CN103086799B - Fertilizer-mix pesticide - Google Patents
Fertilizer-mix pesticide Download PDFInfo
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- CN103086799B CN103086799B CN201310041620.5A CN201310041620A CN103086799B CN 103086799 B CN103086799 B CN 103086799B CN 201310041620 A CN201310041620 A CN 201310041620A CN 103086799 B CN103086799 B CN 103086799B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
The invention relates to a fertilizer-mix pesticide with functions of disease controlling, pest controlling, weed controlling, and fertilizer efficiency enhancing. The fertilizer-mix pesticide comprises pesticidal, bactericidal, and herbicidal active components, and a fertilizer efficiency enhancer. With added necessary auxiliary components, a required dosage form is formed. The fertilizer-mix pesticide can be applied on wheat, rice, corn, sugarcane, eucalyptus, tobacco, potato, sweet potato, and vegetables. With the pesticide, underground pests can be dispelled and killed, soil-borne diseases can be controlled, the occurrence of seedling-stage pests and diseases can be controlled, weeds can be effectively prevented and removed, nitrogen fertilizer utilization rate can be improved, nitrogen effective period is prolonged, and phosphate fertilizer and potash fertilizer are activated. With the pesticide, multiple functions such as disease controlling, pest controlling, weed controlling, fertilizer effect enhancing, and the like are provided.
Description
Technical field
The invention belongs to medicine fertile field, particularly a kind of fertilizer agricultural chemicals of mixing.
Background technology
Agricultural chemicals and fertilizer are the important chemical that ensures agricultural production, agricultural chemicals is used for preventing and treating the various disease pest and weeds of crop in agricultural production process, and fertilizer plays irreplaceable effect providing aspect crop alimentary, by agricultural chemicals and the effective combination of fertilizer, the effectively generation of prevention and control Crops Pests Control of Diseases Insects And Weeds Pests of Crops, and can ensure the nutrition composition that crop is necessary, and greatly reduce labor cost." medicine is fertile " that exist is in the market although by the two effective combination, also there is distinct disadvantage in product.
The one, application has limitation, and quality is outstanding not.Current existing pesticide-fertilizer product is all towards paddy field, and also not for the Weed removal medicinal fertilizer product of dry crop, the scope of application is wideless at present, and universal face is also little.In addition, the medicinal effects of pesticide-fertilizer product is outstanding not, take Weed removal medicinal fertilizer as example, all right for some control efficiency common, non-obstinate weeds, but but seems helpless for crop smothering, the obstinate weeds of large area outburst.For somewhere, have the place of malignant weed, inevitably will additionally re-use weed killer herbicide, the competitive ability of medicine fertilizer is just relatively low like this.If the herbicidal effect of Weed removal medicinal fertilizer can reach the control efficiency the same with other weed killer herbicide, their competitiveness can improve undoubtedly greatly.
The 2nd, fertile on the high side of existing market medicine-feeding, causes cost performance on the low side.Only make medication fertile, average 0.07 hectare will spend 30-35 unit left and right, compare with spray medicine with traditional fertilising, 0.07 hectare fully how 10 yuan of left and right.And be some use in weeding, other effect is also not obvious.Old grass, also except not going, be bought in addition agricultural chemicals spray worm, remove old grass, and the later stage also will be appended fertilizer.Therefore, except saving manually, the fertile place that there is no can attract especially consumer of medicine.For the few common peasant household of some cultivated areas, province's labour cost out does not also offset the cost of increase, and mix fertilizer, by agricultural chemicals and conventional pesticide price, there is no remarkable increase, but fertilizer synergist and particular components have been added, can contribute to active component and fertilizer synergist to be adsorbed on fertilizer, therefore, compare with the fertile series products of medicine, mix fertile pesticide price and have more advantage, and functional stronger.
The 3rd, current pesticide-fertilizer product is to there are certain requirements service time and mode, there are many differences with traditional farming operation, the golden rice dragon striking root herbicide fertilizer of take is example, and its using method is after 7 days, to use once after rice transplanting or rice transplanting, every mu of consumption 5-7 kilogram, execute the rear water layer 5-7 days that keeps 3-5 centimetre, during this, can only continue that pour water can not draining, but must note allowing water logging not have the seedling heart, to avoid poisoning, if rice shoot is small and weak, easily by postponing of water logging, within two days, used again.And general peasant fertilization of rice for fertilizer, phosphatization fertilizer make base manure, potash fertilizer is mainly made tillering fertilizer, employing is the even method of executing repeatedly.And in weeding, peasant has drained paddy field water either to have sprayed medicine again.Medicine is fertile to greatly differ from each other with spray medicine custom with the fertilising of peasant convention, if it is improper to use, must raise the cost, and provided by the invention mixing before fertilizer is used with agricultural chemicals only need can evenly be attached on fertilizer by active component and fertilizer synergist by simple mixing of medicament and fertilizer, then spread fertilizer over the fields, be there is no specific (special) requirements, therefore, mix fertile easy to use, practical with Pesticidal products.
The 4th, the whole-colored granule of current all Weed removal medicinal fertilizer products, also cannot realize with present technology except the medicine fertilizer of liquor, also has all multi-forms available.The researcher Chen Fuliang of the Chinese Academy of Agricultural Sciences Institute of Plant Protection says, medicine fertilizer exists still likely in the mode of pulvis or aqua, but cannot exist in the mode of liquor at all, and the scope of application is obviously narrow.He also thinks, the fertile two large distinct disadvantage that exist of medicine, and the one, fertilizer and agricultural chemicals are upper and asynchronous between in use, during fertilising, not necessarily will spray medicine, during spray medicine, do not need to apply fertilizer; The 2nd, the plantation of crops is all that the amount ratio agricultural chemicals of fertilizer is much larger, and 0.07 hectare needs the fertilizer of 20 jin of left and right, to the demand of agricultural chemicals, may only have 200 grams, and the gap in ratio must cause the fertile effect of medicine little.Provided by the inventionly mix fertile agricultural chemicals and can well solve this two problems: one, mix the fertile agricultural chemicals of using mainly for soil insect, soil-borne disease and weeds, after mixing fertile agricultural chemicals and fertilizer and puddling and spread fertilizer over the fields, can obviously contain developing of disease pest and weed in soil, thereby alleviated the radix of sick Chinese caterpillar fungus, thereby prevented the outburst of later stage disease pest and weed, do not had the inconsistent problem of dispenser and fertilization time; Two, when mixing fertile agricultural chemicals and fertilizer and puddling, owing to having added suitable auxiliary agents, can better be adsorbed in fertilizer, a small amount of agricultural chemicals and fertilizer synergist can be evenly distributed on fertilizer, be so more conducive to the distribution of medicament.
