water hydrogen electricity generation system.
Specific embodiment
The preferred embodiment that according to the present invention will be described in detail below with reference to the accompanying drawings.
Embodiment one
Referring to Fig. 1, the utility model discloses a kind of portable methanol Preparation equipment, the methanol Preparation equipment packet
It includes: nitrogen gas conveying device A1, hydrogen conveyor A2, carbon dioxide conveying device A3, the first mixer A4, the second mixer
A5, micro fixed-bed reactor A7, counterbalance valve A8, alcohol-water separation device A6, chromatograph A9, methanol liquefying plant, methanol, which are collected, to be held
Device, main control module.
Micro fixed-bed reactor is that those skilled in the art can understand according to the description of the present application, be volume compared with
Small fixed bed reactors.Meanwhile Chinese patent CN200610023343.5 be related to one kind be mainly used for it is more under the normal pressure of laboratory
The micro fixed-bed reactor of phase catalytic reaction evaluation, more particularly to a kind of new casing reactor.Applied from above-mentioned 2006
Patent in, can know, " micro fixed-bed reactor " is the conventional techniques of those skilled in the art, is not done here more
Detailed introduction.
The nitrogen gas conveying device A1 includes nitrogen storage container, the first transfer pipeline, and the first transfer pipeline is equipped with first
Shut-off valve A11, the first mass flowmenter A12.
The carbon dioxide conveying device A3 includes carbon dioxide storage container, the second transfer pipeline, the second transfer pipeline
Equipped with the second shut-off valve, the second mass flowmenter.
The hydrogen conveyor A2 includes hydrogen storage vessel, third transfer pipeline, the 4th transfer pipeline, third conveying
Pipeline is equipped with third shut-off valve, third mass flowmenter, and the 4th transfer pipeline is equipped with the 4th shut-off valve, the 4th mass flowmenter.
The hydrogen storage vessel is connect by third transfer pipeline with the first transfer pipeline, third transfer pipeline and first
Transfer pipeline is intersected in one first triple valve A13.The hydrogen storage vessel passes through the 4th transfer pipeline and the second transfer pipeline
Connection, the 4th transfer pipeline and the second transfer pipeline are intersected in one first four-way valve A14.
The first triple valve A13 is connect with the first mixer A4, the other end and the second triple valve of the first mixer A4
A15 connection；Second triple valve A15 connects micro fixed-bed reactor A7 by the 5th transfer pipeline, and the 5th transfer pipeline is equipped with
5th mass flowmenter, pressure gage.
The other end of the micro fixed-bed reactor A7 connects the 4th triple valve A16, and the 4th triple valve A16 is also connected with back
The other end of pressure valve A8, counterbalance valve A8 connect one second four-way valve A10.
The first four-way valve A14 is connect with the second mixer A5, the other end and third triple valve of the second mixer A5
A17 connection；Alcohol-water separation device A6, the second triple valve A15 connection third triple valve A17, alcohol-water separation device A6, methanol solution makeup
It sets, chromatograph A9 the second four-way valve of connection A10；Methanol liquefying plant is connect with methanol collection vessel.
The main control module control all parts movement, the ratio for first controlling high pure nitrogen and high-purity hydrogen to set are passed through
It is emptied after the mixing of first mixer by catalyst bed, switching gas after the completion of catalyst reduction is hydrogen and carbon dioxide
Gaseous mixture, gas boosts to certain pressure through counterbalance valve by catalyst bed and isolates Methanol product through alcohol-water separation device again
And water, unreacted gas continue through reactor cycles reaction after unstripped gas supplements.
The methanol Preparation equipment further includes generating electricity by natural energy device, electrolysis wetting system, utilizes solar energy or/and wind energy
Or/and bioenergy power generation, water is hydrolyzed to by hydrogen and oxygen, methanol Preparation equipment by electrolysis wetting system using the electric energy of sending
The hydrogen being collected into and carbon dioxide are prepared as methanol.
Embodiment two
Referring to Fig. 2, the present embodiment discloses a kind of water hydrogen electricity generation system, the water hydrogen electricity generation system includes: methanol-water weight
Whole device for producing hydrogen 1, hydrogen fuel cell 2, methanol Preparation equipment 3.
The methanol-water reforming hydrogen production device 1 connects hydrogen fuel cell 2；Methanol-water reforming hydrogen production device 1 utilizes methanol-water
It reforms and hydrogen is made, hydrogen is delivered to hydrogen fuel cell 2, hydrogen fuel cell 2 is equipped with air pump, and oxygen-containing gas is pumped into hydrogen by air pump
Fuel cell 2；Hydrogen fuel cell 2 occurs redox reaction using hydrogen and oxygen and generates electricity.
