CN103160345A - Carbinol group clean fuel concoction accessory ingredient and purpose thereof - Google Patents
Carbinol group clean fuel concoction accessory ingredient and purpose thereof Download PDFInfo
- Publication number
- CN103160345A CN103160345A CN2013100457084A CN201310045708A CN103160345A CN 103160345 A CN103160345 A CN 103160345A CN 2013100457084 A CN2013100457084 A CN 2013100457084A CN 201310045708 A CN201310045708 A CN 201310045708A CN 103160345 A CN103160345 A CN 103160345A
- Authority
- CN
- China
- Prior art keywords
- methanol
- weight part
- agent
- clean fuel
- gasoline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Landscapes
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention relates to a carbinol group clean fuel concoction accessory ingredient, a preparation method of the carbinol group clean fuel concoction accessory ingredient and a purpose of the carbinol group clean fuel concoction accessory ingredient. The carbinol group clean fuel concoction accessory ingredient is composed of hydrotropy adjuvant, denaturation improving agent, antioxidant anti-glue agent, synergism complexing agent and combustion improver. The increase of octane value of methanol gasoline which is tempered by the carbinol group clean fuel concoction accessory ingredient is stable. A direct ratio relation exists between additive amount and octane value. Combustion stability of fuel is strengthened, and efficiency of transferring chemical energy into kinetic energy is improved. The carbinol group clean fuel concoction accessory ingredient is good in storage stability and is not prone to causing oxidative deterioration when stored for a long time. Compared with existing gasoline 93 motor gasoline, motor plateau type clean methanol gasoline which is tempered by the carbinol group clean fuel concoction accessory ingredient has the advantages of improving power, reducing emission and reducing environment pollution in high altitude anoxia areas.
Description
[technical field]
The invention belongs to the vehicle fuel technical field.More specifically, the present invention relates to a kind of methanol-based clean fuel blending auxiliary agent, also relate to the preparation method of described methanol-based clean fuel blending auxiliary agent, also relate to the purposes of described methanol-based clean fuel blending auxiliary agent.
[background technology]
Along with the minimizing increasingly of prospective oil in world wide, China's oil resource import volume is but being increased sharply year by year.statistics according to national alcohol-ether fuel and alcohol ether cleaning vehicle Professional Committee, present national automobile pollution reaches more than 7,000 ten thousand, year consumes more than 200,000,000 ton of processed oil, approximately 1,000 ten thousand, annual newly-increased automobile, need newly-increased processed oil to consume more than 2,000 ten thousand ton/years and (do not contain railway, civil aviaton, the consumption of shipping), newly-increased 2,000 ten thousand ton/years of oil-refining capacities though country has the ability, but the bottleneck that crude oil import is worldwide implemented will be more serious, China has become the second-biggest-in-the-world oil consuming countries now, petroleum import in this year amount is over 200,000,000 tons, if rely on Imported oil to make up fully, national economy and social development will enter " oil restriction risk phase ".Current national for this situation, is being just that the encourage consumer chooses automobile with small output volume at Adopts measure on the one hand, reduces energy consumption; The popularization that increases new energy technology on the other hand, substitute the finished product oil consumption, as the methanol gasoline of traditional energy to the new forms of energy transition, be at present feasible, the most real selection, and what the methanol gasoline quality was played key effect is exactly " blending of fuel auxiliary agent ".At present, China scientific worker has carried out broad research to this blending of fuel auxiliary agent, for example CN 1124277A discloses a kind of multiple effect compound additive for gasoline and preparation method thereof, this additive is comprised of methyl tertiary butyl ether, dimethylbenzene and isopropanol mixture, 501 antioxidizing and antigum agents (2,2-ditertbutylparacresol), lauryl methacrylate and methyl cyclopentadienyl tricarbonyl manganese.CN 1239732A discloses a kind of liquid methanol fuel, and it is by methyl alcohol, gasoline and antioxidizing and antigum agent 2, and 6-toluene di-tert-butyl phenol, sanitising agent succimide, smoke suppressor hydrogen peroxide and four kinds of additives of deodovization agent Glacial acetic acid form.CN 101122301A discloses a kind of carbinol gasoline fuel and manufacture method thereof.This fuel is comprised of gasoline, methyl alcohol, sherwood oil, Methylal(dimethoxymethane), octane, toluene, diethyl carbonate, octane-iso, 2-ethylenedioxy ethyl acetate, dibutyl phosphite, ethyl acetate, 3-dihydroxyl butane, ether, isopropyl ether, second acetone, phenylcarbinol, 501 oxidation inhibitor, di-t-butyl, ethanol and corrosion inhibitor.CN 10264391A discloses a kind of gasoline composite additive, it is comprised of gasoline detergent polyisobutene amine and polyetheramine mixture, ignition dope itroparaffin compound, cold-starting rising agent ethyl acetate or acetone, octane promoter methyl tertiary butyl ether, antioxidizing and antigum agent 2,6 ditertiary butyl p cresol, metal corrosion inhibitor benzotriazole or azimido-toluene, solubility promoter toluene or dimethylbenzene.Although these prior aries have obtained good progress, but still there are some more serious technological deficiencies, therefore affect its widespread use.
Therefore, the inventor by great many of experiments and analysis thereof, has completed the present invention finally on the basis of summing up prior art.
[summary of the invention]
[technical problem that will solve]
The purpose of this invention is to provide a kind of methanol-based clean fuel blending auxiliary agent.
Another object of the present invention is to provide the preparation method of described methanol-based clean fuel blending auxiliary agent.
Another object of the present invention is to provide the purposes of described methanol-based clean fuel blending auxiliary agent.
[technical scheme]
The present invention is achieved through the following technical solutions.
The present invention relates to a kind of methanol-based clean fuel blending auxiliary agent.This blending auxiliary agent is comprised of 45 ~ 80 weight part hydrotropy standard-increasing agents, 3 ~ 25 weight part sex change improving agents, 0.005 ~ 0.02 weight part antioxidizing and antigum agent, 3 ~ 20 weight part synergy recombiners and 10 ~ 30 portions of ignition dopes; Wherein:
Described hydrotropy standard-increasing agent is comprised of according to weight ratio 45 ~ 80:0 ~ 15 methyl tertiary butyl ether and methyl methacrylate;
Described sex change improving agent is comprised of according to weight ratio 3 ~ 25:0 ~ 12 methyl cyclopentyl-dialkyl-tricarbon manganium and ethylene glycol ethyl ether;
Described antioxidizing and antigum agent is 2,6 ditertiary butyl p cresol;
Described synergy recombiner is comprised of according to weight ratio 3 ~ 20:5 ~ 10 secondary octanol and isooctyl alcohol;
Described ignition dope is mixed according to weight ratio 10 ~ 30:5 ~ 25:10 ~ 20 with primary isoamyl alcohol by Virahol, the trimethyl carbinol and forms.
A preferred embodiment of the invention, this blending auxiliary agent is comprised of 55 ~ 72 weight part hydrotropy standard-increasing agents, 8 ~ 20 weight part sex change improving agents, 0.008 ~ 0.016 weight part antioxidizing and antigum agent, 6 ~ 15 weight part synergy recombiners and 14 ~ 25 portions of ignition dopes.