The 5th, lack industry standard, market management is chaotic.The fertile industry of China's medicine is scarcely out of swaddling-clothes, and the fertile production industry of medicine lacks industry standard, and market management is chaotic, causes fake products, inferior goods to be walked crosswise, and not little impact has been caused in market, has aggravated especially the randomness in the fertile market of medicine.At present, market has been found to imitate, the fertile illegal product of medicine false, that emit type, arbitrarily adds agricultural chemicals in fertilizer, just claims it is that medicine is fertile.Some manufacturer makes profit as one's only aim, and there is no fully to understand the legitimacy of product, under the temptation of product profit, rashly sell, serious infringement consumer's legitimate rights and interests.
In Chinese patent CN101001525A, also mention fertilizer synergist, but in this patent, fertilizer synergist adopts common application method to be unfavorable for bringing into play its effect, because only have, will after mixing with pesticide active ingredient, use and be adsorbed on fertilizer, just can make fertilizer synergist closer and Fertilizer combination, bring into play the effect of its fertilizer synergistic, and fertilizer can be worked in coordination with economic benefits and social benefits with mixing of agricultural chemicals, increases the active function of fertilizer and agricultural chemicals simultaneously.
For medicine fertilizer, have above defect, the application's object is to develop a kind of being exclusively used in and mixes fertile Pesticidal products, both can solve the fertile problem of adding medicine to, and can keep again the exclusive feature of pesticide-fertilizer product.This mix fertile with Pesticidal products except having prevention and control disease pest and weed performance, also, by adding fertilizer synergist, significantly improved fertilizer efficiency, use and mix fertilely in after Pesticidal products, crop growth period does not need to refertilize and can meet nutritional need.And be exclusively used in, mix fertile product more easily and Fertilizer combination, be mixed simple, evenly, can obviously shorten man-hour, improve work efficiency.
Summary of the invention
One of object of the present invention be to provide a kind of have disease pest and weed control concurrently and improve fertilizer efficiency function mix fertilizer agricultural chemicals;
Two of the object of the invention is to provide a kind of fertile using method with agricultural chemicals of mixing.
Describedly mix the fertile problem that has solved the time and effort consumings such as the single sterilization and disinsection weeding of peasant or single fertilising with agricultural chemicals, thereby reach the multiplex object of a medicine, at the bottom of being applicable to various crops, while topdressing, use, can effectively prevent and treat disease pest and weed, can significantly improve fertilizer efficiency again.
The present invention solves the problems of the technologies described above taked technical scheme:
What have disease pest and weed control and fertilizer synergistic function concurrently mixes a fertilizer agricultural chemicals, desinsection, sterilization and herbicidal active component and fertilizer synergist, consists of.
Preferably, described in mix and fertile with agricultural chemicals, contain and be processed into the necessary auxiliary element of required formulation, auxiliary element comprises solvent, wetting dispersing agent, macromolecule wall material, filler.
The described fertilizer of mixing can be processed as liquid state and solid formulation with agricultural chemicals;
The fertilizer of mixing provided by the invention comprises desinsection, sterilization or herbicidal active component with agricultural chemicals, active insecticidal components is selected from chlopyrifos, fosthiazate, diazinon, carbosulfan, Benfuracard micro, carbaryl, one or more in Imidacloprid, Diacloden, clothianidin, single carbonamidine, Acetamiprid, Nitenpyram, thiacloprid, Avermectin, first dimension salt (Affirm (Merck Co.)), betacyfluthrin, niclosamide triethanolamine salt, the methaldehyde, organic phosphor, carbamate, nicotinoids, chrysanthemum ester class and macrolide insecticides; Fungicide active ingredient is selected from one or more in Tebuconazole, alkene azoles alcohol, tricyclazole, own azoles alcohol, pyraclostrobin, Flutriafol, carbendazim, metalaxyl, the mould spirit of evil, tmtd, mancozeb, thiophanate-methyl; One or more in herbicidal active component Xuan Zi Evil humulone, butachlor, the third careless amine, mefenacet, bensulfuron-methyl, pyrazosulfuron;
To mix the fertile weighing scale with agricultural chemicals, the weight percent content of described desinsection, sterilization or herbicidal active component is 0.1-85%, and the content of fertilizer synergist is 1-40 % by weight.Preferably the content of active component is 0.5-60 % by weight, and the content of fertilizer synergist is 2-30 % by weight.
Preferably, the fertilizer of mixing provided by the present invention contains fertilizer synergist with agricultural chemicals, and described fertilizer synergist is urease inhibitor, nitrification inhibitor or other synergist.
Preferably, described urease inhibitor is selected from one or more in thiophosphoryl triamide and main metabolites N-(normal-butyl) phosphoric triamide, thiophosphoryl triamide, phenyl phosphonic diamines, cyclohexyl thio tricresyl phosphate acid amides, cyclohexyl tricresyl phosphate acid amides and phosphoric triamide.
Preferably, described nitrification inhibitor is selected from one or more in nitrogen-pyridine (chloro-6 (the trichloromethyl)-pyridines of 2-), dicyandiamide, 1-methylpyrazole and metabolite 3-methylpyrazole thereof, 4-aminotriazole(ATA), ATS (Ammonium thiosulphate), thiocarbamide.
This preferred other synergist is poly-aspartic-acid and/or nano-sized carbon.
