CN103087824A - Preparation method of cigarette flavor and application thereof - Google Patents
Preparation method of cigarette flavor and application thereof Download PDFInfo
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- CN103087824A CN103087824A CN2013100369331A CN201310036933A CN103087824A CN 103087824 A CN103087824 A CN 103087824A CN 2013100369331 A CN2013100369331 A CN 2013100369331A CN 201310036933 A CN201310036933 A CN 201310036933A CN 103087824 A CN103087824 A CN 103087824A
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Abstract
The invention relates to a preparation method of a cigarette flavor and an application thereof. The preparation method is characterized by comprising the steps of obtaining algae, washing and removing impurities, drying and crushing, leaching by a solvent, performing solid-liquid separation, performing decompression concentration, performing oxidation and degradation, recovering the solvent and obtaining an algal pigment degradation product. The algal pigment degradation product disclosed by the invention is added into cigarettes according to a certain proportion, so that the aroma quality of the cigarettes can be improved, the concentration of aroma is increased, the miscellaneous gas and the irritation are reduced, and the elegant aroma quality can be given to the cigarettes. The greatest characteristic of the invention is that the novel cigarette flavor is provided; and furthermore, after the cigarette flavor is added, the original performances of the cigarettes are not changed, an original processing technology of the cigarettes is not changed, and the sensory quality of the cigarettes is improved, so that the cigarette flavor has greater practical production significance and value.
Description
Technical field
The present invention relates to preparation and the application of tobacco aromatics using, be specifically related to a kind of preparation of marine alga Pigment degradation product, this marine alga Pigment degradation product is applied in pipe tobacco, do not changing under the original complete processing prerequisite of cigarette the aesthetic quality that can improve cigarette.
Background technology
Carotenoid is the natural pigment that extensively is present in animals and plants, normally the class tetraterpene compound that contains 40 carbon atoms, be connected by 8 isoprene units.Owing to containing a plurality of conjugated double bonds, carotenoid be very easy to be subject to reactive group (as free radical) thus attack oxidized.Except crucial physiological function, sunscreen effect and trophic function in photosynthesis, the fragrance precursor material that carotenoid or a class are important.The composition of the flavour ingredient that carotenoid oxidative degradation produces is by the site decision of carbonatoms and oxide group effect, these compositions are very important for essence and flavoring agent industry, and wherein ((compounds such as β-damascenone) and dihydroactinidiolide (dihydroactinidiolide) are the characteristic perfume compositions in tobacco product for β-ionone), beta-damascenone for oxidation isophorone (4-oxoisophorone), alpha, beta-lonone.
The at present research and development for natural pigment mainly concentrate in terrestrial plant, but the growth of terrestrial plant is subject to the impact of season, weather and region, utilize merely the demand that production that terrestrial plant obtains natural pigment far can not satisfying the market.
China has wide marine site and the marine algae resource that enriches, and has the multiple diagnostic pigments that is different from terrestrial plant because the specific living environment of marine alga makes it.Contain the multiple pigments such as chlorophyll, xenthophylls, carotene, brown alga flavine and phycobiliprotein in marine alga, wherein contained carotenoid extremely people's the concern in recent years of marine alga.Estimate the natural carotenoid ultimate production more than 100 tons per in the annual whole world according to the relevant expert.In 600 kinds of natural carotenoids of known structure, quite a few kind is from marine organisms, and some acetylene series carotenoid almost completely is confined to aquatic environment.
Mainly concentrate at present extraction and the application of polysaccharide for the utilization of marine algae resource, and very limited to the applied research of marine alga pigment.Marine alga processing enterprise after extracting main products, drains various pigments often together with slag and effluent, pigment resource has been caused waste.
Summary of the invention
Purpose of the present invention just is being based on above-mentioned present Research and preparation method and the application thereof of a kind of Novel tobacco flavor of providing, by the oxidative degradation of marine alga pigment is studied, the degraded product of marine alga pigment is put in cigarette, can obviously improve the aesthetic quality of cigarette.
The objective of the invention is to be achieved through the following technical solutions:
A kind of preparation method of tobacco aromatics using comprises the following steps: marine alga → cleaning removal of impurities → oven dry pulverizing → extraction → solid-liquid separation → concentrating under reduced pressure → oxidative degradation → recovery solvent → marine alga Pigment degradation product.
Described marine alga comprises any one in Sargassum fusiforme, wakame, Thallus Gracilariae, diatom, chlorella, salt algae, spirulina.