More preferably, this blending auxiliary agent is comprised of 60 ~ 68 weight part hydrotropy standard-increasing agents, 12 ~ 16 weight part sex change improving agents, 0.010 ~ 0.012 weight part antioxidizing and antigum agent, 8 ~ 12 weight part synergy recombiners and 18 ~ 20 portions of ignition dopes.
The invention still further relates to the preparation method of described methanol-based clean fuel blending auxiliary agent.This preparation method's step is as follows:
Allow 45 ~ 80 weight part hydrotropy standard-increasing agents, 3 ~ 25 weight part sex change improving agents, 0.005 ~ 0.02 weight part antioxidizing and antigum agent, 3 ~ 20 weight part synergy recombiners disperse fully in static mixer and to mix with 10 ~ 30 weight part ignition dopes, obtain described methanol-based clean fuel blending auxiliary agent; Wherein:
Described hydrotropy standard-increasing agent is comprised of according to weight ratio 45 ~ 80:0 ~ 15 methyl tertiary butyl ether and methyl methacrylate;
Described sex change improving agent is comprised of according to weight ratio 3 ~ 25:0 ~ 12 methyl cyclopentyl-dialkyl-tricarbon manganium and ethylene glycol ethyl ether;
Described antioxidizing and antigum agent is 2,6 ditertiary butyl p cresol;
Described synergy recombiner is comprised of according to weight ratio 3 ~ 20:5 ~ 10 secondary octanol and isooctyl alcohol;
Described ignition dope is mixed according to weight ratio 10 ~ 30:5 ~ 25:10 ~ 20 with primary isoamyl alcohol by Virahol, the trimethyl carbinol and forms.
The invention still further relates to the purposes of described methanol-based clean fuel blending auxiliary agent in methanol gasoline or diesel oil.
A preferred embodiment of the invention when methanol gasoline or diesel oil, adds described methanol-based clean fuel blending auxiliary agent in methyl alcohol or diesel oil, its add-on is 2 ~ 15% of methanol gasoline or diesel oil gross weight.
The below will describe the present invention in more detail.
The present invention relates to a kind of methanol-based clean fuel blending auxiliary agent.
Vehicular methanol petrol is playing active effect as a kind of New-type fuel aspect energy substitution, reduction exhaust emissions and exploitation Downstream Products of Methanol.Produce the required methanol gasoline of Vehicular methanol petrol and concoct the final quality that auxiliary agent has determined Vehicular methanol petrol.Use automobile-used plateau type denatured fuel methyl alcohol and the different varieties motor spirit of the production of methanol-based clean fuel blending auxiliary agent should have good dispersion stabilization, its shelf lives is not less than 6 months; Improve octane value, and its adding proportion and the sexual intercourse of octane value retention wire; Its corrosive nature is not less than " motor spirit " national standard; Be not less than " motor spirit " national standard the inductive phase in the standing storage process; The tail gas quantity discharged reduces 20% ~ 30% than gasoline product discharge of poisonous waste total amount under high and cold anoxia condition.Its dynamic performance, economic performance remain unchanged under high and cold anoxia condition.
This blending auxiliary agent is comprised of 45 ~ 80 weight part hydrotropy standard-increasing agents, 3 ~ 25 weight part sex change improving agents, 0.005 ~ 0.02 weight part antioxidizing and antigum agent, 3 ~ 20 weight part synergy recombiners and 10 ~ 30 portions of ignition dopes.
In the present invention, described hydrotropy standard-increasing agent is comprised of according to weight ratio 45 ~ 80:0 ~ 15 methyl tertiary butyl ether and methyl methacrylate, they are all product solds in the market, for example the methyl tertiary butyl ether sold of Beijing swallow fossilisation limited-liability company, organic synthesis factory of Jilin Chemical Industrial Co. Ltd.; The methyl methacrylate that Guangzhou wide well trade Co., Ltd, emerging Shandong, Zibo City chemical industry company limited sell.This hydrotropy standard-increasing agent can make the methanol gasoline octane value of production greater than 97RON, and can impel methanol gasoline complete in the engine internal combustion; Can improve the appearance outlet capacity of methanol gasoline; Can improve anti-bed resolution, methanol gasoline still is not separated under the environment of temperature-38 ℃, improve the stability of methyl alcohol and gasoline mixed solution; Can reduce the discharging of CO in vehicle exhaust, HC and other objectionable impuritiess.Except methyl tertiary butyl ether and methyl methacrylate; every have above-mentioned these performances; these chemical substances that can not damage again methanol-based clean fuel blending additive performance of the present invention may be used to the present invention, and also within protection scope of the present invention.
Preferably, described hydrotropy standard-increasing agent is comprised of according to weight ratio 55 ~ 70:4 ~ 10 methyl tertiary butyl ether and methyl methacrylate.More preferably, described hydrotropy standard-increasing agent is comprised of according to weight ratio 60 ~ 65:6 ~ 8 methyl tertiary butyl ether and methyl methacrylate.
In the present invention, described sex change improving agent is comprised of according to weight ratio 3 ~ 25:0 ~ 12 methyl cyclopentyl-dialkyl-tricarbon manganium and ethylene glycol ethyl ether, they are all product solds in the market, for example the methyl cyclopentyl-dialkyl-tricarbon manganium sold of Jiahe, Shandong methyl chemical industry company limited, the triumphant chemical industry of Nanjing maistre company limited; The ethylene glycol ethyl ether that the south of the River, Nanning chemical inc, Nanjing chemical industry company limited of space section sell.It is poor that described sex change improving agent has the polarity that reduces between alcohol oil, profit, reduces the performance of interfacial tension.Except methyl cyclopentyl-dialkyl-tricarbon manganium and ethylene glycol ethyl ether; every have above-mentioned these performances; these chemical substances that can not damage again methanol-based clean fuel blending additive performance of the present invention may be used to the present invention, and also within protection scope of the present invention.
Preferably, described sex change improving agent is comprised of according to weight ratio 6 ~ 20:2 ~ 10 methyl cyclopentyl-dialkyl-tricarbon manganium and ethylene glycol ethyl ether.More preferably, described sex change improving agent is comprised of according to weight ratio 10 ~ 15:4 ~ 8 methyl cyclopentyl-dialkyl-tricarbon manganium and ethylene glycol ethyl ether.
Described hydrotropy standard-increasing agent is 45 ~ 80 weight parts, and the amount of described sex change improving agent can cause stability in storage to reduce during less than 3 weight part, produces alcohol separating of oil, and other beneficial effects of hydrotropy standard-increasing agent can't be realized; The amount of described sex change improving agent can increase product cost again during greater than 25 weight part, and causes that in use procedure, the residues of combustion particulate matter increases, and discharge of poisonous waste exceeds standard, and seriously violates emission standard; Therefore, when described hydrotropy standard-increasing agent was 45 ~ 80 weight part, the amount of described sex change improving agent was that 5 ~ 25 weight parts are suitable.
