CN102993939A - Polyurethane primer applied to melamine board - Google Patents

Polyurethane primer applied to melamine board Download PDF

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Publication number
CN102993939A
CN102993939A CN201210502729XA CN201210502729A CN102993939A CN 102993939 A CN102993939 A CN 102993939A CN 201210502729X A CN201210502729X A CN 201210502729XA CN 201210502729 A CN201210502729 A CN 201210502729A CN 102993939 A CN102993939 A CN 102993939A
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China
Prior art keywords
weight parts
main paint
solvent
weight
paint
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CN201210502729XA
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Chinese (zh)
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CN102993939B (en
Inventor
李丙亭
伍小燕
钟玉祥
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Shanghai Libang Changrunfa Coatings Co., Ltd.
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SHANGHAI CHANGRUNFA PAINT CO Ltd
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Priority to CN201210502729.XA priority Critical patent/CN102993939B/en
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Abstract

The invention provides a main paint and a primer which are applied to a melamine board. The main paint comprises the following components in parts by weight: 18-35 parts of alkyd resin, 5-15 parts of hydroxy acrylic resin, 3-7 parts of anti-settling thickening agent, 6-10 parts of solvent and 40-60 parts of padding. The hydroxy acrylic resin in the main paint has the advantages of high hardness, high drying speed, good weather resistance and the like and is matched with the alkyd resin for use to increase the adhesive force of paint. The primer containing the main paint provided by the invention can be directly sprayed on the melamine board without polishing the melamine board, thus the labor cost is saved.

Description

A kind of polyurethane primer that is applied to melamine plate
Technical field
The present invention relates to a kind of priming paint, relate in particular to a kind of polyurethane primer of melamine plate and main paint of described priming paint of being applied to.
Background technology
Human being's production and make the history of painting can pass up to the Stone Age.From a large amount of archaeological materials of having found, confirm, the primitive society before apart from modern 7000, the mankind have just used the original covering with paint materials of preparation such as grease, myron and natural pigment of wild beast, with feather, branch etc., are painted, to reach the purpose of decoration.Along with the progress of human society, after entering the Bronze Age, there is different progress ancient civilized country at that time directly utilizing aspect crude substance preparation coating.Lacquer decorative device and palace, temple just take off from wild lacquer tree as far back as the Shang dynasty in China.Just grasped the technology of tempering tung oil coating processed to the The Spring and Autumn Period, can use raw lacquer and the composite coating of tung oil the period of the Warring States, started the technology that makes used additives in coating, promotion paint development to a New Times.From the Changsha Han tomb at Mawangdui, the paint film of unearthed paint coffin and lacquerware is tough and tensile, and the protective value excellence, absolutely proved in B.C. 2nd century, the maturity that China is used the development of raw lacquer technology to reach.Enter eighties of last century, succeeding in developing of the significant achievement of polymer science theory and various macromolecular compounds put into production, for the paint development has been started the New Times.Succeeded in developing the Synolac of the special filmogen as coating the twenties in last century, from then on various synthetic resins newly developed is applied very soon in coating, coating is entered and take and synthesize filmogen as the main epoch.
In the modern furniture production, general coating is brushed and is difficult to smoothly, so will polish, beats what a smooth basal plane for the brushing effect of back.The aesthetic property of furniture surface depends on the quality of the quality of polishing to a great extent.As everyone knows, now in the furniture production process, no matter be solid wood enterprise or plate fitment enterprise, workload and number at most, the most concentrated be exactly between grinding machine, going wrong maximum is also between grinding machine, polishing workshop section is labor intensive, the workshop section that efficiency is the lowest, a general spraying workman, the polishing workman of 4 left and right of need to arranging in pairs or groups, complex part even higher, say that tactics of human sea was not yet.Because furniture manufacturer material, cost of labor increase, furniture manufacturer has to do effort on reduction material cost and cost of labor, white furniture is used melamine material to account for significant proportion, and in the furniture production process, the polishing operation has consumed great amount of cost.
Summary of the invention
The object of the invention is to overcome above-mentioned deficiency, a kind of priming paint of trimeric cyanamide base material and main paint of priming paint of being applied to is provided, can on the melamine plate, not polish and the direct spraying construction, thereby save labour cost.
The invention provides a kind of main paint that is applied to the melamine plate polyurethane primer, wherein, the component of described main paint is counted and is comprised by weight:
Synolac 18 ~ 35 weight parts;
Hydroxylated acrylic resin 5 ~ 15 weight parts;
Anti-settling thickening material 3 ~ 7 weight parts;
Solvent 6 ~ 10 weight parts;
Filler 40 ~ 60 weight parts;
The acid number of described Hydroxylated acrylic resin is 2 ~ 6 mg KOH/g, and hydroxyl quality percentage composition is 0.8 ~ 1.2%, at pressure, is 101.325kPa, and under the condition that temperature is 23 ℃, the viscosity of described Hydroxylated acrylic resin is 4000 ~ 6000 MPa .s.
Wherein, the solid content of described main paint is 60 ~ 80%.
Preferably, the solid content of described main paint is 70%.
Wherein, described Synolac can be selected from least one in oleum lini Synolac, dehydrated castor oil alkyd resin and acrylic acid modified alkyd resin etc.
Wherein, described solvent can be one or more the mixture in esters solvent, aromatic hydrocarbon solvent, pure ether solvent, ketones solvent or alcoholic solvent etc.Esters solvent can be butylacetate, ethyl acetate, methylcarbonate or 1-Methoxy-2-propyl acetate etc.; Aromatic hydrocarbon solvent can be toluene, dimethylbenzene, trimethylbenzene or durene etc.; The alcohol ether solvent can be glycol propyl ether, butyl glycol ether or propylene glycol propyl ether etc.; Ketones solvent can be pimelinketone or methylethylketone etc.; Alcoholic solvent can be Virahol, propyl carbinol or hexalin etc.
Preferably, described solvent is at least one in butylacetate, ethyl acetate, toluene and dimethylbenzene etc.
Wherein, described filler is selected from least one in calcium carbonate, talcum powder, pure aluminium silicate, calcium sulfate, barium sulfate, silicon-dioxide, mica and Calucium Silicate powder etc.
Preferably, described main paint also comprises the auxiliary agent of 1 ~ 3 weight part.
Wherein, described auxiliary agent can be one or more in siccative, toughner, defoamer, emulsifying agent, anti-skinning agent, flow agent, wetting agent, sanitas, freeze-thaw stabiliser or thickening material etc.
The present invention also provides a kind of polyurethane primer that is applied to melamine plate, comprises main paint mentioned above, also comprises solidifying agent, and wherein, curing agent component is counted and comprised by weight:
HDI tripolymer 35 ~ 50 weight parts;
TDI tripolymer 10 ~ 22 weight parts;
Solvent 30 ~ 50 weight parts;
Wherein, HDI refers to hexamethylene diisocyanate (Hexamethylene Diisocyanate), and TDI refers to tolylene diisocyanate, and the TDI tripolymer refers to the tripolymer of tolylene diisocyanate.
Wherein, the solid content of described solidifying agent is 35 ~ 45%.
Preferably, the solid content of described solidifying agent is 40%.
Wherein, the solvent in described solidifying agent can be one or more the mixture in esters solvent, aromatic hydrocarbon solvent, pure ether solvent, ketones solvent or alcoholic solvent etc.Esters solvent can be butylacetate, ethyl acetate, methylcarbonate or 1-Methoxy-2-propyl acetate etc.; Aromatic hydrocarbon solvent can be toluene, dimethylbenzene, trimethylbenzene or durene etc.; The alcohol ether solvent can be glycol propyl ether, butyl glycol ether or propylene glycol propyl ether etc.; Ketones solvent can be pimelinketone or methylethylketone etc.; Alcoholic solvent can be Virahol, propyl carbinol or hexalin etc.
Preferably, the solvent in described solidifying agent is at least one in butylacetate, ethyl acetate, toluene and dimethylbenzene etc.
In main paint provided by the present invention, it is high that Hydroxylated acrylic resin has hardness, rate of drying is fast, the advantages such as good weatherability, use with the Synolac collocation, can significantly improve the sticking power of paint, use the priming paint containing main paint provided by the invention, can on the melamine plate, not polish and the direct spraying construction, thereby save labour cost.
Embodiment
The polyurethane primer that is applied to melamine plate provided by the present invention, the component of described main paint is counted and is comprised by weight:
Synolac 18 ~ 35 weight parts;
Hydroxylated acrylic resin 5 ~ 15 weight parts;
Anti-settling thickening material 3 ~ 7 weight parts;
Solvent 6 ~ 10 weight parts;
Filler 40 ~ 60 weight parts;
Auxiliary agent 1 ~ 3 weight part;
The acid number of Hydroxylated acrylic resin is 2 ~ 6 mg KOH/g, and hydroxyl quality percentage composition is 0.8 ~ 1.2%, at pressure, is 101.325kPa, and under the condition that temperature is 23 ℃, the viscosity of described Hydroxylated acrylic resin is 4000 ~ 6000 MPa .s.
Below by specific embodiment, the present invention is carried out to detailed and concrete introduction, so that better understand the present invention, but following embodiment does not limit the scope of the invention.
In following content, method therefor unless otherwise noted, is this area ordinary method.
The polyurethane primer that is applied to melamine plate provided by the present invention, curing agent component is counted and is comprised by weight:
HDI tripolymer 35 ~ 50 weight parts;
TDI tripolymer 10 ~ 22 weight parts;
Solvent 30 ~ 50 weight parts.
embodiment 1
The polyurethane primer that is applied to melamine plate that the present embodiment provides, its main paint component is counted and is comprised by weight:
Synolac 26 weight parts;
Hydroxylated acrylic resin 10 weight parts;
Anti-settling thickening material 5 weight parts;
Butylacetate 8 weight parts;
Talcum powder 49 weight parts;
Defoamer 1 weight part;
Flow agent 1 weight part;
Siccative 1 weight part.
Synolac, Hydroxylated acrylic resin, anti-settling thickening material, talcum powder, defoamer, flow agent, siccative etc. are added in container, after middling speed stirring 5-10min is even, add butyl acetate solvent, middling speed stirs 5 ~ 10 minutes, both winner's paint.
Solidifying agent:
HDI tripolymer 43 weight parts;
TDI tripolymer 16 weight parts;
Solvent 41 weight parts.
The main paint made is mixed and makes priming paint with appropriate solidifying agent, according to GB 1720-79(89) " paint film adhesion assay method " mensuration sticking power, detected result is secondary.