Solvent in auxiliary element of the present invention is selected from methyl alcohol, ethanol, isopropyl alcohol, ethylene glycol, propane diols, toluene, dimethylbenzene, trimethylbenzene, C10-C18 acid methyl esters, carrene, acetone, cyclohexanone, acetophenone, ethyl acetate, ethyl acetate, 2-butyl acetate, dimethyl formamide, dimethyl sulfoxide (DMSO), 1-METHYLPYRROLIDONE, dibutyl phthalate, repefral, coconut oil fatty acid methyl ester, Methyl palmitoleinate, animal methyl oleate, biodiesel, soybean oil, corn oil, rapeseed oil, one or more in peanut oil and carboxylate thereof.
Wetting dispersing agent in auxiliary element of the present invention is selected from alkylphenol-polyethenoxy tetraether, alkylphenol-polyethenoxy seven ethers, alkylphenol-polyethenoxy ten ethers, alkylphenol-polyethenoxy ten pentaethers, alkylphenol-polyethenoxy 20 ethers, alkylphenol-polyethenoxy polyethenoxy ether, fatty alcohol-polyoxyethylene ether, phenethyl phenol polyethenoxy ether polyoxy third rare ether, castor oil ethylene oxide adduct and derivative thereof, rosin is calculated ethylene oxide adduct and analog thereof, alkylphenol polyoxyethylene formaldehyde condensation products, alkylaryl phenol polyethenoxy ether formaldehyde condensation products, benzylbiphenyl phenol polyethenoxy polyoxy third rare ether, triphen ethyl phenol polyoxyethylene polyoxypropylene block polymer, calcium dodecyl benzene sulfonate, one or more in dehydration sorbic acid APEO.
Macromolecule wall material in auxiliary element of the present invention is selected from one or more in polymethyl methacrylate, poly-styrene block copolymer, Lauxite polymer, polyurethane, polyureas, melamine resin polymer.
Filler in auxiliary element of the present invention is selected from one or more in kaolin, earth powder, bentonite, aluminium-magnesium silicate, marine alga stone, white carbon, diatomite, potter's clay, attapulgite, precipitated calcium carbonate, polyethylene glycol, soluble starch, sodium bicarbonate, sodium carbonate, citric acid, tartaric acid, oxalic acid, boric acid, ammonium sulfate, sodium sulphate, the withered powder of tea, tobacco leaf powder, humus, fulvic acid.
Mixing of providing in the present invention fertile can be processed as liquid formulation and solid formulation with agricultural chemicals, liquid formulation can be missible oil, microemulsion, aqueous emulsion, aqueous emulsion, aqueous suspension agent, micro-capsule suspension, oil-suspending agent, finish, and solid formulation can be pulvis, wetting powder, granule, effervescent agent, water dispersible granules.
Preferred missible oil, microemulsion aqueous emulsion, micro-capsule suspension, pulvis, wetting powder.
In addition, use the helper component of enumerating in this patent, especially use the combination of solid wetting dispersing agent and corresponding filler, more be conducive to help pesticide activity component and fertilizer synergist to be adsorbed on fertilizer, and liquid state is mixed fertile agricultural chemicals and itself had certain adhesiveness owing to using, add better stabilization formulations form of auxiliary agent.It is below concrete test data.
| Helper component | In Absorption for Urea | In composite fertilizer's adsorptivity |
| Sodium lignin sulfonate+humus+earth powder+lauryl sodium sulfate | +++ | +++ |
| Poly-aspartic-acid+kaolin | +++ | +++ |
| Nano-sized carbon+lauryl sodium sulfate+humus+white carbon | +++ | +++ |
| Tartaric acid+boric acid+ammonium sulfate | +++ | +++ |
| Sodium carbonate+oxalic acid+ammonium sulfate+boric acid | +++ | +++ |
| Lauryl sodium sulfate+polyoxyethylene nonylphenol ether+tobacco leaf powder | +++ | +++ |
| Withered powder+castor oil polyoxyethylene ether+the precipitated calcium carbonate of tea | +++ | +++ |
| Fulvic acid+sodium bicarbonate+soluble starch | +++ | +++ |
| Conventional wetting powder | + | + |
| Conventional pulvis | ++ | ++ |
| Conventional effervescent agent | ++ | + |
Note: "+" represents with fertilizer absorption property general, " ++ " represents with fertilizer absorption property better, " +++ " represents with fertilizer absorption property fine.
As can be seen from the table, use the part of auxiliary combination of enumerating in patent can help product to be better adsorbed on fertilizer, and traditional wetting powder, pulvis, effervescent agent and fertilizer adsorptivity are general.Pesticidal preparations and the fertilizer compatibility of other Assisted Combinatorial preparation that the present invention enumerates are also fine, repeat no more.
This invention provides mixes and fertilely with agricultural chemicals, can mix rear use thoroughly with fertilizer, spreads fertilizer over the fields, ditch spread after during use, agricultural chemicals and fertilizer being mixed thoroughly.
Preferably, described in, mix fertilizer and can be used as crop base fertilizer or the use of topdressing with agricultural chemicals.
The fertilizer of mixing provided by the invention can be applied to wheat, paddy rice, corn, sugarcane, eucalyptus, tobacco, potato, Ipomoea batatas, vegetables with agricultural chemicals, after use, can walk quickly and keep away, kill soil insect, control the generation of soil-borne disease and sprout term disease, effective management of weeds, have disease pest and weed control and fertilizer synergistic function concurrently.
The present invention possesses following beneficial effect:
1, guarantee fertilizer efficiency persistence, applied once is mixed fertilizer can guarantee that with agricultural chemicals the whole vegetative stage of crop does not refertilize.
2, mix fertilizer and fully adapted to the worm in crop growth period, disease pest and weed pests occurrence rule by active ingredient in agricultural chemicals, cost performance is high.Combination of active principles is more reasonable.Mixing fertilizer is to be exclusively used in to mix fertile with medicament with agricultural chemicals, can be better and Fertilizer combination use, give full play to efficacy stability, feature that fertilizer efficiency is lasting.
