CN103145450B - Rusty spot transmutation glaze applied to ceramic artwork decoration and preparation method thereof - Google Patents
Rusty spot transmutation glaze applied to ceramic artwork decoration and preparation method thereof Download PDFInfo
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- CN103145450B CN103145450B CN201310101838.5A CN201310101838A CN103145450B CN 103145450 B CN103145450 B CN 103145450B CN 201310101838 A CN201310101838 A CN 201310101838A CN 103145450 B CN103145450 B CN 103145450B
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- glaze
- rust staining
- transmutation glaze
- furnace transmutation
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- 238000009377 nuclear transmutation Methods 0.000 title claims abstract description 31
- 239000000919 ceramic Substances 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 238000005034 decoration Methods 0.000 title abstract 2
- 230000005484 gravity Effects 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 8
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 8
- 238000000227 grinding Methods 0.000 claims abstract description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000001816 cooling Methods 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 7
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 24
- 238000010186 staining Methods 0.000 claims description 24
- 238000010304 firing Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 6
- 230000000694 effects Effects 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 abstract 2
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 235000010216 calcium carbonate Nutrition 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 abstract 1
- 229910052808 lithium carbonate Inorganic materials 0.000 abstract 1
- 238000005245 sintering Methods 0.000 abstract 1
- 238000002791 soaking Methods 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000021715 photosynthesis, light harvesting Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
Abstract
The invention discloses rusty spot transmutation glaze applied to ceramic artwork decoration and a preparation method thereof. According to the formula, the rusty spot transmutation glaze comprises 5-10% of Li2CO3, 30-50% of CaCO3, 15-35% of BaCO3, 0-1.0% (but not including 0%) of CoO, 5-10% of kaolin, 5-10% of rutile and 2-4% of praseodymiumyellow. The preparation method comprises the following steps of: measuring the components, sufficiently mixing, adding the mixture into a grinding tank, adding water which is 60-80wt% of the dry powder, grinding for 4-8 hours, subsequently adjusting the grinded glaze to be of the concentration that the true specific gravity is 24-26 degrees, spraying on or soaking a ceramic product into the glaze, drying, subsequently feeding into a kiln, sintering for 8-11 hours at 1160-1185 DEG C, and finally naturally cooling and discharging from the kiln. The prepared rusty spot transmutation glaze is high in acid chemical stability, strong in processing property and free of toxic and side effects, and is in the natural country style.
Description
Technical field
The present invention relates to a kind of rust staining furnace transmutation glaze of decorating for ceramic artwork and preparation method thereof.
Background technology
General furnace transmutation glaze shows not out its unique effect and artistic value on porcelain base; In traditional Production of Ceramics, the general high quality materials of the configuration of furnace transmutation glaze, foreign matter content is higher, burn till and need 1250 ℃ of above high temperature, and energy dissipation is large, and processing performance is poor.
Summary of the invention
For solving the problems of the technologies described above, the object of the present invention is to provide rust staining furnace transmutation glaze of decorating for ceramic artwork of the naturally rural makings style that a kind of acid-resistant chemical stability is high, processing performance is strong, without any side effects and preparation method thereof.
A kind of rust staining furnace transmutation glaze of decorating for ceramic artwork of the present invention, calculates by mass percentage, following component and content, consists of:
Li
2C0
3：5%≤Li
2C0
3≤10%、
CaCO
3：30%≤CaCO
3≤50%、
BaCO
3：15%≤BaCO
3≤35%、
CoO：0<CoO≤1.0%、
Kaolin: 5%≤kaolin≤10%,
Rutile: 5%≤rutile≤10%,
Pr-yellow material: 2%≤pr-yellow material≤4%.
Wherein, Li
2c0
3be preferably 6%≤Li
2c0
3≤ 8%.
CaCO
3be preferably 40%≤CaCO
3≤ 50%.
BaCO
3be preferably 25%≤BaCO
3≤ 35%.
The preparation method of above-mentioned rust staining furnace transmutation glaze is:
After each component being weighed by formula, fully mix and add in grinding pot, add the water of the 60%-80% that is equivalent to dry powder weight to grind 4-8 hour, then the glaze of milled being adjusted to concentration is true specific gravity 24-26, spray or be soaked on fictile, after airing, in entering kiln, the temperature of 1160 ℃-1185 ℃ of glaze firing carries out burning till for 8-11 hour, finally by naturally cooling kiln discharge, make described rust staining furnace transmutation glaze.
Preferably, at Jia Shui, grind after 4-8 hour, carry out testing graininess, testing graininess is crossed 300 order mesh screens, and residue enters next operation at 1g-3g: it is true specific gravity 24-26 that the glaze of milled is adjusted to concentration.
