CN103160343A - 一种合成柴油及其制备方法 - Google Patents
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- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 claims description 24
- 239000003925 fat Substances 0.000 claims description 17
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- 238000002156 mixing Methods 0.000 claims description 11
- 239000004129 EU approved improving agent Substances 0.000 claims description 10
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- 229910017604 nitric acid Inorganic materials 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 5
- 239000013618 particulate matter Substances 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 235000017550 sodium carbonate Nutrition 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 abstract description 5
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- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 2
- 238000006477 desulfuration reaction Methods 0.000 abstract description 2
- 239000008162 cooking oil Substances 0.000 abstract 2
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 239000002699 waste material Substances 0.000 abstract 2
- NNKQLUVBPJEUOR-UHFFFAOYSA-N 3-ethynylaniline Chemical compound NC1=CC=CC(C#C)=C1 NNKQLUVBPJEUOR-UHFFFAOYSA-N 0.000 abstract 1
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- 238000001308 synthesis method Methods 0.000 abstract 1
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- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- OEOIWYCWCDBOPA-UHFFFAOYSA-N 6-methyl-heptanoic acid Chemical compound CC(C)CCCCC(O)=O OEOIWYCWCDBOPA-UHFFFAOYSA-N 0.000 description 1
- 208000019901 Anxiety disease Diseases 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000036506 anxiety Effects 0.000 description 1
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Abstract
本发明涉及一种的合成柴油，其要点是：合成柴油由0#柴油55～67份、精致潲水油30～40份、十六烷改进剂2.5～3.5份、分散剂0.48～1.46份、添加剂0.02～0.04份；加入不锈钢灌内，通过搅拌均匀，混合液温度保持在65～70℃，保温1.5～2.5小时，过滤静放20～24小时即获得合成柴油。本发明的合成柴油，成本低，合成方法简单；异辛醇分散剂能促进各原料的互溶性、硝酸异辛脂十六烷改进剂能有效的提高十六烷值；添加剂作为去硫剂能有效的除去潲水油中的硫，有利于环境保护；符合国IV车用0#柴油标准，并在柴油发电机、柴油汽车、挖机、船等柴油发动机上试用，达到国IV车用0#柴油的同等效果，但合成柴油的价格比国IV车用0#柴油低15%以上，经济性好。
