CN103087634A - Water-based vessel glaze and preparation method thereof - Google Patents
Water-based vessel glaze and preparation method thereof Download PDFInfo
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- CN103087634A CN103087634A CN2013100533302A CN201310053330A CN103087634A CN 103087634 A CN103087634 A CN 103087634A CN 2013100533302 A CN2013100533302 A CN 2013100533302A CN 201310053330 A CN201310053330 A CN 201310053330A CN 103087634 A CN103087634 A CN 103087634A
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Abstract
The invention discloses a water-based vessel glaze and a preparation method thereof, belongs to the technical field of paint applications and solves the problems that adhesive force of baking finish is poor, the baking finish is easy to drop and a massive organic solvent enters into atmosphere, pollution to the environment is caused and health of people is also influenced as the massive organic solvent is contained in a formula of the baking finish. The water-based vessel glaze disclosed by the invention comprises baking finish and an enhancer, wherein the baking finish comprises the following components in percentage by weight: 20-30% of water-based resin, 5-15% of colouring pigment, 20-30% of organic solvent and 30-40% of water; the enhancer comprises the following components in percentage by weight: 30% of adhesion promoter, 10% of acetic acid and 60% of deionized water; and the weight ratio of the baking finish to the enhancer is 100: (2-3). The invention also provides a preparation method of the water-based vessel glaze. The water-based vessel glaze disclosed by the invention has the advantages that raw materials are easy to get, the preparation method is simple, and cost is low, so that the water-based vessel glaze disclosed by the invention is applicable to popularization.
Description
Technical field
The invention belongs to the application of paints technical field, be specifically related to a kind of water-based vessel glaze and preparation method thereof.
Background technology
In recent years along with development and the growth in the living standard of national economy, glass become people live in the middle of indispensable finishing material, the texture of glass itself is that other finishing material are irreplaceable, and is used for the baking vanish on glass wares surface, can make the abundanter and create an aesthetic feeling of glass color; In addition, glass is a kind of more special material, and its performance requriements to baking vanish is very high.Yet, baking vanish sticking power in the market is all relatively poor, easily come off, when the baking vanish of product surface comes off, must again brush it, each brushing all can have organic solvent to evaporate in atmosphere, and repeatedly brushing causes a large amount of organic solvents to evaporate in atmosphere, serious to atmospheric pollution, also can affect simultaneously people's health; And contain a large amount of organic solvents in existing baking vanish formula, when construction, the part organic solvent can evaporate in atmosphere, equally air is polluted.
Summary of the invention
The object of the present invention is to provide a kind of water-based vessel glaze and preparation method thereof, in the solution prior art, baking vanish sticking power is relatively poor, easily come off, and contain a large amount of organic solvents in the baking vanish formula, cause a large amount of organic solvents to enter in atmosphere environment, affected simultaneously the problem of health of people.
To achieve these goals, the technical solution used in the present invention is as follows:
A kind of water-based vessel glaze comprises baking vanish and toughener, and the weight percent of described baking vanish consists of:
Water-base resin 20～30%
Tinting pigment 5～15%
Organic solvent 20～30%
Water 30～40%;
Described toughener is that 30% adhesion promoter, 10% acetic acid and 60% deionized water form by weight percent, the weight ratio 100:2 of described baking vanish and toughener～3.
Further, described baking vanish also comprises 10%～20% pigment extender.
Further, described tinting pigment is one or more of red pigment, white pigment, yellow ultramarine, blue pigments, veridian, black pigment, metalluster pigment.
The preparation method of above-mentioned a kind of water-based vessel glaze mainly comprises the following steps:
(1) preparation of baking vanish: at first be ground to fineness below 20 microns with joining horizontal grinding machine after water-base resin, tinting pigment, pigment extender, water and the organic solvent mixing less than total organic solvent 50%, then regulate pH value to 7.5～9.0, add again remaining organic solvent, filter by 200 order screen cloths at last, namely get baking vanish;
The preparation of toughener: at first adhesion promoter is joined in container, then add while stirring acetic acid, after mixing 10min, backmost the low rate mixing limit adds deionized water to be hydrolyzed, until pH to 3～4;
(2) baking vanish and toughener are mixed by weight 100:2～3, get product.
As a kind of preferred, described toughener stirs and hydrolysis time is 3h.