3, mix fertile for agricultural chemicals generally application when using base fertilizer and topdressing, with the abundant combination of fertilizer, can greatly alleviate the pressure that peasant buys medicine fertilizer, operate more flexible.Mix fertilizer and considered fertilization rule in crop growth period with agricultural chemicals, the content of developing, consumption all with the close combination of Fertilizer application amount, during use, only product and fertilizer simply need be mixed just can reach and puddle uniform object, after spreading fertilizer over the fields more homogeneous be distributed in field, control the generation of disease pest and weed.
4, effective combination of agricultural chemicals and fertilizer synergist is of the present invention other one large characteristic.The effective combination of the two is applied and is mixed fertilizer, more embodied the development model of agricultural industry, the slowly-releasing of fertilizer, controlled release, medicament effectively hit underground disease pest and weed, and prevention and control are in possible trouble, be to adapt to domestic labor cost progressively to improve, shorten the effective measures of dispenser, fertilization time, number of times.
5, mixing fertilizer and use the formulations of pesticide various, can be many kinds of liquid state preparation and solid formulation, meets the multiple demand of peasant household, no longer for only having a kind of formulation of fertilizer granules and occupation mode worried.And multiple formulation is mixed and fertile also can be adapted to the feature in the prevention and control of various crop disease pest and weed with the exploitation of agricultural chemicals, greatly increased the scope of application of peasant household.
6, mix the fertile generation with agricultural chemicals, can change medicine fertilizer without the present situation of industry standard or national standard.Mix fertilizer and can retrain with national standard and the industry standard of agricultural chemicals with agricultural chemicals, and the use of fertilizer synergist also can classify as farm chemical ingredients, thereby unify constraint and standard, to the fertile industry of national medicine, have great quality to promote.
Embodiment
The present invention is further described according to following embodiment, and those skilled in the art can understand, following embodiment only plays the effect of explanation to the present invention.Without departing from the premise in the spirit of the present invention, any improvement of the present invention being done and alternative all within the scope of protection of the invention.
Reagent and the medicine in embodiment, used are commercially available prod.
Preparation Example
Following examples active component content adds after all calculating by folding hundred.
Embodiment 1:26% carbaryl imidacloprid wettable powder
Preparation method: by the former medicine of 25kg carbaryl (folding hundred), the former medicine of 1kg Imidacloprid (folding hundred), 10kg thiophosphoryl triamide, 10kg thiocarbamide, 20kg humus, 5kg lauryl sodium sulfate, 12kg sodium lignin sulfonate and residue earth powder successively suction airslide disintegrating mill, total amount is 100kg, be crushed to 200-300 order, after mixing, obtain 26% carbaryl imidacloprid wettable powder.
Embodiment 2:60% mancozeb wettable powder
Preparation method is with embodiment 1.
Embodiment 3:30% thiacloprid oil-suspending agent
Preparation method: take 20kg dimethylbenzene, 25kg soybean oil, 12kg alkylphenol-polyethenoxy tetraether and 6kg calcium dodecyl benzene sulfonate, suction high speed shear still, shear 10 minutes, drop into 30kg thiacloprid (folding hundred), 15kg dicyandiamide, shear-mixed entered sand mill after 30 minutes, then suction residue methyl oleate, total amount 100kg, sand milling 3 hours, discharging, obtains 30% thiacloprid oil-suspending agent.
Embodiment 4:30% A Wei poison Diacloden oil-suspending agent
Preparation method is with embodiment 3.
Embodiment 5:30% A Wei poison microcapsule suspending agent
Preparation method: the former medicine of the former medicine of 1kg Avermectin, 15kg dicyandiamide and 29kg chlopyrifos is dropped into reactor, suction 7kg dimethylbenzene and 3kg dimethyl formamide, 7kg alkylphenol-polyethenoxy 20 ethers, 2kg alkylphenol-polyethenoxy polyethenoxy ether, open and stir, after dissolving completely, add residue water high speed shear emulsification 30 minutes, add Lauxite polymer, slowly add hydrochloric acid, regulate pH to 3, react after 3 hours and use sodium hydroxide counter regulation pH to 7, obtain 30% A Wei poison microcapsule suspending agent.
Embodiment 6:5% first dimension salt missible oil
Preparation method: suction 7kg dimethylbenzene, 3kg dimethyl formamide in reactor, 5kg first dimension salt, 15kg cyclohexyl thio tricresyl phosphate acid amides, stir 15 minutes, add 7kg alkylaryl to divide APEO formaldehyde condensation products, 2kg alkylphenol-polyethenoxy ten pentaethers and residue butyl acetate, total amount is 100kg, stir 20 minutes, obtain 5% first dimension salt missible oil.
Embodiment 7:50% clothianidin Acetamiprid oil-suspending agent
Preparation method is with embodiment 3.
Embodiment 8:45% Nitenpyram Benfuracard micro oil-suspending agent
Preparation method is with embodiment 3.
Embodiment 9:30% Imidacloprid fosthiazate oil-suspending agent
Preparation method is with embodiment 3.
Embodiment 10:30% Imidacloprid fosthiazate suspension-microcapsule suspending agent
Preparation method:
The first step: fosthiazate microcapsules preparation.Take 20kg fosthiazate, add 5kg castor oil oxirane and derivative thereof, 1kg Sodium Polyacrylate, after stirring in reactor, add 1kg dibutyl phthalate and 40kg water, under stirring, add 7kg melamine resin polymer, slowly add 1kg hydrochloric acid, regulate pH to 3, react 3 hours, add 1kg sodium hydroxide to regulate pH to neutral, obtain fosthiazate microcapsule suspending agent.
Second step: imidacloprid suspending agent preparation.Take 10kg Imidacloprid, 5kg dicyandiamide, 5kg ATS (Ammonium thiosulphate), 2kg sodium lignin sulfonate and 1kg poly-styrene block copolymer, add residue water, stir and enter sand mill after 20 minutes, sand milling 3 hours, discharging, obtains imidacloprid suspending agent.
