CN103046327B - 芳砜纶短纤维用油剂 - Google Patents
芳砜纶短纤维用油剂 Download PDFInfo
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- 239000008041 oiling agent Substances 0.000 title abstract 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 17
- 239000000194 fatty acid Substances 0.000 claims abstract description 17
- 229930195729 fatty acid Natural products 0.000 claims abstract description 17
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 17
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 claims abstract description 16
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 14
- 244000068988 Glycine max Species 0.000 claims abstract description 9
- 235000010469 Glycine max Nutrition 0.000 claims abstract description 9
- OXPCWUWUWIWSGI-MSUUIHNZSA-N Lauryl oleate Chemical compound CCCCCCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC OXPCWUWUWIWSGI-MSUUIHNZSA-N 0.000 claims abstract description 7
- 239000001103 potassium chloride Substances 0.000 claims abstract description 7
- 235000011164 potassium chloride Nutrition 0.000 claims abstract description 7
- 229940094506 lauryl betaine Drugs 0.000 claims abstract description 6
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 150000003457 sulfones Chemical class 0.000 claims description 22
- 229920002994 synthetic fiber Polymers 0.000 claims description 22
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 7
- 244000060011 Cocos nucifera Species 0.000 claims description 7
- 150000004985 diamines Chemical class 0.000 claims description 7
- ZLVJMOQLHZWPOU-UHFFFAOYSA-N phosphoric acid;tridecan-1-ol Chemical compound OP(O)(O)=O.CCCCCCCCCCCCCO ZLVJMOQLHZWPOU-UHFFFAOYSA-N 0.000 claims description 7
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
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- 229940079840 cocoyl isethionate Drugs 0.000 abstract 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000012360 testing method Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- OXPCWUWUWIWSGI-UHFFFAOYSA-N dodecyl octadec-9-enoate Chemical class CCCCCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC OXPCWUWUWIWSGI-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- BAQMXNHOFSFWHH-UHFFFAOYSA-L dipotassium;tridecyl phosphate Chemical compound [K+].[K+].CCCCCCCCCCCCCOP([O-])([O-])=O BAQMXNHOFSFWHH-UHFFFAOYSA-L 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