In the present invention, described antioxidizing and antigum agent is 2,6 ditertiary butyl p cresol.It is product sold in the market, for example the precious chemical industry of Binzhou nation company limited, Nanjing Ning Kang chemical industry company limited product sold.2,6 ditertiary butyl p cresol (T501 antioxidizing and antigum agent) belongs to the phenols antioxidizing and antigum agent, has antioxygen property preferably, and its working temperature is in the time of 100 ℃, and antioxidant effect is best.It can be combined with the superoxide that described fuel produces in oxidising process, form hydroperoxide, the oil oxidation process is interrupted, thereby stop oxidising process to be carried out, and 2,6 ditertiary butyl p cresol itself forms the antioxidant free radical, and it can form stable dimer, or be combined the intermediate product combination that forms stable compound with peroxylradicals ROO, thereby oxidizing reaction can't be occured.2,6-ditertbutylparacresol toxicity is extremely low, and nearly 40 countries in the whole world allow 2,6 ditertiary butyl p cresol as directly or indirectly foodstuff additive use, China allows use and formulated the use hygienic standard, and the exempt quantities of using separately in food is 0.2gkg.Except 2,6 ditertiary butyl p cresol, every have an above-mentioned performance, and these chemical substances that can not damage again methanol-based clean fuel blending additive performance of the present invention may be used to the present invention, and also within protection scope of the present invention.
Described hydrotropy standard-increasing agent is 45 ~ 80 weight parts, and the amount of described antioxidizing and antigum agent can not reach the required effect of product during less than 0.005 weight part, and corrosion is increased, and antioxidant property reduces; The amount of described antioxidizing and antigum agent can cause again heavy metals emission to exceed standard during greater than 0.02 weight part, or lodges in engine cylinder-body and blowdown system forms mechanical fault; Therefore, when described hydrotropy standard-increasing agent was 45 ~ 80 weight part, the amount of described antioxidizing and antigum agent was that 0.005 ~ 0.02 weight part is suitable.
In the present invention, described synergy recombiner is comprised of according to weight ratio 3 ~ 20:5 ~ 10 secondary octanol and isooctyl alcohol, and they are all general product solds in the market.Secondary octanol and isooctyl alcohol be as the higher alcohols that can mix in any proportion with methyl alcohol, and the effect with promotion methyl alcohol solubleness in gasoline can improve the oil soluble of methyl alcohol effectively together with other fusel class material.Except secondary octanol and isooctyl alcohol, every have an above-mentioned performance, and these chemical substances that can not damage again methanol-based clean fuel blending additive performance of the present invention may be used to the present invention, and also within protection scope of the present invention.
Preferably, described synergy recombiner is comprised of according to weight ratio 6 ~ 16:6 ~ 8 secondary octanol and isooctyl alcohol.More preferably, described synergy recombiner is comprised of according to weight ratio 8 ~ 12:6 ~ 8 secondary octanol and isooctyl alcohol.
Described hydrotropy standard-increasing agent is 45 ~ 80 weight parts, and the amount of described synergy recombiner can make the methyl alcohol oil soluble weaken during less than 3 weight part, and the dispersiveness of methanol solution does not reach service requirements; The amount of described synergy recombiner is during greater than 20 weight part, again can cost up, reduce the product economy performance; Therefore, when described hydrotropy standard-increasing agent was 45 ~ 80 weight part, the amount of described synergy recombiner was that 3 ~ 20 weight parts are suitable.
In the present invention, described ignition dope is mixed according to weight ratio 10 ~ 30:5 ~ 25:10 ~ 20 with primary isoamyl alcohol by Virahol, the trimethyl carbinol and forms, and they are all general product solds in the market.Virahol is the fusel through the single form of screening, main effect improves the methyl alcohol oil soluble jointly with higher alcohols on the one hand, on the other hand by being combined with the superoxide that the gasoline hydrocarbon quasi-molecule produces under the condition of high temperature, improve the capability of antidetonance, make combustion processes even, increase engine power performance, methanol gasoline is directly played combustion-supporting effect.
Preferably, described ignition dope is mixed according to weight ratio 14 ~ 24:8 ~ 18:12 ~ 18 with primary isoamyl alcohol by Virahol, the trimethyl carbinol and forms.More preferably, described ignition dope is mixed according to weight ratio 18 ~ 20:10 ~ 16:14 ~ 16 with primary isoamyl alcohol by Virahol, the trimethyl carbinol and forms.
Described hydrotropy standard-increasing agent is 45 ~ 80 weight parts, and the amount of described ignition dope can in use be burnt insufficient during less than 10 weight part, forms carbon distribution and HC discharging, reduces motor efficiency, increases oil consumption; The amount of described ignition dope can both increase cost again during greater than 30 weight part, reduces the product economy performance, improves again the corrosion risk to metallic facility in oil circuit and engine; Therefore, when described hydrotropy standard-increasing agent was 45 ~ 80 weight part, the amount of described ignition dope was that 10 ~ 30 weight parts are suitable.
A preferred embodiment of the invention, blending auxiliary agent of the present invention is comprised of 55-72 weight part hydrotropy standard-increasing agent, 8-20 weight part sex change improving agent, 0.008-0.016 weight part antioxidizing and antigum agent, 6-15 weight part synergy recombiner and 14-25 part ignition dope.
More preferably, blending auxiliary agent of the present invention is comprised of 60-68 weight part hydrotropy standard-increasing agent, 12-16 weight part sex change improving agent, 0.010-0.012 weight part antioxidizing and antigum agent, 8-10 weight part synergy recombiner and 18-20 part ignition dope.
The invention still further relates to the preparation method of described methanol-based clean fuel blending auxiliary agent.This preparation method's step is as follows:
Allow 45 ~ 80 weight part hydrotropy standard-increasing agents, 3 ~ 25 weight part sex change improving agents, 0.005 ~ 0.02 weight part antioxidizing and antigum agent, 3 ~ 20 weight part synergy recombiners disperse fully in static mixer and to mix with 10 ~ 30 weight part ignition dopes, obtain described methanol-based clean fuel blending auxiliary agent.
Described static mixer is a kind of high-efficiency mixing device that there is no moving parts, its groundwork mechanism is to utilize the flow state of mixed cell structural reform fluid in pipe that is fixed in pipe, to reach good distribution and well-mixed purpose between different fluid.Since 20 century 70s, static mixer just begins to be applied in industries such as chemical industry, foodstuffs industry, weaving light industry, biology, environmental protection, and obtains good achievement.Static mixer is compared with miscellaneous equipments such as orifice plate post, Venturi meter, agitator, homogenizers and is had that efficient is high, energy consumption is low, volume is little, reduced investment, is easy to serialization production.The static mixer that the present invention uses is product sold in the market, for example the static mixer sold of Beijing Chu Guan Science and Technology Ltd., the metallurgical petrochemical machinery of Nantong Zhong Te company limited.
Described hydrotropy standard-increasing agent is comprised of according to weight ratio 45 ~ 80:0 ~ 15 methyl tertiary butyl ether and methyl methacrylate;
Described sex change improving agent is comprised of according to weight ratio 3 ~ 25:0 ~ 12 methyl cyclopentyl-dialkyl-tricarbon manganium and ethylene glycol ethyl ether;
Described antioxidizing and antigum agent is 2,6 ditertiary butyl p cresol;
Described synergy recombiner is comprised of according to weight ratio 3 ~ 20:5 ~ 10 secondary octanol and isooctyl alcohol;
Described ignition dope is mixed according to weight ratio 10 ~ 30:5 ~ 25:10 ~ 20 with primary isoamyl alcohol by Virahol, the trimethyl carbinol and forms.
