CN102977697A - Floor polishing agent composition with anti-static function - Google Patents
Floor polishing agent composition with anti-static function Download PDFInfo
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- CN102977697A CN102977697A CN2012105691543A CN201210569154A CN102977697A CN 102977697 A CN102977697 A CN 102977697A CN 2012105691543 A CN2012105691543 A CN 2012105691543A CN 201210569154 A CN201210569154 A CN 201210569154A CN 102977697 A CN102977697 A CN 102977697A
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Abstract
The invention discloses a floor polishing agent composition with an anti-static function. The floor polishing agent composition with the anti-static function is prepared from the following components by weight percent: 25.0-75.0% of a metal-crosslinking or self-crosslinking polymer film forming agent, 0.1-0.5% of multiwalled carbon nanotubes, 2.0-8.0% of a film forming assistant, 0.001-3.0% of a wetting dispersant, 0.1-1.0% of a defoaming agent, 0.0-5.0% of a plasticizer, 0.0-15.0% of alkaline soluble resin, 0.0-20% of wax emulsion, 0.0-0.5% of a bactericide and the balance of water. The composition provided by the invention contains the metal-crosslinking or self-crosslinking polymer film forming agent and the multiwalled carbon nanotubes, and the coating has the anti-static function after film formation, so that static accumulation is effectively eliminated, surface statics can be favorably released, the functional degradation, invalidation or abandonment phenomenon of electronic elements under a static discharging environment is reduced, the appearance effects of attractive appearance, cleanness, transparency and brightness are kept, and a floor can be protected from being scratched and is wear-resistant and antifouling.
Description
Technical field
The present invention relates to chemical technology field, particularly a kind of ground polishing agent combination with electrostatic-proof function.
Background technology
The floor surface of various base materials often adopts ground lustering agent or rumbling compound coating to carry out daily nursing as plastic floor (as PVC, flax, rubber floor covering), stone material, wood floors and cement based ground etc.,, protection floor attractive in appearance to play and prevent the effect of dirt infiltration.But the coating of these ground lustering agents or rumbling compound, the Performance Ratio of dispersion and conduct charges is poor, and static is easily assembled at floor surface, makes easily sticky ash of floor.More seriously for microelectronics factory, machine room, electronically controlled chamber, telecommunication apparatus district, responsive medical diagnosis equipment etc. require higher place to anti-electrostatic, static the gathering of floor surface may cause electronic devices and components functional deterioration, lost efficacy or scrapped.
Summary of the invention
The purpose of this invention is to provide a kind of ground rumbling compound combination with electrostatic-proof function; polymer film-forming agent and the multi-walled carbon nano-tubes of the crosslinked or self-crosslinking of described composition containing metal; give the coating electrostatic-proof function after film forming; effectively eliminate electrostatic accumulation, contribute to release surface static, reduce electronic devices and components under the static discharge environment functional deterioration, lost efficacy or scrapped; and keep clean, transparent glossy appearance effect attractive in appearance; can protect floor to avoid scratching, resistance to wear, resistant
.
The object of the present invention is achieved like this:
A kind of ground polishing agent combination with electrostatic-proof function is characterized in that its material consists of by weight:
25.0 ~ 75.0% metal corsslinking or the polymer film-forming agent of self-crosslinking,
0.1 ~ 0.5% multi-walled carbon nano-tubes,
2.0 ~ 8.0% film coalescence aid,
0.001 ~ 3.0% wetting dispersing agent,
0.0 ~ 1.0% defoamer,
0.0 ~ 5.0% softening agent,
0.0 ~ 15.0% alkali soluble resins,
0.0 ~ 20% wax emulsion,
0.0 ~ 0.5% sterilant and the water of surplus, gross weight is in 100%.
The polymer film-forming agent of described metal corsslinking or self-crosslinking is one or more in benzene emulsion, pure-acrylic emulsion, organosilicon crylic acid latex.
Described multi-walled carbon nano-tubes can be the carbon nanotube of powder or the dispersion liquid of carbon nanotube.
Described film coalescence aid is diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol propyl ether, dipropylene glycol monomethyl ether, Dipropylene glycol mono-n-butyl Ether, 2,2,4-trimethylammonium-1, one or more mixing in 3-pentanediol-vinylformic acid mono-methyl.
Described wetting dispersing agent is one or more mixing in high fluoro-alkyl sulfonic acid ammonium salt, polyether silicone, fluorocarbon surfactant, fatty alcohol-polyoxyethylene ether, alkynol class, decynediol class, alkynol epoxy adduct.
Described defoamer is a kind of or its several mixing in silicone based resin system, mineral oil system, polar organic compounds.
Described softening agent is one or more mixing in dibutyl phthalate, tributoxyethyl phosphate.
Described wax emulsion is one or more mixing in polythene wax emulsion, polypropylene wax emulsion, polyolefine graft acrylic acid emulsion.
