CN103087634B - A kind of water-based vessel glaze and preparation method thereof - Google Patents
A kind of water-based vessel glaze and preparation method thereof Download PDFInfo
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- CN103087634B CN103087634B CN201310053330.2A CN201310053330A CN103087634B CN 103087634 B CN103087634 B CN 103087634B CN 201310053330 A CN201310053330 A CN 201310053330A CN 103087634 B CN103087634 B CN 103087634B
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Abstract
The invention discloses a kind of water-based vessel glaze and preparation method thereof, belong to application of paints technical field, solve baking vanish sticking power in prior art poor, easily come off, and containing a large amount of organic solvent in baking vanish formula, cause a large amount of organic solvent to enter to environment in air, have impact on the problem of health of people simultaneously.The present invention includes baking vanish and toughener, the weight percent of described baking vanish consists of: water-base resin 20 ~ 30%, tinting pigment 5 ~ 15%, organic solvent 20 ~ 30%, water 30 ~ 40%; Described toughener by weight percent be the adhesion promoter of 30%, the acetic acid of 10% and 60% deionized water form, weight ratio 100:2 ~ 3 of described baking vanish and toughener.Present invention also offers the preparation method of above-mentioned water-based vessel glaze.Raw material of the present invention is easy to get, and preparation method is simple, and cost is lower, is suitable for promoting.
Description
Technical field
The invention belongs to application of paints technical field, be specifically related to a kind of water-based vessel glaze and preparation method thereof.
Background technology
In recent years along with development and the growth in the living standard of national economy, glass become people live in the middle of indispensable finishing material, the texture of glass itself is that other finishing material are irreplaceable, and for the baking vanish on glass wares surface, glass color can be made abundanter and create an aesthetic feeling; In addition, glass is a kind of more special material, and it is very high to the performance requriements of baking vanish.But, baking vanish sticking power is in the market all poor, easily come off, when the baking vanish of product surface comes off, must again brush it, each brushing all can have organic solvent to evaporate in air, repeatedly brushes, and causes a large amount of organic solvent to evaporate in air, serious to atmospheric pollution, also can affect the health of people simultaneously; And containing a large amount of organic solvent in existing baking vanish formula, when constructing, part organic solvent then can evaporate in air, pollutes equally to air.
Summary of the invention
The object of the present invention is to provide a kind of water-based vessel glaze and preparation method thereof, solve baking vanish sticking power in prior art poor, easily come off, and containing a large amount of organic solvent in baking vanish formula, cause a large amount of organic solvent to enter to environment in air, have impact on the problem of health of people simultaneously.
To achieve these goals, the technical solution used in the present invention is as follows:
A kind of water-based vessel glaze, comprise baking vanish and toughener, the weight percent of described baking vanish consists of:
Water-base resin 20 ~ 30%
Tinting pigment 5 ~ 15%
Organic solvent 20 ~ 30%
Water 30 ~ 40%;
Described toughener by weight percent be the adhesion promoter of 30%, the acetic acid of 10% and 60% deionized water form, weight ratio 100:2 ~ 3 of described baking vanish and toughener.
Further, described baking vanish also comprises 10% ~ 20% pigment extender.
Further, described tinting pigment be red pigment, white pigment, yellow ultramarine, blue pigments, veridian, black pigment, metalluster pigment one or more.
The preparation method of above-mentioned a kind of water-based vessel glaze, mainly comprises the following steps:
(1) preparation of baking vanish: first by water-base resin, tinting pigment, pigment extender, water and be less than total organic solvent 50% organic solvent mixing after join horizontal mill and be ground to fineness less than 20 microns, then adjust ph to 7.5 ~ 9.0, add remaining organic solvent again, filter finally by 200 order screen cloths, obtain baking vanish;
The preparation of toughener: first adhesion promoter is joined in container, then add acetic acid while stirring, after mixing 10min, low rate mixing limit, back adds deionized water and is hydrolyzed, until pH to 3 ~ 4;
(2) baking vanish and toughener are mixed by weight 100:2 ~ 3, get product.
Preferred as one, described toughener stirs and hydrolysis time is 3h.
The present invention compared with prior art, has the following advantages and beneficial effect:
(1) present invention uses treated toughener, just significantly can find out that this product is applied on glasswork by table 1, stronger sticking power can be produced, thus reduce the generation of obscission, avoiding repeatedly to brush identical product causes more organic solvent to evaporate in air, pollutes and affect the health of people on air; And the present invention is applied on glasswork, bright-coloured color and luster and good mechanical and physical performance can be produced.
