CN103147809B - Boulez pauses-steam Rankine-ammonia steam Rankine combined cycle generating unit - Google Patents
Boulez pauses-steam Rankine-ammonia steam Rankine combined cycle generating unit Download PDFInfo
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- 229910021529 ammonia Inorganic materials 0.000 title claims abstract description 140
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 242
- 239000007789 gas Substances 0.000 claims abstract description 34
- 239000006200 vaporizer Substances 0.000 claims abstract description 30
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000003546 flue gas Substances 0.000 claims abstract description 27
- 238000009833 condensation Methods 0.000 claims abstract description 19
- 230000005494 condensation Effects 0.000 claims abstract description 19
- 238000009834 vaporization Methods 0.000 claims abstract description 12
- 230000008016 vaporization Effects 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 41
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 33
- 229920006395 saturated elastomer Polymers 0.000 claims description 11
- 238000007599 discharging Methods 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- 238000002485 combustion reaction Methods 0.000 claims description 4
- 239000000446 fuel Substances 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims 1
- 230000005611 electricity Effects 0.000 abstract description 14
- 239000003517 fume Substances 0.000 abstract description 9
- 230000008901 benefit Effects 0.000 abstract description 7
- 238000005260 corrosion Methods 0.000 abstract description 6
- 230000007797 corrosion Effects 0.000 abstract description 6
- 238000010248 power generation Methods 0.000 abstract description 5
- 238000013461 design Methods 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 2
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 239000003595 mist Substances 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 19
- 239000000126 substance Substances 0.000 description 10
- 238000011160 research Methods 0.000 description 9
- 239000000243 solution Substances 0.000 description 7
- 239000002918 waste heat Substances 0.000 description 7
- 238000011161 development Methods 0.000 description 6
- 239000002699 waste material Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000003416 augmentation Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000000567 combustion gas Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 238000005057 refrigeration Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 230000009711 regulatory function Effects 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- HTJJPCOQQINRDG-UHFFFAOYSA-L calcium azane dichloride Chemical compound N.[Cl-].[Cl-].[Ca+2] HTJJPCOQQINRDG-UHFFFAOYSA-L 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- HAAFARYZKVVJHG-UHFFFAOYSA-M sodium azane thiocyanate Chemical compound N.[Na]SC#N HAAFARYZKVVJHG-UHFFFAOYSA-M 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
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- Engine Equipment That Uses Special Cycles (AREA)
Abstract
The present invention relates to a kind of Boulez pauses-steam Rankine-ammonia steam Rankine combined cycle generating unit, Boulez is paused the exhaust of gas turbine as the thermal source of steam Rankine-ammonia steam Rankine combined cycle, using the vaporizer of the vapour condenser of steam Rankine cycle as the Rankine cycle of ammonia steam, the utilization of ammonia steam Rankine cycle system centering low-temperature heat source is utilized to have more high efficiency feature, a large amount of latent heats of vaporization that steam condensation discharges are used for ammonia steam Rankine cycle efficiency power generation, the latent heat of vaporization of steam Kanicme cycle vapor is only utilized to reclaim more than 50 KWhs/ton of steam for this block that generates electricity just more, solve the safety difficulties of ammonia steam Rankine cycle Mist heat recovering simultaneously, effective reduction temperature of exhaust fume also avoids the cold end corrosion of flue gas.The present invention both can be used for the reducing energy consumption of existing unit, also can be used for the design of new-built unit, construction, and economic, society, environmental benefit are remarkable.
Description
Technical field
The present invention relates to a kind of Boulez pauses-steam Rankine-ammonia steam Rankine combined cycle generating unit, and concrete genus thermal power plant field of power equipment technology.
Background technique
Combustion gas one Steam Combined Cycle is because of series of advantages such as its thermal efficiency are high, toggle speed is fast, environmental protection condition is good, installation period is short, investment cost is low, add the develop rapidly of gas turbine technology in recent years, gas turbine single-machine capacity also continues to increase, and combined cycle research has caused attention and the enforcement of countries in the world.