Polymer film-forming agent and the multi-walled carbon nano-tubes of the crosslinked or self-crosslinking of composition containing metal of the present invention; give the coating electrostatic-proof function after film forming; effectively eliminate electrostatic accumulation; contribute to release surface static; reduce electronic devices and components under the static discharge environment functional deterioration, lost efficacy or scrapped, and keep clean, transparent glossy appearance effect attractive in appearance, can protect floor to avoid scratching; resistance to wear, resistant
.
Embodiment
Following examples further illustrate application of the present invention, but scope of the present invention are not produced to any restriction.
In following examples, the main raw material(s) of using is described as follows:
Sunpolymer-200, the self-crosslinking acrylic ester polymer emulsion, solid content 38%, 45 ℃ of second-order transition temperatures, Shanghai Sanrui Chemistry Co., Ltd produces;
Sunpolymer-300, zinc cross linked acrylic styrene polymer emulsion, solid content 38%, 65 ℃ of second-order transition temperatures, Shanghai Sanrui Chemistry Co., Ltd produces;
FSJ, fluorocarbon surfactant, content 40%, E.I.Du Pont Company produces;
Tegopren 5878, polyether silicone surfactants, German goldschmidt chemical corporation production;
SYNTRAN WE1401, polythene wax emulsion, solid content 38%, because safe polymkeric substance trade (Shanghai) Co., Ltd. provides;
SYNTRAN 1560, alkali soluble resins, and solid content 25%, because safe polymkeric substance trade (Shanghai) Co., Ltd. provides;
2-3168, the silicone resin defoamer, provided by Dow Corning Corporation;
Kathon, sterilant, provided by the Dow Chemical Company;
CARBOBYK-9810, the multi-walled carbon nano-tubes dispersion liquid, content of carbon nanotubes is that 8%, BYK company provides.
Embodiment 1
A kind of ground polishing agent combination with electrostatic-proof function, its formula is (weight percent):
The ground polishing agent combination A formula of table 1 electrostatic-proof function
* because content of carbon nanotubes in CARBOBYK-9810 is 8%, therefore in above-mentioned formula, the content of multi-walled carbon nano-tubes in formula is: 0.18%.
Under low rate mixing (about 60rpm) effect, add component according to upper tabular order order, after dispersing or dissolving evenly, a component can be added dropwise to next component, after all components is uniformly dispersed, keep stirring 30 minutes, obtain composition A of the present invention.
Embodiment 2
A kind of ground polishing agent combination with electrostatic-proof function, its formula is (weight percent):
The ground polishing agent combination B formula of table 2 electrostatic-proof function
* because content of carbon nanotubes in CARBOBYK-9810 is 8%, therefore in above-mentioned formula, the content of multi-walled carbon nano-tubes in formula is: 0.312%.
Under low rate mixing (about 60rpm) effect, add component according to upper tabular order order, after dispersing or dissolving evenly, a component can be added dropwise to next component, after all components is uniformly dispersed, keep stirring 30 minutes, obtain composition B of the present invention.
Test:
The above-mentioned polishing agent combination prepared is coated on pure white PVC base material, and glue spread is 50g/m2, is coated with 3 layers, every all over being coated with interval time more than 30 minutes.Coated test plate (panel), place 24 hours.Surface resistivity with surface resistivity determinator testing coating.Result is as shown in the table:
Table 3 polishing agent combination coating obtains resistance
Claims (2)
1. the ground polishing agent combination with electrostatic-proof function, it is characterized in that said composition by weight its material consist of:
The polymer film-forming agent 25.0 ~ 75.0% of metal corsslinking or self-crosslinking,
Multi-walled carbon nano-tubes 0.1 ~ 0.5%,
Film coalescence aid 2.0 ~ 8.0%,
Wetting dispersing agent 0.001 ~ 3.0%,
Defoamer 0.0 ~ 1.0%,
Softening agent 0.0 ~ 5.0%,
Alkali soluble resins 0.0 ~ 15.0%,
Wax emulsion 0.0 ~ 20%,
Sterilant 0.0 ~ 0.5%,
And the water of surplus, gross weight is in 100%; Wherein:
The polymer film-forming agent of described metal corsslinking or self-crosslinking is one or more in benzene emulsion, pure-acrylic emulsion, organosilicon crylic acid latex;
Described film coalescence aid is diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol propyl ether, dipropylene glycol monomethyl ether, Dipropylene glycol mono-n-butyl Ether, 2,2,4-trimethylammonium-1, one or more mixing in 3-pentanediol-vinylformic acid mono-methyl;
Described wetting dispersing agent is one or more mixing in high fluoro-alkyl sulfonic acid ammonium salt, polyether silicone, fluorocarbon surfactant, fatty alcohol-polyoxyethylene ether, alkynol class, decynediol class, alkynol epoxy adduct;
Described defoamer is one or more mixing in silicone based resin system, mineral oil system, polar organic compounds;
Described softening agent is one or more mixing in dibutyl phthalate, tributoxyethyl phosphate;
Described wax emulsion is one or more mixing in polythene wax emulsion, polypropylene wax emulsion, polyolefine graft acrylic acid emulsion.