The particular case of described hydrotropy standard-increasing agent, sex change improving agent, antioxidizing and antigum agent, synergy recombiner and ignition dope is described in detail in front, does not repeat them here.
The invention still further relates to the purposes of described methanol-based clean fuel blending auxiliary agent in methanol gasoline or diesel oil.
When methanol gasoline or diesel oil, add described methanol-based clean fuel blending auxiliary agent in methyl alcohol or diesel oil, its add-on is 2 ~ 15% of methanol gasoline or diesel oil gross weight.
Use methanol-based clean fuel blending auxiliary agent of the present invention to carry out dispersion stabilization, octane value, metallic corrosion, inductive phase, the test of exhaust emissions amount, driving bench testing and road travel test.
A, dispersion stabilization test
according to weight ratio 3-10%, methanol-based clean fuel blending auxiliary agent of the present invention and fuel methanol are concocted the automobile-used plateau type denatured fuel of the present invention methyl alcohol that obtains, 90# with the production of Dushanzi, Xinjiang refinery, the 93# naphthenic base oils, the 90# that Daqing petrochemical company is produced, the 93# paraffin base oil, the 90# that Lanzhou Petrochemical Company is produced, 93# intermediate base base oil, become automobile-used plateau type clean methanol gasoline with M15 ratio proportioning, under the prerequisite that obvious disturbance does not occur, lucifuge is placed on the air test chamber without lagging facility, sample temperature changes and synchronizes with outside air temperature, routine observation is oily per month, the alcohol separating interface, determine automobile-used plateau type clean methanol gasoline dispersion stabilization, its test-results is listed in accompanying drawing 1 and accompanying drawing 2.adopt this test method to draw, when reaching 5%, methanol-based clean fuel blending auxiliary agent content of the present invention (stores the quality guarantee period (" PetroChina Company Ltd.'s processed oil stores relevant regulations ") of 6 months according to processed oil, dispersed target is to separate out 0.3% target value (GB17930-2011 regulation), due to methanol-based clean fuel blending auxiliary agent content and dispersing property relation in direct ratio, it is 0.3% the time of separating out not meet standard when following that content reaches 5%), the dispersion stabilization index meets separated out ratio in 6 months less than the gasoline moisture content index requirement of 0.3% GB17930-2011.
B, octane value test
The automobile-used plateau type denatured fuel of the present invention methyl alcohol that uses 10 % by weight methanol-based clean fuel blending of the present invention auxiliary agent blendings to obtain, be mixed with automobile-used plateau type clean methanol gasoline according to different ratios and different varieties motor spirit, measure the octane value of automobile-used plateau type clean methanol gasoline according to the octane number determination method of routine, its test-results is listed in accompanying drawing 3 and accompanying drawing 4.These test-results show, the automobile-used plateau type denatured fuel of the present invention methyl alcohol addition in 30 % by weight, for all kinds of oil products, the every increase by 5% of the addition of denatured methyl alcohol, their octane value just increases 1RON.Addition and the octane value of methanol-based clean fuel blending auxiliary agent of the present invention are a proportional relationship.
C, metal corrosion test
90#, the 93#, the 97# intermediate base base oil that adopt petroleum products copper strip test method (GB/T5096-1985) to use 90#, the 93# of the production of Dushanzi, Xinjiang refinery, 97# naphthenic base oils, 90#, the 93# of Daqing petrochemical company production, 97# paraffin base oil, Lanzhou Petrochemical Company to produce use the automobile-used plateau type denatured fuel of the present invention methyl alcohol to be mixed with automobile-used plateau type clean methanol gasoline with the M30 ratio and have carried out metal corrosion test.These test-results are listed in the table below 1.
Table 1: various gasoline corrosion test-results
According to the concerned countries standard, result is not more than 1 grade for qualified, and above result all meets the requirements.
D, inductive phase are measured
90#, 93#, 97# intermediate base base oil that 90#, 93#, 97# paraffin base oil, the Lanzhou Petrochemical Company that adopts the stable assay method (GB/T8018-1987) of gasoline oxidation to use 90#, 93#, 97# naphthenic base oils, the Daqing petrochemical company of the production of Dushanzi, Xinjiang refinery to produce produced use the automobile-used plateau type denatured fuel of the present invention methyl alcohol to be mixed with automobile-used plateau type clean methanol gasoline with the M30 ratio and have carried out mensuration inductive phase.These measurement results are listed in the table below 2.
Table 2: various breakdown time measurement results
According to the regulation of GB/T8018-1987, it is qualified being not less than 480min inductive phase.Therefore, these induction period of gasoline are all up to specification.
E, the test of exhaust emissions amount
90#, the 93#, the 97# intermediate base base oil that use 90#, 93#, 97# paraffin base oil, Lanzhou Petrochemical Company that 90#, 93#, 97# naphthenic base oils, Daqing petrochemical company that the Dushanzi, Xinjiang refinery is produced are produced to produce use the automobile-used plateau type denatured fuel of the present invention methyl alcohol to be mixed with automobile-used plateau type clean methanol gasoline with M15, M30, M85 ratio and have carried out the test of exhaust emissions amount.According to design requirements discharge of poisonous waste total amount after using described gasoline, be not less than 25% with respect to 93# gasoline decreased average.Actual detected result is listed in table 3.
Table 3: the discharge of poisonous waste total amount detected result of various gasoline
F, carry out the driving bench testing
The research vehicle motor is to M15 (93#), the M30 (97#) of above-mentioned use denatured methyl alcohol blending, the adaptation situation of M85 Vehicular methanol petrol, and its result is as follows respectively:
1、M15(93＃)
A, 4G15S gasoline M15 Vehicular methanol petrol and use the 93# steam oil ratio (SOR), external characteristics is at 4200r/min, and power rising 4.4kw is 9.1%; Effectively specific fuel consumption on average rises 3.3%.
B, 4G15S gasoline M15 Vehicular methanol petrol and use the 93# steam oil ratio (SOR), on 2000r/min, 2400r/min, 3000r/min, 3400r/min part throttle characteristics effectively specific fuel consumption rise respectively 7.35%, 7.11%, 7.63%, 5.39%; On average risen 6.87%.
C, 4G15S gasoline M15 Vehicular methanol petrol and use the 93# steam oil ratio (SOR), under idling (900r/min) operating mode, the CO quantity discharged drops to 0.10% by 0.15%; The HC quantity discharged drops to 40ppm by 53ppm; Under high idle speed (2500r/min) operating mode, the CO quantity discharged drops to 0.51% by 0.57%; The HC quantity discharged drops to 74ppm by 89ppm;
2、、M30(97＃)
A, 4G15S gasoline M30 Vehicular methanol petrol and use the 93# steam oil ratio (SOR), external characteristics is at 4200r/min, and power decline 0.1kw is 0.21%; Effectively specific fuel consumption on average rises 5.47%.