embodiment 2
The main paint component that is applied to melamine plate that the present embodiment provides is counted and is comprised by weight:
Synolac 26 weight parts;
Hydroxylated acrylic resin 10 weight parts;
Anti-settling thickening material 5 weight parts;
Dimethylbenzene 8 weight parts;
Mica 49 weight parts;
Defoamer 1.5 weight parts;
Flow agent 0.5 weight part.
Synolac, Hydroxylated acrylic resin, anti-settling thickening material, mica, defoamer, flow agent are added in container, after middling speed stirring 5-10min is even, add xylene solvent, middling speed stirs 5 ~ 10 minutes, both winner's paint.
Solidifying agent is identical with embodiment 1.
The main paint made is mixed and makes priming paint with appropriate solidifying agent, according to GB 1720-79(89) " paint film adhesion assay method " mensuration sticking power, detected result is secondary.
embodiment 3
The main paint component that is applied to melamine plate that the present embodiment provides is counted and is comprised by weight:
Synolac 35 weight parts;
Hydroxylated acrylic resin 15 weight parts;
Anti-settling thickening material 5 weight parts;
Butylacetate 8 weight parts;
Talcum powder 49 weight parts;
Defoamer 1 weight part;
Flow agent 1 weight part.
Synolac, Hydroxylated acrylic resin, anti-settling thickening material, talcum powder, defoamer, flow agent are added in container, after middling speed stirring 5-10min is even, add butyl acetate solvent, middling speed stirs 5 ~ 10 minutes, both winner's paint.
Solidifying agent is identical with embodiment 1.
The main paint made is mixed and makes priming paint with appropriate solidifying agent, according to GB 1720-79(89) " paint film adhesion assay method " mensuration sticking power, detected result is secondary.
embodiment 4
The main paint component that is applied to melamine plate that the present embodiment provides is counted and is comprised by weight:
Synolac 30 weight parts;
Hydroxylated acrylic resin 15 weight parts;
Anti-settling thickening material 5 weight parts;
Butylacetate 4 weight parts;
Dimethylbenzene 4 weight parts;
Talcum powder 40 weight parts;
Defoamer 0.5 weight part;
Flow agent 1 weight part.
Synolac, Hydroxylated acrylic resin, anti-settling thickening material, talcum powder, defoamer, flow agent are added in container, after middling speed stirring 5-10min is even, add successively butylacetate, dimethylbenzene equal solvent, middling speed stirs 5 ~ 10 minutes, both winner's paint.
Solidifying agent is identical with embodiment 1.
The main paint made is mixed and makes priming paint with appropriate solidifying agent, according to GB 1720-79(89) " paint film adhesion assay method " mensuration sticking power, detected result is secondary.
embodiment 5
The main paint component that is applied to melamine plate that the present embodiment provides is counted and is comprised by weight:
Synolac 18 weight parts;
Hydroxylated acrylic resin 10 weight parts;
Anti-settling thickening material 4 weight parts;
Dimethylbenzene 8 weight parts;
Mica 40 weight parts;
Defoamer 1 weight part;
Flow agent 1 weight part;
Siccative 1 weight part.
Synolac, Hydroxylated acrylic resin, anti-settling thickening material, mica, defoamer, flow agent, siccative etc. are added in container, after middling speed stirring 5-10min is even, add xylene solvent, middling speed stirs 5 ~ 10 minutes, both winner's paint.
Solidifying agent is identical with embodiment 1.
The main paint made is mixed and makes priming paint with appropriate solidifying agent, according to GB 1720-79(89) " paint film adhesion assay method " mensuration sticking power, detected result is secondary.
In main paint provided by the present invention, it is high that Hydroxylated acrylic resin has hardness, and rate of drying is fast, and the advantages such as good weatherability are used with the Synolac collocation, significantly improve the sticking power of paint.
Solvent is mainly butyl ester, dimethylbenzene etc., and good wettability and release property can be provided.Anti-settling thickening material can prevent the sinking of filler the dilution that improves paint vehicle.Auxiliary agent can improve paint film levelling, froth breaking and dry fast problem.Use the paint base composition containing main paint provided by the invention, can on the melamine plate, not polish and the direct spraying construction, thereby save labour cost.
Above specific embodiments of the invention be have been described in detail, but it is just as example, the present invention is not restricted to specific embodiment described above.To those skilled in the art, any equivalent modifications that the present invention is carried out and alternative also all among category of the present invention.Therefore, equalization conversion and the modification done without departing from the spirit and scope of the invention, all should contain within the scope of the invention.