Description
技术领域
本发明涉及一种合成燃料油，具体涉及一种合成柴油及其制备方法。
背景技术
目前，随着石油资源的紧张、许多合成燃料纷纷生产岀来，但目前的合成燃料如生物柴油存在不稳定，不相溶，燃烧不完全，燃油消耗量大，尾气排放碳氧化物含量高，不利于环境保；对油管和金属零件有腐蚀性，降低了零件的使用寿命，经济性差。
发明内容
本发明的目的是要克服上述技术的缺点，提供一种成本低、容易合成，相容性和互换性好，即可单独使用,也可混合使用，燃烧充分，效率高，污染物排放低的合成柴油及其制备方法。
本发明的合成柴油，其特征在于：所述的合成柴油由下述重量份构成：
0#柴油 55～67份，
精制潲水油 30～40份，
十六烷改进剂 2.5～3.5份，
分散剂 0.48～1.46份，
添加剂 0.02～0.04份。
所述的十六烷改进剂为硝酸异辛脂。
所述的分散剂为异辛醇。
所述的添加剂由下述重量份构成：
氢氧化钠 35～50份，
纯碱 45～55份，
过氧化氢 5～10份。
一种合成柴油的制备方法，其特征在于：所述的合成柴油按下述步骤制备：
A、把30～40份的精制潲水油装入不锈钢灌内；
B、依次向步骤A中加入：十六烷改进剂2.5～3.5份、分散剂0.48～1.46份,盖上罐盖同时搅拌20～30分钟混合均匀后再加热到70℃；
C、向步骤B中加入添加剂0.02～0.04份, 搅拌混合均匀，混合液温度保持在65℃～70℃，保温1.5～2.5小时，自然冷却到环境温度，静放20～24小时；
D、用滤网过滤以上混合液中的颗粒物质，过滤精度为10μm～ 20μm；
E、向步骤D中加入0#柴油55～67份，盖上罐盖，搅拌30分钟～1小时，即获得本发明的合成柴油。
本发明的合成柴油，成本低，合成方法简单；异辛醇分散剂能促进各原料的互溶性、硝酸异辛脂十六烷改进剂能有效的提高合成柴油的十六烷值；添加剂作为去硫剂能有效的除去潲水油中的硫，有利于环境保护；符合国IV车用0#柴油标准，并在柴油发电机、柴油汽车、挖机、船等柴油发动机上试用，达到了国IV车用0#柴油的同等效果，但合成柴油的价格比国IV车用0#柴油低15%以上，经济性好。
具体实施方式
实施例—
合成柴油由0#柴油、精制潲水油、十六烷改进剂、分散剂、添加剂混合按下述重量份构成：
0#柴油 55份，
精制潲水油 40份，
硝酸异辛脂十六烷改进剂 3.5份，
异辛醇分散剂 1.46份，
添加剂 0.04份。
精制潲水油是餐饮后的剩余混合物，通过固液分离、破乳、去除盐分提炼的油，其含动物油脂30%以上、酸碱度为7。
添加剂由下述原料的重量份构成:
氢氧化钠 35份，
纯碱 55份，
过氧化氢 10份。
合成柴油按下述步骤制备：
A、把40份的精制潲水油装入不锈钢罐内；
B、依次向步骤A中加入3.5份十六烷改进剂、1.46份分散剂,盖上罐盖同时搅拌25分钟,混合均匀后再加热到70℃；
C、向步骤B中加入0.04份添加剂盖上罐盖同时搅拌20分钟，混合均匀后，70℃恒温保持两小时，自然冷却至室温，静放24小时；
D、用滤网过滤以上混合液中的颗粒物质，过滤精度为10μm～ 20μm；
E、向步骤D中加入55份0#柴油，盖上罐盖，搅拌40分钟，即获得本发明的合成柴油。
实施例二
合成柴油由0#柴油、精制潲水油、十六烷改进剂、分散剂、添加剂混合按下述重量份构成：
0#柴油 60份，
精制潲水油 35.5份，
硝酸异辛脂十六烷改进剂 3.2份，
异辛酸分散剂 1.27份，
添加剂 0.03份。
精制潲水油与实施例一相同。
添加剂由下述原料的重量份构成:
氢氧化钠 40份，
纯碱 50份，
过氧化氢 10份。
合成柴油按下述步骤制备:
A、把35.5份精制潲水油装入不锈钢罐内；
B、依次向步骤A中加入3.2份十六烷改进剂,1.27份分散剂,盖上罐盖，搅拌25分钟，混合均匀后再加热到70℃；
C、向步骤B中加入0.03份添加剂,盖上罐盖，同时搅拌20分钟，混合均匀后，70℃恒温2小时，自然冷却到室温，静放22小时；
D、用滤网过滤以上混合液中的颗粒物质，过滤精度为10μm～ 20μm；
E、向步骤D中加入60份0#柴油，盖上罐盖，搅拌45分钟，即获得本发明的合成柴油。
实施例三
合成柴油由0#柴油、精制潲水油、十六烷改进剂、分散剂、添加剂混合按下述重量份构成：
0#柴油 67份，
精制潲水油 30份，
硝酸异辛脂十六烷改进剂 2.5份，
异辛醇分散剂 0.48份，
添加剂 0.02份。
精制潲水油与实施例一相同。
添加剂由下述原料的重量份构成:
氢氧化钠 50份，
纯碱 45份，
过氧化氢 5份。
合成柴油按下述步骤制备:
A、把30份精制潲水油装入不锈钢罐内；
B、依次向步骤A中加入2.5份十六烷改进剂,0.48份分散剂,盖上罐盖，搅拌25分钟，混合均匀后再加热到65℃；
C、向步骤B中加入0.02份添加剂,盖上罐盖，同时搅拌20分钟，混合均匀后，65℃恒温2.5小时，自然冷却到室温，静放20小时；
D、用滤网过滤以上混合液中的颗粒物质，过滤精度为10μm～ 20μm；
E、向步骤D中加入67份0#柴油，盖上罐盖，搅拌45分钟，即获得本发明的合成柴油。
Claims (5)
1.本发明的合成柴油，其特征在于：所述的合成柴油由下述重量份构成：
0#柴油 55～67份，
精制潲水油 30～40份，
十六烷改进剂 2.5～3.5份，
分散剂 0.48～1.46份，
添加剂 0.02～0.04份。
2.根据权利要求1所述的合成柴油，其特征在于：所述的十六烷改进剂为硝酸异辛脂。
3.根据权利要求1所述的合成柴油，其特征在于：所述的分散剂为异辛醇。
4.根据权利要求1所述的合成柴油，其特征在于：所述的添加剂由下述重量份构成：
氢氧化钠 35～50份，
纯碱 45～55份，
过氧化氢 5～10份。
5.一种合成柴油的制备方法，其特征在于：所述的合成柴油按下述步骤制备：
A、把30～40份的精制潲水油装入不锈钢灌内；
B、依次向步骤A中加入：十六烷改进剂2.5～3.5份、分散剂0.48～1.46份,盖上罐盖同时搅拌20～30分钟，混合均匀后再加热到70℃;
C、向步骤B中加入添加剂0.02～0.04份, 搅拌混合均匀，混合液温度保持在65℃～70℃，保温1.5～2.5小时，自然冷却到环境温度，静放20～24小时;
D、用滤网过滤以上混合液中的颗粒物质，过滤精度为10μm～ 20μm；
E、向步骤D中加入0#柴油55～67份，盖上罐盖，搅拌30分钟～1小时，即获得本发明的合成柴油。
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1154999A (zh) * | 1996-11-05 | 1997-07-23 | 林金池 | 合成柴油 |
| CN101003756A (zh) * | 2007-01-18 | 2007-07-25 | 鲁希诺 | 合成柴油 |
| CN101089147A (zh) * | 2006-06-15 | 2007-12-19 | 颜克绳 | 一种清洁生物柴油的制备方法 |
| US20080034645A1 (en) * | 2006-07-14 | 2008-02-14 | David Bressler | Methods for producing fuels and solvents |
| KR100929030B1 (ko) * | 2008-08-27 | 2009-11-26 | 전근식 | 폐식용유를 이용한 바이오 디젤 제조장치 및 방법 |
| CN101824369A (zh) * | 2010-05-20 | 2010-09-08 | 浙江交通职业技术学院 | 一种利用泔水油制备船用生物柴油的方法 |
-
2013
- 2013-04-10 CN CN201310121452.0A patent/CN103160343B/zh not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1154999A (zh) * | 1996-11-05 | 1997-07-23 | 林金池 | 合成柴油 |
| CN101089147A (zh) * | 2006-06-15 | 2007-12-19 | 颜克绳 | 一种清洁生物柴油的制备方法 |
| US20080034645A1 (en) * | 2006-07-14 | 2008-02-14 | David Bressler | Methods for producing fuels and solvents |
| CN101003756A (zh) * | 2007-01-18 | 2007-07-25 | 鲁希诺 | 合成柴油 |
| KR100929030B1 (ko) * | 2008-08-27 | 2009-11-26 | 전근식 | 폐식용유를 이용한 바이오 디젤 제조장치 및 방법 |
| CN101824369A (zh) * | 2010-05-20 | 2010-09-08 | 浙江交通职业技术学院 | 一种利用泔水油制备船用生物柴油的方法 |
Non-Patent Citations (1)
| Title |
|---|
| 凌新龙等: "潲水油制备生物柴油工艺的研究", 《安徽农业科学》, vol. 38, no. 30, 31 October 2010 (2010-10-31), pages 17193 - 17195 * |
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