The present invention compared with prior art has the following advantages and beneficial effect:
(1) the present invention has used treated toughener, just can find out significantly that by table 1 this product is applied on glasswork, can produce stronger sticking power, thereby reduced the generation of obscission, avoided identical product is repeatedly brushed and caused more organic solvent to evaporate in atmosphere, air has been polluted and affected people's health; And the present invention is applied on glasswork, can produce bright-coloured color and luster and good mechanical and physical performance.
(2) in product of the present invention, consumption of organic solvent is less, and the selected organic solvent of the present invention containing benezene not, and environmental pollution is low, has reduced simultaneously the impact on HUMAN HEALTH, belongs to a kind of product of environmental protection, is suitable for promoting.
(3) raw material of the present invention is easy to get, and the preparation method is simple, and cost is lower, is suitable for promoting.
Embodiment
The invention will be further described below in conjunction with embodiment, and embodiments of the present invention include but not limited to the following example.
Embodiment 1
A kind of water-based vessel glaze, the baking vanish and the toughener that are 100:2.5 by weight ratio form, wherein baking vanish is comprised of the component of following weight percent: 30% water-base resin (A806, green field, jiangsu wuxi city chemical industry company limited), 8% red pigment (1170H, Shanghai face face chemical industry company limited), 25% organic solvent (propylene glycol monomethyl ether), 37% water; Described toughener is that 30% adhesion promoter (PS-W003, moral nation's chemical industry (Hubei)), 10% acetic acid and 60% deionized water form by weight percent.
Concrete preparation method is as follows:
The preparation of baking vanish: join horizontal grinding machine after at first 30% water-base resin, 8% red pigment, 37% water and 10% organic solvent being mixed and be ground to fineness below 20 microns, then regulate pH value to 7.5～9.0, add again 15% organic solvent, filter by 200 order screen cloths at last, namely get baking vanish.
The preparation of toughener: at first with the adhesion promoter (PS-W003 of weight percent 30%, moral nation chemical industry (Hubei)) join in container, then adding while stirring weight percent is 10% acetic acid, after mixing 10min, backmost to add weight percent be 10% deionized water on the low rate mixing limit, continue to stir that to add weight percent be 10% deionized water again, last again in the situation that stir that to add weight percent be that 40% deionized water is hydrolyzed, until pH to 3～4 namely get toughener.
During construction, baking vanish and the toughener for preparing is the 100:2.5 mixing and stirring by weight percentage, adds dimethylethanolamine to carry out the pH value and regulate, last standing 10min can use.
Embodiment 2
A kind of water-based vessel glaze, the baking vanish and the toughener that are 100:3 by weight ratio form, wherein baking vanish is comprised of the component of following weight percent: 28% water-base resin (A806, green field, jiangsu wuxi city chemical industry company limited), 13% white pigment (902 titanium dioxides, du pont company), 22% organic solvent (propylene glycol monomethyl ether), 37% water; Described toughener is that 30% adhesion promoter (PS-W003, moral nation's chemical industry (Hubei)), 10% acetic acid and 60% deionized water form by weight percent.
Concrete preparation method is as follows:
The preparation of baking vanish: join horizontal grinding machine after at first 28% water-base resin, 13% white pigment, 37% water and 9% organic solvent being mixed and be ground to fineness below 20 microns, then regulate pH value to 7.5～9.0, add again 13% organic solvent, filter by 200 order screen cloths at last, namely get baking vanish.
The preparation of toughener: at first with the adhesion promoter (PS-W003 of weight percent 30%, moral nation chemical industry (Hubei)) join in container, then adding while stirring weight percent is 10% acetic acid, after mixing 10min, backmost to add weight percent be 10% deionized water on the low rate mixing limit, continue to stir that to add weight percent be 10% deionized water again, last again in the situation that stir that to add weight percent be that 40% deionized water is hydrolyzed, until pH to 3～4 namely get toughener.
During construction, baking vanish and the toughener for preparing is the 100:3 mixing and stirring by weight percentage, adds dimethylethanolamine to carry out the pH value and regulate, last standing 10min can use.
Embodiment 3
A kind of water-based vessel glaze, the baking vanish and the toughener that are 100:2.4 by weight ratio form, wherein baking vanish is comprised of the component of following weight percent: 20% water-base resin (A806, green field, jiangsu wuxi city chemical industry company limited), 13% white pigment (902 titanium dioxides, du pont company), 20% organic solvent (propylene glycol monomethyl ether), 30% water, 17% pigment extender (888 talcum powder, Heshan chemical industry (Liaoning) company limited); Described toughener is that 30% adhesion promoter (PS-W003, moral nation's chemical industry (Hubei)), 10% acetic acid and 60% deionized water form by weight percent.
