CN103030912A - Method for preparing composite water self-absorbent containing N, N, N-4 (2-hydroxyethyl) hyamine - Google Patents
Method for preparing composite water self-absorbent containing N, N, N-4 (2-hydroxyethyl) hyamine Download PDFInfo
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Abstract
The invention discloses a method for preparing composite water self-absorbent containing N, N, N-4 (2-hydroxyethyl) hyamine. The method adopts quaterisation reaction synthesis to obtain the N, N, N-4 (2-hydroxyethyl) hyamine; and according to the proportion that the mass percentage of the N, N, N-4 (2-hydroxyethyl) hyamine, a super water absorbent, a preservative, a mildew preventive and a complexing agent is (0.001-98 percent) to (0.00001-98 percent) to (0.001-5 percent) to (0.001-5 percent) to (0.001-5 percent), the N, N, N-4 (2-hydroxyethyl) hyamine, the super water absorbent, the preservative, the mildew preventive and the complexing agent are uniformly mixed to obtain the composite water self-absorbent containing the N, N, N-4 (2-hydroxyethyl) hyamine. The product can be widely applied to cultivation of flowers, grass and trees of the farming, forestry and gardening fields and can be particularly applied to the tree and grass planting engineering of desertification control, and the application prospect is wide. The method is simple, is easy to operate, has small investment, and is beneficial to popularization and application.
Description
Technical field
The present invention relates to a kind of N of containing, N, N, the preparation method of the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt belongs to field of new.
Background technology
Desertification of land refers to comprise the land deterioration of the arid area that all factors of weather mutation and mankind's activity cause, and it constitutes a serious threat to the mankind's existence.The major cause that causes desertification is that population fast growth, soil are excessively cultivated, grassland overgraze, indiscriminate felling of trees forest and irrigation method are unreasonable etc., makes the soil become barren, and vegetation is destroyed, severe water and soil erosion.Meanwhile, increasing this phenomenon of desertification of then further having aggravated of drought.
The statistic data that United Nations Environment Programme (UNEP) announces shows that the whole world has the population about 2,100,000,000 to live in desert or the nonirrigated farmland, and wherein 90% belongs to developing country.The arable land in the whole world about 44% is the nonirrigated farmland, and about 30% cultivated plant is grown on the nonirrigated farmland.At present, the soil of global desertification up to 4,000 ten thousand square kilometres, accounts for 1/4 of whole earth land area, is equivalent to the summation of Russia, Canada, China and U.S.A area, and the country that the whole world is affected by desertification has more than 100.Although each state of the whole world is all in the fight of carrying out with desertification, desertification still enlarges with the speed in 50,000～70,000 square kilometres of every year.Expect the year two thousand twenty, about 1/3 arable land will be lost in the whole world.Have approximately every year 1200 ten thousand hectares of soils to disappear, these soils can produce 2,000 ten thousand ton-grain food, and the annual financial loss that causes because of desertification and land deterioration is up to 42,000,000,000 dollars.Desertification of land has caused the series of problems such as the husky district masses drift about aimlessly, people's life is day by day poor, the serious hysteresis of socio-economic development, has become the severe challenge that human society faces.
China is that world's ccd area is large, one of wide, that harm is serious country distributes.According to statistics, have approximately half territory to be in arid and semiarid zone, because windy and artificial destruction to vegetation short of rain, Desertification and Desertification Soil are ever-increasing situation.From latter stage the 1950's to the seventies, China increases about 1500 square kilometres of desertification land every year on average.After entering the eighties, increase every year on average Desertification Soil up to 2460 square kilometres, be equivalent to the land area in a medium county of annual loss, the annual direct economic loss that causes because of desertification is up to more than 540 hundred million yuan.
Desertification of land has been destroyed natural ecological environment, nibbles and threatening the mankind's living space, is endangering social harmony with stable.The increasingly sharpening of desertification makes that the biomass quantitative change is bad, species abundance reduces, and species diversity is constituted a serious threat.Therefore, desertification is the great environmental problem that the whole world faces, and is the major natural disasters that jeopardize human society existence and Sustainable development.So, explore effective ways and the approach of administering desertification, more effectively contain the impetus that desertification is expanded increasingly, improve or the reconstruction ecotope, realize human social, be national governments' Major Strategic problems very deeply concerned.