(2) in product of the present invention, consumption of organic solvent is less, and the organic solvent not containing benezene selected by the present invention, environmental pollution is low, reduces the impact on HUMAN HEALTH simultaneously, belongs to a kind of product of environmental protection, is suitable for promoting.
(3) raw material of the present invention is easy to get, and preparation method is simple, and cost is lower, is suitable for promoting.
Embodiment
Below in conjunction with embodiment, the invention will be further described, and embodiments of the present invention include but not limited to the following example.
Embodiment 1
A kind of water-based vessel glaze, be that the baking vanish of 100:2.5 and toughener form by weight ratio, wherein baking vanish is made up of the component of following weight percents: 30% water-base resin (A806, Lv Tian Chemical Co., Ltd. of jiangsu wuxi city), 8% red pigment (1170H, Shanghai Yan Yan Chemical Co., Ltd.), 25% organic solvent (propylene glycol monomethyl ether), 37% water; Described toughener by weight percent be the adhesion promoter (PS-W003, moral nation chemical industry (Hubei)) of 30%, the acetic acid of 10% and 60% deionized water form.
Concrete preparation method is as follows:
The preparation of baking vanish: first by 30% water-base resin, 8% red pigment, join horizontal mill and be ground to fineness less than 20 microns after 37% water and the mixing of 10% organic solvent, then adjust ph to 7.5 ~ 9.0, add 15% organic solvent again, filter finally by 200 order screen cloths, obtain baking vanish.
The preparation of toughener: first by the adhesion promoter (PS-W003 of weight percent 30%, moral nation chemical industry (Hubei)) join in container, then the acetic acid that weight percent is 10% is added while stirring, after mixing 10min, backmost low rate mixing limit adds the deionized water that weight percent is 10%, continue to stir and add the deionized water that weight percent is 10% again, last add when stirring again weight percent be 40% deionized water be hydrolyzed, until pH to 3 ~ 4, obtain toughener.
During construction, be 100:2.5 mixing and stirring by weight percentage by the baking vanish for preparing and toughener, adding dimethylethanolamine carries out pH value adjustment, finally leaves standstill 10min, can use.
Embodiment 2
A kind of water-based vessel glaze, be that the baking vanish of 100:3 and toughener form by weight ratio, wherein baking vanish is made up of the component of following weight percents: 28% water-base resin (A806, Lv Tian Chemical Co., Ltd. of jiangsu wuxi city), 13% white pigment (902 titanium dioxides, du pont company), 22% organic solvent (propylene glycol monomethyl ether), 37% water; Described toughener by weight percent be the adhesion promoter (PS-W003, moral nation chemical industry (Hubei)) of 30%, the acetic acid of 10% and 60% deionized water form.
Concrete preparation method is as follows:
The preparation of baking vanish: first by 28% water-base resin, 13% white pigment, join horizontal mill and be ground to fineness less than 20 microns after 37% water and the mixing of 9% organic solvent, then adjust ph to 7.5 ~ 9.0, add 13% organic solvent again, filter finally by 200 order screen cloths, obtain baking vanish.
The preparation of toughener: first by the adhesion promoter (PS-W003 of weight percent 30%, moral nation chemical industry (Hubei)) join in container, then the acetic acid that weight percent is 10% is added while stirring, after mixing 10min, backmost low rate mixing limit adds the deionized water that weight percent is 10%, continue to stir and add the deionized water that weight percent is 10% again, last add when stirring again weight percent be 40% deionized water be hydrolyzed, until pH to 3 ~ 4, obtain toughener.
During construction, be 100:3 mixing and stirring by weight percentage by the baking vanish for preparing and toughener, adding dimethylethanolamine carries out pH value adjustment, finally leaves standstill 10min, can use.
Embodiment 3
A kind of water-based vessel glaze, be that the baking vanish of 100:2.4 and toughener form by weight ratio, wherein baking vanish is made up of the component of following weight percents: 20% water-base resin (A806, Lv Tian Chemical Co., Ltd. of jiangsu wuxi city), 13% white pigment (902 titanium dioxides, du pont company), 20% organic solvent (propylene glycol monomethyl ether), 30% water, 17% pigment extender (888 talcum powder, Heshan chemical industry (Liaoning) company limited); Described toughener by weight percent be the adhesion promoter (PS-W003, moral nation chemical industry (Hubei)) of 30%, the acetic acid of 10% and 60% deionized water form.