The 3rd step: fosthiazate microcapsules and imidacloprid suspending agent are mixed, stir 1 hour, obtain 30% Imidacloprid fosthiazate suspension-microcapsule suspending agent.
Embodiment 11:27% Diacloden methaldehyde chlopyrifos wetting powder
Preparation method is with embodiment 1.
Embodiment 12:27% Diacloden first dimension salt effervescent agent is mixed fertile medicine
Preparation method: under drying condition, take 25kg Diacloden, 2kg first dimension salt, 12kg4-aminotriazole(ATA), 8kg thiocarbamide, 1.5kg nano-sized carbon, 2kg lauryl sodium sulfate, 10kg sodium bicarbonate, 10kg tartaric acid, 2kg boric acid and residual sulfuric acid ammonium, total amount 100kg, suction airslide disintegrating mill successively, be crushed to 200-300 order, enter mixing kettle and be uniformly mixed discharging in 20 minutes, obtain 27% Diacloden first dimension salt effervescent agent.
Embodiment 13:40% Diacloden first dimension salt effervescent agent
Preparation method is with embodiment 12.
Embodiment 14:40% Tebuconazole carbendazim suspending agent
Preparation method is with embodiment 3 oil-suspending agent preparation methods.
The own azoles alcohol of embodiment 15:55% thiophanate-methyl water dispersible granules
Preparation method:
The first step: 55% own azoles alcohol thiophanate-methyl wetting powder preparation.Preparation method is with embodiment 1.
Second step: granulation.55% own azoles alcohol thiophanate-methyl wetting powder is squeezed into mixing kettle, slowly add moisture, enter Squeezinggranulator and carry out granulation.Particle is through dry oven dry of fluid bed 80 degree.Obtain 55% own azoles alcohol thiophanate-methyl water dispersible granules.
Embodiment 16:500g/L mancozeb oil-suspending agent
Preparation method is with embodiment 3.
Embodiment 17:30% dislikes mould clever metalaxyl aqua
Preparation method: take 15kg and dislike mould spirit, 15kg metalaxyl, 8kg3-methylpyrazole, 8kg nitrogen-pyridine (chloro-6 (the trichloromethyl)-pyridines of 2-), add 15kgN-methyl pyrrolidone, 3kg carrene 10kg methyl alcohol and 7kg alkylphenol polyoxyethylene 20 ethers, stir 20 minutes, dissolve completely transparent after, add residue water, stir and within 5 minutes, obtain the mould clever metalaxyl aqua of 30% evil.
Embodiment 18:25% alkene azoles alcohol tricyclazole wettable powder
Preparation method is with embodiment 1.
Embodiment 19:15% Difenoconazole cyproconazole wetting powder
Preparation method is with embodiment 1.
Embodiment 20:10% pyraclostrobin Flutriafol aqueous suspension agent
Preparation method is with embodiment 3 oil-suspending agent preparation methods.
Embodiment 21:22% pyraclostrobin tmtd oil-suspending agent
Preparation method is with embodiment 3.
Embodiment 22:15% dislikes mould clever microemulsion
Preparation method is with embodiment 17 microemulsion preparation methods.
Embodiment 23:40% Evil humulone butachlor wetting powder
Preparation method is with embodiment 1.
Embodiment 24:40% Evil humulone butachlor oil-suspending agent
Preparation method is with embodiment 3.
Embodiment 25:40% Evil humulone the third careless amine pulvis
Preparation method is with embodiment 1 wetting powder preparation method.
Embodiment 26:10% bensulfuron-methyl granule
Preparation method: take the careless amine of 24kg third, add 10kg bensulfuron-methyl, 13kg3-methylpyrazole, the abundant stirring and evenly mixing of 8kg phenyl phosphonic diamines; Mixture is slowly joined in the fine grained of fulvic acid and the withered powder of tea, limit adds mixture, and limit adds 10kg white carbon and 3kg lauryl sodium sulfate, to promote mobility, opens heater, stirs 30 minutes, obtains 10% bensulfuron-methyl granule.
Embodiment 27:20% mefenacet pyrazosulfuron oil-suspending agent
Preparation method is with embodiment 3.
Embodiment 28:30% A Wei Imidacloprid list carbonamidine oil-suspending agent
Preparation method is with embodiment 3.
Embodiment 29:40% metalaxyl Diacloden the third careless amine oil-suspending agent
Preparation method is with embodiment 3.
The careless amine aqueous emulsion of embodiment 30:25% carbosulfan third
Preparation method: take 15kg carbosulfan, the careless amine of 10kg third, 8kg thiocarbamide, 5kg ATS (Ammonium thiosulphate) and add 10kg methyl-sulfoxide, 3kg castor oil polyoxyethylene ether, 1kg alkylphenol-polyethenoxy seven ethers and 5kg propane diols, after stirring, add residue water, high speed shear 20 minutes, obtains the careless amine aqueous emulsion of 25% carbosulfan third.
Embodiment 31:21% first dimension salt niclosamide triethanolamine salt wetting powder
Preparation method is with embodiment 1.
Application Example
Embodiment 32: mixing fertilizer affects result of the test (spring planting sugarcane) with pesticide control sugarcane moth borer to sugarcane yield
Controlling object: sugarcane moth borer
Place: village, three li of Guigangs, Guangxi
Test period: on February 19th, 2011
Contrast medicament: 3% carbofuran granule
50% clothianidin Acetamiprid oil-suspending agent
Table 1 is mixed fertilizer affects result of the test (spring planting sugarcane) with pesticide control sugarcane moth borer to sugarcane yield
Note: base fertilizer is composite fertilizer " 17-17-17 ", topdresses as urea.
Table 1 data can be found out, with mixing the fertile sugarcane field of crossing by pesticide-treated, sugarcane borer is had to good control efficiency, at 30 days, by 100 days, all can there is more than 80% control efficiency, and the treatment region that uses contrast medicament carbofuran to sugarcane moth borer preventive effect at 30 days more than 80%, but along with sugarcane production, control efficiency worse and worse, 60 days and 100 days control efficiency, only have 75.4% and 54.2%, and the processing of manuring late also shows same problem, the combination of contrast medicament clothianidin and Acetamiprid also shows and the similar problem of carbofuran.