Claims (10)

1. a main paint that is applied to the melamine plate polyurethane primer, is characterized in that, the component of described main paint is counted and comprised by weight:
Synolac 18 ~ 35 weight parts;
Hydroxylated acrylic resin 5 ~ 15 weight parts;
Anti-settling thickening material 3 ~ 7 weight parts;
Solvent 6 ~ 10 weight parts;
Filler 40 ~ 60 weight parts;
The acid number of described Hydroxylated acrylic resin is 2 ~ 6 mg KOH/g, and hydroxyl quality percentage composition is 0.8 ~ 1.2%, at pressure, is 101.325kPa, and under the condition that temperature is 23 ℃, the viscosity of described Hydroxylated acrylic resin is 4000 ~ 6000 MPa .s.
2. main paint according to claim 1, is characterized in that, the solid content of described main paint is 60 ~ 80%.
3. main paint according to claim 3, is characterized in that, the solid content of described main paint is 70%.
4. main paint according to claim 1, is characterized in that, described solvent is butylacetate, ethyl acetate, toluene or dimethylbenzene.
5. main paint according to claim 1, is characterized in that, described filler is selected from least one in calcium carbonate, talcum powder, pure aluminium silicate, calcium sulfate, barium sulfate, silicon-dioxide, mica and Calucium Silicate powder.
6. main paint according to claim 1, is characterized in that, described main paint also comprises the auxiliary agent of 1 ~ 3 weight part.
7. main paint according to claim 6, is characterized in that, described adjuvant component contains one or more in defoamer, flow agent, siccative, emulsifying agent, sanitas or freeze-thaw stabiliser.
8. a polyurethane primer that is applied to melamine plate, is characterized in that, comprises main paint as claimed in claim 1, also comprises solidifying agent, and wherein, curing agent component is counted and comprised by weight:
HDI tripolymer 35 ~ 50 weight parts;
TDI tripolymer 10 ~ 22 weight parts;
Solvent 30 ~ 50 weight parts.
9. priming paint according to claim 8, is characterized in that, the solid content of described solidifying agent is 35 ~ 45%.
10. priming paint according to claim 9, is characterized in that, the solid content of described solidifying agent is 40%.
CN201210502729.XA 2012-11-30 2012-11-30 A kind of polyurethane primer being applied to melamine plate Active CN102993939B (en)

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Application Number Priority Date Filing Date Title
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105176361A (en) * 2015-07-23 2015-12-23 三棵树涂料股份有限公司 Low-VOC polyurethane high-light varnish
CN105273588A (en) * 2014-06-29 2016-01-27 江苏飞翔涂料实业总公司 Thermosetting coating used for exterior decorative part of bicycle
CN105733435A (en) * 2016-03-23 2016-07-06 山东巴德士化工有限公司 PU high-fullness matte varnish for melamine board
CN106098333A (en) * 2016-07-30 2016-11-09 罗杰 A kind of power transformer
CN110922869A (en) * 2019-11-25 2020-03-27 广东花王涂料有限公司 Clear primer for scientific wood veneer and preparation method thereof
CN111349386A (en) * 2020-04-28 2020-06-30 上海君子兰新材料股份有限公司 Polyurethane transparent primer and preparation method and construction method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5438085A (en) * 1992-06-12 1995-08-01 Burkett; John Simulated leather-like coating for a vehicle substrate
CN1603369A (en) * 2003-09-29 2005-04-06 上海富臣化工有限公司 Synthetic resin paint for curtain-imitating wall interlayer

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5438085A (en) * 1992-06-12 1995-08-01 Burkett; John Simulated leather-like coating for a vehicle substrate
CN1603369A (en) * 2003-09-29 2005-04-06 上海富臣化工有限公司 Synthetic resin paint for curtain-imitating wall interlayer

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105273588A (en) * 2014-06-29 2016-01-27 江苏飞翔涂料实业总公司 Thermosetting coating used for exterior decorative part of bicycle
CN105176361A (en) * 2015-07-23 2015-12-23 三棵树涂料股份有限公司 Low-VOC polyurethane high-light varnish
CN105733435A (en) * 2016-03-23 2016-07-06 山东巴德士化工有限公司 PU high-fullness matte varnish for melamine board
CN106098333A (en) * 2016-07-30 2016-11-09 罗杰 A kind of power transformer
CN106098333B (en) * 2016-07-30 2017-11-10 嵊州市万智网络科技有限公司 A kind of power transformer
CN110922869A (en) * 2019-11-25 2020-03-27 广东花王涂料有限公司 Clear primer for scientific wood veneer and preparation method thereof
CN111349386A (en) * 2020-04-28 2020-06-30 上海君子兰新材料股份有限公司 Polyurethane transparent primer and preparation method and construction method thereof

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Address after: 201506 No. 578 Xia Sheng Road, Jinshan District, Shanghai

Patentee after: Shanghai Libang Changrunfa Coatings Co., Ltd.

Address before: 201506 No. 578 Xia Sheng Road, Jinshan District, Shanghai

Patentee before: Shanghai Changrunfa Paint Co., Ltd.

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