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- LJGHYPLBDBRCRZ-UHFFFAOYSA-N 3-(3-aminophenyl)sulfonylaniline Chemical compound NC1=CC=CC(S(=O)(=O)C=2C=C(N)C=CC=2)=C1 LJGHYPLBDBRCRZ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 229920000491 Polyphenylsulfone Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
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- KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical class [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
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- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
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- GAJQCIFYLSXSEZ-UHFFFAOYSA-N tridecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCOP(O)(O)=O GAJQCIFYLSXSEZ-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
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Abstract
本发明公开了一种芳砜纶短纤维用油剂，由下述原料按重量份组成：(Z)-9-十八烯酸-十二烷基酯50-70份；月桂基甜菜碱10-30份；1-十三烷醇二氢磷酸酯二钾盐10-30份；氯化钾20-40份；椰子脂肪酸和二聚乙二胺、大豆脂肪酸乙氧基化物、季铵化氯代甲烷的反应产物10-30份。本发明的芳砜纶短纤维用油剂，具有提高芳砜纶短纤维平滑柔软的作用，能够提高芳砜纶短纤维的抗静电性，特别的具有优异的耐热性能。
Description
技术领域
本发明涉及一种纺织纤维油剂，尤其涉及一种芳砜纶短纤维用油剂。
背景技术
在纤维生产和加工中，油剂是一种助剂，它起着中介体的作用，在纺丝、拉伸、纺纱、机织等工序具有非常重要的作用。
油剂是纤维后加工的重要试剂，基本上以表面活性剂为主体。它能增加纤维间的抱和力和平滑性，降低纤维与机械间的摩擦系数，减少静电产生。若调配合适还可增加纱线的强力和耐磨性能，降低加拈的强力损失，提高粘胶帘子线与橡胶的附着力。
油剂的主要成分包括平滑剂、乳化剂、抗静电剂，还可根据纤维的不同用途而添加其他成分，如抗氧剂、防霉剂、防锈剂、消泡剂、与橡胶附着的促进剂、有机溶剂和水等。
芳砜纶纤维属于对位芳纶系列，学名为聚苯砜对苯二甲酰胺纤维，系由4,4二氨基二苯砜，3,3二氨基二苯砜和对苯二甲酰氯的缩聚物制成的纤维。纤维强度为3.0-4.5g/d；伸长率20-25％；初始模量为760kg/mm2；比重为1.416g/cm3。由于芳砜纶既有对位又有间位的结构，大分子链上又有砜基存在，所以具有突出的耐热、耐燃性能，在300℃热空气中加热100小时强力损失小于5％。此外，还有较好的电绝缘性和抗辐射性能。
发明内容
本发明所要解决的技术问题是提供一种芳砜纶短纤维用油剂，对芳砜纶短纤维上油后，具有提高纤维平滑柔软的作用，并且能够提高纤维的抗静电性。
为解决上述技术问题，本发明通过以下技术方案来实现：
一种芳砜纶短纤维用油剂，由下述原料按重量份组成：
(Z)-9-十八烯酸-十二烷基酯50-70份；
月桂基甜菜碱10-30份；
1-十三烷醇二氢磷酸酯二钾盐10-30份；
氯化钾20-40份；
椰子脂肪酸和二聚乙二胺、大豆脂肪酸乙氧基化物、季铵化氯代甲烷的反应产物10-30份。
所述的(Z)-9-十八烯酸-十二烷基酯，英文名:9-Octadecenoicacid(Z)-,dodecyl ester，CAS登录号:36078-10-1。
所述的月桂基甜菜碱，CAS号：83-10-3。
所述的1-十三烷醇二氢磷酸酯二钾盐，CAS号：68541-11-7。英文名称：1-Tridecanol,dihydrogen phosphate,dipotassiumsalt;Tridecyl phosphate,dipotassium salt。
所述的椰子脂肪酸和二聚乙二胺、大豆脂肪酸乙氧基化物、季铵化氯代甲烷的反应产物，英文名:Fatty acids,coco,reactionproducts with diethylenetriamine and soya fatty acids,ethoxylated。CAS登录号68604-75-1。