Effective control of desertification need to be take the state's laws rules as foundation, and the comprehensive treatment scheme of formulating take departments of government is as the basis, take advanced person's improvement technology and improvement method as support.At present, the technological method that prevents and controls desertification is a lot, and main method and countermeasure have: 1. educate grass, sand prevention is windproof; 2. the protection of vegetation and recovery; 3. the exploitation of water resources and management; 4. soil improvement and protection; 5. improve livestock industry production and operation pattern; 6. the method such as social economic environment comprehensive regulation.But in the actual governance process of desertification, often need to adopt multiple feasible method to carry out the comprehensive regulation.In the above-mentioned technological method, educate grass, protection and recovery natural vegetation are the effective ways of desertification treatment.Adopting water-holding agent is to improve to educate one of important means of careless production efficiency.
Use the anti-drought water-retaining agent grass of afforesting in the desertification treatment process, have keeping crop seedling from drought, increasing both production and income, improvement soil, check winds and fix drifting sand, the several functions such as soil conservation, but Effective Raise is educated careless efficient.At present, water-holding agent mostly is super strength water absorbent, and is of a great variety, mainly contains three major types:
1, starch based: carboxymethyl starch, sodium starch glycolate, carboxymethyl starch potassium, carboxymethyl starch ammonium, SANWET, starch-grafted polyacrylic acid potassium, starch-grafted ammonium polyacrylate, starch-grafted polyacrylonitrile hydrolyzed product, starch grafted polyacrylamide etc.;
2, cellulose family: carboxymethyl cellulose, Xylo-Mucine, potassium carboxymethylcellulose, carboxymethyl cellulose ammonium, cellulose graft sodium polyacrylate, cellulose graft polyacrylic acid potassium, cellulose graft ammonium polyacrylate, the polyacrylonitrile hydrolyzed product of cellulose graft, cellulose graft polyacrylamide etc.;
3, synthetic resin: sodium polyacrylate, polyacrylic acid potassium, ammonium polyacrylate, polyacrylamide, sodium acrylate and acrylamide copolymer, potassium acrylate and acrylamide copolymer, ammonium acrylate and acrylamide copolymer, MALEIC ANHYDRIDE-sodium acrylate-acrylamide copolymer, MALEIC ANHYDRIDE-potassium acrylate-acrylamide copolymer, MALEIC ANHYDRIDE-ammonium acrylate-acrylamide copolymer etc.
Above-mentioned existing super strength water absorbent kind is mainly by drinking up the rain or irrigation water and pin moisture and moisten the crops, and in the area of drought, because rainfall amount is few, irrigation water also can't guarantee, lack moisture in the soil, in this case, existing water-holding agent is anhydrous to be absorbed and stores, and can not bring into play well its due effect.In the arid area, still contain a certain amount of moisture in the air, if can utilize the material with hydroscopicity, the long-term airborne moisture of continuous absorption, continuous supplying absorbs to plant and farm crop again, then can significantly alleviate the lack of water phenomenon of plant and farm crop.Therefore, how with airborne moisture absorption and store, discharge again to plant and farm crop and absorb, to satisfy plant and crop growth needs, be the problem that solves in the urgent need to inquiring into, this educates careless efficient to improving, and accelerates desertification treatment speed and has undoubtedly important practical significance.At present, domestic and international research and technology about this respect there is not yet report.
The present invention designs and has synthesized novel deliquescent compound, has very strong Absorb Water deliquescence ability in air, with deliquescent compound and super strength water absorbent and additive compound, has prepared the self-priming aqua.The self-priming aqua is except absorbing rainwater and irrigation water and pinning moisture and moisten the crops, in the arid area, it can also be from air continuous automatic absorption moisture, and moisture stored, again moisture is discharged into soil and moistens plant and farm crop, keep plant and farm crop normal growth, significantly slow down arid to the impact of farm crop, significantly improve surviving rate and the speed of growth of plant and farm crop, reach the purpose that significantly improves production efficiency.By contrast, existing super strength water absorbent but can't be from air automatic absorption moisture, production efficiency obviously reduces.The present invention provides a kind of brand-new self-priming aqua for desertification treatment, has opened up a brand-new approach for desertification treatment, has important practical significance.
