CN103040073A - Compound antioxidant - Google Patents
Compound antioxidant Download PDFInfo
- Publication number
- CN103040073A CN103040073A CN2012105468220A CN201210546822A CN103040073A CN 103040073 A CN103040073 A CN 103040073A CN 2012105468220 A CN2012105468220 A CN 2012105468220A CN 201210546822 A CN201210546822 A CN 201210546822A CN 103040073 A CN103040073 A CN 103040073A
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- China
- Prior art keywords
- parts
- antioxidant
- polypropylene
- ethylene
- vinyl alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 230000003078 antioxidant effect Effects 0.000 title claims abstract description 27
- 239000003963 antioxidant agent Substances 0.000 title claims abstract description 24
- 150000001875 compounds Chemical class 0.000 title abstract 2
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims abstract description 9
- -1 butyl hydroxy Chemical group 0.000 claims abstract description 8
- 235000019281 tert-butylhydroquinone Nutrition 0.000 claims abstract description 8
- AZJQQNWSSLCLJN-UHFFFAOYSA-N 2-ethoxyquinoline Chemical compound C1=CC=CC2=NC(OCC)=CC=C21 AZJQQNWSSLCLJN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims abstract description 7
- 239000004743 Polypropylene Substances 0.000 claims abstract description 7
- 229920001155 polypropylene Polymers 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004250 tert-Butylhydroquinone Substances 0.000 claims abstract description 5
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002131 composite material Substances 0.000 claims description 15
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 claims description 4
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 claims description 4
- 239000004322 Butylated hydroxytoluene Substances 0.000 abstract description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 abstract description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 abstract description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 abstract 1
- 239000012964 benzotriazole Substances 0.000 abstract 1
- 229940095259 butylated hydroxytoluene Drugs 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 description 20
- 230000000694 effects Effects 0.000 description 7
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 description 4
- DJENHUUHOGXXCB-UHFFFAOYSA-N 2-butyl-6-methoxyphenol Chemical class CCCCC1=CC=CC(OC)=C1O DJENHUUHOGXXCB-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- XOBOCRSRGDBOGH-UHFFFAOYSA-N 5-phenylnonan-5-ol Chemical class CCCCC(O)(CCCC)C1=CC=CC=C1 XOBOCRSRGDBOGH-UHFFFAOYSA-N 0.000 description 2
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- HCZKYJDFEPMADG-UHFFFAOYSA-N nordihydroguaiaretic acid Chemical compound C=1C=C(O)C(O)=CC=1CC(C)C(C)CC1=CC=C(O)C(O)=C1 HCZKYJDFEPMADG-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- SRUQARLMFOLRDN-UHFFFAOYSA-N 1-(2,4,5-Trihydroxyphenyl)-1-butanone Chemical compound CCCC(=O)C1=CC(O)=C(O)C=C1O SRUQARLMFOLRDN-UHFFFAOYSA-N 0.000 description 1
- KNENSDLFTGIERH-UHFFFAOYSA-N 2,2,4,4-tetramethyl-3-phenylpentan-3-ol Chemical compound CC(C)(C)C(O)(C(C)(C)C)C1=CC=CC=C1 KNENSDLFTGIERH-UHFFFAOYSA-N 0.000 description 1
- XRCRJFOGPCJKPF-UHFFFAOYSA-N 2-butylbenzene-1,4-diol Chemical compound CCCCC1=CC(O)=CC=C1O XRCRJFOGPCJKPF-UHFFFAOYSA-N 0.000 description 1
- PHWAJJWKNLWZGJ-UHFFFAOYSA-N 3,5-dibromo-4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC(Br)=C(O)C(Br)=C1 PHWAJJWKNLWZGJ-UHFFFAOYSA-N 0.000 description 1
- ULSLJYXHZDTLQK-UHFFFAOYSA-N Coumatetralyl Chemical compound C1=CC=CC2=C1OC(=O)C(C1C3=CC=CC=C3CCC1)=C2O ULSLJYXHZDTLQK-UHFFFAOYSA-N 0.000 description 1
- 239000004258 Ethoxyquin Substances 0.000 description 1
- 239000004263 Guaiac resin Substances 0.000 description 1
- 229920000932 Gum guaicum Polymers 0.000 description 1
- 102100039386 Ketimine reductase mu-crystallin Human genes 0.000 description 1
- 101000772180 Lithobates catesbeianus Transthyretin Proteins 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 235000019285 ethoxyquin Nutrition 0.000 description 1
- 229940093500 ethoxyquin Drugs 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 235000019278 guaiac resin Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a compound antioxidant which comprises the following components in part by weight: 36 to 45 parts of benzotriazole, 10 to 15 parts of dicumyl peroxide, 20 to 30 parts of tert-butyl hydroquinone, 3 to 5 parts of glycidyl methacrylate, 11 to 16 parts of butyl hydroxy anisd, 23 to 26 parts of ethylene-vinyl alcohol copolymer, 11 to 14 parts of polypropylene, 2 to 5 parts of ethoxy quinoline, 1 to 3 parts of butylated hydroxytoluene and 18 to 39 parts of water. The antioxidant has a remarkable antioxidant effect.