Rust staining furnace transmutation glaze is by compound after sufficiently mixing, adds water and grinds to form glaze, and its is sprayed or soaks glaze on fictile, and a kind of furnace transmutation glaze forming after high-temperature firing, is a kind of fictile that is practically applicable to rural soil series style.Its Art kinds, feature are made a world of difference with general furnace transmutation glaze, show not out its unique effect and artistic value on general porcelain base, and it is that glaze combines with body and a kind of original in style artwork that forms.The present invention adopts Li
2cO
3as solvent, lithium compound is one of ideal solvent reducing ceramic firing temperature (the particularly maturing temperature of glaze), can replace 3-5 other basic carbonate doubly, uses Li
2cO
3prepare this furnace transmutation glaze.Because this solvent action is strong, thus AL, O, the SiO content in glaze can be improved, thus improved the chemical stability of glaze, greatly reduce firing temperature.It is quite thin that this glaze invests porcelain base surface, and thickness is at 0.06-0.15mm, and its glaze water true specific gravity, at 24-26, breaks through conventional furnace transmutation glaze layer and wants thick convention, solved on fictile usually with occurring the defects such as distortion, foaming.
Embodiment
By specific embodiments of the invention given below, can further understand the present invention, but they not limitation of the invention.Some nonessential improvement and adjustment of for those skilled in the art, according to foregoing invention content, doing, be also considered as dropping in protection scope of the present invention.
In addition, unless stated otherwise, the per-cent adopting in the present invention is mass percent.
Embodiment 1
Formula 1:
Li
2C0
3：6%、
CaCO
3：50%、
BaCO
3：25%、
CoO：1%、
Kaolin: 7%,
Rutile: 8%,
Pr-yellow material: 3%.
After each component being weighed by formula 1, fully mix and add in grinding pot, add 60% the water that is equivalent to dry powder weight to grind 4 hours, granularity is crossed 300 order mesh screens after tested, residue is as the criterion in 1g-3g left and right, then the glaze of milled being adjusted to concentration is true specific gravity 24-26, sprays or is soaked on fictile, and after airing, in entering kiln, the temperature of 1160 ℃-1185 ℃ of glaze firing carries out burning till for 8 hours, finally by naturally cooling kiln discharge, make rust staining furnace transmutation glaze.
The dilute hydrochloric acid 24 hours of the rust staining furnace transmutation glaze making being put into 1mol/L, its rust staining color remains unchanged.
Embodiment 2
Formula 2:
Li
2C0
3：7%、
CaCO
3：40%、
BaCO
3：35%、
CoO：0.5%、
Kaolin: 6%,
Rutile: 7.5%,
Pr-yellow material: 4%.
After each component being weighed by formula 2, fully mix and add in grinding pot, add 70% the water that is equivalent to dry powder weight to grind 6 hours, granularity is crossed 300 order mesh screens after tested, residue is as the criterion in 1g-3g left and right, then the glaze of milled being adjusted to concentration is true specific gravity 24-26, sprays or is soaked on fictile, and after airing, in entering kiln, the temperature of 1160 ℃-1185 ℃ of glaze firing carries out burning till for 10 hours, finally by naturally cooling kiln discharge, make rust staining furnace transmutation glaze.
The dilute hydrochloric acid 24 hours of the rust staining furnace transmutation glaze making being put into 1mol/L, its rust staining color remains unchanged.
Embodiment 3
Formula 3:
Li
2C0
3：8%、
CaCO
3：45%、
BaCO
3：30%、
CoO：0.4%、
Kaolin: 8%,
Rutile: 6.6%,
Pr-yellow material: 2%.
After each component being weighed by formula 3, fully mix and add in grinding pot, add 80% the water that is equivalent to dry powder weight to grind 8 hours, granularity is crossed 300 order mesh screens after tested, residue is as the criterion in 1g-3g left and right, then the glaze of milled being adjusted to concentration is true specific gravity 24-26, sprays or is soaked on fictile, and after airing, in entering kiln, the temperature of 1160 ℃-1185 ℃ of glaze firing carries out burning till for 11 hours, finally by naturally cooling kiln discharge, make rust staining furnace transmutation glaze.
The dilute hydrochloric acid 24 hours of the rust staining furnace transmutation glaze making being put into 1mol/L, its rust staining color remains unchanged.
Claims (6)
1. a rust staining furnace transmutation glaze of decorating for ceramic artwork, is characterized in that, calculates by mass percentage, following component and content, consists of:
Li
2CO
3：5%≤Li
2CO
3≤10%、
CaCO
3：30%≤CaCO
3≤50%、
BaCO
3：15%≤BaCO
3≤35%、
CoO：0<CoO≤1.0%、
Kaolin: 5%≤kaolin≤10%,
Rutile: 5%≤rutile≤10%,
Pr-yellow material: 2%≤pr-yellow material≤4%;
After each component being weighed by formula, fully mix and add in grinding pot, add the water of the 60%-80% that is equivalent to dry powder weight to grind 4-8 hour, then the glaze of milled being adjusted to concentration is true specific gravity 24-26, spray or be soaked on fictile, after airing, in entering kiln, the temperature of 1160 ℃-1185 ℃ of glaze firing carries out burning till for 8-11 hour, finally by naturally cooling kiln discharge, make described rust staining furnace transmutation glaze.
2. a kind of rust staining furnace transmutation glaze of decorating for ceramic artwork as claimed in claim 1, is characterized in that Li
2cO
3: 6%≤Li
2cO
3≤ 8%; Each component concentration sum is 100%.
3. a kind of rust staining furnace transmutation glaze of decorating for ceramic artwork as claimed in claim 1, is characterized in that CaCO
3: 40%≤CaCO
3≤ 50%.
4. a kind of rust staining furnace transmutation glaze of decorating for ceramic artwork as claimed in claim 1, is characterized in that BaCO
3: 25%≤BaCO
3≤ 35%.
5. the preparation method of the rust staining furnace transmutation glaze described in a claim 1-4 any one, it is characterized in that, after each component being weighed by formula, fully mix and add in grinding pot, add the water of the 60%-80% that is equivalent to dry powder weight to grind 4-8 hour, then the glaze of milled being adjusted to concentration is true specific gravity 24-26, spray or be soaked on fictile, after airing, in entering kiln, the temperature of 1160 ℃-1185 ℃ of glaze firing carries out burning till for 8-11 hour, finally by naturally cooling kiln discharge, make described rust staining furnace transmutation glaze.
6. the preparation method of rust staining furnace transmutation glaze as claimed in claim 5, it is characterized in that, add water and grind after 4-8 hour, carry out testing graininess, testing graininess is crossed 300 order mesh screens, and residue enters next operation at 1g-3g: it is true specific gravity 24-26 that the glaze of milled is adjusted to concentration.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310101838.5A CN103145450B (en) | 2013-03-27 | 2013-03-27 | Rusty spot transmutation glaze applied to ceramic artwork decoration and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310101838.5A CN103145450B (en) | 2013-03-27 | 2013-03-27 | Rusty spot transmutation glaze applied to ceramic artwork decoration and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103145450A CN103145450A (en) | 2013-06-12 |
| CN103145450B true CN103145450B (en) | 2014-04-30 |
Family
ID=48543836
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310101838.5A Active CN103145450B (en) | 2013-03-27 | 2013-03-27 | Rusty spot transmutation glaze applied to ceramic artwork decoration and preparation method thereof |
Country Status (1)
| Country | Link |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4340645A (en) * | 1981-05-11 | 1982-07-20 | Mobay Chemical Corporation | Leadless glazes for whiteware |
| US5091345A (en) * | 1989-05-31 | 1992-02-25 | Johnson Matthey Public Limited Company | Glass composition |
| CN101659567A (en) * | 2009-09-04 | 2010-03-03 | 黄建平 | Furnace transmutation decoration glazed brick and production technology |
| CN102442841A (en) * | 2011-10-12 | 2012-05-09 | 上海高诚艺术包装有限公司 | Panther print glaze and preparation and use method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06279052A (en) * | 1993-03-25 | 1994-10-04 | Horie Kako Kk | Smoky glaze |
-
2013
- 2013-03-27 CN CN201310101838.5A patent/CN103145450B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4340645A (en) * | 1981-05-11 | 1982-07-20 | Mobay Chemical Corporation | Leadless glazes for whiteware |
| US5091345A (en) * | 1989-05-31 | 1992-02-25 | Johnson Matthey Public Limited Company | Glass composition |
| CN101659567A (en) * | 2009-09-04 | 2010-03-03 | 黄建平 | Furnace transmutation decoration glazed brick and production technology |
| CN102442841A (en) * | 2011-10-12 | 2012-05-09 | 上海高诚艺术包装有限公司 | Panther print glaze and preparation and use method thereof |
Non-Patent Citations (1)
| Title |
|---|
| JP特开平6-279052A 1994.10.04 |
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|---|---|
| CN103145450A (en) | 2013-06-12 |
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Effective date of registration: 20151231 Address after: Meixi Lake Road Industrial Park in Tong'an District of Xiamen city in Fujian province 361000 No. 40 Patentee after: XIAMEN EDENUS CERAMIC INDUSTRY Co.,Ltd. Address before: Siming District of Xiamen city in Fujian province 361000 three road No. 288 Pu Xi fourth (plant) Patentee before: EDENUS ART Co.,Ltd. |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
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Denomination of invention: The invention relates to a rusty spot kiln change glaze for ceramic art decoration and a preparation method thereof Effective date of registration: 20220518 Granted publication date: 20140430 Pledgee: Fujian Jin Channel Financing Guarantee Co.,Ltd. Pledgor: XIAMEN EDENUS CERAMIC INDUSTRY Co.,Ltd. Registration number: Y2022980005857 |
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Date of cancellation: 20230814 Granted publication date: 20140430 Pledgee: Fujian Jin Channel Financing Guarantee Co.,Ltd. Pledgor: XIAMEN EDENUS CERAMIC INDUSTRY Co.,Ltd. Registration number: Y2022980005857 |
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Denomination of invention: A Rust Spot Kiln Varying Glaze Used for Decorating Ceramic Artworks and Its Preparation Method Effective date of registration: 20230815 Granted publication date: 20140430 Pledgee: Fujian Jin Channel Financing Guarantee Co.,Ltd. Pledgor: XIAMEN EDENUS CERAMIC INDUSTRY Co.,Ltd. Registration number: Y2023110000344 |