CN103030433A - Novel ceramic glaze and manufacturing technique thereof - Google Patents
Novel ceramic glaze and manufacturing technique thereof Download PDFInfo
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- CN103030433A CN103030433A CN2012105398406A CN201210539840A CN103030433A CN 103030433 A CN103030433 A CN 103030433A CN 2012105398406 A CN2012105398406 A CN 2012105398406A CN 201210539840 A CN201210539840 A CN 201210539840A CN 103030433 A CN103030433 A CN 103030433A
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Abstract
The invention discloses a novel ceramic glaze which comprises a base glaze and a coloring pigment, wherein the base glaze comprises the following components in parts by weight: 50-55 parts of SiO2, 10-11 parts of Al2O3, 9-10 parts of CaO, 20-30 parts of MgO, 20-30 parts of P2O5, 2-4 parts of SrO, 5-6 parts of ZnO, 3-4 parts of K2O, 2-3 parts of Na2O, 3-4 parts of Li2O, 0.2-0.4 part of sodium carboxymethyl cellulose and 2-3 parts of Zr2O.
Description
Technical field
The present invention relates to a kind of new ceramics glaze and manufacture craft thereof.
Background technology
Ceramic glaze is the work in-process of producing porcelain, the general designation parent glaze, and it is to utilize multiple pottery formulated according to a certain percentage with raw material.This ratio is more stable through the performance of lot of experiments acquisition.Its composition: feldspar, quartz, alkaline earth metal oxide (oxide compound and the kaolin that comprise calcium, magnesium, barium, zinc), auxiliary material.Briefly: ceramic pigment is pottery pigment.It is that different metal oxides forms through high-temperature calcination according to different ratio proportionings again.Ceramic pigment generally uses together with base oil, to produce the ceramic product of different colour systems.
The producing and manufacturing technique of domestic ceramics industry traditional ceramics coloured glaze is: join according to a certain percentage ceramic coloring pigment or metal oxide in the parent glaze, and ball milling mixes and makes coloured glaze together, then take to soak the method for glaze or glaze spraying, coloured glaze is fixed on the ceramic body, form the coloured glaze glaze layer of 0.1-0.3mm, at last with on have product firing temperature and the calcining system as required of coloured glaze to fire, thereby obtain a kind of ceramic with the color color.But, according to this ceramic color glaze producing and manufacturing technique, there are many weak points in the product of producing: the bright-coloured degree of the colour generation of color is larger to the dependency of parent glaze, the chemical ingredients of parent glaze has considerable influence to the colour generation of colorant, so require different tinting pigments will have different parent glazes to be complementary with it, the color development effect of the best that just can reach, it is larger to guarantee that like this each color all reaches best color development effect technical difficulty, and technique is more numerous and diverse; Easily produce aberration in the ceramic product edges and corners, especially special-shaped and large part product aberration is obvious especially, because ceramic glaze is in a kind of glass rheology when high temperature, it can move down along product surface under action of gravity, and tinting pigment is blended in the glaze, it is mobile together that it can follow the glaze layer, cause at last the local color of glaze bed thickness dark, thin local of light color of glaze layer causes the whole irregular colour of stopping of product even and form aberration, the number of times that such product flashes back is more, and aberration is obvious; To the high coloured glaze product of the heavy metals such as leaded, cadmium easily segregation out human body is damaged.When there is larger aberration in ceramic color glaze product, there are at present a lot of technician to remedy with regard to taking to beat colo(u)r streak in the product edges and corners or beating golden-rimmed mode, but do not have to solve the problem that there is aberration in ceramic color glaze goods, so not only cost is high, and not attractive in appearance at all.
Summary of the invention
For the shortcoming of prior art, the invention provides a kind of new ceramics glaze and manufacture craft thereof.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
A kind of new ceramics glaze comprises basic glaze and tinting pigment, and wherein, described basic glaze comprises following component and weight proportion: Si0
2, 50～55 parts, A1
20
311 parts of 10-, 9～10 parts of Ca0,20～30 parts of Mg0, P
20
520～30 parts, 2～4 parts of Sr0,5～6 parts of Zn0, K
23～4 parts of O, Na
20 2～3 parts, Li
20 3～4 parts, 0.2～0.4 part of Xylo-Mucine, Zr
20 2～3 parts.
Described tinting pigment is one or several mixtures in ferric oxide, chromic oxide, cupric oxide, weisspiessglanz, nickel oxide, cobalt oxide, stannic oxide, the manganese oxide.