The research of external combined cycle generation technology starts from eighties of last century end of the sixties, through the development of decades, at present, the combustion gas one steam combined cycle power generating technology comparative maturity of many developed countries such as the U.S., Britain, Japan, its power supply efficiency reaches more than 50%.If U.S. CE company is about 53%; ABB AB is 48% ~ 51.9%; Mitsubishi Heavy Industries Ltd are 5l% ~ 52%.Many companies (as Texco company of the U.S., Belgian CMI company etc.) all have the Combined Cycle Heat Recovery Boiler performance design of comparative maturity, system optimization, structure optimization, manufacturing technology, and have grasped thermodynamic property and the roadability of Combined Cycle Heat Recovery Boiler completely.The extraction cycle of Gas-steam Combined Cycle and the at present Cheng's cycle of two-fluid circulation-steam injected gas turbine just under development and the blower outlet water-spraying evaporation at gas turbine, the representative of this technical development just, the former is full-fledged, achieve huge economic benefit, rear both are stepping up among research, and Cheng's cycle has application example and formal product.
Taking water vapor as the thermal power plant of working medium, is to carry out thermal energy to become mechanical energy on a large scale, and the factory transformed mechanical energy into electricity again.The circulation of power station application is very complicated, but in essence, the Rankine cycle be mainly made up of equipment such as boiler, steam turbine, vapour condenser, water pumps has come, its working principle is: feedwater first sends into boiler after feed water pump pressurization, water is by superheated vapor that is heat vaporized, that form High Temperature High Pressure in the boiler, superheated vapor is expansion work in steam turbine, become the exhaust steam of low-temp low-pressure, finally enter vapour condenser and be condensed into condensed water, again through water pump, condensed water is sent into boiler and carry out new circulation.As for the complex loops that thermal power plant uses, only on Rankine cycle basis, in order to improve the thermal efficiency, improved and the new circulation that formed and extraction cycle, the medium of backheat is water.Rankine cycle has become the basic circulation of modern vapor power plant.
Modern big-and-middle-sized steam power plant all adopts the heated feed water extraction cycle that draws gas without any exception, employing is drawn gas after backheat heated feed water, feed temperature is improved, thus improve heating mean temperature, except considerably improving thermal efficiency of cycle, though specific steam consumption increases to some extent, owing to drawing gas step by step, steam discharge rate is reduced, this is conducive to the ratio i.e. internal efficiency ratio η of this circulation of actual acting amount and theoretical acting amount
oiraising, solve simultaneously large steam turbine exhaust stage blade negotiability restriction difficulty, vapour condenser volume also can correspondingly reduce.But still discharge a large amount of latent heats of vaporization when steam condenses in vapour condenser, need a large amount of water or air to cool, namely waste heat, cause thermo-pollution, waste again electric energy, water resources.Therefore how effectively to utilize a large amount of latent heat of vaporization discharged during steam condensation in vapour condenser, be worth further investigation.
Give off a large amount of flue gases in station boiler production process, wherein the heat of recoverable is a lot.Although the waste of this part residual heat resources is huge, recycle and have larger difficulty, its main cause is: the quality of (1) waste heat is lower, does not find effective Application way; (2) reclaim the waste heat of this part flue gas, often change is made to the original thermodynamic system of boiler, there is certain risk; (3) thermal balance question is difficult to tissue, is difficult to all directly utilize in inside plants, often needs outwards to find suitable heat user, and heat user often have fluctuation by heat load, thus limit the versatility of recovery method.
Gu Wei etc. (present Research of low temperature heat energy generating and development trend [J]. Thermal power engneering .2007.03.Vol.22, No.2.) describe present Research and the development trend of domestic and international low temperature heat energy generation technology.From the development of the research of low temperature heat energy generation technology in recent years, research work mainly concentrates on aspects such as the improvement of power cycle work Quality Research and cyclic process and optimal controls.Kalina circulation, ammonia absorption type power refrigeration combined cycle etc. can reach the capacity usage ratio higher than simple cycle in theory.Low temperature heat energy generating based on Finite-Time Thermodynamics becomes factor to significant during the affecting of system when considering, may realize the maximization of the Energy harvesting of system.Raising generating efficiency and environmental protection are the core contents of Low Temperature Thermal power technology.The Kalina circulation mentioned in literary composition, ammonia absorption type power refrigeration combined cycle scheduling theory merit attention.
