CN103052656B - 用于烯烃聚合的催化剂组分 - Google Patents

用于烯烃聚合的催化剂组分 Download PDF

Info

Publication number
CN103052656B
CN103052656B CN201180040869.3A CN201180040869A CN103052656B CN 103052656 B CN103052656 B CN 103052656B CN 201180040869 A CN201180040869 A CN 201180040869A CN 103052656 B CN103052656 B CN 103052656B
Authority
CN
China
Prior art keywords
catalyst component
peak
compound
solid catalyst
diffraction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201180040869.3A
Other languages
English (en)
Chinese (zh)
Other versions
CN103052656A (zh
Inventor
J·T·M·帕特尔
D·利果里
G·维塔尔
G·科利纳
D·布里塔
T·达洛科
G·莫里尼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Poliolefine Italia SRL
Original Assignee
Basell Poliolefine Italia SRL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Poliolefine Italia SRL filed Critical Basell Poliolefine Italia SRL
Publication of CN103052656A publication Critical patent/CN103052656A/zh
Application granted granted Critical
Publication of CN103052656B publication Critical patent/CN103052656B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN201180040869.3A 2010-08-24 2011-08-10 用于烯烃聚合的催化剂组分 Active CN103052656B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US80689210A 2010-08-24 2010-08-24
US12/806892 2010-08-24
EP10175027.1 2010-09-02
EP10175027 2010-09-02
PCT/EP2011/063730 WO2012025379A1 (en) 2010-08-24 2011-08-10 Catalyst components for the polymerization of olefins

Publications (2)

Publication Number Publication Date
CN103052656A CN103052656A (zh) 2013-04-17
CN103052656B true CN103052656B (zh) 2016-06-01

Family

ID=44629937

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201180040869.3A Active CN103052656B (zh) 2010-08-24 2011-08-10 用于烯烃聚合的催化剂组分

Country Status (10)

Country Link
US (1) US10155825B2 (https=)
EP (1) EP2609124B1 (https=)
JP (1) JP5898200B2 (https=)
KR (1) KR101835309B1 (https=)
CN (1) CN103052656B (https=)
BR (1) BR112013004167B1 (https=)
CA (1) CA2805769C (https=)
ES (1) ES2645793T3 (https=)
RU (1) RU2579371C2 (https=)
WO (1) WO2012025379A1 (https=)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10138310B2 (en) * 2010-08-24 2018-11-27 Equistar Chemicals, Lp Preparation of LLDPE resins and films having low gels
EA201791297A1 (ru) * 2014-12-12 2017-12-29 Сабик Глоубл Текнолоджиз Б.В. Полиэтиленовая композиция и труба, содержащая в своем составе такую композицию
ES2834062T3 (es) * 2016-04-29 2021-06-16 Basell Poliolefine Italia Srl Componentes catalizadores para la polimerización de olefinas
WO2017200869A1 (en) 2016-05-20 2017-11-23 Equistar Chemicals, Lp In-line polyolefin based adhesive compositions having graft polyolefin/elastomer compositions having graft polyolefin/lastomer copolymers
WO2017200867A1 (en) * 2016-05-20 2017-11-23 Equistar Chemicals, Lp Processes for producing in-line polyolefin based adhesive compositions, and adhesive compositions and films thereof
BR112019000090A2 (pt) 2016-07-15 2019-04-09 Basell Poliolefine Italia Srl catalisador para a polimerização de olefinas
WO2018060116A1 (en) 2016-09-30 2018-04-05 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins
CA3044047C (en) 2016-11-18 2021-03-09 Equistar Chemicals, Lp Polyolefin materials for rotational molding applications having improved impact properties and color stability
BR112019011717B1 (pt) * 2016-12-19 2022-11-01 Basell Poliolefine Italia S.R.L. Componente catalisador para a polimerização de olefinas, catalisadores obtidos a partir dos mesmos e processo para a (co)polimerização de olefinas
US10604610B2 (en) 2017-01-27 2020-03-31 Equistar Chemicals, Lp Peroxide-modified linear low density polyethylene films, sheets, and multilayer structures
BR112019022081B1 (pt) 2017-05-03 2023-04-18 Equistar Chemicals, Lp Copolímero de etileno alfa-olefina e método para sua produção
EP3621995B1 (en) 2017-05-12 2025-01-22 Basell Poliolefine Italia S.r.l. Process for activating a catalyst for the polymerization of ethylene
WO2019050954A1 (en) 2017-09-08 2019-03-14 Equistar Chemicals, Lp POLYOLEFIN ADHESIVE COMPOSITIONS HAVING GRAFT POLYOLEFIN COPOLYMERS AND METHODS OF FORMING
EP3974052A1 (en) * 2020-09-23 2022-03-30 Basell Polyolefine GmbH Vessel system
RU2759723C1 (ru) * 2020-12-23 2021-11-17 Публичное Акционерное Общество "Нижнекамскнефтехим" Способ непрерывного промотирования титан-магниевого катализатора Циглера-Натта в процессах (со)полимеризации олефинов