Description
Technical field
The invention discloses a kind of composite antioxidant of using; Belong to chemical industry, metallurgical technology field.
Background technology
The feed antioxidant of commonly using at present both at home and abroad is oil-soluble inhibitor, and kind has: butylhydroxy anisole (being called for short BHA), di-tert-butyl hydroxy toluene (being called for short BHT), step butylhydroquinone (being called for short TBHQ), n-propyl gallate (abbreviation PG), ethoxyquin (being called for short EMQ), p-hydroxyanisole and DBHA, THBP, NDGA, vitamin E, guaiac resin etc.Although above-mentioned kind all can be used in the food approval, in feed, use separately the disadvantage that exists weak effect, for example BHT; Although the kind effect that has is better, expensive, such as BHA, PG etc., feedstuff industry can't hold on cost better, but expensive, such as BHA, PG etc., feedstuff industry can't bear on cost.The effect of composite antioxidant generally is better than single antioxidant kind at present.But because many manufacturers have increased considerable commercial profit when composite production, pass through several marketing channel, the price of product has improved greatly with the ratio of cost again.Using widely at China's feedstuff industry at present, kind is that ENDOX(is fresh), this product is built bright industrial group by Kemin Industries Limited() produce, at home and abroad certain reputation is enjoyed in feedstuff industry, especially Southeast Asia.In recent years, the kinds such as antioxygen peace of U.S. Mei Nong company are also squeezed into China feed antioxidant market by certain channel.Although the composite antioxidant effect is better, because the content low (wherein major part is carrier) of effective ingredient, thereby these benefits have just been replaced by the profit of the manufacturer that produces composite antioxidant.Or it is unreasonable to fill a prescription, and gets less than desirable effect.This shows the cost that employing is lower, the composite antioxidant that production performance is good seems necessary.
Summary of the invention
The purpose of this invention is to provide that a kind of cost is low, the significant composite oxidation preventive for fodder of antioxidant effect and production method thereof.
A kind of composite antioxidant of the present invention forms: BTA 36-45 part, cumyl peroxide 10-15 part, TBHQ 20-30 part, GMA 3-5 part, butylhydroxy anisole 11-16 part, ETHYLENE-VINYL ALCOHOL COPOLYMER thing 23-26 part, polypropylene 11-14 part, ethoxyquinoline 2-5 part, dibutyl hydroxy toluene 1-3 part, water 18-39 part by weight.
The using method of a kind of composite antioxidant of the present invention is sketched in lower:
At first, BTA, cumyl peroxide, TBHQ, GMA, butylhydroxy anisole, ETHYLENE-VINYL ALCOHOL COPOLYMER thing are dissolved in the polypropylene, then, ethoxyquinoline, dibutyl hydroxy toluene, water are added simultaneously, stirred 45-60 minute, left standstill again 20-30 minute, and stirred and get final product.
