CN103037949B - 基于氨基聚硅氧烷的消泡剂及其制备方法 - Google Patents

基于氨基聚硅氧烷的消泡剂及其制备方法 Download PDF

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Publication number
CN103037949B
CN103037949B CN201180012111.9A CN201180012111A CN103037949B CN 103037949 B CN103037949 B CN 103037949B CN 201180012111 A CN201180012111 A CN 201180012111A CN 103037949 B CN103037949 B CN 103037949B
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group
nhc
formula
antifoam
fluid
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Expired - Fee Related
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CN201180012111.9A
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English (en)
Chinese (zh)
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CN103037949A (zh
Inventor
A·K·保罗
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Wacker Polymer Systems GmbH and Co KG
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Wacker Polymer Systems GmbH and Co KG
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/02—Foam dispersion or prevention
    • B01D19/04—Foam dispersion or prevention by addition of chemical substances
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/02—Foam dispersion or prevention
    • B01D19/04—Foam dispersion or prevention by addition of chemical substances
    • B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
    • B01D19/0413—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing N-atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/02—Foam dispersion or prevention
    • B01D19/04—Foam dispersion or prevention by addition of chemical substances
    • B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
    • B01D19/0409—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing Si-atoms
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/40—Devices for separating or removing fatty or oily substances or similar floating material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3742—Nitrogen containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/10—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/10—Salts
    • C11D7/12—Carbonates bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/10—Salts
    • C11D7/14—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/20—Water-insoluble oxides

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Toxicology (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Analytical Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Degasification And Air Bubble Elimination (AREA)
  • Silicon Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201180012111.9A 2010-03-02 2011-02-21 基于氨基聚硅氧烷的消泡剂及其制备方法 Expired - Fee Related CN103037949B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IN198KO2010 2010-03-02
IN198/KOL/2010 2010-03-02
PCT/EP2011/052510 WO2011107361A2 (en) 2010-03-02 2011-02-21 Amino silicone based antifoam agent and its process of manufacture

Publications (2)

Publication Number Publication Date
CN103037949A CN103037949A (zh) 2013-04-10
CN103037949B true CN103037949B (zh) 2015-02-25

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CN201180012111.9A Expired - Fee Related CN103037949B (zh) 2010-03-02 2011-02-21 基于氨基聚硅氧烷的消泡剂及其制备方法

Country Status (6)

Country Link
US (1) US8481476B2 (enExample)
EP (1) EP2542317B1 (enExample)
JP (2) JP6336243B2 (enExample)
KR (1) KR101447341B1 (enExample)
CN (1) CN103037949B (enExample)
WO (1) WO2011107361A2 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104784980A (zh) * 2015-04-02 2015-07-22 南京四新科技应用研究所有限公司 一种消泡组合物

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201102750D0 (en) 2011-02-16 2011-03-30 Dow Corning Foam control composition
CN104114685B (zh) * 2012-02-16 2017-09-12 道康宁公司 使用硅氧烷蜡的颗粒状漂洗周期泡沫控制剂
DE102012210211A1 (de) * 2012-06-18 2013-12-19 Wacker Chemie Ag Antischaummittel und deren Verwendung in Waschmitteln
GB201314284D0 (en) 2013-08-09 2013-09-25 Dow Corning Cosmetic compositions containing silicones
WO2015022165A1 (en) 2013-08-13 2015-02-19 Dow Corning Corporation Method of forming an antifoam granule
US10144905B2 (en) * 2014-06-30 2018-12-04 Wacker Metroark Chemicals Pvt. Ltd. Composition and process of making an amino silicone based delayed antifoam for use in laundry detergent
US20160066567A1 (en) * 2014-09-09 2016-03-10 Wacker Chemical Corporation Stable defoamers for high electrolyte agricultural formulations
DE102015207890A1 (de) * 2015-04-29 2016-11-03 Wacker Chemie Ag Antischaummittel und deren Verwendung in Waschmitteln
CN105107237B (zh) * 2015-10-12 2017-03-29 江苏四新科技应用研究所股份有限公司 一种有机硅消泡组合物及其制备方法
CN110624524A (zh) * 2018-06-25 2019-12-31 中国石油化工股份有限公司 一种氨基功能化mcm分子筛的制备方法及其应用
CN109011719B (zh) * 2018-08-23 2020-08-18 南京瑞思化学技术有限公司 一种有机硅组合物及其制备方法
EP3636733B1 (en) 2018-10-12 2022-09-21 Wacker Metroark Chemicals Pvt. Ltd. Silicone composition and its application as an additive in detergent composition to enhance foamability and cleaning effect
CN109395435A (zh) * 2018-11-06 2019-03-01 江苏赛欧信越消泡剂有限公司 一种耐高温强碱硅膏的制备方法
WO2023025761A1 (en) * 2021-08-25 2023-03-02 Unilever Ip Holdings B.V. Detergent composition
CN114392587B (zh) * 2022-03-04 2023-08-29 合肥新万成环保科技有限公司 一种氟改性有机硅聚醚消泡剂的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0718018A3 (en) * 1994-12-24 1997-01-22 Dow Corning Sa Foam control agents in the form of particles and their use
CN1583212A (zh) * 2004-05-11 2005-02-23 南京四新科技应用研究所有限公司 耐高温耐强碱有机硅消泡剂乳液组合物及制备方法
CN1806883A (zh) * 2005-12-15 2006-07-26 南京四新科技应用研究所有限公司 一种印制电路板专用消泡剂的制备

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5969110A (ja) * 1982-10-13 1984-04-19 Shin Etsu Chem Co Ltd 自己乳化型消泡剤
US4637890A (en) * 1986-01-23 1987-01-20 The Procter & Gamble Company Detergent composition providing rinse cycle suds and turbidity control containing a soap, quaternary ammonium salt and a silicone
CA1297757C (en) 1986-07-18 1992-03-24 Takahiro Miura Method for the preparation of a silicone defoamer composition
US4894117A (en) 1988-04-28 1990-01-16 Colgate-Palmolive Company Process for manufacturing high bulk density particulate fabric softening synthetic anionic organic detergent compositions
FR2648821A1 (enExample) * 1989-06-22 1990-12-28 Rhone Poulenc Chimie
DE3928867C1 (enExample) 1989-08-31 1990-10-11 Th. Goldschmidt Ag, 4300 Essen, De
JPH0790128B2 (ja) * 1989-11-08 1995-10-04 ダウコーニングアジア株式会社 シリコーン消泡剤組成物
JPH07323204A (ja) 1994-05-30 1995-12-12 Toray Dow Corning Silicone Co Ltd 抑泡剤組成物
DE19739991A1 (de) * 1997-09-11 1999-03-18 Wacker Chemie Gmbh Aminosiloxan-Polyether-Polymere
JPH11158287A (ja) 1997-11-28 1999-06-15 Dow Corning Toray Silicone Co Ltd ジオルガノポリシロキサンおよび固体処理剤
US6426328B2 (en) * 1998-10-27 2002-07-30 Unilever Home & Personal Care, Usa Division Of Conopco Inc. Wrinkle reduction laundry product compositions
ES2239220T3 (es) * 2001-03-21 2005-09-16 Dow Corning Asia Ltd Agente antiespumante de silicona.
DE102004014218A1 (de) * 2004-03-23 2005-10-13 Wacker-Chemie Gmbh Verfahren zur Herstellung von aminofunktionellen Organopolysiloxanen
WO2007108209A1 (ja) * 2006-03-16 2007-09-27 Kao Corporation 染毛剤組成物
JP2007303016A (ja) 2006-05-10 2007-11-22 Nicca Chemical Co Ltd ドライクリーニング用仕上げ剤組成物
DE102007036069A1 (de) * 2007-08-01 2009-02-05 Wacker Chemie Ag Mehrstufiges Verfahren zur Herstellung von Aminoalkylgruppen aufweisenden Organopolysiloxanen

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0718018A3 (en) * 1994-12-24 1997-01-22 Dow Corning Sa Foam control agents in the form of particles and their use
CN1583212A (zh) * 2004-05-11 2005-02-23 南京四新科技应用研究所有限公司 耐高温耐强碱有机硅消泡剂乳液组合物及制备方法
CN1806883A (zh) * 2005-12-15 2006-07-26 南京四新科技应用研究所有限公司 一种印制电路板专用消泡剂的制备

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104784980A (zh) * 2015-04-02 2015-07-22 南京四新科技应用研究所有限公司 一种消泡组合物

Also Published As

Publication number Publication date
CN103037949A (zh) 2013-04-10
KR20120139771A (ko) 2012-12-27
WO2011107361A2 (en) 2011-09-09
JP2013521997A (ja) 2013-06-13
EP2542317A2 (en) 2013-01-09
WO2011107361A3 (en) 2015-09-03
EP2542317B1 (en) 2016-12-07
JP6336243B2 (ja) 2018-06-06
KR101447341B1 (ko) 2014-10-06
US8481476B2 (en) 2013-07-09
JP2018047447A (ja) 2018-03-29
US20120329701A1 (en) 2012-12-27

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