Aspect sugarcane production-increasing, fertilizer is mixed in use all can make sugarcane production-increasing more than 20% by the processed group of agricultural chemicals, and embodiment 3 processed group effect of increasing production reach 32.2%, and other is mixed fertilizer and has also shown excellent effect of increasing production by pesticide-treated group; Use the processing volume increase 2.1% of base fertilizer, use base fertilizer, the processed group volume increase 5.2% of manuring late, illustrates that mixing fertilizer can effectively slow down fertilizer loss with the building component in agricultural chemicals, with respect to traditional fertilising, has improved the availability of fertilizer greatly.
Embodiment 33: mixing fertilizer affects result of the test (fall planting sugarcane) with pesticide control sugarcane moth borer to sugarcane yield
Controlling object: sugarcane moth borer
Place: Beihai Fisheries Base Guangxi Province Hepu
Test period: on September 9th, 2011
Contrast medicament: 3% carbofuran granule
50% clothianidin Acetamiprid oil-suspending agent
Table 2 is mixed fertilizer affects result of the test (fall planting sugarcane) with pesticide control sugarcane moth borer to sugarcane yield
Note: base fertilizer is composite fertilizer " 17-17-17 ", topdresses as urea
Table 2 data can be found out, with mixing the fertile fall planting sugarcane field of crossing by pesticide-treated, sugarcane borer is also had to good control efficiency, suitable in spring planting sugarcane field preventive effect with February 19, at 30 days to 100 days also all more than 80%, embodiment 5 100 days control efficiency after medicine are 90.3%, can effectively prevent and treat the generation of sugarcane moth borer, and the treatment region of contrast medicament carbofuran is 60.5% and 58.7% to sugarcane moth borer preventive effect control efficiency after 100 days, the preventive effect of contrast medicament 50% clothianidin Acetamiprid oil-suspending agent also only has 55.3%, explanation is along with sugarcane production, control efficiency worse and worse, and the processing of manuring late also shows same problem.
Aspect sugarcane production-increasing, fertilizer is mixed in use all can keep more than 20% rate of growth by the processed group of agricultural chemicals, only applying fertilizer to the subsoil with the processed group volume increase of manuring late is 7.1% and 5.2%, illustrates that use base fertilizer or base fertilizer+topdressing to guarantee the sugarcane fertilizer requirement in a growth season completely.
Embodiment 34: mix fertile with pesticide control wheat aphid and to Wheat Yield Influence result of the test (winter wheat)
Controlling object: wheat aphid
Place: Xinxiang, Henan
Test period: on September 9th, 2011
Contrast medicament: 5% carbosulfan granule
30% thiacloprid oil-suspending agent
Investigation method: this test basis pesticide field efficacy medicine test criterion (two) is carried out, the sampling of 5 of every communities, fixing 20 strains at every has aphid strain (fringe), and the aphid number in strain (fringe) is determined in investigation.In the time of investigation drug effect, investigation is on crop and the impact on other biology.
Drug effect computational methods
Table 3 is mixed fertile with pesticide control wheat aphid and to wheat increase yield result of the test (winter wheat)
Note: base fertilizer is " 17-17-17 " composite fertilizer, topdresses as " 17-17-17 " composite fertilizer.
By the data in table 3, can be found out, in embodiment, mix the fertile wheat of crossing by pesticide-treated remarkable to wheat aphid preventive effect in May 7 next year.In embodiment, preventive effect is respectively 75.6%, 77.3%, 80.3%, 71.3%, 79.3%, and contrast medicament carbofuran preventive effect is respectively 33.4% and 40.3%, and thiacloprid preventive effect is 60.5%, than embodiment, has larger gap.A situation arises for actual aphid, used mix the fertile processed group with agricultural chemicals can be than contrasting few agricultural chemicals of making a call to 2 times.
And used, to mix the fertile processed group with agricultural chemicals also fairly obvious to the effect of increasing production of wheat, data show, mix fertilizer, by pesticide-treated group, wheat increase yield is respectively to 11.3%, 10.8%, 17.4%, 16.4% and 11.6%, and only use the processing of base fertilizer to increase production 3.4%, the processing volume increase 5.7% and 3.5% of manuring late, illustrate that mixing fertilizer not only has good control efficiency to wheat aphid with Pesticidal products, lasting period is longer, can reach 5-7 month, and owing to mixing the fertile synergy to fertilizer with Pesticidal products, than routine, with fertilizer product, improve output better obviously.
Embodiment 35: mix fertile in pesticide control paddy rice Pomacea canaliculata, plant hopper and sprout term disease result of the test
Controlling object: Pomacea canaliculata, plant hopper, bakanae disease, banded sclerotial blight
Place: Guilin
Test period: in March, 2011
Contrast medicament: 10% methaldehyde granule
40% Diacloden first dimension salt effervescent agent
75% carbendazol wettable powder
Rice fulgorid investigation method is as follows:
Investigation insect pest situation before medicine, after medicine, 3d, 7d, 14d investigation rice fulgorid control efficiency, adopt parallel great-jump-forward sampling, every community random searching 10 points, 2 clumps every, record the borer population of living, calculate insect population decline rate and preventive effect.
Computing formula
Rice sheath blight disease investigation standard is as follows:
According to rice leaf sheath and blade damage symptom grading, Yi Zhuwei unit, every community diagonal 5 point samplings, every some investigation is connected 2 clumps, totally 10 clumps, records total strain number, diseased plant number and sick progression.
Grade scale
0 grade: complete stool is anosis;
1 grade: quaterfoil and following leaf sheath thereof, blade morbidity (take sword-like leave as first leaf);
3 grades: the 3rd blade and following leaf sheath thereof, blade morbidity;
5 grades: the second blade and following leaf sheath thereof, blade morbidity;
7 grades: sword-like leave blade and following leaf sheath thereof, blade morbidity;
9 grades: complete stool morbidity, withered ahead of time.