Above-mentionedly mention the shortcoming that card Linne power generation technology also has it intrinsic: as ammonia has inflammable, the explosive feature such as poisonous, when boiler or industrial furnace back-end ductwork utilize fume afterheat to organize card Linne circulating generation, the leakage that in flue gas, dust etc. causes the wearing and tearing, corrosion etc. of the heat exchanger be arranged in flue must be considered, the protection etc. of explosion protection and environment and the job site of drawing thus must be considered; Take ammonia water mixture as the card Linne circulation of working medium, the ammonia in ammoniacal liquor is inflammable, explosive, poisonous medium.This is the difficult problem that card Linne power generation technology reclaims dust-laden, must solve when having the fume afterheat of corrosive deposit in electric power station system.
Therefore the thermomechanics basic law in steam Rankine cycle thermal power plant how is utilized, use for reference the innovative approach that the combined cycle scheduling theory such as thinking and Rankine-Kalina is organized in compound Rankine cycle, retain the advantage based on the power plant technology of Rankine cycle principle, inquire into new combined cycle theoretical, really find the new way increasing substantially thermodynamic cycle power plant thermal efficiency, become the difficult point of this area research.
Summary of the invention
Object of the present invention is the shortcoming solving the existence of the technology such as above-mentioned steam Rankine cycle and the circulation of card Linne, proposing a kind of new Boulez pauses-steam Rankine-ammonia steam Rankine combined cycle generating unit, traditional steam Rankine cycle can be substituted, Gas-steam Combined Cycle and Cheng's cycle unit, the difficult problem that a large amount of latent heat of vaporization discharged when simultaneously solving steam condensation in the key issue of card Linne cycle machine set safe operation and vapour condenser reclaims, the latent heat of vaporization in recovered steam Rankine cycle during steam condensation is used for low-temperature end ammonia steam Rankine cycle generating, thus realize the thermal efficiency effectively improving whole Combined Cycle Unit, finally reach energy-saving and cost-reducing, improve the object of system thermal efficiency.
The object of the invention is to be realized by following measures:
A kind of Boulez pauses-steam Rankine-ammonia steam Rankine combined cycle generating unit, and this device comprises Boulez and to pause circulation, steam Rankine cycle, the Rankine cycle of ammonia steam, it is characterized in that:
Air 35 sends into fuel-burning equipment 37 through gas compressor 36, and with fuel 38 Thorough combustion entered, the high-temperature flue gas of generation enters gas turbine 39, drags gas turbine powered generator 41 and generates electricity, complete gas turbine unit Boulez and to pause circulation.
Described gas turbine 39 high-temperature flue gas 40 of discharging is as the thermal source of steam Rankine cycle system, and high-temperature flue gas 40 is discharged after reducing temperature through exhaust heat boiler body 1, superheater 2, feed water preheater 8, heat exchanger 13.
Described steam Rankine cycle, refers to by exhaust heat boiler body 1 saturated vapour 2 out, forms superheated vapor 3-1 through superheater 3, sends into steam turbine 4 and drives steam-driven generator 21 to generate electricity; Steam turbine 4 exhaust steam 5 out enters condenser/evaporator 10 and forms water of condensation 6, and water of condensation 6 is sent into exhaust heat boiler body 1 through condensate pump 6-1, oxygen-eliminating device 7-1, feed water pump 7, feed water preheater 8, then produced saturated vapour, thus forms steam Rankine cycle circuit.
Described ammonia steam Rankine cycle, refer to that ammoniacal liquor 11 is through recycle pump 12, condenser/evaporator 10, the ammonia steam produced is through exhaust steam regenerator 22, ammonia steam pipe line 24, superheater 9, form ammonia superheated vapor 16, enter ammonia steam turbine 17 to drag ammonia generator 20 and generate electricity, the exhaust steam of discharging from ammonia steam turbine 17 cools and forms ammoniacal liquor 11 through exhaust steam regenerator 22, ammonia condenser 18, then enter recycle pump 12, thus forms ammonia steam Rankine cycle circuit.
Described steam Rankine cycle and ammonia steam Rankine cycle circuit are combined by condenser/evaporator 10, in the Rankine cycle of high efficiente callback steam, the latent heat of vaporization of steam condensation release is used for low-temperature end ammonia steam Rankine cycle generating, and the steam condensation side of described steam Rankine cycle is negative pressure.