Concrete preparation method is as follows:
The preparation of baking vanish: first by 20% water-base resin, 13% white pigment, 17% pigment extender, join horizontal mill and be ground to fineness less than 20 microns after 30% water and the mixing of 8% organic solvent, then adjust ph to 7.5 ~ 9.0, add 12% organic solvent again, filter finally by 200 order screen cloths, obtain baking vanish.
The preparation of toughener: first by the adhesion promoter (PS-W003 of weight percent 30%, moral nation chemical industry (Hubei)) join in container, then the acetic acid that weight percent is 10% is added while stirring, after mixing 10min, backmost low rate mixing limit adds the deionized water that weight percent is 10%, continue to stir and add the deionized water that weight percent is 10% again, last add when stirring again weight percent be 40% deionized water be hydrolyzed, until pH to 3 ~ 4, obtain toughener.
During construction, be 100:2.4 mixing and stirring by weight percentage by the baking vanish for preparing and toughener, adding dimethylethanolamine carries out pH value adjustment, finally leaves standstill 10min, can use.
Embodiment 4
A kind of water-based vessel glaze, be that the baking vanish of 100:2.8 and toughener form by weight ratio, wherein baking vanish is made up of the component of following weight percents: 22% water-base resin (A806, Lv Tian Chemical Co., Ltd. of jiangsu wuxi city), 14% white pigment (902 titanium dioxides, du pont company), 20% organic solvent (propylene glycol monomethyl ether), 30% water, 14% pigment extender (5000 barium sulfate, Heshan chemical industry (Liaoning) company limited); Described toughener by weight percent be the adhesion promoter (PS-W003, moral nation chemical industry (Hubei)) of 30%, the acetic acid of 10% and 60% deionized water form.
Concrete preparation method is as follows:
The preparation of baking vanish: first by 22% water-base resin, 14% white pigment, 14% pigment extender, join horizontal mill and be ground to fineness less than 20 microns after 30% water and the mixing of 8% organic solvent, then adjust ph to 7.5 ~ 9.0, add 12% organic solvent again, filter finally by 200 order screen cloths, obtain baking vanish.
The preparation of toughener: first by the adhesion promoter (PS-W003 of weight percent 30%, moral nation chemical industry (Hubei)) join in container, then the acetic acid that weight percent is 10% is added while stirring, after mixing 10min, backmost low rate mixing limit adds the deionized water that weight percent is 10%, continue to stir and add the deionized water that weight percent is 10% again, last add when stirring again weight percent be 40% deionized water be hydrolyzed, until pH to 3 ~ 4, obtain toughener.
During construction, be 100:2.8 mixing and stirring by weight percentage by the baking vanish for preparing and toughener, adding dimethylethanolamine carries out pH value adjustment, finally leaves standstill 10min, can use.
Embodiment 5
A kind of water-based vessel glaze, be that the baking vanish of 100:2 and toughener form by weight ratio, wherein baking vanish is made up of the component of following weight percents: 28% water-base resin (A806, Lv Tian Chemical Co., Ltd. of jiangsu wuxi city), 13% red pigment (1170H, Shanghai Yan Yan Chemical Co., Ltd.), 21% organic solvent (propylene glycol monomethyl ether), 38% water; Described toughener by weight percent be the adhesion promoter (PS-W003, moral nation chemical industry (Hubei)) of 30%, the acetic acid of 10% and 60% deionized water form.Its preparation method is identical with embodiment 1.
Embodiment 6
A kind of water-based vessel glaze, be that the baking vanish of 100:2.9 and toughener form by weight ratio, wherein baking vanish is made up of the component of following weight percents: 27% water-base resin (A806, Lv Tian Chemical Co., Ltd. of jiangsu wuxi city), 14% white pigment (902 titanium dioxides, du pont company), 20% organic solvent (propylene glycol monomethyl ether), 39% water; Described toughener by weight percent be the adhesion promoter (PS-W003, moral nation chemical industry (Hubei)) of 30%, the acetic acid of 10% and 60% deionized water form.Its preparation method is identical with embodiment 2.