Concrete preparation method is as follows:
The preparation of baking vanish: join horizontal grinding machine after at first 20% water-base resin, 13% white pigment, 17% pigment extender, 30% water and 8% organic solvent being mixed and be ground to fineness below 20 microns, then regulate pH value to 7.5～9.0, add again 12% organic solvent, filter by 200 order screen cloths at last, namely get baking vanish.
The preparation of toughener: at first with the adhesion promoter (PS-W003 of weight percent 30%, moral nation chemical industry (Hubei)) join in container, then adding while stirring weight percent is 10% acetic acid, after mixing 10min, backmost to add weight percent be 10% deionized water on the low rate mixing limit, continue to stir that to add weight percent be 10% deionized water again, last again in the situation that stir that to add weight percent be that 40% deionized water is hydrolyzed, until pH to 3～4 namely get toughener.
During construction, baking vanish and the toughener for preparing is the 100:2.4 mixing and stirring by weight percentage, adds dimethylethanolamine to carry out the pH value and regulate, last standing 10min can use.
Embodiment 4
A kind of water-based vessel glaze, the baking vanish and the toughener that are 100:2.8 by weight ratio form, wherein baking vanish is comprised of the component of following weight percent: 22% water-base resin (A806, green field, jiangsu wuxi city chemical industry company limited), 14% white pigment (902 titanium dioxides, du pont company), 20% organic solvent (propylene glycol monomethyl ether), 30% water, 14% pigment extender (5000 barium sulfate, Heshan chemical industry (Liaoning) company limited); Described toughener is that 30% adhesion promoter (PS-W003, moral nation's chemical industry (Hubei)), 10% acetic acid and 60% deionized water form by weight percent.
Concrete preparation method is as follows:
The preparation of baking vanish: join horizontal grinding machine after at first 22% water-base resin, 14% white pigment, 14% pigment extender, 30% water and 8% organic solvent being mixed and be ground to fineness below 20 microns, then regulate pH value to 7.5～9.0, add again 12% organic solvent, filter by 200 order screen cloths at last, namely get baking vanish.
The preparation of toughener: at first with the adhesion promoter (PS-W003 of weight percent 30%, moral nation chemical industry (Hubei)) join in container, then adding while stirring weight percent is 10% acetic acid, after mixing 10min, backmost to add weight percent be 10% deionized water on the low rate mixing limit, continue to stir that to add weight percent be 10% deionized water again, last again in the situation that stir that to add weight percent be that 40% deionized water is hydrolyzed, until pH to 3～4 namely get toughener.
During construction, baking vanish and the toughener for preparing is the 100:2.8 mixing and stirring by weight percentage, adds dimethylethanolamine to carry out the pH value and regulate, last standing 10min can use.
Embodiment 5
A kind of water-based vessel glaze, the baking vanish and the toughener that are 100:2 by weight ratio form, wherein baking vanish is comprised of the component of following weight percent: 28% water-base resin (A806, green field, jiangsu wuxi city chemical industry company limited), 13% red pigment (1170H, Shanghai face face chemical industry company limited), 21% organic solvent (propylene glycol monomethyl ether), 38% water; Described toughener is that 30% adhesion promoter (PS-W003, moral nation's chemical industry (Hubei)), 10% acetic acid and 60% deionized water form by weight percent.Its preparation method is identical with embodiment 1.
Embodiment 6
A kind of water-based vessel glaze, the baking vanish and the toughener that are 100:2.9 by weight ratio form, wherein baking vanish is comprised of the component of following weight percent: 27% water-base resin (A806, green field, jiangsu wuxi city chemical industry company limited), 14% white pigment (902 titanium dioxides, du pont company), 20% organic solvent (propylene glycol monomethyl ether), 39% water; Described toughener is that 30% adhesion promoter (PS-W003, moral nation's chemical industry (Hubei)), 10% acetic acid and 60% deionized water form by weight percent.Its preparation method is identical with embodiment 2.