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1062538A (zh) * 1988-03-03 1992-07-08 Bp化学有限公司 齐格勒-纳塔型催化剂
WO2004054711A1 (en) * 2002-12-18 2004-07-01 Basell Poliolefine Italia S.P.A. Magnesium dichloride-based adducts and catalyst components obtained therefrom

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU14982A1 (ru) * 1928-02-20 1930-04-30 Б.Г. Соколов Державка дл пластинчатых резцов
DK133012C (da) 1968-11-21 1976-08-09 Montedison Spa Katalysator til polymerisation af alkener
YU35844B (en) 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
JPS5373279A (en) * 1976-12-13 1978-06-29 Mitsubishi Chem Ind Ltd Preparation of olefin polymer
US4302565A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
IT1096661B (it) 1978-06-13 1985-08-26 Montedison Spa Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
FI80055C (fi) 1986-06-09 1990-04-10 Neste Oy Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner.
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
JP2879347B2 (ja) 1989-10-02 1999-04-05 チッソ株式会社 オレフィン重合用触媒の製法
IT1246614B (it) 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine
IT1250731B (it) 1991-07-31 1995-04-21 Himont Inc Procedimento per la preparazione di polietilene lineare a bassa densita'
IT1254279B (it) 1992-03-13 1995-09-14 Montecatini Tecnologie Srl Procedimento per la polimerizzazione in fase gas delle olefine
US5990251A (en) * 1993-07-13 1999-11-23 Bp Chemicals Limited Process for polymerising olefin with a Ziegler-Natta catalyst
DE69821710T2 (de) 1997-03-29 2005-01-13 Basell Poliolefine Italia S.P.A. Magnesiumdihalogenid/alkohol addukte, verfahren zu ihrer herstellung und damit hergestellte katalysatorbestandteile
ES2420879T3 (es) * 2002-12-18 2013-08-27 Basell Poliolefine Italia S.R.L. Componentes catalizadores para la polimerización de olefinas
AU2004242899A1 (en) * 2003-05-29 2004-12-09 Basell Poliolefine Italia S.R.L Process for the preparation of a catalyst component and components therefrom obtained
JP4790627B2 (ja) 2003-12-19 2011-10-12 バーゼル・ポリオレフィン・ゲーエムベーハー エチレン（コ）ポリマーの製造方法
US20080051535A1 (en) * 2006-08-23 2008-02-28 Fina Technology, Inc. Promoter system for polymerization processes and polymers formed therefrom
WO2008074674A1 (en) 2006-12-20 2008-06-26 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins and catalysts therefrom obtained

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1062538A (zh) * 1988-03-03 1992-07-08 Bp化学有限公司 齐格勒-纳塔型催化剂
WO2004054711A1 (en) * 2002-12-18 2004-07-01 Basell Poliolefine Italia S.P.A. Magnesium dichloride-based adducts and catalyst components obtained therefrom

Also Published As

Publication number Publication date
JP5898200B2 (ja) 2016-04-06
RU2579371C2 (ru) 2016-04-10
KR101835309B1 (ko) 2018-03-08
JP2013536290A (ja) 2013-09-19
EP2609124A1 (en) 2013-07-03
US20130158214A1 (en) 2013-06-20
ES2645793T3 (es) 2017-12-07
CA2805769C (en) 2017-11-21
CN103052656A (zh) 2013-04-17
CA2805769A1 (en) 2012-03-01
WO2012025379A1 (en) 2012-03-01
RU2013112943A (ru) 2014-09-27
BR112013004167A2 (pt) 2016-05-10
EP2609124B1 (en) 2017-09-20
US10155825B2 (en) 2018-12-18
BR112013004167B1 (pt) 2020-02-04
KR20130100106A (ko) 2013-09-09

Similar Documents

Publication Publication Date Title
CN103052656B (zh) 用于烯烃聚合的催化剂组分
US8071499B2 (en) Catalyst components for the polymerization of olefins and catalysts therefrom obtained
JP5366898B2 (ja) オレフィン重合用触媒成分
US20100029869A1 (en) Catalyst components for the polymerization of olefins and catalysts therefrom obtained
US6627710B1 (en) Catalyst components for the polymerization of olefins and catalysts therefrom obtained
JP5594969B2 (ja) オレフィンの重合用の触媒成分
EP3484932A1 (en) Catalyst for the polymerization of olefins
WO2018114347A1 (en) Ziegler-natta catalyst and preparation thereof
US20090143549A1 (en) Catalyst Components for the Polymerization of Olefins
WO2001019879A1 (en) Catalyst for the polymerization of olefins
CN101326201B (zh) 用于烯烃聚合的催化剂组分

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant