CN103131073A - Color masterbatch and preparation method thereof - Google Patents
Color masterbatch and preparation method thereof Download PDFInfo
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- CN103131073A CN103131073A CN2011103770461A CN201110377046A CN103131073A CN 103131073 A CN103131073 A CN 103131073A CN 2011103770461 A CN2011103770461 A CN 2011103770461A CN 201110377046 A CN201110377046 A CN 201110377046A CN 103131073 A CN103131073 A CN 103131073A
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Abstract
The invention belongs to the technical field of polymer materials, and discloses a color masterbatch and a preparation method thereof. The color masterbatch is prepared by the following components of, by weight, 40-80 parts of an ethylene-octene-based thermoplastic elastomer, 20-60 parts of titanium dioxide, 0.01-10 parts of carbon black, 0.05-10 parts of a dispersing agent and 0.01-2 parts of an auxiliary agent. The preparation method of the color masterbatch comprises the following steps of adding 40-80 parts of the ethylene-octene-based thermoplastic elastomer, 20-60 parts of titanium dioxide, 0.01-10 parts of carbon black, 0.05-10 parts of the dispersing agent and 0.01-2 parts of the auxiliary agent to a high-speed mixer, stirring for 2-10 min at a normal temperature and at a high speed, then putting the mixed components in a screw extruder, mixing at a temperature for keeping the ethylene-octene-based thermoplastic elastomer in a melt state to obtain a polymer, extruding the obtained polymer, then cutting the extruded polymer in sections so as to form particles. Compared a conventional color masterbatch, the color masterbatch provided by the invention has good compatibility with a polyformaldehyde matrix, uniform color and easy dispersion, the prepared product has good toughness, and the method is simple and easy to realize.
Description
Technical field
The invention belongs to technical field of polymer materials, relate to a kind of Masterbatch and preparation method thereof.
Background technology
Polyoxymethylene (Polyformaldehyde) is the thermoplasticity crystalline polymer, is described as " supersteel " or " match steel ", claims again polyoxymethylene, and english abbreviation is POM.It has higher intensity and Young's modulus, and frictional coefficient is little, and wear resisting property is good, also has the ability of high resistance creep and stress relaxation, and its good stability of the dimension, and water-intake rate is very little, so water-intake rate can not considered the impact of its mechanical property.Polyoxymethylene also has dielectric properties preferably, and in very wide frequency and temperature range, its specific inductivity and dielectric loss angle tangent change very little.
Acetal plastic is the another fine resin kind of development after nylon, can be widely used at the industries such as electric, automobile, building and precision instrument bearing, gear, pull bar and guide rail, body of a motor car, prime the fuel system accessory etc.But POM is one of extremely labile engineering plastics, in the situation that the aerobic heating is easy to decompose, decomposition temperature is 240 ℃, irritant and corrosive gases generation during decomposition.So when selecting tinting material, should be high temperature resistant, the tinting material that prevents again can accelerate POM and decompose (referring to " coloring plastic and Masterbatch application manual ", Wu Lifeng, 1998, the 163 pages).If adopt the method for adding Masterbatch to make POM dyeing, can reduce the number of times of extruding of POM, thereby reduce its decomposition.
Masterbatch is a kind of plastics of the sixties in 20th century exploitation, the painted product innovation of fiber, and it is that the pigment super quantity is attached in resin and the mixture of the polymkeric substance that makes uniformly; The U.S. is referred to as condensed pigment or pigment preparation matter.The Masterbatch chief component is tinting material, carrier, dispersion agent three parts.Wherein, carrier is the matrix of Masterbatch, and can make Masterbatch be particulate state.Require carrier will consider with to be colored resin compatible good, the mobility of carrier should be greater than being colored resin simultaneously, and do not affect the performance (referring to " coloring plastic and Masterbatch application manual ", Wu Lifeng, 1998, the 197 pages) of goods after painted.
But, in preparation POM Masterbatch, if selection POM is matrix, owing to having added a large amount of tinting materials, use the common screw forcing machine to add man-hour, be difficult to avoid the decomposition of matrix.The inventor also once tried out at present relatively commonly used take polymkeric substance such as LLDPE, HDPE or PP as matrix, but in use find, these matrixes and POM consistency are bad, can cause the goods of injection moulding that demixing phenomenon is arranged, frangibility or peeling during bending, especially grey or white Masterbatch need to add the titanium dioxide of larger content, after such Masterbatch adds POM, POM are become fragile.