Described superheater 9 adopts the 4-1 that draws gas of steam turbine 4 in steam Rankine cycle as thermal source, and the 4-1 that draws gas cools formation condensed water 26 through superheater 9 and returns steam Rankine cycle system.
Described ammoniacal liquor 11 is the ammonia of one-component, or be low boiling component with ammonia, the high boiling component mixed solution that is absorbing agent is as ammonia-aqueous solution, ammonia-sodium thiocyanate solution or ammonia-calcium chloride solution etc.
When described ammoniacal liquor is Multi component, be provided with regenerator 15: ammoniacal liquor 11 is through recycle pump 12, regenerator 15, condenser/evaporator 10, the lean solution formed returns ammonia condenser 18 through regenerator 15, the pipeline 19 that backflows, the ammonia steam produced forms ammoniacal liquor 11 through exhaust steam regenerator 22, superheater 9, ammonia steam turbine 17, ammonia condenser 18, return recycle pump 12, thus form ammonia steam Rankine cycle circuit.
Be provided with heat exchanger 13: when heat exchanger 13 is for phase-change heat-exchanger, comprise vaporizer 13-1, condenser 13-2, wherein vaporizer 13-1 is arranged in flue 23, and condenser 13-2 is arranged in outside flue 23, phase-change working substance adopts water or other suitable materials; Flue gas adopts separated type heat exchange mode by the phase-change working substance of phase-change heat-exchanger and condenser/evaporator 10 ammonia steam out: the heat that phase-change working substance absorbs flue gas in vaporizer 13-1 produces saturated vapour, saturated vapour is as the thermal source of ammonia steam, by condenser 13-2 and ammonia steam wall-type heat exchange, form condensation water after cooling and produce steam again by the heat of vaporizer 13-1 absorption flue gas again, thus form the Inner eycle loop of phase-change working substance; Phase-change working substance adopts natural circulation or pump circulation mode; The ammonia steam that condenser/evaporator 10 exports is through the condenser 13-2 of ammonia steam pipe line 25, heat exchanger 13, the ammonia superheated vapor 16 formed enters ammonia steam turbine 17, condenser/evaporator 10 is got back to again through exhaust steam regenerator 22, ammonia condenser 18, recycle pump 12, thus ammonia steam Rankine cycle circuit.
Be provided with ammoniacal liquor vaporizer 14: the exhaust steam that ammoniacal liquor vaporizer 14 adopts ammonia steam turbine 17 to export is as thermal source, the ammonia steam produced is through exhaust steam regenerator 22, superheater 9, ammonia steam turbine 17, drag ammonia generator 20 to generate electricity, the exhaust steam that ammonia steam turbine 17 is discharged cools form ammoniacal liquor 11 through exhaust steam regenerator 22, ammoniacal liquor vaporizer 14, ammonia condenser 18, enter recycle pump 12, ammoniacal liquor vaporizer 14 again, thus form ammonia steam Rankine cycle circuit; As during for multicomponent ammoniacal liquor, the lean solution that ammoniacal liquor vaporizer 14 produces gets back to ammonia condenser 18 through the pipeline 27 that backflows, condenser/evaporator 10, regenerator 15, the pipeline 19 that backflows.
Described feed water preheater 8, superheater 9, condenser/evaporator 10, regenerator 15, heat exchanger 13, ammoniacal liquor vaporizer 14, exhaust steam regenerator 22 can arrange one or more respectively, adopt series, parallel or series-parallel connection mode to connect.
Described ammonia condenser 18 conveniently technology is arranged, and adopts water or air etc. as cooling medium.
The heat-exchanging element of aforementioned device mentioned in the present invention can adopt tubulation, fin tube, coiler or spiral groove pipe, or adopts the pipe of other augmentation of heat transfer measures or the hollow cavity heat-exchanging element of other patterns.
While controlling a little higher than flue gas acid dew point temperature of wall surface temperature of vaporizer 13-1 heat exchanger surface, or adopt corrosion-resistant material effectively to alleviate the cold end corrosion of flue gas, can effectively reduce temperature of exhaust fume, avoiding flue gas low-temperature to corrode, high efficiente callback fume afterheat.
Unaccounted equipment and standby system, pipeline, instrument, valve in the present invention, be incubated, there is regulatory function bypass facility etc. adopt known mature technology to carry out supporting.