In the extraction step, solvent is any one in sherwood oil, chloroform, ether, and amount of solvent is 5～10 times of seaweed meal quality, 30～90 ℃ of extraction temperatures, extraction time 5～15h.
In described concentrating under reduced pressure step, be concentrated into 1/5～1/10 of vat liquor volume.
In described oxidative degradation step, oxygenant is hydrogen peroxide, and the hydrogen peroxide addition is 1/50～1/10 of concentrated solution volume, and system pH is controlled at 2～5,50～80 ℃ of Heating temperatures, heat-up time 2～6h.
In described recovery solvent step, adopt the concentrating under reduced pressure mode.
Marine alga Pigment degradation product of the present invention is through Gc-ms, contain a large amount of fragrance matters in product, mainly contain isophorone, β-cyclocitral, alpha, beta-lonone, 3,4-dehydrogenation-alpha, beta-lonone, 5,6-epoxy-bata-ionone, dihydroactinidiolide, 2,6-dihydroxyl-alpha, beta-lonone, 3-oxo-beta-ionone, 4-hydroxy-beta-jononeionone etc.
Marine alga Pigment degradation product of the present invention is added in cigarette with certain proportion, cigarette flavor matter is improved, perfume quantity increases, and assorted gas and pungency reduce, and give the flavouring essence quality of cigarette gracefulness.The addition of marine alga Pigment degradation product is 0.001～0.01% of tobacco quality, and addition manner evenly is sprayed onto in pipe tobacco for to be mixed with perfuming solution with dissolve with ethanol.
Maximum characteristics of the present invention are to provide a kind of Novel tobacco flavor, and this perfume base is originated abundant, and preparation technology is simple, and do not change original performance of cigarette after adding, do not change the original complete processing of cigarette, improved the organoleptic quality of cigarette, therefore have more the meaning and value of actual production.
Description of drawings
Fig. 1 is that the material after the oxidative degradation of carotenoid forms schematic diagram.
Embodiment
The present invention is described further below in conjunction with embodiment, but does not limit the present invention.
Embodiment 1:
Sargassum fusiforme is pulverized through cleaning removal of impurities, oven dry and is obtained Sargassum fusiforme dry powder, the sherwood oil that adds 6 times of quality, 80 ℃ of backflow lixiviate 6h, filter after stopped heating, clear liquid is through being evaporated to 1/10 of original volume, and regulation system pH to 3 adds 1/50 hydrogen peroxide of concentrated solution volume, 70 ℃ of heating 3h, after stopped heating, concentrating under reduced pressure reclaims solvent and gets Sargassum fusiforme Pigment degradation product.
Sargassum fusiforme Pigment degradation product is mixed with perfuming solution with dissolve with ethanol, evenly is sprayed onto on pipe tobacco by 0.01% of pipe tobacco weight, roll into cigarette after baking.Smoking result shows, perfume quantity obviously increases, and fragrance matter is improved, and assorted gas reduces, and pleasant impression improves.
Embodiment 2:
Thallus Gracilariae is pulverized through cleaning removal of impurities, oven dry and obtains Thallus Gracilariae dry powder, the chloroform that adds 8 times of quality, 70 ℃ of backflow lixiviate 8h, filter after stopped heating, clear liquid is through being evaporated to 1/6 of original volume, adds 1/30 hydrogen peroxide of concentrated solution volume, regulation system pH to 4,50 ℃ of heating 5h, after stopped heating, concentrating under reduced pressure reclaims solvent and gets Thallus Gracilariae Pigment degradation product.
Thallus Gracilariae Pigment degradation product is mixed with perfuming solution with dissolve with ethanol, evenly is sprayed onto on pipe tobacco by 0.001% of pipe tobacco weight, roll into cigarette after baking.Smoking result shows, the flue gas harmony, and perfume quantity increases, and fragrance matter is improved, and assorted gas, pungency alleviate, and pleasant impression is clean.
Embodiment 3:
Wakame is pulverized through cleaning removal of impurities, oven dry and is obtained wakame dry powder, the ether that adds 10 times of quality, 50 ℃ of backflow lixiviate 5h, filter after stopped heating, clear liquid is through being evaporated to 1/4 of original volume, adds 1/10 hydrogen peroxide of concentrated solution volume, regulation system pH to 5,60 ℃ of heating 5h, after stopped heating, concentrating under reduced pressure reclaims solvent and gets wakame Pigment degradation product.
Wakame Pigment degradation product is mixed with perfuming solution with dissolve with ethanol, evenly is sprayed onto on pipe tobacco by 0.005% of pipe tobacco weight, roll into cigarette after baking.Smoking result shows, the flue gas harmony, and perfume quantity increases, and assorted gas, pungency alleviate.
The present invention can also diatom, chlorella, salt algae, spirulina are that raw material obtains corresponding Pigment degradation product through aforesaid method, is applied in pipe tobacco and also can obtains corresponding effect.
Claims (6)
1. the preparation method of a tobacco aromatics using, is characterized in that: comprise the following steps: marine alga → cleaning removal of impurities → oven dry pulverizing → extraction → solid-liquid separation → concentrating under reduced pressure → oxidative degradation → recovery solvent → marine alga Pigment degradation product.
2. the preparation method of tobacco aromatics using according to claim 1, it is characterized in that: described marine alga comprises any one in Sargassum fusiforme, wakame, Thallus Gracilariae, diatom, chlorella, salt algae, spirulina.
3. the preparation method of tobacco aromatics using according to claim 1, it is characterized in that: in the extraction step, solvent is any one in sherwood oil, chloroform, ether, and amount of solvent is 5～10 times of seaweed meal quality, 30～90 ℃ of extraction temperatures, extraction time 5～15h.
4. the preparation method of tobacco aromatics using according to claim 1, it is characterized in that: in the oxidative degradation step, oxygenant is hydrogen peroxide, the hydrogen peroxide addition is 1/50～1/10 of concentrated solution volume, system pH is controlled at 2～5,50～80 ℃ of Heating temperatures, heat-up time 2～6h.
5. application according to the tobacco aromatics using of the described method preparation of claim 1, it is characterized in that: marine alga Pigment degradation product is added in pipe tobacco as tobacco aromatics using, cigarette flavor matter is improved, perfume quantity increases, assorted gas and pungency reduce, and give the flavouring essence quality of cigarette gracefulness.
6. the application of tobacco aromatics using according to claim 5 is characterized in that: the addition of marine alga Pigment degradation product is 0.001～0.01% of tobacco quality, and addition manner evenly is sprayed onto in pipe tobacco for to be mixed with perfuming solution with dissolve with ethanol.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310036933.1A CN103087824B (en) | 2013-01-31 | 2013-01-31 | Preparation method of cigarette flavor and application thereof |
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| CN201310036933.1A CN103087824B (en) | 2013-01-31 | 2013-01-31 | Preparation method of cigarette flavor and application thereof |
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| CN103087824A true CN103087824A (en) | 2013-05-08 |
| CN103087824B CN103087824B (en) | 2014-08-20 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110720663A (en) * | 2019-10-16 | 2020-01-24 | 山西昆明烟草有限责任公司 | Sargassum fusiforme porous particle, preparation method and application in cigarette |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101209985A (en) * | 2006-12-29 | 2008-07-02 | 河南农业大学 | Method for extracting carotinoid from tobacco leaf by overcritical CO2 and application of the carotinoid in perfuming cigarette |
| CN100508801C (en) * | 2006-11-25 | 2009-07-08 | 中国烟草总公司郑州烟草研究院 | Preparing method of sargassum fusiforme alcohol extract and application of sargassum fusiforme in tobacco |
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2013
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100508801C (en) * | 2006-11-25 | 2009-07-08 | 中国烟草总公司郑州烟草研究院 | Preparing method of sargassum fusiforme alcohol extract and application of sargassum fusiforme in tobacco |
| CN101209985A (en) * | 2006-12-29 | 2008-07-02 | 河南农业大学 | Method for extracting carotinoid from tobacco leaf by overcritical CO2 and application of the carotinoid in perfuming cigarette |
Non-Patent Citations (2)
| Title |
|---|
| 《宁波大学学报(理工版)》 20001231 李和生等 "海藻中的类胡萝卜素及其在食品等领域中的应用" 第92-96页 1-6 第13卷, 第4期 * |
| 李和生等: ""海藻中的类胡萝卜素及其在食品等领域中的应用"", 《宁波大学学报(理工版)》, vol. 13, no. 4, 31 December 2000 (2000-12-31), pages 92 - 96 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110720663A (en) * | 2019-10-16 | 2020-01-24 | 山西昆明烟草有限责任公司 | Sargassum fusiforme porous particle, preparation method and application in cigarette |
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| CN103087824B (en) | 2014-08-20 |
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