B, 4G15S gasoline M30 Vehicular methanol petrol and use the 93# steam oil ratio (SOR), on 2000r/min, 2400r/min, 3000r/min, 3400r/min part throttle characteristics effectively specific fuel consumption rise respectively 13.69%, 14.57%, 13.19%, 14.11%; On average risen 13.89%.
C, 4G15S gasoline M30 Vehicular methanol petrol and use the 93# steam oil ratio (SOR), under idling (900r/min) operating mode, the CO quantity discharged drops to 0.11% by 0.15%; The HC quantity discharged drops to 45ppm by 53ppm; Under high idle speed (2500r/min) operating mode, the CO quantity discharged drops to 0.54% by 0.57%; The HC quantity discharged drops to 57ppm by 89ppm;
3、M85
A, 4G15S gasoline M85 Vehicular methanol petrol and use the 93# steam oil ratio (SOR), external characteristics is at 4200r/min, and power rising 1.5kw is 3.1%; Effectively specific fuel consumption on average rises 47.3%.
B, 4G15S gasoline M85 Vehicular methanol petrol and use the 93# steam oil ratio (SOR), on 2000r/min, 2400r/min, 3000r/min, 3400r/min part throttle characteristics effectively specific fuel consumption rise respectively 47.3%, 44.6%, 42.3%, 45.5%; On average risen 44.9%.
C, 4G15S gasoline M85 Vehicular methanol petrol and use the 93# steam oil ratio (SOR), under idling (900r/min) operating mode, the CO quantity discharged drops to 0.09% by 0.15%; The HC quantity discharged drops to 37ppm by 53ppm; Under high idle speed (2500 r/min) operating mode, the CO quantity discharged drops to 0.54% by 0.57%; The HC quantity discharged drops to 46ppm by 89ppm;
G, carry out road travel test
This test is main understands methanol gasoline to impact and the oil consumption of overall vehicle.
Take M15(93#) as main, experiment uses the vehicle experimental period more than 5 years, 132080 kilometers of total kilometres, 12080 liters of the automobile-used plateau type clean methanol gasolines of wastage in bulk or weight are counted 9.06 tons, and 2021.2 liters of mean consumption replacing gasoline consumptions are counted 1.516 tons.the provinces and cities that experiment is passed through are respectively Qinghai, Tibet, Gansu, Shaanxi, Henan, Anhui, Jiangsu, Zhejiang, Shanghai, there is again the Plain on these regional existing plateaus, existing cold and dry area also has coastal damp-heat area, contained national various amblent air temperature condition with typical feature, contrast arranges the result demonstration to related data, use automobile-used plateau type clean methanol gasoline M15 to increase 3.2-3.7% than petrochemical industry gasoline in the plains region oil consumption, increase 3.0-3.3% in the district's oil consumption of height above sea level 1500-3000 meter, reduce 1.0-2.1% in the district's oil consumption of height above sea level 3000-5000 meter, vehicle occurs without air-resistance phenomenon in damp and hot and highlands, the every running condition of engine is good, to fuel tank, oil circuit, piston, cylinder, the rubber parts of vapor pipe and fuel oil contact is without obviously corroding and swelling, startability is identical with petrochemical industry gasoline, use the methanol gasoline M15 of methanol-based clean fuel blending, can keep the former mechanomotive force of engine below 3000 meters at height above sea level, and the Power and fuel consumption rate all has trace to rise, but along with the further rising of height above sea level, dynamic property rises than petrochemical industry gasoline, and specific fuel consumption descends to some extent.
Through experiment in a few years, use the actual performance index of methanol-based clean fuel blending auxiliary agent blending methanol gasoline all to reach following re-set target:
1) methanol-based clean fuel of the present invention blending additive dosage reaches 5%～15%, and methyl alcohol and all kinds of motor spirit can be dissolved each other by arbitrary proportion, separates out for 5% methyl alcohol time limit greater than 360 days after being mixed into automobile-used plateau type clean methanol gasoline; Within 120 days shelf liveves, separate out without obvious methyl alcohol, a small amount of methyl alcohol that standing storage is separated out still can dissolve each other with former mixed solution through the disturbance of unloading, and physico-chemical property is consistent with new preparation mixed solution;
2) the automobile-used plateau type clean methanol gasoline that uses methanol-based clean fuel blending auxiliary agent of the present invention and methyl alcohol and motor spirit to concoct, every interpolation 5% methanol-based clean fuel blending auxiliary agent and methyl alcohol mixed liquor, research octane number (RON) increases by 1 unit, comparatively remarkable to paraffinic base gasoline effect, the denatured methyl alcohol of this auxiliary agent blending can improve the octane value of gasoline effectively, improve on the one hand gasolines, reduce the addition of octane enhancing additive in gasoline, reduce production costs.Improve with octane value on the other hand, fuel combustion stability strengthens, and unit volume fuel output rating increases, the vehicle power increase.Due to flameholding, reduce than petrochemical industry gasoline the infringement of motor car engine is corresponding;
3) the automobile-used plateau type clean methanol gasoline that uses methanol-based clean fuel blending auxiliary agent of the present invention and methyl alcohol, motor spirit to concoct, copper corrosion reaches the 1a level, meet the requirements fully, illustrate that this auxiliary agent can suppress the methanol activity base to the corrosive nature of metallic substance;
4) the automobile-used plateau type clean methanol gasoline that uses methanol-based clean fuel blending auxiliary agent of the present invention and methyl alcohol and different varieties motor spirit to concoct, inductive phase is in 600～699 minutes scopes, stability in storage is good, can satisfy the requirement that stores more than 3 months;
5) due to not sulfur-bearing and other complex organic compounds in methanol-based clean fuel blending auxiliary agent and methyl alcohol, the methyl alcohol oxygen level is higher simultaneously, sufficient combustion, CO, HC, SO in tail gas
2, NO
XWith the pollutents such as suspended substance seldom, objectionable impurities is still less.The automobile-used plateau type clean methanol gasoline that uses methanol-based clean fuel blending auxiliary agent and methyl alcohol and different varieties motor spirit to concoct, the discharge of poisonous waste total amount reduces 20%～25% in vehicle uses.
6) the driving bench testing shows, uses methanol gasoline can increase power of vehicle 4.4kw, rises 9.1%; Effectively specific fuel consumption on average rises 3.3%, and cost effectiveness has significantly raising than petrochemical industry gasoline, is not considering that under the prerequisite of methanol gasoline cost lower than petrochemical industry gasoline, comprehensive benefit is also higher than petrochemical industry gasoline.
7) driving experiment showed, and uses automobile-used plateau type clean methanol gasoline M15 to increase 3.2-3.7% than petrochemical industry gasoline 93# in the plains region oil consumption, and power increases 8-9%, can keep the former mechanomotive force of engine below 3000 meters at height above sea level; At height above sea level 3000-5000 rice, dynamic property rises than petrochemical industry gasoline, and specific fuel consumption reduces 1.0-2.1%.Produce this impact mainly due to the highlands atmosphere force down, the absolute value of oxygen level is few in unit volume, the vehicle actual compression ratio of exercising on the plateau is far smaller than plains region, interior ground, at 4000 meters height of height above sea level, actual compression ratio only has 50% of nominal, when using petrochemical industry gasoline, because of oxygen for quantity not sufficient, part of fuel or be thermal decomposited into carbon granule, or with former chemical state discharging, power is not increased and make contributions.And methanol gasoline is oxygenated fuel due to methyl alcohol itself, and the demand to oxygen in burning is low than petrochemical industry gasoline, and higher than gasoline at the complete transformation efficiency of highlands fuel, especially gasoline of high proportion methanol M30 effect is more obvious.Therefore methanol gasoline is good at the regional accelerating ability of high altitude anoxia, the power variation is less, has reduced the altitude sickness of gasoline vehicle, and the automobile-used plateau type clean methanol gasoline of concocting with methanol-based clean fuel blending auxiliary agent is particularly suitable in high altitude anoxia area use.