When gas turbine in the present invention becomes other pneumatic motors such as internal-combustion engine, Stirling-electric hybrid, the electricity generating device such as Otto-steam Rankine-ammonia steam Rankine combined cycle, Stirling cycle-steam Rankine-ammonia steam Rankine combined cycle can be formed equally.
Be provided with the regulating controller supporting with present system, the known Mature Regulation technology of existing steam Rankine cycle power station, Cheng's cycle power station or gas-steam combined cycle power plant is adopted to carry out supporting, steam Rankine-Ka Linne combined cycle generating unit energy economy, safety, high thermal efficiency are run, reaches energy-saving and cost-reducing object.
the present invention compared to existing technology tool has the following advantages:
1, energy-saving effect is remarkable: the Boulez of the present invention's design pauses-steam Rankine-ammonia steam Rankine combined cycle generating unit, using the vaporizer of the vapour condenser of steam Rankine cycle as the Rankine cycle of ammonia steam, the utilization of ammonia steam Rankine cycle system centering low-temperature heat source is utilized to have more high efficiency feature, a large amount of latent heats of vaporization of steam Kanicme cycle vapor condensation release are used for ammonia steam Rankine cycle efficiency power generation, only utilize the latent heat of vaporization of steam to generate electricity this block just nearly more than 50 KWhs/ton of steam; The absolute amplitude that in the Rankine cycle of ammonia steam, ammonia condenser load alleviates compared with the vapour condenser in conventional vapor Rankine cycle reaches more than 15%, and the power consumption of cooling circulating water significantly reduces.
2, the three wastes of power plant realize integrated utilization: during the heat exchanger employing phase-change heat-exchanger that back-end ductwork is arranged, can the waste heat of high efficiente callback flue gas, temperature of exhaust fume can be reduced to about 120 DEG C, during phase-change heat-exchanger vaporizer employing resistant material, temperature of exhaust fume can reduce more, reach about 85 DEG C, very favourable to the operation of system for desulfuration and denitration, while effectively avoiding flue gas low-temperature to corrode, the heat reclaimed is used for ammonia steam Rankine cycle system efficiency power generation, more meets cascaded utilization of energy principle.The waste heat such as waste water, waste vapour that steam Rankine cycle system produces all can be included ammonia steam Rankine cycle system in and recycle.Fundamentally eliminate other waste gas, waste water, waste vapour waste heat recovering device to the impact of whole unit circulation system, realize the integrated utilization of the real meaning of whole power plant system waste heat, water saving, successful such as joint vapour, economize on electricity etc.
3, adopt steam turbine draw gas as the thermal source of steam in the Rankine cycle of ammonia steam, reclaim further draw gas sensible heat, the latent heat of vaporization for the Rankine cycle of ammonia steam generate electricity, the benefit of whole Combined Cycle Unit is improved further.
4, the solution of the present invention both can be used for design, the construction of newly-built combined power plants system, also can be used for carrying out reducing energy consumption to existing pure condensate formula, sucking condensing type unit, the thermodynamic cycle of existing unit is not had a negative impact, the energy-saving potential of the abundant excavating device of energy, meet the industrial policy of country simultaneously, economical and environmental benefit is remarkable.
Accompanying drawing explanation
Fig. 1 is that a kind of Boulez of the present invention pauses-steam Rankine-ammonia steam Rankine combined cycle generating unit schematic flow sheet.
In Fig. 1: 1-exhaust heat boiler body, 2-saturated vapour, 3-superheater, 3-1-superheated vapor, 4-steam turbine, 4-1-draws gas, 5-exhaust steam, 6-water of condensation, 6-1-condensate pump, 7-feed water pump, 7-1-oxygen-eliminating device, 8-feed water preheater, 9-superheater, 10-condenser/evaporator, 11-ammoniacal liquor, 12-recycle pump, 13-heat exchanger, 13-1-vaporizer, 13-2-condenser, 14-ammoniacal liquor vaporizer, 15-regenerator, 16-ammonia superheated vapor, 17-ammonia steam turbine, 18-ammonia condenser, 19-backflows liquid, 20-ammonia generator, 21-steam-driven generator, 22-exhaust steam regenerator, 23-flue, 24-ammonia steam pipe line, 25-ammonia steam pipe line, 26-water of condensation, 27-backflows pipeline, 35-air, 36-gas compressor, 37-fuel-burning equipment, 38-fuel, 39-gas turbine, 40-high-temperature flue gas, 41-generator.