将(Z)-9-十八烯酸-十二烷基酯；月桂基甜菜碱；1-十三烷醇二氢磷酸酯二钾盐；氯化钾；椰子脂肪酸和二聚乙二胺、大豆脂肪酸乙氧基化物、季铵化氯代甲烷的反应产物按比例称取，搅拌混合均匀，即可制得本发明的芳砜纶短纤维用油剂。
本发明的芳砜纶短纤维用油剂，具有提高芳砜纶短纤维平滑柔软的作用，能够提高芳砜纶短纤维的抗静电性，特别的具有优异的耐热性能。
具体实施方式
实施例1
称取：(Z)-9-十八烯酸-十二烷基酯6公斤；月桂基甜菜碱2公斤；1-十三烷醇二氢磷酸酯二钾盐2公斤；氯化钾3公斤；椰子脂肪酸和二聚乙二胺、大豆脂肪酸乙氧基化物、季铵化氯代甲烷的反应产物2公斤，搅拌混合均匀，即可制得本发明的芳砜纶短纤维用油剂。
将上述制得的本发明的芳砜纶短纤维用油剂加入适量的去离子水中，搅拌混合均匀，制得有效成分浓度0.5-5wt%的油剂水液。
油剂水液配好后，即可通过喷晒法或浸润法进行上油。
比电阻测试：
将上述制得的本发明的芳砜纶短纤维用油剂加入适量的去离子水中，搅拌混合均匀，制得有效成分质量浓度4%的油剂水液，在40℃左右的水浴中，搅拌均匀。将无油芳砜纶短纤维放入该油剂水液中浸泡4分钟，甩干，在烘箱中100℃烘6小时，制成测试纤维样品。测试数据见下表。
| 实施例1 | 实施例2 | 实施例3 | |
| 芳砜纶短纤维体积比电阻,Ω·cm | 2.8×107 | 3.2×107 | 3.1×107 |
| 上油率，% | 0.9 | 0.9 | 0.9 |
耐热性能测试：
将制得的油剂，从100℃开始，以5℃/min的速度升温至290℃。观察其现象，具体见下表。
| 实施例1 | 实施例2 | 实施例3 | |
| 250℃ | 浓缩 | 浓缩 | 浓缩 |
| 260℃ | 颜色加深 | 颜色加深 | 颜色加深 |
| 270℃ | 黄褐色 | 黄褐色 | 黄褐色 |
| 280℃ | 开始燃烧 | 开始燃烧 | 开始燃烧 |
芳砜纶纤维产品广泛应用于高温环境（250℃），因此对纤维油剂的耐温性要求很高。经上述实验测试，本发明的芳砜纶短纤维用油剂在270℃高温下依然可以正常工作。
实施例2
称取：(Z)-9-十八烯酸-十二烷基酯7公斤；月桂基甜菜碱1公斤；1-十三烷醇二氢磷酸酯二钾盐1公斤；氯化钾2公斤；椰子脂肪酸和二聚乙二胺、大豆脂肪酸乙氧基化物、季铵化氯代甲烷的反应产物3公斤，搅拌混合均匀，即可制得本发明的芳砜纶短纤维用油剂。
实施例3
称取：(Z)-9-十八烯酸-十二烷基酯5公斤；月桂基甜菜碱3公斤；1-十三烷醇二氢磷酸酯二钾盐3公斤；氯化钾4公斤；椰子脂肪酸和二聚乙二胺、大豆脂肪酸乙氧基化物、季铵化氯代甲烷的反应产物1公斤，搅拌混合均匀，即可制得本发明的芳砜纶短纤维用油剂。
本发明的芳砜纶短纤维用油剂，具有提高芳砜纶短纤维平滑柔软的作用，能够提高芳砜纶短纤维的抗静电性，特别的具有优异的耐热性能。
Claims (1)
1.一种芳砜纶短纤维用油剂，其特征在于，由下述原料按重量份组成：
(Z)-9-十八烯酸-十二烷基酯50-70份；
月桂基甜菜碱10-30份；
1-十三烷醇二氢磷酸酯二钾盐10-30份；
氯化钾20-40份；
椰子脂肪酸和二聚乙二胺、大豆脂肪酸乙氧基化物、季铵化氯代甲烷的反应产物10-30份。
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101858036A (zh) * | 2010-06-04 | 2010-10-13 | 上海里奥纤维企业发展有限公司 | 溶剂法纤维处理用油剂 |
| CN102400352A (zh) * | 2010-09-13 | 2012-04-04 | 曹德如 | 编织丝用锦纶油剂 |
| CN102400314A (zh) * | 2010-09-13 | 2012-04-04 | 王琳 | 锦纶长丝卷绕油剂 |
| CN102400355A (zh) * | 2010-09-14 | 2012-04-04 | 殷兰芳 | 维纶纺纱油剂 |
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| JPH01246471A (ja) * | 1988-03-23 | 1989-10-02 | Kao Corp | 熱可塑性合成繊維処理用油剤 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101858036A (zh) * | 2010-06-04 | 2010-10-13 | 上海里奥纤维企业发展有限公司 | 溶剂法纤维处理用油剂 |
| CN102400352A (zh) * | 2010-09-13 | 2012-04-04 | 曹德如 | 编织丝用锦纶油剂 |
| CN102400314A (zh) * | 2010-09-13 | 2012-04-04 | 王琳 | 锦纶长丝卷绕油剂 |
| CN102400355A (zh) * | 2010-09-14 | 2012-04-04 | 殷兰芳 | 维纶纺纱油剂 |
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| JP平1-246471A 1989.10.02 |
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