2. the ground polishing agent combination with electrostatic-proof function according to claim 1, is characterized in that described multi-walled carbon nano-tubes is powder or dispersion liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105691543A CN102977697A (en) | 2012-12-25 | 2012-12-25 | Floor polishing agent composition with anti-static function |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012105691543A CN102977697A (en) | 2012-12-25 | 2012-12-25 | Floor polishing agent composition with anti-static function |
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| CN102977697A true CN102977697A (en) | 2013-03-20 |
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| CN2012105691543A Pending CN102977697A (en) | 2012-12-25 | 2012-12-25 | Floor polishing agent composition with anti-static function |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103849267A (en) * | 2014-03-28 | 2014-06-11 | 立邦涂料（中国）有限公司 | Water-based paint composition and preparation method thereof |
| CN104650659A (en) * | 2013-11-15 | 2015-05-27 | 埃科莱布美国股份有限公司 | Antistatic high-gloss wear-resistant floor coating composition |
| CN104974673A (en) * | 2014-12-02 | 2015-10-14 | 裴萌 | Shoe polish |
| CN105506637A (en) * | 2015-12-01 | 2016-04-20 | 安徽天思朴超精密模具股份有限公司 | Metal polishing agent material composition and preparation method and application of metal polishing agent |
| CN106566410A (en) * | 2016-11-04 | 2017-04-19 | 广西钱隆投资管理有限公司 | Car wax and preparation method thereof |
| CN107523221A (en) * | 2013-04-28 | 2017-12-29 | 艺康美国股份有限公司 | Stone material crystal face treatment compositions and its manufacture method |
| CN109971361A (en) * | 2019-04-02 | 2019-07-05 | 广州市众道汽车有限公司 | A kind of automobile finish polishing agent and preparation method thereof |
| CN111040219A (en) * | 2019-12-27 | 2020-04-21 | 合肥乐凯科技产业有限公司 | Anti-adhesion antistatic polyester film |
| CN111944432A (en) * | 2020-08-31 | 2020-11-17 | 康丽莱(山东)环境科技有限公司 | Quick-drying brightener and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1693392A (en) * | 2004-05-09 | 2005-11-09 | 中国科学院成都有机化学有限公司 | Electrostatic conducting corrosion-proof coating and preparation process thereof |
| CN101037571A (en) * | 2007-04-25 | 2007-09-19 | 上海三瑞化学有限公司 | Low-luster polishing agent combination and preparation method thereof |
-
2012
- 2012-12-25 CN CN2012105691543A patent/CN102977697A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1693392A (en) * | 2004-05-09 | 2005-11-09 | 中国科学院成都有机化学有限公司 | Electrostatic conducting corrosion-proof coating and preparation process thereof |
| CN101037571A (en) * | 2007-04-25 | 2007-09-19 | 上海三瑞化学有限公司 | Low-luster polishing agent combination and preparation method thereof |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107523221A (en) * | 2013-04-28 | 2017-12-29 | 艺康美国股份有限公司 | Stone material crystal face treatment compositions and its manufacture method |
| CN104650659A (en) * | 2013-11-15 | 2015-05-27 | 埃科莱布美国股份有限公司 | Antistatic high-gloss wear-resistant floor coating composition |
| CN103849267A (en) * | 2014-03-28 | 2014-06-11 | 立邦涂料（中国）有限公司 | Water-based paint composition and preparation method thereof |
| CN103849267B (en) * | 2014-03-28 | 2016-07-13 | 立邦涂料（中国）有限公司 | A kind of water-based paint compositions and preparation method thereof |
| CN104974673A (en) * | 2014-12-02 | 2015-10-14 | 裴萌 | Shoe polish |
| CN105506637A (en) * | 2015-12-01 | 2016-04-20 | 安徽天思朴超精密模具股份有限公司 | Metal polishing agent material composition and preparation method and application of metal polishing agent |
| CN106566410A (en) * | 2016-11-04 | 2017-04-19 | 广西钱隆投资管理有限公司 | Car wax and preparation method thereof |
| CN109971361A (en) * | 2019-04-02 | 2019-07-05 | 广州市众道汽车有限公司 | A kind of automobile finish polishing agent and preparation method thereof |
| CN111040219A (en) * | 2019-12-27 | 2020-04-21 | 合肥乐凯科技产业有限公司 | Anti-adhesion antistatic polyester film |
| CN111040219B (en) * | 2019-12-27 | 2022-05-03 | 合肥乐凯科技产业有限公司 | Anti-adhesion antistatic polyester film |
| CN111944432A (en) * | 2020-08-31 | 2020-11-17 | 康丽莱(山东)环境科技有限公司 | Quick-drying brightener and preparation method thereof |
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Application publication date: 20130320 |