Methanol-water reforming hydrogen production device 1, hydrogen fuel cell 2 form methanol-water reformation hydrogen production electricity generation system, and methanol-water is reformed
The basic composition of preparing hydrogen, generating power system is that those skilled in the art can realize substantially according to the related patents of the applicant
(patents of invention of such as four authorizations: Chinese patent CN201210339912.2, it is a kind of using methanol-water prepare hydrogen system and
Method；Chinese patent CN201310578035.9, instant preparing hydrogen, generating power system and method；Chinese patent CN
201310520538.0 a kind of instant preparing hydrogen, generating power system and method；Chinese patent CN201410621689.X, methanol-water hydrogen manufacturing
Reformer, Methanol water hydrogen production system and the hydrogen production process of system), it is not described herein.
The methanol Preparation equipment 3 connects methanol-water reforming hydrogen production device 1, provides first for methanol-water reforming hydrogen production device 1
Raw polyol；The structure of methanol Preparation equipment 3 can refer to the description in embodiment one.
The electric energy that the hydrogen fuel cell 2 issues is set for methanol-water reforming hydrogen production device 1, hydrogen fuel cell 2, methanol preparation
Standby 3 work.
In addition, the water hydrogen electricity generation system further includes generating electricity by natural energy equipment, generating electricity by natural energy equipment includes the sun
At least one of energy power generator 5, wind electricity generating system 6, hydropower generating device 7.
The electric energy that device of solar generating 5, wind electricity generating system 6, hydropower generating device 7 issue can be utilized in real time,
It can also be stored in rechargeable battery, then reuse.This is the ways customary of those skilled in the art, is not done here
It repeats.
The water hydrogen electricity generation system further include electrolysis wetting system 4, using device of solar generating 5, wind electricity generating system 6,
(i.e. people's life and work is not required to electric energy to be used to the extra electric energy that hydropower generating device 7 issues, naturally it is also possible to be hydrogen fuel
The part electric energy that battery 2 issues) by being electrolysed wetting system water is hydrolyzed to hydrogen and oxygen, methanol Preparation equipment 3 will be collected into
Hydrogen and carbon dioxide be prepared as methanol.
In order to which methanol-water reforming hydrogen production device 1 does not discharge carbon dioxide, and by the carbon dioxide collection of discharge, methanol-water weight
Whole device for producing hydrogen may include carbon dioxide collecting device, the carbon dioxide of discharge be stored by storage device, carbon dioxide
Storage device can share a container with feedstock storage unit.Electricity generation system work when, raw material reduce, discharge carbon dioxide
Increase, therefore, the volume that raw material is stored in identical container becomes smaller, and the volume for storing carbon dioxide becomes larger.Specific structure can be with
Referring to " a kind of alcohol hydrogen generating equipment and its storage device " of the applicant's application, the patent No.: 201520872773.9.
In conclusion the utility model proposes portable methanol Preparation equipment and water hydrogen electricity generation system, preparation can be improved
Efficiency improves the concentration that methanol is made.The carbon dioxide that the utility model can use hydrogen from methyl alcohol power generation release prepares methanol,
It can be by heat recovery.Methanol needed for the utility model water hydrogen electricity generation system can make electricity generation system by oneself, and avoid dioxy
Change the discharge of carbon.
Here the description and application of the utility model are illustrative, are not wishing to for the scope of the utility model being limited in
It states in embodiment.The deformation and change of embodiments disclosed herein be it is possible, for the ordinary skill people of those this fields
The replacement of embodiment and equivalent various parts are well known for member.It should be appreciated by the person skilled in the art that not taking off
In the case where spirit or essential characteristics from the utility model, the utility model can in other forms, structure, arrangement, ratio,
And it is realized with other components, material and component.It, can be to this in the case where not departing from the scope of the utility model and spirit
In disclosed embodiment carry out other deformations and change.