2.6 computing formula:
Table 4 is mixed fertile in pesticide control paddy rice Pomacea canaliculata, plant hopper result of the test-1
Table 5 is mixed fertile in pesticide control rice seedling disease result of the test-2
Note: the base fertilizer in table 4 and 5 is " 15-15-15 " composite fertilizer, topdresses as " 30-0-10 " composite fertilizer
Table 4 result can find out, mix fertile with agricultural chemicals, in paddy rice base fertilizer, admix after, can play and significantly kill spiral shell, kill plant hopper effect.And conventional molluscicide enters the methaldehyde, kills and shown poor preventive effect when plant hopper medicament Diacloden and first dimension salt composite is used as routine.Data show, mix fertile with agricultural chemicals to Pomacea canaliculata and plant hopper preventive effect more than 80%, conventional pesticide only has 56.2% and 60.4% to Pomacea canaliculata and plant hopper preventive effect.
And mix, fertile with agricultural chemicals, equally rice seedling disease is had to more significant control efficiency, the data in table 5 reflect to mix fertilely has larger gap with agricultural chemicals and conventional bactericide 10% pyraclostrobin Flutriafol aqueous suspension agent.
Volume increase aspect, is used to mix and fertilely with Pesticidal products processed group, all can after single-dose application, no longer topdress, and volume increase is at 13.2%-18.6%, and base fertilizer adds the processing of manuring late and increases production and only have 9.4% and 10.7%.The volume increase of disease field is also only had to 9.4%.
Embodiment 36: mix fertile in pesticide control tobacco soil insect result of the test
Controlling object: mole cricket, grub, cutworm
Place: Yunnan Yuxi
Test period: in May, 2011
Contrast medicament: 3% carbofuran Granules
30% Avermectin chlopyrifos Diacloden oil-suspending agent
Testing program: the cotton plants investigation of being injured
Control time: each investigation in 15 days once after neat seedling and Qi Miao.
Investigation method: every community is got 5 points at random, goes long 10 meters at every, investigates total strain number and the strain of being injured, and records pest species according to killed shape simultaneously.
Insect density investigation
Respondent: aphid and soil insect (grub, cutworm)
Soil insect investigation method: 5 samplings of " Z " font in community, take the sampling survey of cutting the earth, every some 50cm * 50cm, the about 30cm of digging depth, records worm amount and worm kind in unit are
In experiment, be also noted that whether observe crop has poisoning to produce, and records type and the degree of poisoning if any medicine.
Table 6 is mixed fertile in pesticide control tobacco soil insect result of the test
Note: base fertilizer is " 26-13-0 " composite fertilizer, topdresses as " 30-0-10 " composite fertilizer.
Result of the test shows, using to mix fertilely has good control efficiency with the processing of agricultural chemicals to tobacco soil insect grub, cutworm etc., and traditional high toxicant Furadan is with use Avermectin+chlopyrifos+Diacloden control efficiency is general separately.In process of the test, root has been dug, has observed Tobacco Root minister gesture situation and find, use mix the fertile product with agricultural chemicals not only root be subject to soil insect infringement lighter, and root growing way is flourishing, is obviously better than conventional fertilizers processing.And mix fertile in control efficiency and effect of increasing production no significant difference between agricultural chemicals.
Embodiment 37: mix fertile in pesticide control corn malignant weed-rhizome of nutgrass flatsedge and field bindweed result of the test
Controlling object: the Maize at Seedling Stage rhizome of nutgrass flatsedge, field bindweed
Place: Dali County, weinan
Test period: in March, 2011
Contrast medicament: 960g/L gold is that missible oil all
40% Evil humulone butachlor oil-suspending agent
Investigation method: 3 communities of the fixing investigation of every processing, random 3 points, every the 1 * 1m of selecting in each community
2carry out sample investigation.By range estimation, the overall coverage rate of corn weeds etc. is investigated before medicine; After medicine 14d and 21d respectively the strain number of the Dui Ge community rhizome of nutgrass flatsedge and field bindweed carry out investigation statistics, calculate strain preventive effect; Strain number and the fresh weight of the medicine Hou28dDui community rhizome of nutgrass flatsedge and field bindweed are investigated, and then calculate respectively strain preventive effect and fresh weight preventive effect.
Control time and number of times: investigate altogether 4 times.Before processing, investigate the coverage rate of weeds kind and weeds etc., after processing, 14d, 21d and 28d carry out the investigation of strain preventive effect and fresh weight preventive effect.
Drug effect computational methods:
Strain preventive effect (%)=(the remaining careless number of blank district careless number-treatment region alive) careless number * 100 alive ,/blank district
Fresh weight preventive effect (%)=(blank district weeds fresh weight-treatment region weeds fresh weight)/weeds fresh weight * 100, blank district
Poisoning investigation method: after dispenser, whether 28d range estimation medicament has poisoning to crop continuously.
Table 7 is mixed fertile in pesticide control corn field weed effect
Note: 1 base fertilizer is " 15-15-15 " composite fertilizer.
2 preventive effects letter below represents the significance difference opposite sex, lowercase representative there were significant differences under 0.05 level property; Capitalization representative there were significant differences under 0.01 level property.
Table 7 shows, 14d after medicine, mix fertile with agricultural chemicals no matter to the rhizome of nutgrass flatsedge or the preventive effect of field bindweed is all better than contrasting medicament, both othernesses are remarkable, are in different preventing and treating in level.21d after medicine, embodiment 23-27, mixes fertilizer for 5 kinds, with agricultural chemicals, the preventive effect of the rhizome of nutgrass flatsedge is respectively to 24.6%, 26.2%, 22.6%, 27.2%, 25.6%, be all better than contrasting 16.2% and 15.2% of medicament, and difference is comparatively obvious, same, does not prevent and treat in level; To the preventive effect of field bindweed, be also to mix fertilizer to be better than contrasting chemicals treatment by the preventive effect of pesticide-treated group.28 days strain preventive effects and fresh weight preventive effect are also better than contrasting medicament.Continuous Observation 28d after medicine, each is processed without poisoning phenomenon.