In this manual, M15 should be appreciated that it is the modified methanol that uses methanol-based clean fuel blending auxiliary agent of the present invention blending, is that 15:85 concocts the automobile-used plateau type clean methanol gasoline that obtains according to the weight ratio of modified methanol and gasoline.
M30 should be appreciated that it is the modified methanol that uses methanol-based clean fuel blending auxiliary agent of the present invention blending, is that 30:70 concocts the automobile-used plateau type clean methanol gasoline that obtains according to the weight ratio of modified methanol and gasoline.
Automobile-used plateau type denatured fuel methyl alcohol all should be appreciated that it is the modified methanol that uses methanol-based clean fuel blending auxiliary agent of the present invention blending to obtain.
[beneficial effect]
Beneficial effect of the present invention is as follows: use the octane value increase of methanol-based clean fuel blending auxiliary agent blending methanol gasoline of the present invention stable, there are proportional relation in addition and octane value, can strengthen fuel combustion stability, improve the efficient that chemical energy is converted into kinetic energy; Stability in storage is good, and standing storage is difficult for deterioration by oxidation; Take existing 93# motor spirit as reference, use the automobile-used plateau type clean methanol gasoline with the blending of methanol-based clean fuel blending auxiliary agent, have in the high altitude anoxia area advantage that improves power, reduces discharging, environmental contamination reduction.
[description of drawings]
Fig. 1 is the automobile-used plateau type clean methanol gasoline of 90# dispersion stabilization figure;
Fig. 2 is the automobile-used plateau type clean methanol gasoline of 93# dispersion stabilization figure;
Fig. 3 is the automobile-used plateau type clean methanol gasoline of 90# octane value variation diagram;
Fig. 4 is the automobile-used plateau type clean methanol gasoline of 93# octane value variation diagram.
[embodiment]
Can understand better the present invention by following embodiment.
Embodiment 1: the preparation of methanol-based clean fuel blending auxiliary agent
The implementation step of this embodiment is as follows:
At first, methyl tertiary butyl ether and methyl methacrylate are obtained a kind of hydrotropy standard-increasing agent according to weight ratio 45:4 preparation;
Methyl cyclopentyl-dialkyl-tricarbon manganium and ethylene glycol ethyl ether are obtained a kind of sex change improving agent according to weight ratio 6:0 preparation;
Secondary octanol and isooctyl alcohol are obtained a kind of synergy recombiner according to weight ratio 16:5 preparation;
Virahol, the trimethyl carbinol and primary isoamyl alcohol are obtained a kind of ignition dope according to weight ratio 24:18:14 preparation;
Then allow hydrotropy standard-increasing agent, the sex change improving agent of the 25 above-mentioned preparations of weight part, 0.005 weight part 2 of the 60 above-mentioned preparations of weight part, the synergy recombiner of 6-ditertbutylparacresol antioxidizing and antigum agent, the 8 above-mentioned preparations of weight part disperses fully and mixes in the static mixer that Beijing Chu Guan Science and Technology Ltd. sells with the ignition dope of the 14 above-mentioned preparations of weight part, obtains methanol-based clean fuel blending auxiliary agent of the present invention.
Embodiment 2: the preparation of methanol-based clean fuel blending auxiliary agent
The implementation step of this embodiment is as follows:
At first, methyl tertiary butyl ether and methyl methacrylate are obtained a kind of hydrotropy standard-increasing agent according to weight ratio 80:0 preparation;
Methyl cyclopentyl-dialkyl-tricarbon manganium and ethylene glycol ethyl ether are obtained a kind of sex change improving agent according to weight ratio 20:4 preparation;
Secondary octanol and isooctyl alcohol are obtained a kind of synergy recombiner according to weight ratio 8:10 preparation;
Virahol, the trimethyl carbinol and primary isoamyl alcohol are obtained a kind of ignition dope according to weight ratio 18:5:16 preparation;
Then allow hydrotropy standard-increasing agent, the sex change improving agent of the 8 above-mentioned preparations of weight part, 0.02 weight part 2 of the 68 above-mentioned preparations of weight part, the synergy recombiner of 6-ditertbutylparacresol antioxidizing and antigum agent, the 10 above-mentioned preparations of weight part and the ignition dope of the 25 above-mentioned preparations of weight part disperse fully and mix in the static mixer that the metallurgical petrochemical machinery of Nantong Zhong Te company limited sells, and obtain methanol-based clean fuel blending auxiliary agent of the present invention.
Embodiment 3: the preparation of methanol-based clean fuel blending auxiliary agent
The implementation step of this embodiment is as follows:
At first, methyl tertiary butyl ether and methyl methacrylate are obtained a kind of hydrotropy standard-increasing agent according to weight ratio 55:1 preparation;
Methyl cyclopentyl-dialkyl-tricarbon manganium and ethylene glycol ethyl ether are obtained a kind of sex change improving agent according to weight ratio 3:8 preparation;
Secondary octanol and isooctyl alcohol are obtained a kind of synergy recombiner according to weight ratio 3:6 preparation;
Virahol, the trimethyl carbinol and primary isoamyl alcohol are obtained a kind of ignition dope according to weight ratio 10:25:10 preparation;
Then allow hydrotropy standard-increasing agent, the sex change improving agent of the 20 above-mentioned preparations of weight part, 0.008 weight part 2 of the 45 above-mentioned preparations of weight part, the synergy recombiner of 6-ditertbutylparacresol antioxidizing and antigum agent, the 3 above-mentioned preparations of weight part disperses fully and mixes in the static mixer that Beijing Chu Guan Science and Technology Ltd. sells with the ignition dope of the 10 above-mentioned preparations of weight part, obtains methanol-based clean fuel blending auxiliary agent of the present invention.
Embodiment 4: the preparation of methanol-based clean fuel blending auxiliary agent
The implementation step of this embodiment is as follows:
At first, methyl tertiary butyl ether and methyl methacrylate are obtained a kind of hydrotropy standard-increasing agent according to weight ratio 70:5 preparation;
Methyl cyclopentyl-dialkyl-tricarbon manganium and ethylene glycol ethyl ether are obtained a kind of sex change improving agent according to weight ratio 25:12 preparation;
Secondary octanol and isooctyl alcohol are obtained a kind of synergy recombiner according to weight ratio 20:8 preparation;
Virahol, the trimethyl carbinol and primary isoamyl alcohol are obtained a kind of ignition dope according to weight ratio 30:8:20 preparation;
Then allow hydrotropy standard-increasing agent, the sex change improving agent of the 12 above-mentioned preparations of weight part, 0.016 weight part 2 of the 80 above-mentioned preparations of weight part, the synergy recombiner of 6-ditertbutylparacresol antioxidizing and antigum agent, the 20 above-mentioned preparations of weight part and the ignition dope of the 30 above-mentioned preparations of weight part disperse fully and mix in the static mixer that the metallurgical petrochemical machinery of Nantong Zhong Te company limited sells, and obtain methanol-based clean fuel blending auxiliary agent of the present invention.