Claims (9)
1. a kind of portable methanol Preparation equipment, which is characterized in that the methanol Preparation equipment includes: nitrogen gas conveying device, hydrogen
Gas conveying device, carbon dioxide conveying device, the first mixer, the second mixer, micro fixed-bed reactor, counterbalance valve, alcohol
Separator, chromatograph, methanol liquefying plant, methanol collection vessel, main control module；
The nitrogen gas conveying device includes nitrogen storage container, the first transfer pipeline, the first transfer pipeline be equipped with the first shut-off valve,
First mass flowmenter；
The carbon dioxide conveying device includes carbon dioxide storage container, the second transfer pipeline, and the second transfer pipeline is equipped with the
Two shut-off valves, the second mass flowmenter；
The hydrogen conveyor includes hydrogen storage vessel, third transfer pipeline, the 4th transfer pipeline, and third transfer pipeline is set
There are third shut-off valve, third mass flowmenter, the 4th transfer pipeline is equipped with the 4th shut-off valve, the 4th mass flowmenter；
The hydrogen storage vessel is connect by third transfer pipeline with the first transfer pipeline, third transfer pipeline and the first conveying
Pipeline is intersected in one first triple valve；
The hydrogen storage vessel is connect by the 4th transfer pipeline with the second transfer pipeline, the 4th transfer pipeline and the second conveying
Pipeline is intersected in one first four-way valve；
First triple valve is connect with the first mixer, and the other end of the first mixer is connect with the second triple valve；Two or three
Port valve connects micro fixed-bed reactor by the 5th transfer pipeline, and the 5th transfer pipeline is equipped with the 5th mass flowmenter, pressure
Meter；
The other end of the micro fixed-bed reactor connects the 4th triple valve, and the 4th triple valve is also connected with counterbalance valve, counterbalance valve
The other end connect one second four-way valve；
First four-way valve is connect with the second mixer, and the other end of the second mixer is connect with third triple valve；Alcohol moisture
Third triple valve is connected from device, the second triple valve, alcohol-water separation device, methanol liquefying plant, chromatograph connect the second four-way valve；First
Alcohol liquefying plant is connect with methanol collection vessel；The main control module control all parts movement；
The methanol Preparation equipment further includes generating electricity by natural energy device, is sent out using solar energy or/and wind energy or/and biological energy source
Water is hydrolyzed to hydrogen and oxygen using the electric energy of sending by electricity, and the hydrogen being collected into and carbon dioxide are prepared as methanol.
2. a kind of portable methanol Preparation equipment, which is characterized in that the methanol Preparation equipment includes: hydrogen conveyor,
Two conveying devices, synthesis reactor；
Second conveying device is carbon dioxide conveying device or/and carbon monoxide conveying device；The hydrogen conveyor,
Second conveying device is connect with synthesis reactor respectively；Hydrogen and carbon dioxide or carbon monoxide are anti-in the synthesis reactor
It answers, generates methanol and water.
3. portable methanol Preparation equipment according to claim 2, it is characterised in that:
The methanol Preparation equipment includes alcohol-water separation device, and synthesis reactor is connect with alcohol-water separation device, and alcohol-water separation device is by first
Alcohol is separated from water.
4. portable methanol Preparation equipment according to claim 2, it is characterised in that:
The methanol Preparation equipment includes mixer, before mixer is set to synthesis reactor, first by hydrogen, carbon dioxide or one
Carbonoxide enters synthesis reactor after mixing according to set proportion；
The methanol Preparation equipment further includes nitrogen gas conveying device, is connect with synthesis reactor, in hydrogen and carbon dioxide or one
Nitrogen is first passed through before carbon dioxide reaction, other gases are discharged.
5. portable methanol Preparation equipment according to claim 2, it is characterised in that:
The methanol Preparation equipment further includes nitrogen gas conveying device, the second mixer, micro fixed-bed reactor, counterbalance valve；
The nitrogen gas conveying device includes nitrogen storage container, the first transfer pipeline；The carbon dioxide conveying device includes two
Carbonoxide storage container, the second transfer pipeline；The hydrogen conveyor includes hydrogen storage vessel, third transfer pipeline,
Four transfer pipelines；
The hydrogen storage vessel is connect by third transfer pipeline with the first transfer pipeline, third transfer pipeline and the first conveying
Pipeline is intersected in one first triple valve；
The hydrogen storage vessel is connect by the 4th transfer pipeline with the second transfer pipeline, the 4th transfer pipeline and the second conveying
Pipeline is intersected in one first four-way valve；
First triple valve is connect with the first mixer, and the other end of the first mixer is connect with the second triple valve；Two or three
Port valve connects micro fixed-bed reactor by the 5th transfer pipeline；
The other end of the micro fixed-bed reactor connects the 4th triple valve, and the 4th triple valve is also connected with counterbalance valve, counterbalance valve
The other end connect one second four-way valve；
First four-way valve is connect with the second mixer, and the other end of the second mixer is connect with third triple valve；Alcohol moisture
Third triple valve is connected from device, the second triple valve, alcohol-water separation device, methanol liquefying plant, chromatograph connect the second four-way valve；First
Alcohol liquefying plant is connect with methanol collection vessel；The main control module control all parts movement.