By above embodiment, can find out, mix fertile with agricultural chemicals, have to kill press down diseases and pests of agronomic crop or plant growth one or more the function in regulating, and can nutrition be provided or there is the nutrition of providing and the functional product of raising fertilizer and agricultural chemicals availability simultaneously for crops, especially under the environment that cost of labor improves now, use and reasonably mix fertilizer Pesticidal products, can improve the control efficiency of medicament, single-dose application is simultaneously without topdressing, just can guarantee the crop fertilizer demand of a season of growth, greatly improve work efficiency.
Claims (6)
1. mix a fertilizer agricultural chemicals, it is characterized in that being formed by following component: carbaryl 25kg, Imidacloprid 1kg, thiophosphoryl triamide 10kg, thiocarbamide 10kg, humus 20kg, lauryl sodium sulfate 5kg, sodium lignin sulfonate 12kg, earth powder is mended to 100kg.
2. mix fertilizer agricultural chemicals for one kind, it is characterized in that being formed by following component: Avermectin 1kg, chlopyrifos 10kg, Diacloden 19kg, dicyandiamide 15kg, alkylphenol-polyethenoxy ten ether 5kg, fatty alcohol-polyoxyethylene ether 10kg, the rare ether 2kg of phenethyl phenol polyethenoxy ether polyoxy third, methyl oleate is mended to 100kg.
3. mix fertilizer agricultural chemicals for one kind, it is characterized in that being formed by following component: clothianidin 25kg, Acetamiprid 25kg, dicyandiamide 12kg, cyclohexyl tricresyl phosphate acid amides 10Kg, alkylphenol-polyethenoxy 20 ether 7kg, the rare ether 2kg of benzylbiphenyl phenol polyethenoxy polyoxy third, soybean oil 15kg, dibutyl phthalate is mended to 100kg.
4. mix a fertilizer agricultural chemicals, it is characterized in that being formed by following component: Imidacloprid 10kg, fosthiazate 20kg, dicyandiamide 5kg, ATS (Ammonium thiosulphate) 5kg, castor oil ethylene oxide adduct and derivative 5kg thereof, Sodium Polyacrylate 1kg, sodium lignin sulfonate 2kg, melamine resin polymer 7kg, hydrochloric acid 1kg, sodium hydroxide 1kg, poly-styrene block copolymer 1kg, dibutyl phthalate 1kg, water is mended to 100kg.
5. mix a fertilizer agricultural chemicals, it is characterized in that being formed by following component: Diacloden 35kg, first dimension salt 5kg, 4-aminotriazole(ATA) 10kg, dicyandiamide 5kg, sodium carbonate 5kg, citric acid 2kg, oxalic acid 3kg, aluminium-magnesium silicate 3.3kg, sodium sulphate is mended to 100kg.
6. mix a fertilizer agricultural chemicals, it is characterized in that being formed by following component: Evil humulone 16kg, the third careless amine 24kg, 3-methylpyrazole 13kg, phenyl phosphonic diamines 8kg, lauryl sodium sulfate 3kg, white carbon 10kg, the withered powder 5kg of tea, diatomite is mended to 100kg.
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| CN116218494B (en) * | 2021-12-06 | 2024-04-12 | 中国石油天然气股份有限公司 | Composite auxiliary agent, deep profile control crosslinking agent, preparation method and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1285145A (en) * | 2000-07-21 | 2001-02-28 | 长春市恒大实业有限责任公司 | Novel pesticide of monosultap ammonium and productive technology thereof |
| CN1402995A (en) * | 2002-10-09 | 2003-03-19 | 华南农业大学 | Pesticide prepn of mixed nimbin and pymetrozine |
| CN1486607A (en) * | 2003-07-30 | 2004-04-07 | 湖南化工研究院 | Nano powder composition containing effective pesticidal component and its prepn process |
| CN101036457A (en) * | 2006-03-14 | 2007-09-19 | 北京华京五方实用纳米科技开发有限公司 | Microemulsion |
| CN101044860A (en) * | 2006-03-30 | 2007-10-03 | 云南省农业科学院农业环境资源研究所 | Agricultural chemical composition containing natural pyrethrum and admire and its application |
| CN101643375A (en) * | 2009-09-16 | 2010-02-10 | 贵州金致农业科技有限公司 | Fertilizer synergist prepared from traditional Chinese medicinal materials and production and application methods thereof |
| CN102100229A (en) * | 2009-12-16 | 2011-06-22 | 联合国南通农药剂型开发中心 | Pesticide micro-capsule granules and preparation method thereof |
-
2013
- 2013-02-04 CN CN201310041620.5A patent/CN103086799B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1285145A (en) * | 2000-07-21 | 2001-02-28 | 长春市恒大实业有限责任公司 | Novel pesticide of monosultap ammonium and productive technology thereof |
| CN1402995A (en) * | 2002-10-09 | 2003-03-19 | 华南农业大学 | Pesticide prepn of mixed nimbin and pymetrozine |
| CN1486607A (en) * | 2003-07-30 | 2004-04-07 | 湖南化工研究院 | Nano powder composition containing effective pesticidal component and its prepn process |
| CN101036457A (en) * | 2006-03-14 | 2007-09-19 | 北京华京五方实用纳米科技开发有限公司 | Microemulsion |
| CN101044860A (en) * | 2006-03-30 | 2007-10-03 | 云南省农业科学院农业环境资源研究所 | Agricultural chemical composition containing natural pyrethrum and admire and its application |
| CN101643375A (en) * | 2009-09-16 | 2010-02-10 | 贵州金致农业科技有限公司 | Fertilizer synergist prepared from traditional Chinese medicinal materials and production and application methods thereof |
| CN102100229A (en) * | 2009-12-16 | 2011-06-22 | 联合国南通农药剂型开发中心 | Pesticide micro-capsule granules and preparation method thereof |
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