Summary of the invention
For matrix in prior art and the bad problem of polyoxymethylene consistency, the objective of the invention is in order to provide a kind of, color even good with the polyformaldehyde resin consistency easily to disperse, and can increase the Masterbatch of polyoxymethylene toughness.
Another object of the present invention is to provide a kind of preparation method of above-mentioned Masterbatch.
Technical scheme of the present invention is as follows:
The invention provides a kind of Masterbatch, this Masterbatch is made by the component that comprises following weight part:
Ethylene octene base thermoplastic elastomer 40-80 part,
Titanium dioxide 20-60 part,
Carbon black 0.01-10 part,
Dispersion agent 0.05-10 part,
Auxiliary agent 0.01-2 part.
Described Masterbatch is made by the component that comprises following weight part:
Ethylene octene base thermoplastic elastomer 50-70 part,
Titanium dioxide 30-50 part,
Carbon black 0.01-8 part,
Dispersion agent 0.5-5 part,
Auxiliary agent 0.02-1 part.
Described titanium dioxide is anatase titanium dioxide or rutile-type, and median size is 0.01～1 μ m, and pH value is between 6～8.
The preferred median size of described titanium dioxide is 0.1～0.2 μ m, and pH value is between 7～8.
The median size of described carbon black is 10～500 μ m, preferably 20～200 μ m; PH value is 3～9.5, preferably 7～8.
Described dispersion agent is selected from one or more the material in polyethylene wax, Poly Propylene Wax, modified polyethylene wax or paraffin.
Described auxiliary agent is selected from one or more the material in weighting agent, oxidation inhibitor, photostabilizer, static inhibitor, coupling agent, tinting material or softening agent.
Described weighting agent is selected from one or more the material in calcium carbonate, kaolin, talcum powder, mica powder, wollastonite or whisker.
Described oxidation inhibitor is selected from 2,6-di-tert-butyl-4-methy phenol, 3-(3, the 5-di-tert-butyl-hydroxy phenyl) material of one or more in the positive stearyl alcohol ester of propionic acid, four [3-(3 ', 5 '-di-t-butyl-4 '-hydroxy phenyl) propionic acid] pentaerythritol ester, Tyox B or thio-2 acid distearyl acid alcohol ester.
Described photostabilizer is selected from ESCALOL 567, Octabenzone, 2-(2 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl)-5-chlorinated benzotriazole, 2-(2 '-hydroxyl-3 ', 5 '-di-tert-pentyl-phenyl)-5-chlorinated benzotriazole, two (3,5-di-tert-butyl-4-hydroxyl benzyl phosphonic acids mono ethyl ester) nickel or sebacic acid two (2,2,6,6-tetramethyl piperidine alcohol ester) a kind of in or more than one material.
Described static inhibitor is selected from glycerol monostearate or N, the mixture of two (2-hydroxyethyl) fatty acid amines of N-and ester thereof (the Lankrostat LDN that produces as Diamod Shamroch company).
Described coupling agent is selected from vinyltriethoxysilane, isopropyl triisostearoyl titanate, aluminium titanium composite coupler or Aluminate composite coupler.
Described tinting material is selected from that cadmium yellow, cadmium orange, cadmium red, ferric oxide, mercury are red, one or more the material in cobalt violet, ultramarine, phthalocyanine blue or phthalein viridescent.
Described softening agent is selected from dioctyl phthalate (DOP) or dibutyl phthalate.
The present invention also provides a kind of preparation method of above-mentioned Masterbatch, and the method comprises the following steps:
With 40-80 part ethylene octene base thermoplastic elastomer, 20-60 part titanium dioxide, 0.01-10 part carbon black, 0.05-10 part dispersion agent and 0.01-2 part auxiliary agent, add in high-speed mixer, high-speed stirring 2～10min under normal temperature, then after mixing, component is put into screw extrusion press, mix at the temperature that makes ethylene octene base thermoplastic elastomer maintenance melted state and obtain polymkeric substance, polymer-extruded with what obtain, then the section of being cut to, form particle.
Described forcing machine is single screw rod or twin screw extruder, and the length-to-diameter ratio of forcing machine is 24: 1～48: 1.
It is described that to make ethylene octene base thermoplastic elastomer keep the temperature of melted state be 120～220 ℃.
The present invention compared with prior art has the following advantages and beneficial effect:
Principle of the present invention is to have selected ethylene octene base thermoplastic elastomer as the matrix of polyoxymethylene with grey Masterbatch, ethylene octene base thermoplastic elastomer is that ethylene chain with the flexible chain coiled structure of octene and crystallization is as the physical crosslinking point, make the toughness of its existing excellence that good processibility be arranged again, on the one hand it and polyoxymethylene have better consistency, it can improve the toughness of polyoxymethylene on the other hand, has reduced the impact on polyoxymethylene toughness of adding of titanium dioxide.And ethylene octene base thermoplastic elastomer narrow molecular weight distribution, have mobility preferably, can improve the dispersion effect of filler, also can improve the weld mark strength of goods simultaneously.In addition, there is no unsaturated double-bond in this elastomer molecules structure, have good ageing-resistant performance, do with it the ageing-resistant performance that matrix can also improve polyoxymethylene to a certain extent.The titanium dioxide of selecting and the pH value of carbon black between 7～8, are that polyoxymethylene more easily decomposes because under the environment of acidity, have therefore selected the toner of meta-alkalescence.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.
It is the POE 745L product of DOW company that ethylene octene base thermoplastic elastomer is executed what adopt in example.
Described polyoxymethylene is the POM M90-44 of Bao Li company.
Embodiment 1
40 parts of ethylene octene base thermoplastic elastomers; Titanium dioxide: rutile-type, median size are 0.01 μ m, and pH value is at 6,20 parts; Carbon black: median size is that 10 μ m, pH value are 3,0.01 parts; 0.05 part, polyethylene of dispersing agent wax; 0.005 part of 0.005 part of oxidation inhibitor 2,6 di tert butyl 4 methyl phenol and photostabilizer ESCALOL 567.Take raw material according to above component and weight part content, add in high-speed mixer, high-speed stirring 2min under normal temperature; After mixing, to put into length-to-diameter ratio be the single screw extrusion machine of 24: 1 to component, and the temperature of controlling forcing machine is 120 ℃, mixes to obtain polymkeric substance, and the polymkeric substance that obtains is extruded with strip, and then the section of being cut to, form particle.
Masterbatch particle and polyoxymethylene that aforesaid way obtains is even according to blend in 1: 25, the particle after blend is injection molded into the standard batten according to iso standard, see its outward appearance and survey its mechanical property, see Table 1.By the performance of test in table 1 as seen, after adding the Masterbatch of this embodiment, the polyoxymethylene surface property is good, be difficult for layering or peeling after folding, unaffected on its mechanical properties.
Embodiment 2
80 parts of ethylene octene base thermoplastic elastomers; Titanium dioxide: anatase titanium dioxide, median size are that 1 μ m, pH value are 8,60 parts; Carbon black: median size is that 10 μ m, pH value are 9.5,10 parts; 10 parts of dispersion agent Poly Propylene Waxes; 0.25 part of the positive stearyl alcohol ester of oxidation inhibitor 3-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid; [3-(3 ' for oxidation inhibitor four, 5 '-di-t-butyl-4 '-hydroxy phenyl) propionic acid] 0.25 part of pentaerythritol ester and 0.25 part of photostabilizer Octabenzone, the steady agent sebacic acid of light two (2,2,6,6-tetramethyl piperidine alcohol ester) 0.25 part, 0.8 part of weighting agent talcum powder, 0.2 part of coupling agent vinyltriethoxysilane.
Take raw material according to above component and weight part content, add in high-speed mixer, high-speed stirring 10min under normal temperature; After mixing, to put into length-to-diameter ratio be the twin screw extruder of 48: 1 to component, and the temperature of controlling forcing machine is 220 ℃, mixes to obtain polymkeric substance, and the polymkeric substance that obtains is extruded with strip, and then the section of being cut to, form particle.
Masterbatch particle and polyoxymethylene that aforesaid way obtains is even according to blend in 1: 20, the particle after blend is injection molded into the standard batten according to iso standard, see its outward appearance and survey its mechanical property, see Table 1.By the performance of test in table 1 as seen, after adding the Masterbatch of this embodiment, the polyoxymethylene surface property is good, be difficult for layering or peeling after folding, unaffected on its mechanical properties.
Embodiment 3
60 parts of ethylene octene base thermoplastic elastomers; Titanium dioxide: anatase titanium dioxide, median size are that 0.5 μ m, pH value are 8,40 parts; The median size of carbon black is that 250 μ m, pH value are 6.5,5 parts; 5 parts of dispersion agent Poly Propylene Waxes; Auxiliary agent has adopted 0.25 part of photostabilizer Octabenzone, 0.25 part of photostabilizer sebacic acid two (2,2,6,6-tetramethyl piperidine alcohol ester), 0.4 part, weighting agent calcium carbonate, 0.1 part, tinting material ultramarine.Take raw material according to above component and weight part content, add in high-speed mixer, high-speed stirring 6min under normal temperature.After mixing, to put into length-to-diameter ratio be the single screw extrusion machine of 36: 1 to component, and the temperature of controlling forcing machine is 170 ℃, mixes to obtain polymkeric substance, and the polymkeric substance that obtains is extruded with strip, and then the section of being cut to, form particle.
Masterbatch particle and polyoxymethylene that aforesaid way obtains is even according to blend in 1: 30, the particle after blend is injection molded into the standard batten according to iso standard, see its outward appearance and survey its mechanical property, see Table 1.By the performance of test in table 1 as seen, after adding the Masterbatch of this embodiment, the polyoxymethylene surface property is good, be difficult for layering or peeling after folding, unaffected on its mechanical properties.
Embodiment 4
50 parts of ethylene octene base thermoplastic elastomers; Titanium dioxide: rutile-type, for median size is that 0.1 μ m, pH value are 7,30 parts; Carbon black: median size is that 20 μ m, pH value are 7,0.01 parts; 0.5 part of dispersion agent modified polyethylene wax; Auxiliary agent has adopted 0.01 part of static inhibitor glycerol monostearate, 0.005 part of coupling agent isopropyl triisostearoyl titanate, 0.005 part of tinting material cadmium yellow.
Take raw material according to above component and weight part content, add in high-speed mixer, high-speed stirring 3min under normal temperature; After mixing, to put into length-to-diameter ratio be 30: 1 single screw extrusion machines to component, and the temperature of controlling forcing machine is 120～220 ℃, mixes obtaining polymkeric substance, and the polymkeric substance that obtains is extruded with strip, and then the section of being cut to, form particle.
Masterbatch particle and polyoxymethylene that aforesaid way obtains is even according to blend in 1: 35, the particle after blend is injection molded into the standard batten according to iso standard, see its outward appearance and survey its mechanical property, see Table 1.By the performance of test in table 1 as seen, after adding the Masterbatch of this embodiment, the polyoxymethylene surface property is good, be difficult for layering or peeling after folding, unaffected on its mechanical properties.
Table 1
Embodiment 5
70 parts of ethylene octene base thermoplastic elastomers; Titanium dioxide: anatase titanium dioxide, median size are that 0.2 μ m, pH value are 8,50 parts; Carbon black: median size is that 200 μ m, pH value are 8,8 parts; 5 parts, dispersion agent paraffin; Auxiliary agent has adopted static inhibitor N, 0.5 part, the mixture of two (2-hydroxyethyl) fatty acid amines of N-and ester thereof (Diamod Shamroch company produce Lankrostat LDN), 0.025 part of tinting material ferric oxide, dark green 0.03 part of phthalein.
Take raw material according to above component and weight part content, add in high-speed mixer, high-speed stirring 10min under normal temperature.After mixing, to put into length-to-diameter ratio be the twin screw extruder of 40: 1 to component, and the temperature of controlling forcing machine is 120～190 ℃, mixes to obtain polymkeric substance, and the polymkeric substance that obtains is extruded with strip, and then the section of being cut to, form particle.