The product that the present invention prepares is respectively used on glassware with currently available products on the market, and every group is adopted 1000 glasswares, then it is carried out sticking power and detects, and its result is as follows:
Table 1
| Detect sticking power | Currently available products | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Normality | 0～1 grade | 0～1 grade | 0～1 grade | 0～1 grade | 0～1 grade | 0～1 grade | 0～1 grade |
| Alcohol immersion 4h | 0～3 grade or come off | 0～1 grade | 0～1 grade | 0～1 grade | 0～1 grade | 0～1 grade | 0～1 grade |
| Water soaking 24h | 0～3 grade | 0～1 grade | 0～1 grade | 0～1 grade | 0～1 grade | 0～1 grade | 0～1 grade |
| Boiling water soaks 1h | Come off | 0～1 grade | 0～1 grade | 0～1 grade | 0～1 grade | 0～1 grade | 0～1 grade |
In table 1, the sticking power level has 0,1,2,3,4,5 six rank, wherein 0 grade best, 5 grades are the poorest, generally can not use greater than the product of 2 grades.
Show by upper table result, its sticking power of product of the present invention is stronger, and difficult drop-off has played protection and decorative effect to glassware.
According to above-described embodiment, just can realize well the present invention.What deserves to be explained is; under prerequisite based on above-mentioned design, for solving same technical problem, even some that make in the present invention are without substantial change or polishing; the essence of the technical scheme that adopts is still the same with the present invention, therefore it also should be in protection scope of the present invention.
Claims (5)
1. a water-based vessel glaze, is characterized in that, comprise baking vanish and toughener, the weight percent of described baking vanish consists of:
Water-base resin 20～30%
Tinting pigment 5～15%
Organic solvent 20～30%
Water 30～40%;
Described toughener is that 30% adhesion promoter, 10% acetic acid and 60% deionized water form by weight percent, the weight ratio 100:2 of described baking vanish and toughener～3.
2. a kind of water-based vessel glaze according to claim 1, is characterized in that, described baking vanish also comprises 10%～20% pigment extender.
3. a kind of water-based vessel glaze according to claim 2, is characterized in that, described tinting pigment is one or more of red pigment, white pigment, yellow ultramarine, blue pigments, veridian, black pigment, metalluster pigment.
4. the preparation method of the described a kind of water-based vessel glaze of claim 1～3 any one, is characterized in that, mainly comprises the following steps:
(1) preparation of baking vanish: at first be ground to fineness below 20 microns with joining horizontal grinding machine after water-base resin, tinting pigment, pigment extender, water and the organic solvent mixing less than total organic solvent 50%, then regulate pH value to 7.5～9.0, add again remaining organic solvent, filter by 200 order screen cloths at last, namely get baking vanish;
The preparation of toughener: at first adhesion promoter is joined in container, then add while stirring acetic acid, after mixing 10min, backmost the low rate mixing limit adds deionized water to be hydrolyzed, until pH to 3～4;
(2) baking vanish and toughener are mixed by weight 100:2～3, get product.
5. the preparation method of a kind of water-based vessel glaze according to claim 4, is characterized in that, described toughener stirs and hydrolysis time is 3h.
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| CN201310053330.2A CN103087634B (en) | 2013-02-19 | 2013-02-19 | A kind of water-based vessel glaze and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108698079A (en) * | 2016-02-18 | 2018-10-23 | 巴斯夫涂料有限公司 | Purposes of the low molecular carboxylic acid in water colour paint |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US20070106009A1 (en) * | 2005-11-09 | 2007-05-10 | Jts Corporation | Thermosetting ultraviolet cut coating and film obtained therefrom |
| CN102459483A (en) * | 2009-05-27 | 2012-05-16 | 埃西勒国际通用光学公司 | Process for preparing articles having anti-fog layer by layer coating and coated articles having enhanced anti-fog and durability properties |
| CN102061126A (en) * | 2010-11-25 | 2011-05-18 | 上海金力泰化工股份有限公司 | Ceramic coating film composite and preparation method thereof |
| CN102212301A (en) * | 2011-01-17 | 2011-10-12 | 立邦涂料（中国）有限公司 | Renovating coating for waterborne ceramic tiles and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108698079A (en) * | 2016-02-18 | 2018-10-23 | 巴斯夫涂料有限公司 | Purposes of the low molecular carboxylic acid in water colour paint |
| US11123764B2 (en) | 2016-02-18 | 2021-09-21 | Basf Coatings Gmbh | Use of low-molecular carboxylic acids in aqueous base coats |
| CN108698079B (en) * | 2016-02-18 | 2022-06-07 | 巴斯夫涂料有限公司 | Use of low molecular carboxylic acids in aqueous paints |
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| CN103087634B (en) | 2015-10-28 |
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