6. portable methanol Preparation equipment according to claim 2, it is characterised in that:
The methanol Preparation equipment further include generating electricity by natural energy device, electrolysis wetting system, using solar energy or/and wind energy or/
And bioenergy power generation, water is hydrolyzed to by hydrogen and oxygen by electrolysis wetting system using the electric energy of sending, the hydrogen that will be collected into
Methanol is prepared as with carbon dioxide.
7. a kind of water hydrogen electricity generation system, which is characterized in that the water hydrogen electricity generation system includes: methanol-water reforming hydrogen production device, hydrogen
Fuel cell, methanol Preparation equipment；
The methanol-water reforming hydrogen production device connects hydrogen fuel cell；Methanol-water reforming hydrogen production device is reformed using methanol-water and is made
Hydrogen is delivered to hydrogen fuel cell by hydrogen, and hydrogen fuel cell is equipped with air pump, and oxygen-containing gas is pumped into hydrogen fuel cell by air pump；
Hydrogen fuel cell occurs redox reaction using hydrogen and oxygen and generates electricity；
The methanol Preparation equipment connects methanol-water reforming hydrogen production device, provides methanol feedstock for methanol-water reforming hydrogen production device；
The electric energy that the hydrogen fuel cell issues works for methanol-water reforming hydrogen production device, hydrogen fuel cell, methanol Preparation equipment.
8. water hydrogen electricity generation system according to claim 7, it is characterised in that:
The water hydrogen electricity generation system further includes generating electricity by natural energy equipment, and generating electricity by natural energy equipment includes solar power generation dress
It sets, at least one of wind electricity generating system, hydropower generating device；
The water hydrogen electricity generation system further includes electrolysis wetting system, water is hydrolyzed to hydrogen and oxygen using electric energy, methanol preparation is set
It is standby that the hydrogen being collected into and carbon dioxide are prepared as methanol.
9. water hydrogen electricity generation system according to claim 7, it is characterised in that:
The methanol Preparation equipment includes: nitrogen gas conveying device, hydrogen conveyor, carbon dioxide conveying device, the first mixing
Device, the second mixer, micro fixed-bed reactor, counterbalance valve, alcohol-water separation device, chromatograph, methanol liquefying plant, methanol are collected
Container, main control module；The carbon dioxide conveying device connects the side that the storage container collects carbon dioxide；It is prepared
Methanol be delivered to the methanol water mixed liquid side of storage container；
The nitrogen gas conveying device includes nitrogen storage container, the first transfer pipeline, the first transfer pipeline be equipped with the first shut-off valve,
First mass flowmenter；
The carbon dioxide conveying device includes carbon dioxide storage container, the second transfer pipeline, and the second transfer pipeline is equipped with the
Two shut-off valves, the second mass flowmenter；
The hydrogen conveyor includes hydrogen storage vessel, third transfer pipeline, the 4th transfer pipeline, and third transfer pipeline is set
There are third shut-off valve, third mass flowmenter, the 4th transfer pipeline is equipped with the 4th shut-off valve, the 4th mass flowmenter；
The hydrogen storage vessel is connect by third transfer pipeline with the first transfer pipeline, third transfer pipeline and the first conveying
Pipeline is intersected in one first triple valve；
The hydrogen storage vessel is connect by the 4th transfer pipeline with the second transfer pipeline, the 4th transfer pipeline and the second conveying
Pipeline is intersected in one first four-way valve；
First triple valve is connect with the first mixer, and the other end of the first mixer is connect with the second triple valve；Two or three
Port valve connects micro fixed-bed reactor by the 5th transfer pipeline, and the 5th transfer pipeline is equipped with the 5th mass flowmenter, pressure
Meter；
The other end of the micro fixed-bed reactor connects the 4th triple valve, and the 4th triple valve is also connected with counterbalance valve, counterbalance valve
The other end connect one second four-way valve；
First four-way valve is connect with the second mixer, and the other end of the second mixer is connect with third triple valve；Alcohol moisture
Third triple valve is connected from device, the second triple valve, alcohol-water separation device, methanol liquefying plant, chromatograph connect the second four-way valve；First
Alcohol liquefying plant is connect with methanol collection vessel；The main control module control all parts movement.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2016202962903 | 2016-04-11 | ||
| CN201620296290 | 2016-04-11 |
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| CN209652201U true CN209652201U (en) | 2019-11-19 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201720368717.0U Active CN209652201U (en) | 2016-04-11 | 2017-04-10 | Portable methanol Preparation equipment and water hydrogen electricity generation system |
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| CN (1) | CN209652201U (en) |
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