The product that the present invention prepares and on the market currently available products are respectively used on glassware, and often organize employing 1000 glasswares, then carry out sticking power detection to it, its result is as follows:
Table 1
| Detect sticking power | Currently available products | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Normality | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade |
| Alcohol immersion 4h | 0 ~ 3 grade or come off | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade |
| Water soaking 24h | 0 ~ 3 grade | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade |
| Boiling water soaks 1h | Come off | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade | 0 ~ 1 grade |
In table 1, sticking power level has 0,1,2,3,4,5 six rank, wherein 0 grade best, 5 grades are the poorest, and the product being generally greater than 2 grades can not use.
Shown by upper table result, its sticking power of product of the present invention is comparatively strong, and difficult drop-off, serves protection and decorative effect to glassware.
According to above-described embodiment, just the present invention can be realized well.What deserves to be explained is; under prerequisite based on above-mentioned design, for solving same technical problem, even if some making on the invention are without substantial change or polishing; the essence of the technical scheme adopted is still the same with the present invention, therefore it also should in protection scope of the present invention.
Claims (4)
1. a water-based vessel glaze, is characterized in that, is made up of baking vanish and toughener, and the weight percent of described baking vanish consists of:
Water-base resin 20 ~ 30%
Tinting pigment 5 ~ 15%
Organic solvent 20 ~ 30%
Pigment extender 10 ~ 20%
Water 30 ~ 40%;
Described toughener by weight percent be the adhesion promoter of 30%, the acetic acid of 10% and 60% deionized water form, weight ratio 100:2 ~ 3 of described baking vanish and toughener.
2. a kind of water-based vessel glaze according to claim 1, is characterized in that, described tinting pigment be red pigment, white pigment, yellow ultramarine, blue pigments, veridian, black pigment, metalluster pigment one or more.
3. the preparation method of a kind of water-based vessel glaze described in claim 1 or 2, is characterized in that, mainly comprise the following steps:
(1) preparation of baking vanish: first by water-base resin, tinting pigment, pigment extender, water and be less than total organic solvent 50% organic solvent mixing after join horizontal mill and be ground to fineness less than 20 microns, then adjust ph to 7.5 ~ 9.0, add remaining organic solvent again, filter finally by 200 order screen cloths, obtain baking vanish;
The preparation of toughener: first adhesion promoter is joined in container, then add acetic acid while stirring, after mixing 10min, low rate mixing limit, back adds deionized water and is hydrolyzed, until pH to 3 ~ 4;
(2) baking vanish and toughener are mixed by weight 100:2 ~ 3, get product.
4. the preparation method of a kind of water-based vessel glaze according to claim 3, is characterized in that, described toughener stirs and hydrolysis time is 3h.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102061126A (en) * | 2010-11-25 | 2011-05-18 | 上海金力泰化工股份有限公司 | Ceramic coating film composite and preparation method thereof |
| CN102212301A (en) * | 2011-01-17 | 2011-10-12 | 立邦涂料（中国）有限公司 | Renovating coating for waterborne ceramic tiles and preparation method thereof |
| CN102459483A (en) * | 2009-05-27 | 2012-05-16 | 埃西勒国际通用光学公司 | Method for producing articles with antifogging layer-by-layer coating and coated articles with enhanced antifogging and durability properties |
| CN102585630A (en) * | 2011-12-19 | 2012-07-18 | 青岛爱尔家佳新材料有限公司 | Water-based glass baking paint and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US20070106009A1 (en) * | 2005-11-09 | 2007-05-10 | Jts Corporation | Thermosetting ultraviolet cut coating and film obtained therefrom |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102459483A (en) * | 2009-05-27 | 2012-05-16 | 埃西勒国际通用光学公司 | Method for producing articles with antifogging layer-by-layer coating and coated articles with enhanced antifogging and durability properties |
| CN102061126A (en) * | 2010-11-25 | 2011-05-18 | 上海金力泰化工股份有限公司 | Ceramic coating film composite and preparation method thereof |
| CN102212301A (en) * | 2011-01-17 | 2011-10-12 | 立邦涂料（中国）有限公司 | Renovating coating for waterborne ceramic tiles and preparation method thereof |
| CN102585630A (en) * | 2011-12-19 | 2012-07-18 | 青岛爱尔家佳新材料有限公司 | Water-based glass baking paint and preparation method thereof |
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