The present invention also provides a kind of technique for preparing the new ceramics glaze, comprises the steps:
S1: the preparation of basic glaze:
S2: get 30～40 parts of the silica powders that 325 orders or thinner mesh screen sieve, get 30～40 parts of the feldspars in powder that 325 orders or thinner mesh screen sieve, get 5～8 parts of the kaolin that 325 orders or thinner mesh screen sieve, 7～10 parts of boraxs, 4～6 parts in zinc oxide, 3～4 parts of zirconium silicates, 8～12 parts in calcium carbonate, 4～8 parts in magnesiumcarbonate. 2～4 parts of Vanadium Pentoxide in FLAKESs, 3～4 parts of Strontium carbonate powders, 5～7 parts of Quilonum Retards, 0.2～0.4 part of Xylo-Mucine;
S3: after above-mentioned raw materials mixed, 1350 ℃～1500 ℃ fusings, put into the cold water shrend and make frit;
S4: the preparation of tinting pigment: be 10:(4～7 according to weight ratio with tinting pigment and water) prepare, and colorant suspension agent mixing and stirring can use, described colorant suspension agent is 1～2 part of tinting pigment weight percent.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention is by the composition of each material composition, the aberration, color development that solves ceramic color glaze product not just with the problem of the heavy metal contaminations such as lead, cadmium, solve simultaneously tinting pigment or metal oxide to the Dependence Problem of parent glaze, material is so that become more thickness of glaze product simultaneously, moulding is simple, and tack is good.
Embodiment
The present invention is further illustrated below in conjunction with the Concrete facts mode.
EXAMPLE l
Getting the pottery large red of parcel and water is that 10:7 prepares according to weight ratio, and colorant suspension agent (ammonia chloride) weight percent is that 1. 2 parts of mixing and stirring get final product, then the parcel large red pigment that the mode of taking to soak or spray will prepare is fixed on the ceramic body, will form a layer thickness on ceramic body is 0. 02-0. 15mm coat of colo(u)r, then the oxydizing flame pate dure burns till under 1250 ℃ temperature, the high temperature constant temperature time is 80 minutes, firing period is 10 hours, high temperature burn till rear large red firmly sintering on the surface of ceramic body, the mode of taking again to soak or spray is fixed on parent glaze the ceramic surface of porcelain, fire at 1100 ℃ of temperature of glaze firing oxydizing flame at last, the high temperature constant temperature time is 60 minutes, firing period is 6 hours, and it is even so just to be fired into a kind of color development, be colour-stable, color is beautiful, the glaze light, the bright red coloured glaze product of lead and cadmium free heavy metal contamination.
Embodiment 2
Getting the golden yellow pigment of pottery parcel and water is that 5:3 joins and stops according to weight ratio, and colorant suspension agent (magnesium chloride) weight percent is that 2. 5 parts of mixing and stirring get final product, then the parcel orient yellow that the mode of taking to soak or spray will prepare is fixed on the ceramic body, will form a layer thickness on ceramic body is 0. 02-0. 15mm coat of colo(u)r, then the oxydizing flame pate dure burns till under 1270 ℃ temperature, the high temperature constant temperature time is 80 minutes, firing period is 10 hours, high temperature burn till rear golden yellow pigment firmly sintering on the surface of ceramic body, the mode of taking again to soak or spray is fixed on parent glaze the ceramic surface of porcelain, fire at 1130 ℃ of temperature of glaze firing oxydizing flame at last, the high temperature constant temperature time is 60 minutes, firing period is 6 hours, and it is even so just to be fired into a kind of color development, be colour-stable, color is beautiful, the glaze light, the golden yellow coloured glaze product of lead and cadmium free heavy metal contamination.
Embodiment 3
Getting pottery parcel pigment scarlet and water is that 5:2 prepares according to weight ratio, and colorant suspension agent (ammonia chloride) weight percent is that 0.8% mixing and stirring gets final product, then the parcel red lake pigment that the mode of taking to soak or spray will prepare is fixed on the ceramic body, will form a layer thickness on ceramic body is 0. 02-0. 15mm coat of colo(u)r, then the oxydizing flame pate dure burns till under 1265 ℃ temperature, the high temperature constant temperature time is 80 minutes, firing period is 10 hours, high temperature burn till rear pigment scarlet firmly sintering on the surface of ceramic body, the mode of taking again to soak or spray is fixed on parent glaze the ceramic surface of porcelain, fire at 1150c temperature of glaze firing oxydizing flame at last, the high temperature constant temperature time is 60 minutes, firing period is 6 hours, and it is even so just to be fired into a kind of color development, be colour-stable, color is beautiful, the glaze light, the dark red coloured glaze product of lead and cadmium free heavy metal contamination.
Claims (3)
1. a new ceramics glaze comprises basic glaze and tinting pigment, it is characterized in that, described basic glaze comprises following component and weight proportion: Si0
2, 50～55 parts, A1
20
311 parts of 10-, 9～10 parts of Ca0,20～30 parts of Mg0, P
20
520～30 parts, 2～4 parts of Sr0,5～6 parts of Zn0, K
23～4 parts of O, Na
20 2～3 parts, Li
20 3～4 parts, 0.2～0.4 part of Xylo-Mucine, Zr
20 2～3 parts.
2. new ceramics glaze according to claim 1 is characterized in that, described tinting pigment is one or several mixtures in ferric oxide, chromic oxide, cupric oxide, weisspiessglanz, nickel oxide, cobalt oxide, stannic oxide, the manganese oxide.
3. a technique for preparing the new ceramics glaze comprises the steps:
S1: the preparation of basic glaze:
S2: get 30～40 parts of the silica powders that 325 orders or thinner mesh screen sieve, get 30～40 parts of the feldspars in powder that 325 orders or thinner mesh screen sieve, get 5～8 parts of the kaolin that 325 orders or thinner mesh screen sieve, 7～10 parts of boraxs, 4～6 parts in zinc oxide, 3～4 parts of zirconium silicates, 8～12 parts in calcium carbonate, 4～8 parts in magnesiumcarbonate. 2～4 parts of Vanadium Pentoxide in FLAKESs, 3～4 parts of Strontium carbonate powders, 5～7 parts of Quilonum Retards, 0.2～0.4 part of Xylo-Mucine;
S3: after above-mentioned raw materials mixed, 1350 ℃～1500 ℃ fusings, put into the cold water shrend and make frit;
S4: the preparation of tinting pigment: be 10:(4～7 according to weight ratio with tinting pigment and water) prepare, and colorant suspension agent mixing and stirring can use, described colorant suspension agent is 1～2 part of tinting pigment weight percent.
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| CN2012105398406A CN103030433A (en) | 2012-12-14 | 2012-12-14 | Novel ceramic glaze and manufacturing technique thereof |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103360123A (en) * | 2013-07-01 | 2013-10-23 | 安徽鑫民玻璃制品有限公司 | Method for firing manganese-chromium ceramic glaze surface |
| CN103439165A (en) * | 2013-09-11 | 2013-12-11 | 淄博出入境检验检疫局综合技术服务中心 | Preparation method of cobalt-containing ceramic glaze standard sample |
| CN106242290A (en) * | 2016-08-26 | 2016-12-21 | 德化县如瓷生活文化有限公司 | Ferrimanganic rust glaze porcelain and processing technology thereof |
| CN106430974A (en) * | 2016-10-20 | 2017-02-22 | 沈阳建筑大学 | Bovine blood color copper red ceramic glaze and preparation method thereof |
| CN107324775A (en) * | 2017-08-29 | 2017-11-07 | 赵永强 | A kind of pottery of utilization mine tailing production and preparation method thereof |
| CN107365147A (en) * | 2017-08-29 | 2017-11-21 | 赵永强 | A kind of pottery and preparation method thereof |
| CN107619190A (en) * | 2017-10-13 | 2018-01-23 | 沈阳建筑大学 | Tin ash darkviolet point-like metallic crystal ceramic glaze and preparation method thereof |
| CN107915407A (en) * | 2017-11-30 | 2018-04-17 | 南宁市生润科技有限公司 | A kind of black glazed tiles glaze |
| CN108640511A (en) * | 2018-07-27 | 2018-10-12 | 醴陵千汇实业有限公司 | A kind of iron oxide black orange peel glaze and preparation method thereof |
| CN108715539A (en) * | 2018-06-15 | 2018-10-30 | 江西嘉逸陶瓷有限公司 | A kind of brown glaze thermal-resisting ceramic vessel and preparation method thereof |
| CN108793955A (en) * | 2018-07-06 | 2018-11-13 | 福建省德化县嘉威陶瓷有限公司 | A kind of the lavender grey glaze ceramic and its preparation process of high-transmittance |
| CN109704579A (en) * | 2019-03-06 | 2019-05-03 | 盐城工业职业技术学院 | A kind of ceramic glaze and preparation method thereof with antibacterial functions |
| CN110803867A (en) * | 2019-12-16 | 2020-02-18 | 黄奕雯 | Water-soluble black ceramic glaze, glaze and preparation method of ceramic |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101759440A (en) * | 2009-12-18 | 2010-06-30 | 深圳市永丰源实业有限公司 | Lead-free ceramic glaze and preparation process thereof |
| CN101759441A (en) * | 2009-12-31 | 2010-06-30 | 深圳市永丰源实业有限公司 | Ceramic glaze and preparation process thereof |
-
2012
- 2012-12-14 CN CN2012105398406A patent/CN103030433A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101759440A (en) * | 2009-12-18 | 2010-06-30 | 深圳市永丰源实业有限公司 | Lead-free ceramic glaze and preparation process thereof |
| CN101759441A (en) * | 2009-12-31 | 2010-06-30 | 深圳市永丰源实业有限公司 | Ceramic glaze and preparation process thereof |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103360123B (en) * | 2013-07-01 | 2014-12-10 | 安徽鑫民玻璃制品有限公司 | Method for firing manganese-chromium ceramic glaze surface |
| CN103360123A (en) * | 2013-07-01 | 2013-10-23 | 安徽鑫民玻璃制品有限公司 | Method for firing manganese-chromium ceramic glaze surface |
| CN103439165A (en) * | 2013-09-11 | 2013-12-11 | 淄博出入境检验检疫局综合技术服务中心 | Preparation method of cobalt-containing ceramic glaze standard sample |
| CN103439165B (en) * | 2013-09-11 | 2015-09-30 | 淄博出入境检验检疫局综合技术服务中心 | A kind of preparation method containing cobalt ceramic glaze standard sample |
| CN106242290B (en) * | 2016-08-26 | 2019-01-29 | 德化县如瓷生活文化有限公司 | Ferrimanganic rust glaze porcelain and its manufacture craft |
| CN106242290A (en) * | 2016-08-26 | 2016-12-21 | 德化县如瓷生活文化有限公司 | Ferrimanganic rust glaze porcelain and processing technology thereof |
| CN106430974A (en) * | 2016-10-20 | 2017-02-22 | 沈阳建筑大学 | Bovine blood color copper red ceramic glaze and preparation method thereof |
| CN106430974B (en) * | 2016-10-20 | 2019-07-09 | 沈阳建筑大学 | A kind of ox blood color copper red ceramic glaze and preparation method thereof |
| CN107324775A (en) * | 2017-08-29 | 2017-11-07 | 赵永强 | A kind of pottery of utilization mine tailing production and preparation method thereof |
| CN107365147A (en) * | 2017-08-29 | 2017-11-21 | 赵永强 | A kind of pottery and preparation method thereof |
| CN107619190A (en) * | 2017-10-13 | 2018-01-23 | 沈阳建筑大学 | Tin ash darkviolet point-like metallic crystal ceramic glaze and preparation method thereof |
| CN107915407A (en) * | 2017-11-30 | 2018-04-17 | 南宁市生润科技有限公司 | A kind of black glazed tiles glaze |
| CN108715539A (en) * | 2018-06-15 | 2018-10-30 | 江西嘉逸陶瓷有限公司 | A kind of brown glaze thermal-resisting ceramic vessel and preparation method thereof |
| CN108715539B (en) * | 2018-06-15 | 2021-04-27 | 江西嘉逸陶瓷有限公司 | Brown glaze heat-resistant ceramic pot and preparation method thereof |
| CN108793955A (en) * | 2018-07-06 | 2018-11-13 | 福建省德化县嘉威陶瓷有限公司 | A kind of the lavender grey glaze ceramic and its preparation process of high-transmittance |
| CN108793955B (en) * | 2018-07-06 | 2020-06-02 | 福建省德化县嘉威陶瓷有限公司 | High-transmittance pink-green glaze ceramic product and preparation process thereof |
| CN108640511A (en) * | 2018-07-27 | 2018-10-12 | 醴陵千汇实业有限公司 | A kind of iron oxide black orange peel glaze and preparation method thereof |
| CN109704579A (en) * | 2019-03-06 | 2019-05-03 | 盐城工业职业技术学院 | A kind of ceramic glaze and preparation method thereof with antibacterial functions |
| CN110803867A (en) * | 2019-12-16 | 2020-02-18 | 黄奕雯 | Water-soluble black ceramic glaze, glaze and preparation method of ceramic |
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Application publication date: 20130410 |