Summary of the invention
A kind of N that contains of the present invention, N, N, the preparation method of the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt provides a kind of oxyethane, trolamine, deionized water is mixed with acid, obtains N through synthetic reaction, separating-purifying, N, N, N-four (2-hydroxyethyl) quaternary ammonium salt adds super strength water absorbent, sanitas, mould inhibitor and complexing agent again and mixes, prepare and contain N, N, N, the method for the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt.
A kind of N that contains of the present invention, N, N, the preparation method of the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt, the prepared N that contains, N, N, the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt can be applicable to the cultivation of farming, woods and gardening field flower, grass, trees and farm crop, and careless engineering is educated in the forest cultivation that especially can be applicable to desertification treatment, improve and educate careless efficient, have broad application prospects.
A kind of N that contains of the present invention, N, N, the preparation method of the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt, adopt following technical scheme:
1, N, N, N, synthesizing of N-four (2-hydroxyethyl) quaternary ammonium salt: according to oxyethane, trolamine, the mass percent of acid and deionized water is (0.001%～80%): (0.00001%～80%): (0.00001%～80%): the ratio of (0.00001%～95%), trolamine and water are added reactor, be added dropwise to acid under stirring, obtain the aqueous solution of triethanolamine salt through neutralization reaction, it is 30-120 ℃ in temperature of reaction again, reaction pressure is under the condition of 50-1000kPa, pass into reacting ethylene oxide 0.1h～40h and obtain crude product, crude product removes residual oxyethane and water namely obtains N at 50～100 ℃ through underpressure distillation, N, N, N-four (2-hydroxyethyl) quaternary ammonium salt;
2, contain N, N, N, the preparation of the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt: according to N, N, N, N-four (2-hydroxyethyl) quaternary ammonium salt, super strength water absorbent, sanitas, the mass percent of mould inhibitor and complexing agent is (0.001%～98%): (0.00001%～98%): (0.001%～5%): (0.001%～5%): the ratio of (0.001%～5%), and with N, N, N, N-four (2-hydroxyethyl) quaternary ammonium salt, super strength water absorbent, sanitas, mould inhibitor and complexing agent mix, and namely obtain containing N, N, N, the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt.
A kind of N that contains of the present invention, N, N, the preparation method of the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt, its outstanding feature is: owing to having adopted easy deliquescence to have the N of hydroscopicity, N, N, N-four (2-hydroxyethyl) quaternary ammonium salt so that product can be from air continuous automatic absorption moisture, continuous supplying absorbs to plant and farm crop again, therefore, even use this compound self-priming aqua in the arid area, also can significantly alleviate the lack of water phenomenon of plant and farm crop, greatly improve the forest cultivation of desertification treatment engineering and educate careless efficient and flower, grass, the cultivation efficient of trees and farm crop.
A kind of N that contains of the present invention, N, N, the preparation method of the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt reacts used acid and is in hydrochloric acid, Hydrogen bromide, hydroiodic acid HI, sulfuric acid, nitric acid, phosphoric acid, formic acid, acetic acid, propionic acid, butyric acid, Phenylsulfonic acid and the tosic acid any one or more.
A kind of N that contains of the present invention, N, N, the preparation method of the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt, used super strength water absorbent is carboxymethyl starch, sodium starch glycolate, carboxymethyl starch potassium, the carboxymethyl starch ammonium, SANWET, starch-grafted polyacrylic acid potassium, starch-grafted ammonium polyacrylate, starch-grafted polyacrylonitrile hydrolyzed product, starch grafted polyacrylamide, carboxymethyl cellulose, Xylo-Mucine, potassium carboxymethylcellulose, carboxymethyl cellulose ammonium, the cellulose graft sodium polyacrylate, the cellulose graft polyacrylic acid potassium, the cellulose graft ammonium polyacrylate, the polyacrylonitrile hydrolyzed product of cellulose graft, the cellulose graft polyacrylamide, sodium polyacrylate, polyacrylic acid potassium, ammonium polyacrylate, polyacrylamide, sodium acrylate and acrylamide copolymer, potassium acrylate and acrylamide copolymer, ammonium acrylate and acrylamide copolymer, MALEIC ANHYDRIDE-sodium acrylate-acrylamide copolymer, MALEIC ANHYDRIDE-potassium acrylate-acrylamide copolymer, in MALEIC ANHYDRIDE-ammonium acrylate-acrylamide copolymer any one or more.
A kind of N that contains of the present invention, N, N, the preparation method of the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt, used sanitas is any one or more in phenylformic acid, Sodium Benzoate, potassium benzoate, Sodium Nitrite, formaldehyde, trioxymethylene, Paraformaldehyde 96, Whitfield's ointment, methyl p-hydroxybenzoate, ethyl p-hydroxybenzoate, propylparaben, Sorbic Acid, sodium sorbate, the potassium sorbate.
A kind of N that contains of the present invention, N, N, the preparation method of the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt, used mould inhibitor is any one or more in dodecyl benzyl dimethyl ammonium chloride, dodecyl dimethyl benzyl ammonium bromide, phenol, pentachlorophenol, the p-cresol.
A kind of N that contains of the present invention, N, N, the preparation method of the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt, used complexing agent is any one or more in ethylenediamine tetraacetic acid (EDTA), disodium EDTA, Trisodium Citrate, Tripotassium Citrate, ammonium citrate, sodium tartrate, soluble tartrate, ammonium tartrate, the Seignette salt.
Embodiment
The below is a kind of N of containing of the present invention, N, N, the preparation method's of the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt non-limiting example.Providing of these examples only is for illustrative purposes, can not be interpreted as limitation of the invention.Because without departing from the spirit and scope of the present invention, can carry out many conversion to the present invention.In these embodiments, unless stated otherwise, all per-cent all refers to mass percent.
Embodiment 1
N, N, N, N-four (2-hydroxyethyl) ammonium chloride synthetic:
Oxyethane 11%
Trolamine 32%
36% hydrochloric acid 21%
Deionized water 36%
According to above-mentioned mass percent, trolamine and deionized water are added reactor, being added dropwise to 36% hydrochloric acid under stirring, obtaining the aqueous solution of triethanolamine hydrochloride through neutralization reaction, is 80 ℃ in temperature of reaction again, reaction pressure is under the condition of 100kPa, slowly pass into reacting ethylene oxide 20h and obtain crude product, crude product removes residual oxyethane and water namely obtains N, N at 85 ℃ through underpressure distillation, N, N-four (2-hydroxyethyl) ammonium chloride;
Contain N, N, N, the preparation of the compound self-priming aqua of N-four (2-hydroxyethyl) ammonium chloride:
According to above-mentioned mass percent, with N, N, N, N-four (2-hydroxyethyl) ammonium chloride, SANWET, cellulose graft polyacrylamide, sodium acrylate and acrylamide copolymer, Sodium Benzoate, methyl p-hydroxybenzoate, phenol, dodecyl benzyl dimethyl ammonium chloride, disodium EDTA and soluble tartrate mix, and namely obtain containing N, N, N, the compound self-priming aqua of N-four (2-hydroxyethyl) ammonium chloride.
Embodiment 2
N, N, N, N-four (2-hydroxyethyl) ammonium sulfate synthetic:
Oxyethane 10%
Trolamine 30%
50% sulfuric acid 20%
Deionized water 40%
According to above-mentioned mass percent, trolamine and deionized water are added reactor, being added dropwise to 50% sulfuric acid under stirring, obtaining the aqueous solution of trolamine vitriol through neutralization reaction, is 85 ℃ in temperature of reaction again, reaction pressure is under the condition of 120kPa, slowly pass into reacting ethylene oxide 18h and obtain crude product, crude product removes residual oxyethane and water namely obtains N, N at 90 ℃ through underpressure distillation, N, N-four (2-hydroxyethyl) ammonium sulfate;
Contain N, N, N, the preparation of the compound self-priming aqua of N-four (2-hydroxyethyl) ammonium sulfate:
According to above-mentioned mass percent, with N, N, N, N-four (2-hydroxyethyl) ammonium sulfate, starch grafted polyacrylamide, ammonium polyacrylate, MALEIC ANHYDRIDE-potassium acrylate-acrylamide copolymer, potassium benzoate, propylparaben, pentachlorophenol, Tripotassium Citrate and ammonium tartrate mix, and namely obtain containing N, N, N, the compound self-priming aqua of N-four (2-hydroxyethyl) ammonium sulfate.
Embodiment 3
N, N, N, N-four (2-hydroxyethyl) ammonium phosphate synthetic:
Oxyethane 10%
Trolamine 29%
Phosphoric acid 7%
Deionized water 54%
According to above-mentioned mass percent, trolamine and deionized water are added reactor, being added dropwise to phosphoric acid under stirring, obtaining the phosphatic aqueous solution of trolamine through neutralization reaction, is 88 ℃ in temperature of reaction again, reaction pressure is under the condition of 110kPa, slowly pass into reacting ethylene oxide 16h and obtain crude product, crude product removes residual oxyethane and water namely obtains N, N at 95 ℃ through underpressure distillation, N, N-four (2-hydroxyethyl) ammonium phosphate;
Contain N, N, N, the preparation of the compound self-priming aqua of N-four (2-hydroxyethyl) ammonium phosphate:
According to above-mentioned mass percent, with N, N, N, N-four (2-hydroxyethyl) ammonium phosphate, sodium starch glycolate, starch-grafted ammonium polyacrylate, cellulose graft sodium polyacrylate, potassium acrylate and acrylamide copolymer, Paraformaldehyde 96, Whitfield's ointment, dodecyl dimethyl benzyl ammonium bromide, p-cresol, sodium tartrate and disodium EDTA mix, and namely obtain containing N, N, N, the compound self-priming aqua of N-four (2-hydroxyethyl) ammonium phosphate.
Embodiment 4
N, N, N, N-four (2-hydroxyethyl) ammonium acetate synthetic:
Oxyethane 13%
Trolamine 40%
Acetic acid 16%
Deionized water 31%
According to above-mentioned mass percent, trolamine and deionized water are added reactor, being added dropwise to acetic acid under stirring, obtaining the aqueous solution of trolamine acetate through neutralization reaction, is 90 ℃ in temperature of reaction again, reaction pressure is under the condition of 125kPa, slowly pass into reacting ethylene oxide 10h and obtain crude product, crude product removes residual oxyethane and water namely obtains N, N at 95 ℃ through underpressure distillation, N, N-four (2-hydroxyethyl) ammonium acetate;
Contain N, N, N, the preparation of the compound self-priming aqua of N-four (2-hydroxyethyl) ammonium acetate:
According to above-mentioned mass percent, with N, N, N, N-four (2-hydroxyethyl) ammonium acetate, starch-grafted polyacrylic acid potassium, carboxymethyl starch ammonium, potassium carboxymethylcellulose, MALEIC ANHYDRIDE-sodium acrylate-acrylamide copolymer, sodium polyacrylate, ethyl p-hydroxybenzoate, sodium sorbate, dodecyl benzyl dimethyl ammonium chloride, p-cresol, Trisodium Citrate and disodium EDTA mix, namely obtain containing N, N, N, the compound self-priming aqua of N-four (2-hydroxyethyl) ammonium acetate.
Embodiment 5
N, N, N, N-four (2-hydroxyethyl) paratoluenesulfonic acid ammonium salt synthetic:
Oxyethane 8%
Trolamine 24%
Tosic acid 28%
Deionized water 40%
According to above-mentioned mass percent, trolamine and deionized water are added reactor, being added dropwise to tosic acid under stirring, obtaining the aqueous solution of trolamine tosilate through neutralization reaction, is 85 ℃ in temperature of reaction again, reaction pressure is under the condition of 115kPa, slowly pass into reacting ethylene oxide 13h and obtain crude product, crude product removes residual oxyethane and water namely obtains N, N at 95 ℃ through underpressure distillation, N, N-four (2-hydroxyethyl) paratoluenesulfonic acid ammonium salt;
Contain N, N, N, the preparation of the compound self-priming aqua of N-four (2-hydroxyethyl) paratoluenesulfonic acid ammonium salt:
According to above-mentioned mass percent, with N, N, N, N-four (2-hydroxyethyl) paratoluenesulfonic acid ammonium salt, carboxymethyl starch potassium, starch-grafted polyacrylonitrile hydrolyzed product, cellulose graft ammonium polyacrylate, polyacrylamide, ammonium acrylate and acrylamide copolymer, trioxymethylene, potassium sorbate, dodecyl dimethyl benzyl ammonium bromide, pentachlorophenol, ammonium citrate and Seignette salt mix, namely obtain containing N, N, N, the compound self-priming aqua of N-four (2-hydroxyethyl) paratoluenesulfonic acid ammonium salt.
Embodiment 6
N, N, N, N-four (2-hydroxyethyl) ammonium benzene sulfonate synthetic:
Oxyethane 10%
Trolamine 25%
Phenylsulfonic acid 27%
Deionized water 38%
According to above-mentioned mass percent, trolamine and deionized water are added reactor, being added dropwise to Phenylsulfonic acid under stirring, obtaining the aqueous solution of trolamine benzene sulfonate through neutralization reaction, is 100 ℃ in temperature of reaction again, reaction pressure is under the condition of 115kPa, slowly pass into reacting ethylene oxide 8h and obtain crude product, crude product removes residual oxyethane and water namely obtains N, N at 95 ℃ through underpressure distillation, N, N-four (2-hydroxyethyl) ammonium benzene sulfonate;
Contain N, N, N, the preparation of the compound self-priming aqua of N-four (2-hydroxyethyl) ammonium benzene sulfonate:
According to above-mentioned mass percent, with N, N, N, N-four (2-hydroxyethyl) ammonium benzene sulfonate, SANWET, starch grafted polyacrylamide, Xylo-Mucine, cellulose graft polyacrylic acid potassium, polyacrylic acid potassium, MALEIC ANHYDRIDE-ammonium acrylate-acrylamide copolymer, ammonium acrylate and acrylamide copolymer, Sorbic Acid, formaldehyde, pentachlorophenol and disodium EDTA mix, namely obtain containing N, N, N, the compound self-priming aqua of N-four (2-hydroxyethyl) ammonium benzene sulfonate.
Claims (7)
1. one kind contains N, N, and N, the preparation method of the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt is characterized in that the technical scheme that adopts is:
1. N, N, N, synthesizing of N-four (2-hydroxyethyl) quaternary ammonium salt: according to oxyethane, trolamine, the mass percent of acid and deionized water is (0.001%～80%): (0.00001%～80%): (0.00001%～80%): the ratio of (0.00001%～95%), trolamine and water are added reactor, be added dropwise to acid under stirring, obtain the aqueous solution of triethanolamine salt through neutralization reaction, it is 30-120 ℃ in temperature of reaction again, reaction pressure is under the condition of 50-1000kPa, pass into reacting ethylene oxide 0.1h～40h and obtain crude product, crude product removes residual oxyethane and water namely obtains N at 50～100 ℃ through underpressure distillation, N, N, N-four (2-hydroxyethyl) quaternary ammonium salt;
2. contain N, N, N, the preparation of the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt: according to N, N, N, N-four (2-hydroxyethyl) quaternary ammonium salt, super strength water absorbent, sanitas, the mass percent of mould inhibitor and complexing agent is (0.001%～98%): (0.00001%～98%): (0.001%～5%): (0.001%～5%): the ratio of (0.001%～5%), and with N, N, N, N-four (2-hydroxyethyl) quaternary ammonium salt, super strength water absorbent, sanitas, mould inhibitor and complexing agent mix, and namely obtain containing N, N, N, the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt.
2. preparation method as claimed in claim 1, it is characterized in that a kind of N of containing, N, N, the distinguishing feature of the compound self-priming aqua of N-four (2-hydroxyethyl) quaternary ammonium salt is: owing to having adopted easy deliquescence to have the N of hydroscopicity, N, N, N-four (2-hydroxyethyl) quaternary ammonium salt so that product can be from air continuous automatic absorption moisture, continuous supplying absorbs to plant and farm crop again, therefore, even use this compound self-priming aqua in the arid area, also can significantly alleviate the lack of water phenomenon of plant and farm crop, greatly improve the forest cultivation of desertification treatment engineering and educate careless efficient and flower, grass, the cultivation efficient of trees and farm crop.
3. preparation method as claimed in claim 1 is characterized in that the acid of reacting used is any one or more in hydrochloric acid, Hydrogen bromide, hydroiodic acid HI, sulfuric acid, nitric acid, phosphoric acid, formic acid, acetic acid, propionic acid, butyric acid, Phenylsulfonic acid and the tosic acid.
4. preparation method as claimed in claim 1 is characterized in that used super strength water absorbent is carboxymethyl starch, sodium starch glycolate, carboxymethyl starch potassium, the carboxymethyl starch ammonium, SANWET, starch-grafted polyacrylic acid potassium, starch-grafted ammonium polyacrylate, starch-grafted polyacrylonitrile hydrolyzed product, starch grafted polyacrylamide, carboxymethyl cellulose, Xylo-Mucine, potassium carboxymethylcellulose, carboxymethyl cellulose ammonium, the cellulose graft sodium polyacrylate, the cellulose graft polyacrylic acid potassium, the cellulose graft ammonium polyacrylate, the polyacrylonitrile hydrolyzed product of cellulose graft, the cellulose graft polyacrylamide, sodium polyacrylate, polyacrylic acid potassium, ammonium polyacrylate, polyacrylamide, sodium acrylate and acrylamide copolymer, potassium acrylate and acrylamide copolymer, ammonium acrylate and acrylamide copolymer, MALEIC ANHYDRIDE-sodium acrylate-acrylamide copolymer, MALEIC ANHYDRIDE-potassium acrylate-acrylamide copolymer, in MALEIC ANHYDRIDE-ammonium acrylate-acrylamide copolymer any one or more.
5. preparation method as claimed in claim 1 is characterized in that used sanitas is any one or more in phenylformic acid, Sodium Benzoate, potassium benzoate, Sodium Nitrite, formaldehyde, trioxymethylene, Paraformaldehyde 96, Whitfield's ointment, methyl p-hydroxybenzoate, ethyl p-hydroxybenzoate, propylparaben, Sorbic Acid, sodium sorbate, the potassium sorbate.
6. preparation method as claimed in claim 1 is characterized in that used mould inhibitor is any one or more in dodecyl benzyl dimethyl ammonium chloride, dodecyl dimethyl benzyl ammonium bromide, phenol, pentachlorophenol, the p-cresol.
7. preparation method as claimed in claim 1 is characterized in that used complexing agent is any one or more in ethylenediamine tetraacetic acid (EDTA), disodium EDTA, Trisodium Citrate, Tripotassium Citrate, ammonium citrate, sodium tartrate, soluble tartrate, ammonium tartrate, the Seignette salt.
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| CN116590821B (en) * | 2023-05-10 | 2024-02-06 | 潮州市苏菲亚时装有限公司 | Synthesis method and application of breathable polyester fabric |
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| CN1314924A (en) * | 1997-08-14 | 2001-09-26 | 陶氏化学公司 | Hydroxy-functionalized poly(amino ether) salts |
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|---|---|---|---|---|
| JPS57106717A (en) * | 1980-12-17 | 1982-07-02 | Kanebo Synthetic Fibers Ltd | Porous synthetic vinyl fiber having water and moisture absorbing property |
| CN1314924A (en) * | 1997-08-14 | 2001-09-26 | 陶氏化学公司 | Hydroxy-functionalized poly(amino ether) salts |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116590821B (en) * | 2023-05-10 | 2024-02-06 | 潮州市苏菲亚时装有限公司 | Synthesis method and application of breathable polyester fabric |
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