Advantage of the present invention and good effect are sketched in lower: antioxidant effect is remarkable.The key component of composite antioxidant is antioxidant; the compatibility of various antioxidants has played synergy; antagonism absolutely not; the antioxidant that adopts among the present invention all can be dissolved among the Main Components EMQ; and " stream of the wriggling " characteristic of EMQ so that behind the various antioxidant mixing fully with need the nutrition of protection fully to contact in the feed; thereby the effect that makes antioxidant is able to comprehensive performance, has overcome the disadvantage that most of antioxidant (because outward appearance is that crystallization or powder can not fully contact with feed) is not brought into play effect.
The specific embodiment
Embodiment 1:
A kind of composite antioxidant forms: 36 parts of BTAs, 10 parts of cumyl peroxides, 20 parts of TBHQs, 3 parts of GMAs, 11 parts of butylhydroxy anisoles, 23 parts of ETHYLENE-VINYL ALCOHOL COPOLYMER things, 11 parts of polypropylene, 2 parts of ethoxyquinolines, 1 part of dibutyl hydroxy toluene, 18 parts in water by weight.
Embodiment 2:
A kind of composite antioxidant forms: 45 parts of BTAs, 15 parts of cumyl peroxides, 30 parts of TBHQs, 5 parts of GMAs, 16 parts of butylhydroxy anisoles, 26 parts of ETHYLENE-VINYL ALCOHOL COPOLYMER things, 14 parts of polypropylene, 5 parts of ethoxyquinolines, 3 parts of dibutyl hydroxy toluenes, 39 parts in water by weight.
Embodiment 3:
A kind of composite antioxidant forms: 39 parts of BTAs, 14 parts of cumyl peroxides, 25 parts of TBHQs, 4 parts of GMAs, 12 parts of butylhydroxy anisoles, 25 parts of ETHYLENE-VINYL ALCOHOL COPOLYMER things, 13 parts of polypropylene, 4 parts of ethoxyquinolines, 2 parts of dibutyl hydroxy toluenes, 26 parts in water by weight.
Claims (1)
1. a composite antioxidant is characterized in that, forms by weight:
BTA 36-45 part, cumyl peroxide 10-15 part, TBHQ 20-30 part, GMA 3-5 part, butylhydroxy anisole 11-16 part, ETHYLENE-VINYL ALCOHOL COPOLYMER thing 23-26 part, polypropylene 11-14 part, ethoxyquinoline 2-5 part, dibutyl hydroxy toluene 1-3 part, water 18-39 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210546822.0A CN103040073B (en) | 2012-12-17 | 2012-12-17 | Compound antioxidant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210546822.0A CN103040073B (en) | 2012-12-17 | 2012-12-17 | Compound antioxidant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103040073A true CN103040073A (en) | 2013-04-17 |
| CN103040073B CN103040073B (en) | 2014-10-08 |
Family
ID=48053117
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210546822.0A Expired - Fee Related CN103040073B (en) | 2012-12-17 | 2012-12-17 | Compound antioxidant |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103040073B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104287053A (en) * | 2014-09-30 | 2015-01-21 | 杭州娃哈哈科技有限公司 | Oil-in-water type water-soluble antioxidant compound and preparation method thereof |
| CN104824371A (en) * | 2015-04-10 | 2015-08-12 | 周建康 | Novel liquid antioxidant and preparation method thereof |
| CN106566297A (en) * | 2016-10-11 | 2017-04-19 | 王胜利 | Material of anti-oxidation film of nonmetallic object and preparation method thereof |
| CN111117627A (en) * | 2019-12-01 | 2020-05-08 | 梁山新翔新材料有限公司 | Production formula of emulsion type antioxidant |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2035877C1 (en) * | 1991-03-07 | 1995-05-27 | Львовский политехнический институт | Antioxidant for stabilization of vitamins in feed mixtures |
| CN1113117A (en) * | 1995-04-25 | 1995-12-13 | 李侯根 | Composite oxidation preventive for fodder and its production method |
| CN1473487A (en) * | 2003-07-19 | 2004-02-11 | 宜兴市天石饲料有限公司 | Fodder antioxidant and its producing method |
| CN102293318A (en) * | 2010-06-25 | 2011-12-28 | 广州天科生物科技有限公司 | Plant antioxidant functional feed additive |
| CN102640968A (en) * | 2012-03-31 | 2012-08-22 | 宁波它世界生物科技有限公司 | Complex antioxidant and preparation method thereof |
-
2012
- 2012-12-17 CN CN201210546822.0A patent/CN103040073B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2035877C1 (en) * | 1991-03-07 | 1995-05-27 | Львовский политехнический институт | Antioxidant for stabilization of vitamins in feed mixtures |
| CN1113117A (en) * | 1995-04-25 | 1995-12-13 | 李侯根 | Composite oxidation preventive for fodder and its production method |
| CN1473487A (en) * | 2003-07-19 | 2004-02-11 | 宜兴市天石饲料有限公司 | Fodder antioxidant and its producing method |
| CN102293318A (en) * | 2010-06-25 | 2011-12-28 | 广州天科生物科技有限公司 | Plant antioxidant functional feed additive |
| CN102640968A (en) * | 2012-03-31 | 2012-08-22 | 宁波它世界生物科技有限公司 | Complex antioxidant and preparation method thereof |
Non-Patent Citations (5)
| Title |
|---|
| 刘岭 等: "复配抗氧化剂的研究进展", 《中国食品添加剂》 * |
| 李侯根 等: "饲料抗氧化剂的抗氧化活性及产品稳定性", 《饲料研究》 * |
| 李刚: "饲料抗氧化剂的选择和应用", 《畜牧与饲料科学》 * |
| 欧阳平 等: "多功能润滑添加剂-苯并三氮唑衍生物的研究进展", 《润滑油》 * |
| 邬小兵 等: "食品级抗氧化剂(TBHQ)及其衍生物在饲料中的抗氧化能力", 《湖南饲料》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104287053A (en) * | 2014-09-30 | 2015-01-21 | 杭州娃哈哈科技有限公司 | Oil-in-water type water-soluble antioxidant compound and preparation method thereof |
| CN104287053B (en) * | 2014-09-30 | 2018-05-29 | 杭州娃哈哈科技有限公司 | A kind of emulsifying Water Soluble Compound antioxidant and preparation method thereof |
| CN104824371A (en) * | 2015-04-10 | 2015-08-12 | 周建康 | Novel liquid antioxidant and preparation method thereof |
| CN106566297A (en) * | 2016-10-11 | 2017-04-19 | 王胜利 | Material of anti-oxidation film of nonmetallic object and preparation method thereof |
| CN111117627A (en) * | 2019-12-01 | 2020-05-08 | 梁山新翔新材料有限公司 | Production formula of emulsion type antioxidant |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103040073B (en) | 2014-10-08 |
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Free format text: CORRECT: INVENTOR; FROM: CAO MAN GUO BINGYU LIU LIN TO: SU JIANLI Free format text: CORRECT: ADDRESS; FROM: 266101 QINGDAO, SHANDONG PROVINCE TO: 266061 QINGDAO, SHANDONG PROVINCE |
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Effective date of registration: 20140730 Address after: 266061 Shandong, Laoshan, Hongkong East Road, No. Pioneering Park, biological park, room 248, No. 239 Applicant after: Qingdao Wenchuang Science & Technology Co., Ltd. Address before: Hi Tech Park Laoshan Keyuan weft four road 266101 Shandong Province, Qingdao City No. 30 Applicant before: Qingdao Tianren Environment Co., Ltd. |
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Effective date of registration: 20170301 Address after: Hangzhou City, Zhejiang province 310000 Xihu District Baochu Road No. 193 No. 15 facade Patentee after: Zhejiang Tong Tong Construction Co., Ltd. Address before: 266061 Shandong, Laoshan, Hongkong East Road, No. Pioneering Park, biological park, room 248, No. 239 Patentee before: Qingdao Wenchuang Science & Technology Co., Ltd. |
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