Embodiment 5: the preparation of methanol-based clean fuel blending auxiliary agent
The implementation step of this embodiment is as follows:
At first, methyl tertiary butyl ether and methyl methacrylate are obtained a kind of hydrotropy standard-increasing agent according to weight ratio 60:10 preparation;
Methyl cyclopentyl-dialkyl-tricarbon manganium and ethylene glycol ethyl ether are obtained a kind of sex change improving agent according to weight ratio 10:2 preparation;
Secondary octanol and isooctyl alcohol are obtained a kind of synergy recombiner according to weight ratio 6:6 preparation;
Virahol, the trimethyl carbinol and primary isoamyl alcohol are obtained a kind of ignition dope according to weight ratio 14:10:12 preparation;
Then allow hydrotropy standard-increasing agent, the sex change improving agent of the 3 above-mentioned preparations of weight part, 0.010 weight part 2 of the 55 above-mentioned preparations of weight part, the synergy recombiner of 6-ditertbutylparacresol antioxidizing and antigum agent, the 6 above-mentioned preparations of weight part and the ignition dope of the 18 above-mentioned preparations of weight part disperse fully and mix in the static mixer that the metallurgical petrochemical machinery of Nantong Zhong Te company limited sells, and obtain methanol-based clean fuel blending auxiliary agent of the present invention.
Embodiment 6: the preparation of methanol-based clean fuel blending auxiliary agent
At first, methyl tertiary butyl ether and methyl methacrylate are obtained a kind of hydrotropy standard-increasing agent according to weight ratio 65:8 preparation;
Methyl cyclopentyl-dialkyl-tricarbon manganium and ethylene glycol ethyl ether are obtained a kind of sex change improving agent according to weight ratio 15:10 preparation;
Secondary octanol and isooctyl alcohol are obtained a kind of synergy recombiner according to weight ratio 12:8 preparation;
Virahol, the trimethyl carbinol and primary isoamyl alcohol are obtained a kind of ignition dope according to weight ratio 20:16:18 preparation;
Then allow hydrotropy standard-increasing agent, the sex change improving agent of the 16 above-mentioned preparations of weight part, 0.012 weight part 2 of the 72 above-mentioned preparations of weight part, the synergy recombiner of 6-ditertbutylparacresol antioxidizing and antigum agent, the 15 above-mentioned preparations of weight part disperses fully and mixes in the static mixer that Beijing Chu Guan Science and Technology Ltd. sells with the ignition dope of the 20 above-mentioned preparations of weight part, obtains methanol-based clean fuel blending auxiliary agent of the present invention.
Claims (6)
1. a methanol-based clean fuel blending auxiliary agent, is characterized in that this blending auxiliary agent is comprised of 45 ~ 80 weight part hydrotropy standard-increasing agents, 3 ~ 25 weight part sex change improving agents, 0.005 ~ 0.02 weight part antioxidizing and antigum agent, 3 ~ 20 weight part synergy recombiners and 10 ~ 30 portions of ignition dopes; Wherein:
Described hydrotropy standard-increasing agent is comprised of according to weight ratio 45 ~ 80:0 ~ 15 methyl tertiary butyl ether and methyl methacrylate;
Described sex change improving agent is comprised of according to weight ratio 3 ~ 25:0 ~ 12 methyl cyclopentyl-dialkyl-tricarbon manganium and ethylene glycol ethyl ether;
Described antioxidizing and antigum agent is 2,6 ditertiary butyl p cresol;
Described synergy recombiner is comprised of according to weight ratio 3 ~ 20:5 ~ 10 secondary octanol and isooctyl alcohol;
Described ignition dope is mixed according to weight ratio 10 ~ 30:5 ~ 25:10 ~ 20 with primary isoamyl alcohol by Virahol, the trimethyl carbinol and forms.
2. methanol-based clean fuel blending auxiliary agent according to claim 1, is characterized in that this blending auxiliary agent is comprised of 55 ~ 72 weight part hydrotropy standard-increasing agents, 8 ~ 20 weight part sex change improving agents, 0.008 ~ 0.016 weight part antioxidizing and antigum agent, 6 ~ 15 weight part synergy recombiners and 14 ~ 25 portions of ignition dopes.
3. methanol-based clean fuel blending auxiliary agent according to claim 1, is characterized in that this blending auxiliary agent is comprised of 60 ~ 68 weight part hydrotropy standard-increasing agents, 12 ~ 16 weight part sex change improving agents, 0.010 ~ 0.012 weight part antioxidizing and antigum agent, 8 ~ 12 weight part synergy recombiners and 18 ~ 20 portions of ignition dopes.
4. the preparation method of methanol-based clean fuel blending auxiliary agent is characterized in that this preparation method's step is as follows:
Allow 45 ~ 80 weight part hydrotropy standard-increasing agents, 3 ~ 25 weight part sex change improving agent improving agents, 0.005 ~ 0.02 weight part antioxidizing and antigum agent, 3 ~ 20 weight part synergy recombiners disperse fully in static mixer and to mix with 10 ~ 30 weight part ignition dopes, obtain described methanol-based clean fuel blending auxiliary agent; Wherein:
Described hydrotropy standard-increasing agent is comprised of according to weight ratio 45 ~ 80:0 ~ 15 methyl tertiary butyl ether and methyl methacrylate;
Described sex change improving agent is comprised of according to weight ratio 3 ~ 25:0 ~ 12 methyl cyclopentyl-dialkyl-tricarbon manganium and ethylene glycol ethyl ether;
Described antioxidizing and antigum agent is 2,6 ditertiary butyl p cresol;
Described synergy recombiner is comprised of according to weight ratio 3 ~ 20:5 ~ 10 secondary octanol and isooctyl alcohol;
Described ignition dope is mixed according to weight ratio 10 ~ 30:5 ~ 25:10 ~ 20 with primary isoamyl alcohol by Virahol, the trimethyl carbinol and forms.
5. the purposes of the described methanol-based clean fuel blending auxiliary agent of arbitrary claim in methanol gasoline or diesel oil according to claim 1-3.
6. according to claim 1-5 described purposes, it is characterized in that when methanol gasoline or diesel oil, add the described methanol-based clean fuel blending of arbitrary claim auxiliary agent in claim 1-3 in methyl alcohol or diesel oil, its add-on is 2 ~ 15% of methanol gasoline or diesel oil gross weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310045708.4A CN103160345B (en) | 2013-02-05 | 2013-02-05 | Carbinol group clean fuel concoction accessory ingredient and purpose thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310045708.4A CN103160345B (en) | 2013-02-05 | 2013-02-05 | Carbinol group clean fuel concoction accessory ingredient and purpose thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103160345A true CN103160345A (en) | 2013-06-19 |
| CN103160345B CN103160345B (en) | 2015-02-11 |
Family
ID=48583884
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310045708.4A Active CN103160345B (en) | 2013-02-05 | 2013-02-05 | Carbinol group clean fuel concoction accessory ingredient and purpose thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103160345B (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107011954A (en) * | 2017-04-28 | 2017-08-04 | 马健 | Alcohol-based fuel cosolvent |
| CN107723050A (en) * | 2017-11-23 | 2018-02-23 | 陆克 | A kind of efficient biomass hybrid fuel |
| CN107841364A (en) * | 2017-11-23 | 2018-03-27 | 广西银英生物质能源科技开发股份有限公司 | A kind of environmentally friendly biomass fuel additive |
| CN107841367A (en) * | 2017-11-23 | 2018-03-27 | 广西银英生物质能源科技开发股份有限公司 | A kind of quick burning biomass fuel feed additives |
| CN107841366A (en) * | 2017-11-23 | 2018-03-27 | 广西银英生物质能源科技开发股份有限公司 | A kind of biomass fuel feed additives |
| CN107841365A (en) * | 2017-11-23 | 2018-03-27 | 广西银英生物质能源科技开发股份有限公司 | A kind of efficient biomass fuel additive |
| CN107858188A (en) * | 2017-11-23 | 2018-03-30 | 陆克 | A kind of clean type biomass composite fuel |
| CN107903970A (en) * | 2017-11-23 | 2018-04-13 | 陆克 | A kind of quick burning biomass composite fuel |
| CN107937086A (en) * | 2017-11-23 | 2018-04-20 | 广西银英生物质能源科技开发股份有限公司 | A kind of flavouring biomass fuel feed additives |
| CN107955662A (en) * | 2017-11-23 | 2018-04-24 | 陆克 | A kind of environmentally friendly biomass hybrid fuel |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101412933A (en) * | 2007-10-15 | 2009-04-22 | 李隆梅 | Broadspectrum environment-protective alcohol-base liquid fuel and preparation thereof |
| CN101633855A (en) * | 2008-07-25 | 2010-01-27 | 湖南金悦世纪能源有限公司 | Highly cleaning, environmental-friendly and energy-saving gasoline |
| CN101760261A (en) * | 2010-01-13 | 2010-06-30 | 上海塔博环保科技有限公司 | Gasoline environmental-protection additive |
| CN102051236A (en) * | 2009-10-27 | 2011-05-11 | 北京清研利华石油化学技术有限公司 | Modified methanol and preparation method thereof |
| CN102492497A (en) * | 2011-12-15 | 2012-06-13 | 河北冀春能源投资集团有限公司 | Additive of M50 methanol gasoline |
-
2013
- 2013-02-05 CN CN201310045708.4A patent/CN103160345B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101412933A (en) * | 2007-10-15 | 2009-04-22 | 李隆梅 | Broadspectrum environment-protective alcohol-base liquid fuel and preparation thereof |
| CN101633855A (en) * | 2008-07-25 | 2010-01-27 | 湖南金悦世纪能源有限公司 | Highly cleaning, environmental-friendly and energy-saving gasoline |
| CN102051236A (en) * | 2009-10-27 | 2011-05-11 | 北京清研利华石油化学技术有限公司 | Modified methanol and preparation method thereof |
| CN101760261A (en) * | 2010-01-13 | 2010-06-30 | 上海塔博环保科技有限公司 | Gasoline environmental-protection additive |
| CN102492497A (en) * | 2011-12-15 | 2012-06-13 | 河北冀春能源投资集团有限公司 | Additive of M50 methanol gasoline |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107011954A (en) * | 2017-04-28 | 2017-08-04 | 马健 | Alcohol-based fuel cosolvent |
| CN107723050A (en) * | 2017-11-23 | 2018-02-23 | 陆克 | A kind of efficient biomass hybrid fuel |
| CN107841364A (en) * | 2017-11-23 | 2018-03-27 | 广西银英生物质能源科技开发股份有限公司 | A kind of environmentally friendly biomass fuel additive |
| CN107841367A (en) * | 2017-11-23 | 2018-03-27 | 广西银英生物质能源科技开发股份有限公司 | A kind of quick burning biomass fuel feed additives |
| CN107841366A (en) * | 2017-11-23 | 2018-03-27 | 广西银英生物质能源科技开发股份有限公司 | A kind of biomass fuel feed additives |
| CN107841365A (en) * | 2017-11-23 | 2018-03-27 | 广西银英生物质能源科技开发股份有限公司 | A kind of efficient biomass fuel additive |
| CN107858188A (en) * | 2017-11-23 | 2018-03-30 | 陆克 | A kind of clean type biomass composite fuel |
| CN107903970A (en) * | 2017-11-23 | 2018-04-13 | 陆克 | A kind of quick burning biomass composite fuel |
| CN107937086A (en) * | 2017-11-23 | 2018-04-20 | 广西银英生物质能源科技开发股份有限公司 | A kind of flavouring biomass fuel feed additives |
| CN107955662A (en) * | 2017-11-23 | 2018-04-24 | 陆克 | A kind of environmentally friendly biomass hybrid fuel |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103160345B (en) | 2015-02-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103160345B (en) | Carbinol group clean fuel concoction accessory ingredient and purpose thereof | |
| CN101121901A (en) | Methanol gasoline for vehicle | |
| CN102660337A (en) | Method for preparing novel clean synthetic diesel oil | |
| CN101955819B (en) | Biomass nano-fuel combustion-supporting additive | |
| CN101550363A (en) | Novel carbinol gasoline fuel | |
| CN101177633A (en) | Vehicle high(middle) ratio low-carbon alcohol gasoline | |
| CN102533351B (en) | Alcohol ether fuel | |
| CN103756752B (en) | Improve the compositions of additives of M85 methanol gasoline NOx emission | |
| CN102559294B (en) | Alcohol ether diesel oil | |
| CN102559296A (en) | Methanol gasoline | |
| CN101195769B (en) | Low carbon mixture alcohol gasoline | |
| CN101139534A (en) | Fuel oil cleaning agent and preparation method thereof | |
| CN102268305A (en) | Environmentally-friendly methanol diesel oil for automobile and preparation method thereof | |
| CN103695050A (en) | Vehicle methanol gasoline composite additive | |
| CN101580747A (en) | Fuel composition capable of meeting motor vehicle pollutant emission limit | |
| CN103160335B (en) | Automotive plateau-type modified fuel methanol and purposes thereof | |
| CN100577777C (en) | Alcohol ether substituted clean fuel for automobile | |
| CN103146442B (en) | M15 automotive plateau type clean methanol gasoline and production method thereof | |
| CN102533357B (en) | Methanol diesel fuel | |
| CN100506954C (en) | Fuel oil additive | |
| CN101200657A (en) | Combustion engine composite fuel and preparation method thereof | |
| CN103160341B (en) | M30 car plateau type cleaning methanol gasoline and manufacture method thereof | |
| CN100393855C (en) | Composite fuel for automobile engine | |
| CN102719281A (en) | Fuel composition for vehicles and preparation method of fuel composition | |
| CN109705932A (en) | A kind of environmental protection and energy saving standard increasing agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |