CN103126073A - Filter stick fiber base material additive capable of reducing tar content in main cigarette stream smoke and application - Google Patents
Filter stick fiber base material additive capable of reducing tar content in main cigarette stream smoke and application Download PDFInfo
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- CN103126073A CN103126073A CN2013100696456A CN201310069645A CN103126073A CN 103126073 A CN103126073 A CN 103126073A CN 2013100696456 A CN2013100696456 A CN 2013100696456A CN 201310069645 A CN201310069645 A CN 201310069645A CN 103126073 A CN103126073 A CN 103126073A
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- additive
- citric acid
- base material
- fiber base
- type compound
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Abstract
The invention discloses a filter stick fiber base material additive capable of reducing the tar content in main cigarette stream smoke, a compound additive and application. The fiber base material additive comprises one or more of citrate ester compounds as active ingredients. The compound additive comprises, by volume, 30-85% of active ingredients and 15-70% of adjuvant. The application means applying one or more of the citrate ester compounds as active ingredients to prepare the filter stick fiber base material additive which is capable of reducing the tar content in the main cigarette stream smoke. A filter stick made of a fiber base material containing the additive can maximally reduce the tar content in the main cigarette stream smoke by 10.3%.
Description
Technical field
The present invention relates to a kind of filter stick fiber base material additive and complex additive and application that reduces tar content in cigarette mainstream flue gas, belong to technical field of cigarette preparation.
Background technology
Cigarette filter is very important bridge between smoker and cigarette, it can not only effectively hold back the TPM in cigarette mainstream flue gas, reduce tar content, and the part harmful components in can also the filtering flue gas, flue gas reduced to the harm of health and environment.Therefore design effective additive and add in cigarette filter, can directly strengthen filter tip to the filter efficiency of main flume, effectively reduce the harmful components in flue gas, have very great significance for the Harm reduction techniques tool.
Citric acid ester type compound is the nonpoisonous and tasteless additive of a class, and the developed countries such as the U.S., European Union successively put into effect regulation allow this compounds be applied to the closely-related product of human body in.Therefore, citric acid ester type compound has been widely used in the fields such as cosmetics, commodity, pharmaceuticals industry and toy for children.But the report that this compounds is applied to tobacco business is very few, up to the present, does not still have citric acid ester type compound tar content in cigarette mainstream flue gas to be had the report of reduction.
Goal of the invention
The objective of the invention is to be to provide the filter stick fiber base material additive of tar content in a kind of effective reduction cigarette mainstream flue gas, this additive raw material is simple and easy to, implement convenient, use cost is cheap.
Another object of the present invention is to be to provide a kind of filter stick fiber base material complex additive that optionally reduces tar content in cigarette mainstream flue gas, and this complex additive raw material is simple and easy to, implement convenient, use cost is cheap.
A further object of the invention is the application that is to provide citric acid ester type compound, citric acid ester type compound is applied to prepare the filter stick fiber base material additive of the tar content that can effectively reduce in cigarette mainstream flue gas as active ingredient, contain the filter stick that the fiber base material of this additive makes and fall the tar successful, and free from extraneous odour, can be widely used, the raw material of additive is simple and easy to, implement convenient, use cost is cheap.
The invention provides a kind of filter stick fiber base material additive that reduces tar content in cigarette mainstream flue gas, this additive with one or more in the citric acid ester type compound with formula 1 structure as active ingredient.
The volume content of described active ingredient in additive is not less than 30%.
The present invention also provides a kind of filter stick fiber base material complex additive that reduces tar content in cigarette mainstream flue gas, and this complex additive is comprised of following volume constituents: active ingredient 30～85%, auxiliary agent 15～70%; Described active ingredient is one or more that have in the citric acid ester type compound of formula 1 structure; Described auxiliary agent is one or more in triacetyl glycerine, polyethylene glycol, levulic acid, triethylene-glycol diacetate, 1,2-PD and phosphoric acid.
The present invention also provides the application of citric acid ester type compound, and one or more that will have in the citric acid ester type compound of formula 1 structure are applied to prepare the filter stick additive that can reduce the tar content in cigarette mainstream flue gas as active ingredient.
Described application is preferably and will has one or more in the citric acid ester type compound of formula 1 structure directly as the cigarette filter rod fiber base material additive that can reduce the tar content in cigarette mainstream flue gas, perhaps one or more in citric acid ester type compound is prepared the cigarette filter rod fiber base material additive that can reduce the tar content in cigarette mainstream flue gas as active ingredient and additive compound.
Described auxiliary agent is one or more in triacetyl glycerine, polyethylene glycol, levulic acid, triethylene-glycol diacetate, 1,2-PD and phosphoric acid.
The mean molecule quantity of described polyethylene glycol is between 200～600.
The volume content of described active ingredient in additive is not less than 30%.
Described composite be that following volume constituents is mixed: active ingredient 30～85%, auxiliary agent 15～70%.
Described additive accounts for 4～12% of fiber base material gross mass.
Citric acid ester type compound of the present invention has formula 1 structure:
Formula 1
Wherein, R
1, R
2And R
3Be selected from independently of one another C
1～C
4Alkyl in a kind of or hydrogen atom;
R
4Be selected from hydrogen atom or acetyl group;
R
1, R
2And R
3Be not hydrogen atom simultaneously.
The preferred citric acid ester type compound of the present invention comprises: in triethyl citrate, citric acid isopropyl ester, ATBC and tributyl 2-acetylcitrate one or more.
Described additive is sprayed on the fiber base material of cigarette filter rod, and after cigarette becomes filter stick, more further cigarette becomes cigarette.
Beneficial effect of the present invention: the present invention prepares the filter stick fiber base material additive of the tar content in the selectivity reducing cigarette main flume first take citric acid ester type compound as active ingredient; Contain the cigarette filter rod that the fiber base material of this additive makes tar content in cigarette mainstream flue gas is reduced successful, tar content is the highest reduces by 10.3%; This additive is simple and easy to, cheapness, and it is convenient to implement, and does not affect cigarette odor-absorbing, but extensive use.
The specific embodiment
Following examples are intended to illustrate the present invention, rather than to further restriction of the present invention.
Embodiment 1
Triethyl citrate is sprayed directly on diacetate fiber as additive, and the additive capacity that is sprayed on diacetate fiber is 7～8% of filter stick fiber base material weight, prepares the fine filter stick of vinegar.
Embodiment 2
ATBC is sprayed directly on diacetate fiber as additive, and the additive capacity that is sprayed on diacetate fiber is 7～8% of filter stick fiber base material weight, prepares the fine filter stick of vinegar.
Embodiment 3
Tributyl 2-acetylcitrate is sprayed directly on diacetate fiber as additive, and the additive capacity that is sprayed on diacetate fiber is 7～8% of filter stick fiber base material weight, prepares the fine filter stick of vinegar.
Embodiment 4
With citric acid isopropyl ester and phosphoric acid in the 5:1(volume ratio) ratio carry out compositely, complex additive directly is added on diacetate fiber, the additive capacity that is added on diacetate fiber is 9～10% of filter stick fiber base material weight, prepares the fine filter stick of vinegar.
Embodiment 5
With triethyl citrate and triacetyl glycerine in the 1:1(volume ratio) ratio carry out compositely, complex additive is sprayed directly on diacetate fiber, the additive capacity that is sprayed on diacetate fiber is 5～6% of filter stick fiber base material weight, prepares the fine filter stick of vinegar.
Embodiment 6
With triethyl citrate and triacetyl glycerine in the 3:7(volume ratio) ratio carry out compositely, complex additive is sprayed directly on diacetate fiber, the additive capacity that is sprayed on diacetate fiber is 5～6% of filter stick fiber base material weight, prepares the fine filter stick of vinegar.
Embodiment 7
With triethyl citrate and polyethylene glycol (400) in the 7:3(volume ratio) ratio carry out composite, complex additive is sprayed directly on diacetate fiber, the additive capacity that is sprayed on diacetate fiber is 9～10% of filter stick fiber base material weight, prepares the fine filter stick of vinegar.
Embodiment 8
With triethyl citrate and polyethylene glycol (600) in the 7:3(volume ratio) ratio composite, complex additive is sprayed directly on diacetate fiber, the additive capacity that is sprayed on diacetate fiber is 9～10% of filter stick fiber base material weight, prepares the fine filter stick of vinegar.
Embodiment 9
With triethyl citrate and levulic acid in the 4:1(volume ratio) ratio carry out compositely, complex additive is sprayed directly on diacetate fiber, the additive capacity that is sprayed on diacetate fiber is 7～8% of filter stick fiber base material weight, prepares the fine filter stick of vinegar.
Embodiment 10
With ATBC and triethylene-glycol diacetate and 1,2 propane diols are in the 5:1:1(volume ratio) ratio carry out composite, complex additive is sprayed directly on diacetate fiber, and the additive capacity that is sprayed on diacetate fiber is 7～8% of filter stick fiber base material weight, prepares the fine filter stick of vinegar.
Embodiment 11
With triethyl citrate and tributyl 2-acetylcitrate in the 1:1(volume ratio) ratio mix, be sprayed directly on diacetate fiber as additive, the additive capacity that is sprayed on diacetate fiber is 7～8% of filter stick fiber base material weight, prepares the fine filter stick of vinegar.
The filter stick cigarette that embodiment 1-11 is prepared becomes cigarette, the compositions such as TPM, tar, nicotine in the analytical test cigarette mainstream flue gas, analytical test result such as table 1.
Table 1 flue gas analysis result
Claims (12)
1. the filter stick fiber base material additive that can reduce tar content in cigarette mainstream flue gas, is characterized in that, with one or more in the citric acid ester type compound with formula 1 structure as active ingredient;
Formula 1
Wherein, R
1, R
2And R
3Be selected from independently of one another C
1～C
4Alkyl in a kind of or hydrogen atom;
R
4Be selected from hydrogen atom or acetyl group;
R
1, R
2And R
3Be not hydrogen atom simultaneously.
2. additive according to claim 1, is characterized in that, described citric acid ester type compound comprises: in triethyl citrate, citric acid isopropyl ester, ATBC and tributyl 2-acetylcitrate one or more.
3. additive according to claim 1, is characterized in that, the volume content of described active ingredient in additive is not less than 30%.
4. the filter stick fiber base material complex additive that can reduce tar content in cigarette mainstream flue gas, is characterized in that, is comprised of following volume constituents: active ingredient 30～85%, auxiliary agent 15～70%; Described active ingredient is one or more that have in the citric acid ester type compound of formula 1 structure; Described auxiliary agent is one or more in triacetyl glycerine, polyethylene glycol, levulic acid, triethylene-glycol diacetate, 1,2-PD and phosphoric acid;
Formula 1
Wherein, R
1, R
2And R
3Be selected from independently of one another C
1～C
4Alkyl in a kind of or hydrogen atom;
R
4Be selected from hydrogen atom or acetyl group;
R
1, R
2And R
3Be not hydrogen atom simultaneously.
5. complex additive according to claim 1, is characterized in that, described citric acid ester type compound comprises: in triethyl citrate, citric acid isopropyl ester, ATBC and tributyl 2-acetylcitrate one or more.
6. the application of citric acid ester type compound, is characterized in that, one or more that will have in the citric acid ester type compound of formula 1 structure are applied to prepare the filter stick additive that can reduce the tar content in cigarette mainstream flue gas as active ingredient;
Formula 1
Wherein, R
1, R
2And R
3Be selected from independently of one another C
1～C
4Alkyl in a kind of or hydrogen atom;
R
4Be selected from hydrogen atom or acetyl group;
R
1, R
2And R
3Be not hydrogen atom simultaneously.
7. application according to claim 6, is characterized in that, described citric acid ester type compound comprises: in triethyl citrate, citric acid isopropyl ester, ATBC and tributyl 2-acetylcitrate one or more.
8. application according to claim 6, it is characterized in that, to have one or more in the citric acid ester type compound of formula 1 structure directly as the cigarette filter rod fiber base material additives that can reduce the tar content in cigarette mainstream flue gas, perhaps one or more in citric acid ester type compound can be reduced the cigarette filter rod fiber base material additive of the tar content in cigarette mainstream flue gas as active ingredient and additive compound preparation.
9. application according to claim 8, is characterized in that, described auxiliary agent is one or more in triacetyl glycerine, polyethylene glycol, levulic acid, triethylene-glycol diacetate, 1,2-PD and phosphoric acid.
10. application according to claim 6, is characterized in that, the volume content of described active ingredient in additive is not less than 30%.
11. application according to claim 8 is characterized in that, described composite be that following volume constituents is mixed: active ingredient 30～85%, auxiliary agent 15～70%.
12. according to claim 6～10 described application is characterized in that described additive accounts for 4～12% of fiber base material gross mass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310069645.6A CN103126073B (en) | 2013-03-05 | 2013-03-05 | Filter stick fiber base material additive capable of reducing tar content in main cigarette stream smoke and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310069645.6A CN103126073B (en) | 2013-03-05 | 2013-03-05 | Filter stick fiber base material additive capable of reducing tar content in main cigarette stream smoke and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103126073A true CN103126073A (en) | 2013-06-05 |
| CN103126073B CN103126073B (en) | 2015-03-11 |
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| CN201310069645.6A Active CN103126073B (en) | 2013-03-05 | 2013-03-05 | Filter stick fiber base material additive capable of reducing tar content in main cigarette stream smoke and application |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103141941A (en) * | 2013-03-05 | 2013-06-12 | 湖南中烟工业有限责任公司 | Groove filter stick cellulose paper additive capable of selectively reducing phenolic compounds in cigarette mainstream smoke and application |
| CN107927904A (en) * | 2017-10-09 | 2018-04-20 | 广西中烟工业有限责任公司 | Cigarette filter rod curing agent and its preparation and application |
| CN108095191A (en) * | 2017-11-10 | 2018-06-01 | 河南中烟工业有限责任公司 | A kind of tobacco plug plasticizer and its application |
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| CN1039530A (en) * | 1987-02-10 | 1990-02-14 | R.J.雷诺兹烟草公司 | Cigarette |
| CN101023811A (en) * | 2007-02-05 | 2007-08-29 | 中国科学院长春应用化学研究所 | Filtering rod for cigarette and preparing method |
| US20080110470A1 (en) * | 2006-08-03 | 2008-05-15 | Philip Morris Usa Inc. | Immobilized diluents for smoking articles |
| WO2009037461A2 (en) * | 2007-09-19 | 2009-03-26 | Filtrona International Limited | Tobacco smoke filter |
| CN103141941A (en) * | 2013-03-05 | 2013-06-12 | 湖南中烟工业有限责任公司 | Groove filter stick cellulose paper additive capable of selectively reducing phenolic compounds in cigarette mainstream smoke and application |
| CN103126075B (en) * | 2013-03-05 | 2014-08-06 | 湖南中烟工业有限责任公司 | Filter stick fiber base material additive capable of reducing phenolic compound in main cigarette stream smoke and application of filter stick fiber base material additive |
| CN103126074B (en) * | 2013-03-05 | 2014-08-20 | 湖南中烟工业有限责任公司 | Paper filter stick core base material additive capable of reducing phenolic compound in main cigarette stream smoke and application |
-
2013
- 2013-03-05 CN CN201310069645.6A patent/CN103126073B/en active Active
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| CN1039530A (en) * | 1987-02-10 | 1990-02-14 | R.J.雷诺兹烟草公司 | Cigarette |
| US20080110470A1 (en) * | 2006-08-03 | 2008-05-15 | Philip Morris Usa Inc. | Immobilized diluents for smoking articles |
| CN101023811A (en) * | 2007-02-05 | 2007-08-29 | 中国科学院长春应用化学研究所 | Filtering rod for cigarette and preparing method |
| WO2009037461A2 (en) * | 2007-09-19 | 2009-03-26 | Filtrona International Limited | Tobacco smoke filter |
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| CN103126075B (en) * | 2013-03-05 | 2014-08-06 | 湖南中烟工业有限责任公司 | Filter stick fiber base material additive capable of reducing phenolic compound in main cigarette stream smoke and application of filter stick fiber base material additive |
| CN103126074B (en) * | 2013-03-05 | 2014-08-20 | 湖南中烟工业有限责任公司 | Paper filter stick core base material additive capable of reducing phenolic compound in main cigarette stream smoke and application |
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| 钟洪权: "《工程科技I辑》", 15 November 2007 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103141941A (en) * | 2013-03-05 | 2013-06-12 | 湖南中烟工业有限责任公司 | Groove filter stick cellulose paper additive capable of selectively reducing phenolic compounds in cigarette mainstream smoke and application |
| CN107927904A (en) * | 2017-10-09 | 2018-04-20 | 广西中烟工业有限责任公司 | Cigarette filter rod curing agent and its preparation and application |
| CN108095191A (en) * | 2017-11-10 | 2018-06-01 | 河南中烟工业有限责任公司 | A kind of tobacco plug plasticizer and its application |
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| Publication number | Publication date |
|---|---|
| CN103126073B (en) | 2015-03-11 |
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