Embodiment
Below in conjunction with the drawings and specific embodiments, the present invention is described in further detail.
embodiment 1:
As shown in Figure 1, a kind of Boulez pauses-steam Rankine-ammonia steam Rankine Rankine combined cycle generating unit, and this device comprises Boulez and to pause circulation, steam Rankine cycle, ammonia steam Rankine cycle system, and specific embodiment is as follows:
Air 35 sends into fuel-burning equipment 37 through gas compressor 36, and with fuel 38 Thorough combustion entered, the high-temperature flue gas of generation enters gas turbine 39, drags gas turbine powered generator 41 and generates electricity, complete gas turbine unit Boulez and to pause circulation.
Described gas turbine 39 high-temperature flue gas 40 of discharging is as the thermal source of steam Rankine cycle system, and high-temperature flue gas 40 is discharged after reducing temperature through exhaust heat boiler body 1, superheater 2, feed water preheater 8, vaporizer 13-1.
Described steam Rankine cycle, refers to by exhaust heat boiler body 1 saturated vapour 2 out, forms superheated vapor 3-1 through superheater 3, sends into steam turbine 4 and drives steam-driven generator 21 to generate electricity; Steam turbine 4 exhaust steam 5 out enters condenser/evaporator 10 and forms water of condensation 6, and water of condensation 6 is sent into exhaust heat boiler body 1 through condensate pump 6-1, oxygen-eliminating device 7-1, feed water pump 7, feed water preheater 8, then produced saturated vapour, thus forms steam Rankine cycle circuit.
Described ammonia steam Rankine cycle, refer to that ammoniacal liquor 11 is through recycle pump 12, regenerator 15, condenser/evaporator 10, the lean solution formed returns ammonia condenser 18 through regenerator 15, the pipeline 19 that backflows, the ammonia steam produced is through exhaust steam regenerator 22, superheater 9, ammonia steam turbine 17, the exhaust steam of discharging from ammonia steam turbine 17 forms ammoniacal liquor 11 through exhaust steam regenerator 22, ammonia condenser 18, return recycle pump 12, thus form ammonia steam Rankine cycle circuit;
Or ammoniacal liquor 11 is through recycle pump 12, condenser/evaporator 10, the ammonia steam produced enters heat exchanger 13 through ammonia steam pipe line 25, form ammonia superheated vapor 16, enter ammonia steam turbine 17 to drag ammonia generator 20 and generate electricity, the exhaust steam of discharging from ammonia steam turbine 17 cools formation ammoniacal liquor 11 through ammonia condenser 18, enter recycle pump 12 again, thus form ammonia steam Rankine cycle circuit;
Described steam Rankine cycle and ammonia steam Rankine cycle circuit are combined by condenser/evaporator 10, in the Rankine cycle of high efficiente callback steam, the latent heat of vaporization of steam condensation release is used for low-temperature end ammonia steam Rankine cycle generating, and the steam condensation side of described steam Rankine cycle is negative pressure.
Described superheater 9 adopts the 4-1 that draws gas of steam turbine 4 in steam Rankine cycle as thermal source, and the 4-1 that draws gas cools formation condensed water 26 through superheater 9 and returns steam Rankine cycle system.
When described heat exchanger 13 is phase-change heat-exchanger, comprise vaporizer 13-1, condenser 13-2, wherein vaporizer 13-1 is arranged in flue 23, and condenser 13-2 is arranged in outside flue 23, and phase-change working substance adopts water; Flue gas adopts separated type heat exchange mode by the phase-change working substance of phase-change heat-exchanger 13 and condenser/evaporator 10 ammonia steam out: the heat that phase-change working substance absorbs flue gas in vaporizer 13-1 produces saturated vapour, saturated vapour is as the thermal source of ammonia steam, by condenser 13-2 and ammonia steam wall-type heat exchange, form condensation water after cooling and produce steam again by the heat of vaporizer 13-1 absorption flue gas again, thus form the Inner eycle loop of phase-change working substance; Phase-change working substance adopts natural circulation mode; The ammonia steam at condenser/evaporator 10 outlet manifold place is through the condenser 13-2 of ammonia steam pipe line 25, heat exchanger 13, the ammonia steam formed enters ammonia steam turbine 17 through superheater 9, get back to condenser/evaporator 10 through exhaust steam regenerator 22, ammonia condenser 18, recycle pump 12 again, thus form ammonia steam Rankine cycle circuit.