Embodiment 6
50 parts of ethylene octene base thermoplastic elastomers; Titanium dioxide: anatase titanium dioxide, median size are that 0.1～0.2 μ m, pH value are 7,50 parts; Carbon black: median size is that 20～200 μ m, pH value are 7.5,4 parts; 2.5 parts of dispersion agent modified polyethylene waxs; Auxiliary agent has adopted photostabilizer 2-(2 '-hydroxyl-3 ', 5 '-di-tert-pentyl-phenyl)-0.01 part of 5-chlorinated benzotriazole, photostabilizer sebacic acid two (2,2,6,6-tetramethyl piperidine alcohol ester) 0.01 part of 0.01 part, 0.02 part of weighting agent wollastonite and plasticizer phthalic acid dioctyl ester.
Take raw material according to above component and weight part content, add in high-speed mixer, high-speed stirring 5min under normal temperature.After mixing, to put into length-to-diameter ratio be the twin screw extruder of 35: 1 to component, and the temperature of controlling forcing machine is 190～220 ℃, mixes to obtain polymkeric substance, and the polymkeric substance that obtains is extruded with strip, and then the section of being cut to, form particle.
The above-mentioned description to embodiment is can understand and apply the invention for ease of those skilled in the art.The person skilled in the art obviously can easily make various modifications to these embodiment, and in the General Principle of this explanation is applied to other embodiment and needn't pass through performing creative labour.Therefore, the invention is not restricted to the embodiment here, those skilled in the art are according to announcement of the present invention, and not breaking away from the improvement that category of the present invention makes and revise all should be within protection scope of the present invention.
Claims (9)
1. Masterbatch, it is characterized in that: this Masterbatch is made by the component that comprises following weight part:
Ethylene octene base thermoplastic elastomer 40-80 part,
Titanium dioxide 20-60 part,
Carbon black 0.01-10 part,
Dispersion agent 0.05-10 part,
Auxiliary agent 0.01-2 part.
2. Masterbatch according to claim 1, it is characterized in that: described Masterbatch is made by the component that comprises following weight part:
Ethylene octene base thermoplastic elastomer 50-70 part,
Titanium dioxide 30-50 part,
Carbon black 0.01-8 part,
Dispersion agent 0.5-5 part,
Auxiliary agent 0.02-1 part.
3. Masterbatch according to claim 1, it is characterized in that: described titanium dioxide is anatase titanium dioxide or rutile-type, and median size is 0.01～1 μ m, and pH value is between 6～8; Preferred median size is 0.1～0.2 μ m, and pH value is between 7～8.
4. Masterbatch according to claim 1, it is characterized in that: the median size of described carbon black is 10～500 μ m, preferably 20～200 μ m; PH value is 3～9.5, preferably 7～8.
5. Masterbatch according to claim 1 is characterized in that: described dispersion agent is selected from one or more the material in polyethylene wax, Poly Propylene Wax, modified polyethylene wax or paraffin.
6. Masterbatch according to claim 1 is characterized in that: described auxiliary agent is selected from one or more the material in weighting agent, oxidation inhibitor, photostabilizer, static inhibitor, coupling agent, tinting material or softening agent; Wherein: weighting agent is selected from one or more the material in calcium carbonate, kaolin, talcum powder, mica powder, wollastonite or whisker; Oxidation inhibitor is selected from 2,6-di-tert-butyl-4-methy phenol, 3-(3, the 5-di-tert-butyl-hydroxy phenyl) material of one or more in the positive stearyl alcohol ester of propionic acid, four [3-(3 ', 5 '-di-t-butyl-4 '-hydroxy phenyl) propionic acid] pentaerythritol ester, Tyox B or thio-2 acid distearyl acid alcohol ester; Photostabilizer is selected from ESCALOL 567, Octabenzone, 2-(2 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl)-5-chlorinated benzotriazole, 2-(2 '-hydroxyl-3 ', 5 '-di-tert-pentyl-phenyl)-5-chlorinated benzotriazole, two (3,5-di-tert-butyl-4-hydroxyl benzyl phosphonic acids mono ethyl ester) nickel or sebacic acid two (2,2,6,6-tetramethyl piperidine alcohol ester) a kind of in or more than one material; Static inhibitor is selected from glycerol monostearate or N, the mixture of two (2-hydroxyethyl) fatty acid amines of N-and ester thereof; Coupling agent is selected from vinyltriethoxysilane, isopropyl triisostearoyl titanate, aluminium titanium composite coupler or Aluminate composite coupler; Tinting material is selected from that cadmium yellow, cadmium orange, cadmium red, ferric oxide, mercury are red, one or more the material in cobalt violet, ultramarine, phthalocyanine blue or phthalein viridescent; Softening agent is selected from dioctyl phthalate (DOP) or dibutyl phthalate.
7. the preparation method of the arbitrary described Masterbatch of claim 1 to 6, it is characterized in that: the method comprises the following steps:
With 40-80 part ethylene octene base thermoplastic elastomer, 20-60 part titanium dioxide, 0.01-10 part carbon black, 0.05-10 part dispersion agent and 0.01-2 part auxiliary agent, add in high-speed mixer, high-speed stirring 2～10min under normal temperature, then after mixing, component is put into screw extrusion press, mix at the temperature that makes ethylene octene base thermoplastic elastomer maintenance melted state and obtain polymkeric substance, polymer-extruded with what obtain, then the section of being cut to, form particle.
8. the preparation method of Masterbatch according to claim 7, it is characterized in that: described forcing machine is single screw rod or twin screw extruder, the length-to-diameter ratio of forcing machine is 24: 1～48: 1.
9. the preparation method of Masterbatch according to claim 7 is characterized in that: described to make ethylene octene base thermoplastic elastomer keep the temperature of melted state be 120～220 ℃.
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| CN2011103770461A CN103131073A (en) | 2011-11-23 | 2011-11-23 | Color masterbatch and preparation method thereof |
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| CN2011103770461A CN103131073A (en) | 2011-11-23 | 2011-11-23 | Color masterbatch and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194148A (en) * | 2014-08-08 | 2014-12-10 | 宁波天启蜂窝材料有限公司 | Polypropylene honeycomb hollow plate material |
| CN112480550A (en) * | 2020-11-30 | 2021-03-12 | 重庆普利特新材料有限公司 | Floating-fiber-free high-welding-strength soft-touch polypropylene composite material and preparation method thereof |
| CN114702755A (en) * | 2022-05-13 | 2022-07-05 | 张家港绿洲新材料科技有限公司 | Functional master batch suitable for thin-wall high-length-diameter-ratio polypropylene ribbon and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101691438A (en) * | 2009-09-22 | 2010-04-07 | 广州市波斯塑胶颜料有限公司 | ABS color master batch |
| CN102070820A (en) * | 2010-12-01 | 2011-05-25 | 浙江七色鹿色母粒有限公司 | Polyethylene of raised temperature resistance (PE-RT) master batch and preparation method thereof |
-
2011
- 2011-11-23 CN CN2011103770461A patent/CN103131073A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101691438A (en) * | 2009-09-22 | 2010-04-07 | 广州市波斯塑胶颜料有限公司 | ABS color master batch |
| CN102070820A (en) * | 2010-12-01 | 2011-05-25 | 浙江七色鹿色母粒有限公司 | Polyethylene of raised temperature resistance (PE-RT) master batch and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 朱勇平等: ""弹性体增韧POM的研究进展"", 《塑料》, vol. 37, no. 6, 18 December 2008 (2008-12-18) * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194148A (en) * | 2014-08-08 | 2014-12-10 | 宁波天启蜂窝材料有限公司 | Polypropylene honeycomb hollow plate material |
| CN112480550A (en) * | 2020-11-30 | 2021-03-12 | 重庆普利特新材料有限公司 | Floating-fiber-free high-welding-strength soft-touch polypropylene composite material and preparation method thereof |
| CN114702755A (en) * | 2022-05-13 | 2022-07-05 | 张家港绿洲新材料科技有限公司 | Functional master batch suitable for thin-wall high-length-diameter-ratio polypropylene ribbon and preparation method and application thereof |
| CN114702755B (en) * | 2022-05-13 | 2024-01-09 | 张家港绿洲新材料科技有限公司 | Functional master batch applicable to thin-wall high-length-diameter-ratio polypropylene ribbon as well as preparation method and application thereof |
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Application publication date: 20130605 |