Be provided with ammoniacal liquor vaporizer 14: the exhaust steam that ammoniacal liquor vaporizer 14 adopts ammonia steam turbine 17 to export is as thermal source, the ammonia steam produced is through exhaust steam regenerator 22, superheater 9, ammonia steam turbine 17, drag ammonia generator 20 to generate electricity, the exhaust steam that ammonia steam turbine 17 is discharged cools form ammoniacal liquor 11 through exhaust steam regenerator 22, ammoniacal liquor vaporizer 14, ammonia condenser 18, enter recycle pump 12, ammoniacal liquor vaporizer 14 again, thus form ammonia steam Rankine cycle circuit; The lean solution that ammoniacal liquor vaporizer 14 produces gets back to ammonia condenser 18 through the pipeline 27 that backflows, condenser/evaporator 10, regenerator 15, the pipeline 19 that backflows.
Described feed water preheater 8, superheater 9, condenser/evaporator 10, regenerator 15, heat exchanger 13, ammoniacal liquor vaporizer 14, exhaust steam regenerator 22 can arrange one or more respectively, adopt series, parallel or series-parallel connection mode to connect.
Described ammonia condenser 18 conveniently technology is arranged, and adopts water or air etc. as cooling medium.
The heat-exchanging element of aforementioned device mentioned in the present invention can adopt tubulation, fin tube, coiler or spiral groove pipe, or adopts the pipe of other augmentation of heat transfer measures or the hollow cavity heat-exchanging element of other patterns.
While controlling a little higher than flue gas acid dew point temperature of wall surface temperature of vaporizer 13-1 heat exchanger surface, or adopt corrosion-resistant material effectively to alleviate the cold end corrosion of flue gas, can effectively reduce temperature of exhaust fume, avoiding flue gas low-temperature to corrode, high efficiente callback fume afterheat.
Unaccounted equipment and standby system, pipeline, instrument, valve in the present invention, be incubated, there is regulatory function bypass facility etc. adopt known mature technology to carry out supporting.
Be provided with the regulating controller supporting with present system, the known Mature Regulation technology of existing steam Rankine cycle power station, Cheng's cycle power station or gas-steam combined cycle power plant is adopted to carry out supporting, steam Rankine-organic Rankine combined cycle generating unit energy economy, safety, high thermal efficiency are run, reaches energy-saving and cost-reducing object.
Although the present invention with preferred embodiment openly as above, they are not for limiting the present invention, being anyly familiar with this those skilled in the art, without departing from the spirit and scope of the invention, from ought making various changes or retouch, belong to the protection domain of the present invention equally.What therefore protection scope of the present invention should define with the claim of the application is as the criterion.
Claims (2)
1. Boulez pauses-steam Rankine-ammonia steam Rankine combined cycle generating unit, and this device comprises Boulez and to pause circulation, steam Rankine cycle and ammonia steam Rankine cycle system, it is characterized in that:
Air (35) sends into fuel-burning equipment (37) through gas compressor (36), with the fuel entered (38) Thorough combustion, the high-temperature flue gas generated enters gas turbine (39), drag gas turbine powered generator (41) generating, gas turbine (39) high-temperature flue gas (40) of discharging is discharged as after the thermal source cooling of steam Rankine cycle system, thus completes gas turbine unit Boulez and to pause circulation;
Described steam Rankine cycle, refers to by exhaust heat boiler body (1) saturated vapour out (2), forms superheated vapor (3-1) through the first superheater (3), sends into steam turbine (4) and drives steam-driven generator (21) generating; Steam turbine (4) exhaust steam out (5) forms water of condensation (6) through condenser/evaporator (10), through oxygen-eliminating device (7-1), feed water pump (7), feed water preheater (8), exhaust heat boiler body (1), produce saturated vapour again, thus form steam Rankine cycle circuit;
Described ammonia steam Rankine cycle, refer to that ammoniacal liquor (11) is through recycle pump (12), condenser/evaporator (10), the ammonia steam produced enters the second superheater (9) through the first ammonia steam pipe line (24), form ammonia superheated vapor (16), enter ammonia steam turbine (17) and drag ammonia generator (20) generating, the exhaust steam of discharging from ammonia steam turbine (17) forms ammoniacal liquor (11) through ammonia condenser (18) cooling, enter recycle pump (12) again, thus form ammonia steam Rankine cycle circuit; Or ammoniacal liquor (11) is through recycle pump (12), condenser/evaporator (10), the ammonia steam that condenser/evaporator (10) outlet manifold goes out is through the second ammonia steam pipe line (25), condenser (13-2), form ammonia superheated vapor (16), enter ammonia steam turbine (17) and drag ammonia generator (20) generating, the exhaust steam of discharging from ammonia steam turbine (17) forms ammoniacal liquor (11) through ammonia condenser (18) cooling, enter recycle pump (12) again, thus form ammonia steam Rankine cycle circuit;
The constituent element that condenser (13-2) is phase-change heat-exchanger and heat exchanger (13), heat exchanger (13) comprises vaporizer (13-1), condenser (13-2), wherein vaporizer (13-1) is arranged in flue (23), and condenser (13-2) is arranged in flue (23) outward;
Draw gas (4-1) of described steam turbine (4) forms condensed water (26) through the second superheater (9), returns steam Rankine cycle system; Described steam Rankine cycle and ammonia steam Rankine cycle circuit are combined by condenser/evaporator (10), and in the Rankine cycle of high efficiente callback steam, the latent heat of vaporization of steam condensation release is used for ammonia steam Rankine cycle generating.
2. device according to claim 1, is characterized in that, is provided with ammonia evaporator (14), exhaust steam regenerator (22):
Ammoniacal liquor (11) is through recycle pump (12), ammonia evaporator (14), exhaust steam regenerator (22), the first ammonia steam pipe line (24), the second superheater (9), enter ammonia steam turbine (17) and drag ammonia generator (20) generating, the exhaust steam that ammonia steam turbine (17) is discharged forms ammoniacal liquor (11) through exhaust steam regenerator (22), ammonia evaporator (14), ammonia condenser (18) cooling, enter recycle pump (12), ammonia evaporator (14) again, thus form ammonia steam Rankine cycle circuit.
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| CN201310029373.7A CN103147809B (en) | 2013-01-27 | 2013-01-27 | Boulez pauses-steam Rankine-ammonia steam Rankine combined cycle generating unit |
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| CN201310029373.7A CN103147809B (en) | 2013-01-27 | 2013-01-27 | Boulez pauses-steam Rankine-ammonia steam Rankine combined cycle generating unit |
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| CN104929707B (en) * | 2015-05-30 | 2017-01-25 | 东北电力大学 | Power station exhaust steam latent heat and exhaust smoke waste heat combined generating system and optimizing running method |
| US10641132B2 (en) * | 2017-07-17 | 2020-05-05 | DOOSAN Heavy Industries Construction Co., LTD | Supercritical CO2 power generating system for preventing cold-end corrosion |
| CN116378863B (en) * | 2023-03-28 | 2024-07-09 | 哈尔滨工程大学 | Distributed multi-source energy supply integrated system based on zero-carbon internal combustion engine |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6820421B2 (en) * | 2002-09-23 | 2004-11-23 | Kalex, Llc | Low temperature geothermal system |
| CN202024347U (en) * | 2011-03-09 | 2011-11-02 | 南京华电节能环保设备有限公司 | Boiler low-temperature flue gas waste heat recovery plant |
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| GB1219559A (en) * | 1968-10-01 | 1971-01-20 | Sulzer Ag | Method of operating a closed circuit gas-turbine plant |
| CN1954134A (en) * | 2004-06-01 | 2007-04-25 | 正田登 | Highly efficient heat cycle device |
| CN102084093A (en) * | 2008-02-01 | 2011-06-01 | 西门子公司 | Method for operating a thermodynamic cycle, and thermodynamic cycle |
| CN201280956Y (en) * | 2008-10-31 | 2009-07-29 | 郭清温 | Flue gas waste heat recovering and generating set |
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